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USGS1977

Use of water in Arkansas, 1975

This report contains statistical information relating to water use in Arkansas. The principle categories of water use, other than hydroelectric energy generation, are public supply, self-supplied industrial use, rural domestic and livestock use, irrigation, fish and minnow farming, water for wild life impoundments, and thermoelectric-energy generation. About half the total or 2,440 Mgal/d was used for irrigation, and of that 86 percent was ground water. A little more than half the water used in the state was ground water; streams and reservoirs supplied the rest.

Arkansas↗
USGS1982

Water use in Wisconsin, 1979

This report summarizes the uses of water in Wisconsin for 1979, except aesthetics, navigation, and recreational use. The greatest single use of water, an instream use, was for hydroelectric power production. About 26 trillion gallons, or 93 percent, was used for this purpose. Of the other 7 percent where water is pumped to a different location, 81 percent (6 percent of all water use) was cooling water for thermoelectric powerplants. Withdrawals of surface water and ground water by public and private systems are for residential, industrial, commercial, irrigation, and stock uses.

Wisconsin↗
USGS1995

Ground-water flow and water quality in the sand aquifer of Long Beach Peninsula, Washington

This report describes an investigation of ground-water flow and water quality in the sand aquifer of the Long Beach Peninsula. The peninsula is located in the southwestern corner of the State of Washington, is about 27 miles long, and has an average width of about 1.5 miles. It is surrounded by seawater, by the Pacific Ocean on the west and Willapa Bay on the east. Water supplies on the peninsula are derived mostly from a local water-table aquifer composed largely of sand. The recent growth of population on the peninsula and the projected future growth have created concerns about the quantity and quality of the ground-water resource. Some issues include declining ground-water levels from increased pumpage, and ground-water contamination from seawater intrusion, pesticides or fertilizers from cranberrygrowing areas, and septic-system effluent. The ground-water system of the Long Beach Peninsula consists of a sand aquifer with some lenses of silt and clay that may act as confining beds in local areas. Data are lacking or inconsistent to define a confining bed that extends throughout the peninsula. Hydraulic conductivity calculated from slug tests in 58 shallow wells ranged from 10 to 37 feet per day with a median of 22 feet per day. Average annual ground-water recharge by infiltration and percolation of precipitation is estimated to be about 58 inches or 111,000 acre-feet, which is 72 percent of the average annual precipitation of 80 inches. Average annual ground-water discharge is estimated to be about 30,200 acre-feet to the Pacific Ocean, 56,000 acre-feet to Willapa Bay, and 24,800 acre-feet to surface-water drainage channels. Ground-water movement is generally perpendicular to the spine of the peninsula. A ground-water divide occurs along a north-south line and ground water flows west or east from the divide toward the Pacific Ocean or Willapa Bay. There does not appear to have been any long-term decline of the water table of the sand aquifer from 1974-92. Ground-water levels measured at three east-west cross sections in 1974-75 were at about the same altitude as water levels measured in 1992. Relatively accurate individual regression relations were developed at 45 wells with ground-water altitude as a response variable and cumulative precipitation for 4 months as an explanatory variable. The average coefficient of determination for all individual relations was 0.77, with a range of 0.11 to 0.89. Some empirical frequency or probability relations for precipitation and ground-water levels were used to estimate how often the maximum water levels measured in this study would be expected to occur in the future. These water levels reflected the lower-than-average precipitation that occurred during the study. Assuming that the annual maximum precipitation for 4 consecutive months is random and independent, the historical record of precipitation is representative of the future distribution of precipitation, and the relation between precipitation and water levels is accurate and stationary; a probability analysis of the historical record indicates that in any one year in the future there is a probability of 70 percent that the maximum water levels measured in wells during the winter of 1991-92 would be equaled or exceeded. The shallow ground water had generally low dissolved-solids concentrations in July 1992, with a median concentration of 92 milligrams per liter (mg/L) and a range of 56 to 218 mg/L. Sodium was the dominant cation and bicarbonate was the dominant anion. The distribution of hardness of the water samples was 84 percent with soft water and 16 percent with moderately hard water. The water quality of the shallow ground water was generally good, with a few small to moderate problems. A natural problem is locally high concentrations of dissolved iron. About 30 percent of the water samples had dissolved-iron concentrations of greater than 0.3 mg/L, which is the secondary maximum contaminant level established by the U.S. Environmental Protection Agency. No appreciable amount of seawater has intruded into the sand aquifer. The samples of shallow ground water collected in July 1992 had a median chloride concentration of 15 mg/L and a maximum concentration of 52 mg/L. The heavy average annual precipitation of about 80 inches, large average annual ground-water recharge of about 58 inches or 111,000 acre-feet, and small ground-water withdrawal rate (about 780 acre-feet per year in 1992) combine to maintain a thick freshwater lens of ground water that prevents seawater intrusion throughout the year. Agricultural activities do not appear to have appreciably affected the quality of shallow ground water on the Long Beach Peninsula. The concentration of nitrate in ground water was not significantly higher near cranberry-growing areas, and no sample of ground water or surface water had concentrations of selected pesticides or associated compounds that were above the analytical detection limits. Of the seven ground-water samples in which bacteria were detected, only one sample appeared to be related to agriculture; that sample was from a well located in an area where cattle graze for part of the year. Septic systems probably caused an increase in the concentration of nitrate in shallow ground water in areas of higher population density. Concentrations of nitrate were significantly related to population density. However, the concentrations were not generally high; median concentrations of nitrate increased from less than 0.05 mg/L in areas of low population density to 0.74 mg/L in areas of high density. Septic systems did not cause regional bacterial contamination of the ground water. Bacteria were detected in seven ground-water samples; however, only two of those samples were from wells that are close to septic systems. A limited amount of historical water-quality data is available for the peninsula; therefore, it is difficult to assess long-term changes. From 1968-92, chloride concentrations and values of specific conductance appear to have remained stable. Likewise, it appears that nitrate concentrations did not change from 1987-92.

