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Young explosive eruptions from the Clear Lake volcanic field

The Clear Lake volcanic field is the northernmost and youngest field in a chain of volcanic fields in and near the California Coast Range mountains. For 2 million years, numerous eruptions have happened around (and through) Clear Lake. The most recent period of activity in the Clear Lake volcanic field probably started around 40,000 years ago and was mainly explosive eruptions concentrated on and near faults in and around the lake. The combination of hot magma and groundwater created explosive releases of hot steam. The craters, called maars, threw out volcanic ash, pumice, and lava fragments, which fell back to the ground and draped the surrounding landscape. The deposits are visible in many places around the southeast end of the lake.

California

Sediment thickness map of United States Atlantic and Gulf Coastal Plain Strata, and their influence on earthquake ground motions

With the recent successful accounting of basin depth ground-motion adjustments in seismic hazard analyses for select areas of the western United States, we move toward implementing similar adjustments in the Atlantic and Gulf Coastal Plains by constructing a sediment thickness model and evaluating multiple relevant site amplification models for central and eastern United States seismic hazard analyses. We digitize and combine existing sediment thickness data sets into a composite surface that delineates the base of Cretaceous sediments under the Atlantic Coastal Plain and the base of Mesozoic sediments under the Gulf Coastal Plain. Amplification models dependent on sediment thickness, site natural period, and source-to-site path length are compared with data sets of observed ground motions to evaluate the ability of the new models to improve ground motion estimates. We find that the amplification models can account for observed trends in sediment-thickness and period-dependent residuals, but some tuning is required. For example, the model of Chapman and Guo requires a reference V S 30 , the time-averaged shear-wave velocity within 30 m of the Earth’s surface, for non-Coastal Plain sites, which we estimate to be between about 1 and 2 km/s. Along with our sediment thickness model, we estimate a velocity profile for application to the Harmon et al. site-natural-period-based model in order to best match the Chapman and Guo period dependence for a broad range of sediment thicknesses. The Next Generation of Attenuation models for the eastern United States Gulf Coast path-based adjustment models can also account for seismic attenuation in the Coastal Plain sediments and reduce the standard deviation of total residuals. If enacted in the U.S. Geological Survey National Seismic Hazard Model, these amplification models will reduce predicted short-period (<1 s) and increase predicted long-period (>1 s) ground motions in the Coastal Plains appreciably.

Earthquake Spectra

Triple-oxygen isotopic evidence of prolonged direct bioleaching of pyrite with O2

Sulfate is often touted as containing atmospheric oxygen whose isotopic signature can constrain redox, environmental conditions, and biological activity. Yet, the amount and isotopic fractionation associated with air-O 2 incorporation during sulfate formation is still debated, making its verification difficult. In this study, we identify a distinct, microbially dominated environment with the potential to preserve maximum signals of air-O 2 in sulfate. We report triple-oxygen isotope data for sulfate produced from pyrite oxidation in microbial and abiotic experiments, and from natural dissolved sulfate from the Rio Tinto, Spain, an acid mine drainage site. The oxygen isotope systematics of sulfate in these environments define a unique kinetic isotope effect associated with initial stage pyrite oxidation by Acidithiobacillus ferrooxidans that preserves >80 % oxygen from air-O 2 in sulfate. Unlike experiments, which evolve toward water-oxygen dominated sulfate on short time scales, Rio Tinto, Spain hosts a microbe rich environment with distinct geochemistry that maintains high O 2 -oxygen in sulfate. Therefore, in addition to containing isotopic records from water and air, sulfates can also contain a biosignature that is promising for understanding conditions on Mars and early Earth.

Earth and Planetary Science Letters

Simulation of groundwater flow and brine discharge to the Dolores River in the Paradox Valley, Montrose County, Colorado

