Geology Reports⌕ Search

SEARCH · Geology Reports

Results for “Atmospheric Research”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 847 records · Page 47Linked to original sources

Development of a global land cover characteristics database and IGBP DISCover from 1 km AVHRR data

Researchers from the U.S. Geological Survey, University of Nebraska-Lincoln and the European Commission's Joint Research Centre, Ispra, Italy produced a 1 km resolution global land cover characteristics database for use in a wide range of continental-to global-scale environmental studies. This database provides a unique view of the broad patterns of the biogeographical and ecoclimatic diversity of the global land surface, and presents a detailed interpretation of the extent of human development. The project was carried out as an International Geosphere-Biosphere Programme, Data and Information Systems (IGBP-DIS) initiative. The IGBP DISCover global land cover product is an integral component of the global land cover database. DISCover includes 17 general land cover classes defined to meet the needs of IGBP core science projects. A formal accuracy assessment of the DISCover data layer will be completed in 1998. The 1 km global land cover database was developed through a continent-by-continent unsupervised classification of 1 km monthly Advanced Very High Resolution Radiometer (AVHRR) Normalized Difference Vegetation Index (NDVI) composites covering 1992-1993. Extensive post-classification stratification was necessary to resolve spectral/temporal confusion between disparate land cover types. The complete global database consists of 961 seasonal land cover regions that capture patterns of land cover, seasonality and relative primary productivity. The seasonal land cover regions were aggregated to produce seven separate land cover data sets used for global environmental modelling and assessment. The data sets include IGBP DISCover, U.S. Geological Survey Anderson System, Simple Biosphere Model, Simple Biosphere Model 2, Biosphere-Atmosphere Transfer Scheme, Olson Ecosystems and Running Global Remote Sensing Land Cover. The database also includes all digital sources that were used in the classification. The complete database can be sourced from the website: http://edcwww.cr.usgs.gov/landdaac/glcc/glcc.html.

International Journal of Remote Sensing↗

Precipitation intensity increased across the South Pacific Convergence Zone in the Industrial Age

The position, strength, and variability of precipitation in the South Pacific Convergence Zone (SPCZ) remain challenging for coupled ocean-atmosphere climate models to represent, leaving future rainfall projections in this dynamically important region uncertain. Here, we present quantitative records of mean annual precipitation (MAP) spanning the past 1,000 years using sediment cores from five freshwater lakes on different islands in the western portion of the SPCZ. Precipitation reconstructions are based on the hydrogen isotope composition of the dinoflagellate biomarker dinosterol, which is inversely correlated with MAP. We show that MAP in the western tropical Pacific increased over the past ∼300 years, with a significant increase beginning in 1,820 ± 75 C.E., coincident with a warming trend in the Western Pacific Warm Pool. These results contrast with the expected drying associated with reduced Pacific Walker Circulation as global temperatures increase in many climate models. Future warming may promote more intense SPCZ precipitation.

Geophysical Research Letters↗

Research-derived insights into surface geochemical hydrocarbon exploration

Research studies based on foreland basins (mainly in eastern Colorado) examined three surface geochemical exploration (SGE) methods as possible hydrocarbon (HC) exploration techniques. The first method, microbial soil surveying, has high potential as an exploration tool, especially hi development and enhanced recovery operations. Integrative adsorption, the second technique, is not effective as a quantitative SGE method because water, carbon dioxide, nitrous oxide, unsaturated hydrocarbons, and organic compounds are collected by the adsorbent (activated charcoal) much more strongly than covalently bonded microseeping Q-Cs thermogenic HCs. Qualitative comparisons (pattern recognition) of C8+ mass spectra cannot gauge HC gas microseepage that involves only the Q-Cs HCs. The third method, soil cakite surveying, also has no potential as an exploration tool. Soil calcite concentrations had patterns with pronounced areal contrasts, but these patterns had no geometric relationship to surface traces of established or potential production, that is, the patterns were random. Microscopic examination of thousands of soils revealed that soil calcite was an uncrystallized caliche coating soil particles. During its precipitation, caliche captures or occludes any gases, elements, or compounds in its immediate vicinity. Thus, increased signal intensity of some SGE methods should depend on increasing soil calcite concentrations. Analyses substantiate this hypothesis. Because soil calcite has no utility as a surface exploration tool, any surface method that depends on soil calcite has a diminished utility as an SGE tool. Isotopic analyses of soil calcites revealed carbonate carbon ??13C values of -4.0 to +2.07co (indicating a strong influence of atmospheric CO2) as opposed to expected values of-45 to -30%c if the carbonate carbon had originated from microbial oxidation of microseeping HC gases. These analyses confirm a surface origin for this soil calcite (caliche), which is not necessarily related to HC gas microseepage. This previously unappreciated pivotal role of caliche is hypothesized to contribute significantly to the poor and inconsistent results of some SGE methods.

