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At least 829 records · Page 46Linked to original sources
USGS2003

Integrating soils and geomorphology in mountains - An example from the Front Range of Colorado

Soil distribution in high mountains reflects the impact of several soil-forming factors. Soil geomorphologists use key pedological properties to estimate ages of Quaternary deposits of various depositional environments, estimate long-term stability and instability of landscapes, and make inferences on past climatic change. Once the influence of the soil-forming factors is known, soils can be used to help interpret some aspects of landscape evolution that otherwise might go undetected. The Front Range of Colorado rises from the plains of the Colorado Piedmont at about 1700 m past a widespread, dissected Tertiary erosion surface between 2300 and 2800 m up to an alpine Continental Divide at 3600 to over 4000 m. Pleistocene valley glaciers reached the western edge of the erosion surface. Parent rocks are broadly uniform (granitic and gneissic). Climate varies from 46 cm mean annual precipitation (MAP) and 11 ??C mean annual temperature (MAT) in the plains to 102 cm and -4 ??C, respectively, near the range crest. Vegetation follows climate with grassland in the plains, forest in the mountains, and tundra above 3450 m. Soils reflect the bioclimatic transect from plains to divide: A/Bw or Bt/Bk or K (grassland) to A/E/Bw or Bt/C (forest) to A/Bw/C (tundra). Corresponding soil pH values decrease from 8 to less than 5 with increasing elevation. The pedogenic clay minerals dominant in each major vegetation zone are: smectite (grassland), vermiculite (forest), and 1.0-1.8 nm mixed-layer clays (tundra). Within the lower forested zone, the topographic factor (aspect) results in more leached, colder soils, with relatively thin O horizons, well-expressed E horizons and Bt horizons (Alfisols) on N-facing slopes, whereas soils with thicker A horizons, less developed or no E horizons, and Bw or Bt horizons (Mollisols) are more common on S-facing slopes. The topographic factor in the tundra results in soil patterns as a consequence of wind-redistributed snow and the amount of time it lingers on the landscape. An important parent material factor is airborne dust, which results in fine-grained surface horizons and, if infiltrated, contributes to clay accumulation in some Bt horizons. The time factor is evaluated by soil chronosequence studies of Quaternary deposits in tundra, upper forest, and plains grassland. Few soils in the study area are >10,000 years old in the tundra, >100,000 years old in the forest, and >2 million years old in the grassland. Stages of granite weathering vary with distance from the Continental Divide and the best developed is grus near the sedimentary/granitic rock contact just west of the mountain front. Grus takes a minimum of 100,000 years to form. Some of the relations indicated by the soil map patterns are: (1) parts of the erosion surface have been stable for 100,000 years or more; (2) development of grus near the mountain front could be due in part to pre-Pennsylvanian weathering; (3) a few soil properties reflect Quaternary paleoclimate; and (4) a correlation between soil development in the canyons and stream incision rates. ?? 2003 Elsevier Science B.V. All rights reserved.

Geomorphology↗
USGS2019

Tracing the cycling and fate of the munition, Hexahydro-1,3,5-trinitro-1,3,5-triazine in a simulated sandy coastal marine habitat with a stable isotopic tracer, 15N-[RDX]

Coastal marine habitats become contaminated with the munitions constituent, Hexahydro-1,3,5-trinitro-1,3,5-trazine (RDX), via military training, weapon testing and leakage of unexploded ordnance. This study used 15 N labeled RDX in simulated aquarium-scale coastal marine habitat containing seawater, sediment, and biota to track removal pathways from surface water including sorption onto particulates, degradation to nitroso-triazines and mineralization to dissolved inorganic nitrogen (DIN). The two aquaria received continuous RDX inputs to maintain a steady state concentration (0.4 mg L −1 ) over 21 days. Time series RDX and nitroso-triazine concentrations in dissolved (surface and porewater) and sorbed phases (sediment and suspended particulates) were analyzed. Distributions of DIN species (ammonium, nitrate + nitrite and dissolved N 2 ) in sediments and overlying water were also measured along with geochemical variables in the aquaria. Partitioning of RDX and RDX-derived breakdown products onto surface sediment represented 13% of the total added 15 N as RDX ( 15 N-[RDX]) equivalents after 21 days. Measured nitroso-triazines in the aquaria accounted for 6–13% of total added 15 N-[RDX]. 15 N-labeled DIN was found both in the oxic surface water and hypoxic porewaters, showing that RDX mineralization accounted for 34% of the 15 N-[RDX] added to the aquaria over 21 days. Labeled ammonium ( 15 NH 4 + , found in sediment and overlying water) and nitrate + nitrite ( 15 NO X , found in overlying water only) together represented 10% of the total added 15 N-[RDX]. The production of 15 N labeled N 2 ( 15 N 2 ), accounted for the largest individual sink during the transformation of the total added 15 N-[RDX] (25%). Hypoxic sediment was the most favorable zone for production of N 2 , most of which diffused through porous sediments into the water column and escaped to the atmosphere.

