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Stream classification of the Apalachicola-Chattahoochee-Flint River System to support modeling of aquatic habitat response to climate change

A stream classification and associated datasets were developed for the Apalachicola-Chattahoochee-Flint River Basin to support biological modeling of species response to climate change in the southeastern United States. The U.S. Geological Survey and the Department of the Interior’s National Climate Change and Wildlife Science Center established the Southeast Regional Assessment Project (SERAP) which used downscaled general circulation models to develop landscape-scale assessments of climate change and subsequent effects on land cover, ecosystems, and priority species in the southeastern United States. The SERAP aquatic and hydrologic dynamics modeling efforts involve multiscale watershed hydrology, stream-temperature, and fish-occupancy models, which all are based on the same stream network. Models were developed for the Apalachicola-Chattahoochee-Flint River Basin and subbasins in Alabama, Florida, and Georgia, and for the Upper Roanoke River Basin in Virginia. The stream network was used as the spatial scheme through which information was shared across the various models within SERAP. Because these models operate at different scales, coordinated pair versions of the network were delineated, characterized, and parameterized for coarse- and fine-scale hydrologic and biologic modeling. The stream network used for the SERAP aquatic models was extracted from a 30-meter (m) scale digital elevation model (DEM) using standard topographic analysis of flow accumulation. At the finer scale, reaches were delineated to represent lengths of stream channel with fairly homogenous physical characteristics (mean reach length = 350 m). Every reach in the network is designated with geomorphic attributes including upstream drainage basin area, channel gradient, channel width, valley width, Strahler and Shreve stream order, stream power, and measures of stream confinement. The reach network was aggregated from tributary junction to tributary junction to define segments for the benefit of hydrological, soil erosion, and coarser ecological modeling. Reach attributes are summarized for each segment. In six subbasins segments are assigned additional attributes about barriers (usually impoundments) to fish migration and stream isolation. Segments in the six sub-basins are also attributed with percent urban area for the watershed upstream from the stream segment for each decade from 2010–2100 from models of urban growth. On a broader scale, for application in a coarse-scale species-response model, the stream-network information is aggregated and summarized by 256 drainage subbasins (Hydrologic Response Units) used for watershed hydrologic and stream-temperature models. A model of soil erodibility based on the Revised Universal Soil Loss Equation also was developed at this scale to parameterize a model to evaluate stream condition. The reach-scale network was classified using multivariate clustering based on modeled channel width, valley width, and mean reach gradient as variables. The resulting classification consists of a 6-cluster and a 12-cluster classification for every reach in the Apalachicola-Chattahoochee-Flint Basin. We present an example of the utility of the classification that was tested using the occurrence of two species of darters and two species of minnows in the Apalachicola-Chattahoochee-Flint River Basin, the blackbanded darter and Halloween darter, and the bluestripe shiner and blacktail shiner.

Alabama, Florida, Georgia, Virginia↗

Effects of prescribed fire timing on vigor of the invasive forb sericea lespedeza (Lespedeza cuneata), total forage biomass accumulation, plant-community composition, and native fauna on tallgrass prairie in the Kansas Flint Hills

The predominant grazing-management practice of the Kansas Flint Hills involves annual prescribed burning in March or April with postfire grazing by yearling beef cattle at a high stocking density from April to August. There has been a dramatic increase in sericea lespedeza ( Lespedeza cuneata [Dumont] G. Don) coincident with this temporally focused use of prescribed fire in the Flint Hills region. The species is an aggressive invader and a statewide noxious weed in Kansas. Control has generally been attempted using repeated herbicide applications. This approach has not limited proliferation of sericea lespedeza and resulted in collateral damage to nontarget flora and fauna. Alternative timing of prescribed fire has not been evaluated for its control. Our objectives for this 4-yr experiment were to (1) document the effects of prescribed burning during early April, early August, or early September on vigor of sericea lespedeza, standing forage biomass, and basal cover of native graminoids, forbs, and shrubs and (2) measure responses to fire regimes by grassland bird and butterfly communities. Whole-plant dry mass, basal cover, and seed production of sericea lespedeza were markedly less ( P < 0.01) in areas treated with prescribed fire in August or September compared with April. Forage biomass did not differ ( P ≥ 0.43) among treatments when measured during July; moreover, frequencies of bare soil, litter, and total basal plant cover were not different ( P ≥ 0.29) among treatments. Combined basal covers of C4 grasses, C3 grasses, annual grasses, forbs, and shrubs also did not differ ( P ≥ 0.11) between treatments. Densities of grasshopper sparrow ( Ammodramus savannarum ), dickcissel ( Spiza americana ), and eastern meadowlark ( Sturnella magna ) were not negatively affected ( P > 0.10) by midsummer or late-summer fires relative to early-spring fires. There were no differences ( P > 0.10) in densities of grassland-specialist butterfly species across fire regimes. Under the conditions of our experiment, prescribed burning during summer produced no detrimental effects on forage production, desirable nontarget plant species, grassland birds, or butterfly communities but had strong suppressive effects on sericea lespedeza. Additional research is warranted to investigate how to best incorporate late-summer prescribed fire into common grazing-management practices in the Kansas Flint Hills.

