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Alaska natural gas hydrate production testing: Test site selection, characterization and testing operations

This Interagency Agreement supports the U.S. Department of Energy (DOE) and its research partners in understanding, predicting, and testing the recoverability and potential production characteristics of onshore natural gas hydrate in the Greater Prudhoe Bay area on the Alaska North Slope (ANS: Prudhoe Bay, Kuparuk River, and Milne Point areas) or other areas deemed suitable by DOE and USGS for potential long-term production testing of gas hydrate. Researchers will accomplish these tasks by evaluating the occurrence and resource potential of the known gas hydrate accumulations in the Eileen trend. Geologic, geochemical, and geophysical (2-D and 3-D seismic surveys) data from northern Alaska and other data sources, including wireline and mud log surveys of wells of opportunity, will be used to assess the occurrence and nature of the known gas hydrate accumulations. The project involves two primary areas of effort: the geologic and engineering assessment of the Eileen gas-hydrate accumulation and support of DOE and its industry partners in evaluating, planning, and preparing for drilling and testing gas hydrate research wells in northern Alaska.

Alaska↗

Qualitative and quantitative analysis of Dibenzofuran, Alkyldibenzofurans, and Benzo[b]naphthofurans in crude oils and source rock extracts

Dibenzofuran (DBF), its alkylated homologues, and benzo[b]naphthofurans (BNFs) are common oxygen-heterocyclic aromatic compounds in crude oils and source rock extracts. A series of positional isomers of alkyldibenzofuran and benzo[b]naphthofuran were identified in mass chromatograms by comparison with internal standards and standard retention indices. The response factors of dibenzofuran in relation to internal standards were obtained by gas chromatography-mass spectrometry analyses of a set of mixed solutions with different concentration ratios. Perdeuterated dibenzofuran and dibenzothiophene are optimal internal standards for quantitative analyses of furan compounds in crude oils and source rock extracts. The average concentration of the total DBFs in oils derived from siliciclastic lacustrine rock extracts from the Beibuwan Basin, South China Sea, was 518 μg/g, which is about 5 times that observed in the oils from carbonate source rocks in the Tarim Basin, Northwest China. The BNFs occur ubiquitously in source rock extracts and related oils of various origins. The results of this work suggest that the relative abundance of benzo[b]naphthofuran isomers, that is, the benzo[b]naphtho[2,1-d]furan/{benzo[b]naphtho[2,1-d]furan + benzo[b]naphtho[1,2-d]furan} ratio, may be a potential molecular geochemical parameter to indicate oil migration pathways and distances.

Energy & Fuels↗

Airborne radioactivity survey of the Devils Tower area, Crook county, Wyoming

The accompanying map shows the results of an airborne radioactivity survey covering 45 square miles northwest of Devils Tower, Crook County, Wyoming. The survey was made by the U.S. Geological Survey on September 4, 1952, as part of a cooperative program with the U.S. Atomic Energy Commission. The survey was made with scintillation-detection equipment mounted in a Douglas DC-3 aircraft. Parallel traverse lines, spaced at quarter-mile intervals, were flown approximately 500 feet above the ground. Aerial photographs were used for pilot guidance, and the flight path of the aircraft was recorded by a gyro-stabilized, continuous-strip-film camera. The distance of the aircraft from the ground was measured with a continuously recording radio altimeter. At 500 feet above the ground, the width of the zone from which anomalous radioactivity is measured varies with the intensity of radiation of the source and, for strong sources, the width would be as much as 1,400 feet. Quarter-mile spacing of the flight paths of the aircraft should be adequate to detect anomalies from strong sources of radioactivity. However, small areas of considerable radioactivity midway between flight paths may not be noted. The approximate location of each radioactivity anomaly is shown on the accompanying map. The plotted position of an anomaly may be in error by as much as a quarter of a mile owing to errors in the available base maps up to several square miles in which it is impossible to find and plot recognizable landmarks. The radioactivity that is recorded by airborne measurements at 500 feet above the ground can be caused by: 1. A moderately large area in which the rocks and soils are slightly more radioactive than the rocks and soils of the surrounding area. 2. A smaller area in which the rocks and soils are considerably more radioactive than rocks and soils in the surrounding area. 3. A very small area in which to rocks and soils are much more radioactive than the rocks and soils of the surrounding area. Any particular anomaly, therefore, may represent either slightly greater-than-average radioactivity over an area of a few thousand square feet, or high radioactivity over an area of a few hundred square feet. The radioactivity anomalies shown on the accompanying map indicate localities of more-than-average radioactivity, and therefore, suggest areas in which uranium or thorium deposits are more likely to occur.

