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At least 811 records · Page 45Linked to original sources

The structure of subtidal currents within and around Lydonia Canyon: Evidence for enhanced cross-shelf fluctuations over the mouth of the canyon

Between October 1980 and April 1981, currents were measured within Lydonia Canyon and on the adjacent shelf and slope. The amplitude of the subtidal currents over the shelf and slope ranged between 10 and 30 cm s −1 , but within the canyon, they were typically smaller than 5 cm s −1 . The subtidal currents had well-defined spatial structures over the shelf and the slope and in the middle and outer portions of the canyon. The along-isobath flow over the shelf and slope was unaltered by the canyon. Currents within the canyon and just above it were driven up and down the canyon by the cross-shelf pressure gradient in geostrophic equilibrium with the along-shelf flow. The measurements suggest that the Coriolis force on the cross-canyon flow, turbulent Reynolds stresses, and acceleration of the along-canyon flow balanced the imposed pressure gradient for flow near the rim of Lydonia Canyon. The Coriolis force was not important in the deeper portions of the canyon, where baroclinic adjustments of the density field began to be an important factor in the momentum balance. A simple model indicates that the magnitude of the horizontal turbulent viscosity coefficient for subtidal flow in this narrow canyon is 10 6 to 10 7 cm 2 s −1 . The mixing indicated by the large amplitude of the viscosity coefficient was probably caused by the strong tidal currents present within Lydonia Canyon. On the shelf, along-isobath currents were locally driven by the large-scale component of the wind field; along-shelf currents were equally correlated with local winds and with winds from sites 700 km northeast of Lydonia Canyon. Wind stress was not correlated with currents over the slope in water deeper than 450 m or with currents within the canyon.

Journal of Geophysical Research - Oceans↗

The early bird gets the shrimp: Confronting assumptions of isotopic equilibrium and homogeneity in a wild bird population

1. Because stable isotope distributions in organic material vary systematically across energy gradients that exist in ecosystems, community and population structures, and in individual physiological systems, isotope values in animal tissues have helped address a broad range of questions in animal ecology. It follows that every tissue sample provides an isotopic profile that can be used to study dietary or movement histories of individual animals. Interpretations of these profiles depend on the assumption that metabolic pools are isotopically well mixed and in equilibrium with dietary resources prior to tissue synthesis, and they extend to the population level by assuming isotope profiles are identically distributed for animals using the same proximal dietary resource. As these assumptions are never fully met, studying structure in the variance of tissue isotope values from wild populations is informative. 2. We studied variation in δ 13 C, δ 15 N, δ 2 H and δ 18 O data for feathers from a population of eared grebes (Podiceps nigricollis) that migrate to Great Salt Lake each fall to moult feathers. During this time, they cannot fly and feed almost exclusively on superabundant brine shrimp (Artemia franciscana). The ecological simplicity of this situation minimized the usual spatial and trophic complexities often present in natural studies of feather isotope values. 3. Ranges and variances of isotope values for the feathers were larger than those from previously published studies that report feather isotopic variance, but they were bimodally distributed in all isotope dimensions. Isotope values for proximal dietary resources and local surface water show that some of the feathers we assumed to have been grown locally must have been grown before birds reached isotopic equilibrium with local diet or immediately prior to arrival at Great Salt Lake. 4. Our study provides novel insights about resource use strategies in eared grebes during migration. More generally, it demonstrates the utility of studying variance structures and questioning assumptions implicit in the interpretation of stable isotope data from wild animals.

Utah↗

Practical application of time-lapse camera imagery to develop water-level data for three hydrologic monitoring sites in Wisconsin during water year 2020

