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The area of influence of an exploratory hole

A method is presented for calculating the area of influence of exploratory drill holes by using the size and shape of resource targets. The solution presented is for elliptical and circular targets, but the method is applicable to any shaped target. The degree to which points have been explored depends upon their distance away from a drill hole and the possible orientations of the target. Several hypothetical examples demonstrate how: (1) maps can be generated that show the degree to which areas within the region of interest have been explored; (2) graphs can be constructed to evaluate the possibility of undiscovered targets of specific sizes and shapes in a region; (3) the sequence of physical exhaustion in a region can be used to make estimates of undiscovered resources.

Economic Geology↗

Direct dating of mineralization at Goldfield, Nevada, by potassium-argon and fission-track methods

Potassium-argon dating of hypogene alunite and K-mica from hydrothermally altered rocks at Goldfield, Nevada, yields mineralization ages of 20 to 21 m.y., in good agreement with a mineralization age established by potassium-argon dating of unaltered premineralization and postmineralization volcanic units. Premineralization volcanic units that are pervasively propylitized cannot be dated by the potassium-argon method but yield zircon fission-track ages, and in several cases yield concordant apatite fission-track ages. Two samples from premineralization units yield apatite ages concordant with the age of mineralization established by potassium-argon geochronometry, reflecting annealing of the apatite during the hydrothermal episode.Potassium-argon dating of supergene alunite samples yields imprecise ages in the range 9 to 12 m.y. that probably record the first exposure of their hydrothermally altered host rocks to oxidizing conditions. Potassium-argon dating of postmineralization basalts and silicic tuffs interbedded with conglomerates bearing altered rock clasts shows that the altered area was eroded nearly to present topographic levels by 11 m.y. ago, at which time it was covered by basalt flows now represented only by scattered remnants. Apatites from premineralization volcanic units give fission-track ages of 20 m.y. or more, indicating that no significant thermal event has affected altered rocks at Goldfield since mineralization took place.

Nevada↗

Origin of a South Texas roll-type uranium deposit; I, Alteration of iron-titanium oxide minerals

The detrital Fe-Ti oxide minerals and their authigenic alteration products in samples from cores spanning 1.7 km across a roll-type uranium deposit in the mid-Tertiary Catahoula Tuff, south Texas, record important information on host-rock preparation and on development of the altered tongue of the deposit. In reduced rock, in front of and enveloping the altered tongue, iron disulfide minerals (pyrite and marcasite) have partially to completely replaced titanomagnetite and, to a lesser extent, titanohematite. Subsequent oxidation of these sulfidized Fe-Ti oxides, by processes that formed the altered tongue and uranium roll, produced ferric oxide and hydroxide phases (limonite) pseudomorphous after the sulfides. Fe-Ti oxides 1.0 km updip from the roll front were never sulfidized; titanomagnetite (partly replaced by hematite) and martite constitute nearly half of the heavy mineral fraction and limonite is absent. Oxidized rocks 210 m and closer to the nose of the roll front, however, are nearly devoid of titanomagnetite and contain abundant limonite. The redox interface that bounds the altered tongue, therefore, moved more than 210 m but less than 1.0 km. Detrital Fe-Ti oxide minerals are increasingly sulfidized in the downdip direction indicating that initial sulfidizaton was more intense in that direction. Organic carbon content is uniformly very low throughout the host sandstone, which implies that heterotrophic sulfate-reducing bacteria were not involved in the generation of sulfide. The H 2 S for the initial sulfidization may have been derived from oil and gas in formations that underlie the Catahoula Tuff. The H 2 S probably invaded the Catahoula along a fault that is 1.5 km downdip from the present roll front.

Texas↗

Origin of a South Texas roll-type deposit; II, Sulfide petrology and sulfur isotope studies