Salinity, or total dissolved solids (TDS), of the Colorado River affects agricultural, municipal, and industrial water users and is an important concern in the Western United States. In the Paradox Valley of southwestern Colorado, natural discharge of sodium-chloride brine to the Dolores River from the underlying core of a salt-valley anticline accounts for about 6 percent of the salinity load to the Colorado River. Formation of the Paradox Valley began during the Miocene, and subsequent erosion exposed the Pennsylvania Paradox Formation in the core of the anticline where a cap rock, collapse features, breccia, and sodium-chloride saturated brine developed at the top of the exposed salt diapir. The discharge of brine to the Dolores River is affected by these dissolution features, along with seasonal hydrologic conditions and density-dependent flow between older dense brine and the younger fresh groundwater in the overlying alluvial aquifer. To reduce TDS concentrations in the Dolores River through the Paradox Valley, the Bureau of Reclamation has pumped brine from a series of shallow wells adjacent to the river since July 1996. The pumped brine is collected and piped to a deep disposal well where it is injected into the Mississippian Leadville Limestone at a depth of about 4,570-meters below land surface. The pumping and injection operation is collectively known as the Paradox Valley Unit (PVU), and by 2015, the PVU had substantially reduced TDS concentrations in the Dolores River by about 70 percent. Since 2019, injection-pressure limits and related seismic activity have constrained deep-well injection and thus brine pumping at the PVU. In cooperation with the Bureau of Reclamation, the U.S. Geological Survey developed a MODFLOW-6 three-dimensional, variable-density groundwater flow and TDS transport model of the Paradox Valley to evaluate the effects of PVU pumping operations on brine discharge to the Dolores River and to guide additional research. The finite-difference model grid consists of 76 rows and 48 columns oriented from northwest to southeast in alignment with valley topography and groundwater-flow directions in the near-surface freshwater alluvial aquifer. A 7-layer hydrogeologic framework was developed from existing datasets to represent the alluvial aquifer, cap rock, collapse breccia, and groundwater flow and TDS transport from the underlying Paradox Formation salt to the Dolores River. The model represents a 33-year transient calibration period from 1987 through 2020 that includes pre-PVU conditions from 1987 through June 1996 and post-PVU conditions from July 1996 through 2020. A 1,000-year simulation of groundwater flow and coupled TDS transport computed the initial conditions for the subsequent 33-year transient simulation. Observations of precipitation, streamflow, evaporation, agricultural land use, and PVU brine pumping rates were used to specify appropriate boundary conditions to the model representing time-varying recharge, tributary streamflow, groundwater underflow, evapotranspiration (ET), and PVU pumping. Values for average monthly streamflow and TDS concentration at the upstream streamgage, the Dolores River at Bedrock (USGS streamgage 09169500), were specified as model input where the Dolores River enters Paradox Valley. Observed pumping from the PVU, water levels and TDS concentrations in groundwater, and streamflow and estimated TDS concentrations at the downstream streamgage, the Dolores River near Bedrock (USGS streamgage 09171100), were calibration targets that constrained the manual calibration of model parameters representing aquifer hydraulic conductivity, storage, streambed conductance, recharge, and (ET). Two primary model-calibration targets were the match between observed and simulated TDS mass flux from PVU pumping wells and the match between estimated and simulated TDS mass flux to the Dolores River. The simulated TDS mass withdrawn by pumping wells is calculated by the model as the product of the assigned pumping rate and simulated groundwater TDS concentrations. Because actual pumping rates were assigned as simulated values, the total simulated PVU pumping for the 33-year calibration is within 0.5 percent of the observed values. However, simulated concentrations and thus mass flux of TDS withdrawn by the PVU pumping wells were consistently about 26 percent less than observed values for all the simulated time periods (33-year simulation, pre-PVU, and post-PVU). The representation of brine inflow was explored through additional modeling to evaluate the effect of the simulated brine source on groundwater TDS concentrations. Results indicated that a saturated-salt constant-flux brine source best replicated the magnitude and transient pattern observed for TDS mass flux from PVU pumping wells. The simulated TDS mass flux to the Dolores River is compared to estimates based on observed streamflow and specific conductance (SC) data for the downstream streamgage. The calibrated model provided a close fit of simulated to measured streamflow at the downstream streamgage, and the calibrated model fit to estimated TDS concentrations at the downstream streamgage was reasonable. The greatest differences between simulated and estimated values occurred during drought periods from June 2000 to March 2003, May 2012 to June 2013, and October 2013 to October 2014, when simulated TDS concentrations in the river were greater than estimated concentrations. In general, simulated TDS mass flux to the river for the pre-PVU period is in good agreement with estimated values (2-percent difference), but the model overestimated TDS mass flux to the river by about 41 percent during the post-PVU period. The model uncertainty with respect to TDS mass flux to the river indicates other processes or model parameters not well represented by the model are affecting the system, especially during drought. During model calibration, the most sensitive parameters were identified as vertical hydraulic conductivity of the alluvial aquifer, conductance of the Dolores River streambed, ET extinction depth and rate, and recharge rate. Five 5-year scenarios of conditions for 2021–25 were simulated to assist evaluation of alternative strategies to manage the discharge of brine into the Dolores River. The first scenario simulates no PVU pumping and serves as a base case for comparison to the other scenarios. Two scenarios simulate the effects of varying withdrawal timing at an annual rate about one-third less than during 2010 through 2018. During high-flow spring snowmelt runoff periods when brine discharge is naturally minimized, PVU pumping does not substantially affect salinity in the Dolores River, and comparison of these two scenarios indicates that scheduling brine withdrawals during times of low river stage is nearly as effective at reducing TDS mass flux to the river as pumping brine year-round. Cessation of pumping during periods of high river stage may be advantageous for system maintenance, brine injection, and seismic-risk reduction. The fourth scenario tested the effect of reducing irrigation-return flow on brine discharge and predicted a slight reduction of TDS mass flux to the Dolores River, but not as great a reduction as that of using the PVU to remove brine. The fifth scenario simulated 5 years of drought conditions without PVU pumping and indicates brine discharge during drought about 15 percent greater than during average hydrologic conditions. Results from scenario 5 are consistent with the calibrated model results and indicate that aquifer properties and ET processes and parameters may be affecting simulation results during drought. The Paradox Valley groundwater model provides a reasonable overall match to observed conditions in the Dolores River. The model is useful for evaluating relative differences between brine management scenarios to inform PVU operational decisions and to identify gaps in data and process understanding. Representation of the brine source, hydraulic-conductivity parameters, and recharge and ET processes were identified as potential areas for additional field and modeling research. Additional research in the Paradox Valley might include field-data collection that provides additional information on the hydrogeologic framework, groundwater levels, groundwater TDS concentrations, stream characteristics, and aquifer properties. Additional modeling efforts could benefit from applying advanced tools for model development, calibration, and visualization including parameter-estimation and sensitivity analysis. Statistical evaluation of known model uncertainties such as hydraulic conductivity, streambed conductance, representations of the brine source, recharge, and ET could improve the match between simulated and estimated TDS mass flux from PVU pumping wells and to the Dolores River further informing model predictions and system understanding for the Paradox Valley.