AAPG Memoir↗

Mercury in Long Island Sound sediments

Mercury (Hg) concentrations were measured in 394 surface and core samples from Long Island Sound (LIS). The surface sediment Hg concentration data show a wide spread, ranging from <50 ppb Hg in eastern LIS to >600 ppb Hg in westernmost LIS. Part of the observed range is related to variations in the bottom sedimentary environments, with higher Hg concentrations in the muddy depositional areas of central and western LIS. A strong residual trend of higher Hg values to the west remains when the data are normalized to grain size. Relationships between a tracer for sewage effluents (C. perfringens) and Hg concentrations indicate that between 0-50 % of the Hg is derived from sewage sources for most samples from the western and central basins. A higher percentage of sewage-derived Hg is found in samples from the westernmost section of LIS and in some local spots near urban centers. The remainder of the Hg is carried into the Sound with contaminated sediments from the watersheds and a small fraction enters the Sound as in situ atmospheric deposition. The Hg-depth profiles of several cores have well-defined contamination profiles that extend to pre-industrial background values. These data indicate that the Hg levels in the Sound have increased by a factor of 5-6 over the last few centuries, but Hg levels in LIS sediments have declined in modern times by up to 30 %. The concentrations of C. perfringens increased exponentially in the top core sections which had declining Hg concentrations, suggesting a recent decline in Hg fluxes that are unrelated to sewage effluents. The observed spatial and historical trends show Hg fluxes to LIS from sewage effluents, contaminated sediment input from the Connecticut River, point source inputs of strongly contaminated sediment from the Housatonic River, variations in the abundance of Hg carrier phases such as TOC and Fe, and focusing of sediment-bound Hg in association with westward sediment transport within the Sound.

Connecticut;New York↗

Ash3d: A finite-volume, conservative numerical model for ash transport and tephra deposition

We develop a transient, 3-D Eulerian model (Ash3d) to predict airborne volcanic ash concentration and tephra deposition during volcanic eruptions. This model simulates downwind advection, turbulent diffusion, and settling of ash injected into the atmosphere by a volcanic eruption column. Ash advection is calculated using time-varying pre-existing wind data and a robust, high-order, finite-volume method. Our routine is mass-conservative and uses the coordinate system of the wind data, either a Cartesian system local to the volcano or a global spherical system for the Earth. Volcanic ash is specified with an arbitrary number of grain sizes, which affects the fall velocity, distribution and duration of transport. Above the source volcano, the vertical mass distribution with elevation is calculated using a Suzuki distribution for a given plume height, eruptive volume, and eruption duration. Multiple eruptions separated in time may be included in a single simulation. We test the model using analytical solutions for transport. Comparisons of the predicted and observed ash distributions for the 18 August 1992 eruption of Mt. Spurr in Alaska demonstrate to the efficacy and efficiency of the routine.

