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USGS1977

Workshop on automatic and interactive processing of seismic network data

On October 5 and 6, 1976, a small workshop was held at the U.S. Geological Survey in Menlo Park, California, to discuss recent advances and future goals in automatic and interactive processing of network data used in earthquake prediction research. The group consisted of 35 engineers, computer programmers, and seismologists from universities, industry, and government research laboratories across the country. There was intensive discussion. A number of important conclusions were reached that will be listed after a brief review of the information presented.

Open-File Report↗

USGS1979

Selected bibliography on subsidence processes and related engineering problems in carbonate rocks

The Solution Subsidence and Collapse project is a U.S. Geological Survey research activity funded by the Reactor Hazards Research program. The objective of the study is to determine the geologic and hydrologic controls and mechanisms of ground subsidence in soluble rock terranes caused by natural processes and man's activities. The results of the research will be used for the general geologic characterization of proposed and existing nuclear reactor sites in regions underlain by soluble rocks. In addition, the knowledge gained from the study will be applied to defining potential geologic hazards in soluble rock areas where ground subsidence or collapse can occur. The Solution Subsidence and Collapse project is divided into two study units, one looking at subsidence in evaporitic terranes, the other in carbonate terranes. Each of the two geologic environments has its own unique set of conditions that lead to subsidence and, therefore, each warrants its own special study. As part of the subsidence study a selected bibliography covering various topics on ground subsidence in carbonate karst terranes was compiled and is presented here. The entries in the bibliography are placed in five categories: (1) General; (2) Geology, Geomorphology, Hydrology; (3) Caves, Solution Channels; (4) Subsidence, Sinkholes; and (5) Engineering, Land Use, Detection. A separate bibliography on ground subsidence caused by dissolution and removal of salt and other soluble evaporites has been published as a companion reference to this report (Ege, 1979).

Open-File Report↗

USGS1985

Data processing programs for aerial gamma-ray data

The U.S. Geological Survey (USGS) uses computer programs to process aerial gamma-ray data; some do editing and data manipulation to allow for corrections. Programs to convert flight-line data to latitude-longitude coordinates are included. Plotting programs include contour plotting, profile plots, and photographic raster plots.

Open-File Report↗

USGS1993

Quality assurance plan for the collection and processing of sediment data by the U.S. Geological Survey, Water Resources Division

The U.S. Geological Survey sediment data quality assurance plan identifies and explains required quality assurance and suggested quality control practices. The approach is to subdivide the process for obtaining sediment data into 3 parts: (1) field, (2) office, and (3) laboratory operations. The report also summarizes recommended goals for each subcategory. The quality assurance and quality control practices are described by stating the minimum acceptable activities that a district should conduct. For example, the plan describes field calibration of thermometers and standards used to calibrate a thermometer. The plan also proposes corrective actions if the quality control procedures identify a problem. The plan describes the formal reports prepared by a district that describe the completeness of sediment data and presents an evaluation of data obtained by the quality assurance program. Also described in the plan are the external (non-district) reviews that are needed to examine district sediment operations for conformity with district quality assurance plans and national quality assurance programs.

Open-File Report↗

USGS1995

Geographic information system programs for use in the water-supply-allocation permitting process

Computer programs designed for use in a geographic information system as an aid in the water-supply- allocation permitting process are described. These programs were developed by the U.S. Geological Survey during a project conducted in cooperation with the New Jersey Department of Environmental Protection. The programs enable a user to display proposed water-supply-allocation sites in a defined area together with present sites and important hydrologic and geographic features on a computer screen or on hardcopy plots. The programs are menu-driven and do not require familiarity with geographic information systems. Source codes for the programs are included in appendixes.

Open-File Report↗

USGS1995

Arctic delta processes: A computer animation and paper models

This report shows, by means of a computer animation and paper models, how deltas are affected by fresh and salt water currents, topography and location. The report is intended to help students and others visualize how ice shapes and forms a delta. By studying the animations and the paper models, students will come to understand why deltas have different shapes and different interior structures. The diskette version has an animation of arctic delta processes. While both the diskette and paper versions have teacher guide and paper models.