Colorado

Assessment of density pattern retention of generalized data for 1:100,000-scale United States topographic maps

Cartographic generalization reduces the complexity of geographic data to produce legible, smaller-scale displays that retain essential information and logical geographic patterns. Generalization is a vital process in topographic map production. An important challenge in this process is managing and evaluating consistency across scale in the density and spatial distribution of map features such as buildings, roads, streams, water bodies, and elevation contours. Density patterns in these features reflect underlying physiographic conditions, which include factors such as bedrock geology, tectonics, climate, and landforms. Assessments of an acceptable level of change in feature density patterns are critical to ensuring the readability, usability, and accuracy of generalized maps and data. Preserving realistic density patterns across mapping scales also supports sustainable development goals in cartography, by helping to prioritize and communicate the relative reliability of geospatial data at specific scales.

Conference Paper

Bayesian mapping of regionally grouped, sparse, univariate earth science data

Some earth science data are naturally grouped by region, and it is often desirable to map these data by region. However, if there are only a few samples within each region, then the map should be smoothed in an appropriate way to mitigate the problems that arise from having only a few samples. A smoothing algorithm based on a Bayesian hierarchical model is developed and presented in this report. This algorithm has several features that make it especially suitable for mapping earth science data: it can account for measurements that are censored, it can process multiple datasets with different measurement errors and different censoring thresholds, and it can calculate the uncertainty in any statistic that is mapped. The algorithm is demonstrated by mapping gold concentrations that are measured in streambed sediments in the Taylor Mountains quadrangle in southwestern Alaska.

