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USGS1995

Synthesis of nutrient and sediment data for watersheds within the Chesapeake Bay drainage basin

Nutrient and sediment data collected by Federal and state agencies from 1972 through 1992 at 1,058 surface-water sites in nontidal parts of the Chesapeake Bay Basin were compiled into a large database. Adequate nutrient, sediment, and streamflow data were not available to compute annual loads for all sites because water-quality monitoring at many of the sites was either short term or noncontinuous or because stream-flow was not measured. Annual nutrient and sediment loads were calculated at a total of 127 sites. Annual loads of dissolved nitrate were calculated for 108 sites, but total nitrogen loads could be calculated for only 48 of these sites because ammonia plus organic nitrogen data were not available for many of these 108 sites. Annual loads of total phosphorus were calculated for 99 sites, and annual loads of suspended sediment were calculated for 33 sites. Loads could be calculated for only a very few sites in the Juniata River Basin (a tributary to the Susquehanna River), the York River Basin, the middle and lower reaches of the James River, and the nontidal parts of the eastern shore of the Bay. Geographic Information System (GIS) spatial data sets of land use, physiographic province, rock type, and watershed delineation were compiled for the entire Chesapeake Bay Basin (approximately 64,000 square miles). The nutrient- and sediment-yield were evaluated with respect to land use, physiographic province, rock type, and hydrologic characteristics. During years that the mean streamflow was about equal to the long-term mean streamflow, the Susquehanna River contributed about 50 percent of the freshwater, 66 percent of the total nitrogen, and 40 percent of the total phosphorus transported by tributaries to the Bay. Nutrient and sediment data were available for less than 18 percent of the predominantly agricultural areas underlain by siliciclastic rock and for less than 35 percent of the predominantly agricultural areas underlain by either carbonate rock or unconsolidated rock. Nutrient and sediment data were available for about 91 percent of the predominantly forested areas underlain by siliciclastic rock. Spatial and temporal gaps in the water-quality data and GIs data sets limited some data analysis. Correlations of annual yields or nutrients and sediment with respect to land use, physiographic province, and rock type indicated (1) basins with larger percentages of agricultural land had larger nutrient and sediment yields, (2) basins with larger percentages of forest land had smaller nutrient and sediment loads, (3) the largest total nitrogen yields were from agricultural basins underlain by carbonate rock, (4) yields or nutrients from urban basins were substantially less than yields from agricultural basins, and (5) basins with small amounts of agricultural and urban land had relatively small nutrient and sediment yields.

Chesapeake Bay drainage basin↗

USGS1997

Water-quality assessment of the Ozark Plateaus study unit, Arkansas, Kansas, Missouri, and Oklahoma: Organic compounds in surface water, bed sediment, and biological tissue, 1992-95

Organic-compound samples, including pesticides and semi-volatiles, were collected from 1992-95 at 43 surface-water and 27 bed-sediment and biological-tissue sampling sites within the Ozark Plateaus National Water-Quality Assessment Program study unit. Most surface-water, bed-sediment, and biological-tissue sites have drainage basins predominantly in the Springfield and Salem Plateaus. At most surface-water sampling sites, one to three pesticide samples were collected in the spring and early summer of 1994 and 1995; two sites had additional samples collected either weekly, biweekly, or monthly from February 1994 through December 1994. At most bed-sediment and biological-tissue sampling sites, a single organic-compounds sample was collected. Agricultural pesticide use was approximately 4.9 million pounds of active ingredients per year from 1987-91 in the study unit and was generally greatest in the Springfield and Salem Plateaus pasturelands and in the Osage Plains and Mississippi Alluvial Plain cropland areas. The most frequently applied pesticide in the study unit was 2,4-D. Atrazine was the second most frequently applied pesticide. Corn, pasture, rice, sorghum, and soybeans received approximately 85 percent of the pesticides applied within the study unit. The highest pesticide application rate occurred on these crops in the Mississippi Alluvial and Osage Plains. Pastureland was the crop type that received the greatest amount of pesticides in 53 of the 96 counties in the study unit. The most commonly detected herbicide (63 samples) in surface water was atrazine. Five other pesticides--desethylatrazine, tebuthiuron, prometon, metolachlor, and simazine--were detected in 15 or more samples. The most commonly detected insecticide (13 samples) was p,p'-DDE. Two other insecticides, diazinon and cis-permethrin, were detected in seven or more samples. Pesticides were detected at 39 surface-water sites; samples collected at Yocum Creek near Oak Grove, Ark. had the most pesticide detections (13). Seventeen other sites had samples with six or more pesticide detections. Analysis of pesticide data collected at surface-water sites indicates that the largest variety of different pesticides detected (18) was in small, agricultural drainage basins; the largest percentage of detections of a single pesticide (about 80) was in medium, agricultural basins. Pesticide concentrations were small, and in most cases, at or near the detection limit. Maximum concentrations ranged from 0.001 to 0.007 micrograms per liter (mg/L) at small, forest sites; 0.001 to 0.029 mg/L at medium, forest sites; 0.001 to 0.079 mg/L at small, agricultural sites; and 0.003 to 0.29 mg/L at medium, agricultural sites. Pesticides were detected significantly more often in medium, agricultural basins in the Springfield Plateau. The most commonly detected (13 samples) organic compound in bed sediment, in concentrations noticeably above background levels, was 2,6-dimethylnaphthalene; the maximum concentration of 2,6-dimethylnaphthalene was 130 micrograms per kilogram. Seventeen or more compounds were detected in bed-sediment samples collected at three sites. Four compounds were detected in biological-tissue samples: p,p'-DDT in Corbicula fluminea (Asiatic clam) tissue collected at the Osage River near St. Thomas, Mo. and cis-chlordane, trans-chlordane, and trans-nonachlor in C. fluminea tissue collected at the James River near Boaz, Mo. Organic compounds collected at surface-water, bed-sediment, or biological-tissue sampling sites were not detected in concentrations that exceeded any health criteria or standards. Based on this information, organic compounds do not pose any widespread or persistent problems in the study unit.