Petrologic and sulfur isotopic studies have been carried out on drill core samples from a roll-type uranium deposit in the mid-Tertiary Catahoula Tuff, Webb County, south Texas. Epigenetic iron disulfide minerals formed in two distinct stages. The first stage involved sulfidization of the host rock by sulfide (H 2 S, HS-)-bearing solutions that emanated from a fault about 1.5 km downdip from and subparallel to the orebody. Pyrite was the dominant iron disulfide mineral formed from this fault sulfide. The isotopic composition (delta 34 S) of first-stage iron disulfide is quite heavy (>0 per mil), in part because the fault-derived H 2 S was isotopically heavy. The development of the second-stage sulfides was related to processes that formed the uranium roll. Iron disulfide minerals produced during this second stage commonly occur as rims around the first-stage sulfides. The rims are exclusively marcasite in and adjacent to ore, but the pyrite content in these rims increases with increasing distance from ore. The sulfur of the second-stage sulfides in the vicinity of the roll front is isotopically light (--25 to --40 per mil). The virtual absence of organic carbon in the host sand precludes a bacterial origin for the ore-stage iron disulfide minerals and, therefore, eliminates bacterial metabolism as the mechanism for isotopic fractionation. Instead, the sulfur source for ore-stage sulfides was preore (first stage) sulfides, remobilized via partial oxidation to soluble metastable sulfur oxyanions.

Texas↗

Genesis of ore deposits in the San Juan Volcanic Field, Southwestern Colorado-lead isotope evidence

In the San Juan volcanic area of southwestern Colorado, the isotopic composition of lead in ores and ore prospects of Cenozoic age ranges widely: 17.72 to 21.13 for 206 Pb/ 204 Pb; 15.50 to 15.81 for 207 Pb/ 204 Pb; and 37.21 to 38 for 208 Pb/ 204 Pb. Examination of the lead isotope data indicates that once deposition of lead minerals begins, further exchange of lead between fluid and wall rock is insignificant. This conclusion is supported by the relatively constant isotopic composition of the lead in these ores, which is not affected by the grade of ore mineralization or type of wall rock. The values of 206 Pb/ 204 Pb in some vein-type deposits exceed the maximum value known for all Mesozoic and Cenozoic igneous rocks of the Rocky Mountain region. These isotopic relations show that if ore-forming solutions are composed of meteoric water, as indicated in studies of light stable isotopes, they must have penetrated deep enough to acquire lead from Pre-cambrian rocks or sediments derived from them. The fact that some of these vein ores are now in Cenozoic igneous rocks indicates the ore fluid had an upward vertical component to its movement. The lead isotope data therefore support a circulating cell hypothesis for these kinds of ores, as suggested by many recent studies of light stable isotopes as related to mineralization. Some other deposits (Summitville, Jasper, Red Mountain district) have values of 206 Pb/ 204 Pb similar to those of the large volumes of altered rock that enclose them ( 206 Pb/ 204 Pb ∼ 18.5), suggesting that in places the lead may have been locally derived by leaching of the adjacent rocks or from magmatogenic fluids. When the lead isotope data are treated in detail, the rocks and galenas of the Platoro caldera complex, of the central San Juan caklera complex, and of the Baughman Creek center appear to contain significant components derived from 1,400- to l,500-m.y.-old and 1,700- to 1,800 m.y.-old source materials. These also are the ages of the two main groups of rocks that comprise the Precambrian basement under the San Juan volcanic area. Although the data from the western San Juan caldera complex scatter considerably, the only obvious source for the lead seems to be the 1,700- to l,800-m.y.-old rocks or detritus of such age in Phanerozoic sediments. Where the involvement of 1,400- to l,500-m.y.-old sources is greatest, the Th/U ratio in the source material is small (calculated to be about 0.7), whereas the Th/U ratio of the 1,700- to l,800-m.y.-old source material appears to be 2.3 to 3.3. The largest Th/U values are from the western San Juan caldera complex. © 1979 Society of Economic Geologists, Inc.

Colorado↗

Spectra of altered rocks in the visible and near infrared

Visible and near-infrared (0.35 to 2.5 mu m) bidirectional reflection spectra were recorded for a suite of well-characterized hydrothermally altered rock samples. The spectra typically display well-defined bands caused by both electronic and vibrational processes in the individual mineral constituents.Electronic transitions in the iron-bearing constituent minerals produce diagnostic minima near 0.43, 0.65, 0.85, and 0.93 mu m. Vibrational transitions in clay and water-bearing mineral constituents typically produce characteristic single or multiple features over limited spectral ranges near 1.4, 1.75, 1.9, 2.2, and 2.35 mu m. The most abundant feature-producing minerals present in these rocks are hematite, goethite, and alunite, while others frequently present are jarosite, kaolinite, potassium micas, pyrophyllite, montmorillonite, diaspore, and gypsum.This study shows that visible-near infrared spectrometry is a reliable and rapid technique for detecting and identifying clay minerals and alunite in rocks. Because these minerals are important constituents of altered rocks, the feasibility of using the visible and near infrared for detecting altered rocks by remote-sensing techniques is indicated. The spectral region near 2.2 mu m is particularly important for this purpose.