Kansas↗

Sequestration of hydrophobic organic contaminants by geosorbents

The chemical interactions of hydrophobic organic contaminants (HOCs) with soils and sediments (geosorbents) may result in strong binding and slow subsequent release rates that significantly affect remediation rates and endpoints. The underlying physical and chemical phenomena potentially responsible for this apparent sequestration of HOCs by geosorbents are not well understood. This challenges our concepts for assessing exposure and toxicity and for setting environmental quality criteria. Currently there are no direct observational data revealing the molecular-scale locations in which nonpolar organic compounds accumulate when associated with natural soils or sediments. Hence macroscopic observations are used to make inferences about sorption mechanisms and the chemical factors affecting the sequestration of HOCs by geosorbents. Recent observations suggest that HOC interactions with geosorbents comprise different inorganic and organic surfaces and matrices, and distinctions may be drawn along these lines, particularly with regard to the roles of inorganic micropores, natural sorbent organic matter components, combustion residue particulate carbon, and spilled organic liquids. Certain manipulations of sorbates or sorbent media may help reveal sorption mechanisms, but mixed sorption phenomena complicate the interpretation of macroscopic data regarding diffusion of HOCs into and out of different matrices and the hysteretic sorption and aging effects commonly observed for geosorbents. Analytical characterizations at the microscale, and mechanistic models derived therefrom, are needed to advance scientific knowledge of HOC sequestration, release, and environmental risk.

Environmental Science & Technology↗

Sources and haloacetic acid/trihalomethane formation potentials of aquatic humic substances in the Wakarusa River and Clinton Lake near Lawrence, Kansas

Gram quantities of aquatic humic substances (AHS) were extracted from the Wakarusa River−Clinton Lake Reservoir system, near Lawrence, KS, to support nuclear magnetic resonance (NMR) experimental studies, report concentrations of dissolved organic carbon (DOC) and AHS, define sources of the AHS, and determine if the AHS yield sufficient quantities of haloacetic acids (HAA5) and trihalomethanes (THM4) that exceed U.S. Environmental Protection Agency (EPA) Maximum Contaminant Levels (MCL) in drinking water. AHS from the Wakarusa River and Clinton Lake originated from riparian forest vegetation, reflected respective effects of soil organic matter and aquatic algal/bacterial sources, and bore evidence of biological degradation and photodegradation. AHS from the Wakarusa River showed the effect of terrestrial sources, whereas Clinton Lake humic acid also reflected aquatic algal/bacterial sources. Greater amounts of carbon attributable to tannin-derived chemical structures may correspond with higher HAA5 and THM4 yields for Clinton Lake fulvic acid. Prior to appreciable leaf-fall from deciduous trees, the combined (humic and fulvic acid) THM4 formation potentials for the Wakarusa River approached the proposed EPA THM4 Stage I MCL of 80 μg/L, and the combined THM4 formation potential for Clinton Lake slightly exceeded the proposed THM4 Stage II MCL of 40 μg/L. Finally, AHS from Clinton Lake could account for most (>70%) of the THM4 concentrations in finished water from the Clinton Lake Water Treatment Plant based on September 23, 1996, THM4 results.