Open-File Report↗

USGS1999

Seismic-reflection surveys of the Blake Ridge, R/V Cape Hatteras 1992 and 1995: Data acquisition, navigation, and processing

As part of an ongoing study, seismic-reflection profiles were collected over the Blake Ridge in 1992 and 1995, in order to map the volume and distribution of methane hydrate. Faulting and seafloor instabilities appear to be related to methane hydrate processes at the Blake Ridge. Seismic profiles display a prominent collapse structure at the crest, which is inferred to have resulted from the mobilization of sediment that was associated with methane hydrate dissociation.

Open-File Report↗

USGS2004

Debris flows: geologic process and hazard; illustrated by a surge sequence at Jiangjia Ravine, Yunnan, China

Debris flows are slurries of sediment and water that are both an important geologic process and a major hazard. They present large risks to those living in mountainous areas, as well as downstream from volcanoes in the case of the flows known as lahars that may travel 100200 kilometers (62-124 miles). The accompanying video records a series of debris flow surges at Jiangjia Ravine, in Yunnan Province in southern China. This rugged and remote site is famous for the annual occurrence of debris flows triggered each summer by monsoonal rains. The video illustrates the unique characteristics of debris flows, how they behave, and why they cause large losses of life and property in China and many other parts of the world. This report is a summary for those wishing more information than is presented in the video, and for the specialist we include dynamical data on the flows and textural data on their deposits.

Yunnan↗

USGS2005

Channel and hillslope processes revisited in the Arroyo de los Frijoles watershed near Santa Fe, New Mexico

Detailed documentation of geomorphic changes in the landscape of more than a few years is rarely possible. Channel cross sections, channel profiles, sediment deposition behind dams, and hillslope-erosion plots, originally benchmarked within several watersheds outside Santa Fe, New Mexico, in the 1950’s and 1960’s, for a 1966 report that documented processes and rates of arid-region sediment production and deposition, were resurveyed in the mid-1990’s. Many of the original study sites were relocated and surveyed in the mid-1990’s to determine subsequent channel and hillslope changes and to determine whether trends of channel and hillslope aggradation and degradation that were evident in the 1950’s and 1960’s have continued. In general, the net change in channel geometry has been small over the last 30–40 years. The average change in cross-sectional area of 32 resurveyed cross sections was erosion of 0.27 square meter, which equates to a 4-percent increase in cross-sectional area. The average net change in thalweg elevation for 51 resurveyed cross sections was degradation of 0.04 meter. Unpublished data (1964–68) from the scour chains showed that 371 chains had an average scour of 0.14 ± 0.14 meter and that 372 chains showed an average fill of 0.13 + 0.11 meter. Scour, found in the original study (1958–64) to be proportional to the square root of discharge, was confirmed with the addition of unpublished data (1964–68). The observed channel changes have no consistent trend, compared either to results observed in the original 1966 study or to distance from the watershed divide. The conclusion drawn in the original study was that most channels were aggrading; the resurvey showed that aggradation did not continue. An increase in housing and population in the Arroyo de los Frijoles watershed since the 1950’s has led to more roads. Channel degradation is most noticeable at road crossings. The greatest degradation of the main channel Arroyo de los Frijoles, 1.53 meters, and the greatest aggradation, 0.38 meter, occur downstream and upstream, respectively, from a culvert in a dirt road. Periods of high average annual rainfall intensity reported for Santa Fe for 1853–80 immediately preceded late 19th century arroyo incision, and another period of high-intensity rainfall began in 1967. This may indicate that climatic factors are again favorable for arroyo incision in this part of New Mexico; data from this resurvey, however, do not provide evidence of a renewed cycle of erosion. At a 1930’s Civilian Conservation Corps-constructed dam on Coyote C. Arroyo, the measured sediment yield from 1966 to 1993 was 139 metric tonnes per square kilometer per year. Sediment yields have decreased through time because of either a decrease in the trap efficiency of the reservoir over time or a decrease in sediment delivery to the reservoir because of upstream channel storage. The effects of base-level rise on the channel profile were documented in 1993 through resurveys of sediment deposits behind two small dams, Big Sweat Dam and Little Sweat Dam. Both dams, built in 1960, showed sediment deposition that extends 20 and 9.3 meters upstream, respectively, and the 1993 sediment gradient was nearly the same as the unaffected channel upstream. Big Sweat Dam showed fluctuations in channel gradient within 5.3 meters of the dam, which may be a result of local scour following complete filling of the dam, scour from increased sinuosity, or differences in the location of surveying stations over time. The sinuosity of the channel has increased over time, presumably from a reduction in slope. Channel gradients 0 to 11.0 meters upstream from Little Sweat Dam have remained constant at about 0.028 from 1964 to 1993. Measurement of erosion or hillslope-erosion plots show that average values of surface erosion range from 0.019 to 0.096 centimeters per year and are within values reported for regional erosion and denudation studies. Sediment yield from the Slopewash Tributary erosion plot was 307 metric tonnes per square kilometer per year. The reproducibility and accuracy of the resurveys from the 1950’s to the 1990’s attest to the concepts used to quantify geomorphic features established in the Vigil Network. With relatively simple techniques, more than 30 years of geomorphic change were observed in this study.