Using camera imagery to measure water level (camera-stage) is a well-researched area of study. Previous camera-stage studies have shown promising results when implementing this technology with tight constraints on test conditions. However, there is a need for a more comprehensive evaluation of the extensibility of camera-stage to practical applications. Therefore, the aim of this study was to test a camera-stage method under a wide variety of test conditions to better understand the successes and challenges of using this technology in real-world scenarios. In this study, this approach was tested during Water Year 2020 at three existing U.S. Geological Study (USGS) stream gaging stations in south central Wisconsin that had existing USGS water-level instrumentation. The specific reference objects tested were white pipes and a concrete wall. Since successful application of camera-stage relies on use of suitable images, all captured images in this study were visually inspected to determine suitability for application of camera-stage. Camera-stage measurements were then computed only on images deemed suitable and the results were compared with ground-truth stage values to determine the accuracy. For the purposes of this study, camera-stage values within ±0.10 ft of the actual stage were considered acceptable. One major challenge highlighted was the potential difficulty in obtaining suitable imagery, with the proportion of suitable images varying greatly between the four trials from 38 % to 92 %. The results from applying camera-stage to suitable images were encouraging though, with 79 % to 99 % of evaluated camera-stage values qualifying as acceptable among the four test trials.

Wisconsin↗

Hydrologic properties of coal beds in the Powder River Basin, Montana I. Geophysical log analysis

As part of a multidisciplinary investigation designed to assess the implications of coal-bed methane development on water resources for the Powder River Basin of southeastern Montana, six wells were drilled through Paleocene-age coal bedsalong a 31-km east–west transect within the Tongue River drainage basin. Analysis of geophysical logs obtained in these wells provides insight into the hydrostratigraphic characteristics of the coal and interbedded siliciclastic rocks and their possible interaction with the local stress field. Natural gamma and electrical resistivity logs were effective in distinguishing individual coal beds. Full-waveform sonic logs were used to determine elastic properties of the coal and an attendant estimate of aquifer storage is in reasonable agreement with that computed from a pumping test. Inspection of magnetically oriented images of the borehole walls generated from both acoustic and optical televiewers and comparison with coal cores infer a face cleat orientation of approximately N33°E, in close agreement with regional lineament patterns and the northeast trend of the nearby Tongue River. The local tectonic stress field in this physiographic province as inferred from a nearby 1984 earthquake denotes an oblique strike-slip faulting regime with dominant east–west compression and north–south extension. These stress directions are coincident with those of the primary fracture sets identified from the televiewer logs and also with the principle axes of the drawdown ellipse produced from a complementary aquifer test, but oblique to apparent cleat orientation. Consequently, examination of these geophysical logs within the context of local hydrologic characteristics indicates that transverse transmissivity anisotropy in these coals is predominantly controlled by bedding configuration and perhaps a mechanical response to the contemporary stress field rather than solely by cleat structure.

Montana↗

Predicting unsaturated zone nitrogen mass balances in agricultural settings of the United States

Unsaturated zone N fate and transport were evaluated at four sites to identify the predominant pathways of N cycling: an almond [ Prunus dulcis (Mill.) D.A. Webb] orchard and cornfield ( Zea mays L.) in the lower Merced River study basin, California; and corn–soybean [ Glycine max (L.) Merr.] rotations in study basins at Maple Creek, Nebraska, and at Morgan Creek, Maryland. We used inverse modeling with a new version of the Root Zone Water Quality Model (RZWQM2) to estimate soil hydraulic and nitrogen transformation parameters throughout the unsaturated zone; previous versions were limited to 3-m depth and relied on manual calibration. The overall goal of the modeling was to derive unsaturated zone N mass balances for the four sites. RZWQM2 showed promise for deeper simulation profiles. Relative root mean square error (RRMSE) values for predicted and observed nitrate concentrations in lysimeters were 0.40 and 0.52 for California (6.5 m depth) and Nebraska (10 m), respectively, and index of agreement ( d ) values were 0.60 and 0.71 ( d varies between 0 and 1, with higher values indicating better agreement). For the shallow simulation profile (1 m) in Maryland, RRMSE and d for nitrate were 0.22 and 0.86, respectively. Except for Nebraska, predictions of average nitrate concentration at the bottom of the simulation profile agreed reasonably well with measured concentrations in monitoring wells. The largest additions of N were predicted to come from inorganic fertilizer (153–195 kg N ha −1 yr −1 in California) and N fixation (99 and 131 kg N ha −1 yr −1 in Maryland and Nebraska, respectively). Predicted N losses occurred primarily through plant uptake (144–237 kg N ha −1 yr −1 ) and deep seepage out of the profile (56–102 kg N ha −1 yr −1 ). Large reservoirs of organic N (up to 17,500 kg N ha −1 m −1 at Nebraska) were predicted to reside in the unsaturated zone, which has implications for potential future transfer of nitrate to groundwater.