Environmental Science & Technology↗

Sorption of pure N 2 O to biochars and other organic and inorganic materials under anhydrous conditions

Suppression of nitrous oxide (N 2 O) emissions from soil is commonly observed after amendment with biochar. The mechanisms accounting for this suppression are not yet understood. One possible contributing mechanism is N 2 O sorption to biochar. The sorption of N 2 O and carbon dioxide (CO 2 ) to four biochars was measured in an anhydrous system with pure N 2 O. The biochar data were compared to those for two activated carbons and other components potentially present in soils—uncharred pine wood and peat—and five inorganic metal oxides with variable surface areas. Langmuir maximum sorption capacities ( Q max ) for N 2 O on the pine wood biochars (generated between 250 and 500 °C) and activated carbons were 17–73 cm 3 g –1 at 20 °C (median 51 cm 3 g –1 ), with Langmuir affinities ( b ) of 2–5 atm –1 (median 3.4 atm –1 ). Both Q max and b of the charred materials were substantially higher than those for peat, uncharred wood, and metal oxides [ Q max 1–34 cm 3 g –1 (median 7 cm 3 g –1 ); b 0.4–1.7 atm –1 (median 0.7 atm –1 )]. This indicates that biochar can bind N 2 O more strongly than both mineral and organic soil materials. Q max and b for CO 2 were comparable to those for N 2 O. Modeled sorption coefficients obtained with an independent polyparameter—linear free-energy relationship matched measured data within a factor 2 for mineral surfaces but underestimated by a factor of 5–24 for biochar and carbonaceous surfaces. Isosteric enthalpies of sorption of N 2 O were mostly between −20 and −30 kJ mol –1 , slightly more exothermic than enthalpies of condensation (−16.1 kJ mol –1 ). Q max of N 2 O on biochar (50000–130000 μg g –1 biochar at 20 °C) exceeded the N 2 O emission suppressions observed in the literature (range 0.5–960 μg g –1 biochar; median 16 μg g –1 ) by several orders of magnitude. Thus, the hypothesis could not be falsified that sorption of N 2 O to biochar is a mechanism of N 2 O emission suppression.

Environmental Science & Technology↗

ChemCam activities and discoveries during the nominal mission of the Mars Science Laboratory in Gale crater, Mars

At Gale crater, Mars, ChemCam acquired its first laser-induced breakdown spectroscopy (LIBS) target on Sol 13 of the landed portion of the mission (a Sol is a Mars day). Up to Sol 800, more than 188 000 LIBS spectra were acquired on more than 5800 points distributed over about 650 individual targets. We present a comprehensive review of ChemCam scientific accomplishments during that period, together with a focus on the lessons learned from the first use of LIBS in space. For data processing, we describe new tools that had to be developed to account for the uniqueness of Mars data. With regard to chemistry, we present a summary of the composition range measured on Mars for major-element oxides (SiO 2 , TiO 2 , Al 2 O 3 , FeO T , MgO, CaO, Na 2 O, K 2 O) based on various multivariate models, with associated precisions. ChemCam also observed H, and the non-metallic elements C, O, P, and S, which are usually difficult to quantify with LIBS. F and Cl are observed through their molecular lines. We discuss the most relevant LIBS lines for detection of minor and trace elements (Li, Rb, Sr, Ba, Cr, Mn, Ni, and Zn). These results were obtained thanks to comprehensive ground reference datasets, which are set to mimic the expected mineralogy and chemistry on Mars. With regard to the first use of LIBS in space, we analyze and quantify, often for the first time, each of the advantages of using stand-off LIBS in space: no sample preparation, analysis within its petrological context, dust removal, sub-millimeter scale investigation, multi-point analysis, the ability to carry out statistical surveys and whole-rock analyses, and rapid data acquisition. We conclude with a discussion of ChemCam performance to survey the geochemistry of Mars, and its valuable support of decisions about selecting where and whether to make observations with more time and resource-intensive tools in the rover's instrument suite. In the end, we present a bird's-eye view of the many scientific results: discovery of felsic Noachian crust, first observation of hydrated soil, discovery of manganese-rich coatings and fracture fills indicating strong oxidation potential in Mars' early atmosphere, characterization of soils by grain size, and wide scale mapping of sedimentary strata, conglomerates, and diagenetic materials.