Washington↗
USGS1993

Simulating the variable-source-area concept of streamflow generation with the watershed model TOPMODEL

This report describes TOPMODEL, which is a physically based watershed model that simulates the variable-source-area concept of streamflow generation. The report describes the theoretical background, model equations, methods to determine parameter values, Fortran computer code, and an example interactive simulation. Using TOPMODEL requires specification of soils and topographic parameters, watershed latitude, and time series of precipitation and air temperature. Model predictions include, in addition to streamflow, estimates of overland and subsurface flow, and an estimate of the spatial pattern of the depth to the water table in the watershed.

Water-Resources Investigations Report↗
USGS1986

Plan of study for the regional aquifer-system analysis of the San Juan structural basin, New Mexico, Colorado, Arizona, and Utah

The San Juan structural basin is an 18,000 sq mi area that contains several extensive aquifers. The basin includes three surface drainage basins and parts of New Mexico, Colorado, Arizona, and Utah. Surface water in the area is fully appropriated, and the steadily increasing demand for groundwater has resulted in water supply concerns. Competition is great between mining and electric power companies, municipalities, and Indian communities for the limited groundwater supplies. This report outlines a 4-year plan for a study of the regional aquifer system in the San Juan structural basin. The purposes of the study are to define and understand the aquifer system; to assess the effects of groundwater use on the aquifers and streams; and to determine the availability and quality of groundwater in the basin. (Author 's abstract)

Water-Resources Investigations Report↗
USGS1999

Occurrence and distribution of fish species in the Great and Little Miami River basins, Ohio and Indiana, pre-1900 to 1998

Historically, 133 fish species representing 25 families have been documented in the Great and Little Miami River Basins. Of these, 132 species have been reported in the basins since 1901, 123 since 1955, 117 since 1980, and 113 post-1990. Natural processes and human activities have both been shown to be major factors in the alteration of fish-community structure and the decrease in species diversity. In the late 1800's, dam construction and the removal of riparian zones restricted fish migration and altered habitat. Industrialization and urbanization increased considerably in the 1900's, further degrading stream habitat and water quality. Species requiring riffles and clean, hard stream bottoms were the most adversely affected. The use of agricultural and industrial chemicals prompted fish-consumption advisories and an increase in studies reporting the occurrence of external fish anomalies. Over the last 20 years, water quality has improved in part because of the upgrading of wastewater-treatment facilities; and, as a result, many streams of the Great and Little Miami River Basins generally meet or exceed existing water-quality standards. Although significant improvements have occurred in the basins, continued efforts to improve water quality and restore the physical habitat of streams will be necessary to increase fish abundance and biodiversity.