Arkansas, Kansas, Missouri, Oklahoma↗

USGS1998

Surface-water quality at fixed sites in the Western Lake Michigan Drainages, Wisconsin and Michigan, and the effects of natural and human factors, 1993-95

Streamwater samples were collected from April 1993 through July 1995 at 11 fixed sites in the Western Lake Michigan Drainages Study Unit of the U.S. Geological Survey's National Water-Quality Assessment Program. Water samples were collected monthly at all Fixed Sites, and an additional two to four samples were collected each year during periods of high flow. Streamflow was monitored continuously at the Fixed Sites for the duration of the study period. This report describes field techniques used to collect the water samples, and the analytical methods used for laboratory analyses, statistical analyses of the data, and an attempt to determine the effect of natural and anthropogenic factors on concentrations of nutrients and selected major ions and suspended solids. Locations of eight of the Fixed Sites were selected to represent areas with unique combinations of land use/land cover, surficial deposits, and bedrock geology and are referred to as 'indicator sites.' The remaining three sites were located near the mouths of major rivers and are referred to as 'integrator sites.' The integrator sites represent a large part of the total flow from the Study Unit to Green Bay and western Lake Michigan, and drain various combinations of land use, bedrock, and surficial deposits. These data indicate that land use and surficial deposits may be the primary factors affecting nitrate and total phosphorus concentrations in this Study Unit. Median concentrations of nitrate at the forested sites were less than the National Median Concentration (NMC), and those at urban fixed sites were similar to the NMC. Median nitrate concentrations at the Tomorrow River, North Branch Milwaukee River, and Duck Creek agricultural indicator sites were twice the NMC, but median concentrations at the remaining agricultural indicator sites were similar to the NMC. Nitrate concentrations at one agricultural indicator site exceeded the U. S. Environmental Protection Agency (USEPA) maximum contaminant level in three run-off samples in the growing seasons of 1994 and 1995. Median concentrations of total phosphorus at the forested indicator sites were below the NMC. Tomorrow River was the only agricultural indicator site where the median total-phosphorus concentration was less than the NMC; median concentrations at the remaining agricultural Fixed Sites were similar to the NMC and exceeded 0.1 mg/L, the USEPA suggested total-phosphorus concentration in flowing water. The USEPA recommends that total-phosphorus concentration not exceed this limit to discourage excessive aquatic plant growth in flowing waters. Median total-phosphorus concentration at the urban indicator site was less than the urban NMC. Median concentrations for both nitrate and total phosphorus at the mouth of the Fox River and the Milwaukee River integrator sites were similar to the NMC for the dominant land use, agriculture, within their basins, and were lower than that at the Menominee River integrator site with a dominant forest land use. During this study, potassium concentrations were generally highest in areas of clay-dominated surficial deposits, silica was generally highest in areas of sandy surficial deposits, iron generally highest in areas of igneous/metamorphic bedrock, and calcium generally highest in areas of carbonate bedrock. The highest median fluoride concentration occurred at an urban site that receives treated water.

Michigan, Wisconsin↗

USGS1999

Pesticides in streams in New Jersey and Long Island, New York, and relation to land use