Science of the Total Environment↗
USGS1983

Anaerobic oxalate degradation: Widespread natural occurrence in aquatic sediments

Significant concentrations of oxalate (dissolved plus particulate) were present in sediments taken from a diversity of aquatic environments, ranging from 0.1 to 0.7 mmol/liter of sediment. These included pelagic and littoral sediments from two freshwater lakes (Searsville Lake, Calif., and Lake Tahoe, Calif.), a hypersaline, meromictic, alkaline lake (Big Soda Lake, Nev.), and a South San Francisco Bay mud flat and salt marsh. The oxalate concentration of several plant species which are potential detrital inputs to these aquatic sediments ranged from 0.1 to 5.0% (wt/wt). In experiments with litter bags, the oxalate content of Myriophyllum sp. samples buried in freshwater littoral sediments decreased to 7% of the original value in 175 days. This suggests that plant detritus is a potential source of the oxalate within these sediments. [ 14 C]oxalic acid was anaerobically degraded to 14 CO 2 in all sediment types tested, with higher rates evident in littoral sediments than in the pelagic sediments of the lakes studied. The turnover time of the added [ 14 C]oxalate was less than 1 day in Searsville Lake littoral sediments. The total sediment oxalate concentration did not vary significantly between littoral and pelagic sediments and therefore did not appear to be controlling the rate of oxalate degradation. However, depth profiles of [ 14 C]oxalate mineralization and dissolved oxalate concentration were closely correlated in freshwater littoral sediments; both were greatest in the surface sediments (0 to 5 cm) and decreased with depth. The dissolved oxalate concentration (9.1 μmol/liter of sediment) was only 3% of the total extractable oxalate (277 μmol/liter of sediment) at the sediment surface. These results suggest that anaerobic oxalate degradation is a widespread phenomenon in aquatic sediments and may be limited by the dissolved oxalate concentration within these sediments.

California, Nevada↗
USGS2023

Anthropogenic influence on groundwater geochemistry in Horn Creek Watershed near the Orphan Mine in Grand Canyon National Park, Arizona, USA

Breccia pipe deposits of the Grand Canyon region contain ore grade copper and uranium. Horn Creek is located near the Orphan Mine mineralized breccia pipe deposit and groundwater emerging from the bedrock in the headwaters of Horn Creek has the highest uranium concentrations in the region. Uranium decreases an order of magnitude between the groundwater at the top of the watershed and the groundwater emerging from the alluvial material lower in the watershed. Horn Creek water has low sulfur and uranium isotopic ratios which may suggest interaction with sulfide and uranium minerals found in mineralized breccia pipe deposits. Per- and polyfluoroalkyl substances (PFBA and PFBS) were found in low concentrations in groundwater from the bedrock and may be related to mining process materials or other anthropogenic activities. PHREEQC modeling suggests that water that is elevated in uranium emerging from the bedrock in the upper watershed may mix with other groundwater and atmospheric precipitation infiltrated into the alluvial material in the lower watershed. Tritium is elevated in Horn Creek groundwaters suggesting a component of modern water, some of which may have interacted with Orphan Mine workings. Additional studies could build on this understanding of chemistry changes in waters of Horn Creek to provide more direct evidence of contribution of water moving through the Orphan Mine.

Arizona↗
USGS2025

Melt generation sources and conditions in the wake of a migrating slab window: Geochemistry and petrology of the million-year history of primitive volcanism at Clear Lake volcanic field, California

Clear Lake volcanic field (CLVF) is the northernmost and youngest (~2.2 Ma to 8 ka) of the volcanic centers distributed along the San Andreas transform fault in western California. The initial phase of CLVF volcanism (interval one) occurred between ~2.2 and 1.3 Ma and extends ~35 km southeast of Clear Lake, forming a semi-continuous upland plateau capped by lava flows, with isolated volcanic remnants on the periphery. This volcanism is broadly characterized by geochemically primitive compositions that reflect three source compositions and conditions of melt generation. (1) Partial melting of upwelling asthenospheric mantle lherzolite at moderate pressures (1.2–1.4 GPa) and temperatures (1297–1329 °C) produced high-CaO (9.8–11.3 wt %) basalts with high Al 2 O 3 (16.8–17.6 wt %), Mg#s (66–70), MgO (8–10 wt %), Ni (103–262 μg/g), and Cr (284–609 μg/g). These high-CaO basalts contain olivine (Fo 87–91 ) phenocrysts with Cr-spinel inclusions ± subordinate plagioclase and crop out only in the southern part of the CLVF. (2) Partial melting of depleted sub-continental lithospheric mantle harzburgite at variable pressures (0.7–1.5 GPa) and temperatures (1097–1299 °C) produced a compositional continuum of med-K 2 O, calc-alkaline, high-MgO basalts through high-MgO andesites with high Mg#s (67–77), MgO (8–14 wt %) and high Ni and Cr abundances (154–439 and 340–1124 μg/g, respectively). Mineral assemblages are olivine (Fo 88–93 ) with Cr-spinel inclusions ± subordinate clinopyroxene, orthopyroxene and plagioclase. Small (<2.5 cm) mantle harzburgite xenoliths and mantle olivine xenocrysts are also found in several of these samples. These high-MgO basalts through andesites represent the largest volume of primitive compositions and have erupted predominantly along the main, fault-controlled northwest-southeast trending axis of volcanism with peripheral outcrops to the north, west, and east. (3) Partial melting of the Gorda eclogite slab edge produced adakitic silicic slab melts with strong depletion in the heavy rare earth elements (Yb = 0.6 μg/g). Subsequent reaction of those melts with depleted ultramafic rocks during ascent imprinted the adakitic dacites with high Mg#s (65–78) and elevated Ni (117–210 μg/g) and Cr (191–283 μg/g). Phenocrysts of orthopyroxene (En 87–94 ) with spinel inclusions (Cr# = 80–88) and extremely Ni-rich (9483 μg/g) olivine cores (Fo 84–93 ) record those reactions. Small-volume outcrops of the adakites on the eastern periphery of the CLVF track the passing slab edge. The trio of melting sources recorded by early CLVF magmatism reflect the tectonically complex environment and the hot (1097–1329 °C), shallow (0.7–1.5 GPa) melting conditions for these primitive compositions and provide estimates of the heat delivered to the crust. Over time, this flux led to maturation of the CLVF magmatic system toward the more voluminous and silicic volcanism that characterizes the balance of its subsequent volcanic history and maintains the present-day anomalously high heat flow in the region. The current interval (interval four) of volcanic activity at CLVF is characterized by low-volume, fault-controlled eruptions of basaltic andesite and andesite suggestive of mantle magma and heat delivery to the crust, similar to interval one. This analogous activity provides motivation for the current study and begs the question of whether the system is undergoing thermal priming for renewed silicic volcanism.