Alaska

Global performance of remote sensing-based and reanalysis-driven models to estimate open water evaporation

Evaporation plays an essential role in the water cycle, influencing local and regional climates while directly impacting water availability in lakes. However, directly measuring evaporation over water bodies remains challenging due to the high costs of installing and maintaining the required in situ instrumentation. Although several remote sensing algorithms have been providing evaporation estimates, the lack of a global validation hinders our understanding of their relative uncertainties and performances across different regions. Here, we analyze the performance of a suite of models that leverage satellite data and meteorological reanalysis to estimate evaporation over lakes worldwide. We compare 3 remote sensing-based models, 1 reanalysis-driven model and 1 ensemble approach, using in situ observations from 27 lakes representing a diverse range of geographic and climatic regions. Our results demonstrate that, overall, the ensemble outperformed any individual model in terms of accuracy, with a RMSE and a bias of 1.3 and 0.3 mm day −1 , respectively. These findings highlight the benefits of using an ensemble approach to estimate open water evaporation with satellite-based models at the global scale, leveraging the unique strengths of each model. For the individual models, differences in the representation of heat storage changes and advection effects led to lower values of RMSE and bias, depending on the location and depth of the lakes. This study sets the path for future improvement of open water evaporation algorithms globally, while remote sensing techniques are proven satisfactory to monitoring of water loss in lakes globally, an essential step toward effective large-scale water resources management.

Water Resources Research

U.S. Geological Survey—Department of the Interior, Region 11, Alaska—2023–24 biennial science report

Introduction U.S. Geological Survey (USGS) Mission—The USGS national mission is to monitor, analyze, and predict the current and evolving dynamics of complex human and natural Earth-system interactions and to deliver actionable information at scales and timeframes relevant to decision makers. Consistent with the national mission, the USGS in Alaska provides timely and objective scientific information to help address issues and inform management decisions across five interconnected focus areas: Energy and Minerals; Geospatial Mapping; Natural Hazards; Water Quality, Streamflow, and Ice Dynamics; and Ecosystems. The USGS in Alaska consists of approximately 350 scientists and support staff working in 3 Alaska-based science centers. USGS science activities are also initiated by the Cooperative Research Unit and USGS centers outside Alaska. In the last 5 years, USGS research in Alaska has produced many scientific benefits resulting from more than 900 publications. Publications relevant to Alaska can be conveniently searched by keyword through the USGS Publications Warehouse at https://pubs.usgs.gov/.

Alaska

Near-surface material and topography generate anomalous high-frequency ground motion amplification in Chugiak, Alaska

An ∼3 km long nodal array oriented approximately east–west was deployed in Chugiak, Alaska, by the U.S. Geological Survey during 2021. The array intersects with the permanent NetQuakes station NP.ARTY, where peak ground acceleration (PGA) value of 1.98 g was recorded during the 2018 M w 7.1 Anchorage, Alaska, earthquake, in sharp contrast to the PGA of ∼0.3 g at a site just 4 km to the west. Seismic data for M w 1.8–4.3 aftershocks from the M w 7.1 event recorded by the nodal array confirm the anomalously large ground motions obtained at NP.ARTY as well as similar amplifications at nodes within ∼1 km to the east. Here, we performed 0–10 Hz 3D finite‐difference simulations, including high‐resolution surface topography, to explore the cause of the unexpectedly large amplification. As expected, the simulations computed with a regional 3D tomography velocity model severely underpredict the 0–10 Hz acceleration records at almost all sites. Adding a near‐surface low‐velocity taper to 300 m depth amplifies the accelerations by up to a factor of 5 and enables a reasonable match between the nodal data and simulations at sites to the west of NP.ARTY. However, this model still underpredicts the spectral energy in the area covered by glacial sediments by up to an order of magnitude. The addition of a till layer using a depth‐dependent shear‐wave velocity ( ⁠⁠ V s ) profile along with a homogeneous, 8 m thick low‐velocity layer with V s = 250 m/s representing the kame terraces improves the fit to data to within a factor of 2 at nodes located on top of the glacial sediments. Our study shows that the anomalously large high‐frequency amplification recorded at and near NP.ARTY can be explained by a combination of topographic effects and near‐surface low‐velocity material with amplification effects on the high‐frequency ground motion by up to about 40% and an order of magnitude, respectively.

Alaska

Rapid emplacement of the Keaiwa Lava Flow of 1823 from the Great Crack in the Southwest Rift Zone of Kilauea volcano

