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At least 829 records · Page 46Linked to original sources
USGS2007

Nitrogen species in soil, sediment, and ground water at a former sewage-treatment wastewater lagoon: Naval Air Station Whidbey Island, Island County, Washington

The potential for contamination of ground water from remnant sewage sludge in re-graded sediments of a deconstructed sewage-treatment lagoon was evaluated. Ground-water levels were measured in temporary drive-point wells, and ground-water samples were collected and analyzed for nutrients and other water-quality characteristics. Composite soil and sediment samples were collected and analyzed for organic carbon and nitrogen species. Multiple lines of evidence, including lack of appreciable organic matter in sediments of the former lagoon, agronomic analysis of nitrogen, the sequestration of nitrogen in the developing soils at the former lagoon, and likely occurrence of peat deposits within the aquifer material, suggest that the potential for substantial additions of nitrogen to ground water beneath the former sewage lagoon resulting from remnant sewage sludge not removed from the former lagoon are small. Concentrations of nitrogen species measured in ground-water samples were small and did not exceed the established U.S. Environmental Protection Agency’s maximum contaminant levels for nitrate (10 milligrams per liter). Concentrations of nitrate in ground-water samples were less than the laboratory reporting limit of 0.06 milligram per liter. Seventy to 90 percent of the total nitrogen present in ground water was in the ammonia form with a maximum concentration of 7.67 milligrams per liter. Concentrations of total nitrogen in ground water beneath the site, which is the sum of all forms of nitrogen including nitrate, nitrite, ammonia, and organic nitrogen, ranged from 1.15 to 8.44 milligrams per liter. Thus, even if all forms of nitrogen measured in ground water were converted to nitrate, the combined mass would be less than the maximum contaminant level. Oxidation-reduction conditions in ground water beneath the former sewage lagoon were reducing. Given the abundant supply of ambient organic carbon in the subsurface and in ground water at the former lagoon, any nitrate that may leach from residual sludge and be transported to ground water with recharge is expected to be quickly denitrified or transformed to nitrite and ammonia under the strongly reducing geochemical conditions that are present. Concentrations of organic carbon, the primary constituent of sewage sludge, in sediments of the former sewage lagoon were less than 1 percent, indicating a near absence of organic matter. The amount of total nitrogen present in the sediments at the former sewage lagoon was only about 25 percent of the amount typically present in developed agricultural soils. The lack of substantial carbon and nitrogen in sediments of the former sewage lagoon indicates that surficial sediments of the former lagoon are essentially devoid of residual sewage sludge. The largest concentration of total nitrogen measured in soil samples from the former sewage lagoon (330 milligrams per kilogram) was used to calculate an estimate of the amount of nitrogen that might be leached from residual sewage sludge by recharge. During the first two years following deconstruction of the former sewage lagoon, the concentration of total nitrogen in recharge leachate might exceed 10 milligrams per liter but the recharge leachate would not likely result in substantial increases in the nitrate concentration in ground water to concentrations greater than the drinking-water maximum contaminant level of 10 milligrams per liter.

Washington↗
USGS2003

Geohydrology, geochemistry, and ground-water simulation-optimization of the Central and West Coast Basins, Los Angeles County, California

Historical ground-water development of the Central and West Coast Basins in Los Angeles County, California through the first half of the 20th century caused large water-level declines and induced seawater intrusion. Because of this, the basins were adjudicated and numerous ground-water management activities were implemented, including increased water spreading, construction of injection barriers, increased delivery of imported water, and increased use of reclaimed water. In order to improve the scientific basis for these water management activities, an extensive data collection program was undertaken, geohydrological and geochemical analyses were conducted, and ground-water flow simulation and optimization models were developed. In this project, extensive hydraulic, geologic, and chemical data were collected from new multiple-well monitoring sites. On the basis of these data and data compiled and collected from existing wells, the regional geohydrologic framework was characterized. For the purposes of modeling, the three-dimensional aquifer system was divided into four aquifer systems?the Recent, Lakewood, Upper San Pedro, and Lower San Pedro aquifer systems. Most pumpage in the two basins is from the Upper San Pedro aquifer system. Assessment of the three-dimensional geochemical data provides insight into the sources of recharge and the movement and age of ground water in the study area. Major-ion data indicate the chemical character of water containing less than 500 mg/L dissolved solids generally grades from calcium-bicarbonate/sulfate to sodium bicarbonate. Sodium-chloride water, high in dissolved solids, is present in wells near the coast. Stable isotopes of oxygen and hydrogen provide information on sources of recharge to the basin, including imported water and water originating in the San Fernando Valley, San Gabriel Valley, and the coastal plain and surrounding hills. Tritium and carbon-14 data provide information on relative ground-water ages. Water with abundant tritium (greater than 8 tritium units) is found in and downgradient from the Montebello Forebay and near the seawater barrier projects, indicating recent recharge. Water with less than measurable tritium is present in, and downgradient from, the Los Angeles Forebay and in most wells in the West Coast Basin. Water from several deep wells was analyzed for carbon-14. Uncorrected estimates of age for these samples range from 600 to more than 20,000 years before present. Chemical and isotopic data are combined to evaluate changes in chemical character along flow paths emanating from the Montebello and Los Angeles Forebays. A four-layer ground-water flow model was developed to simulate steady-state ground-water conditions representative of those in 1971 and transient conditions for the period 1971?2000. Model results indicate increases in ground-water storage in all parts of the study area over the simulated thirty-year period. The model was used to develop a three-dimensional ground-water budget and to assess impacts of two alternative future (2001?25) ground-water development scenarios?one that assumes continued pumping at average current rates and a second that assumes increasing pumping from most wells in the Central Basin. The model simulates stable or slightly increasing water levels for the first scenario and declining water levels (25 to 50 ft in the Central Basin) in the second scenario. Model sensitivity to parameter values and to the assumed Orange County boundary condition was evaluated. Particle tracking was applied to simulate advective transport of water from the spreading ponds, the coastline, and the seawater injection barriers. Particle tracking results indicate that most flow within the Upper San Pedro aquifer system occurs within about 20 percent of the total aquifer system thickness and that virtually all water injected into the seawater barrier projects has flowed inland. The simulation model was linked with optimizatio