Wyoming↗

Airborne radioactivity of portions of the Defiance Uplift and Carrizo Mountains, Apache county, Arizona

The accompanying map shows the results of an airborne radioactivity survey covering 940 square miles in Apache county, Arizona. The survey was made by the U.S. Geological Survey from September 8 to October 3, 1952, as part of a cooperative program with the U.S. Atomic Energy Commission. The survey was made with scintillation-detection equipment mounted in a Douglas DC-3 aircraft. Parallel traverse lines, spaced at quarter-mile intervals, were flown approximately 500 feet above the ground. Aerial photographs were used for pilot guidance, and the flight path of the aircraft was recorded by a gyro-stabilized, continuous-strip-film camera. The distance of the aircraft from the ground was measured with a continuously recording radio altimeter. At 500 feet above the ground, the width of the zone from which anomalous radioactivity is measured varies with the intensity of radiation of the source and, for strong sources, the width would be as much as 1,400 feet. Quarter-mile spacing of the flight paths of the aircraft should be adequate to detect anomalies from strong sources of radioactivity. However, small areas of considerable radioactivity midway between flight paths may not be noted. The approximate location of each radioactivity anomaly is shown on the accompanying map. The plotted position of an anomaly may be in error by as much as a quarter of a mile owing to errors in the available base maps up to several square miles in which it is impossible to find and plot recognizable landmarks. The radioactivity anomaly that is recorded by airborne measurements at 500 feet above the ground can be caused by: 1. A moderately large area in which the rocks and soils are slightly more radioactive than the rocks and soils of the surrounding area. 2. A smaller area in which the rocks and soils are considerably more radioactive than rocks and soils in the surrounding area. 3. A very small area in which to rocks and soils are much more radioactive than the rocks and soils of the surrounding area. Any particular anomaly, therefore, may represent either slightly greater-than-average radioactivity over an area of a few thousand square feet, or high radioactivity over an area of a few hundred square feet. The radioactivity anomalies shown on the accompanying map indicate localities of more-than-average radioactivity, and therefore, suggest areas in which uranium or thorium deposits are more likely to occur.

Arizona↗

Airborne radioactivity survey of the Aspen Mountain area, Sweetwater county, Wyoming

The accompanying map shows the results of an airborne radioactivity survey covering 700 square miles in the Aspen Mountain area, Sweetwater county, Wyoming. The survey was made by the U.S. Geological Survey, October 22, 1952, as part of a cooperative program with the U.S. Atomic Energy Commission. The survey was made with scintillation-detection equipment mounted in a Douglas DC-3 aircraft. Parallel traverse lines, spaced at quarter-mile intervals, were flown approximately 500 feet above the ground. Aerial photographs were used for pilot guidance, and the flight path of the aircraft was recorded by a gyro-stabilized, continuous-strip-film camera. The distance of the aircraft from the ground was measured with a continuously recording radio altimeter. At 500 feet above the ground, the width of the zone from which anomalous radioactivity is measured varies with the intensity of radiation of the source and, for strong sources, the width would be as much as 1,400 feet. Quarter-mile spacing of the flight paths of the aircraft should be adequate to detect anomalies from strong sources of radioactivity. However, small areas of considerable radioactivity midway between flight paths may not be noted. The approximate location of each radioactivity anomaly is shown on the accompanying map. The plotted position of an anomaly may be in error by as much as a quarter of a mile owing to errors in the available base maps up to several square miles in which it is impossible to find and plot recognizable landmarks. The radioactivity anomaly that is recorded by airborne measurements at 500 feet above the ground can be caused by: 1. A moderately large area in which the rocks and soils are slightly more radioactive than the rocks and soils of the surrounding area. 2. A smaller area in which the rocks and soils are considerably more radioactive than rocks and soils in the surrounding area. 3. A very small area in which to rocks and soils are much more radioactive than the rocks and soils of the surrounding area. Any particular anomaly, therefore, may represent either slightly greater-than-average radioactivity over an area of a few thousand square feet, or high radioactivity over an area of a few hundred square feet. The radioactivity anomalies shown on the accompanying map indicate localities of more-than-average radioactivity, and therefore, suggest areas in which uranium or thorium deposits are more likely to occur.