The Keaīwa Lava Flow of 1823 in the Southwest Rift Zone of Kīlauea volcano is unusual for its expansive pāhoehoe sheet flow morphology and lack of constructive vent topography, despite having a similar tholeiitic basalt composition to other lavas erupted from Kīlauea. This lava flow issued from a ∼10-km-long continuous fissure now known as the Great Crack, and has an unusually thin sheet flow morphology with margin thicknesses of ∼15–110 cm (average of 42 cm). Based on field observations of the lava flow at its fissure vent (e.g., drain-back features), we propose that the Great Crack formed, or at least significantly widened, just prior to and syn-eruptively with this 1823 eruption. The absence of pyroclastic cones or spatter ramparts indicates that the eruption consisted of a rapid outpouring of relatively degassed lava as the fissure unzipped. The rapidly moving lava flow overtopped pre-existing tumuli and scoria cones (e.g., Lava Plastered Cones) up to ∼10 m tall. Glass and whole-rock chemistry yield homogeneous compositions for the lavas erupted from the Great Crack, with glass compositions of 6.40 ± 0.10 wt% MgO and whole-rock compositions of 7.39 ± 0.07 wt% MgO. Lava pads erupted from a short western fissure system are richer in mafic minerals (e.g., olivine and clinopyroxene), and show slightly more MgO-rich whole-rock compositions (7.79 ± 0.05 wt%). MgO-in-glass thermometry on juvenile spatter yield eruption temperatures of 1153 ± 13°C that are typical of Kīlauea lavas. Thus, the extensive sheet-like lava flow morphology is not a direct consequence of unusual magmatic or rheological conditions (i.e., low viscosity). Instead, the flow morphology is associated with high effusion rates caused by sudden drainage of uprift magma as it erupted from the Great Crack. Lava flow modeling on a 2-m-resolution digital elevation model indicates that a minimum bulk effusion rate of ∼5800 m 3 /s (∼3500 m 3 /s dense rock equivalent) and a minimum flow velocity of ∼11 m/s are required for the lava flow to overcome the topography of the Lava Plastered Cones. This effusion rate is among the highest inferred for eruptions in Hawaiʻi and around the world. This study highlights a less frequent eruption style at Hawaiian volcanoes characterized by a sudden outpouring of lava from an unusual fissure system. Local eyewitness accounts indicate that the 1823 eruption was preceded by seismicity. Given the complex magmatic-volcanic-tectonic relations across Kīlauea, we speculate that the south flank could have slipped over one or more events that ultimately triggered unzipping of the Great Crack and passive release of briefly stored uprift magma. An eruption similar to 1823 at Kīlauea or Mauna Loa, with an eruptive timeframe that could be as short as an hour, with high effusion rates and rapid flow front velocities, would not easily allow for a timely response.

Hawaii

Central Valley Hydrologic Model version 2 (CVHM2): Decision support tool for groundwater and land subsidence management

The San Joaquin Valley (SJV) of California is one of the world’s most productive agricultural regions. Reliance on groundwater has led to some of the greatest rates of human-induced land subsidence in the world in the 20th century, as well as more recently. The United States Geological Survey (USGS) has recently developed an integrated surface–subsurface hydrologic model, the Central Valley Hydrologic Model 2 (CVHM2), that represents the major components of the hydrologic system of California’s Central Valley. In this study, CVHM2 was applied as a decision support tool while simulating various management strategies to mitigate the land subsidence caused by the extraction of groundwater. CVHM2 was extended through to 2073 and applied to simulate management scenarios in terms of three primary drivers and their impact on subsidence along the Delta–Mendota Canal (DMC), a critical piece of infrastructure in the western SJV. The drivers considered were agricultural water demands, managed aquifer recharge (MAR), and changes in future climate. The results show that future subsidence is most sensitive to water demands, second most sensitive to future changes in climate, and relatively insensitive to MAR when it is applied as a surface application in the western SJV. However, we demonstrate via proof-of-concept scenarios that the MAR is capable of arresting subsidence when implemented via injection below the Corcoran Clay Member of the Tulare Formation instead of as a surface application. We also examine the uncertainty that is the result of climate variability and how to use the tool to identify the most appropriate strategies to constrain future subsidence to acceptable levels.

California

Special issue "Effects of surface geology on seismic motion (ESG): General state-of-research"

To understand and predict the behaviors of strong ground motions incurred during devastating earthquakes, studies focused on the “effects of surface geology (ESG) on seismic motions” (following tradition, herein contracted as: “ESG”) have progressed steadily in the last three decades. These ESG studies typically involve in situ measurements of the wavefield and commonly apply both analytical and computational approaches. Concurrently, improvements in ESG related research can be readily attributed to the proliferation of openly accessible strong motion data, as well as advances in computational power. Nevertheless, there remain significant shortfalls in our understanding of the epistemic and aleatory uncertainties associated with the ESG as demonstrated by phenomena from recent deadly earthquake-related site effects. Thus, investigations toward addressing these deficiencies should be underscored in future earthquake related disaster mitigation efforts. This special issue of Earth, Planets, and Space (EPS) is dedicated to the ongoing efforts by the International Association of Seismology and Physics of the Earth’s Interior (IASPEI) and the International Association of Earthquake Engineering (IAEE) that champion activities promoting studies related to the ESG.