California↗
USGS1997

Geohydrology and Numerical Simulation of the Ground-Water Flow System of Molokai, Hawaii

A two-dimensional, steady-state, areal ground-water flow model was developed for the island of Molokai, Hawaii, to enhance the understanding of (1) the conceptual framework of the ground-water flow system, (2) the distribution of aquifer hydraulic properties, and (3) the regional effects of ground-water withdrawals on water levels and coastal discharge. The model uses the finite-element code AQUIFEM-SALT, which simulates flow of fresh ground water in systems that may have a freshwater lens floating on denser underlying saltwater. Model results are in agreement with the general conceptual model of the flow system on Molokai, where ground water flows from the interior, high-recharge areas to the coast. The model-calculated ground-water divide separating flow to the northern and southern coasts lies to either the north or the south of the topographic divide but is generally not coincident with the topographic divide. On the basis of model results, the following horizontal hydraulic conductivities were estimated: (1) 1,000 feet per day for the dike-free volcanic rocks of East and West Molokai, (2) 100 feet per day for the marginal dike zone of the East Molokai Volcano, (3) 2 feet per day for the West Molokai dike complex, (4) 0.02 feet per day for the East Molokai dike complex, and (5) 500 feet per day for the Kalaupapa Volcanics. Three simulations to determine the effects of proposed ground-water withdrawals on water levels and coastal discharge, relative to model-calculated water levels and coastal discharge for 1992-96 withdrawal rates, show that the effects are widespread. For a withdrawal rate of 0.337 million gallons per day from a proposed well about 4 miles southeast of Kualapuu and 3 miles north of Kamiloloa, the model-calculated drawdown of 0.01 foot or more extends 4 miles southeast and 6 miles northwest from the well. For a withdrawal rate of 1.326 million gallons per day from the same well, the model-calculated drawdown of 0.01 foot or more extends 6 miles southeast and 9 miles northwest from the well. In a third scenario, the withdrawal rate from an existing well near Kualapuu was increased by 0.826 million gallons per day. The model-calculated drawdown of 0.01 foot or more extends 6 miles southeast and 8 miles northwest from the well. In all scenarios, coastal discharge is reduced by an amount equal to the additional withdrawal. Additional data needed to improve the understanding of the ground-water flow system on Molokai include: (1) a wider spatial distribution and longer temporal distribution of water-levels, (2) independent estimates of hydraulic conductivity, (3) improved recharge estimates, (4) information about the vertical distribution of salinity in ground water, (5) streamflow data at additional sites, and (6) improved information about the subsurface geology.

Water-Resources Investigations Report↗
USGS2008

Ground-Water Conditions and Studies in the Albany Area of Dougherty County, Georgia, 2007

The U.S. Geological Survey (USGS) has been working with the Albany Water, Gas, and Light Commission to monitor ground-water quality and availability since 1977. This report presents an overview of ground-water conditions and studies in the Albany area of Dougherty County, Georgia, during 2007. Historical data are also presented for comparison with 2007 data. Ongoing monitoring activities include continuous water-level recording in 24 wells and monthly water-level measurements in 5 wells. During 2007, water levels in 21 of the continuous-recording wells were below normal, corresponding to lower than average rainfall. Ground-water samples collected from the Upper Floridan aquifer indicate that nitrate levels have decreased or remained about the same since 2006. Water samples were collected from the Flint River and wells at the Albany wellfield, and data were plotted on a trilinear diagram to show the percent composition of selected major cations and anions. Ground-water constituents (major cations and anions) of the Upper Floridan aquifer at the Albany wellfield are distinctly different from those in the water of the Flint River. To improve the understanding of the ground-water flow system and nitrate movement in the Upper Floridan aquifer, the USGS is developing a ground-water flow model in the southwestern Albany area of Georgia. The model is being calibrated to simulate periods of dry (October 1999) and relatively wet (March 2001) hydrologic conditions. Preliminary water-level simulations indicate a generally good fit to measured water levels.