Journal of Geophysical Research↗

Time-dependent pore filling

Capillarity traps fluids in porous media during immiscible fluid displacement. Most field situations involve relatively long time scales, such as hydrocarbon migration into reservoirs, resource recovery, nonaqueous phase liquid remediation, geological CO 2 storage, and sediment‐atmosphere interactions. Yet laboratory studies and numerical simulations of capillary phenomena rarely consider the impact of time on these processes. We use time‐lapse microphotography to record the evolution of saturation in air‐ or hydrocarbon‐filled capillary tubes submerged in water to investigate long‐term pore filling phenomena beyond imbibition. Microphotographic sequences capture a lively pore filling history where various concurrent physical phenomena coexist. Dissolution and diffusion play a central role. Observations indicate preferential transport of the wetting liquid along corners, vapor condensation, capillary flow induced by asymmetrical interfaces, and interface pinning that defines the diffusion length. Other processes include internal snap‐offs, fluid redistribution, and changes in wettability as fluids dissolve into each other. Overall, the rate of pore filling is diffusion‐controlled for a given interfacial configuration; diffusive transport takes place at a constant rate for pinned interfaces and is proportional to the square root of time for free interfaces where the diffusion length increases with time.

Water Resources Research↗

Regional variability in peatland burning at mid-to high-latitudes during the Holocene

Northern peatlands store globally-important amounts of carbon in the form of partly decomposed plant detritus. Drying associated with climate and land-use change may lead to increased fire frequency and severity in peatlands and the rapid loss of carbon to the atmosphere. However, our understanding of the patterns and drivers of peatland burning on an appropriate decadal to millennial timescale relies heavily on individual site-based reconstructions. For the first time, we synthesise peatland macrocharcoal records from across North America, Europe, and Patagonia to reveal regional variation in peatland burning during the Holocene. We used an existing database of proximal sedimentary charcoal to represent regional burning trends in the wider landscape for each region. Long-term trends in peatland burning appear to be largely climate driven, with human activities likely having an increasing influence in the late Holocene. Warmer conditions during the Holocene Thermal Maximum (∼9–6 cal. ka BP) were associated with greater peatland burning in North America's Atlantic coast, southern Scandinavia and the Baltics, and Patagonia. Since the Little Ice Age, peatland burning has declined across North America and in some areas of Europe. This decline is mirrored by a decrease in wider landscape burning in some, but not all sub-regions, linked to fire-suppression policies, and landscape fragmentation caused by agricultural expansion. Peatlands demonstrate lower susceptibility to burning than the wider landscape in several instances, probably because of autogenic processes that maintain high levels of near-surface wetness even during drought. Nonetheless, widespread drying and degradation of peatlands, particularly in Europe, has likely increased their vulnerability to burning in recent centuries. Consequently, peatland restoration efforts are important to mitigate the risk of peatland fire under a changing climate. Finally, we make recommendations for future research to improve our understanding of the controls on peatland fires.

Quaternary Science Reviews↗

Vulnerability of riparian ecosystems to elevated CO 2 and climate change in arid and semiarid western North America

Riparian ecosystems, already greatly altered by water management, land development, and biological invasion, are being further altered by increasing atmospheric CO 2 concentrations ([CO 2 ]) and climate change, particularly in arid and semiarid (dryland) regions. In this literature review, we (1) summarize expected changes in [CO 2 ], climate, hydrology, and water management in dryland western North America, (2) consider likely effects of those changes on riparian ecosystems, and (3) identify critical knowledge gaps. Temperatures in the region are rising and droughts are becoming more frequent and intense. Warmer temperatures in turn are altering river hydrology: advancing the timing of spring snow melt floods, altering flood magnitudes, and reducing summer and base flows. Direct effects of increased [CO 2 ] and climate change on riparian ecosystems may be similar to effects in uplands, including increased heat and water stress, altered phenology and species geographic distributions, and disrupted trophic and symbiotic interactions. Indirect effects due to climate-driven changes in streamflow, however, may exacerbate the direct effects of warming and increase the relative importance of moisture and fluvial disturbance as drivers of riparian ecosystem response to global change. Together, climate change and climate-driven changes in streamflow are likely to reduce abundance of dominant, native, early-successional tree species, favor herbaceous species and both drought-tolerant and late-successional woody species (including many introduced species), reduce habitat quality for many riparian animals, and slow litter decomposition and nutrient cycling. Climate-driven changes in human water demand and associated water management may intensify these effects. On some regulated rivers, however, reservoir releases could be managed to protect riparian ecosystem. Immediate research priorities include determining riparian species' environmental requirements and monitoring riparian ecosystems to allow rapid detection and response to undesirable ecological change.