Earth, Planets and Space

Hydrogeologic characterization of the Cahuilla Valley and Terwilliger Valley Groundwater Basins, Riverside County, California

The relation between the groundwater and the amount of natural recharge to the Cahuilla Valley and Terwilliger Valley groundwater basins is not well understood. During the 20th century, the reliance on groundwater near Anza, California, used for agricultural, domestic, and municipal reasons has increased, and there is the potential for changes in groundwater availability related to climate change. Several types of existing data were evaluated, and new data were collected for this study, with the goal of characterizing the region’s hydrogeology. The study’s scope included constructing a geologic framework model to show where the groundwater-bearing units are present and their relation to each other, estimating the major components of the groundwater budget, and understanding local short-term and regional long-term groundwater flow and how that has changed since the early 1900s. Two electrical resistivity tomography surveys were done in the Durasno Valley about 2,150 feet apart to identify the thickness of the alluvium, its horizontal extent, and the depth-to-basement along two profiles perpendicular to Cahuilla Creek. The subsurface sediments were mostly horizontally layered and the transitional boundary between the alluvium and basement was thinner and shallower along the upgradient profile where the depth-to-basement was about 70 feet below land surface; the depth-to-basement at the downgradient profile was more than about 140 feet below land surface. The results from the surveys were used to place four monitoring wells at two sites along the survey profiles. Artesian flow from the deepest well at the downgradient site indicated that the decomposed and competent basement likely contributed some groundwater to the overlying alluvium, laterally, from below, or both. A digital three-dimensional geologic framework model was constructed using EarthVision software to represent the subsurface geometry of the alluvium, decomposed basement, and competent basement. Maps and cross sections of the modeled thicknesses of the alluvium and decomposed basement, and the modeled elevation of the top of the competent basement, were made to show the subsurface geometry of vertical faults, selected wells, and the groundwater-bearing units. Because natural recharge is related to the variable cycles of precipitation, estimates are difficult to quantify. Recharge and runoff have extreme interannual variability in the study area; recharge and runoff can be sporadic, and a substantive amount may not occur in some years. Estimates of recharge from a previous study and the regional-scale Basin Characterization Model for California for four different periods ranged from 3,800 acre-feet/year for 1897–1947 to 5,900 acre-feet/year for 1971–2000. Potential recharge from the disposal of domestic septic systems may have been as much as 500 acre-feet in 2020. It was estimated that between about 400 and 2,400 acre-feet/year of groundwater is lost through evapotranspiration by vegetation and evaporation from open water bodies, but the main source of discharge is through pumpage, mainly used for agriculture from the alluvium in the Cahuilla Valley and Terwilliger Valley groundwater basins. The estimated total pumpage for 1991–2021 ranged from about 1,140 acre-feet in 2019 to about 3,450 acre-feet in 1994. When summed, the cumulative amount of estimated pumpage between 1991 and 2021 was about 81,400 acre-feet. The general direction of groundwater flow is from the northeast along the San Jacinto fault zone at the headwaters of Cahuilla and Hamilton Creeks, to the surface-water outlets at the west and southeast parts of the study area. Groundwater-level data from the 1950s and earlier indicate that there was a natural groundwater divide between the Cahuilla Valley and Terwilliger Valley groundwater basins, but the changing magnitude and extent of the groundwater depressions caused by pumping since about 1950 indicate that the location of the natural groundwater boundary between the Cahuilla Valley and Terwilliger Valley groundwater basins has migrated over time. Flow from the upper to the lower parts of the Cahuilla Valley groundwater basin roughly follows the course of Cahuilla Creek through the narrow Durasno Valley where an estimated volume of flow in April 2019 was about 10–150 acre-feet/year. Short-term trends in groundwater levels, particularly in wells where groundwater is shallow and in the basement unit, show how some areas respond quickly to recharge and discharge. Wells located further to the east within the Cahuilla Valley groundwater basin in the alluvium show much less of a response to recharge events; areas of sustained pumpage from the alluvium, primarily for agriculture, show long-term declines in groundwater levels and generally do not show the effects of storm events or recent runoff. Groundwater levels in wells that are farthest from where most of the recharge occurs and where pumping has been the greatest, had some of the largest long-term groundwater-level declines at a rate of about 0.8 foot/year between 1971 and 2021.