Indiana, Ohio↗
USGS1986

Percentage change in saturated thickness of the High Plains Aquifer, west-central Kansas, 1950 to average 1984-86

Continuing studies are being made in west-central Kansas to provide up-to-date information that will aid in the management of groundwater for irrigation. The results are presented of the sixth in a series of studies that used a statistical technique called kriging, to produce hydrologic maps. The kriging technique interpolates water level altitudes at the center of each 1 sq mi section in the study area on the basis of water level measurements from 169 observation wells. For this study, measurements made at each site during the winter months of 1984, 1985, and 1986 were averaged. These interpolated altitudes (1 ,859 in all), along with bedrock-surface and base yr water level altitudes, were used to prepare a hydrologic map that illustrates percentage change in saturated thickness. Saturated thickness, as used in this report, is the thickness of the High Plains aquifer between the groundwater surface, as indicated by water level altitudes, and the bedrock surface. Because irrigation development in west-central Kansas was minimal prior to 1950, the saturated thickness during 1950 represented a nearly static condition in the aquifer. Thus, the decrease in saturated thickness of the aquifer since 1950 is related to the effects of irrigation withdrawals on the volume of water in storage.

Kansas↗
USGS1997

Water-quality assessment of the Lower Susquehanna River Basin, Pennsylvania and Maryland: sources, characteristics, analysis and limitations of nutrient and suspended-sediment data, 1975-90

This report describes analyses of available information on nutrients and suspended sediment collected in the Lower Susquehanna River Basin during water years 1975-90. Most of the analyses were applied to data collected during water years 1980-89. The report describes the spatial and temporal availability of nutrient and suspended-sediment data and presents a preliminary concept of the spatial and temporal patterns of concentrations and loads within the basin. Where data were available, total and dissolved forms of nitrogen and phosphorus species from precipitation, surface water, ground water, and springwater, and bottom material from streams and reservoirs were evaluated. Suspended-sediment data from streams also were evaluated. The U.S. Geological Survey National Water Information System (NWIS) database was selected as the primary database for the analyses. Precipitation-quality data from the National Atmospheric Deposition Program (NADP) and bottom-material-quality data from the National Uranium Resource Evaluation (NURE) were used to supplement the water-quality data from NWIS. Concentrations of nutrients were available from 3 precipitation sites established for longterm monitoring purposes, 883 wells (854 synoptic areal survey sites and 29 project and research sites), 23 springs (17 synoptic areal survey sites and 6 project and research sites), and 894 bottom-material sites (840 synoptic areal survey sites and 54 project and research sites). Concentrations of nutrients and (or) suspended sediment were available from 128 streams (36 long-term monitoring sites, 51 synoptic areal survey sites, and 41 project and research sites). Concentrations of nutrients and suspended sediment in streams varied temporally and spatially and were related to land use, agricultural practices, and streamflow. A general north-to-south pattern of increasing median nitrate concentrations, from 2 to 5 mg/L, was detected in samples collected in study unit streams. In streams that drain areas dominated by agriculture, concentrations of nutrients and suspended sediment tend to be elevated with respect to those found in areas of other land-use types and are related to the amount of commercial fertilizer and animal manure applied to the area drained by the streams. Animal manure is the dominant source of nitrogen for the streams in the lower, agricultural part of the basin. Concentrations of nutrients in samples from wells varied with season and well depth and were related to hydrogeologic setting. Median concentrations of nitrate were 2.5 and 3.5 mg/L for wells drawing water at depths of 0 to 100 ft and 101 to 200 ft, respectively. The lowest median concentrations for nitrate in ground water from wells were generally found in siliciclastic-bedrock, forested settings of the Ridge and Valley Physiographic Province, and the highest were found in carbonate-bedrock agricultural settings of the Piedmont Physiographic Province. Twenty-five percent of the measurements from wells in carbonate rocks in the Piedmont Physiographic Province exceeded the Pennsylvania drinking-water standard. An estimate of mass balance of nutrient loads within the Lower Susquehanna River Basin was produced by combining the available information on stream loads, atmosphericdeposition loads, commercial-fertilizer applications, animal-manure production, privateseptic-system nonpoint-source loads, and municipal and industrial point-source loads. The percentage of the average annual nitrate load carried in base flow of streams in the study unit ranged from 45 to 76 percent, and the average annual phosphorus load carried in base flow ranged from 20 to 33 percent. Average annual yields of nutrients and suspended sediment from tributary basins are directly related to percentage of drainage area in agriculture and inversely to drainage area. Information required to compute loads of nitrogen and phosphorus were available for all sources except atmospheric deposition, for which only nitrogen data were available. Atmospheric deposition is the dominant source of nitrogen for the mostly forested basins draining the upper half of the study unit. The estimate of total annual nitrogen load to the study unit from precipitation is 98.8 million pounds. Nonpoint and point sources of nutrients were estimated. Nonpoint and point sources combined, including atmospheric deposition, provide a potential annual load of 390 million pounds of nitrogen and 79.5 million pounds of phosphorus. The range of percentages of the estimated nonpoint and point sources that were measured in the stream was 20 to 47 percent for nitrogen and 6 to 14 percent for phosphorus. On the average, the Susquehanna River discharges 141,000 pounds of nitrogen and 7,920 pounds of phosphorus to the Lower Susquehanna River reservoir system each year. About 98 percent of the nitrogen and 60 percent of the phosphorus passes through the reservoir system. Interpretations of available water-quality data and conclusions about the water quality of the Lower Susquehanna River Basin were limited by the scarcity of certain types of water-quality data and current ancillary data. A more complete assessment of the water quality of the basin with respect to nutrients and suspended sediment would be enhanced by the availability of additional data for multiple samples over time from all water environments; samples from streams in the northern and western part of the basin; samples from streams and springs throughout the basin during high base-flow or stormflow conditions; and information on current land-use, and nutrient loading from all types of land-use settings.

