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Rate of sulfuric acid formation in Yellowstone National Park

Sulfuric acid forms near sulfurous hot springs as the result of oxidation of hydrogen sulfide exhalations by atmospheric oxygen. This strong acid rapidly alters the surrounding rocks and can destroy man-made structures and contaminate streams. Four tracts of acid-altered ground in Yellowstone National Park were studied in order to determine the rate at which sulfuric acid is forming. Although the size of the hot-spring areas varied by as much as a factor of 19, acid production was nearly uniform at about 10 grams per square meter of area per day. The near constancy of acid production per unit area implies that the area of land surface is a major control of the oxidation reaction of sulfide to sulfate. This is consistent with a biological origin for the acid by aerobic sulfur-oxidizing bacteria living close to the land surface. Laboratory rates of acid production for sulfur-oxidizing bacteria are as much as 200 times greater than the rates measured in Yellowstone National Park. A strictly biological origin for the acid is, therefore, quantitatively feasible. The data gathered in this study, however, do not rule out the possibility of the formation of natural sulfuric acid in hot springs by inorganic processes.

Wyoming↗

Surficial Geologic Map of the Clinton-Concord-Grafton-Medfield 12-Quadrangle Area in East Central Massachusetts

The surficial geologic map shows the distribution of nonlithified earth materials at land surface in an area of twelve 7.5-minute quadrangles (total 660 square miles) in east-central Massachusetts. The geologic map differentiates surficial materials of Quaternary age on the basis of their lithologic characteristics (grain size, sedimentary structures, mineral and rock-particle composition), constructional geomorphic features, stratigraphic relationships, and age. Surficial earth materials significantly affect human use of the land, and an accurate description of their distribution is particularly important for water resources, construction aggregate resources, earth-surface hazards assessments, and land-use decisions. This compilation of surficial geologic materials is an interim product that defines the areas of exposed bedrock, and the boundaries between glacial till, glacial stratified deposits, and overlying postglacial deposits. This work is part of a comprehensive study to produce a statewide digital map of the surficial geology at a 1:24,000-scale level of accuracy. This report includes explanatory text (PDF), a regional map at 1:50,000 scale (PDF), quadrangle maps at 1:24,000 scale (12 PDF files), GIS data layers (ArcGIS shapefiles), scanned topographic base maps (TIF), metadata for the GIS layers, and a readme.txt file.

Open-File Report↗

Surficial geologic map of the Salem Depot-Newburyport East-Wilmington-Rockport 16-quadrangle area in northeast Massachusetts

The surficial geologic map shows the distribution of nonlithified earth materials at land surface in an area of 16 7.5-minute quadrangles (total 658 mi2) in northeast Massachusetts. The geologic map differentiates surficial materials of Quaternary age on the basis of their lithologic characteristics (grain size, sedimentary structures, mineral and rock-particle composition), constructional geomorphic features, stratigraphic relationships, and age. Surficial earth materials significantly affect human use of the land, and an accurate description of their distribution is particularly important for water resources, construction aggregate resources, earth-surface hazards assessments, and land-use decisions. This compilation of surficial geologic materials is an interim product that defines the areas of exposed bedrock, and the boundaries between glacial till, glacial stratified deposits, and overlying postglacial deposits. This work is part of a comprehensive study to produce a statewide digital map of the surficial geology at a 1:24,000-scale level of accuracy. This report includes explanatory text (PDF), a regional map at 1:50,000 scale (PDF), quadrangle maps at 1:24,000 scale (PDF files), GIS data layers (ArcGIS shapefiles), metadata for the GIS layers, scanned topographic base maps (TIF), and a readme.txt file.

Massachusetts↗

A summary report of the regional geology, petroleum potential, environmental geology, and operational considerations in the area of proposed lease sale No. 68, offshore southern California

This report reviews geological, geophysical and technological data that are pertinent to proposed OCS Lease Sale 68. Under consideration are 26,000 mi 2 (67,400 km 2 ) of the California Continental Borderland north of the U.S.-Mexico boundary. The area includes both leased and unleased tracts and lies adjacent to the highly productive coastal basins of southern California. Factors that have contributed to petroleum generation in the onshore basins, such as thickness, burial depth and hydrocarbon content, are less favorable in parts of the offshore region. Nevertheless, regional geologic and geophysical mapping together with data from stratigraphic test wells and bottom samples suggest that source beds, reservoir rocks and traps are present beneath the borderland. Strata of Miocene age are widespread within the area of proposed OCS Lease Sale 68 and contain fair to excellent potential source rocks. Eocene and early Miocene sandstone beds in the Cortes Bank test well and late Miocene and Pliocene rocks in the Point Conception test well have porosities that are within the range of good reservoir rocks. Late middle Miocene through Pliocene sandy turbidites of reservoir quality possibly occur in some outer borderland basins. Additional prospective targets are fractured Miocene shale beds that may be present in the deeper basins and on the down-flank margins of major uplifts. Numerous structural and stratigraphic traps, which formed in response to late Cenozoic wrench tectonics, are distributed throughout the borderland.