New Mexico↗

USGS2007

The question of recharge to the deep thermal reservoir underlying the geysers and hot springs of Yellowstone National Park: Chapter H in Integrated geoscience studies in Integrated geoscience studies in the Greater Yellowstone Area—Volcanic, tectonic, and hydrothermal processes in the Yellowstone geoecosystem

The extraordinary number, size, and unspoiled beauty of the geysers and hot springs of Yellowstone National Park (the Park) make them a national treasure. The hydrology of these special features and their relation to cold waters of the Yellowstone area are poorly known. In the absence of deep drill holes, such information is available only indirectly from isotope studies. The δD-δ18O values of precipitation and cold surface-water and ground-water samples are close to the global meteoric water line (Craig, 1961). δD values of monthly samples of rain and snow collected from 1978 to 1981 at two stations in the Park show strong seasonal variations, with average values for winter months close to those for cold waters near the collection sites. δD values of more than 300 samples from cold springs, cold streams, and rivers collected during the fall from 1967 to 1992 show consistent north-south and east-west patterns throughout and outside of the Park, although values at a given site vary by as much as 8 &permil; from year to year. These data, along with hot-spring data (Truesdell and others, 1977; Pearson and Truesdell, 1978), show that ascending Yellowstone thermal waters are modified isotopically and chemically by a variety of boiling and mixing processes in shallow reservoirs. Near geyser basins, shallow recharge waters from nearby rhyolite plateaus dilute the ascending deep thermal waters, particularly at basin margins, and mix and boil in reservoirs that commonly are interconnected. Deep recharge appears to derive from a major deep thermal-reservoir fluid that supplies steam and hot water to all geyser basins on the west side of the Park and perhaps in the entire Yellowstone caldera. This water (T ≥350°C; δD = –149±1 &permil;) is isotopically lighter than all but the farthest north, highest altitude cold springs and streams and a sinter-producing warm spring (δD = –153 &permil;) north of the Park. Derivation of this deep fluid solely from present-day recharge is problematical. The designation of source areas depends on assumptions about the age of the deep water, which in turn depend on assumptions about the nature of the deep thermal system. Modeling, based on published chloride-flux studies of thermal waters, suggests that for a 0.5- to 4-km-deep reservoir the residence time of most of the thermal water could be less than 1,900 years, for a piston-flow model, to more than 10,000 years, for a well-mixed model. For the piston-flow model, the deep system quickly reaches the isotopic composition of the recharge in response to climate change. For this model, stable-isotope data and geologic considerations suggest that the most likely area of recharge for the deep thermal water is in the northwestern part of the Park, in the Gallatin Range, where major north-south faults connect with the caldera. This possible recharge area for the deep thermal water is at least 20 km, and possibly as much as 70 km, from outflow in the thermal areas, indicating the presence of a hydrothermal system as large as those postulated to have operated around large, ancient igneous intrusions. For this model, the volume of isotopically light water infiltrating in the Gallatin Range during our sampling period is too small to balance the present outflow of deep water. This shortfall suggests that some recharge possibly occurred during a cooler time characterized by greater winter precipitation, such as during the Little Ice Age in the 15th century. However, this scenario requires exceptionally fast flow rates of recharge into the deep system. For the well-mixed model, the composition of the deep reservoir changes slowly in response to climate change, and a significant component of the deep thermal water could have recharged during Pleistocene glaciation. The latter interpretation is consistent with the recent discovery of warm waters in wells and springs in southern Idaho that have δD values 10–20 &permil; lower than the winter snow for their present-day high-level recharge. These waters have been interpreted to be Pleistocene in age (Smith and others, 2002). The well-mixed model permits a significant component of recharge water for the deep system to have δD values less negative than –150 &permil; and consequently for the deep system recharge to be closer to the caldera at a number of possible localities in the Park.