Maryland, Pennsylvania↗
USGS1994

Low-flow and flow-duration characteristics of Alabama streams

Estimates of minimum 7-day average discharges with recurrence intervals of 2 and 10 years for 228 continuous-record gaging stations are presented in this report. Low-flow frequency discharge estimates for 447 partial-record stations are also presented. These discharge estimates were computed by relating base-flow discharge measurements at the partial- record stations to daily-mean discharge values at selected continuous-record gaging stations. Flow- duration characteristics for 207 continuous-record gaging stations are also provided.

Water-Resources Investigations Report↗
USGS1998

Water resources of Mellette and Todd counties, South Dakota

Mellette and Todd Counties are located in south-central South Dakota and have a combined area of 2,694 square miles. The White River and its tributaries, which include the Little White River, drain Mellette County and about one-half of Todd County. Tributaries to the Niobrara River, which include the Keya Paha River, drain the other one-half of Todd County. The average discharge of the Little White River is about 56 cubic feet per second as the river enters Todd County and is about 131 cubic feet per second as it discharges to the White River in northern Mellette County. The average discharge of the Keya Paha River just outside Todd County is about 39 cubic feet per second. The average annual runoff for Mellette and Todd Counties ranges from 0.94 to 2.36 inches based on records from nine streamflow-gaging stations in and near the counties. The average annual runoff is 1.62 inches, which compares with the average annual precipitation of about 19 inches. In Todd County, shallow wells completed in the alluvial, Ogallala, Arikaree, and White River aquifers generally can supply water that has low concentrations of dissolved solids, is fresh, and is soft to moderately hard. Ground water from shallow aquifers is limited in Mellette County; therefore, deep wells, often greater than 1,000 feet, are sometimes installed. The Pierre Shale often is used to supply rural domestic and stock wells in Mellette County even though well yields are low and the water has high dissolved solids, is moderately saline, and is very hard. Alluvial aquifers are present in both counties and store an estimated 1.6 million acre-feet of water. The water quality of the alluvial aquifers is dependent on the underlying deposits, and generally the water has low concentrations of dissolved solids, is fresh, and is soft to moderately hard where underlain by the Ogallala and Arikaree Formations; has moderate concentrations of dissolved solids, is slightly saline, and is hard where underlain by the White River Group; and has high concentrations of dissolved solids, is saline, and is very hard where underlain by the Pierre Shale. Also, yields often are lower where the alluvial aquifers are underlain by the Pierre Shale. The Ogallala aquifer is present in only Todd County, and the Arikaree aquifer is present throughout most of Todd County and southwestern and south-central Mellette County. The Ogallala aquifer contains an estimated 17 million acre-feet of water in storage, and the Arikaree aquifer contains an estimated 50 million acre-feet of water in storage. Both aquifers generally are suitable for irrigation, and yields from these aquifers are sometimes greater than 1,000 gallons per minute. Nitrate concentrations in 13 out of 92 water samples collected from the Ogallala aquifer exceeded the Primary Drinking Water Maximum Contaminant Level (MCL) of 10 milligrams per liter. In 11 out of 46 samples collected from the Arikaree aquifer, arsenic concentrations exceeded the MCL of 50 micrograms per liter. The White River aquifer, where present, is usually the shallowest source of ground water in Mellette County. The White River aquifer also is used in northern Todd County where the Ogallala and Arikaree aquifers are not present. The White River aquifer contains an estimated 50 million acre-feet of water in storage. Reported yields from the aquifer range from 1 to 30 gallons per minute, which generally is insufficient to support irrigation in most areas. However, yields are sufficient for livestock-watering and rural-domestic purposes. In both counties, the Pierre Shale is the shallowest bedrock aquifer and is exposed at the land surface throughout most of Mellette County. This aquifer is used primarily in Mellette County. Although the aquifer contains an estimated maximum of 1.5 million acre-feet of water in storage, it is not a viable source of ground water because the aquifer is relatively impermeable, yields are low, and water usually can be obtained from shallower sources, especially in Todd County. Reported yields from the Pierre Shale aquifer range from 1 to 8 gallons per minute. Because few test holes and wells penetrate below the Pierre Shale, little is known about the extent of the deeper bedrock aquifers. All wells completed in the Dakota Sandstone, Inyan Kara, and Minnelusa and Madison aquifers in the counties are used for stock-watering purposes. High concentrations of dissolved solids and hard water are characteristic of the water quality in the bedrock aquifers. Depths to the top of the deeper bedrock aquifers range from 1,270 feet to greater than 2,000 feet below land surface.