Wyoming↗

Airborne radioactivity survey of the Tabernacle Buttes area, Sublette and Fremont counties, Wyoming

The accompanying map shows the results of an airborne radioactivity survey in an area of 670 square miles in Sublette and Fremont counties, Wyoming. The survey was made by the U.S. Geological Survey, October 20, 1952, as part of a cooperative program with the U.S. Atomic Energy Commission. The survey was made with scintillation-detection equipment mounted in a Douglas DC-3 aircraft. Parallel traverse lines, spaced at quarter-mile intervals, were flown approximately 500 feet above the ground. Aerial photographs were used for pilot guidance, and the flight path of the aircraft was recorded by a gyro-stabilized, continuous-strip-film camera. The distance of the aircraft from the ground was measured with a continuously recording radio altimeter. At 500 feet above the ground, the width of the zone from which anomalous radioactivity is measured varies with the intensity of radiation of the source and, for strong sources, the width would be as much as 1,400 feet. Quarter-mile spacing of the flight paths of the aircraft should be adequate to detect anomalies from strong sources of radioactivity. However, small areas of considerable radioactivity midway between flight paths may not be noted. The approximate location of each radioactivity anomaly is shown on the accompanying map. The plotted position of an anomaly may be in error by as much as a quarter of a mile owing to errors in the available base maps up to several square miles in which it is impossible to find and plot recognizable landmarks. The radioactivity anomaly that is recorded by airborne measurements at 500 feet above the ground can be caused by: 1. A moderately large area in which the rocks and soils are slightly more radioactive than the rocks and soils of the surrounding area. 2. A smaller area in which the rocks and soils are considerably more radioactive than rocks and soils in the surrounding area. 3. A very small area in which to rocks and soils are much more radioactive than the rocks and soils of the surrounding area. Any particular anomaly, therefore, may represent either slightly greater-than-average radioactivity over an area of a few thousand square feet, or high radioactivity over an area of a few hundred square feet. The radioactivity anomalies shown on the accompanying map indicate localities of more-than-average radioactivity, and therefore, suggest areas in which uranium or thorium deposits are more likely to occur.

Wyoming↗

Airborne radioactivity survey of the West Lonetree area, Uinta county, Wyoming

The accompanying map shows the results of an airborne radioactivity survey in an area of 154 square miles in Uinta county, Wyoming. The survey was made by the U.S. Geological Survey, October 23, 1952, as part of a cooperative program with the U.S. Atomic Energy Commission. The survey was made with scintillation-detection equipment mounted in a Douglas DC-3 aircraft. Parallel traverse lines, spaced at quarter-mile intervals, were flown approximately 500 feet above the ground. Aerial photographs were used for pilot guidance, and the flight path of the aircraft was recorded by a gyro-stabilized, continuous-strip-film camera. The distance of the aircraft from the ground was measured with a continuously recording radio altimeter. At 500 feet above the ground, the width of the zone from which anomalous radioactivity is measured varies with the intensity of radiation of the source and, for strong sources, the width would be as much as 1,400 feet. Quarter-mile spacing of the flight paths of the aircraft should be adequate to detect anomalies from strong sources of radioactivity. However, small areas of considerable radioactivity midway between flight paths may not be noted. The approximate location of each radioactivity anomaly is shown on the accompanying map. The plotted position of an anomaly may be in error by as much as a quarter of a mile owing to errors in the available base maps up to several square miles in which it is impossible to find and plot recognizable landmarks. The radioactivity anomaly that is recorded by airborne measurements at 500 feet above the ground can be caused by: 1. A moderately large area in which the rocks and soils are slightly more radioactive than the rocks and soils of the surrounding area. 2. A smaller area in which the rocks and soils are considerably more radioactive than rocks and soils in the surrounding area. 3. A very small area in which to rocks and soils are much more radioactive than the rocks and soils of the surrounding area. Any particular anomaly, therefore, may represent either slightly greater-than-average radioactivity over an area of a few thousand square feet, or high radioactivity over an area of a few hundred square feet. The radioactivity anomalies shown on the accompanying map indicate localities of more-than-average radioactivity, and therefore, suggest areas in which uranium or thorium deposits are more likely to occur.