California

Environmental monitoring of groundwater, surface water, and soil at the Ammonium Perchlorate Rocket Motor Destruction Facility at the Letterkenny Army Depot, Chambersburg, Pennsylvania, 2021

Letterkenny Army Depot in Chambersburg, Pennsylvania, built an Ammonium Perchlorate Rocket Motor Destruction (ARMD) Facility in 2016 to centralize rocket motor destruction and contain all waste during the destruction process. The U.S. Geological Survey has collected environmental samples from groundwater, surface water, and soils at ARMD since 2016. During 2021, samples were collected from four groundwater wells in September, one surface-water site in October, and five soil sites in November near the facility. Samples were analyzed for nutrients, trace metals, major ions, total volatile organic compounds, and perchlorate. Perchlorate was not detected in any 2021 samples. Groundwater results showed no constituents exceeded any U.S. Environmental Protection Agency (EPA) maximum contaminant level (MCL). Dissolved arsenic (As) was detected in one well above the reporting detection level (RDL) of 3 micrograms per liter (μg/L) at 5.4 μg/L but below its MCL of 10 μg/L. Dissolved iron (Fe) was the only inorganic constituent measured above an EPA secondary maximum contaminant level (SMCL). All groundwater samples collected in 2021 exceeded the Fe SMCL of 300 μg/L, with concentrations ranging from 390 μg/L to 3,500 μg/L. Surface-water data collected during 2021 showed no measured constituents in the surface-water sample that exceeded any EPA MCL or SMCL. Soil samples collected from 2016 through 2021 showed all concentrations of As exceeded the EPA soil screening levels of 3 milligrams per kilogram (mg/kg) but did not exceed the Pennsylvania medium-specific concentrations for As of 61 mg/kg. Arsenic concentrations in 2021 ranged from 9.1 mg/kg to 12.9 mg/kg. The 2021 results for the ARMD Facility indicate no increases in concentrations of reported compounds compared to data from 2016 to 2020. The contained burn treatment facility for demilitarization of rocket motors during 2021 appears to have operated without elevating concentrations of target compounds compared to previous years.

Pennsylvania

Solution-collapse breccia pipe uranium deposits of the southern Colorado Plateau, northwestern Arizona, USA

Some of the highest-grade uranium deposits in the United States occur in breccia pipes that formed by solution and collapse of sedimentary strata, which occur in the southern portion of the Colorado Plateau in northwestern Arizona. The host breccia pipes are up to 1200 m in vertical extent, average about 90 m in diameter, and can cross-cut strata from their base in the Mississippian Redwall Limestone to as stratigraphically high on some plateaus as the Triassic Chinle Formation. These uranium-base metal deposits are up to 600 m thick and formed within the breccia pipes where they transect the Permian Coconino Sandstone, Hermit Formation, and the Esplanade Sandstone. Of the hundreds of breccia pipes identified across this region, only a small percentage are known to contain mineralization. The main uranium ore mineral is uraninite that is intergrown with at least 20 base-metal sulfide minerals, which contribute Fe, Cu, Co, As, Pb, Zn, Ni, and Ag to the deposits. This study considered regional stratigraphy, sulfur isotope systematics, mineralogy, in situ dating, and compilation and analysis of previous work on the deposits. A comprehensive deposit model has not been published for these deposits. This analysis identified new additions to update the deposit model for these unusual, possibly unique deposits. Proposed modifications to the model include: (1) the source, mechanisms, timing of the base-metal sulfide mineral assemblages, and (2) the source, mechanism, and timing of the uranium mineralization. Sulfide and uranium deposition are shown to be separate mineralization events. The study proposes the possible role of gypsum as a source of sulfur for the sulfide minerals in the deposits. Groundwaters carrying uranium encountered the preexisting sulfides in breccia pipes, reducing the uranyl ions, and precipitating U oxide (as uraninite). Analysis of the regional stratigraphy recognized that numerous beds of gypsum are in the strata that lie only tens of meters above the breccia pipe deposits. In the breccia pipe region, if these stratigraphic units (Toroweap and Kaibab Formations) do not contain gypsum layers then the underlying pipes are not mineralized; where these Permian gypsum layers do occur, breccia pipes can host mineralization. This new understanding should be useful in identifying the prospective region for mineralized pipes.