Journal of Environmental Quality↗

The perfect debris flow? Aggregated results from 28 large-scale experiments

Aggregation of data collected in 28 controlled experiments reveals reproducible debris-flow behavior that provides a clear target for model tests. In each experiment ∼10 m 3 of unsorted, water-saturated sediment composed mostly of sand and gravel discharged from behind a gate, descended a steep, 95-m flume, and formed a deposit on a nearly horizontal runout surface. Experiment subsets were distinguished by differing basal boundary conditions (1 versus 16 mm roughness heights) and sediment mud contents (1 versus 7 percent dry weight). Sensor measurements of evolving flow thicknesses, basal normal stresses, and basal pore fluid pressures demonstrate that debris flows in all subsets developed dilated, coarse-grained, high-friction snouts, followed by bodies of nearly liquefied, finer-grained debris. Mud enhanced flow mobility by maintaining high pore pressures in flow bodies, and bed roughness reduced flow speeds but not distances of flow runout. Roughness had these effects because it promoted debris agitation and grain-size segregation, and thereby aided growth of lateral levees that channelized flow. Grain-size segregation also contributed to development of ubiquitous roll waves, which had diverse amplitudes exhibiting fractal number-size distributions. Despite the influence of these waves and other sources of dispersion, the aggregated data have well-defined patterns that help constrain individual terms in a depth-averaged debris-flow model. The patterns imply that local flow resistance evolved together with global flow dynamics, contradicting the hypothesis that any consistent rheology applied. We infer that new evolution equations, not new rheologies, are needed to explain how characteristic debris-flow behavior emerges from the interactions of debris constituents.

Journal of Geophysical Research F: Earth Surface↗

Physical properties of sediment from the Mount Elbert Gas Hydrate Stratigraphic Test Well, Alaska North Slope

This study characterizes cored and logged sedimentary strata from the February 2007 BP Exploration Alaska, Department of Energy, U.S. Geological Survey (BPXA-DOE-USGS) Mount Elbert Gas Hydrate Stratigraphic Test Well on the Alaska North Slope (ANS). The physical-properties program analyzed core samples recovered from the well, and in conjunction with downhole geophysical logs, produced an extensive dataset including grain size, water content, porosity, grain density, bulk density, permeability, X-ray diffraction (XRD) mineralogy, nuclear magnetic resonance (NMR), and petrography. This study documents the physical property interrelationships in the well and demonstrates their correlation with the occurrence of gas hydrate. Gas hydrate (GH) occurs in three unconsolidated, coarse silt to fine sand intervals within the Paleocene and Eocene beds of the Sagavanirktok Formation: Unit D-GH (614.4 m-627.9 m); unit C-GH1 (649.8 m-660.8 m); and unit C-GH2 (663.2 m-666.3 m). These intervals are overlain by fine to coarse silt intervals with greater clay content. A deeper interval (unit B) is similar lithologically to the gas-hydrate-bearing strata; however, it is water-saturated and contains no hydrate. In this system it appears that high sediment permeability (k) is critical to the formation of concentrated hydrate deposits. Intervals D-GH and C-GH1 have average "plug" intrinsic permeability to nitrogen values of 1700 mD and 675 mD, respectively. These values are in strong contrast with those of the overlying, gas-hydrate-free sediments, which have k values of 5.7 mD and 49 mD, respectively, and thus would have provided effective seals to trap free gas. The relation between permeability and porosity critically influences the occurrence of GH. For example, an average increase of 4% in porosity increases permeability by an order of magnitude, but the presence of a second fluid (e.g., methane from dissociating gas hydrate) in the reservoir reduces permeability by more than an order of magnitude.