Wyoming↗

Bioelectrical impedance analysis: A new tool for assessing fish condition

Bioelectrical impedance analysis (BIA) is commonly used in human health and nutrition fields but has only recently been considered as a potential tool for assessing fish condition. Once BIA is calibrated, it estimates fat/moisture levels and energy content without the need to kill fish. Despite the promise held by BIA, published studies have been divided on whether BIA can provide accurate estimates of body composition in fish. In cases where BIA was not successful, the models lacked the range of fat levels or sample sizes we determined were needed for model success (range of dry fat levels of 29%, n = 60, yielding an R 2 of 0.8). Reduced range of fat levels requires an increased sample size to achieve that benchmark; therefore, standardization of methods is needed. Here we discuss standardized methods based on a decade of research, identify sources of error, discuss where BIA is headed, and suggest areas for future research.

Fisheries↗

Characterizing large earthquakes before rupture is complete

Whether large and very large earthquakes are distinguishable from each other early on in the rupture process has been a subject often debated over the past several decades. Studies have shown that the frequency content of radiated seismic energy in the first few seconds of an earthquake scales with the final magnitude of the event, implying determinism. Other studies have shown that the recordings of ground displacement from small-to-moderate sized earthquakes are indistinguishable, and thus earthquakes share a universal early rupture process. Regardless of how earthquakes start, however, at some point in the rupture process events of different sizes must be distinguishable from one another. If that difference occurs early - i.e., before the rupture duration of the smaller event - this implies that earthquakes demonstrate some level of determinism. Here we show through analysis of a large database of source time functions and near-source displacement records that after an initiation phase, ruptures of M7-9 earthquakes organize into a slip pulse, the kinematic properties of which scale with magnitude. As such, early in the rupture process - after about 10s - large and very large earthquakes demonstrate different properties and can thus be distinguished.

Science Advances↗

Evidence of Late Pliocene-Early Pleistocene marine environments in the deep subsurface of the Lihue Basin, Kauai, Hawaii

Cuttings recovered from two deep exploratory wells in the Lihue Basin, Kauai, Hawaii, include fossiliferous marine deposits that offer an uncommon opportunity to study paleoenvironments from the deep subsurface in Hawaii and interpret the paleogeography and geologic history of Kauai. These deposits indicate that two marine incursions gave rise to protected shallow-water, low-energy embayments in the southern part of the Lihue Basin in the late Pliocene-early Pleistocene. During the first marine incursion, the embayment was initially zoned, with a variable-salinity environment nearshore and a normal-marine reef environment offshore. The offshore reef environment eventually evolved to a nearshore, variable-salinity environment as the outer part of the embayment shallowed. During the second marine incursion, the embayment had normal-marine to hypersaline conditions, which constitute a significant departure from the variable-salinity environment present during the first marine incursion. Large streams draining the southern Lihue Basin are a likely source of the freshwater that caused the salinity fluctuations evident in the fossils from the first marine incursion. Subsequent volcanic eruptions produced lava flows that buried the embayment and probably diverted much of the stream flow in the southern Lihue Basin northward, to its present point of discharge north of Kalepa Ridge. As a result, the embayment that formed during the second marine incursion received less freshwater, and a normal-marine to hypersaline environment developed. The shallow-water marine deposits, currently buried between 86 m and 185 m below present sea level, have implications for regional tectonics and global eustasy. Copyright ?? 2008, SEPM (Society for Sedimentary Geology).

Palaios↗

The international scale of the groundwater issue

Throughout history, and throughout the world, groundwater has been a major source of water for sustaining human life. Use of this resource has increased dramatically over the last century. In many areas of the world, the balance between human and ecosystem needs is difficult to maintain. Understanding the international scale of the groundwater issue requires metrics and analysis at a commensurate scale. Advances in remote sensing supplement older traditional direct measurement methods for understanding the magnitude of depletion, and all measurements motivate the need for common data standards to collect and share information. In addition to metrics of groundwater availability, four key international groundwater issues are depletion of water, degradation of water quality, the water-energy nexus, and transboundary water conflicts. This chapter is devoted to introducing these issues, which are also discussed in more detail in later chapters.