California↗

Preliminary report on the geology and gold mineralization of the Gold Basin-Lost Basin mining districts, Mohave County, Arizona

The Gold Basin-Lost Basin mining districts are adjacent to each other in northwestern Arizona, south of Lake Mead, and just west of the Grand Wash Cliffs. Most recorded production from lode deposits is credited to mines in the Gold Basin district, which is in the southern White Hills, whereas the bulk of the placer production has been from placers worked along the eastern flank of the Lost Basin range, about 16 km to the northeast across Hualapai Valley. Gold in quartz veins apparently was first discovered in the 1870's. Recorded production from the districts between 1901 and 1942 includes 13,508 oz gold and 6,857 oz silver, and this recorded production has a dollar value of about $359,000 of which 98 percent is credited to gold. Most known occurrences of lode gold in the districts are associated with widespread quartz-cored pegmatite-vein systems, presumably emplaced episodically during Proterozoic X, Proterozoic Y, and Late Cretaceous time into Proterozoic X metamorphic and igneous rocks. The bulk of the veins apparently were emplaced during the Late Cretaceous, and they were localized along both high- and low-angle structures in the Proterozoic X terrane. These veins appear to be associated genetically with presumably Late Cretaceous, two-mica magmatism. A Late Cretaceous two-mica monzogranite crops out in an approximately 4 to 5 km 2 area in the southern part of the Gold Basin district and includes some facies of episyenite. Some gold is found also in small episyenitic alteration pipes, or in veins caught up tectonically along a regionally extensive, low-angle detachment surface which crops out prominently in the southern White Hills, and has been traced for at least 30 km along the western flank of the White Hills. Hydrothermal micas from selected veins in the districts give K-Ar ages of 822, 712, 69, 68, and 65 m.y. (million years), and from the pipes, ages of 130 and 127 m.y. The oldest ages (822 and 712 m.y.) presumably reflect resetting of veins that probably were emplaced penecontemporaneous with emplacement of the 1,400-m.y. granite of Gold Butte, which crops out just to the north of Lake Mead. The latter ages (130 and 127 m.y.) must reflect either the presence of excess radiogenic argon in the hydrothermal environment of the evolving pipes, or contamination of the dated mineral separates by Proterozoic mica and (or) feldspar. Primary white mica from the two-mica monzogranite gives a K-Ar age of 72 m.y.. Most occurrences of gold in the veins and pipes probably reflect either remobilization of gold from gold-bearing, near-surface Proterozoic source areas, or anatectic incorporation of gold into Late Cretaceous, two-mica magmas from very deep gold-bearing Proterozoic sources. Deposition of gold occurred in a mesothermal environment during the galena-, chalcopyrite-, ferroan-carbonate-bearing stages of the veins. Homogenization studies of fluid inclusions prominent in the veins and pipes yield temperatures mostly in the range 150 to 280°C. Early-stage, trapping temperatures at the pipes probably were about 330°C and pressures in the range 500 to 700 bars can be inferred. Fluids were moderately saline, mostly 4 to 16 weight percent NaC1 equivalent, nonboiling, and also contain appreciable amounts of carbon dioxide and, in places, fluorine. Such fluids associated with the deposition of gold in these districts largely bridge the fluid composition interval between many other epithermal precious-metal and porphyry coper deposits. Approximately 350 compositional analyses obtained from native-gold samples from 20 mines in the Gold Basin district and 48 veins in the Lost Basin district show silver contents that range from 6 to approximately 50 weight percent, and copper from 0.01 to 0.5 weight percent. Metal zonation and possible relation to a porphyry copper system at depth can be inferred from some of these chemical data. The differences in the composition of placer gold from 24 occurrences in the Lost Basin district from that of nearby lode sources suggest that other sources contributed gold to the placers or that locally derived grains were enriched by oxidation and weathering of the lodes.