Alaska↗

The M2 tide on the Amazon Shelf

As part of A Multidisciplinary Amazon Shelf Sediment Study (AMASSEDS), moored and shipboard current measurements made over the Amazon shelf during 1990–1991 have been analyzed to determine the dominant semidiurnal tidal constituent, the M 2 . These results have been combined with coastal sea level data from within the Amazon and Para Rivers, the adjacent shelf, and with satellite‐derived tidal elevation data from off the shelf to provide a more complete description of the M 2 tide in this complex river/shelf system. Near the Amazon River mouth the M 2 tide propagates across the shelf and through the mouth as a damped progressive wave, with its amplitude decreasing and phase increasing upriver. Over the adjacent shelf north of Cabo Norte, the M 2 tide approaches a damped standing wave, with large amplitudes (greater than 1.5 m) near the coast due to near resonance within the coastal embayment formed by the Cabo Norte shoal to the south and Cabo Cassipore to the north. The observed M 2 tidal currents are nearly rectilinear and oriented primarily across the local isobaths. Comparisons between tidal observations in both the North Channel and the Cabo Norte‐Cabo Cassipore embayment and a simple variable‐width channel tidal model indicate that (1) most of the M 2 tidal energy dissipation occurs over the mid‐ and inner shelf (in water depths less than 20 m) and (2) fluid muds found there cause a significant reduction (of order 50%) in the effective bottom friction felt by the M 2 tide. The approximate resonant period of the Cabo Norte‐Cabo Cassipore embayment is 11.9 hours, and at resonance the average energy dissipation per forcing period is roughly 2.2 times the average mechanical energy in the embayment. This damping rate is large enough that the tidal amplification is rather insensitive to forcing frequency, so that the response of the embayment to forcing over the semidiurnal band should be essentially the same. The vertical structure of the M 2 tidal current is examined at one outer shelf site located in 65‐m water depth. The observed semimajor axis increases logarithmically with height above bottom within the lowest 1–2 m and reaches a maximum in excess of 0.5 m/s at approximately 11 m above bottom. The mean ellipticity is small (less than 0.1) and positive, indicating clockwise rotation of a nearly rectilinear current, and the semimajor axis is oriented within 10° of the local cross‐isobath direction. The M 2 phase increases with height above bottom, with flood at the bottom leading flood at the surface by about 1 hour. A simple, local homogeneous tidal model with time‐ and space‐dependent eddy viscosity simulates the observed near‐bottom velocity reasonably well, however, the model suggests that stratification above the lowest few meters may significantly affect the tidal boundary layer structure at this site. The M 2 energy flux onto the Amazon shelf and into the Amazon and Para Rivers has been estimated using current and surface elevation data and the best fit variable‐width channel model results. The net M 2 energy flux into the mouths of the Amazon and Para Rivers is 0.47×10 10 W and 0.19×10 10 W, respectively. A net M 2 energy flux of about 3.3×10 10 W occurs onto the shelf between the North Channel of the Amazon River and Cabo Cassipore. This stretch of the Amazon shelf accounts for about 1.3% of the global dissipation of the M 2 tide.

Journal of Geophysical Research C: Oceans↗

Spatial habitat use patterns of sea otters in coastal washington

Sea otter (Enhydra lutris kenyoni) movements, home range, and activity budgets were described from data collected during very-high-frequency radiotelemetry studies of 75 individuals on the outer coast of Washington State between 1992 and 1999. Sea otters were located at least once per week from 22 accessible sites along the coast. Over the 7-year study period, range expansion occurred from the core range north and east into the Strait of Juan de Fuca (SJF) as well as southward on the outer coast. Forty-three percent of the sea otters moved into the SJF at least once, most often in winter, using habitat that had not been occupied by sea otters since their extirpation 100 years ago. All sea otters spent portions of their time in the vicinity of Cape Alava, and many animals demonstrated consistent periodic seasonal shifts between specific portions of the coastline over several years. Ninety-five percent annual linear home ranges differed between sex and age classes. Adult males used the largest amount of coastline (50 km ?? 9 5D) and subadult females used the least (24 ?? 9 km). Both adult males and females demonstrated high seasonal periodicity in range use in summer and winter. Twenty-four-hour time budgets in the core portion of the range revealed on average sea otters spent 41% ?? 14% SD of the time foraging and 45% ?? 13% of the time resting (age and sex classes pooled). Adult and subadult female sea otters were most frequently found resting and foraging close to shore (< 1,000 m) and in shallow water (0-10 m), whereas adult and subadult males rested and foraged > 1,000 m offshore and at depths between 10 and 30 m. Given current rates of population growth and observed mobility, sea otters in Washington have high potential for range expansion into unoccupied habitat such as Grays Harbor, Willapa Bay, the SJF, or along Vancouver Island. ?? 2009 American Society of Mammalogists.