Georgia↗
USGS2003

Estimating Ground-Water Recharge from Precipitation on Whidbey and Camano Islands, Island County, Washington, Water Years 1998 and 1999

Ground-water recharge from precipitation to unconsolidated deposits on Whidbey and Camano Islands, Washington, was estimated for water years 1998-99 using a near-surface water-balance method and a chloride mass-balance method. A daily near-surface water-balance method, the Deep Percolation Model (DPM), was used to simulate water budgets for October 1, 1997 through September 30, 1999 (water years 1998-99) for six small drainage basins?four on Whidbey Island and two on Camano Island. Adjusted parameters from the DPM for each small basin were then used in island-wide DPM simulations. A spatial distribution of annual recharge was simulated for each island, with island averages of 5.71 inches per year for Whidbey Island and 5.98 inches per year for Camano Island. The spatial distribution of simulated annual recharge for each island reflects variations in precipitation amounts and the distribution of surficial materials. DPM results indicate that recharge generally is higher in areas underlain by coarse-grained deposits (outwash) than in areas underlain by fine-grained deposits (till). A chloride mass-balance method was used to estimate combined recharge to unconsolidated deposits on Whidbey and Camano Islands. The average combined recharge for Whidbey and Camano Islands estimated by this method was 2.00 inches per year. The range of chloride concentrations in ground-water samples from selected wells indicates that the average recharge to unconsolidated deposits ranges from 0.78 to 7.81 inches per year. Sources of chloride in ground water other than from the atmosphere would cause recharge estimated by the chloride mass-balance method to be less than the actual recharge, therefore, these estimates may represent lower limits.

Water-Resources Investigations Report↗
USGS1995

Assessment of information on ground-water/surface-water interactions in the northern midcontinent

Ground-water/surface-water interactions are important to the hydrology of shallow aquifers, streams, lakes, and wetlands. Information on ground-water/surface-water interactions in the northern midcontinent was assessed. The ground-water/surface-water interactions in physiographic and climatic areas that contain many wetlands differed from the interactions in areas that consisted predominantly of alluvial aquifers along large streams. In both types of areas, however, the interactions are complex. The distribution of shallow ground-water observation wells in the northern midcontinent and the frequency of measurement were evaluated. Most shallow wells are located adjacent to major streams, especially in areas where wetlands are not a dominant surface-water feature. The frequency of measurement was inconsistent between states.

Conference Paper↗
USGS2001

Ground-water discharge determined from estimates of evapotranspiration, Death Valley regional flow system, Nevada and California

The Death Valley regional flow system (DVRFS) is one of the larger ground-water flow systems in the southwestern United States and includes much of southern Nevada and the Death Valley region of eastern California. Centrally located within the ground-water flow system is the Nevada Test Site (NTS). The NTS, a large tract covering about 1,375 square miles, historically has been used for testing nuclear devices and currently is being studied as a potential repository for the long-term storage of high-level nuclear waste generated in the United States. The U.S. Department of Energy, as mandated by Federal and State regulators, is evaluating the risk associated with contaminants that have been or may be introduced into the subsurface as a consequence of any past or future activities at the NTS. Because subsurface contaminants can be transported away from the NTS by ground water, components of the ground-water budget are of great interest. One such component is regional ground-water discharge. Most of the ground water leaving the DVRFS is limited to local areas where geologic and hydrologic conditions force ground water upward toward the surface to discharge at springs and seeps. Available estimates of ground-water discharge are based primarily on early work done as part of regional reconnaissance studies. These early efforts covered large, geologically complex areas and often applied substantially different techniques to estimate ground-water discharge. This report describes the results of a study that provides more consistent, accurate, and scientifically defensible measures of regional ground-water losses from each of the major discharge areas of the DVRFS. Estimates of ground-water discharge presented in this report are based on a rigorous quantification of local evapotranspiration (ET). The study identifies areas of ongoing ground-water ET, delineates different ET areas based on similarities in vegetation and soil-moisture conditions, and determines an ET rate for each delineated area. Each area, referred to as an ET unit, generally consists of one or more assemblages of local phreatophytes or a unique moist soil environment. Ten ET units are identified throughout the DVRFS based on differences in spectral-reflectance characteristics. Spectral differences are determined from satellite imagery acquired June 21, 1989, and June 13, 1992. The units identified include areas of open playa, moist bare soils, sparse to dense vegetation, and open water. ET rates estimated for each ET unit range from a few tenths of a foot per year for open playa to nearly 9 feet per year for open water. Mean annual ET estimates are computed for each discharge area by summing estimates of annual ET from each ET unit within a discharge area. The estimate of annual ET from each ET unit is computed as the product of an ET unit's acreage and estimated ET rate. Estimates of mean annual ET range from 450 acre-feet in the Franklin Well area to 30,000 acre-feet in Sarcobatus Flat. Ground-water discharge is estimated as annual ET minus that part of ET attributed to local precipitation. Mean annual ground-water discharge estimates range from 350 acre-feet in the Franklin Well area to 18,000 acre-feet in Ash Meadows. Generally, these estimates are greater for the northern discharge areas (Sarcobatus Flat and Oasis Valley) and less for the southern discharge areas (Franklin Lake, Shoshone area, and Tecopa/ California Valley area) than those previously reported.