Journal of Analytical Atomic Spectrometry↗

Improving the ability to include freshwater wetland plants in process-based models

Considerable effort and resources have been placed into conservation programs designed to reduce or alleviate negative environmental effects of crop production and into evaluation of the benefits of these programs. Wetlands are an important source of ecosystem services, but modeling wetland plants is an emerging science. To date, wetland plant growth has not been explicitly accounted for in ecosystem service models that quantify conservation program effects. As part of an effort to more accurately simulate wetland plants within process-based models, we expanded upon plant growth data collected in an earlier effort with additional sampling at two of four previously sampled areas, and included a fifth sampling site. We then used data from the five sites spanning five years as wetland plant parameters at both the species and functional group levels for the Agricultural Land Management Alternative with Numerical Assessment Criteria (ALMANAC) model. In addition to individual species, modelers are interested in functional groups representing a collection of species because it is unrealistic to model every species occurring in an ecosystem. ALMANAC simulations were completed at three sites for both individual wetland plant species and functional groups. At each site, simulated plant yields were within 1 Mg ha –1 (±7%) of measured values ( r 2 = 0.99). Multisite species simulated yields were within 37% of measured values ( r 2 = 0.95). Functional groups performed as well as individual species simulations. Functional group simulated yields were within 1 Mg ha –1 (±5%) of measured yields. Plant growth is a major component of these wetland ecosystems, and ALMANAC verified wetland plant parameters support more accurate assessments of conservation programs and practices on the influence of wetland ecosystems embedded within agricultural fields. The improved plant parameters we provide here will be transferred to other process-based models that focus on other ecosystem components such as soil and water effects, facilitating wetland evaluations across the United States and elsewhere.

California, Delaware, Maryland, North Dakota, Texa↗

Occurrence of antibiotics in wastewater treatment facilities in Wisconsin, USA

Samples from several wastewater treatment facilities in Wisconsin were screened for the presence of 21 antibiotic compounds. These facilities spanned a range of community size served (average daily flow from 0.0212 to 23.6 million gallons/day), secondary treatment processes, geographic locations across the state, and they discharged the treated effluents to both surface and ground waters (for ground water after a soil passage). A total of six antibiotic compounds were detected (1–5 compounds per site), including two sulfonamides (sulfamethazine, sulfamethoxazole), one tetracycline (tetracycline), fluoroquinolone (ciprofloxacin), macrolide (erythromycin-H 2 O) and trimethoprim. The frequency of detection of antibiotics was in the following order: tetracycline and trimethoprim (80%) > sulfamethoxazole (70%) > erythromycin-H 2 O (45%) > ciprofloxacin (40%) > sulfamethazine (10%). However, the soluble concentrations were in the parts-per-billion (ppb) range (≤ 1.3 μg/L), and importantly were unaffected by the size of the wastewater treatment facility. The concentrations detected were within an order of magnitude of those reported for similar systems in Europe and Canada: they were within a factor of two in comparison to those reported for Canada but generally lower relative to those measured in wastewater systems in Europe. Only sulfamethoxazole and tetracycline were detected in groundwater monitoring wells adjacent to the treatment systems. Future intensive wastewater monitoring programs in Wisconsin may be limited to the six antibiotic compounds detected in this study.

Science of the Total Environment↗

Identifying and filling critical knowledge gaps can optimize financial viability of blue carbon projects in tidal wetlands

One of the world’s largest “blue carbon” ecosystems, Louisiana’s tidal wetlands on the US Gulf of Mexico coast, is rapidly being lost. Louisiana’s strong legal, regulatory, and monitoring framework, developed for one of the world’s largest tidal wetland systems, provides an opportunity for a programmatic approach to blue carbon accreditation to support restoration of these ecologically and economically important tidal wetlands. Louisiana’s coastal wetlands span ∼1.4 million ha and accumulate 5.5–7.3 Tg yr −1 of blue carbon (organic carbon), ∼6%–8% of tidal marsh blue carbon accumulation globally. Louisiana has a favorable governance framework to advance blue carbon accreditation, due to centralized restoration planning, long term coastal monitoring, and strong legal and regulatory frameworks around carbon. Additional restoration efforts, planned through Louisiana’s Coastal Master Plan, over 50 years are projected to create, or avoid loss of, up to 81,000 ha of wetland. Current restoration funding, primarily from Deepwater Horizon oil spill settlements, will be fully committed by the early 2030s and additional funding sources are required. Existing accreditation methodologies have not been successfully applied to coastal Louisiana’s ecosystem restoration approaches or herbaceous tidal wetland types. Achieving financial viability for accreditation of these restoration and wetland types will require expanded application of existing blue carbon crediting methodologies. It will also require expanded approaches for predicting the future landscape without restoration, such as numerical modeling, to be validated. Additional methodologies (and/or standards) would have many common elements with those currently available but may be beneficial, depending on the goals and needs of both the state of Louisiana and potential purchasers of Louisiana tidal wetland carbon credits. This study identified twenty targeted needs that will address data and knowledge gaps to maximize financial viability of blue carbon accreditation for Louisiana’s tidal wetlands. Knowledge needs were identified in five categories: legislative and policy, accreditation methodologies and standards, soil carbon flux, methane flux, and lateral carbon flux. Due to the large spatial scale and diversity of tidal wetlands, it is expected that progress in coastal Louisiana has high potential to be generalized to similar wetland ecosystems across the northern Gulf of Mexico and globally.