Arizona↗

Ground-water conditions in the Green Bay area, Wisconsin, 1950-60

The Green Bay area, which includes parts of Brown, Outagamie, and Shawano Counties, has an area of about 525 square miles in eastern Wisconsin at the south end of Green Bay. In 1960, it had a population estimated at 124,000; Green Bay, the largest city in the area, had a population of 62,888. The Green Bay area is underlain by a basement complex of crystalline rocks of Precambrian age. Sedimentary rocks of Cambrian, Ordovician, and Silurian ages overlie the crystalline rocks. These rocks are divided, in ascending order, as follows: The Dresbach Group, Franconia Sandstone, and Trempealeau Formation of Cambrian age; the Prairie du Chien Group, St. Peter Sandstone, Platteville Formation, and Maquoketa Shale of Ordovician age; and the Niagara Dolomite of Silurian age. The Maquoketa Shale and Niagara Dolomite are present only in the eastern part of the area. Unconsolidated deposits, largely of Pleistocene age and glacial origin, overlie the older rocks in most of the area. The rocks of the Dresbach Group, Franconia Sandstone, Trempealeau Formation, Prairie du Chien Group, and St. Peter Sandstone are connected hydraulically and can be considered to form one aquifer, called the sandstone aquifer. The sandstone aquifer is the principal source of ground-water supply in the Green Bay area and is one of the most productive water-bearing units in Wisconsin. All the public water supplies in the area, except the supply for the city of Green Bay, and many of the industrial water supplies are obtained from wells tapping the sandstone aquifer. Rates of discharge of individual wells range from about 200 to 1,000 gallous per minute. The city of Green Bay also obtained its water supply from wells tapping the sandstone aquifer until August 1957, when it began using Lake Michigan as a source of water supply. Several industries also use large quantities of surface water. The Niagara Dolomite, although largely undeveloped, is potentially an important aquifer, in the eastern part of the area. Small amounts of water are obtained from dolomite of the Platteville Formation and from sand and gravel deposits of Pleistocene age. Recharge to the sandstone aquifer in the Green Bay area is derived chiefly from precipitation that infiltrates at or near the outcrop area of the aquifer in northwestern Brown County, eastern Outagamie and Shawano Counties, and southern Oconto County. The amount of recharge is estimated to be at least 30 mgd (million gallons per day). Withdrawals of water from wells tapping the sandstone aquifer in the area began when the first well was drilled in 1886. The withdrawals gradually increased to an average of about 6 mgd in 1940, about 10 mgd in 1950, and about 13 mgd in January-July of 1957, after which time the city of Green Bay discontinued pumping from wells. From August 1957 through 1960, average annual withdrawals of water remained relatively constant at about 5 mgd. Water levels in wells tapping the sandstone aquifer persistently declined until August 1957 as a result of the gradually increasing withdrawals of water. In the area of concentrated ground-water withdrawals in downtown Green Bay, the piezometric surface, which had been about 100 feet above land surface in 1886, was about 340 feet below land surface in 1957. The cessation of pumping by the city of Green Bay in August 1957 resulted in a decrease in withdrawals of ground water from about 13.1 mgd in the first half of 1957 to about 5.3 mgd in the last half and a rapid recovery in water levels. ]n the area of concentrated withdrawals, the piezometric surface had recovered about 300 feet by September 1960. Rises in water levels were recorded throughout the Green Bay area, with the amount of the rise depending on the distance from the Green Bay city wells. In September 1960, water levels appeared to be affected more by local variations in the rates of pumping than by the recovery resulting from 1957 reduction in pumping. Much additional ground water could

Wisconsin↗

Lidar-revised geologic map of the Uncas 7.5' quadrangle, Clallam and Jefferson Counties, Washington

In 2000 and 2001, the Puget Sound Lidar Consortium obtained 1 pulse/m 2 lidar data for about 65 percent of the Uncas 7.5' quadrangle. For a brief description of LIDAR (LIght Detection And Ranging) and this data acquisition program, see Haugerud and others (2003). This map combines geologic interpretation (mostly by Haugerud and Tabor) of the 6-ft (2-m) lidar-derived digital elevation model (DEM) with the geology depicted on the Preliminary Geologic Map of the Uncas 7.5' Quadrangle, Clallam and Jefferson Counties, Washington, by Peter J. Haeussler and others (1999). The Uncas quadrangle in the northeastern Olympic Peninsula covers the transition from the accreted terranes of the Olympic Mountains on the west to the Tertiary and Quaternary basin fills of the Puget Lowland to the east. Elevations in the map area range from sea level at Port Discovery to 4,116 ft (1,255 m) on the flank of the Olympic Mountains to the southwest. Previous geologic mapping within and marginal to the Uncas quadrangle includes reports by Cady and others (1972), Brown and others (1960), Tabor and Cady (1978a), Yount and Gower (1991), and Yount and others (1993). Paleontologic and stratigraphic investigations by University of Washington graduate students (Allison, 1959; Thoms, 1959; Sherman, 1960; Hamlin, 1962; Spencer, 1984) also encompass parts of the Uncas quadrangle. Haeussler and Wells mapped in February 1998, following preliminary mapping by Yount and Gower in 1976 and 1979. The description of surficial map units follows Yount and others (1993) and Booth and Waldron (2004). Bedrock map units are modified from Yount and Gower (1991) and Spencer (1984). We used the geologic time scale of Gradstein and others (2005). The Uncas quadrangle lies in the forearc of the Cascadia subduction zone, about 6.25 mi (10 km) east of the Cascadia accretionary complex exposed in the core of the Olympic Mountains (Tabor and Cady, 1978b). Underthrusting of the accretionary complex beneath the forearc uplifted and tilted eastward the Coast Range basalt basement and overlying marginal basin strata, which comprise most of the rocks of the Uncas quadrangle. The Eocene submarine and subaerial tholeiitic basalt of the Crescent Formation on the Olympic Peninsula is thought to be the exposed mafic basement of the Coast Range, which was considered by Snavely and others (1968) to be an oceanic terrane accreted to the margin in Eocene time. In this interpretation, the Coast Range basalt terrane may have originated as an oceanic plateau or by oblique marginal rifting, but its subsequent emplacement history was complex (Wells and others, 1984). Babcock and others (1992) and Haeussler and others (2003) favor the interpretation that the basalts were the product of an oceanic spreading center interacting with the continental margin. Regardless of their origin, onlapping strata in southern Oregon indicate that the Coast Range basalts were attached to North America by 50 Ma; but on southern Vancouver Island, where the terrane-bounding Leech River Fault is exposed, Brandon and Vance (1992) concluded that suturing to North America occurred in the broad interval between 42 and 24 Ma. After emplacement of the Coast Range basalt terrane, the Cascadia accretionary wedge developed by frontal accretion and underplating (Tabor and Cady, 1978b; Clowes and others, 1987). Domal uplift of the part of the accretionary complex beneath the Olympic Mountains occurred after ~18 Ma (Brandon and others, 1998). Continental and alpine glaciation during Quaternary time reshaped the uplifted rocks of the Olympic Mountains.