Pesticide compounds were detected in all 50 water samples collected from streams in New Jersey and Long Island, New York, during June 9-18, 1997. Samples were analyzed for 47 compounds, of which 25 were detected. The number of pesticides detected at each site ranged from 1 to 14. The seven most frequently detected pesticides were atrazine (in 93 percent of samples), metolachlor (86 percent), prometon (84 percent), desethyl-atrazine (78 percent), simazine (78 percent), carbaryl (44 percent), and diazinon (44 percent). All pesticide concentrations were within both U.S. Environmental Protection Agency (USEPA) and State maximum contaminant levels (MCL?s) for drinking water and USEPA lifetime health advisory levels (HAL?s). Concentrations of dieldrin and methylazinphos at one or more sites, however, equaled or exceeded a Federal or State water-quality criterion for aquatic life. The pesticides detected in a stream were related to the land-use composition of the basin. Detection frequencies of 14 of the 25 pesticides detected were highest at agricultural sites; acetochlor, azinphos-methyl, carbofuran, and pebulate were detected only at agricultural sites. Seven compounds were detected most frequently at urban sites; trifluralin, dieldrin, napropamide, and benfluralin were detected only at urban sites. Four compounds were detected most frequently at sites draining areas of mixed land use. No pesticides were detected most frequently at sites draining forested areas. The median concentration and the detection frequency of a given pesticide always were highest in samples from sites in the same land-use category.The median concentrations of seven pesticides at the agricultural sites were at least twice as high as the median concentrations at sites in other land-use categories. The median concentrations of the seven compounds detected most frequently at urban sites were equal to or only slightly higher than the median concentrations at sites in other land-use categories. The median total-pesticide concentration was highest at agricultural sites (0.2 mg/L (micrograms per liter)) and lowest at forested sites (0.025 mg/L). Total-pesticide concentrations varied most at agricultural sites and least at forested sites. Total-pesticide concentration and number of pesticides detected at a site increased as the percentage of agricultural land in the basin increased and decreased as the percentage of undeveloped land increased. Only three of the seven most frequently detected compounds?atrazine, metolachlor, and carbaryl?are among the seven most heavily applied pesticides in New Jersey. This is because detection frequencies are the result of physical and chemical properties of the pesticide compounds as well as application rates. Water solubility and soil-adsorption coefficients appear to be the two physical properties of pesticides that most influence their presence in streams.

New Jersey, New York↗

USGS1992

Winter habitat occurrence patterns of temperate migrant birds in Belize

We used mist nets and point counts to sample bird populations in 61 sites in Belize during January-March of 1987-1991. Sites were classified as forest, second growth, woody agricultural crops (citrus, mango, cacao, and cashew), or non-woody agricultural crops (rice and sugar cane). We evaluated patterns of occurrence of wintering temperate migrant bird species in these habitats. Mist net captures of 22 of 31 migrant species differed significantly among habitats. Of these, 13 species were captured more frequently in the agricultural habitats. American Redstart (Setophaga ruticilla), Black-and-white Warbler (Mniotilta varia), and Magnolia Warbler (Dendroica magnolia) were among the species captured most frequently in woody agricultural habitats; captures of Common Yellowthroat (Geothlypis trichas), Indigo Bunting (Passerina cyanea), and Northern (lcterus galbula) and Orchard orioles (I. spur/anus) were highest in the non-woody agricultural sites. We relate these occurrence patterns to trends in breeding populations in North America. While count data provide a wide picture of winter habitat distribution of migrants, more intensive work is necessary to assess temporal and geographic variation of migrant bird use of agricultural habitats.

El Pitirre (Society of Caribbean Ornithology)↗

USGS2011

Ecoregional differences in late-20th-century land-use and land-cover change in the U.S. northern great plains

Land-cover and land-use change usually results from a combination of anthropogenic drivers and biophysical conditions found across multiple scales, ranging from parcel to regional levels. A group of four Level 111 ecoregions located in the U.S. northern Great Plains is used to demonstrate the similarities and differences in land change during nearly a 30-year period (1973-2000) using results from the U.S. Geological Survey's Land Cover Trends project. There were changes to major suites of land-cover; the transitions between agriculture and grassland/shrubland and the transitions among wetland, water, agriculture, and grassland/ shrubland were affected by different factors. Anthropogenic drivers affected the land-use tension (or land-use competition) between agriculture and grassland/shrubland land-covers, whereas changes between wetland and water land-covers, and their relationship to agriculture and grassland/shrubland land-covers, were mostly affected by regional weather cycles. More land-use tension between agriculture and grassland/shrubland landcovers occurred in ecoregions with greater amounts of economically marginal cropland. Land-cover change associated with weather variability occurred in ecoregions that had large concentrations of wetlands and water impoundments, such as the Missouri River reservoirs. The Northwestern Glaciated Plains ecoregion had the highest overall estimated percentage of change because it had both land-use tension between agriculture and grassland/shrubland land-covers and wetland-water changes.