California↗
USGS2007

Sources and temporal dynamics of arsenic in a New Jersey watershed, USA

We examined potential sources and the temporal dynamics of arsenic (As) in the slightly alkaline waters of the Wallkill River, northwestern New Jersey, where violations of water-quality standards have occurred. The study design included synoptic sampling of stream water and bed sediments in tributaries and the mainstem, hyporheic-zone/ground water on the mainstem, and seasonal and diurnal sampling of water at selected mainstem sites. The river valley is bordered by gneiss and granite highlands and shale lowlands and underlain by glacial deposits over faulted dolomites and the Franklin Marble. Ore bodies in the Marble, which have been mined for rare Zn ore minerals, also contain As minerals. Tributaries, which drain predominantly forested and agricultural land, contributed relatively little As to the river. The highest concentrations of As (up to 34 μg/L) emanated from the outlet of man-made Lake Mohawk at the river's headwaters; these inputs varied substantially with season—high during warm months, low during cold months, apparently because of biological activity in the lake. Dissolved As concentrations were lower (3.3 μg/L) in river water than those in ground water discharging into the riverbed (22 μg/L) near the now-closed Franklin Mine. High total As concentrations (100–190 mg/kg) on the < 0.63 μm fraction of bed sediments near the mine apparently result from sorption of the As in the ground-water discharge as well as from the As minerals in the streambed. As concentrations in river water were diluted during high stream flow in fall, winter and spring, and concentrated during low flow in summer. In unfiltered samples from a wetlands site, diurnal cycles in trace-element concentrations occurred; As concentrations appeared to peak during late afternoon as pH increased, but Fe, Mn, and Zn concentrations peaked shortly after midnight. The temporal variability of As and its presence at elevated concentrations in ground water and sediments as well as streamwater demonstrate the importance of (1) sampling a variety of media and (2) determining the time scales of As variability to fully characterize its passage through a river system.

New Jersey↗
USGS2021

Porphyry and epithermal mineral deposits

Porphyry and epithermal mineral deposits form large economic ore bodies that provide the global economy with copper, molybdenum, gold, silver and other byproducts (Re, Te, Se). They form in the upper crust and are related to sulfur- and water-rich intermediate to silicic magmatic sources of hydrothermal fluids that move upward and produce extensive hydrolytic and alkali wall-rock alteration, quartz veins, and sulfides. Porphyry-type deposits are formed above magma chambers where fluids hydrofracture rock at 700–350 °C and at pressures ranging from supra-lithostatic to supra-hydrostatic. The depth of formation ranges from 2 to 10 km and influences orebody geometries and the types and mineralogy of veins, sulfides and wall-rock alteration. The temporal evolution of hydrothermal events is documented by cross-cutting veins and is commonly characterized by a decline in fluid temperature and concordant evolution from potassic alteration to sericitic alteration, with attendant increase in sulfidation state of copper-iron sulfides. In some localities porphyry copper deposits transition upwards to lower temperature base metal lodes (350–200 °C) and eventually the formation of near surface (<1.5 km depth) intermediate- and high-sulfidation epithermal deposits (~300–120 °C). Extensional environments are often characterized by porphyry molybdenum and low-sulfidation epithermal deposits. In the base metal lode and epithermal environments, mixtures of magmatic and meteoric fluids produce ore fluids at hydrostatic pressures that advect freely both vertically and laterally along permeability provided by faults, joints, and porous lithologies. Wall-rock alteration ranges from hydrolytic to alkali-carbonate, and from high- to low-sulfidation state sulfide assemblages, respectively. In porphyry, base metal lode, and epithermal environments, geology and the zonation of wall-rock alteration, veins, sulfide assemblages, and metals are useful for exploration.