Book chapter↗

Porphyry copper assessment of northeast Asia: Far East Russia and northeasternmost China: Chapter W in Global mineral resource assessment

The U.S. Geological Survey assesses resources (mineral, energy, water, environmental, and biologic) at regional, national, and global scales to provide science in support of land management and decision making. Mineral resource assessments provide a synthesis of available information about where mineral deposits are known and suspected to be in the Earth’s crust, which commodities may be present, and estimates of amounts of resources in undiscovered deposits. A probabilistic mineral resource assessment of undiscovered resources associated with porphyry copper deposits in northeast Asia—composed mainly of Far East Russia and a small part of northeasternmost China—was completed as part of a global mineral resource assessment. Porphyry copper deposits are the main source of copper globally. Russia is an important source of copper, consistently ranking as 6th, 7th, or 8th in world production since 2000, and ranked 7th in 2014. Most of this production has been from magmatic copper-nickel-platinum-group element, volcanogenic massive sulfide, and sediment-hosted copper deposit types. The purpose of the assessment was to (1) compile a database of known deposits and significant prospects, (2) delineate permissive areas (tracts) for undiscovered porphyry copper deposits that may be present in the upper kilometer of the Earth’s crust, and (3) provide probabilistic estimates of amounts of copper (Cu), molybdenum (Mo), gold (Au), and silver (Ag) that could be contained in undiscovered porphyry copper deposits in the tracts. The assessment was completed by the U.S. Geological Survey in collaboration with geologists from the Russian Academy of Sciences and industry consultants. The database of known deposits, significant prospects, and prospects includes an inventory of mineral resources in two known porphyry copper deposits, as well as key characteristics derived from available exploration reports for 70 significant porphyry copper prospects and 86 other prospects. Resource and exploration and development activity are updated with information current through February 2013.

Scientific Investigations Report↗

Tidal flat sediments - texture, Willapa Bay, Washington

The purpose of this study was to texturally characterize the sediments of the mid-estuary tidal flats between Goose Point and Pickernell Creek in Willapa Bay, Washington and to compare these flats with other flats in the estuary. The mean grain size of sediments on tidal flats in the mid-estuary are fine sand (2-3 V). Sand shoals at the Bay entrance and erosion of cliffs between Goose Point and Pickernell Creek are the source of the sand. The subordinate mud fraction is supplied by rivers and creeks; little mud is deposited on the tidal flats except for those flats immediately adjacent to the rivers. Gravel is a minor component and is concentrated in sediments near the base of the cliffs high on the tidal flats. Variability in texture within the study area is most pronounced near the Palix River and Pickernell Creek. The average characteristics of mid-estuary tidal flat sediments are best described as poorly sorted, fine-grained sand with strongly-fine skewed leptokurtic distributions. Distribution patterns of textural parameters show consistent trends of hydraulic energy. Locally, textural patterns reflect (1) the coarsing effects of a flood current gyre between Goose Point and Sandy Point, and (2) relatively narrow flats (i.e., greater slopes) have coarser sediments proportionately higher upslope than wider flats. The following comparisons can be made between tide flats in Willapa Bay. Mean grain size varies systematically up-estuary permitting the estuary to be artificially divided into 3 parts: outer estuary = 2-3 Ø ; mid-estuary = 3-4 Ø ; and inner estuary = greater than 4 Ø . Outer estuarine tide flats extend deep into the estuary, particularly to the south. The transition from outer to inner estuarine tide flats based on textural differences is a rapid change (i.e., occurs over a short distance).

Washington↗

An international code comparison study on coupled thermal, hydrologic and geomechanical processes of natural gas hydrate-bearing sediments