Global Change Biology↗

Critical loads of atmospheric deposition to Adirondack lake watersheds: A guide for policymakers

Acid deposition is sometimes referred to as “acid rain,” although part of the acid load reaches the surface by means other than rainfall. In the eastern U.S., acid deposition consists of several forms of sulfur and nitrogen that largely originate as emissions to the atmosphere from sources such as electricity-generating facilities (coal, oil, and natural gas), diesel- and gasoline-burning vehicles, some agricultural activities, and smokestack industries. Acid deposition is known to cause deleterious effects to sensitive ecosystems of which the Adirondack region of New York State provides several well-known and well-studied examples. This largely forested region includes abundant lakes, streams, and wetlands and possesses several landscape features that result in high ecosystem sensitivity to acid deposition. These features include bedrock that weathers slowly, steep slopes, and thin, naturally acidic soils. An ecosystem is described as sensitive to, or affected by, acid deposition if prolonged exposure to acid deposition has resulted in detrimental ecosystem effects. Soils, streams, and lakes that are less sensitive are better able to buffer acid deposition. A principal reason that acidification is a concern for resource managers is because of the changes induced in native biota and their habitat on land and in water. As the chemistry of soils and surface waters in sensitive landscapes changes in response to prolonged exposure to acid deposition, organisms that cannot tolerate high acidity, such as sugar maple trees and many species of fish and aquatic insects, may be gradually eliminated from the ecosystem. Other biota such as red spruce may experience increased stress and reduced growth rates as a result of acidification, exposing these species to increased susceptibility to disease and other natural stressors and perhaps increased mortality. The ecological effects of acid deposition have been documented by extensive research that began in the U.S. in the 1970s and continues today. This report does not provide a detailed discussion of these ecological effects, but interested readers can refer to four publications that provide good summaries of current scientific knowledge of these effects, including extensive reference to previous research in the Adirondacks (Driscoll et al. 2001, Jenkins et al. 2007, Burns et al. 2011, Sullivan 2015).

New York↗

Mars Global Surveyor Thermal Emission Spectrometer experiment: Investigation description and surface science results

The Thermal Emission Spectrometer (TES) investigation on Mars Global Surveyor (MGS) is aimed at determining (1) the composition of surface minerals, rocks, and ices; (2) the temperature and dynamics of the atmosphere; (3) the properties of the atmospheric aerosols and clouds; (4) the nature of the polar regions; and (5) the thermophysical properties of the surface materials. These objectives are met using an infrared (5.8- to 50-μm) interferometric spectrometer, along with broadband thermal (5.1- to 150-μm) and visible/near-IR (0.3- to 2.9-μm) radiometers. The MGS TES instrument weighs 14.47 kg, consumes 10.6 W when operating, and is 23.6×35.5×40.0 cm in size. The TES data are calibrated to a 1-σ precision of 2.5 −6 ×10 −8 W cm −2 sr −1 /cm −1 , 1.6×10 −6 W cm −2 sr −1 , and ∼0.5 K in the spectrometer, visible/near-IR bolometer, and IR bolometer, respectively. These instrument subsections are calibrated to an absolute accuracy of ∼4×10 −8 W cm −2 sr −1 /cm −1 (0.5 K at 280 K), 1–2%, and ∼1–2 K, respectively. Global mapping of surface mineralogy at a spatial resolution of 3 km has shown the following: (1) The mineralogic composition of dark regions varies from basaltic, primarily plagioclase feldspar and clinopyroxene, in the ancient, southern highlands to andesitic, dominated by plagioclase feldspar and volcanic glass, in the younger northern plains. (2) Aqueous mineralization has produced gray, crystalline hematite in limited regions under ambient or hydrothermal conditions; these deposits are interpreted to be in-place sedimentary rock formations and indicate that liquid water was stable near the surface for a long period of time. (3) There is no evidence for large-scale (tens of kilometers) occurrences of moderate-grained (>50-μm) carbonates exposed at the surface at a detection limit of ∼10%. (4) Unweathered volcanic minerals dominate the spectral properties of dark regions, and weathering products, such as clays, have not been observed anywhere above a detection limit of ∼10%; this lack of evidence for chemical weathering indicates a geologic history dominated by a cold, dry climate in which mechanical, rather than chemical, weathering was the significant form of erosion and sediment production. (5) There is no conclusive evidence for sulfate minerals at a detection limit of ∼15%. The polar region has been studied with the following major conclusions: (1) Condensed CO 2 has three distinct end-members, from fine-grained crystals to slab ice. (2) The growth and retreat of the polar caps observed by MGS is virtually the same as observed by Viking 12 Martian years ago. (3) Unique regions have been identified that appear to differ primarily in the grain size of CO 2 ; one south polar region appears to remain as black slab CO 2 ice throughout its sublimation. (4) Regional atmospheric dust is common in localized and regional dust storms around the margin and interior of the southern cap. Analysis of the thermophysical properties of the surface shows that (1) the spatial pattern of albedo has changed since Viking observations, (2) a unique cluster of surface materials with intermediate inertia and albedo occurs that is distinct from the previously identified low-inertia/bright and high-inertia/dark surfaces, and (3) localized patches of high-inertia material have been found in topographic lows and may have been formed by a unique set of aeolian, fluvial, or erosional processes or may be exposed bedrock.