Nevada↗

Environment of ore deposition in the Creede mining district, San Juan Mountains, Colorado; Part IV, source of fluids, from oxygen, hydrogen, and carbon isotope studies

The hydrogen isotopic composition of fluids responsible for formation of the near-surface silver-base metal vein deposits at Creede was measured by direct analysis of inclusion fluids in sphalerite, quartz, and rhodochrosite and was estimated from analyses of illite and chlorite. The oxygen isotopic composition was determined directly on inclusion fluids in sphalerite and was estimated from analyses of quartz, illite, rhodochrosite, siderite, and adularia. The carbon isotopic composition was estimated from analyses of rhodochrosite and siderite. The ranges in isotopic composition for water and CO 2 in the fluids associated with the formation of each of the minerals is given below (number of determinations given in parentheses):Mineral delta D (sub H 2 ) O ppm delta 18 O (sub H 2 ) O ppm delta 13 C (sub CO 2 ) ppmSphalerite -81 to -54 (4) -10.1 to -4.5 (4)Quartz -97 to -86 (4) -5.9 to 1.8 (18)Illite -62 to -50 (8) -1.6 to 1.2(7)Chlorite -64 to -55 (10) -2.2 to 0.8 (10)Adularia 4.2 (1)Rhodochrosite -82 to -78 (2) 4.2 to 9.4 (9) -5.7 to -4.2 (9)Siderite 4.9 to 9.9 (6) -6.9 to -2.7 (6)The delta D (sub H 2 ) O and delta 18 O (sub H 2 ) O values of fluids associated with the formation of sphalerite, quartz, illite/chlorite, and carbonate minerals differ substantially from one another, and these differences appear to have been maintained throughout the depositional history, regardless of the positions of the minerals in the paragenetic sequence.The data suggest that waters from three coexisting reservoirs fed the vein system alternately and episodically during vein formation, and apparently there was little mixing of the fluids from the different reservoirs. The hydrogen, oxygen, and carbon isotope data suggest that the carbonate waters were deep seated, probably dominantly magmatic, in origin. The sphalerite and illite/chlorite waters must have been dominantly meteoric in origin and substantially oxygen shifted by exchange with the volcanic country rocks. The quartz waters were also oxygen shifted meteoric waters but were some 40 per mil lower in deuterium content than the sphalerite and illite/chlorite waters.We propose that the quartz fluids entered the vein system from reservoirs beneath the mountainous areas to the north in the vicinity of the present Continental Divide, but that the sphalerite and illite/chlorite fluids entered the vein system from a topographically low area to the south along the structural moat of the Creede caldera. The difference in delta D between the two meteoric waters may reflect differences in altitude of the recharge areas for the two reservoirs or may be clue to isotopic evolution of the closed-basin lake and interstitial waters in the moat surrounding the Creede caldera.

Colorado↗

Pliocene intrusive rocks and mineralization near Rico, Colorado

Fission-track and potassium-argon studies of intrusive rocks in the vicinity of Rico, Colorado, have shown that there are at least two periods of igneous activity and that significant ore mineralization is associated with alaskites and latites that are 3 to 5 m.y. old. Discordant fission track ages of apatite and zircon in the older rocks reveal a major heat source that cooled in late Miocene or early Pliocene and is centered under the mineralized rocks near the townsite of Rico. This heating may indicate the presence of a buried stock that is related to the mineralization.

Colorado↗

Uranium contents of glassy and devitrified andesites and dacites, Mount Mazama, Oregon

By direct comparison of devitrified and granophyrically crystallized specimens with nonhydrated glassy materials from the same units, Rosholt and coworkers (Rosholt and Noble, 1969; Rosholt et al., 1971) showed that specimens of primarily crystallized but otherwise unaltered peralkaline and subalkaline rhyolite from the western United States had lost from 30 to 80 percent of the uranium that they originally possessed. They suggested that uranium was lost both during crystallization, perhaps as the volatile hexafluoride, and/or later through the action of ground water. Similar results have been obtained by Shatkov et al. (1970) and Kovalev and Maylasova (1973). Zielinski (1978) compared the uranium contents of paired nonhydrated glassy and primarily devitrified phases of a number of subalkaline rhyolitic lavas and tuffs from various localities in the western United States. He found a generally smaller degree of uranium loss than had been observed by Rosholt et al. (1971) for peralkaline materials. In addition, Zielinski noted that older specimens had, as a group, lost a greater percentage of their original uranium than had younger rocks and suggested that uranium is generally lost progressively over periods of many millions of years.