South Dakota↗
USGS1987

Percentage change in saturated thickness of the High Plains aquifer, west-central Kansas, 1950 to average 1985-87

Continuing studies are being made in west-central Kansas to provide up-to-date information that will aid in the management of groundwater for irrigation. This report, prepared by the U.S> Geological Survey in cooperation with the Western Kansas Groundwater Management District No. 1, presents the results of the seventh in a series of studies that uses a statistical technique, called kriging, to produce hydrologic maps. The kriging technique interpolates water-level altitudes at the center of each 1-square-mile section in the study area on the basis of water-level measurements from 164 observation wells. For this study, measurements made at each site during the winter months of 1985, 1986, and 1987 were averaged. These interpolated altitudes (1859 in all), along with bedrock-surface and base-year water-level altitudes were used to prepare a hydrologic map that illustrates percentage change in saturated thickness. Saturated thickness, as used in this report, is the thickness of the High Plains Aquifer between the groundwater surface, as indicated by water-level altitudes, and the bedrock surface. Because irrigation development in west-central Kansas was minimal prior to 1950, the saturated thickness during 1950 represented a nearly static condition in the aquifer. Thus, the decrease in saturated thickness of the aquifer since 1950 is related to the effects of irrigation withdrawals on the volume of water in storage.

Kansas↗
USGS1976

Availability of ground water in the Middle Connecticut River basin, west-central New Hampshire

This report provides a guide for ground-water exploration and for water- and land-use planning and management. Sufficient amounts of water to supply single family homes are available from the bedrock aquifer nearly everywhere in the middle Connecticut River basin. Relatively thin and narrow, unconsolidated aquifers of sand or sand and gravel commonly capable of yielding more than 200 gallons per minute (12.6 litres per second) to properly located and constructed wells are found only in major stream valley.

New Hampshire↗
USGS1995

Potentiometric surface of the Sparta and Memphis aquifers in eastern Arkansas, April through July 1993

A water-level map of the Sparta and Memphis aquifers for 1993 is presented in this map report. The Sparta-Memphis aquifer, consisting of sands of Eocene age, is present in much of southern and eastern Arkansas. The potentiometric surface map and long-term hydrographs illustrate the effects of large withdrawals for industrial and public supply and, to a lesser extent, agricultural use, on water levels in the aquifer. Three cones of depression, centered in Columbia, Jefferson, and Union Counties, occur in the potentiometric surface.