Journal of Geophysical Research E: Planets↗

The role of groundwater transport in aquatic mercury cycling

Mercury, which is transported globally by atmospheric pathways to remote aquatic environments, is a ubiquitous contaminant at very low (nanograms Hg per liter) aqueous concentrations. Until recently, however, analytical and sampling techniques were not available for freshwater systems to quantify the actual levels of mercury concentrations without introducing significant contamination artifacts. Four different sampling strategies were used to evaluate ground water flow as a mercury source and transport mechanism within aquatic systems. The sampling strategies employ ultraclean techniques to determine mercury concentrations in groundwater and pore water near Pallette Lake, Wisconsin. Ambient groundwater concentrations are about 2&ndash;4 ng Hg L &minus;1 , whereas pore waters near the sediment/water interface average about 12 ng Hg L &minus;1 , emphasizing the importance of biogeochemical processes near the interface. Overall, the groundwater system removes about twice as much mercury (1.5 g yr &minus;1 ) as it contributes (0.7 g yr &minus;1 ) to Pallette Lake. About three fourths of the groundwater mercury load is recycled, thought to be derived from the water column.

Wisconsin↗

Use of output from high‐resolution atmospheric models in landscape‐scale hydrologic models: An assessment

In this paper we investigate the feasibility of coupling regional climate models (RCMs) with landscape‐scale hydrologic models (LSHMs) for studies of the effects of climate on hydrologic systems. The RCM used is the National Center for Atmospheric Research/Pennsylvania State University mesoscale model (MM4). Output from two year‐round simulations (1983 and 1988) over the western United States is used to drive a lake model for Pyramid Lake in Nevada and a streamfiow model for Steamboat Creek in Oregon. Comparisons with observed data indicate that MM4 is able to produce meteorologic data sets that can be used to drive hydrologic models. Results from the lake model simulations indicate that the use of MM4 output produces reasonably good predictions of surface temperature and evaporation. Results from the streamflow simulations indicate that the use of MM4 output results in good simulations of the seasonal cycle of streamflow, but deficiencies in simulated wintertime precipitation resulted in underestimates of streamflow and soil moisture. Further work with climate (multiyear) simulations is necessary to achieve a complete analysis, but the results from this study indicate that coupling of LSHMs and RCMs may be a useful approach for evaluating the effects of climate change on hydrologic systems.