Oregon↗

Textural and structural evidence for a predeformation hydrothermal origin of the Tungsten Queen Deposit, Hamme District, North Carolina

The Hamme tungsten district is composed of a series of steeply dipping quartz-wolframite veins in the Piedmont of North Carolina. Veins are concentrated near the border of the lower Paleozoic Vance County pluton, along its western contact with green-schist-facies metapelites and metavolcanic rocks of the Carolina slate belt. One of these quartz veins, the Snead-Walker, hosts the Tungsten Queen deposit. The vein is 0 to 10 m thick and trends N 35 degrees E for approximately 3,500 m through slate belt rocks and the granitic pluton. The deposit has been worked to a depth of nearly 520 m and contains eight en echelon ore lodes that plunge 42 degrees to 65 degrees between S 10 degrees E and S 10 degrees W. Ore lodes commonly are encased in thin lenses of quartz-sericite greisen. The principal ore mineral is huebnerite and is accompanied by scattered occurrences of pyrite, sphalerite, galena, chalcopyrite, and tetrahedrite. The gangue is predominantly quartz with minor amounts of fluorite, sericite, and carbonate.Studies of minor structures and mineral textures indicate that both the wall rock and the ore and gangue minerals within the vein have been deformed by at least two events. The first event produced relatively gentle, open, and shallow-plunging folds; later, an intense episode of right-lateral shearing developed steeply plunging, tight folds and numerous northeast-trending shears. This latter deformation also developed a prominent alignment of ore and gangue minerals oblique to the vein walls and may have formed the en echelon distribution of ore lodes.In relatively undeformed parts of the vein, clusters of euhedral huebnerite crystals are oriented perpendicular to vein layering. Some prismatic crystals have terminations with cappings of sulfides and in polished thin section show concentric growth zones. These features are similar to textures found in unmetamorphosed tungsten-bearing hydrothermal vein deposits such as those at Pasto Bueno, Peru; Carrock Fell, England; and Panasqueria, Portugal. The relationships of mineral textures and minor structures indicate that the Tungsten Queen deposit formed by open-space fillings of linear faults or fractures and was subsequently deformed by at least two episodes of folding and shearing.

North Carolina↗

Uranium in secondary silica: A possible exploration guide

Study of uraniferous silica precipitates in the Shirley Basin, Wyoming, identified areas where ancient uraniferous ground water once ponded. Chalcedony collected from and directly beneath thick accumulations of rhyolite ash contain as much as 250 ppm uranium in a pre-ash topographic low and lesser concentrations (10 to 160 ppm) elsewhere. Differences in the U concentration of chalcedony collected from approximately the same stratigraphic horizon reflect the enrichment of uranium in ground water as it percolated downward and basinward through the overlying rhyolite ash. Uranium is homogeneously distributed as a uranyl species within the chalcedony and reflects coprecipitation of dissolved uranium and colloidal silica in a uraniferous silica-gel. Laboratory measurements of the partitioning of uranium between various solutions and silica-gel precipitates indicate that, for ranges of pH and dissolved carbonate typical of ground water, dried silica-gel contains about 400 to 1,000 times the uranium concentration of the solution from which it forms. Uranium is postulated to be incorporated as an adsorbed uranyl-silica-hydroxyl complex. A 20-m.y.-minimum apparent age for uraniferous chalcedony was obtained by U-Pb isotope dating. Reported minimum ages for nearby sedimentary uranium deposits generally lie between this age and the age of rhyolite which hosts the silica (32.4 + or - 2.6 m.y.). Leaching of uranium from ash during the period 20 to 32 m.y. is therefore compatible with a volcanic source-rock hypothesis.

Wyoming↗

U-Pb isotope systematics and age of uranium mineralization, Midnite mine, Washington.