California;Nevada↗
USGS2000

Effects of alternative Missouri River management plans on ground-water levels in the lower Missouri River flood plain

In 1998, the U.S. Army Corps of Engineers (USACE) proposed eight Alternative River Management Plans (ARMPs) for managing reservoir levels and water-release rates for the Missouri River. The plans include the Current Water Control Plan (CWCP), Conservation 18, 31, and 44 (C18, C31, and C44) that provide different levels of water conservation in the reservoirs during droughts, Fish and Wildlife 10, 15, and 20 (FW10, FW15, and FW20) that vary water-release rates to provide additional fish and wildlife benefits, and Mississippi River 66 (M66) that maintains a 66,000 cubic feet per second discharge at St. Louis to provide navigation support for the Mississippi River. Releases from Gavin?s Point Dam affect both the lower 1,305 kilometers of the Missouri River and ground-water levels in the lower Missouri River flood plain. Changes in the magnitude and timing of ground-water-level fluctuations in response to changes in river management could impact agriculture, urban development, and wetland hydrology along the lower Missouri River flood plain. This study compared simulated ground-water altitude and depth to ground water for the CWCP in the Missouri River alluvial aquifer near the Kansas City area between 1970 and 1980 with each ARMP, determined the average change in simulated ground-water level for selected river-stage flood pulses at selected distances from the river, and compared simulated flood pulse, ground-water responses with actual flood pulse, and ground-water responses measured in wells located at three sites along the lower Missouri River flood plain.For the model area, the percent total shallow ground-water area (depth to ground water less than 0.3048 meter) is similar for each ARMP because of overall similarities in river flow between ARMPs. The percent total shallow ground-water area for C18 is the most similar to CWCP followed by C31, M66, C44, FW10, FW15, and FW20. ARMPs C18, C31, C44, and M66 do not cause large changes in the percent shallow ground-water area when compared to CWCP. FW10 and FW15 each cause a spring increase and a summer decrease in the shallow ground-water area. FW20 has a larger spring increase in the shallow ground-water area, but the largest decrease is delayed into November. Analysis of daily changes between the ARMPs indicate large differences can exist in both duration and extent of shallow ground-water areas.A series of 12 flood pulses of 0.5-, 1-, and 3-meters in magnitude and 1-, 8-, 32-, and 128-days in duration were simulated using the ground-water flow model. A ground-water response factor (GWRF, defined as the change in ground-water level at a known distance from the river, at a specified time after the beginning of a flood pulse divided by the magnitude of the flood pulse) was determined daily for selected distances from the river. The GWRF multiplied by the magnitude of the flood pulse can be used to estimate the change in ground-water level at a known time after the beginning of a flood pulse for a known distance from the river. Flood-pulse simulation results indicate the relatively small impact on ground-water levels of small river-stage fluctuations of short duration as might occur daily or weekly. The larger impact on ground-water levels from larger river-stage increases of longer duration indicate the importance of river management flow releases, seasonal changes in river flow, and the effects of continuous high-river stage for long periods on ground-water levels of the lower Missouri River flood plain.A comparison of model results to well hydrographs from three areas along the lower Missouri River flood plain was used to determine how closely the simulated GWRFs matched the measured GWRFs for similar flood pulses and the transferability of GWRFs to other parts of the lower Missouri River flood plain. The comparison between the measured and simulated ground-water responses indicate that the simulated ground-water responses can provide a reasonable estimate of the ground-water resp

Water-Resources Investigations Report↗
USGS1944

Ground-water resources of the Houston district, Texas

This report covers the current phase of an investigation of the supply of ground water available for the Houston district and adjacent region, Texas,- that has been in progress during the past 10 years. The field operations included routine inventories of pumpage, measurements of water levels in observation wells and collection of other hydrologic data, pumping tests on 21 city-owned wells to determine coefficients of permeability and storage, and the drilling of 13 deep test wells in unexplored parts of the district. Considerable attention has been given to studies of the location of areas or beds of sand that contain salt water. The ground water occurs in beds of sand, sandstone, and gravel of Miocene, Pliocene, and Pleistocene age. These formations crop out in belts that dip southeastward from their outcrop areas and are encountered by wells at progressively greater depths toward the southeast. The beds throughout the section are lithologically similar, and there is little agreement among geologists as to their correlation. -In this investigation, however, the sediments, penetrated by the wells are separated into six zones, chiefly on the basis of electrical logs. Most of the water occurs in zone 3, which ranges in thickness from 800 to 1,200 feet. Large quantities of ground water are pumped in three areas in the Houston district, as follows: The Houston tromping area, which includes Houston and the areas immediately adjacent; the Pasadena pumping area, which includes the industrial section extending along the ship channel from the Houston city limits eastward to Deer Park; and the Katy pumping area, an irregular-shaped area of several hundred square miles, which is roughly centered around the town of Katy, 30 miles west of Houston. In 1930 the total combined withdrawal of ground water in the Houston and Pasadena pumping areas averaged about 50 million gallons a day. It declined somewhat during 1932 and 1933 and then gradually increased, until in 1935 the total pumpage was about the same as it was in 1930. About March 1, 1937, the pumpage was increased by about 40 percent, when new wells near Pasadena were put into operation. During 1940 it is estimated that the total pumpage in the Houston and Pasadena areas averaged about 79 million gallons a day, an increase of about 65 percent over the pumpage in 1935. About 25 million gallons of this increase has occurred in the Pasadena area. In the Katy rice-growing area the pumpage in 1935 was about 14 million gallons a day; in 1937 it was about 30 million gallons a day; in 1939 about 40 million gallons a day; and in 1940 about 45 million gallons a day. In 1940 the estimated total pumpage from the Houston, Pasadena, and Katy pumping areas was about 124 million gallons a day, or twice as much as it was in 1935. The increase in pumping at Pasadena in the spring-of 1937 caused the water leveling wells in the Houston and Pasadena areas, which had not varied materially for about 7 years, to decline at a rapid rate. Further increases in the pumping both at Houston and Pasadena in 1939 and 1940 has caused further substantial decline. The water levels in wells in the Katy rice-growing area also declined materially. The evidence points to the probability that in all parts of the Houston district, except the Katy rice-growing area, the rainfall is recharging the aquifers at a rate greater than that at which the water is transmitted down the dip. In the Katy area the recharge is insufficient to balance the joint discharge by transmission down the dip and withdrawal from rice-irrigating wells. The average coefficient of transmissibility was. calculated as 160,000 gallons a day. On the basis of these estimates the inflow in February 1940 across the artesian contour 10 feet below sea level (see pl. 10) was computed as 72 million gallons a day. The amount of water taken out of artesian storage in the 300-square mile area within the -10 contour during the period February 1939 to February