Louisiana↗

Partition characteristics of polycyclic aromatic hydrocarbons on soils and sediments

The partition behavior was determined for three polycyclic aromatic hydrocarbons (PAHs), i.e., naphthalene, phenanthrene, and pyrene, from water to a range of soil and sediment samples. The measured partition coefficients of the individual PAHs between soil/sediment organic matter (SOM) and water (i.e., K(oc) values) are relatively invariant either for the 'clean' (uncontaminated) soils or for the clean sediments; however, the mean K(oc) values on the sediments are about twice the values on the soils. This disparity is similar to the earlier observation for other nonpolar solutes and reflects the compositional differences between soil and sediment organic matters. No significant differences in K(oc) are observed between a clean coastal marine sediment and freshwater sediments. The coastal sediments that are significantly impacted by organic contaminants exhibit higher K(oc) values. At given K(ow) values (octanol-water), the PAHs exhibit much higher K(oc) values than other relatively nonpolar solutes (e.g., chlorinated hydrocarbons). This effect is shown to result from the enhanced partition of PAHs to SOM rather than from lower K(ow) values of PAHs at given supercooled liquid solute solubilities in water. The enhanced partition of PAHs over other nonpolar solutes in SOM provides an account of the markedly different correlations between log K(oc) and log K(ow) for PAHs and for other nonpolar solutes. The improved partition of PAHs in SOM stems apparently from the enhanced compatibility of their cohesive energy densities with those of the aromatic components in SOM. The approximate aromatic fraction in soil/sediment organic matter has been assessed by solid-state 13C-NMR spectroscopy.The partition behavior was determined for three polycyclic aromatic hydrocarbons (PAHs), i.e., naphthalene, phenanthrene, and pyrene, from water to a range of soil and sediment samples. The measured partition coefficients of the individual PAHs between soil/sediment organic matter (SOM) and water (i.e., Koc values) are relatively invariant either for the `clean' (uncontaminated) soils or for the clean sediments; however, the mean Koc values on the sediments are about twice the values on the soils. This disparity is similar to the earlier observation for other nonpolar solutes and reflects the compositional differences between soil and sediment organic matters. No significant differences in Koc are observed between a clean coastal marine sediment and freshwater sediments. The coastal sediments that are significantly impacted by organic contaminants exhibit higher Koc values. At given Kow values (octanol-water), the PAHs exhibit much higher Koc values than other relatively nonpolar solutes (e.g., chlorinated hydrocarbons). This effect is shown to result from the enhanced partition of PAHs to SOM rather than from lower Kow values of PAHs at given supercooled liquid solute solubilities in water. The enhanced partition of PAHs over other nonpolar solutes in SOM provides an account of the markedly different correlations between log Koc and log Kow for PAHs and for other nonpolar solutes. The improved partition of PAHs in SOM stems apparently from the enhanced compatibility of their cohesive energy densities with those of the aromatic components in SOM. The approximate aromatic fraction in soil/sediment organic matter has been assessed by solid-state 13C-NMR spectroscopy.