Washington↗

Total petroleum system assessment of undiscovered resources in the giant Barnett Shale continuous (unconventional) gas accumulation, Fort Worth Basin, Texas

Undiscovered natural gas having potential for additions to reserves in the Mississippian Barnett Shale of the Fort Worth Basin, north-central Texas, was assessed using the total petroleum system assessment unit concept and a cell-based methodology for continuous-type (Unconventional) resources. The Barnett-Paleozoic total petroleum system is defined in the Bend arch-Fort Worth Basin as encompassing the area in which the organic-rich Barnett is the primary source rock for oil and gas produced from Paleozoic carbonate and clastic reservoirs. Exploration, technology, and drilling in the Barnett Shale play have rapidly evolved in recent years, with about 3500 vertical and 1000 horizontal wells completed in the Barnett through 2005 and more than 85% of the them completed since 1999. Using framework geology and historical production data, assessment of the Barnett Shale was performed by the U.S. Geological Survey using vertical wells at the peak of vertical well completions and before a transition to completions with horizontal wells. The assessment was performed after (1) mapping critical geological and geochemical parameters to define assessment unit areas with future potential, (2) defining distributions of drainage area (cell size) and estimating ultimate recovery per cell, and (3) estimating future success rates. Two assessment units are defined and assessed for the Barnett Shale continuous gas accumulation, resulting in a total mean undiscovered volume having potential for additions to reserves of 26.2 TCFG. The greater Newark East fracture-barrier continuous Barnett Shale gas assessment unit represents a core-producing area where thick, organic-rich, siliceous Barnett Shale is within the thermal window for gas generation (Ro ??? 1.1%) and is overlain and underlain by impermeable limestone barriers (Pennsylvanian Marble Falls Limestone and Ordovician Viola Limestone, respectively) that serve to confine induced fractures during well completion to maximize gas recovery. The extended continuous Barnett Shale gas assessment unit, which had been less explored, defines a geographic area where Barnett Shale is (1) within the thermal window for gas generation, (2) greater than 100 ft (30 m) thick, and (3) where at least one impermeable limestone barrier is absent. Mean undiscovered gas having potential for additions to reserves in the greater Newark East assessment unit is estimated at 14.6 tcf, and in the less tested extended assessment unit, a mean resource is estimated at 11.6 TCFG. A third hypothetical basin-arch Barnett Shale oil assessment unit was defined but not assessed because of a lack of production data. Copyright ?? 2007. The American Association of Petroleum Geologists. All rights reserved.

American Association of Petroleum Geologists Bulle↗

Mapping Evapotranspiration Units in the Basin and Range Carbonate-Rock Aquifer System, White Pine County, Nevada, and Adjacent Areas in Nevada and Utah

Accurate estimates of ground-water discharge are crucial in the development of a water budget for the Basin and Range carbonate-rock aquifer system study area. One common method used throughout the southwestern United States is to estimate ground-water discharge from evapotranspiration (ET). ET is a process by which water from the Earth's surface is transferred to the atmosphere. The volume of water lost to the atmosphere by ET can be computed as the product of the ET rate and the acreage of vegetation, open water, and moist soil through which ET occurs. The procedure used in the study groups areas of similar vegetation, water, and soil conditions into different ET units, assigns an average annual ET rate to each unit, and computes annual ET from each ET unit within the outer extent of potential areas of ground-water discharge. Data sets and the procedures used to delineate the ET-unit map used to estimate ground-water discharge from the study area and a qualitative assessment of the accuracy of the map are described in this report.