Geologic reservoirs containing gas hydrate occur beneath permafrost environments and within marine continental slope sediments, representing a potentially vast natural gas source. Numerical simulators provide scientists and engineers with tools for understanding how production efficiency depends on the numerous, interdependent (coupled) processes associated with potential production strategies for these gas hydrate reservoirs. Confidence in the modeling and forecasting abilities of these gas hydrate reservoir simulators (GHRSs) grows with successful comparisons against laboratory and field test results, but such results are rare, particularly in natural settings. The hydrate community recognized another approach to building confidence in the GHRS: comparing simulation results between independently developed and executed computer codes on structured problems specifically tailored to the interdependent processes relevant for gas hydrate-bearing systems. The United States Department of Energy, National Energy Technology Laboratory (DOE/NETL), sponsored the first international gas hydrate code comparison study, IGHCCS1, in the early 2000s. IGHCCS1 focused on coupled thermal and hydrologic processes associated with producing gas hydrates from geologic reservoirs via depressurization and thermal stimulation. Subsequently, GHRSs have advanced to model more complex production technologies and incorporate geomechanical processes into the existing framework of coupled thermal and hydrologic modeling. This paper contributes to the validation of these recent GHRS developments by providing results from a second GHRS code comparison study, IGHCCS2, also sponsored by DOE/NETL. IGHCCS2 includes participants from an international collection of universities, research institutes, industry, national laboratories, and national geologic surveys. Study participants developed a series of five benchmark problems principally involving gas hydrate processes with geomechanical components. The five problems range from simple geometries with analytical solutions to a representation of the world’s first offshore production test of methane hydrates, which was conducted with the depressurization method off the coast of Japan. To identify strengths and limitations in the various GHRSs, study participants submitted solutions for the benchmark problems and discussed differing results via teleconferences. The GHRSs evolved over the course of IGHCCS2 as researchers modified their simulators to reflect new insights, lessons learned, and suggested performance enhancements. The five benchmark problems, final sample solutions, and lessons learned that are presented here document the study outcomes and serve as a reference guide for developing and testing gas hydrate reservoir simulators.

Journal of Marine and Petroleum Geology↗

Prospectivity mapping for geologic hydrogen

Geologic, or naturally occurring, hydrogen has the potential to become a new, low-carbon, primary energy resource. Often referred to as “white” or “gold” hydrogen, this gas occurs naturally in the Earth’s subsurface, similar to petroleum resources. However, unlike petroleum, which releases carbon dioxide when burned, burning hydrogen only produces water as a byproduct. Exploration for geologic hydrogen remains in an early stage and discoveries of high concentrations of subsurface hydrogen are still relatively rare. To facilitate research and exploration for this potential resource, this report presents the first publicly available prospectivity map of geologic hydrogen accumulations in the conterminous United States. Prospective regions are those regions in which all major components necessary for a hydrogen accumulation likely are present—a source of sufficient hydrogen generation, porous reservoirs for storage, and seals to prevent leakage. The midcontinent region of the United States and the central California coast are revealed as having high prospectivity. This analysis also identifies previously unrecognized prospective regions that may be favorable due to long distance lateral migration of subsurface hydrogen, such as the offshore eastern seaboard of the United States, and can provide a linkage between surface observations of hydrogen degassing and far-field source regions. The methodology developed to create this map is expandable and flexible and may be adapted to incorporate new concepts in the hydrogen system and for application to other regions of the world.

conterminous United States↗

Enhanced transpiration by riparian buffer trees in response to advection in a humid temperate agricultural landscape

Riparian buffers are designed as management practices to increase infiltration and reduce surface runoff and transport of sediment and nonpoint source pollutants from crop fields to adjacent streams. Achieving these ecosystem service goals depends, in part, on their ability to remove water from the soil via transpiration. In these systems, edges between crop fields and trees of the buffer systems can create advection processes, which could influence water use by trees. We conducted a field study in a riparian buffer system established in 1994 under a humid temperate climate, located in the Corn Belt region of the Midwestern U.S. (Iowa). The goals were to estimate stand level transpiration by the riparian buffer, quantify the controls on water use by the buffer system, and determine to what extent advective energy and tree position within the buffer system influence individual tree transpiration rates. We primarily focused on the water use response (determined with the Heat Ratio Method) of one of the dominant species ( Acer saccharinum ) and a subdominant ( Juglans nigra ). A few individuals of three additional species ( Quercus bicolor, Betula nigra, Platanus occidentalis ) were monitored over a shorter time period to assess the generality of responses. Meteorological stations were installed along a transect across the riparian buffer to determine the microclimate conditions. The differences found among individuals were attributed to differences in species sap velocities and sapwood depths, location relative to the forest edge and prevailing winds and canopy exposure and dominance. Sapflow rates for A. saccharinum trees growing at the SE edge (prevailing winds) were 39% greater than SE interior trees and 30% and 69% greater than NW interior and edge trees, respectively. No transpiration enhancement due to edge effect was detected in the subdominant J. nigra . The results were interpreted as indicative of advection effects from the surrounding crops. Further, significant differences were document in sapflow rates between the five study species, suggesting that selection of species is important for enhancing specific riparian buffer functions. However, more information is needed on water use patterns among diverse species growing under different climatic and biophysical conditions to assist policy and management decisions regarding effective buffer design.