Idaho, Montana, Wyoming↗

USGS2012

Water quality and landscape processes of four watersheds in eastern Puerto Rico

Humid tropical regions occupy about a quarter of Earth's land surface, yet they contribute a substantially higher fraction of the water, solutes, and sediment discharged to the world's oceans. Nearly half of Earth's population lives in the tropics, and development stresses can potentially harm soil resources, water quality, and water supply and in addition increase landslide and flood hazards. Owing to Puerto Rico's steep topography, low water storage capacity, and dependence on trade-wind precipitation, the island's people, ecosystems, and water supply are vulnerable to extreme weather such as hurricanes, floods, and droughts. Eastern Puerto Rico offers a natural laboratory for separating geologic and land-cover influences from regional- and global-scale influences because of its various bedrock types and the changing land cover surrounding intact, mature forest of the Luquillo Experimental Forest. Accordingly, a multiyear assessment of hydrological and biogeochemical processes was designed to develop an understanding of the effects of these differences on local climate, streamflow, water quality, and ecosystems, and to form the basis for a long-term and event-based program of climate and hydrologic monitoring. Because infrequent, large storms play a major role in this landscape, we focused on high-runoff events, sampling 263 storms, including all major hurricanes from 1991 through 2005. The largest storms have profound geomorphic consequences, such as landslides, debris flows, deep gullying on deforested lands, excavation and suspension of sediment in stream channels, and delivery of a substantial fraction of annual stream sediment load. Large storms sometimes entrain ocean foam and spray causing high concentrations of seasalt-derived constituents in stream waters during the storm. Past deforestation and agricultural activities in the Cayaguás and Canóvanas watersheds accelerated erosion and soil loss, and this material continues to be remobilized during large storms. Nearly 5,000 routine and event samples were analyzed for parameters that allow determination of denudation rates based on suspended and dissolved loads; 860 of these samples were analyzed for a comprehensive suite of chemical constituents. The rivers studied are generally similar in water-quality characteristics, and windward or leeward aspect appears to exert a stronger influence on water quality than geology or land cover. Of samples analyzed for comprehensive chemistry and for sediment, 543 were collected at runoff rates greater than 1 millimeter per hour, 256 at rates exceeding 10 millimeters per hour, and 3 at rates exceeding 90 millimeters per hour. Streams have rarely been sampled during events with such high runoff rates. Rates of physical and chemical weathering are especially high, and physical denudation rates, forested watersheds included, are considerably greater than is expected for a steady-state system. The elevated physical erosion drives an increased particulate organic carbon flux, one that is large, important to the carbon cycle, and sustainable, because soil-carbon regeneration is rapid. The 15-year Water, Energy, and Biogeochemical Budget dataset, which includes discharge, field parameters, suspended sediment, major cations and anions, and nutrients, is available from the U.S. Geological Survey's National Water Information System (http://waterdata.usgs.gov/nwis). The dataset provides a baseline for characterizing future environmental change and will improve our understanding of the interdependencies of land, water, and biological resources and their responses to changes in climate and land use. Because eastern Puerto Rico resembles many tropical regions in terms of geology and patterns of development, implications from this study are transferable to other tropical regions facing deforestation, rapid land-use change, and climate change.

Professional Paper↗

USGS2023

Determining three-dimensional hydrologic processes in the eastern Snake River Plain aquifer using geochemical mass-balance modeling, Idaho National Laboratory, eastern Idaho, with contributions by Treinen, K.C.