Journal of Mammalogy↗

Trends in snowfall versus rainfall in the western United States

The water resources of the western United States depend heavily on snowpack to store part of the wintertime precipitation into the drier summer months. A well-documented shift toward earlier runoff in recent decades has been attributed to 1) more precipitation falling as rain instead of snow and 2) earlier snowmelt. The present study addresses the former, documenting a regional trend toward smaller ratios of winter-total snowfall water equivalent (SFE) to winter-total precipitation (P) during the period 1949-2004. The trends toward reduce d SFE are a response to warming across the region, with the most significant reductions occurring where winter wet-day minimum temperatures, averaged over the study period, were warmer than -5??C. Most SFE reductions were associated with winter wet-day temperature increases between 0?? and +3??C over the study period. Warmings larger than this occurred mainly at sites where the mean temperatures were cool enough that the precipitation form was less susceptible to warming trends. The trends toward reduced SFE/P ratios w ere most pronounced in March regionwide and in January near the West Coast, corresponding, to widespread warming in these months. While mean temperatures in March were sufficiently high to allow the warming, trend to produce SFE/P declines across the study region, mean January temperatures were cooler. with the result that January SFE/P impacts were restricted to the lower elevations near the West Coast. Extending the analysis back to 1920 sho ws that although the trends presented here may be partially attributable to interdecadal climate variability associated with the Pacific decadal oscillation. they also appear to result from still longer-term climate shifts.

Journal of Climate↗

Evaluation of select velocity measurement techniques for estimating discharge in small streams across the United States

Multiple instruments and methods exist for collecting discrete streamflow measurements in small streams with low flows, defined here as less than 5.7 m 3 /s (200 ft3/s). Included in the available methods are low-cost approaches that are infrequently used, in part, because their uncertainty is not well known. In this work, we evaluated the accuracy and suitability of three low-cost velocity measurement methods (surface float [SF], velocity head rod [VR], and rising body [RB]) and three conventional current meters (acoustic Doppler velocimeter, and mechanical Price type AA and Price Pygmy meters) relative to discharge calculated from stable artificial hydraulic controls. A total of 231 measurements were made by 20 individuals during 88 site visits to 24 sites in eight states. Accuracies were assessed for all methods and precision was evaluated for the low-cost methods. The median percent error was below 5% for conventional methods, and below 20% for the low-cost methods. The SF was the most accurate (median absolute percent error 14%) and precise (mean percent precision of 11%) low-cost method. The RB and VR, respectively, had 15% and 20% median absolute percent error and 29% and 12% mean percent precision. Results suggest that low-cost methods, when used appropriately, can be used to estimate discharge data under low flow conditions when measurements with conventional methods are not feasible and the associated accuracies meet end-user measurement objectives.

continental United States↗

Coupled effects of vertical mixing and benthic grazing on phytoplankton populations in shallow, turbid estuaries