Great Plains Research↗

USGS2005

Upper Auglaize watershed AGNPS modeling project

The Upper Auglaize Watershed agricultural non-point source modeling project was an interagency effort to use a Geographic Information System (GIS)-based modeling approach for assessing and reducing pollution from agricultural runoff and other non-point sources. This project applied the U.S. Department of Agriculture (USDA), Agricultural Research Service’s AGricultural Non-Point Source (AGNPS) suite of models to the Upper Auglaize River Watershed, a major watershed within the Maumee River Basin. This modeling project was conducted by an interagency team consisting of a partnership between the: (1) USDA, Agricultural Research Service (ARS); (2) USDA, Natural Resources Conservation Service (NRCS); (3) U.S. Army Corps of Engineers (USACE); (4) U.S. Geological Survey (USGS); (5) Ohio State University; (6) University of Toledo (UT); (7) Heidelberg College; (8) Ohio Department of Natural Resources (ODNR), Division of Soil and Water Conservation; (9) Ohio Environmental Protection Agency (OEPA); and (10) Allen, Auglaize, Van Wert, and Putnam Soil and Water Conservation Districts. The partnership was the first step in a process to eventually apply the model in a portioned subset of watersheds for the Maumee Basin, and then to link them to form a comprehensive basin-wide model This work was performed under the authority of Section 516(e) of the Water Resources Development Act (WRDA) of 1996, as amended, for the purpose of assisting State and local watershed managers with their evaluation, prioritization and implementation of alternatives for soil conservation, sediment trapping and non-point source pollution prevention in the Upper Auglaize River watershed. The project team, working in a cooperative effort, used the models to determine sediment sources, contributing locations, and the effect of application of best management practices (BMPs) on rates of sediment delivery to the mouth of the watershed. The results will be used to guide conservation incentive and land treatment programs. The team relied heavily on Geographic Information System (GIS)-based applications to expedite the application of the model. The results of the analysis demonstrated that the application of BMPs would have a positive effect on reducing the loadings of sediment leaving the mouth of the Upper Auglaize Watershed. An application of 17 percent new no-till acres and eight percent new grassland acres, when randomly applied to the watershed, reduced loadings at the mouth to 82 percent of the simulated existing condition loadings. No-till, conversion of cropland to grassland, other uses including grass buffers, and reforestation of parts of the watershed, were all shown by the model to have a measurable effect on reducing sediment loads. Conversion of all of the cropland in the watershed to no-till would reduce the average unit load (tons of sediment per acre) leaving the mouth of the watershed to a level that is 42 percent of the simulated existing condition load. Ephemeral gullies were found to be the primary source of erosion (72 percent), sediment yield (73 percent), and sediment loading (73 percent). Controlling sediment load means controlling gully erosion and possibly trapping sediment yield before it reaches the stream system. Most BMPs (e.g., no-till, conversion of cropland, etc.) that reduce sheet and rill erosion and its sediment yield will also reduce gully erosion and its sediment yield. However, grassed waterways, which have no effect on sheet and rill erosion, are frequently an effective BMP to prevent ephemeral gullies. And, of course, riparian vegetation and sediment traps would reduce the delivery ratios of all types of landscape erosion. New techniques were developed by the team to quantify the ephemeral gully erosion within the model. When calibrated to available stream gage data the model suggests that more (73% in the existing condition simulation) of the sediment load originates from ephemeral gully erosion than from traditional sheet and rill erosion. The model quantified the value of tile drainage in reducing the sediment load from the watershed. Loadings under drained conditions were always less than loadings under undrained conditions for otherwise identical land uses. The average sediment load of all alternatives for drained loadings was 89.2 percent of the load for the corresponding undrained loadings. The model established that while many conservation incentive programs treat tile drainage as a production practice, significant erosion and sediment control benefits are provided by the practice in comparison to cultivation in an undrained state.

Ohio↗

USGS2021

Appendix C: Central sands lakes study technical report: Modeling documentation

This report provides the necessary documentation of the numerical models developed for the Central Sands Lake study in central Wisconsin and will be included as a technical appendix in the report to the Wisconsin State Legislature by the Wisconsin Department of Natural Resources (WDNR) in response to 2017 Wisconsin Act 10. This legislation directed WDNR to determine whether existing and potential groundwater withdrawals are causing or are likely to cause significant reduction of mean seasonal water levels at Pleasant Lake, Long Lake, and Plainfield Lake (s. 281.34(7m)(2)(b), Wis. Stats.) in Waushara County, Wisconsin. To evaluate the potential hydrologic connection between groundwater withdrawals and the nearby study lakes, hydrologic models were created that focused on the lakes of interest and yet were large enough to cover a broad enough region to extend to the major hydrologic boundaries of the natural flow system. The areas near the lakes require finer-scale grid discretization (or spacing) to better represent the lakes and streams in the model, but also need to cover a large enough area to include the groundwater withdrawal locations that have the potential to cause reduction in water levels in the lakes. To accomplish these goals, three groundwater models were created: a regional model extending to major hydrologic boundaries; and two inset models, inheriting boundaries from the regional model but focused near the lakes. Each of the inset models, in turn, included a detailed area close to the lakes surrounded by an area at the same spatial scale as the regional model (Figure 1). To support WDNR in evaluating the connection between groundwater withdrawals and lake levels, a representative time period was required over which to compare land use with and without irrigated agriculture and for WDNR to evaluate potential lake stage and flux changes related to irrigated agriculture. WDNR chose the climate period of 1981-2018 to be representative of a typical period and provided two land use scenarios—one with no irrigated agriculture and one with assumed crop rotations similar to current conditions—to simulate with groundwater models to, then, compare lake responses with. As a result, simulations over this climate record are not intended to recreate the history of 1981-2018 because land use changed over that time. These runs are, instead, intended to provide a basis on which to compare land use with and without irrigation-related groundwater withdrawals based on the current arrangement of land use and a varied climatic record. Groundwater withdrawals focused on irrigated-agriculture-related water use because greater than 95% of groundwater withdrawal in the two inset models around the study lakes is for irrigated agriculture water use. The period of 2012-2018 was used for parameter estimation (synonymously referred to as “history matching”) for the groundwater models. This time period was chosen because it includes the most complete water use records to simulate groundwater withdrawals. History matching was performed using groundwater elevations, lake stages, and streamflow observations over the 2012-2018 time period and processed observations derived from those raw data. Climatic data were incorporated into the model using a soil-water balance approach. A soil water balance model was constructed at the scale of the regional groundwater model to both calculate recharge based on land use and climate, and in the long-term climate-period runs, to estimate water use required by irrigated agriculture to apply as well boundary conditions in the groundwater model in the absence of reported water use values over that period.