Forest Ecology and Management↗

A ground electromagnetic survey used to map sulfides and acid sulfate ground waters at the abandoned Cabin Branch Mine, Prince William Forest Park, northern Virginia gold-pyrite belt

INTRODUCTION AND BACKGROUND: Prince William Forest Park is situated at the northeastern end of the Virginia Gold-Pyrite belt northwest of the town of Dumfries, VA. The U. S. Marine Corps Reservation at Quantico borders the park on the west and south, and occupies part of the same watershed. Two abandoned mines are found within the park: the Cabin Branch pyrite mine, a historic source of acid mine drainage, and the Greenwood gold mine, a source of mercury contamination. Both are within the watershed of Quantico Creek (Fig.1). The Cabin Branch mine (also known as the Dumfries mine) lies about 2.4 km northwest of the town of Dumfries. It exploited a 300 meter-long, lens-shaped body of massive sulfide ore hosted by metamorphosed volcanic rocks; during its history over 200,000 tons of ore were extracted and processed locally. The site became part of the National Capitol Region of the National Park Service in 1940 and is currently managed by the National Park Service. In 1995 the National Park Service, in cooperation with the Virginia Department of Mines, Minerals, and Energy reclaimed the Cabin Branch site. The Virginia Gold-Pyrite belt, also known as the central Virginia volcanic-plutonic belt, is host to numerous abandoned metal mines (Pavlides and others, 1982), including the Cabin Branch deposit. The belt itself extends from its northern terminus near Cabin Branch, about 50 km south of Washington, D.C., approximately 175 km to the southwest into central Virginia. It is underlain by metamorphosed volcanic and clastic (non-carbonate) sedimentary rocks, originally deposited approximately 460 million years ago during the Ordovician Period (Horton and others, 1998). Three kinds of deposits are found in the belt: volcanic-associated massive sulfide deposits, low-sulfide quartz-gold vein deposits, and gold placer deposits. The massive sulfide deposits such as Cabin Branch were historically mined for their sulfur, copper, zinc, and lead contents, but also yielded byproduct gold and silver. The environmental impact of massive sulfide deposits can be substantial. These deposits are characterized by high concentrations of heavy-metal sulfide minerals, hosted by silicate rocks. Thus, weathering of these deposits and their mine wastes has the potential to generate heavy-metal laden sulfuric acid that can have negative impacts on aquatic ecosystems. In addition, lead associated with solid mine wastes has the potential for human health impacts through ingestion. The heavy metals that are encountered in these deposits and are most likely to cause environmental impacts include copper, zinc, lead, cadmium, and arsenic. In addition, the weathering of pyrite releases large amounts of iron, and the acid generated attacks the country rocks and causes the release of large amounts of aluminum, which also can severely impact aquatic ecosystems. A reclamation attempt was made at the site in 1995, including construction of storm-water diversion trenches around the abandoned mine area, grading tailings away from the stream bank, addition of pulverized limestone and topsoil, and revegetation. The post-reclamation chemistry of shallow groundwaters (<3 meters deep) shows a neutral pH on the southwestern bank of the stream but pH of 4.1 to 4.5 on the northeastern bank. The dominant ions are Fe2+ and SO42- (Seal, Haffner, Meier, and Pollio, 1999) A ground electromagnetic survey was conducted over the site in 1999 as part of a wider study ( Seal, Haffner, and Meier, 1998a,b, 1999). It was hoped that a 3-D map of the soil conductivity derived from the survey could provide insight into the distribution of the mobilized sulfides present under the ground.

Virginia↗

Evaluating tsunami hazards from debris flows

Debris flows that enter water bodies may have significant kinetic energy, some of which is transferred to water motion or waves that can impact shorelines and structures. The associated hazards depend on the location of the affected area relative to the point at which the debris flow enters the water. Three distinct regions (splash zone, near field, and far field) may be identified. Experiments demonstrate that characteristics of the near field water wave, which is the only coherent wave to emerge from the splash zone, depend primarily on debris flow volume, debris flow submerged time of motion, and water depth at the point where debris flow motion stops. Near field wave characteristics commonly may be used as & proxy source for computational tsunami propagation. This result is used to assess hazards associated with potential debris flows entering a reservoir in the northwestern USA. ?? 2003 Millpress,.

Conference Paper↗