Coastal ocean waters tend to have very different patterns of phytoplankton biomass variability from the open ocean, and the connections between physical variability and phytoplankton bloom dynamics are less well established for these shallow systems. Predictions of biological responses to physical variability in these environments is inherently difficult because the recurrent seasonal patterns of mixing are complicated by aperiodic fluctuations in river discharge and the high-frequency components of tidal variability. We might expect, then, less predictable and more complex bloom dynamics in these shallow coastal systems compared with the open ocean. Given this complex and dynamic physical environment, can we develop a quantitative framework to define the physical regimes necessary for bloom inception, and can we identify the important mechanisms of physical-biological coupling that lead to the initiation and termination of blooms in estuaries and shallow coastal waters? Numerical modeling provides one approach to address these questions. Here we present results of simulation experiments with a refined version of Cloern's (1991) model in which mixing processes are treated more realistically to reflect the dynamic nature of turbulence generation in estuaries. We investigated several simple models for the turbulent mixing coefficient. We found that the addition of diurnal tidal variation to Cloern's model greatly reduces biomass growth indicating that variations of mixing on the time scale of hours are crucial. Furthermore, we found that for conditions representative of South San Francisco Bay, numerical simulations only allowed for bloom development when the water column was stratified and when minimal mixing was prescribed in the upper layer. Stratification, however, itself is not sufficient to ensure that a bloom will develop: minimal wind stirring is a further prerequisite to bloom development in shallow turbid estuaries with abundant populations of benthic suspension feeders.

Journal of Marine Research↗

Comparing seasonal dynamics of the Lake Huron zooplankton community between 1983-1984 and 2007 and revisiting the impact of Bythotrephes planktivory

Zooplankton community composition can be influenced by lake productivity as well as planktivory by fish or invertebrates. Previous analyses based on long-term Lake Huron zooplankton data from August reported a shift in community composition between the 1980s and 2000s: proportional biomass of calanoid copepods increased while that of cyclopoid copepods and herbivorous cladocerans decreased. Herein, we used seasonally collected data from Lake Huron in 1983–1984 and 2007 and reported similar shifts in proportional biomass. We also used a series of generalized additive models to explore differences in seasonal abundance by species and found that all three cyclopoid copepod species ( Diacyclops thomasi, Mesocylops edax, Tropocyclops prasinus mexicanus ) exhibited higher abundance in 1983–1984 than in 2007. Surprisingly, only one ( Epischura lacustris ) of seven calanoid species exhibited higher abundance in 2007. The results for cladocerans were also mixed with Bosmina spp. exhibiting higher abundance in 1983–1984, while Daphnia galeata mendotae reached a higher level of abundance in 2007. We used a subset of the 2007 data to estimate not only the vertical distribution of Bythotrephes longimanus and their prey, but also the consumption by Bythotrephes in the top 20 m of water. This epilimnetic layer was dominated by copepod copepodites and nauplii, and consumption either exceeded (Hammond Bay site) or equaled 65% (Detour site) of epilimnetic zooplankton production. The lack of spatial overlap between Bythotrephes and herbivorous cladocerans and cyclopoid copepod prey casts doubt on the hypothesis that Bythotrephes planktivory was the primary driver underlying the community composition changes in the 2000s.

Lake Huron↗

Organic petrology of Paleocene Marcelina Formation coals, Paso Diablo mine, western Venezuela: Tectonic controls on coal type

About 7??Mt of high volatile bituminous coal are produced annually from the four coal zones of the Upper Paleocene Marcelina Formation at the Paso Diablo open-pit mine of western Venezuela. As part of an ongoing coal quality study, we have characterized twenty-two coal channel samples from the mine using organic petrology techniques. Samples also were analyzed for proximate-ultimate parameters, forms of sulfur, free swelling index, ash fusion temperatures, and calorific value. Six of the samples represent incremental benches across the 12-13??m thick No. 4 bed, the stratigraphically lowest mined coal, which is also mined at the 10??km distant Mina Norte open-pit. Organic content of the No. 4 bed indicates an upward increase of woody vegetation and/or greater preservation of organic material throughout the life of the original mire(s). An upward increase in telovitrinite and corresponding decrease in detrovitrinite and inertinite illustrate this trend. In contrast, stratigraphically higher coal groups generally exhibit a 'dulling upward' trend. The generally high inertinite content, and low ash yield and sulfur content, suggest that the Paso Diablo coals were deposited in rain-fed raised mires, protected from clastic input and subjected to frequent oxidation and/or moisture stress. However, the two thinnest coal beds (both 0.7??m thick) are each characterized by lower inertinite and higher telovitrinite content relative to the rest of Paso Diablo coal beds, indicative of less well-established raised mire environments prior to drowning. Foreland basin Paleocene coals of western Venezuela, including the Paso Diablo deposit and time-correlative coal deposits of the Ta??chira and Me??rida Andes, are characterized by high inertinite and consistently lower ash and sulfur relative to Eocene and younger coals of the area. We interpret these age-delimited coal quality characteristics to be due to water availability as a function of the tectonic control of subsidence rate. It is postulated that slower subsidence rates dominated during the Paleocene while greater foreland basin subsidence rates during the Eocene-Miocene resulted from the loading of nappe thrust sheets as part of the main construction phases of the Andean orogen. South-southeastward advance and emplacement of the Lara nappes during the oblique transpressive collision of the Caribbean and South American tectonic plates in the Paleocene was further removed from the sites of peat deposition, resulting in slower subsidence rates. Slower subsidence in the Paleocene may have favored the growth of raised mires, generating higher inertinite concentrations through more frequent moisture stress. Consistently low ash yield and sulfur content would be due to the protection from clastic input in raised mires, in addition to the leaching of mineral matter by rainfall and the development of acidic conditions preventing fixation of sulfur. In contrast, peat mires of Eocene-Miocene age encountered rapid subsidence due to the proximity of nappe emplacement, resulting in lower inertinite content, higher and more variable sulfur content, and higher ash yield.