Water Supply Paper↗
USGS1999

Geostatistical applications in ground-water modeling in south-central Kansas

This paper emphasizes the supportive role of geostatistics in applying ground-water models. Field data of 1994 ground-water level, bedrock, and saltwater-freshwater interface elevations in south-central Kansas were collected and analyzed using the geostatistical approach. Ordinary kriging was adopted to estimate initial conditions for ground-water levels and topography of the Permian bedrock at the nodes of a finite difference grid used in a three-dimensional numerical model. Cokriging was used to estimate initial conditions for the saltwater-freshwater interface. An assessment of uncertainties in the estimated data is presented. The kriged and cokriged estimation variances were analyzed to evaluate the adequacy of data employed in the modeling. Although water levels and bedrock elevations are well described by spherical semivariogram models, additional data are required for better cokriging estimation of the interface data. The geostatistically analyzed data were employed in a numerical model of the Siefkes site in the project area. Results indicate that the computed chloride concentrations and ground-water drawdowns reproduced the observed data satisfactorily.This paper emphasizes the supportive role of geostatistics in applying ground-water models. Field data of 1994 ground-water level, bedrock, and saltwater-freshwater interface elevations in south-central Kansas were collected and analyzed using the geostatistical approach. Ordinary kriging was adopted to estimate initial conditions for ground-water levels and topography of the Permian bedrock at the nodes of a finite difference grid used in a three-dimensional numerical model. Cokriging was used to estimate initial conditions for the saltwater-freshwater interface. An assessment of uncertainties in the estimated data is presented. The kriged and cokriged estimation variances were analyzed to evaluate the adequacy of data employed in the modeling. Although water levels and bedrock elevations are well described by spherical semivariogram models, additional data are required for better cokriging estimation of the interface data. The geostatistically analyzed data were employed in a numerical model of the Siefkes site in the project area. Results indicate that the computed chloride concentrations and ground-water drawdowns reproduced the observed data satisfactorily.

Journal of Hydrologic Engineering↗
USGS2003

Ground-Water Resources in the Black Hills Area, South Dakota

The availability of ground-water resources in the Black Hills area is influenced by many factors including location, local recharge and ground-water flow conditions, and structural features. Thus, the availability of ground water can be extremely variable throughout the Black Hills area, and even when water is available, it may not be suitable for various uses depending on the water quality. The major bedrock aquifers in the Black Hills area are the Deadwood, Madison, Minnelusa, Minnekahta, and Inyan Kara aquifers. Minor bedrock aquifers occur in other hydrogeologic units, including confining units, due to fracturing and interbedded permeable layers. Various information and maps are presented in this report that describe availability and quality of ground-water resources in the Black Hills area. However, there is no guarantee of obtaining usable water at any location due to the extreme potential variability in conditions that can affect the availability and quality of ground water in the area. Maps presented in this report include the distribution of hydrogeologic units; depth to the top of the five formations that contain major aquifers; thickness of the five formations that contain major aquifers; potentiometric maps for the five major aquifers; saturated thickness of the Madison and Minnelusa aquifers; water temperature in the Madison aquifer; specific conductance in the Madison, Minnelusa, and Inyan Kara aquifers; hardness in the Inyan Kara aquifer; sulfate concentrations in the Minnelusa aquifer; and radon concentrations in the Deadwood aquifer. Water quality of the major aquifers generally is very good in and near outcrop areas but deteriorates progressively with distance from the outcrops. In the Minnelusa aquifer, an abrupt increase in concentrations of dissolved sulfate occurs downgradient from outcrop areas, where a zone of active anhydrite dissolution occurs. Most limitations for the use of ground water are related to aesthetic qualities associated with hardness and high concentrations of chloride, sulfate, sodium, manganese, and iron. Very few health-related limitations exist for ground water; most limitations are for radionuclides, such as radon and uranium. In addition, high concentrations of arsenic have been measured in a few samples from the Minnelusa aquifer.

Water-Resources Investigations Report↗
USGS1994

Effects of ground-water chemistry and flow on quality of drainflow in the western San Joaquin Valley, California

Chemical and geohydrologic data were used to assess the effects of regional ground-water flow on the quality of on-farm drainflows in a part of the western San Joaquin Valley, California. Shallow ground water beneath farm fields has been enriched in stable isotopes and salts by partial evaporation from the shallow water table and is being displaced by irrigation, drainage, and regional ground-water flow. Ground-water flow is primarily downward in the study area but can flow upward in some down- slope areas. Transitional areas exist between the downward and upward flow zones, where ground water can move substantial horizontal distances (0.3 to 3.6 kilometers) and can require 10 to 90 years to reach the downslope drainage systems. Simulation of ground-water flow to drainage systems indicates that regional ground water contributes to about 11 percent of annual drainflow. Selenium concentrations in ground water and drainwater are affected by geologic source materials, partial evaporation from a shallow water table, drainage-system, and regional ground-water flow. Temporal variability in drainflow quality is affected in part by the distribution of chemical constituents in ground water and the flow paths to the drainage systems. The mass flux of selenium in drainflows, or load, generally is proportional to flow, and reductions in drainflow quantity should reduce selenium loads over the short-term. Uncertain changes in the distribution of ground-water quality make future changes in drainflow quality difficult to quantify.