Book chapter↗
USGS2008

Igneous phenocrystic origin of K-feldspar megacrysts in granitic rocks from the Sierra Nevada batholith

Study of four K-feldspar megacrystic granitic plutons and related dikes in the Sierra Nevada composite batholith indicates that the megacrysts are phenocrysts that grew in contact with granitic melt. Growth to megacrystic sizes was due to repeated replenishment of the magma bodies by fresh granitic melt that maintained temperatures above the solidus for extended time periods and that provided components necessary for K-feldspar growth. These intrusions cooled 89-83 Ma, are the youngest in the range, and represent the culminating magmatic phase of the Sierra Nevada batholith. They are the granodiorite of Topaz Lake, the Cathedral Peak Granodiorite, the Mono Creek Granite, the Whitney Granodiorite, the Johnson Granite Porphyry, and the Golden Bear Dike. Megacrysts in these igneous bodies attain 4-10 cm in length. All have sawtooth oscillatory zoning marked by varying concentration of BaO ranging generally from 3.5 to 0.5 wt%. Some of the more pronounced zones begin with resorption and channeling of the underlying zone. Layers of mineral inclusions, principally plagioclase, but also biotite, quartz, hornblende, titanite, and accessory minerals, are parallel to the BaO-delineated zones, are sorted by size along the boundaries, and have their long axes preferentially aligned parallel to the boundaries. These features indicate that the K-feldspar megacrysts grew while surrounded by melt, allowing the inclusion minerals to periodically attach themselves to the faces of the growing crystals. The temperature of growth of titanite included within the K-feldspar megacrysts is estimated by use of a Zr-in-titanite geothermometer. Megacryst-hosted titanite grains all yield temperatures typical of felsic magmas, mainly 735-760 ??C. Titanite grains in the granodiorite hosts marginal to the megacrysts range to lower growth temperatures, in some instances into the subsolidus. The limited range and igneous values of growth temperatures for megacryst-hosted titanite grains support the interpretation that the megacrysts formed ag igneous sanidine phenocrysts, that intrusion temperatures varied by only small amounts while the megacrysts grew, and that megacryst growth ceased before the intrusions cooled below the solidus. Individual Ba-enriched zones were apparently formed by repeated surges of new, hotter granitic melt that replenished these large magma chambers. Each recharge of hot magron offset cooling, maintained the partially molten or mushy character of the chamber, stirred up crystals, and induced convective currents that lofted, settling megacrysts back up into the chamber. Because of repeated reheating of the magma chamber and prolonged maintenance of the melt, this process apparently continued long enough to provide the ideal environment for the growth of these extraordinarily large K-feldspar phenocrysts. ??2008 Geological Society of America.

Geosphere↗
USGS2007

Organic petrology of Paleocene Marcelina Formation coals, Paso Diablo mine, western Venezuela: Tectonic controls on coal type

About 7??Mt of high volatile bituminous coal are produced annually from the four coal zones of the Upper Paleocene Marcelina Formation at the Paso Diablo open-pit mine of western Venezuela. As part of an ongoing coal quality study, we have characterized twenty-two coal channel samples from the mine using organic petrology techniques. Samples also were analyzed for proximate-ultimate parameters, forms of sulfur, free swelling index, ash fusion temperatures, and calorific value. Six of the samples represent incremental benches across the 12-13??m thick No. 4 bed, the stratigraphically lowest mined coal, which is also mined at the 10??km distant Mina Norte open-pit. Organic content of the No. 4 bed indicates an upward increase of woody vegetation and/or greater preservation of organic material throughout the life of the original mire(s). An upward increase in telovitrinite and corresponding decrease in detrovitrinite and inertinite illustrate this trend. In contrast, stratigraphically higher coal groups generally exhibit a 'dulling upward' trend. The generally high inertinite content, and low ash yield and sulfur content, suggest that the Paso Diablo coals were deposited in rain-fed raised mires, protected from clastic input and subjected to frequent oxidation and/or moisture stress. However, the two thinnest coal beds (both 0.7??m thick) are each characterized by lower inertinite and higher telovitrinite content relative to the rest of Paso Diablo coal beds, indicative of less well-established raised mire environments prior to drowning. Foreland basin Paleocene coals of western Venezuela, including the Paso Diablo deposit and time-correlative coal deposits of the Ta??chira and Me??rida Andes, are characterized by high inertinite and consistently lower ash and sulfur relative to Eocene and younger coals of the area. We interpret these age-delimited coal quality characteristics to be due to water availability as a function of the tectonic control of subsidence rate. It is postulated that slower subsidence rates dominated during the Paleocene while greater foreland basin subsidence rates during the Eocene-Miocene resulted from the loading of nappe thrust sheets as part of the main construction phases of the Andean orogen. South-southeastward advance and emplacement of the Lara nappes during the oblique transpressive collision of the Caribbean and South American tectonic plates in the Paleocene was further removed from the sites of peat deposition, resulting in slower subsidence rates. Slower subsidence in the Paleocene may have favored the growth of raised mires, generating higher inertinite concentrations through more frequent moisture stress. Consistently low ash yield and sulfur content would be due to the protection from clastic input in raised mires, in addition to the leaching of mineral matter by rainfall and the development of acidic conditions preventing fixation of sulfur. In contrast, peat mires of Eocene-Miocene age encountered rapid subsidence due to the proximity of nappe emplacement, resulting in lower inertinite content, higher and more variable sulfur content, and higher ash yield.