International Journal of Coal Geology↗

Structured heterogeneity in a marine terrace chronosequence: Upland mottling

Soil mottles generally are interpreted as a product of reducing conditions during periods of water saturation. The upland soils of the Santa Cruz, CA, marine terrace chronosequence display an evolving sequence of reticulate mottling from the youngest soil (65 ka) without mottles to the oldest soil (225 ka) with well-developed mottles. The mottles consist of an interconnected network of clay and C-enriched regions (gray, 2.5Y 6/1) bordered by leached parent material (white, 2.5Y 8/1) within a diminishing matrix of oxidized parent material (orange, 7.5YR 5/8). The mottles develop in soils that formed from relatively uniform nearshore sediments and occur below the depth of soil bioturbation. To explore how a presumably wetland feature occurs in an unsaturated upland soil, physical and chemical characteristics of mottle separates (orange, gray, and white) were compared through the deep time represented by the soil chronosequence. Mineralogical, isotopic, and surface-area differences among mottle separates indicate that rhizogenic centimeter-scale mass transfer acting across millennia is an integral part of weathering, pedogenesis, and C and nutrient transfer. Elemental analysis, electron microscopy, and Fe-isotope systematics indicate that mottle development is driven by deep roots together with their fungal and microbial symbionts. Taken together, these data suggest that deep soil horizons on old stable landforms can develop reticulate mottling as the long-term imprint of rhizospheric processes. The processes of rhizogenic mottle formation appear to regulate pedogenesis, nutrients, and C sequestration at depth in unsaturated zones.

California↗

Hydrochemical determination of source water contributions to Lake Lungo and Lake Ripasottile (central Italy)

Lake Lungo and Lake Ripasottile are two shallow (4-5 m) lakes located in the Rieti Basin, central Italy, that have been described previously as surface outcroppings of the groundwater table. In this work, the two lakes as well as springs and rivers that represent their potential source waters are characterized physio-chemically and isotopically, using a combination of environmental tracers. Temperature and pH were measured and water samples were analyzed for alkalinity, major ion concentration, and stable isotope (δ2H, δ18O, δ13C of dissolved inorganic carbon, and δ34S and δ18O of sulfate) composition. Chemical data were also investigated in terms of local meteorological data (air temperature, precipitation) to determine the sensitivity of lake parameters to changes in the surrounding environment. Groundwater represented by samples taken from Santa Susanna Spring was shown to be distinct with SO42- and Mg2+ content of 270 and 29 mg/L, respectively, and heavy sulfate isotopic composition(δ34S=15.2 ‰ and δ18O=10‰). Outflow from the Santa Susanna Spring enters Lake Ripasottile via a canal and both spring and lake water exhibits the same chemical distinctions and comparatively low seasonal variability. Major ion concentrations in Lake Lungo are similar to the Vicenna Riara Spring and are interpreted to represent the groundwater locally recharged within the plain. The δ13CDIC exhibit the same groupings as the other chemical parameters, providing supporting evidence of the source relationships. Lake Lungo exhibited exceptional ranges of δ13CDIC (±5 ‰) and δ2H, δ18O (±5 ‰ and ±7 ‰, respectively), attributed to sensitivity to seasonal changes. The hydrochemistry results, particularly major ion data, highlight how the two lakes, though geographically and morphologically similar, represent distinct hydrochemical facies. These data also show a different response in each lake to temperature and precipitation patterns in the basin that may be attributed to lake water retention time. The sensitivity of each lake to meteorological patterns can be used to understand the potential effects from long-term climate variability.