Open-File Report↗
USGS2007

Rock-Bound Arsenic Influences Ground Water and Sediment Chemistry Throughout New England

The information in this report was presented at the Northeastern Region Geological Society of America meeting held March 11-14, 2007, in Durham, New Hampshire. In the New England crystalline bedrock aquifer, concentrations of arsenic that exceed the drinking water standard of 10 ?g/L occur most frequently in ground water from wells sited in specific metamorphic and igneous rock units. Geochemical investigations indicate that these geologic units typically have moderately elevated whole-rock concentrations of arsenic compared to other rocks in the region. The distribution of ground water wells with As > 5 ?g/L has a strong spatial correlation with specific bedrock units where average whole-rock concentrations of arsenic exceed 1.1 mg/kg and where geologic and geochemical factors produce high pH ground water. Arsenic concentrations in stream sediments collected from small drainages reflect the regional distribution of this natural arsenic source and have a strong correlation with both rock chemistry and the distribution of bedrock units with elevated arsenic chemistry. The distribution of ground water wells with As > 5 ?g/L has a strong spatial correlation with the distribution of stream sediments where concentrations of arsenic exceed 6 mg/kg. Stream sediment chemistry also has a weak correlation with the distribution of agricultural lands where arsenical pesticides were used on apple, blueberry, and potato crops. Elevated arsenic concentrations in bedrock wells, however, do not correlate with agricultural areas where arsenical pesticides were used. These results indicate that both stream sediment chemistry and the solubility and mobility of arsenic in ground water in bedrock are influenced by host-rock arsenic concentrations. Stream sediment chemistry and the distribution of geologic units have been found to be useful parameters to predict the areas of greatest concern for elevated arsenic in ground water and to estimate the likely levels of human exposure to elevated arsenic in drinking water in New England. However, the extreme local variability of arsenic concentrations in ground water from these rock sources indicate that arsenic concentrations in ground water are affected by other factors in addition to arsenic concentrations in rock.

Open-File Report↗
USGS2009

Ground-water quality data in the San Francisco Bay study unit, 2007: Results from the California GAMA Program

Ground-water quality in the approximately 620-square-mile San Francisco Bay study unit (SFBAY) was investigated from April through June 2007 as part of the Priority Basin project of the Ground-Water Ambient Monitoring and Assessment (GAMA) Program. The GAMA Priority Basin project was developed in response to the Groundwater Quality Monitoring Act of 2001, and is being conducted by the U.S. Geological Survey (USGS) in cooperation with the California State Water Resources Control Board (SWRCB). The study was designed to provide a spatially unbiased assessment of raw ground-water quality, as well as a statistically consistent basis for comparing water quality throughout California. Samples in SFBAY were collected from 79 wells in San Francisco, San Mateo, Santa Clara, Alameda, and Contra Costa Counties. Forty-three of the wells sampled were selected using a spatially distributed, randomized grid-based method to provide statistical representation of the study unit (grid wells). Thirty-six wells were sampled to aid in evaluation of specific water-quality issues (understanding wells). The ground-water samples were analyzed for a large number of synthetic organic constituents (volatile organic compounds [VOC], pesticides and pesticide degradates, pharmaceutical compounds, and potential wastewater-indicator compounds), constituents of special interest (perchlorate and N-nitrosodimethylamine [NDMA]), naturally occurring inorganic constituents (nutrients, major and minor ions, trace elements, chloride and bromide isotopes, and uranium and strontium isotopes), radioactive constituents, and microbial indicators. Naturally occurring isotopes (tritium, carbon-14 isotopes, and stable isotopes of hydrogen, oxygen, nitrogen, boron, and carbon), and dissolved noble gases (noble gases were analyzed in collaboration with Lawrence Livermore National Laboratory) also were measured to help identify the source and age of the sampled ground water. Quality-control samples (blank samples, replicate samples, matrix spike samples) were collected for approximately one-third of the wells, and the results for these samples were used to evaluate the quality of the data for the ground-water samples. Assessment of the quality-control information from the field blanks resulted in applying “V” codes to approximately 0.1 percent of the data collected for ground-water samples (meaning a constituent was detected in blanks as well as the corresponding environmental data). See the Appendix section “Quality-Control-Sample Results.” This study did not attempt to evaluate the quality of water delivered to consumers; after withdrawal from the ground, water typically is treated, disinfected, and (or) blended with other waters to maintain acceptable water quality. Regulatory thresholds apply to treated water that is delivered to the consumer, not to raw ground water. However, to provide some context for the results, concentrations of constituents measured in the raw ground water were compared with regulatory and non-regulatory health-based thresholds established by the U.S. Environmental Protection Agency (USEPA) and California Department of Public Health (CDPH) and thresholds established for aesthetic concerns (secondary maximum contaminant levels, SMCL-CA) by CDPH. VOCs were detected in about one-half of the grid wells, while pesticides were detected in about one-fifth of the grid wells. Concentrations of all VOCs and pesticides detected in samples from all SFBAY wells were below health-based thresholds. No pharmaceutical compounds were detected in any SFBAY well. One potential wastewater-indicator compound, caffeine, was detected in one grid well in SFBAY. Concentrations of most trace elements and nutrients detected in samples from all SFBAY wells were below health-based thresholds. Exceptions include nitrate, detected above the USEPA maximum contaminant level (MCL-US) in 3samples; arsenic, above the USEPA maximum contaminant level (MCL-US) in 3 samples; cadmium, above the MCL-US in 1 sample; boron, above the CDPH notification level (NL-CA) in 2 samples; and strontium, above the USEPA lifetime health advisory level (HAL-US) in 2 samples. The radioactive constituent radon-222 was detected above the proposed MCL-US in two grid wells, but no wells had detections above the proposed alternative MCL-US. Most of the samples from all SFBAY wells had concentrations of major ions, total dissolved solids, and trace elements below the non-enforceable thresholds set for aesthetic concerns. Six or fewer samples contained chloride, sulfate, or iron at concentrations above the SMCL-CA thresholds. No microbial indicators were detected in SFBAY grid wells.