Environmental Science & Technology↗

Silicate melt inclusions and glasses in lunar soil fragments from the Luna 16 core sample

More than 2000 fragments were studied microscopically, and electron microprobe analyses were made of 39 selected areas, from a few square mm of polished surface, through 75- to 425-μm fragments of lunar soil from two samples of the Luna 16 core. The silicate melt inclusions and glasses differ in important details from those observed earlier in the Apollo samples. Melt inclusions in olivine contain epitaxially oriented daughter crystals, but also show a similar epitaxy around the outside of the crystals not observed in previous lunar samples. Melt inclusions in ilmenite suggest trapping at successive stages in a differentiation sequence. There is abundant evidence for late-stage silicate liquid immiscibility, with melt compositions similar but not identical to those from Apollo 11 and 12. A comparison of the alkali ratio of any given bulk rock analysis with that of its late-stage, high-silica melt shows gross differences for different rocks. This is pertinent to understanding late-stage differentiation processes. Glass fragments and spherules exhibit a wide range of crystallization textures, reflecting their wide range of compositions and cooling histories. No significant differences were found between the two portions of core examined (Zones A and D).

Earth and Planetary Science Letters↗

Predicting redox conditions in groundwater at a national scale using random forest classification

Redox conditions in groundwater may markedly affect the fate and transport of nutrients, volatile organic compounds, and trace metals, with significant implications for human health. While many local assessments of redox conditions have been made, the spatial variability of redox reaction rates makes the determination of redox conditions at regional or national scales problematic. In this study, redox conditions in groundwater were predicted for the contiguous United States using random forest classification by relating measured water quality data from over 30,000 wells to natural and anthropogenic factors. The model correctly predicted the oxic/suboxic classification for 78 and 79% of the samples in the out-of-bag and hold-out data sets, respectively. Variables describing geology, hydrology, soil properties, and hydrologic position were among the most important factors affecting the likelihood of oxic conditions in groundwater. Important model variables tended to relate to aquifer recharge, groundwater travel time, or prevalence of electron donors, which are key drivers of redox conditions in groundwater. Partial dependence plots suggested that the likelihood of oxic conditions in groundwater decreased sharply as streams were approached and gradually as the depth below the water table increased. The probability of oxic groundwater increased as base flow index values increased, likely due to the prevalence of well-drained soils and geologic materials in high base flow index areas. The likelihood of oxic conditions increased as topographic wetness index (TWI) values decreased. High topographic wetness index values occur in areas with a propensity for standing water and overland flow, conditions that limit the delivery of dissolved oxygen to groundwater by recharge; higher TWI values also tend to occur in discharge areas, which may contain groundwater with long travel times. A second model was developed to predict the probability of elevated manganese (Mn) concentrations in groundwater (i.e., ≥50 μg/L). The Mn model relied on many of the same variables as the oxic/suboxic model and may be used to identify areas where Mn-reducing conditions occur and where there is an increased risk to domestic water supplies due to high Mn concentrations. Model predictions of redox conditions in groundwater produced in this study may help identify regions of the country with elevated groundwater vulnerability and stream vulnerability to groundwater-derived contaminants.

contiguous United States↗

“Leaky weirs” capture alluvial deposition and enhance seasonal mountain-front recharge in dryland streams

“Leaky weirs” are rock structures installed in dryland streams, which are anchored into exposed bedrock, loosely cemented, and designed to allow water to slowly pass through. They are being tested at a ranch in southeastern Arizona, USA, to restore and conserve the historic range and desert wetlands. Data are collected to assess how leaky weirs impact surface water, subsurface water, and groundwater recharge—including stream discharge, timing, and depth of infiltration, and groundwater elevations. Three adjacent watersheds, two with outlets just below leaky weirs and one with leaky weirs farther upstream, were instrumented with water-level loggers, wildlife cameras, and crest stage instruments with temperature sensors in the soil. As most groundwater recharge is assumed to be focused along the mountain fronts in this region, mountain-block recharge is also evaluated to differentiate between the two using isotope analyses. Finally, a single, late-season flood event is scrutinized to consider the leaky weir effect on all monitored components in the water budget. Results indicated groundwater flow is primarily from the mountains to the east via older, regional mountain-block recharge. However, the development of shallow alluvial aquifers is supported by the leaky weirs, that slow flows, capture permeable sediments, and allow infiltration, thus enhancing mountain-front recharge. In turn, these new pockets of water help support the restoration of historic wetlands. Sediment accumulates where leaky weirs are installed, reducing flashy peak flows, and resulting in a series of infiltration ponds along the channel that support vegetation during growing seasons and recharge the shallow aquifer during non-growing seasons.