Scientific Investigations Report↗

Regolith in the Piedmont Upland Section, Piedmont Province, York, Lancaster, and Chester Counties, southeastern Pennsylvania

Regolith has been mapped in the Piedmont Upland Section of the Piedmont Province in York, Lancaster, and Chester Counties, southeastern Pennsylvania. The Piedmont Upland Section is an area of rounded hills and flat-floored valleys developed by weathering and erosion of schist, gneiss, metaquartzite, and other metamorphic rocks. In situ regolith includes weathered rock and saprolite. Transported regolith includes alluvium, colluvium, fluvial terrace deposits, and anthropogenic deposits. Weathered rock occurs almost everywhere except where erosion has exposed unweathered bedrock in valley bottoms. Thin colluvium occurs discontinuously on hill tops and side slopes while thicker colluvium occurs in heads of first-order drainage basins and in small valleys lacking perennial streams. Alluvium is present in all valleys with perennial streams. This regolith is the product of early to middle Cenozoic weathering, middle to late Cenozoic erosion, Pleistocene periglacial erosion and deposition, and recent anthropogenic activity.

Southeastern Geology↗

Mineralogical, magnetic and geochemical data constrain the pathways and extent of weathering of mineralized sedimentary rocks

The oxidative weathering of sulfidic rock can profoundly impact watersheds through the resulting export of acidity and metals. Weathering leaves a record of mineral transformation, particularly involving minor redox-sensitive phases, that can inform the development of conceptual and quantitative models. In sulfidic sedimentary rocks, however, variations in depositional history, diagenesis and mineralization can change or overprint the distributions of these trace minerals, complicating the interpretation of weathering signatures. Here we show that a combination of bulk mineralogical and geochemical techniques, micrometer-resolution X-ray fluorescence microprobe analysis and rock magnetic measurements, applied to drill core samples and single weathered fractures, can provide data that enable the development of a geochemically consistent weathering model. This work focused on one watershed in the Upper Colorado River Basin sitting within the Mesaverde Formation, a sedimentary sandstone bedrock with disseminated sulfide minerals, including pyrite and sphalerite, that were introduced during diagenesis and subsequent magmatic-hydrothermal mineralization. Combined analytical methods revealed the pathways of iron (Fe), carbonate and silicate mineral weathering and showed how pH controls element retention or release from the actively weathering fractured sandstone. Drill core logging, whole rock X-ray diffraction, and geochemical measurements document the progression from unweathered rock at depth to weathered rock at the surface. X-ray microprobe analyses of a 1-cm size weathering profile along a fracture surface are consistent with the mobilization of Fe(II) and Fe(III) into acidic pore water from the dissolution of primary pyrite, Fe-sphalerite, chlorite, and minor siderite and pyrrhotite. These reactions are followed by the precipitation of secondary minerals such as of goethite and jarosite, a Fe-(oxyhydr)oxide and hydrous Fe(III) sulfate, respectively. Microscale analyses also helped explain the weathering reactions responsible for the mineralogical transformations observed in the top and most weathered section of the drill core. For example, dissolution of feldspar and chlorite neutralizes the acidity generated by Fe and sulfide mineral oxidation, oversaturating the solution in both Fe-oxides. The combination of X-ray spectromicroscopy and magnetic measurements show that the Fe(III) product is goethite, mainly present either as a coatings on fracture surfaces in the actively weathering region of the core or more homogeneously contained within the unconsolidated regolith at the top of the core. Low-temperature magnetic data reveal the presence of ferromagnetic Fe-sulfide pyrrhotite that, although it occurs at trace concentrations, could provide a qualitative proxy for unweathered sulfide minerals because the loss of pyrrhotite is associated with the onset of oxidative weathering. Pyrrhotite loss and goethite formation are detectable through room-temperature magnetic coercivity changes, suggesting that rock magnetic measurements can determine weathering intensity in rock samples at many scales. This work contributes evidence that the weathering of sulfidic sedimentary rocks follows a geochemical pattern in which the abundance of sulfide minerals controls the generation of acidity and dissolved elements, and the pH-dependent mobility of these elements controls their export to the ground- and surface-water.