California↗
USGS1995

Anomalous gold, antimony, arsenic, and tungsten in ground water and alluvium around disseminated gold deposits along the Getchell Trend, Humboldt County, Nevada

Ground-water, alluvium, and bedrock samples were collected from drill holes near the Chimney Creek, Preble, Summer Camp, and Rabbit Creek disseminated gold deposits in northern Nevada to determine if Au and ore-related metals, such as As, Sb, and W, are being hydromorphically mobilized from buried mineralized rock, and, if they are, to determine whether the metal-enriched ground water is reacting with the alluvial material to produce a geochemical anomaly within the overburden. Results of chemical analyses of drill-hole water samples show the presence of hydromorphic dispersion anomalies of Au, As, Sb, and W in the local ground-water systems associated with these deposits. Background concentrations for Au in the ground water up-gradient from the buried deposits was less than 1 nanogram per liter (ng/L), near the deposits the Au values ranged from 1 to 140 ng/ L, and in drill holes penetrating mineralized rock, concentrations of Au in the ground water were as high as 4700 ng/L. Highest concentrations of Au were found in ground-water samples where the measured E h and the distribution of arsenic species, arsenite [As(III)] and arsenate [As(V)], indicated oxidizing redox potentials. Similarly, As, Sb, and W concentrations in the ground water near the deposits were significantly enriched relative to concentrations in the ground water up-gradient from the deposits. In general, however, the highest concentrations of As, Sb, and W occurred in ground-water samples where the measured E h and the distribution of arsenic species indicated reducing conditions. Arsenic concentrations ranged from 9 to 710 micrograms per liter (μg/L); Sb, from less than 0.1 to 250 μg/L; and W, from 1 to 260 μg/L. In addition, analysis of sequential dissolution and extraction solutions of drill cuttings of alluvium and bedrock indicate geochemical anomalies of gold and ore-related metals in the overburden at depths corresponding to the location of the present-day water table. This relationship suggests that water-rock reactions around these buried deposits are active and that this information could be very useful in exploration programs for concealed disseminated gold deposits.

Journal of Geochemical Exploration↗
USGS1999

Age, double porosity, and simple reaction modifications for the MOC3D ground-water transport model

This report documents modifications for the MOC3D ground-water transport model to simulate (a) ground-water age transport; (b) double-porosity exchange; and (c) simple but flexible retardation, decay, and zero-order growth reactions. These modifications are incorporated in MOC3D version 3.0. MOC3D simulates the transport of a single solute using the method-of-characteristics numerical procedure. The age of ground water, that is the time since recharge to the saturated zone, can be simulated using the transport model with an additional source term of unit strength, corresponding to the rate of aging. The output concentrations of the model are in this case the ages at all locations in the model. Double porosity generally refers to a separate immobile-water phase within the aquifer that does not contribute to ground-water flow but can affect solute transport through diffusive exchange. The solute mass exchange rate between the flowing water in the aquifer and the immobile-water phase is the product of the concentration difference between the two phases and a linear exchange coefficient. Conceptually, double porosity can approximate the effects of dead-end pores in a granular porous media, or matrix diffusion in a fractured-rock aquifer. Options are provided for decay and zero-order growth reactions within the immobile-water phase. The simple reaction terms here extend the original model, which included decay and retardation. With these extensions, (a) the retardation factor can vary spatially within each model layer, (b) the decay rate coefficient can vary spatially within each model layer and can be different for the dissolved and sorbed phases, and (c) a zero-order growth reaction is added that can vary spatially and can be different in the dissolved and sorbed phases. The decay and growth reaction terms also can change in time to account for changing geochemical conditions during transport. The report includes a description of the theoretical basis of the model, a detailed description of input requirements and output options, and the results of model testing and evaluation. The model tests illustrate use of these modifications and demonstrate that accurate solutions can be obtained for these simple cases. Two test cases have no dispersion, illustrating the suitability of this method-of-characteristics model for simulation of advection-dominated transport in ground water.