Wisconsin↗

USGS2017

Dissolved organic matter compositional change and biolability during two storm runoff events in a small sgricultural watershed

Agricultural watersheds are globally pervasive, supporting fundamentally different organic matter source, composition, and concentration profiles in comparison to natural systems. Similar to natural systems, agricultural storm runoff exports large amounts of organic carbon from agricultural land into waterways. But intense management of upper soil layers, waterway channelization, wetland and riparian habitat removal, and postharvest vegetation removal promise to uniquely drive organic matter release to waterways. During a winter first flush and a subsequent storm event, this study investigated the influence of a small agricultural watershed on dissolved organic matter (DOM) source, composition, and biolability. Storm water discharge released strongly terrestrial yet biolabile (23 to 32%) dissolved organic carbon (DOC). Following a 21 day bioassay, a parallel factor analysis identified an 80% reduction in a protein-like (phenylpropyl) component (C2) that was previously correlated to lignin phenol concentration, and a 10% reduction in a humic-like, terrestrially sourced component (C4). Storm-driven releases tripled DOC concentration (from 2.8 to 8.7 mg L −1 ) during the first flush event in comparison to base flow and were terrestrially sourced, with an eightfold increase in vascular plant derived lignin phenols (23.0 to 185 μg L −1 ). As inferred from system hydrology, lignin composition, and nitrate as a groundwater tracer, an initial pulse of dilute water from the upstream watershed caused a counterclockwise DOC hysteresis loop. DOC concentrations peaked after 3.5 days, with the delay between peak discharge and peak DOC attributed to storm water hydrology and a period of initial water repellency of agricultural soils, which delayed DOM leaching.

California↗

USGS2021

Cross-ecosystem fluxes of pesticides from prairie wetlands mediated by aquatic insect emergence: Implications for terrestrial insectivores

Contaminants alter the quantity and quality of insect prey available to terrestrial insectivores. In agricultural regions, the quantity of aquatic insects emerging from freshwaters can be impacted by insecticides originating from surrounding croplands. We hypothesized that, in such regions, adult aquatic insects could also act as vectors of pesticide transfer to terrestrial food webs. To estimate insect-mediated pesticide flux from wetlands embedded in an important agricultural landscape, semipermanetly and temporarily ponded wetlands were surveyed in cropland and grassland landscapes across a natural salinity gradient in the Prairie Pothole Region of North Dakota (USA) during the bird breeding season in 2015 and 2016 ( n = 14 and 15 wetlands, respectively). Current-use pesticides, including the herbicide atrazine and the insecticides bifenthrin and imidacloprid, were detected in newly emerged insects. Pesticide detections were similar in insects emerging from agricultural and grassland wetlands. Biomass of emerging aquatic insects decreased 43%, and insect-mediated pesticide flux increased 50% along the observed gradient in concentrations of insecticides in emerging aquatic insects (from 3 to 577 ng total insecticide g –1 insect). Overall, adult aquatic insects were estimated to transfer between 2 and 180 µg total pesticide wetland –1 d –1 to the terrestrial ecosystem. In one of the 2 study years, biomass of emerging adult aquatic insects was also 73% lower from agricultural than grassland wetlands and was dependent on salinity. Our results suggest that accumulated insecticides reduce the availability of adult aquatic insect prey for insectivores and potentially increase insectivore exposure to insect-borne pesticides. Adult aquatic insects retain pesticides across metamorphosis and may expose insectivores living near both agricultural and grassland wetlands to dietary sources of toxic chemicals.