Colorado↗

Ground water in the Corvallis-Albany area, central Willamette Valley, Oregon

The Corvallis-Albany area is part of the alluvial plain that lies between the Cascade and Coast Ranges in the central Willamette Valley in northwestern Oregon. As used in this report, the Corvallis-Albany area consists of approximately 210 square miles and includes a part of the lower foothills of the Coast and Cascade Ranges. Volcanic and marine sedimentary units exposed in the foothills range in age from Eocene to Oligocene or Miocene. The volcanic rocks are primarily pillow lavas and basalt flows, which yield only small quantities of water generally adequate for domestic and stock use. Marine-deposited sandstone, siltstone, and shale of the older sedimentary units are fine grained, poorly permeable, and generally yield small volumes of water to wells. In the valley plain the older units are overlain by Pleistocene and Holocene alluvial deposits. The alluvial deposits (sand and gravel) of the valley plain contain the most productive aquifers in the area and are considered to be the only units feasible for large-scale development of ground-water supplies. Aquifers in the area are recharged principally by direct infiltration of precipitation. Most of the precipitation (about 38 in. per yr avg) occurs during late autumn and winter. Ground water is discharged naturally from the area by seepage and spring flow to streams, by evapotranspiration, by underflow, and artificially through wells. During 1971 the seasonal decline of water levels from winter to late summer averaged about 10 feet for the alluvial deposits. The seasonal change of storage in that year was estimated to be about 130,000 acre-feet. Of this volume, about 14,000 acre-feet was pumped from wells; the rest (about 116,000 acre-feet) was discharged through seeps and springs by evapotranspiration. The difference between pumpage and natural discharge indicates that a great quantity of additional water is available for development. The storage capacity of the alluvial aquifers in the area is estimated to be about 750,000 acre-feet between depths of 10 and 100 feet. Ground water from the alluvial deposits is chemically suitable for all uses, as is most of the water from perched-water bodies in the older sedimentary and volcanic rocks. However, the mineral content of water from the older sedimentary rocks, particularly from deeper producing zones in the valley plain, is greater than that from the alluvial deposits. Locally, some of the water from the older rocks is too saline for general use. Analysis of water samples for coliform bacteria indicates that ground-water pollution exists in parts of the Corvallis-Albany area. Further study is necessary to document fully the nature and extent of pollution.

Oregon↗

Occurrences of alunite, pyrophyllite, and clays in the Cerro La Tiza area, Puerto Rico

A deposit of hydrothermally altered rocks in the Cerro La Tiza area located between the towns of Comerio and Aguas Buenas, approximately 25 kilometers southwest of San Juan, Puerto Rico, was mapped and studied to determine the principal minerals, their extent distribution and origin, and the possibility of their economic utilization, especially in Puerto Rico. The Cerro la Tiza area is about 7 1 / 2 kilometers long, has an average width of about 1 1 / 2 kilometers and embraces a total area of approximately 15 square kilometers. The principal mineralized zone, a dike-like mass of light-colored rocks surrounded by dark-colored volcanic country rocks, occupies the crest and upper slopes of east-trending Cerro La Tiza ridge and is believed to be of Late Cretaceous or Eocene age. This zone is approximately 5,300 meters long, 430 meters wide and has an area of approximately 225 hectares (556 acres). The rocks of the mineralized zone are of mixed character and consist mainly of massive quartzose rocks and banded quartz-alunite rocks closely associated with foliated pyrophyllitic, sericitic and clayey rocks. The principal minerals in probably order of abundance are quartz, alunite, pyrophyllite, kaolin group clays (kaolinite and halloysite) and sericite. Minerals of minor abundance are native sulfure, diaspore, svanbergite (?), sunyite (?), hematite, goethite, pyrite, rutile (?) and very small quantities of unidentified minerals. The mineralized zone has broken down to deposits of earth-rock debris of Quaternary age that cover much of the slopes and flanks of Cerro La Tiza. This debris consists generally of fragments and boulders with a very large size range embedded in a clayey matrix. The distribution of the earth-rock debris with respect to the present topography and drainage suggests that it may have undergone at least two cycles of erosion. Underlying the earth-rock debris and completely enclosing the mineralized zone are country rocks of probably Late Cretaceous age. These consist principally of low flows and volcanic and flow breccias but contain thin interbedded siltstones and sandstones. The lavas are generally predominant at the western end of the area and the breccias at the eastern end. The mineralized zone and the country rocks are sheared along two predominant directions that are approximately N 70 degrees E and N 70 degrees W. The ridge of Cerro La Tiza appears to be a broad shear zone through which hydrothermal emanations gained access to the country rocks. The emanations are believed to have originated from intrusive rocks that probably underlie the area. The surrounding area contains both large and small exposed intrusive bodies. The largest one is the San Lorenzo batholith of Late Cretaceous or Eocene age whose exposed northwest edge is approximately 19 kilometers southeast of the eastern end of the Cerro La Tiza area. Other zones of hydrothermally altered rocks were discovered along a mineralized belt extending eastward from Cerro La Tiza through the Rio Gurabo Valley nearly to the Vieques Passage bordering the east coast of Puerto Rico. Other zones were discovered north and south of this belt and still others were found circumventing the San Lorenzo batholith. The most abundant minerals of the mineralized zone can be exploited for economic utilization in Puerto Rico. Alunite can be utilized in the manufacture of aluminum sulfate for water purification. It can also be used in the manufacture of alumina refractory materials. Pyrophyllite can be used as a carrier for insecticides and fungicides. It can also be utilized for the manufacture of ceramic products, as a filler in the soap industry and as a carrier for paint pigments. Kaolinite can be used in the ceramic industry and in the manufacture of glass as a substitute for feldspar. Halloysite might be utilized as a catalyst support in the cracking of petroleum. Tonnages of reserve ore on Cerro La Tiza are calculated to be 1,590,000 inferred short tons (1,440,000,000 inferred metric tons) of mixed minerals. These tonnages are based on the assumption that the depth of the mineralized zone is one-half of the exposed width. The deposit is well situated for open pit mining, but because of the existing cover of earth-rock debris, soil foliage, exploration should proceed exploitation for better determination of the most promising areas containing the best concentrations of the minerals sought.