Uranium ores at the Midnite mine, near Spokane, Washington, occur in phyllites and calcsilicates of the Proterozoic Togo Formation, near the margins of an anomalously uraniferous, porphyritic quartz monzonite of Late Cretaceous age. The present geometry of the ore zones is tabular, with the thickest zones above depressions in the pluton-country rock contact. Analyses of high-grade ores from the mine define a 207 Pb/ 204 Pb- 235 U/ 204 Pb isochron indicating an age of mineralization of 51.0 + or - 0.5 m.y. This age coincides with a time of regional volcanic activity (Sanpoil Volcanics), shallow intrusive activity, erosion, and faulting. U-Th-Pb isotopic ages of zircons from the porphyritic quartz monzonite in the mine indicate an age of about 75 m.y., hence the present orebodies were formed about 24 m.y. after its intrusion. The 51-m.y. time of mineralization probably represents a period of mobilization and redeposition of uranium by supergene ground waters, perhaps aided by mild heating and ground preparation and preserved by a capping of newly accumulated, impermeable volcanic rocks. It seems most likely that the initial concentration of uranium occurred about 75 m.y. ago, probably from relatively mild hydrothermal fluids in the contact-metamorphic aureole of the U-rich porphyritic quartz monzonite.Pitchblende, coffinitc, pyrite, marcasite, and hisingerite are the most common minerals in the uranium-bearing veinlets, with minor sphalerite and chalcopyrite. Coffinitc with associated marcasite is paragenetically later than pitchblende, though textural and isotopic evidence suggests no large difference in the times of pitchblende and colfinite formation.The U-Pb isotope systematics of total ores and of pitchblende-coffinite and pyrite-marcasite separates show that whereas open system behavior for U and Pb is essentially negligible for large (200-500 g) ore samples, Pb migration has occurred on a scale of 1 to 10 mm (out of pitchblende and coffinite and into pyrite and marcasite). Also, long-term continuous leakage of radioactive daughters of 238 U (probably 222 Rn) has occurred on scales of from approximately 100 mu m approximately 10 cm. The isotopic composition of unsupported radiogenic Pb in pyrite-marcasite seems to depend on the mineralogical microenvironment of the grains, so that the radiogenic Pb in pyrite-marcasite intimately intermixed with pitchblende-coffinite tends to be deficient in 206 Pb, and the radiogenic Pb in pyrite-marcasite in gangue tends to have excess 206 Pb. These systematics probably reflect differences between the average distances of Pb and 222 Rn diffusion since the formation of the ores.

Washington↗

A lithologic-tectonic framework for the metallogenic provinces of California

The lithologic-tectonic framework of California developed principally during Mesozoic time when various terranes of oceanic crust and island-arc crust were accreted to older sialic crust, resulting in westward growth of the continent. Emplacement of great batholithic masses of granitoid rocks cutting all these crustal types also took place during the Mesozoic period. The discrete tectonostratigraphic terranes that resulted from these events and subsequent Tertiary and Quaternary volcanic events are characterized by specific types of metallic mineral deposits or, in some terranes, by the virtual absence of deposits. Lead-silver-zinc replacement-type deposits are common in the Paleozoic carbonate terrane in the eastern part of the state and occur sporadically elsewhere in the miogeoclinal and cratonal terranes but are absent from the oceanic and island-arc terranes. The vast majority of contact metasomatic tungsten deposits, including all the large ones, are in pendants of miogeoclinal rocks in the Sierra Nevada batholith, but the important Atolia deposits reside in granitoid rocks that invade oceanic terrane. Molybdenum distribution closely follows that of tungsten. All the large contact metasomatic iron deposits in California are in craton and miogeoclinal terranes, but sparse small deposits of this type also occur in island-arc terranes of the northern Sierra Nevada and eastern Klamath Mountains. Lode gold deposits, although widely scattered, show a marked preference for oceanic and island-arc terranes that have been invaded by granitoid plutons. All the major deposits, including late Tertiary bonanza deposits such as Bodie, are in such terranes. It appears that magmatic processes were responsible for mobilizing and transporting the gold, but the metal was perhaps derived from the eugeosynclinal rocks, notably the mafic volcanics. Most mercury deposits are found in the Coast Ranges, where they commonly occur in silica-carbonate rock, an alteration product of serpentinite. The deposits appear to be spatially related to the Coast Range thrust, and the source of the mercury may have been sedimentary rocks of the underlying Franciscan assemblage. Epigenetic mineralization occurred at several different times during the Mesozoic, and again during Miocene and Pliocene time. The timing of mineralization events and the distribution of various deposit types indicate that no broad-scale zoning of epigenetic deposits exists around the Sierra Nevada batholith.Syngenetic deposits are represented mainly by massive sulfides, chert-associated manganese, and chromite. The massive sulfide deposits, with one exception, are restricted to island-arc terranes, and nearly all of these deposits are in silicic volcanic rocks. They are interpreted to be syngenetic with the enclosing rocks, although some redistribution of metals may have occurred after the original deposition. The deposits occur in volcanic sequences of at least five different ages ranging from Early Devonian to Late Jurassic or Early Cretaceous and, along with their enclosing rocks, were probably formed at some distance from their present sites. Chert-associated manganese deposits occur mainly in exotic blocks of oceanic crust in melange and probably formed in fairly deep ocean environments. Chromite is confined to ultramafic rock, much of which occupies suture zones separating various accreted terranes.