Water Resources Research↗

Gulf Coast Ecosystem Restoration Task Force---Gulf of Mexico Ecosystem Science Assessment and Needs

The Gulf Coast Ecosystem Restoration Task Force (GCERTF) was established by Executive Order 13554 as a result of recommendations from “America’s Gulf Coast: A Long-term Recovery Plan after the Deepwater Horizon Oil Spill” by Secretary of the Navy Ray Mabus (Mabus Report). The GCERTF consists of members from 11 Federal agencies and representatives from each State bordering the Gulf of Mexico. The GCERTF was charged to develop a holistic, long-term, science-based Regional Ecosystem Restoration Strategy for the Gulf of Mexico. Federal and State agencies staffed the GCERTF with experts in fields such as policy, budgeting, and science to help develop the Strategy. The Strategy was built on existing authorities and resources and represents enhanced collaboration and a recognition of the shared responsibility among Federal and State governments to restore the Gulf Coast ecosystem. In this time of severe fiscal constraints, Task Force member agencies and States are committed to establishing shared priorities and working together to achieve them. As part of this effort, three staffers, one National Oceanic and Atmospheric Administration (NOAA) scientist and two U.S. Geological Survey (USGS) scientists, created and led a Science Coordination Team (SCT) to guide scientific input into the development of the Gulf of Mexico Regional Ecosystem Restoration Strategy. The SCT leads from the GCERTF coordinated more than 70 scientists from the Federal and State Task Force member agencies to participate in development of a restoration-oriented science document focused on the entire Gulf of Mexico, from inland watersheds to the deep blue waters. The SCT leads and scientists were organized into six different working groups based on expanded goals from the Mabus Report: Coastal habitats are healthy and resilient. Living coastal and marine resources are healthy, diverse, and sustainable. Coastal communities are adaptive and resilient. Storm buffers are sustainable. Inland habitats and watersheds are managed to help support healthy and sustainable Gulf of Mexico ecosystems. Offshore environments are healthy and well managed Each working group was charged with defining their specific goal, describing the current conditions related to that goal (for example, the status of coastal habitats in the Gulf of Mexico), providing highlevel activities needed to further define and achieve the goal, with associated outcome-based performance indicators, and identifying the scientific gaps in understanding to accomplish the goal and implement the recommended activities. The overall scientific assessment reveals that the Gulf of Mexico ecosystem continues to suffer from extensive degradation, and action is necessary to develop a healthy, resilient, and sustainable Gulf of Mexico ecosystem. The six groups also were tasked with outlining the necessary monitoring, modeling, and research needs to aid in achieving the goals. Recognizing that (1) the scientific needs (monitoring, modeling, and research) overlap among many of the goals, and (2) an overarching scientific framework could be developed to implement the necessary science in support of the Strategy, a seventh group was created with several members from each of the original six working groups. This seventh group compiled all of the cross-cutting monitoring, modeling, and research needs previously identified by the individual groups. These scientific requirements are found in Chapter 5 of this document. The seventh group also has developed a Science Plan, outlined in Chapter 6. The Science Plan provides the basic science infrastructure to support the overall Gulf restoration program and Strategy. The Science Plan allows for the development of an iterative and flexible approach to adaptive management and decision-making related to restoration projects based on sound science that includes monitoring, modeling, and research. Taken in its entirety, this document helps to articulate the current state of the system and the critical science needs to support effective restoration of the Gulf of Mexico resources that have been trending towards decline for decades.

Report↗

Spectrophotometric properties of materials observed by Pancam on the Mars Exploration Rovers: 2. Opportunity