Cerro La Tiza↗

Coal in sub-Saharan-African countries undergoing desertification

Coal has been reported in 11 of the 16 sub-Saharan countries discussed in this appraisal: Mauritania, Senegal, Mali, Niger, Benin, Nigeria, Cameroon, Central African Republic, Sudan, Ethiopia, and Somalia. No coal occurrences have been reported in Gambia, Togo, Burkina, Chad, and Djibouti but coal may be present within these countries because neighboring countries do contain coal-bearing rocks. Most of these countries are undergoing desertification or will in the near future. Wood, directly or in the form of charcoal, constitutes two-thirds of the fuel used in Africa. Destruction of forest and shrub lands for fuel is occurring at an increasing rate because of desertification and increasing energy demands. The decline in biological productivity, coupled with concentration of population in areas where water is available and crops may be grown, leads to increasing shortages of wood for fuel. Part of the present and future energy needs of the sub-Saharan region could be met by use of indigenous coal and peat. Nine sedimentary basins, completely or partially within the sub-Saharan region, have the potential of either coal and/or peat deposits of economic value: 1- Senegal Basin, 2- Taoudeni Basin and Gao Trough, 3- Niger Basin, 4- Chad Basin, 5- Chari Basin, 6- Benue Trough (Depression), 7- Sudan Trough, 8- Plateau and Rift Belt, and 9- Somali Basin. Niger and Nigeria are the only countries in sub-Saharan Africa in which coal is presently being mined as a fuel source for powerplants and domestic use. Peat occurs in the deltas, lower river, and interdunal basin areas of Senegal, Mauritania, and Sudan. Peat can be used as an alternate fuel source and is currently being tested as a soil amendment in the agricultural sector.

Journal of African Earth Sciences↗

Eolian sediments

The origin and nature of eolian (wind-blown) sediments are reviewed, with an emphasis on the occurrence of these features in the Quaternary. Eolian sediments consist of windblown sand, loess, and long-range-transported (LRT) dust, in order of decreasing particle size. Eolian sand forms some of the most dramatic landscapes in the world, particularly when these sediments are deposited as dunes in sand seas. The largest eolian sand seas are found in subtropical deserts and in mid-latitude basins that are arid because of rainshadow effects. Dunes can be helpful in interpreting past climates, both for understanding past moisture balance and paleowinds (past wind directions). Loess is windblown silt that can be recognized in the field and mapped as a geologic body. It can be many tens of meters thick, but usually decreases systematically with distance from its source or sources. Much loess is glaciogenic, the result of glacial grinding of bedrock into “rock flour” that is easily entrained by the wind, but some loess owes its origins to nonglacial processes or is simply inherited from silt-rich rocks. The geologic record shows that both glacial loess and non-glacial loess accumulated mostly during glacial periods, suggesting that particular environmental conditions are favorable for loess accumulation. These conditions include increased source sediments, a dry, windy environment with minimal vegetation cover, and a decreased intensity of the hydrological cycle. The same conditions apparently enhance the production of LRT dust, which consists of particles generally less than 10 μm. At present, most dust sources are in the same regions where the largest eolian sand seas occur, although sandy sediments are not the only sources of finer-grained dust. LRT dust can be transported across oceans, from continent to continent, and may play important roles in the overall planetary radiation balance, as fertilizer to the world's primary producers in the oceans, and as a soil parent material. Geologic records of LRT dust transport can be found in deep-sea sediments, ice caps, lakes, distal loess deposits, and soils. These records indicate that, like loess, the flux of dust was greater during glacial periods. Although eolian sand, loess, and LRT dust all have rich geologic records in the Quaternary, there is an increasing recognition of the importance of all these features in the longer, pre-Quaternary geologic record.