Arizona↗

Pancam multispectral imaging results from the Spirit Rover at Gusev crater

Panoramic Camera images at Gusev crater reveal a rock-strewn surface interspersed with high- to moderate-albedo fine-grained deposits occurring in part as drifts or in small circular swales or hollows. Optically thick coatings of fine-grained ferric iron-rich dust dominate most bright soil and rock surfaces. Spectra of some darker rock surfaces and rock regions exposed by brushing or grinding show near-infrared spectral signatures consistent with the presence of mafic silicates such as pyroxene or olivine. Atmospheric observations show a steady decline in dust opacity during the mission, and astronomical observations captured solar transits by the martian moons, Phobos and Deimos, as well as a view of Earth from the martian surface.

Science↗

Radiocarbon dates of pre-Mankato events in eastern and central North America

1) A group of samples from horizons previously correlated with the upper part of the Cary substage confirms the correlation as reasonable and is consistently related in time to the dates of the peat layer at Two Creeks and subsequent Mankato events. 2) A major glaciation affected the Great Lakes region beginning 25,000 or more yr ago and reaching its maximum extent about 18,000 yr ago. It is represented by drift correlated in Ohio with the Cary substage and, at least in part, with the Tazewell substage; in Illinois and adjacent states it is correlated with most of the Tazewell substage and with the Farmdale loess. 3) The ecology and other associations implied by the dated samples are more consistent with glacial than with nonglacial conditions. 4) The lower till at Sidney, Ohio (W-188), on which is developed a soil considered a correlative of the Fox series soil on gravels and also buried by till of the major glaciation of 25,000 to 18,000 yr ago, indicates an earlier glaciation extensively exposed in Ohio and believed to be an early Wisconsin event. Table 2. List of samples and dates arranged by age groups. [See table in the PDF file] 5) An earlier glaciation, or glaciations, is implied at several localities by peat, gyttja, or wood more than 30,000 yr old, overlain by till. 6) The time interval between the middle group and the old group of samples, which has been determined within conservative radiocarbon limits to be greater than 3000 yr, is possibly of the order of 16,000 yr, as suggested by the depth of leaching at Sidney, Ohio.(The ages of all the samples discussed are listed in Table 2.) 7) An attempt should now be made to fix more closely the dates of the old samples and to reexamine in the field the stratigraphic sequence in the light of the radiocarbon dates discussed.

Science↗

Debris-flow mobilization from landslides

Field observations, laboratory experiments, and theoretical analyses indicate that landslides mobilize to form debris flows by three processes: ( a ) widespread Coulomb failure within a sloping soil, rock, or sediment mass, ( b ) partial or complete liquefaction of the mass by high pore-fluid pressures, and ( c ) conversion of landslide translational energy to internal vibrational energy (i.e. granular temperature). These processes can operate independently, but in many circumstances they appear to operate simultaneously and synergistically. Early work on debris-flow mobilization described a similar interplay of processes but relied on mechanical models in which debris behavior was assumed to be fixed and governed by a Bingham or Bagnold rheology. In contrast, this review emphasizes models in which debris behavior evolves in response to changing pore pressures and granular temperatures. One-dimensional infinite-slope models provide insight by quantifying how pore pressures and granular temperatures can influence the transition from Coulomb failure to liquefaction. Analyses of multidimensional experiments reveal complications ignored in one-dimensional models and demonstrate that debris-flow mobilization may occur by at least two distinct modes in the field.

Annual Review of Earth and Planetary Sciences↗

Sources and chemical stability of soil organic carbon in natural and created coastal marshes of Louisiana