Alberta, Iowa, Manitoba, Minnesota, Montana, North↗

USGS2000

Comparison of pesticides in eight U.S. urban streams

Little is known of the occurrence of pesticides in urban streams compared to streams draining agricultural areas. Water samples from eight urban streams from across the United States were analyzed for 75 pesticides and seven transformation products. For six of the eight urban streams, paired agricultural streams were used for comparisons. The herbicides detected most frequently in the urban streams were prometon, simazine, atrazine, tebuthiuron, and metolachlor, and the insecticides detected most frequently were diazinon, carbaryl, chlorpyrifos, and malathion. In contrast to similar-sized agricultural streams, total insecticide concentrations commonly exceeded total herbicide concentrations in these urban streams. In general, the temporal concentration patterns in the urban streams were consistent with the characteristics of the local growing season. The insecticides carbaryl and diazinon exceeded criteria for the protection of aquatic life in many of the urban streams in the spring and summer. When the country as a whole is considered, the estimated mass of herbicides contributed by urban areas to streams is dwarfed by the estimated contribution from agricultural areas, but for insecticides, contributions from urban and agricultural areas may be similar. The results of this study suggest that urban areas should not be overlooked when assessing sources and monitoring the occurrence of pesticides in surface waters.

Connecticut, Colorado, Florida, Georgia, Maryland,↗

USGS1993

Trace elements and organochlorines in the shoalgrass community of the lower Laguna Madre Texas

Our objectives were to measure concentrations of seven trace elements and 14 organochlorine compounds in sediment and biota of the shoalgrass ( Halodule wrightii ) community of the lower Laguna Madre of south Texas and to determine whether chemicals associated with agriculture (e.g. mercury, arsenic, selenium, organochlorine pesticides) were highest near agricultural drainages. Arsenic, mercury, selenium, lead, cadmium, and organochlorines were generally at background concentrations throughout the lower Laguna Madre. Nickel and chromium concentrations were exceptionally high in shrimp and pinfish ( Lagodon rhomboides ), which is difficult to explain because of no known anthropogenic sources for these trace elements. For sediment and blue crabs ( Callinectes sapidus ), mercury was highest near agricultural drainages. Also, DDE was more frequently detected in blue crabs near agricultural drainages than farther away. In contrast, selenium concentrations did not differ among collecting sites and arsenic concentrations were lowest in shoalgrass, blue crabs, and brown shrimp ( Penaeus aztecus ) near agricultural drainages.

Texas↗

USGS2011

Native and exotic plants of fragments of sagebrush steppe produced by geomorphic processes versus land use

Habitat fragmentation and invasion by exotic species are regarded as major threats to the biodiversity of many ecosystems. We surveyed the plant communities of two types of remnant sagebrush-steppe fragments from nearby areas on the Snake River Plain of southeastern Idaho, USA. One type resulted from land use (conversion to dryland agriculture; hereafter AG Islands) and the other from geomorphic processes (Holocene volcanism; hereafter kipukas). We assessed two predictions for the variation in native plant species richness of these fragments, using structural equation models (SEM). First, we predicted that the species richness of native plants would follow the MacArthur–Wilson (M–W) hypothesis of island biogeography, as often is expected for the communities of habitat fragments. Second, we predicted a negative relationship between native and exotic plants, as would be expected if exotic plants are decreasing the diversity of native plants. Finally, we assessed whether exotic species were more strongly associated with the fragments embedded in the agricultural landscape, as would be expected if agriculture had facilitated the introduction and naturalization of non-native species, and whether the communities of the two types of fragments were distinct. Species richness of native plants was not strongly correlated with M–W characteristics for either the AG Islands or the **kipukas. The AG Islands had more species and higher cover of exotics than the kipukas, and exotic plants were good predictors of native plant species richness. Our results support the hypothesis that proximity to agriculture can increase the diversity and abundance of exotic plants in native habitat. In combination with other information, the results also suggest that agriculture and exotic species have caused loss of native diversity and reorganization of the sagebrush-steppe plant community.

Idaho↗

USGS2013

Sediment source analysis in the Linganore Creek watershed, Maryland, USA, using the sediment fingerprinting approach: 2008 to 2010

Purpose: Fine-grained sediment is an important pollutant in streams and estuaries, including the Chesapeake Bay in the USA. The objective of this study was to determine the sources of fine-grained sediment using the sediment fingerprinting approach in the Linganore Creek watershed, a tributary to the Chesapeake Bay. Materials and methods: The sediment fingerprinting approach was used in the agricultural and forested, 147-km 2 Linganore Creek watershed, Maryland from 1 August 2008 to 31 December 2010 to determine the relative percentage contribution from different potential sources of fine-grained sediment. Fine-grained suspended sediment samples (<63 μm) were collected during storm events in Linganore Creek using an automatic sampler and manual isokinetic samplers. Source samples were collected from 40 stream bank sites, 24 agricultural (cropland and pasture) sites, and 19 forested sites. Suspended sediment and source samples were analyzed for elements and stable isotopes. Results and discussion: Results of sediment fingerprinting for 194 samples collected in 36 separate storm events indicate that stream banks contributed 53% of the annual fine-grained suspended sediment load, agriculture contributed 44%, and forests contributed 3%. Peak flows and sediment loads of the storms correlate to stream bank erosion. The highest peak flows occurred in the winter and, along with freeze–thaw activity, contributed to winter months showing the highest rate of stream bank erosion. Peak flow was negatively correlated to sediment sources from agricultural lands which had the greatest contribution in non-winter months. Caution should be observed when trying to interpret the relation between sediment sources and individual storms using the sediment fingerprinting approach. Because the sediment fingerprinting results from individual storms may not include the temporal aspects of the sourced sediment, sediment that is in storage from previous events, remobilized and sampled during the current event, will reflect previous storm characteristics. Stream bank sediment is delivered directly to the channel during an event, whereas the delivery of upland sediment to the stream is lower due to storage on hillslopes and/or in channels, sediment from stream banks are more likely to be related to the characteristics of the sampled storm event. Conclusions: Stream banks and agricultural lands are both important sources of fine-grained sediment in the Linganore Creek watershed. Peak flows and sediment loads for the 36 storms show a significant relation to sediment sources from stream bank erosion. Attempting to link upland sediment sources to flow and seasonal characteristics is difficult since much of the upland sediment eroded in an event goes into storage. By averaging sediment sources over several storms, it may be possible to determine not only the sediment sources that are directly contributed during the current event but also sediment from previous events that was in storage and remobilized.