Arkansas↗
USGS1987

Water resources of the Rio Grande de Añasco-lower valley, Puerto Rico

A large amount of water suitable for most uses is available in the lower Rio Grande de Anasco Valley, the major source of which is the Rio Grande de Anasco which contributes about 95% of the surface water inflow to the lower valley. River flow at El Espino exceeds 100 cu ft/sec about 85% of the time and 200 cu ft/sec 50% of the time. Average daily flow for the driest months of the year (February, March, and April), is almost always <100 cu ft/sec. In contrast, the average daily flow for the wettest, months of the year (September, October, and November), is > 120 cu ft/sec. During the study period, flows of the Rio Canas averaged about 5 cu ft/sec. The lower valley is underlain by igneous rocks that have been eroded to depths of 350 ft or more below sea level. The valley is filled with 250 ft or more of limestone and clay, that in turn is overlain by as much as 100 ft of alluvium. The amount of groundwater available is unknown. There are large volumes of water in the saturated mostly fine-grained alluvium of Zone II, but as a whole the alluvium does not yield water readily to wells. Sand and gravel deposits associated with former river channels yield an estimated 100 to 150 gal/min to wells. The principal source of groundwater is the limestone of Zone III, that reportedly yields as much as 500 gal/min to wells. The quality of surface water especially that of Rio Grande de Anasco was very good. Specific conductance seldom exceeds 250 microsiemens/cm, even at low flows. Both salinity and sodium are low, falling in the Cl-S1 irrigation water classification. Water quality in the lower 5,000 ft or so of the river was affected by saltwater encroachment from the sea. The water quality of the other streams and canals in the lower valley was variable depending on susceptibility of saltwater encroachment, contamination from man-made sources, and concentration of minerals by evapotranspiration. Specific conductance however seldom exceeded 500 microsiemens/cm and the water usually falls in the C1-S2 classification. The quality of groundwater in the alluvial aquifer was about the same as that of the water of the Rio Grande de Anasco except where encroached by saltwater or contaminated. The water from the limestone was more mineralized than that of the alluvium (about 600 to 700 microsiemens/cm), and was somewhat similar to that of the smaller streams and canals in the valley.

Puerto Rico↗
USGS2003

Surface-Water Quality of the Skokomish, Nooksack, and Green-Duwamish Rivers and Thornton Creek, Puget Sound Basin, Washington, 1995-98

Streamflow and surface-water-quality data were collected from November 1995 through April 1998 (water years 1996-98) from a surface-water network in the Puget Sound Basin study unit of the U.S. Geological Survey National Water-Quality Assessment program. Water samples collected monthly and during storm runoff events were analyzed for nutrients, major ions, organic carbon, and suspended sediment, and at selected sites, samples were analyzed for pesticides and volatile organic compounds. Eleven sites were established in three major watersheds--two in the Skokomish River Basin, three in the Nooksack River Basin, five in the Green-Duwamish River Basin, and one site in Thornton Creek Basin, a small tributary to Lake Washington. The Skokomish River near Potlatch, Nooksack River at Brennan, and Duwamish River at Tukwila are integrators of mixed land uses with the sampling sites locally influenced by forestry practices, agriculture, and urbanization, respectively. The remaining eight sites are indicators of relatively homogeneous land use/land cover in their basins. The site on the North Fork Skokomish River is an indicator site chosen to measure reference or background conditions in the study unit. In the Nooksack River Basin, the site on Fishtrap Creek is an indicator of agriculture, and the Nooksack River at North Cedarville is an indicator site of forestry practices in the upper watershed. In the Green-Duwamish River Basin, Springbrook Creek is an urban indicator, Big Soos Creek is an indicator of a rapidly developing suburban basin; Newaukum Creek is an indicator of agriculture; and the Green River above Twin Camp Creek is an indicator of forestry practices. Thornton Creek is an indicator of high-density urban residential and commercial development. Conditions during the first 18 months of sampling were dominated by above-normal precipitation. For the Seattle-Tacoma area, water year 1997 was the wettest of the 3 years during the sample-collection period. Nearly 52 inches fell (about 14 inches above average) and monthly precipitation was often 200 percent of normal. The wet years kept streamflows generally above normal and contributed to high concentrations of pesticides, nutrients, suspended sediment, and organic carbon in samples. On the basis of chemical concentrations, dissolved oxygen concentrations, and water temperature, the relative quality of water among the 11 study sites ranged from exceptionally high in the North Fork Skokomish and the Green to fair in Springbrook and Thornton. Water in the large rivers (Skokomish, Nooksack, Green-Duwamish) and in two of the small streams in the Puget Sound Lowlands (Big Soos and Newaukum) was characterized by dilute water chemistry with dissolved solids concentrations less than 130 milligrams per liter. Water in three other small streams in the Lowlands (Fishtrap, Springbrook, and Thornton) had dissolved solids concentrations as high as 320 milligrams per liter. Nutrient and pesticide concentrations mostly were higher in the small streams than in the large rivers. Suspended-sediment concentrations, however, were highest in the large rivers, with averages ranging from 85 to 443 milligrams per liter. During storm and flood events, suspended-sediment concentrations in samples from the Nooksack were as much as 2,800 milligrams per liter, and from the Skokomish, 1,500 milligrams per liter. Out of 86 pesticides and 86 volatile organic compounds analyzed, a total of 35 pesticides and 11 volatile organic compounds were detected at concentrations above laboratory reporting levels in samples collected from the four intensively studied sites, the lower Nooksack River, Duwamish River, Fishtrap Creek, and Thornton Creek. Herbicides were detected more frequently than insecticides. The herbicide prometon was detected in 66 percent of all 124 samples collected, followed by simazine (65 percent), atrazine (64 percent), and the insecticide diazinon (50 percent). The detected volatile organic c