International Journal of Coal Geology↗
USGS2021

GIS-based identification of areas that have resource potential for sediment-hosted Pb-Zn deposits in Alaska

A state-wide Geographic Information System analysis was conducted to assess prospectivity for lead (Pb) and zinc (Zn) in sediment-hosted deposits in Alaska. The datasets that were utilized include publicly available geospatial datasets of lithologic, geochemical, and mineral occurrence data. Key characteristics of Pb-Zn deposits were identified in available datasets and scored with respect to relative importance. To evaluate resource potential, drainage basins of the smallest size were chosen, each of which covers approximately 100 square kilometers (km 2 ). Drainage basins are the most logical and efficient unit for evaluation because the most regionally robust dataset comes from stream sediment geochemistry. Sediment-hosted Pb-Zn deposits in Alaska include those contained in carbonate rocks (similar to Mississippi Valley Type or MVT deposits) and those contained in clastic-dominated (CD) sequences (CD Pb-Zn), historically referred to as SEDEX (sedimentary exhalative). The latter include the deposits currently being mined in the Red Dog district in the western Brooks Range. Host rocks for the two subtypes are distinct: carbonate versus fine-grained clastic rocks for CD Pb-Zn deposits. However, there are exceptions: some CD Pb-Zn deposits are hosted in carbonate layers within a thick clastic-dominated rock sequence. The statewide geologic map database contains units that commonly include mixed carbonate-clastic sequences that cannot be subdivided. The most significant difference between the two deposit types is their respective depositional environments and tectonic settings, but at the reconnaissance level of mapping in most areas of the state, these distinctions are not possible. Furthermore, nearly all critical geochemical parameters (silver [Ag], barium [Ba], Pb, Zn) are common to both types, and therefore it was not possible to do separate assessments for carbonate-hosted and CD Pb-Zn deposits. Areas identified that have moderate to high potential for sediment-hosted Pb-Zn deposits include the (1) western and central Brooks Range, referred to in this report as the Brooks Range zinc belt; (2) Seward Peninsula (and adjacent St. Lawrence Island); (3) Farewell terrane in Interior Alaska; (4) two spatially distinct belts in east-central Alaska; and (5) the central Alaska Range. All areas contain some known deposits, and that provides credibility to the scoring process. Some hydrologic unit codes (HUCs) that have high potential for sediment-hosted Pb-Zn deposits are located adjacent to areas of known deposits and indicate the potential for expansion of known Pb-Zn districts. There are a few areas that have high potential but contain no known sediment hosted Pb-Zn occurrences, prospects, or deposits. In such areas, future investigations could be focused on better defining and constraining prospectivity with additional data.

Alaska↗
USGS1979

Chemical analyses of coal from the Emery and Ferron Sandstone members of the Mancos Shale, Henry Mountains Field, Wayne and Garfield counties, Utah

As part of a continuing program by the U.S. Geological Survey to collect and chemically analyze representative samples of U.S. coals, 18 samples were collected from the Upper Cretaceous Emery and Ferron Sandstone Members of the Mancos Shale in the Henry Mountains coal field, Wayne and Garfield Counties, Utah (fig. 1). The 18 samples are briefly described in table 1. Thirteen of these samples were collected from seven holes that were drilled in connection with the Henry Mountains EMRIA (Energy Mineral Rehabilitation Inventory and Analyses) study (U.S. Department of the Interior, 1978). The locations of the seven core holes and the four other sampling sites are shown on figure 2. The Henry Mountains coal field is adjacent to the Henry Mountains of southeastern Utah. The basin is a long, narrow syncline about 110 km long and 24 km wide bounded on the west by the Waterpocket Fold and on the east by the Henry Mountains. The most comprehensive geologic report available on the area is by Hunt and others (1953). Their work included a considerable amount of information on the coal resources. Other work in the area concerning coal or stratigraphy of coal bearing units includes: Doelling (1972), Peterson and Ryder (1975), Doelling (1975), Law (1977; 1978; 1979 a,b), and U.S. Department of the Interior (1978). In the Henry Mountains field, there are three coal bearing units in rocks of Late Cretaceous age. In ascending order they are the Dakota Sandstone, the Ferron Sandstone Member of the Mancos Shale, and the Emery Sandstone Member of the Mancos Shale. The coal beds of the Henry Mountains coal field originated as layers of peat that were deposited, for the most part, in coastal swamp environments. Individual coal beds are discontinuous and exhibit large variations in thickness and quality. The thickest and most continuous coal beds occur in the Emery Sandstone Member along or near the axis of the Henry Mountains syncline (Law, 1978).