Maryl↗

USGS2012

GRACEnet: addressing policy needs through coordinated cross-location research

GRACEnet (Greenhouse gas Reduction through Agricultural Carbon Enhancement network) was conceived to build upon ongoing USDA Agricultural Research Service (ARS) research to improve soil productivity, while addressing the challenges and opportunities of interest in C sequestration from a climate change perspective. The vision for GRACEnet was and remains: Knowledge and information used to implement scientifically based agricultural management practices from the field to national policy scales on C sequestration, greenhouse gas (GHG) emissions, and environmental benefits. The national focus of GRACEnet uses a standardized approach by ARS laboratories and university and land manager (e.g. farmer and rancher) cooperators to assess C sequestration and GHG emission from different crop and grassland systems. Since 2002, GRACEnet has significantly expanded GHG mitigation science and delivered usable information to agricultural research and policy organizations. Recent developments suggest GRACEnet will have international impact by contributing leadership and technical guidance for the Global Research Alliance on Agricultural Greenhouse Gases.

Book chapter↗

USGS2014

Analysis of projected water availability with current basin management plan, Pajaro Valley, California

The projection and analysis of the Pajaro Valley Hydrologic Model (PVHM) 34 years into the future using MODFLOW with the Farm Process (MF-FMP) facilitates assessment of potential future water availability. The projection is facilitated by the integrated hydrologic model, MF-FMP that fully couples the simulation of the use and movement of water from precipitation, streamflow, runoff, groundwater flow, and consumption by natural and agricultural vegetation throughout the hydrologic system at all times. MF-FMP allows for more complete analysis of conjunctive-use water-resource systems than previously possible with MODFLOW by combining relevant aspects of the landscape with the groundwater and surface-water components. This analysis is accomplished using distributed cell-by-cell supply-constrained and demand-driven components across the landscape within “water-balance subregions” (WBS) comprised of one or more model cells that can represent a single farm, a group of farms, watersheds, or other hydrologic or geopolitical entities. Analysis of conjunctive use would be difficult without embedding the fully coupled supply-and-demand into a fully coupled simulation, and are difficult to estimate a priori. The analysis of projected supply and demand for the Pajaro Valley indicate that the current water supply facilities constructed to provide alternative local sources of supplemental water to replace coastal groundwater pumpage, but may not completely eliminate additional overdraft. The simulation of the coastal distribution system (CDS) replicates: 20 miles of conveyance pipeline, managed aquifer recharge and recovery (MARR) system that captures local runoff, and recycled-water treatment facility (RWF) from urban wastewater, along with the use of other blend water supplies, provide partial relief and substitution for coastal pumpage (aka in-lieu recharge). The effects of these Basin Management Plan (BMP) projects were analyzed subject to historical climate variations and assumptions of 2009 urban water demand and land use. Water supplied directly from precipitation, and indirectly from reuse, captured local runoff, and groundwater is necessary but inadequate to satisfy agricultural demand without coastal and regional storage depletion that facilitates seawater intrusion. These facilities reduce potential seawater intrusion by about 45% with groundwater levels in the four regions served by the CDS projected to recover to levels a few feet above sea level. The projected recoveries are not high enough to prevent additional seawater intrusion during dry-year periods or in the deeper aquifers where pumpage is greater. While these facilities could reduce coastal pumpage by about 55% of the historical 2000–2009 pumpage for these regions, and some of the water is delivered in excess of demand, other coastal regions continue to create demands on coastal pumpage that will need to be replaced to reduce seawater intrusion. In addition, inland urban and agricultural demands continue to sustain water levels below sea level causing regional landward gradients that also drive seawater intrusion. Seawater intrusion is reduced by about 45% but it supplies about 55% of the recovery of groundwater levels in the coastal regions served by the CDS. If economically feasible, water from summer agricultural runoff and tile-drain returnflows could be another potential local source of water that, if captured and reused, could offset the imbalance between supply and demand as well as reducing discharge of agricultural runoff into the National Marine Sanctuary of Monterey Bay. A BMP update (2012) identifies projects and programs that will fund a conservation program and will provide additional, alternative water sources to reduce or replace coastal and inland pumpage, and to replenish the aquifers with managed aquifer recharge in an inland portion of the Pajaro Valley.