Idaho↗

USGS2023

Evaluation of hydrologic processes in the eastern Snake River Plain aquifer using uranium and strontium isotopes, Idaho National Laboratory, eastern Idaho

Waste constituents discharged to the eastern Snake River Plain aquifer at the U.S. Department of Energy (DOE) Idaho National Laboratory (INL) pose risks to the water quality of the aquifer. To understand these risks, the U.S. Geological Survey, in cooperation with the DOE, is conducting geochemical studies to better understand the hydrologic processes at the INL that affect the movement of groundwater and waste constituents. In this study, we used natural uranium ( 234 U/ 238 U) and strontium ( 87 Sr/ 86 Sr) isotope ratios of surface water and groundwater to identify the sources of water, the mixing of different source waters, and the flow directions in the shallow part (upper 250 feet) of the aquifer at the INL. Samples were collected from 17 sites at and near the INL that represent the source-water contributions to the aquifer. These source-water sites included surface water, regional groundwater, and springs. Groundwater samples from 63 sites were collected at and near the INL. For all sites, sample collection dates ranged from 1979 to 2019, but groundwater samples collected at the INL are representative of wet climate cycles when the Big Lost River (BLR) was flowing onto the INL. The 234 U/ 238 U activity ratios and 87 Sr/ 86 Sr from groundwater at the INL were plotted on graphs within ternary mixing webs in which the three end members of the mixing web represented specific sources of recharge. The large number of sources of recharge required numerous mixing webs, representing various geographic locations at the INL, so that each mixing web represented an area with just three sources of recharge. Considerations for determining the sources of recharge to groundwater sites included chemical signatures in addition to 234 U/ 238 U and 87 Sr/ 86 Sr, hydrologic context, and geographic location. The mixing webs were used to estimate the percentage of recharge from specific sources to groundwater at wells. The results of this study identified groundwater from the Lemhi Range as a source of recharge to the INL, which was a previously unsuspected source of recharge. The estimated spatial distribution of recharge from the BLR and groundwater from the Lost River Range also decreased and increased, respectively, relative to the spatial distribution estimated from an earlier study. Upwelling geothermal water was identified at only one well, which indicates that the upward movement of deep groundwater to the shallow part of the aquifer is largely nonexistent. Mixing between surface water and groundwater, different groundwater recharge sources, or both is ubiquitous at the INL. Mixing of water fully explains the distribution of 234 U/ 238 U and 87 Sr/ 86 Sr in groundwater at the INL and thus renders unnecessary the hypothesis that fast and slow flow zones at the INL are required to explain the distribution of 234 U/ 238 U and 87 Sr/ 86 Sr.

Idaho↗

USGS1966

Channel and hillslope processes in a semiarid area, New Mexico

Ephemeral washes having drainage areas from a few acres to 5 square miles are shown by actual measurement to be accumulating sediment on the streambed. This aggradation is not apparent to the eye but is clearly shown in 7 years of annual remeasurement. A similar aggradation was in progress in the same area some 3000 years ago as evidenced by an alluvial terrace later dissected by the present channel system. At that time as well as at present, aggradation occurred even in tributary areas draining a few acres. Colluvial accumulations merge with channel deposits and blanket the valleys and tributary basins even up to a few hundred feet of the drainage divides. The present study concerned the amounts of sediment produced by different erosion processes in various physiographic positions in the drainage basins. Measurements show that by far the largest sediment source is sheet erosion operating on the small percentage of basin area near the basin divides. Mass movement, gully head extension, and channel enlargement are presently small contributors of sediment compared with sheet erosion on unrilled slopes. As in previous studies, not all of the erosion products could be accounted for by accumulations on colluvial slopes and on beds of channels. The discrepancies are attributed primarily to sediment carried completely out of the basins studied and presumably deposited somewhere downstream. Aggradation of alluvial valleys of 5 square miles area and smaller both in the present epicycle, and in prehistorical but post-glacial times in this locality, cannot be attributed to gullying or rill extension in the headwater tributaries but to sheet erosion of the most upstream margins of the basins. Studies of rainfall characteristics of the 7 years of measurement compared with previous years in the 100-year record do not provide a clear-out difference which would account for the presently observed aggradation of channels. Longer period of measurement of erosion and sedimentation will be necessary to identify what precipitation parameters govern whether the channels aggrade or degrade.