Utah↗
USGS2017

Constraining the thermal history of the North American Midcontinent Rift System using carbonate clumped isotopes and organic thermal maturity indices

The Midcontinent Rift System (MRS) is a Late Mesoproterozoic (∼1.1 Ga) sequence of volcanic and sedimentary rocks exposed in the Lake Superior Region of North America. The MRS continues to be the focus of much research due to its economic mineral deposits as well as its archive of Precambrian life and tectonic processes. In order to constrain the post-depositional thermal history of the MRS, samples were analyzed for carbonate clumped isotope composition and organic thermal maturity. Clumped isotope values from sedimentary/early-diagenetic samples were partially reset during burial to temperatures between 68 and 75 °C. Solid-state reordering models indicate that maximum burial temperatures of 125–155 °C would reset the clumped isotope values to the observed temperature range prior to the onset of regional cooling and uplift. Clumped isotope results from late-stage veins in the White Pine Mine encompass a greater temperature range (49–116 °C), indicative of spatially variable hydrothermal activity and vein emplacement after burial temperatures fell below 100 °C during regional cooling and uplift. Clumped isotope and organic thermal maturity data do not indicate significant spatial differences in thermal history along the MRS. Observed variability in bulk organic matter composition and biomarker indices are therefore more likely a result of shifts in primary productivity or early-degradation processes. These results demonstrate that the MRS experienced a spatially consistent, relatively mild thermal history (125–155 °C) and is therefore a valuable archive for understanding the Late Mesoproterozoic environment.

Lake Superior↗
USGS2024

Hydrothermal plume fallout, mass wasting, and volcanic eruptions contribute to sediments at Loki’s Castle vent field, Mohns Ridge

Sediments surrounding hydrothermal vents are important transition spaces between hydrothermal and pelagic environments. These sediments accumulate through diverse processes that include water column plume fallout, volcanic ash deposition, and mass wasting of hydrothermal chimneys and mounds superimposed upon background sedimentation which may originate from pelagic, terrestrial, and volcanic sources. In addition to being a sink for elements discharged from hydrothermal vents, elements may also be scavenged from seawater onto oxidized hydrothermal material. Preservation of these hydrothermal sediments may occur depending on the extent of oxidative and/or reductive dissolution processes after burial. Sediments remaining adjacent to active venting may also be hydrothermally altered after emplacement. To better understand these processes, here we evaluate sediment push cores collected from the Loki's Castle vent field at the intersection of the slow-ultraslow spreading Mohns and Knipovich mid-ocean ridges. All samples were collected within ∼225 m of current high-temperature (299–316°C) “black smoker” fluid discharge. These sediment cores are highly heterogeneous and lack stratigraphic correlation, even for samples taken within meters of each other. Most sediment cores are dominated by either pelagic sediments or mass wasted hydrothermal material, with hydrothermal plume fallout contributing a low proportion of material, and only a single volcanic ash layer occurring in one of the 13 cores. Dominant hydrothermal minerals found include talc, goethite, pyrite, pyrrhotite, and sphalerite. We find that even after several thousand years, most mass wasted hydrothermal material remains minimally altered, with sedimentation rates indistinguishable from background rates within several hundred meters of the hydrothermal vent source.

Geochemistry, Geophysics, Geosystems↗
USGS1991

Sedimentary facies and depositional environments of early Mesozoic Newark Supergroup basins, eastern North America

The early Mesozoic Newark Supergroup consists of continental sedimentary rocks and basalt flows that occupy a NE-trending belt of elongate basins exposed in eastern North America. The basins were filled over a period of 30–40 m.y. spanning the Late Triassic to Early Jurassic, prior to the opening of the north Atlantic Ocean. The sedimentary rocks are here divided into four principal lithofacies. The alluvial-fan facies includes deposits dominated by: (1) debris flows; (2) shallow braided streams; (3) deeper braided streams (with trough crossbeds); or (4) intense bioturbation or hyperconcentrated flows (tabular, unstratified muddy sandstone). The fluvial facies include deposits of: (1) shallow, ephemeral braided streams; (2) deeper, flashflooding, braided streams (with poor sorting and crossbeds); (3) perennial braided rivers; (4) meandering rivers; (5) meandering streams (with high suspended loads); (6) overbank areas or local flood-plain lakes; or (7) local streams and/or colluvium. The lacustrine facies includes deposits of: (1) deep perennial lakes; (2) shallow perennial lakes; (3) shallow ephemeral lakes; (4) playa dry mudflats; (5) salt-encrusted saline mudflats; or (6) vegetated mudflats. The lake margin clastic facies includes deposits of: (1) birdfoot deltas; (2) stacked Gilbert-type deltas; (3) sheet deltas; (4) wave-reworked alluvial fans; or (5) wave-sorted sand sheets. Coal deposits are present in the lake margin clastic and the lacustrine facies of Carnian age (Late Triassic) only in basins of south-central Virginia and North and South Carolina. Eolian deposits are known only from the basins in Nova Scotia and Connecticut. Evaporites (and their pseudomorphs) occur mainly in the northern basins as deposits of saline soils and less commonly of saline lakes, and some evaporite and alkaline minerals present in the Mesozoic rocks may be a result of later diagenesis. These relationships suggest climatic variations across paleolatitudes, more humid to the south where coal beds are preserved, and more arid in the north where evaporites and eolian deposits are common. Fluctuations in paleoclimate that caused lake levels to rise and fall in hydrologically closed basins are preserved as lacustrine cycles of various scales, including major shifts in the Late Triassic from a wet Carnian to an arid Norian. In contrast, fluvial deposits were mainly formed in response to the tectonic evolution of the basins, but to some extent also reflect climatic changes. The Newark Supergroup illustrates the complexity of rift-basin sedimentation and the problems that may arise from using a single modern analog for sedimentary deposition spanning millions of years. It also shows that a tremendous wealth of depositional, climatic, and tectonic information is preserved in ancient rift-basin deposits which can be recovered if the depositional processes of modern rift-basin deposits are understood.