Water-Resources Investigations Report↗
USGS2003

Methods of analysis by the U.S. Geological Survey National Water Quality Laboratory-Determination of organophosphate pesticides in whole water by continuous liquid-liquid extraction and capillary-column gas chromatography with flame photometric detection

A method for the isolation of 20 parent organophosphate pesticides and 5 organophosphate pesticide degradates from natural-water samples is described. Compounds are extracted from water samples with methylene chloride using a continuous liquid-liquid extractor for 6 hours. The solvent is evaporated using heat and a flow of nitrogen to a volume of 1 milliliter and solvent exchanged to ethyl acetate. Extracted compounds are determined by capillary-column gas chromatography with flame photometric detection. Single-operator derived method detection limits in three water-matrix samples ranged from 0.003 to 0.009 microgram per liter. Method performance was validated by spiking all compounds in three different matrices at three different concentrations. Eight replicates were analyzed at each concentration in each matrix. Mean recoveries of most method compounds spiked in surface-water samples ranged from 54 to 137 percent and those in ground-water samples ranged from 40 to 109 percent for all pesticides. Recoveries in reagent-water samples ranged from 42 to 104 percent for all pesticides. The only exception was O-ethyl-O-methyl-S-propylphosphorothioate, which had variable recovery in all three matrices ranging from 27 to 79 percent. As a result, the detected concentration of O-ethyl-O-methyl-S-propylphosphorothioate in samples is reported in this method with an estimated remark code. Based on the performance issue, two more compounds, disulfoton and ethion monoxon, also will be reported in this method with an estimated remark code. Estimated-value compounds, which are ?E-coded? in the data base, do not meet the performance criteria for unqualified quantification, but are retained in the method because the compounds are important owing to high use or potential environmental effects and because analytical performance has been consistent and reproducible.

Water-Resources Investigations Report↗
USGS1976

A technique for estimating the time of travel of water in Indiana streams

Estimates of the traveltime of waterborne particles in streams is important for pollution studies and in the event of spills of contaminants. This report provides data for the 16 Indiana streams on which time-of-travel information has been obtained and a means for estimating the velocity of any naturally flowing stream in Indiana with a drainage area of 80 square miles (210 square kilometres) or more. Measured velocity rates compiled from the time-of-travel data collected in Indiana are releated to 25, 50, 100, and 200 percent of the average discharge of streams shown in this report. Velocities at these discharges are significantly related to their respective watershed characteristics (average discharge and slope). Generalized relations of the velocities as functions of the streams' watershed characteristics are developed as multivariate regression equations using the data from each of the measured streams. Examples of uses and applications of the measured data and the predictive equations are given.

Indiana↗
USGS2005

Chapter A6. Section 6.7. Turbidity

Turbidity is one of the indicators used to assess the environmental health of water bodies. Turbidity is caused by the presence of suspended and dissolved matter, such as clay, silt, finely divided organic matter, plankton and other microscopic organisms, organic acids, and dyes. This section of the National Field Manual (NFM) describes the USGS protocols for determining turbidity in surface and ground waters, including extensive guidance for equipment selection and data reporting. It includes the revised approach to turbidity measurement and reporting that was implemented by the U.S. Geological Survey (USGS) in October 2004 to account for technological advances and consequent measurement complexities. Each chapter of the National Field Manual is published separately and revised periodically. Newly published and revised chapters will be announced on the USGS Home Page on the World Wide Web under 'New Publications of the U.S. Geological Survey.'

Techniques of Water-Resources Investigations↗