Coastal marshes are globally important for sequestering carbon, yet sea-level rise and anthropogenic stressors can reduce their capacity as carbon sinks. Marsh restoration can offset a portion of carbon loss through the degradation of natural marshes, but potential differences in the sources and stability of soil organic carbon (SOC) between created and natural marshes may affect their function as a long-term carbon sink. Here, we examine the sources and chemical stability of SOC in natural and created marshes across the Gulf coast of Louisiana, USA. Marshes were examined along an estuarine salinity gradient in a former interdistributary basin of the Mississippi River Delta and in six created marshes across a 32-year chronosequence and a natural reference marsh ( n = 6) in the Chenier Plain. Carbon source was assessed using δ 13 C analysis and chemical stability was determined through an acid hydrolysis digestion that removed labile carbon (LC). Soil δ 13 C values suggested that the local vegetation dominated SOC in all natural marshes although brackish marshes had a mix of sources and degradation of SOC. Recalcitrant carbon (RC) was 72.2 ± 0.5 % of SOC across fresh, brackish and saline marshes. The depth-averaged RC accumulation rate was almost three times greater than LC accumulation rate, yet both contributed significantly to accretion and long-term SOC accumulation (124–132 g m −2 y −1 in natural marshes). RC and SOC accumulation rate increased with mineral sediment accumulation rate. For the created marshes, SOC became increasingly recalcitrant due to an increase in in-situ plant inputs, but accumulation rates were lower than the natural marshes. Overall, this study illustrates that natural marshes have a large stock of RC from the vegetation while dredge sediment created marshes have no plant-derived carbon initially, which accumulates slowly thereafter. Restoration practices may be improved by preserving and augmenting these deteriorating but carbon-rich natural marshes.

Louisiana↗

Using high resolution satellite and telemetry data to track flooded habitats, their use by waterfowl, and evaluate effects of drought on waterfowl and shorebird bioenergetics in California

Wetland managers in the Central Valley of California, a dynamic hydrological landscape, require information regarding the amount and location of existing wetland habitat to make decisions on how to best use water resources to support multiple wildlife objectives, particularly during drought. Scientists from the U.S. Geological Survey Western Ecological Research Center (WERC), Point Blue Conservation Science (Point Blue), and the U.S. Fish and Wildlife Service (USFWS) partnered to learn how wetland and flooded agricultural habitats used by waterfowl and shorebirds change during the non-breeding season (July–April) particularly during drought. During extreme drought conditions, the ability to provide sufficient water for wildlife often depends on the timing of water deliveries to managed wetlands and winter-flooded crop fields and decisions on whether to fallow croplands. Waterfowl and shorebirds could be particularly affected by these decisions because they typically rest and feed in flooded habitats. Poor habitat conditions resulting from spatially or temporally suboptimal water deliveries (that is, mismatch between waterfowl habitat needs and timing and location of flooded habitats) could reduce waterfowl hunting opportunities and body condition. Point Blue scientists developed a system for near real-time tracking of habitats used by waterfowl, shorebirds, and some other wetland-dependent “waterbirds” ( www.pointblue.org/watertracker ) and to assess the impacts of drought on habitat availability and on waterfowl and shorebird bioenergetics. The WERC researchers linked these data with near real-time tracking (telemetry) data of duck locations throughout the Valley. The team used these two datasets to relate duck locations to open-water characteristics and to learn how waterfowl use habitats under spatially and temporally changing conditions during drought and non-drought periods. We found that recent extreme drought (2013–15) significantly changed the timing and magnitude of flooding and consequently reduced the availability of habitats used by waterfowl and shorebirds more than other recent historic droughts 2000–11. Drought reduced irrigations of moist soil seed plants and thus there was lower food energy available for waterfowl. Analyses using bioenergetics models indicated that, overall, extreme drought increased food energy deficits (total number of deficit days) for shorebirds and waterfowl. Our analysis indicated a strong direct relationship between duck locations and classified habitat derived from open-water data during the wintering period (October–March). This result helps confirm the application of dynamic water data to identify flooded areas that provide waterfowl habitat. Presence of open water at a 1-hectare resolution can be used effectively to identify flooded landscape areas available as habitat for ducks. Our discoveries from evaluating use of space by ducks also indicated that nighttime feeding locations of ducks were concentrated nearby primary roosts and that foraging distances could depend on hydrologic dynamics of location (Suisun Marsh versus California excluding Suisun Marsh) and time of season (early, middle, late). Other results indicated that some areas on the California landscape with extremely reliable water supplies could receive consistent use by ducks year after year (in essence, almost drought proof). The Water Tracker is set up to automatically track wetland habitat and food availability each year and is making these data available to water and wetland managers. Results from this research are a significant step toward understanding how waterfowl and shorebird habitats can be optimally managed on the landscape to support desired populations of these migratory birds during extreme drought.

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