The Panoramic Camera (Pancam) on the Mars Exploration Rover Opportunity acquired visible/near‐infrared multispectral observations of soils and rocks under varying viewing and illumination geometries that were modeled using radiative transfer theory to improve interpretations of the microphysical and surface scattering nature of materials in Meridiani Planum. Nearly 25,000 individual measurements were collected of rock and soil units identified by their color and morphologic properties over a wide range of phase angles (0–150°) at Eagle crater, in the surrounding plains, in Endurance crater, and in the plains between Endurance and Erebus craters through Sol 492. Corrections for diffuse skylight incorporated sky models based on observations of atmospheric opacity throughout the mission. Disparity maps created from Pancam stereo images allowed inclusion of local facet orientation estimates. Outcrop rocks overall exhibited the highest single scattering albedos (≤0.9 at 753 nm), and most spherule‐rich soils exhibited the lowest (≤0.6 at 753 nm). Macroscopic roughness among outcrop rocks varied but was typically larger than spherule‐rich soils. Data sets with sufficient phase angle coverage (resulting in well‐constrained Hapke parameters) suggested that models using single‐term and two‐term Henyey‐Greenstein phase functions exhibit a dominantly broad backscattering trend for most undisturbed spherule‐rich soils. Rover tracks and other compressed soils exhibited forward scattering, while outcrop rocks were intermediate in their scattering behaviors. Some phase functions exhibited wavelength‐dependent trends that may result from variations in thin deposits of airfall dust that occurred during the mission.

Journal of Geophysical Research E: Planets↗

Train, inform, borrow, or combine? Approaches to process-guided deep learning for groundwater-influenced stream temperature prediction

Although groundwater discharge is a critical stream temperature control process, it is not explicitly represented in many stream temperature models, an omission that may reduce predictive accuracy, hinder management of aquatic habitat, and decrease user confidence. We assessed the performance of a previously-described process-guided deep learning model of stream temperature in the Delaware River Basin (USA). We found lower accuracy (root mean square error [RMSE] of 1.71 versus 1.35°C) and stronger seasonal bias (absolute mean monthly bias of 1.06 vs. 0.68°C) for reaches primarily influenced by deep groundwater as compared to atmospheric conditions. We then tested four approaches for improving groundwater process representation: (a) a custom loss function leveraging the unique patterns of air and water temperature coupling characteristic of different temperature drivers, (b) inclusion of additional groundwater-relevant catchment attributes, (c) incorporation of additional process model outputs, and (d) a composite model. The custom loss function and the additional attributes significantly improved the predictive accuracy in groundwater-dominated reaches (RMSE of 1.37 and 1.26°C) and reduced the seasonal bias (absolute mean monthly bias of 0.44 and 0.48°C), but neither approach could identify holdout groundwater reaches. Variable importance analysis indicates the custom loss function nudges the model to use the existing inputs more efficiently, whereas with the added features the model relies on a broader suite of inputs. This analysis is a substantial step toward more accurately representing groundwater discharge processes in stream temperature models and will improve predictive accuracy and inform habitat management.

Delaware River Basin↗

Injection, transport, and deposition of tephra during event 5 at Redoubt Volcano, 23 March, 2009

Among the events of the 2009 eruption at Redoubt Volcano, Alaska, event 5 was the best documented by radar, satellite imagery, and deposit mapping. We use the new Eulerian tephra transport model Ash3d to simulate transport and deposition of event 5 tephra at distances up to 350 km. The eruption, which started at about 1230 UTC on 23 March, 2009, sent a plume from the vent elevation (estimated at 2.3 ± 0.1 km above sea level or a.s.l.) to about 16 ± 2 km above sea level in 5 min. The plume was a few kilometers higher than would be expected for the estimated average mass eruption rate and atmospheric conditions, possibly due to release of most of the eruptive mass in the first half of the 20-minute event. The eruption injected tephra into a wind field of high shear, with weak easterly winds below ~ 3 km elevation, strong southerly winds at 6–10 km and weak westerlies above ~ 16 km. Model simulations in this wind field predicted development of a northward-migrating inverted “v”-shaped cloud with a southwest-trending arm at a few kilometers elevation, which was not visible in IR satellite images due to cloud cover, and a southeast-trending arm at > 10 km elevation that was clearly visible. Simulations also predicted a deposit distribution that strongly depended on plume height: a plume height below 15 km predicted ash deposits that were located west of those mapped, whereas good agreement was reached with a modeled plume height of 15–18 km. Field sampling of the deposit found it to contain abundant tephra aggregates, which accelerated the removal of tephra from the atmosphere. We were able to reasonably approximate the effect of aggregation on the deposit mass distribution by two methods: (1) adjusting the grain-size distribution, taking the erupted mass < = 0.063 mm in diameter and distributing it evenly into bins of coarser size; and (2) moving 80–90% of the mass < = 0.063 mm into a single particle bin ranging in size from 0.25 to 1 mm. These methods produced an area inside the 100 g m − 2 isomass lines that was within a few tens of percent of mapped area; however they under-predicted deposit mass at very proximal (< 50 km) and very distal (> 250 km) locations. Modeled grain-size distributions at sample locations are also generally coarser than observed. The mismatch may result from a combination of limitations in field sampling, approximations inherent in the model, errors in the numerical wind field, and aggregation of particles larger than 0.063 mm.