Professional Paper↗

USGS2004

Nutrient enrichment, phytoplankton algal growth, and estimated rates of instream metabolic processes in the Quinebaug River Basin, Connecticut, 2000-2001

A consistent and pervasive pattern of nutrient enrichment was substantiated by water-quality sampling in the Quinebaug River and its tributaries in eastern Connecticut during water years 2000 and 2001. Median total nitrogen and total phosphorus concentrations exceeded the U.S. Environmental Protection Agency?s recently recommended regional ambient water-qual-ity criteria for streams (0.71 and 0.031 milligrams per liter, respectively). Maximum total phosphorus concentrations exceeded 0.1 milligrams per liter at nearly half the sampled locations in the Quinebaug River Basin. Elevated total nitrogen and total phosphorus concentrations were measured at all stations on the mainstem of the Quinebaug River, the French River, and the Little River. Nutrient enrichment was related to municipal wastewater point sources at the sites on the mainstem of the Quinebaug River and French River, and to agricultural nonpoint nutrient sources in the Little River Basin. Nutrient enrichment and favorable physical factors have resulted in excessive, nuisance algal blooms during summer months, particularly in the numerous impoundments in the Quinebaug River system. Phytoplankton algal density as high as 85,000 cells per milliliter was measured during such nuisance blooms in water years 2000 and 2001. Different hydrologic conditions during the summers of 2000 and 2001 produced very different seston algal populations. Larger amounts of precipitation sustained higher streamflows in the summer of 2000 (than in 2001), which resulted in lower total algal abundance and inhibited the typical algal succession from diatoms to cyanobacteria. Despite this, nearly half of all seston chlorophyll-a concentrations measured during this study exceeded the recommended regional ambient stream-water-quality criterion (3.75 micrograms per liter), and seston chlorophyll-a concentrations as large as 42 micrograms per liter were observed in wastewa-ter-receiving reaches of the Quinebaug River. Estimates of primary productivity and respiration obtained from diel dissolved oxygen monitoring and from light- and dark-bottle dissolved oxygen measurements demonstrated that instream metabolic processes are consistent with a seston-algae dominant system. The highest estimated maximum primary productivity rate was 1.72 grams of oxygen per cubic meter per hour at the Quinebaug River at Jewett City during September 2001. The observed extremes in diel dissolved oxygen concentrations (less than 5 milligrams per liter) and pH (greater than 9) may periodically stress aquatic organisms in the Quinebaug River Basin.

Scientific Investigations Report↗

USGS2008

Hydrogeology, Chemical Characteristics, and Transport Processes in the Zone of Contribution of a Public-Supply Well in York, Nebraska