Water-Resources Investigations Report↗
USGS1998

Effects of farming systems on ground-water quality at the management systems evaluation area near Princeton, Minnesota, 1991-95

Ground-water quality in an unconfined sand and gravel aquifer was monitored during 1991-95 at the Minnesota Management Systems Evaluation Area (MSEA) near Princeton, Minnesota. The objectives of the study were to: (1) describe the effects of three farming systems on groundwater quality, and (2) evaluate the factors affecting ground-water quality and transport of agricultural chemicals at the site. Concentrations of nitrate nitrogen (nitrate-N) in the upper 1 meter (m) of the saturated zone were greatest beneath the two cropped areas having a potato-sweet corn annual rotation (median concentrations of 23 and 22 mg/L). Concentrations of nitrate-N were least beneath a cropped area having a field cornsoybean annual rotation (median of 14 mg/L); another cropped area having the field corn-soybean rotation had similar nitrate-N concentrations to those beneath a cropped area having field corn in consecutive years (continuous corn)(medians of 17 mg/L). Concentrations of atrazine plus metabolites de-ethylatrazine (DEA) and de-isopropylatrazine (DIA), atrazine plus metabolites, were significantly greater during 1994-95 than during 1992- 93 beneath all cropped areas in the upper 1 m of the saturated zone. Concentrations of atrazine plus metabolites during 1994-95 were greatest beneath the continuous corn (median of 1.07 ( μ g/L), intermediate beneath one cropped area with the potato-sweet corn rotation (median of 0.37 μ g/L), and least beneath the other cropped area with the potato-sweet corn rotation, the field corn-soybean rotation, and background areas (medians ranging from 0.11 to 0.21 μ g/L), for which concentrations were not significantly different. Concentrations of atrazine plus metabolites during 1992-93 were mostly similar beneath the different cropped areas and background areas. DEA was the predominant atrazine-metabolite detected in ground water; the average DEA to atrazine ratio was 8.0. The herbicides metribuzin, alachlor, and metolachlor were rarely detected in ground water at trace levels and could not be linked to the MSEA farming systems, with the exception of metribuzin detections during 1993-94 at concentrations of 0.14-1.24 ( μ g/L beneath one cropped area where metribuzin was applied to potatoes. Peak concentrations of chloride and bromide tracers were usually detected in the upper 2 m of the saturated zone 11 to 19 months after application. Peak concentrations of nitrate-N and atrazine plus metabolites were usually detected about 13 to 27 months and 2 years after application, respectively. The estimated proportion of applied nitrogen that reached ground water ranged from about 13 to 50 percent with an average of 30 percent. Differences in the concentrations of nitrate-N in ground water between different cropped areas were related to varying nitrogen application rates, timing of nitrogen application, timing of recharge in relation to crop rotation, and differences in nitrogen uptake by crops. In order of importance, plant uptake and leaching to ground water likely account for most of the nitrogen applied. Denitrification likely is an important mechanism affecting nitrate-N concentrations at depths greater than 2 m below the water table. The proportion of applied atrazine in ground water, detected as atrazine or its metabolites, ranged from 0 to about 1 percent with an average of 0.37 percent. The small proportion of applied atrazine detected in ground water indicates that atrazine was predominantly affected by processes occurring in the soil such as adsorption and degradation. Concentrations of atrazine plus metabolites were related to application rates.

Minnesota↗
USGS2006

Hydrology and simulation of ground-water flow, Lake Point, Tooele County, Utah

Water for new residential development in Lake Point, Utah may be supplied by public-supply wells completed in consolidated rock on the east side of Lake Point. Ground-water flow models were developed to help understand the effect the proposed withdrawal will have on water levels, flowing-well discharge, spring discharge, and ground-water quality in the study area. This report documents the conceptual and numerical ground-water flow models for the Lake Point area. The ground-water system in the Lake Point area receives recharge from local precipitation and irrigation, and from ground-water inflow from southwest of the area. Ground water discharges mostly to springs. Discharge also occurs to evapotranspiration, wells, and Great Salt Lake. Even though ground water discharges to Great Salt Lake, dense salt water from the lake intrudes under the less-dense ground water and forms a salt-water wedge under the valley. This salt water is responsible for some of the high dissolved-solids concentrations measured in ground water in Lake Point. A steady-state MODFLOW-2000 ground-water model of Tooele Valley adequately simulates water levels, ground-water discharge, and ground-water flow direction observed in Lake Point in 1969 and 2002. Simulating an additional 1,650 acre-feet per year withdrawal from wells causes a maximum projected drawdown of about 550 feet in consolidated rock near the simulated wells and drawdown exceeding 80 feet in an area encompassing most of the Oquirrh Mountains east of Lake Point. Drawdown in most of Lake Point ranges from 2 to 10 ft, but increases to more than 40 feet in the areas proposed for residential development. Discharge to Factory Springs, flowing wells, evapotranspiration, and Great Salt Lake is decreased by about 1,100 acre-feet per year (23 percent). The U.S. Geological Survey SUTRA variable-density ground-water-flow model generates a reasonable approximation of 2002 dissolved-solids concentration when simulating 2002 withdrawals. At most locations with measured dissolved-solids concentration in excess of 1,000 milligrams per liter, the model simulates salt-water intrusion with similar concentrations. Simulating an additional 1,650 acre-feet per year withdrawal increased simulated dissolved-solids concentration by 200 to 1,000 milligrams per liter throughout much of Lake Point and near Fac­tory Springs at a depth of about 250 to 300 feet below land surface. The increase in dissolved-solids concentration with increased withdrawals is greater at a depth of about 700 to 800 feet and exceeds 1,000 milligrams per liter throughout most of Lake Point. At the north end of Lake Point, increases exceed 10,000 milligrams per liter.

Utah↗