California↗

USGS2020

Using NASA Earth observations and Google Earth Engine to map winter cover crop conservation performance in the Chesapeake Bay watershed

Winter cover crops such as barley, rye, and wheat help to improve soil structure by increasing porosity, aggregate stability, and organic matter, while reducing the loss of agricultural nutrients and sediments into waterways. The environmental performance of cover crops is affected by choice of species, planting date, planting method, nutrient inputs, temperature, and precipitation. The Maryland Department of Agriculture (MDA) oversees an agricultural cost-share program that provides farmers with funding to cover costs associated with planting winter cover crops, and the U.S. Geological Survey (USGS) and the U.S. Department of Agriculture-Agricultural Research Service (USDA-ARS) have partnered with the MDA to develop satellite remote sensing techniques for measuring cover crop performance. The MDA has developed the capacity to digitize field boundaries for all fields enrolled in their cover crop programs (>26,000 fields per year) to support a remote sensing performance analysis at a statewide scal,e and has requested assistance with the associated imagery processing from the National Aeronautics and Space Administration (NASA). Using the Google Earth Engine (GEE) cloud computing platform, scripts were developed to process Landsat 5/7/8 and Harmonized Sentinel-2 imagery to measure winter cover crop performance. We calibrated cover crop performance models using linear regression between satellite vegetation indices and USGS / USDA-ARS field sampling data collected on Maryland farms between 2006 and 2012 (1298 samples). Satellite-derived Normalized Difference Vegetation Index (NDVI) values showed significant correlation with the natural logarithm of cover crop biomass ( p ≤0.01, R 2 = 0.56) and with observed percent vegetative ground cover (p ≤0.01, R 2 = 0.68). The GEE scripts were used to composite seasonal maximum NDVI values for each enrolled cover crop field and calculate performance metrics for the winter and spring seasons of three enrollment years (2014–15, 2015–16, and 2017–18) for four Maryland counties. Results from winter 2017–18 demonstrate that rye and barley fields had higher biomass than wheat fields, and that early planting, along with planting methods that increase seed-soil contact, increased performance. The processing capabilities of GEE will support the MDA in scaling up remote sensing performance analysis statewide, providing information to evaluate the environmental outcomes associated with various agronomic management strategies. The tool can be modified for different seasonal cutoffs, utilize new sensors to capture phenology in winter and spring, and scale to larger regions for use in adaptive management of winter cover crops planted for environmental benefit.

Maryland↗

USGS2011

Relating nutrient and herbicide fate with landscape features and characteristics of 15 subwatersheds in the Choptank River watershed

Excess nutrients and agrochemicals from non-point sources contribute to water quality impairment in the Chesapeake Bay watershed and their loading rates are related to land use, agricultural practices, hydrology, and pollutant fate and transport processes. In this study, monthly baseflow stream samples from 15 agricultural subwatersheds of the Choptank River in Maryland USA (2005 to 2007) were characterized for nutrients, herbicides, and herbicide transformation products. High-resolution digital maps of land use and forested wetlands were derived from remote sensing imagery. Examination of landscape metrics and water quality data, partitioned according to hydrogeomorphic class, provided insight into the fate, delivery, and transport mechanisms associated with agricultural pollutants. Mean Nitrate-N concentrations (4.9 mg/L) were correlated positively with percent agriculture (R 2 = 0.56) and negatively with percent forest (R 2 = 0.60). Concentrations were greater ( p = 0.0001) in the well-drained upland (WDU) hydrogeomorphic region than in poorly drained upland (PDU), reflecting increased denitrification and reduced agricultural land use intensity in the PDU landscape due to the prevalence of hydric soils. Atrazine and metolachlor concentrations (mean 0.29 μg/L and 0.19 μg/L) were also greater ( p = 0.0001) in WDU subwatersheds than in PDU subwatersheds. Springtime herbicide concentrations exhibited a strong, positive correlation (R 2 = 0.90) with percent forest in the WDU subwatersheds but not in the PDU subwatersheds. In addition, forested riparian stream buffers in the WDU were more prevalent than in the PDU where forested patches are typically not located near streams, suggesting an alternative delivery mechanism whereby volatilized herbicides are captured by the riparian forest canopy and subsequently washed off during rainfall. Orthophosphate, CIAT (6-chloro- N -(1-methylethyl)-1,3,5-triazine-2,4-diamine), CEAT (6-chloro- N -ethyl-1,3,5-triazine-2,4-diamine), and MESA (2-[(2-ethyl-6-methylphenyl) (2-methoxy-1-methylethyl)amino]-2-oxoethanesulfonic acid) were also analyzed. These findings will assist efforts in targeting implementation of conservation practices to the most environmentally-critical areas within watersheds to achieve water quality improvements in a cost-effective manner.

Delaware, Maryland↗