Arizona

Igneous differentiation in arcs

This chapter assesses crystallization-differentiation of convergent-margin magmas both from the standpoints of natural rock suites and from laboratory phase-equilibrium experiments. Crystallization-differentiation of dry subalkaline and alkaline basalts are summarized at the beginning for reference and context. Experiments crystallizing arc basalts through andesites at middle to upper crustal pressures (100–400 MPa), saturated either with H 2 O or mixed H 2 O-CO 2 , produce liquid lines of descent similar to arc igneous suites, with higher f O 2 s giving results closer to calc-alkaline magma series. Early enrichment of melts in SiO 2 with little or no enrichment in FeO* (total Fe as FeO) comes about by the combined effects of H 2 O suppressing crystallization of plagioclase relative to olivine, shifting plagioclase to more calcic – therefore lower SiO 2 – compositions, and suppressing silicate minerals to greater extents than Fe-rich spinel. Also contributing to SiO 2 enrichment is crystallization near the liquidus of higher proportions of olivine relative to calcic clinopyroxene, compared with MORB, but it is unclear if this is brought about by H 2 O or elevated pressure. Exhumed arc terranes, however, generally fail to expose evidence for primitive liquids having reached and differentiated at middle to upper crustal depths, at least in any abundance. Instead, most differentiation in arcs appears to take place in the lower crust or near the crust-mantle transition, and although hydrous experiments at such pressures produce liquids broadly similar to arc suites in their SiO 2 enrichment, the experimental liquids differ in becoming peraluminous at early stages of differentiation while melts have basaltic, basaltic andesitic, or andesitic SiO 2 concentrations. Crystallization of abundant calcic clinopyroxene close to the liquidus causes the high-pressure experimental liquids to become peraluminous with only small increases in SiO 2 concentration. In contrast, natural arc volcanic and plutonic suites become gradually less metaluminous with increasing SiO 2 , crossing to peraluminous at dacitic to rhyolitic SiO 2 concentrations. Hybridism, encompassing magma-mixing, assimilation of old crust, and incorporation of near-solidus melts from only shortly older deep, antecedent arc intrusions may accompany natural crystallization-differentiation, preventing melts from attaining peraluminous compositions at low-SiO 2 concentrations. If so, then nearly all arc suites are to substantial extents composites, rather than preserving simple, progressive liquid lines of descent. Some comments and assessments are also made on the participation of garnet in arc differentiation and on the production of arc batholiths.

Book chapter

Divisions of geologic time—Major chronostratigraphic and geochronologic units

Effective communication in the geosciences requires consistent uses of stratigraphic nomenclature, especially divisions of geologic time. A geologic time scale is composed of standard stratigraphic divisions based on rock sequences and calibrated in years. Over the years, the development of new dating methods and refinement of previous ones have stimulated revisions to geologic time scales. Since the mid-1990s, geologists from the U.S. Geological Survey (USGS), State geological surveys, academia, and other organizations have sought a consistent time scale to be used in communicating ages of geologic units in the United States. Many international debates have occurred over names and boundaries of units, and various time scales have been used by the geoscience community. For consistency purposes, the USGS Geologic Names Committee and the Association of American State Geologists developed Divisions of Geologic Time .

Fact Sheet

Critical minerals in mine waste

Introduction Critical minerals are commodities with vulnerable supply chains that play a vital role in supporting the United States’ economy, national defense and security, emerging technologies, and energy independence. The prosperity of our Nation depends on generating a resilient supply of domestic critical minerals; mine waste may be an untapped source of these commodities. Mine waste from centuries of legacy mining persist on the landscape and may contain critical minerals and other valuable commodities previously deemed uneconomic to recover. At modern mines, the financial viability of recovering byproduct critical minerals, which are not the primary target, may be marginal and can ultimately destine them to mine waste. Further, mine waste can be a liability for the mining company or, at legacy mines, the taxpayer because of its effect on the landscape. The U.S. Geological Survey (USGS) has several initiatives to evaluate critical mineral resources in various types of waste. This factsheet highlights studies of mine waste carried out by USGS scientists at the Geology, Energy & Minerals Science Center in collaboration with other science centers funded through the USGS Mineral Resources Program. Recovery of critical minerals from mine waste can aid in remediation efforts and increase domestic supply of vital mineral resources.

Fact Sheet