eastern North America↗
USGS2026

Geochemical disequilibrium at the brittle-ductile transition

We investigate the microtextural, microchemical, and isotopic effects of late-stage ductile deformation in quartzite mylonites and kyanite–muscovite–quartz veins from the Raft River shear zone (Utah). Quartz microstructures record pervasive disequilibrium, expressed by unannealed features including undulatory extinction, deformation lamellae, and poorly defined fabrics, typical of waning deformation in shear zones. Microchemical disequilibrium is best preserved in kyanite quartzites, where CL-zoned kyanite records repeated fractures, overgrowth, and mineral precipitation, and in muscovite from muscovite-poor quartzite mylonites that shows minor-element zoning consistent with syn-deformational overgrowth on detrital cores. In contrast, muscovite from muscovite-rich kyanite quartzites exhibits minimal chemical zoning. These microchemical variations correlate with 40 Ar/ 39 Ar age systematics. Chemically zoned muscovite preserves variable single-step ages, including ∼150 Ma ages, reflecting retention of detrital cores. In contrast, syndeformational muscovite consistently yields Miocene ages, indicating recrystallization and new growth below argon closure temperatures that reset inherited isotopic signatures. Similar trends are observed in quartzite mylonites, where increasing quartz recrystallization and stronger crystallographic preferred orientations occur toward deeper structural levels. Together, these observations indicate increasing retrograde deformation and recrystallization with depth in the Raft River shear zone and demonstrate that strain-driven recrystallization exerts a first-order control on muscovite ages. We suggest that apparent thermochronologic gradients in retrograde shear zones may reflect recrystallization gradients rather than temperature gradients. Where cooling limits the thermal driving force for recrystallization, isotopic relics are preserved, and local deformation and fluid availability control re-equilibration. Consequently, isotopic disequilibrium—particularly in the 40 Ar/ 39 Ar system—may be the rule rather than the exception of retrograde tectonic environments.

Idaho, Utah↗
USGS1988

Natural aggregates of the conterminous United States

Crushed stone and sand and gravel are the two main sources of natural aggregates. These materials are commonly used construction materials and frequently can be interchanged with one another. They are widely used throughout the United States, with every State except two producing crushed stone. Together they amount to about half the mining volume in the United States. Approximately 96 percent of sand and gravel and 77 percent of the crushed stone produced in the United States are used in the construction industry. Natural aggregates are widely distributed throughout the United States in a variety of geologic environments. Sand and gravel deposits commonly are the results of the weathering of bedrock and subsequent transportation and deposition of the material by water or ice (glaciers). As such, they commonly occur as river or stream deposits or in glaciated areas as glaciofluvial and other deposits. Crushed stone aggregates are derived from a wide variety of parent bedrock materials. Limestone and other carbonates account for approximately three quarters of the rocks used for crushed stone, with granite and other igneous rocks making up the bulk of the remainder. Limestone deposits are widespread throughout the Central and Eastern United States and are scattered in the West. Granites are widely distributed in the Eastern and Western United States, with few exposures in the Midwest. Igneous rocks (excluding granites) are largely concentrated in the Western United States and in a few isolated localities in the East. Even though natural aggregates are widely distributed throughout the United States, they are not universally available for consumptive use. Some areas are devoid of sand and gravel, and potential sources of crushed stone may be covered with sufficient unconsolidated material to make surface mining impractical. In some areas many aggregates do not meet the physical property requirements for certain uses, or they may contain mineral constituents that react adversely when used as concrete aggregate. In areas where suitable natural aggregate is not available or accessible, it may become necessary to improve the quality of existing aggregate, to import aggregate from outside the area, or to substitute artificial aggregate for natural aggregate. In most cases, all of these alternatives add substantially to the cost of the final product. Even though an area may be blessed with an abundance of aggregate suitable for the intended purpose, existing land uses, zoning, or regulations may preclude commercial exploitation of the aggregate. This report also discusses the aggregate industry in general terms, including exploration, mining, and processing, as well as aggregate production rates. Proper long-range planning based on an understanding of the aggregate industry can help assure adequate supplies of aggregate.

conterminous United States↗
USGS1994

Use of geoelectrical methods in groundwater pollution surveys in a coastal environment