In 2001, the U.S. Geological Survey, as part of the National Water Quality Assessment (NAWQA) Program, initiated a topical study of Transport of Anthropogenic and Natural Contaminants (TANC) to PSW (public-supply wells). Local-scale and regional-scale TANC study areas were delineated within selected NAWQA study units for intensive study of processes effecting transport of contaminants to PSWs. This report describes results from a local-scale TANC study area at York, Nebraska, within the High Plains aquifer, including the hydrogeology and geochemistry of a 108-square-kilometer study area that contains the zone of contribution to a PSW selected for study (study PSW), and describes factors controlling the transport of selected anthropogenic and natural contaminants to PSWs. Within the local-scale TANC study area, the High Plains aquifer is approximately 75 m (meter) thick, and includes an unconfined aquifer, an upper confining unit, an upper confined aquifer, and a lower confining unit with lower confined sand lenses (units below the upper confining unit are referred to as confined aquifers) in unconsolidated alluvial and glacial deposits overlain by loess and underlain by Cretaceous shale. From northwest to southeast, land use in the local-scale TANC study area changes from predominantly irrigated agricultural land to residential and commercial land in the small community of York (population approximately 8,100). For the purposes of comparing water chemistry, wells were classified by degree of aquifer confinement (unconfined and confined), depth in the unconfined aquifer (shallow and deep), land use (urban and agricultural), and extent of mixing in wells in the confined aquifer with water from the unconfined aquifer (mixed and unmixed). Oxygen (delta 18O) and hydrogen (delta D) stable isotopic values indicated a clear isotopic contrast between shallow wells in the unconfined aquifer (hereinafter, unconfined shallow wells) and most monitoring wells in the confined aquifers (hereinafter, confined unmixed wells). Delta 18O and delta D values for a minority of wells in the confined aquifers were intermediate between those for the unconfined shallow wells and those for the confined unmixed wells. These intermediate values were consistent with mixing of water from unconfined and confined aquifers (hereinafter, confined mixed wells). Oxidation-reduction conditions were primarily oxic in the unconfined aquifer and variably reducing in the confined aquifers. Trace amounts of volatile organic compounds (VOC), particularly tetrachloroethylene (PCE) and trichloroethylene (TCE), were widely detected in unconfined shallow urban wells and indicated the presence of young urban recharge waters in most confined mixed wells. The presence of degradation products of agricultural pesticides (acetochlor and alachlor) in some confined mixed wells suggests that some fraction of the water in these wells also was the result of recharge in agricultural areas. In the unconfined aquifer, age-tracer data (chlorofluorocarbon and sulfur hexafluoride data, and tritium to helium-3 ratios) fit a piston-flow model, with apparent recharge ages ranging from 7 to 48 years and generally increasing with depth. Age-tracer data for the confined aquifers were consistent with mixing of 'old' water, not containing modern tracers recharged in the last 60 years, and exponentially-mixed 'young' water with modern tracers. Confined unmixed wells contained less than (<) 3 percent (%) young water mixed with a much larger fraction greater than or equal to (>=) 97% of old water. Confined mixed wells contained >30% young water and mean ages ranged from 12 to 14 years. Median concentrations of nitrate (as nitrogen, hereinafter, nitrate-N) were 17.3 and 16.0 mg/L (milligram per liter) in unconfined shallow urban and agricultural wells, respectively, indicating a range of likely nitrate sources. Septic systems are most numerous near the edge of the urban area and appear to be

Scientific Investigations Report↗

USGS2009

DayCent-Chem simulations of ecological and biogeochemical processes of eight mountain ecosystems in the United States

Atmospheric deposition of nitrogen (N) and sulfur (S) cause complex responses in ecosystems, from fertilization to forest ecosystem decline, freshwater eutrophication to acidification, loss of soil base cations, and alterations of disturbance regimes. DayCent-Chem, an ecosystem simulation model that combines ecosystem nutrient cycling and plant dynamics with aqueous geochemical equilibrium calculations, was developed to address ecosystem responses to combined atmospheric N and S deposition. It is unique among geochemically-based models in its dynamic biological cycling of N and its daily timestep for investigating ecosystem and surface water chemical response to episodic events. The model was applied to eight mountainous watersheds in the United States. The sites represent a gradient of N deposition across locales, from relatively pristine to N-saturated, and a variety of ecosystem types and climates. Overall, the model performed best in predicting stream chemistry for snowmelt-dominated sites. It was more difficult to predict daily stream chemistry for watersheds with deep soils, high amounts of atmospheric deposition, and a large degree of spatial heterogeneity. DayCent-Chem did well in representing plant and soil carbon and nitrogen pools and fluxes. Modeled stream nitrate (NO 3 - ) and ammonium (NH 4 + ) concentrations compared well with measurements at all sites, with few exceptions. Simulated daily stream sulfate (SO 4 2- ) concentrations compared well to measured values for sites where SO 4 2- deposition has been low and where SO 4 2- adsorption/desorption reactions did not seem to be important. The concentrations of base cations and silica in streams are highly dependent on the geochemistry and weathering rates of minerals in each catchment, yet these were rarely, if ever, known. Thus, DayCent-Chem could not accurately predict weathering products for some catchments. Additionally, few data were available for exchangeable soil cations or the magnitude of base cation deposition as a result of dry and fog inputs. The uncertainties related to weathering reactions, deposition, soil cation exchange capacity, and groundwater contributions influenced how well the simulated acid neutralizing capacity (ANC) and pH estimates compared to observed values. Daily discharge was well represented by the model for most sites. The chapters of this report describe the parameterization for each site and summarize model results for ecosystem variables, stream discharge, and stream chemistry. This intersite comparison exercise provided insight about important and possibly not well understood processes.