Book chapter↗

Petroleum system analysis of the Hunton Group in West Edmond field, Oklahoma

West Edmond field, located in central Oklahoma, is one of the largest oil accumulations in the Silurian–Devonian Hunton Group in this part of the Anadarko Basin. Production from all stratigraphic units in the field exceeds 170 million barrels of oil (MMBO) and 400 billion cubic feet of gas (BCFG), of which approximately 60 MMBO and 100 BCFG have been produced from the Hunton Group. Oil and gas are stratigraphically trapped to the east against the Nemaha uplift, to the north by a regional wedge-out of Hunton strata, and by intraformational diagenetic traps. Hunton Group reservoirs are the Bois d'Arc and Frisco Limestones, with lesser production from the Chimneyhill subgroup, Haragan Shale, and Henryhouse Formation. Hunton Group cores from three wells that were examined petrographically indicate that complex diagenetic relations influence permeability and reservoir quality. Greatest porosity and permeability are associated with secondary dissolution in packstones and grainstones, forming hydrocarbon reservoirs. The overlying Devonian–Mississippian Woodford Shale is the major petroleum source rock for the Hunton Group in the field, based on one-dimensional and four-dimensional petroleum system models that were calibrated to well temperature and Woodford Shale vitrinite reflectance data. The source rock is marginally mature to mature for oil generation in the area of the West Edmond field, and migration of Woodford oil and gas from deeper parts of the basin also contributed to hydrocarbon accumulation.

Oklahoma↗

Minerals of the cassiterite-bearing veins at Irish Creek, Virginia, and their paragenetic relations

Major rock types of the Irish Creek district are gneisses and schists, intruded by granodiorite. All these rocks are believed to be Precambrian. The ore deposits are fissure veins consisting largely of quartz veins bordered by greisen, and enriched by recurrent deposition. From field and microscopic evidence six stages of mineral formation have been deduced: 1. Crystallization of the granodiorite with the formation of hypersthene, augite, hornblende, andesine, orthoclase, microcline, and quartz; and accessory apatite, rutile, ilmenite, titanomagnetite, and zircon. 2. Metamorphism of the granodiorite and gneiss with formation of uralitic actinolite, epidote, and sphene. 3. A period of fracturing and formation of quartz veins. 4. Greisenization of the host rock producing first: coarse muscovite, brown biotite, cassiterite, beryl, wolframite, and quartz; then producing a second group of minerals-fluorite, green biotite, chlorite, phenakite, siderite, ankerite, parisite, sphalerite, sulfides, including aikinite and galeno-bismutite, leucoxene, fine muscovite, and quartz. 5. Formation of late vein minerals, clinozoisite, calcite, nontronite, and montmorillonite. 6. Formation of surficial alteration products, kaolinite, vermiculite, hematite, limonite, and scorodite. The italicized mineral names indicate the minerals heretofore unreported from Irish Creek; parisite, aikinite, and galenobismutite are new minerals for Virginia. Included in the detailed descriptions of all the minerals is a chemical analysis of beryl.

Virginia↗

Geologic Map of the Edwards Aquifer In Northern Medina and Northeastern Uvalde Counties, South-central Texas

The southern segment of the Edwards aquifer in south-central Texas is one of the most productive subsurface reservoirs of potable water in the world, providing water of excellent quality to more than a million people in the San Antonio region, where the Environmental Protection Agency (EPA) has declared it to be a sole-source aquifer (van der Leeden and others, 1990). Depending on the depositional province within which the associated carbonate rocks originated (Maclay and Small, 1984), the Edwards aquifer is composed of several geologic formations (primarily limestone and dolostone) of Early Cretaceous age. Most water pumped from the Edwards aquifer comes form the Person and Kainer Formations, which were deposited over the San Marcos Platform. The principal source of ground water in study area is the Devils River Formation, which was deposited in the Devils River trend. The Devils River Formation provides large quantities of irrigation water to fertile bottomland areas of Medina and Uvalde Counties, where the success of farming and ranching activities has long depended upon water from the Edwards aquifer. The study area includes all of the Edwards aquifer recharge zone between the Sabinal River (on the west) and the Medina River (on the east) plus an updip fringe of the confined zone in east-central Uvalde and central Medina Counties. Over about ninety percent of the study area--within the Devils River trend--the Edwards aquifer is composed of the Georgetown Formation plus the underlying Devils River Formation. Over the remaining area--over the southwestern margin of the San Marcos platform--the Edwards aquifer consists of the Georgetown Formation plus the underlying Edwards Group (Rose, 1972), which comprises the Kainer and Person Formations.

Open-File Report↗