The pollution of coastal aquifers by old landfills can contaminate valuable and scarce water resources in the freshwater lens utilized seasonably by overcrowded communities. The pollutants will ultimately flow into the sea where they may also cause a coastal water pollution problem. We have detected pollution in the freshwater lens from a sanitary landfill near Provincetown, Cape Cod, using the geoelectrical resistivity method. This survey included Schlumberger geoelectrical depth soundings and a horizontal geoelectrical profile using the Wenner configuration. The geoelectrical survey was conducted at a site along Highway 6 where it passes the coastal town of Provincetown and a sanitary landfill that has been in operation since 1954. The depth soundings suggest the characteristic decrease in resistivity vs. depth from the high resistivity of the unsaturated zone to the low resistivity of the saltwater saturated zone. The freshwater lens is clearly identified by the change in slope of the steeply dipping curve of resistivity versus electrode spacing. Interpretations made using a multilayer program, Geomate, resulted in layer resistivities between 460 and 95 ohm?m for the freshwater lens. A comparison with well water resistivities suggests that a layer resistivity of 230 ohm?m or lower is indicative of pollution in the freshwater lens. The results of the geoelectrical depth soundings were confirmed in the Wenner horizontal profile. Both measurements suggest that the pollutants do not spread evenly as one would expect for a homogeneous and isotropic medium. Instead, a preferred channel for the flow of the pollutants is observed along a path from the landfill toward the shoreline. The depth to the saltwater/freshwater interface or, more specifically, to the low resistivity-high resistivity interface appears to be shallow where the freshwater lens is polluted. This was confirmed by pore water well samples that were highly mineralized. The equilibrium postulated by the Ghyben-Herzberg relation appears to be disturbed in the area of aquifer pollution. This rise in the conductivity boundary is caused by the highly mineralized bottom of the contaminant plume that submerges into the saltwater saturated zone. In the area of high freshwater pollution the groundwater can be subdivided into three layers that show a decrease in resistivity with depth. The formation factor, F, defined as the ratio of bulk aquifer resistivity to pore water resistivity, shows unusually high values between 10 and 12. These high values are unexpected for an unconsolidated sand. Pollution residues are suspected to clog the pores and thus to increase the resistivity. It is possible that iron-oxidizing bacteria and the precipitation of dissolved iron or organic pollutants are the cause of the high values of F. If proven correct, these interesting possibilities could lead to future new applications of the geoelectrical resistivity method in contaminant hydroloy.

Journal of Applied Geophysics↗
USGS2001

Geologic map and database of the Roseburg 30' x 60' quadrangle, Douglas and Coos Counties, Oregon

The Roseburg 30' x 60' Quadrangle covers the southeastern margin of the Oregon Coast Range and its tectonic boundary with Mesozoic terranes of the Klamath Mountains (see figures 1 and 2 in pamphlet, also shown on map sheet). The geologic framework of the Roseburg area was established by the pioneering work of Diller (1898), Wells and Peck, (1961) and Ewart Baldwin (1974) and his students (see figure 3 in pamphlet, also shown on map sheet). Baldwin and his students focussed on the history of the Eocene Tyee basin, where the sediments lap across the tectonic boundary with the Mesozoic terranes and record the accretion of the Coast Range basement to the continent. Others have examined the sedimentary fill of the Tyee basin in detail, recognizing the deep marine turbidite facies of the Tyee Formation (Snavely and others, 1964) and proposing several models for the Eocene evolution of the forearc basin (Heller and Ryberg, 1983; Chan and Dott, 1983; Heller and Dickinson, 1985; Molenaar, 1985; see Ryu and others, 1992 for a comprehensive summary). Along the eastern margin of the quadrangle, both the Tyee basin and the Klamath terranes are overlain by Eocene volcanic rocks of the Western Cascade arc (Walker and MacLeod, 1991). The thick Eocene sedimentary sequence of the Tyee basin has significant oil and gas potential (Armentrout and Suek, 1985; Gautier and others, 1993; Ryu and others, 1996). Although 13 deep test wells have been drilled in the Roseburg quadrangle (see figure 2 and table 1 in pamphlet, also shown on map sheet), exploration to date has been hampered by an incomplete understanding of the basin�s tectonic setting and evolution. In response, the Oregon Department of Geology and Mineral Industries (DOGAMI) initiated a five year assessment of the oil and gas potential of the Tyee basin. This map is a product of a cooperative effort by the U. S. Geological Survey, Oregon State University, and DOGAMI to systematically map the sedimentary facies and structure of the Tyee basin. New geologic mapping of twenty-eight 7.5' quadrangles is summarized on the map (see figure 3, also shown on map sheet), and the digital database contains geologic information suitable for both 1:100K and 1:24K scale analysis. DOGAMI has published a compilation and synthesis of previous mapping (Niem and Niem, 1990), a basin-wide sequence stratigraphic model and correlations (Ryu and others, 1992), and a report on the oil and gas potential (Ryu and others, 1996). Readers interested in the oil and gas potential of the Roseburg quadrangle should use the map in combination with Ryu and others (1996) to address specific stratigraphic units and structural plays. Stratigraphic terminology for the Tyee basin adopts the type sections, formation names, and framework of Ryu and others (1992, 1996), which were developed concurrently with the mapping and are recognized throughout the basin. For detailed discussion of nomenclature, type sections, lithology, thickness and distribution, age, contact relationships, and depositional environment of stratigraphic units, the reader is referred to Ryu and others (1992). In this report we focus on the spatial, temporal, and structural relationships between units revealed by geologic mapping. Map unit ages (see figure 4 in pamphlet, also shown on map sheeet) are adjusted slightly from Ryu and others (1992, 1996) to fit new coccolith age determinations (D. Bukry, cited in pamphlet), paleomagnetic polarity data (Simpson, 1977 and new data cited in pamphlet), and the time scale of Berggren and others (1995).

Oregon↗