Scientific Investigations Report↗

USGS2009

Sand resources, regional geology, and coastal processes of the Chandeleur Islands Coastal System: An evaluation of the Breton National Wildlife Refuge

Breton National Wildlife Refuge, the Chandeleur Islands chain in Louisiana, provides habitat and nesting areas for wildlife and is an initial barrier protecting New Orleans from storms. The U.S. Geological Survey (USGS) in partnership with the University of New Orleans Pontchartrain Institute for Environmental Sciences undertook an intensive study that included (1) an analysis of island change based on historical maps and remotely sensed shoreline and topographic data; (2) a series of lidar surveys at 3- to 4-month intervals after Hurricane Katrina to determine barrier island recovery potential; (3) a discussion of sea level rise and effects on the islands; (4) an analysis of sea floor evolution and sediment dynamics in the refuge over the past 150 years; (5) an assessment of the local sediment transport and sediment resource availability based on the bathymetric and subbottom data; (6) a carefully selected core collection effort to groundtruth the geophysical data and more fully characterize the sediments composing the islands and surrounds; (7) an additional survey of the St. Bernard Shoals to assess their potential as a sand resource; and (8) a modeling study to numerically simulate the potential response of the islands to the low-intensity, intermediate, and extreme events likely to affect the refuge over the next 50 years. Results indicate that the islands have become fragmented and greatly diminished in subaerial extent over time: the southern islands retreating landward as they reorganize into subaerial features, the northern islands remaining in place. Breton Island, because maintenance of the Mississippi River-Gulf Outlet (MRGO) outer bar channel requires dredging, is deprived of sand sufficient to sustain itself. Regional sediment transport trends indicate that large storms are extremely effective in transporting sand and controlling the shoreline development and barrier island geometry. Sand is transported north and south from a divergent zone near Monkey Bayou at the southern end of the Chandeleur Islands. Numerical simulation of waves and sediment transport supports the geophysical results and indicates that vast areas of the lower shoreface are affected and are undergoing erosion during storm events, that there is little or no fair weather mechanism to rework material into the littoral system, and that as a result, there is a net loss of sediment from the system. Lidar surveys revealed that the island chain immediately after Hurricane Katrina lost about 84 percent of its area and about 92 percent of its prestorm volume. Marsh platforms that supported the islands’ sand prior to the storm were reduced in width by more than one-half. Repeated lidar surveys document that in places the shoreline has retreated about 100 m under the relatively low-energy waves since Hurricanes Katrina and Rita; however, this retreat is nonuniform. Recent high-resolution geophysical surveys of the sea floor and subsurface within 5–6 km of the Chandeleur Islands during 2006 and 2007 show that, in addition to the sand that is rebuilding portions of the island chain, a large volume of sand is contained in Hewes Point, in an extensive subtidal spit platform that has formed at the northern end of the Chandeleur Islands. Hewes Point appears to be the depositional terminus of the alongshore transport system. In the southern Chandeleurs, sand is being deposited in a broad tabular deposit near Breton Island called the southern offshore sand sheet. These two depocenters account for approximately 70 percent of the estimated sediment volume located in potential borrow sites. An additional large potential source of sand for restoration lies in the St. Bernard Shoals, which are estimated to contain approximately 200 × 10 6 m 3 of sand. Successful restoration planning for the Breton National Wildlife Refuge should mimic the natural processes of early stages of barrier island evolution including lateral transport to the flanks of the island chain from a centralized sand source that will ultimately enhance the ability of the islands to naturally build backbarrier marsh, dunes, and a continuous sandy shoreline. Barrier island sediment nourishment should be executed with the understanding that gulf shoreline erosion is inevitable but that island area can be maintained and enhanced during retreat (thus significantly prolonging the life of the island chain) with strategic sand placement.

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