Alaska↗

Aquatic carbon export and dynamics in mountain headwater streams of the western U.S.

Mountain headwater streams actively cycle carbon, receiving it from terrestrial landscapes and exporting it through downstream transport and gas exchange with the atmosphere. Although their importance is now widely recognized, aquatic carbon fluxes in headwater streams remain poorly characterized. In this study, aquatic carbon fluxes were measured in 15 mountain headwater streams and were used in a geostatistical analysis to determine how landscape characteristics influence aquatic carbon fluxes. In-stream sensors were used to measure fluorescent dissolved organic matter (fDOM) (a surrogate for dissolved organic carbon (DOC)) at a subset of sites to characterize dynamic responses to hydroclimatic events. Wetlands have a positive influence on aquatic carbon fluxes, whereas perennial snow/ice has the opposite effect, reflecting differences in soil organic matter content in these landscapes. Mean annual temperature (MAT) has a complex influence on DOC, with peak DOC exports in basins with MAT of 0–2°C. Precipitation has a strong positive influence on aquatic carbon fluxes, and declining snowpacks in the western United States may reduce future aquatic carbon exports. fDOM (and by implication DOC) and

Journal of Geophysical Research: Biogeosciences.↗

Tropical forest carbon balance in a warmer world: a critical review spanning microbial- to ecosystem-scale processes

Tropical forests play a major role in regulating global carbon (C) fluxes and stocks, and even small changes to C cycling in this productive biome could dramatically affect atmospheric carbon dioxide (CO 2 ) concentrations. Temperature is expected to increase over all land surfaces in the future, yet we have a surprisingly poor understanding of how tropical forests will respond to this significant climatic change. Here we present a contemporary synthesis of the existing data and what they suggest about how tropical forests will respond to increasing temperatures. Our goals were to: (i) determine whether there is enough evidence to support the conclusion that increased temperature will affect tropical forest C balance; (ii) if there is sufficient evidence, determine what direction this effect will take; and, (iii) establish what steps should to be taken to resolve the uncertainties surrounding tropical forest responses to increasing temperatures. We approach these questions from a mass-balance perspective and therefore focus primarily on the effects of temperature on inputs and outputs of C, spanning microbial- to ecosystem-scale responses. We found that, while there is the strong potential for temperature to affect processes related to C cycling and storage in tropical forests, a notable lack of data combined with the physical, biological and chemical diversity of the forests themselves make it difficult to resolve this issue with certainty. We suggest a variety of experimental approaches that could help elucidate how tropical forests will respond to warming, including large-scale in situ manipulation experiments, longer term field experiments, the incorporation of a range of scales in the investigation of warming effects (both spatial and temporal), as well as the inclusion of a diversity of tropical forest sites. Finally, we highlight areas of tropical forest research where notably few data are available, including temperature effects on: nutrient cycling, heterotrophic versus autotrophic respiration, thermal acclimation versus substrate limitation of plant and microbial communities, below-ground C allocation, species composition (plant and microbial), and the hydraulic architecture of roots. Whether or not tropical forests will become a source or a sink of C in a warmer world remains highly uncertain. Given the importance of these ecosystems to the global C budget, resolving this uncertainty is a primary research priority.

Biological Reviews↗