Economic Geology↗

A review of regional mineral resource assessment methods

Over 100 papers on regional mineral resource assessment of nonfuels are classified according to method(s) used and form(s) of product in order to help identify possible methods for future assessments. Types of products that have been used include: tons of metal; tons of rock and associated grade; gross value; potential; number of deposits; probability of one or more deposits; tons of rock, grade, and number of deposits by type; potential supply; and net value. Assessment methods considered are: time-rate, crustal abundance, cumulative tonnage versus grade, simple subjective, complex subjective, Bayesian, frequency, trend, geometric probability, multiple regression, discriminant analysis, modified component, multivariate logistic, cluster analysis or pattern recognition, and simulation.Selection of a method to be employed in an assessment should be based on: (1) appropriateness of the product to the problem, (2) limitations in resources, such as information or time available for the assessment, (3) the level of uncertainty and acceptability of biases in the assessment, and (4) the need for verification of results and acceptance of the method.

Economic Geology↗

Massive sulfide deposits of the Southern Appalachians central Virginia volcanic-plutonic belt as a host for massive sulfide deposits

Strata-bound massive sulfide deposits of the central Virginia Piedmont occur in a volcanic- plutonic belt composed of Lower Cambrian(?) metamorphosed volcanic rocks and locally of pre-Upper Ordovician, low potassium granitoid rocks. The belt, interpreted as an ancient island arc, begins about 50 km south of Washington, D. C, and extends some 175 km south- westward. The volcanic rocks within the belt are located along the flanks of the Quantico- Columbia synclinorium and the Arvonia syncline. The Chopawamsic Formation, a western facies of the belt, consists of volcanic rocks that have the geochemical features (rare earth and immobile elements) of a tholeiitic island-arc suite; it also contains calc-alkaline components. Tholeiitic amphibolites of the Ta River Metamorphic Suite on the eastern side of the belt form an oceanward facies of the island arc, coeval with the Chopawamsic. This distribution suggests an underlying westward-dipping Cambrian(?) subduction zone. Contrasts in stratigraphy, geochemistry, and magnetic and gravity features indicate that the central Virginia volcanic- plutonic belt is not related to the Carolina slate belt as has been proposed in the past. Known sulfide bodies in the Chopawamsic and its coeval units total about 13.5 million tons. The Mineral district on the northwest flank of the Quantico-Columbia synclinorium has the largest deposits and contains about 10 million tons. Sulfide bodies in the belt consist largely of pyrite with minor sphalerite and chalcopyrite; Zn and Pb are important in a few of the smaller deposits. There are local concentrations of sphalerite and other base metal minerals within the major pyritic deposits (Zn = 1-12.5%; Cu - 1-2%; Pb as much as 5%). The dom- inantly sphaleritic deposits are found in and northward for about 15 km from the Mineral district. Sulfide mineralization is found in all types of volcanic rock, but the large sulfide bodies on the northwest flank of the Quantico-Columbia synclinorium are in felsite. Am- phibolite, containing local beds of iron-formation, is abundant on the southeast flank of the Arvonia syncline; however, most sulfide mineralization there took place in felsitic to intermediate layers. Mineralization, attributed to submarine volcanic exhalation, took place during formation of the island arc.

Economic Geology↗