Lake Lungo, Lake Ripasottile↗

Multiple oxygen and sulfur isotopic analyses on water-soluble sulfate in bulk atmospheric deposition from the southwestern United States

Sulfate is a major component of bulk atmospheric deposition (including dust, aerosol, fog, and rain). We analyzed sulfur and oxygen isotopic compositions of water-soluble sulfate from 40 sites where year-round dust traps collect bulk atmospheric deposition in the southwestern United States. Average sulfur and oxygen isotopic compositions (δ 34 S and δ 18 O) are 5.8 ± 1.4 (CDT) and 11.2 ± 1.9 (SMOW) (n = 47), respectively. Samples have an oxygen 17 anomaly (Δ 17 O), with an average value of 1.0 ± 0.6‰. Except for a weak positive correlation between δ 18 O and Δ 17 O values (r 2 ≈ 0.4), no correlation exists for δ 18 O versus δ 34 S, Δ 17 O versus δ 34 S, or any of the three isotopic compositions versus elevation of the sample site. Exceptional positive Δ 17 O values (up to 4.23‰) are found in samples from sites in the vicinity of large cities or major highways, and near-zero Δ 17 O values are found in samples close to dry lakes. Comparison of isotopic values of dust trap sulfate and desert varnish sulfate from the region reveals that varnish sulfate has average isotopic values that are ∼4.8‰ lower for δ 18 O, ∼2.1‰ higher for δ 34 S, and ∼0.3‰ lower for Δ 17 O than those of the present-day bulk deposition sulfate. Although other factors could cause the disparity, this observation suggests a possibility that varnish sulfate may have recorded a long-term atmospheric sulfate deposition during the Holocene or Pleistocene, as well as the differences between sulfur and oxygen isotopic compositions of the preindustrial bulk deposition sulfate and those of the industrial era.

Journal of Geophysical Research D: Atmospheres↗

Forecasting water levels using the ConvLSTM algorithm in the Everglades, USA

Forecasting water levels in complex ecosystems like wetlands can support effective water resource management, ecological conservation, and understanding surface and groundwater hydrology. Predictive models can be used to simulate the complex interactions among natural processes, hydrometeorological factors, and human activities. The Greater Everglades in the USA is a well-known example of an ecosystem where complexity has motivated adoption of machine learning algorithms in water level prediction studies. This paper aims to contribute to extending existing machine learning algorithms by integrating spatiotemporal data with deep-learning algorithms in the forecasting process. In this study, a deep-learning model is developed to predict water levels on a regional scale, covering a large area of approximately 9,138 square kilometers in the Everglades ecosystem. This model has the architecture of Convolutional Long Short-Term Memory which can deal with spatiotemporal data by capturing both spatial and temporal dependencies in the training data. The forecasting capabilities of this model (referred to as the global model) are assessed by comparing the global model to two Artificial Neural Networks developed at two different gaging stations, referred to here as local models. One local model is developed at a gaging station directly influenced by nearby water control structures, whereas the other is developed at a gaging station located farther away from these structures. By leveraging data from the Everglades Depth Estimation Network spanning from January 2002 to May 2023, the global and local models were trained to forecast water levels with a two-day lead time. Our findings suggest that both the global and local models perform with approximately the same level of accuracy, with Mean Absolute Relative Error values ranging from 0.38% to 1.4% at the selected stations. The developed global model has demonstrated strong potential as a standalone forecasting tool for the entire study area in the Everglades and could eliminate the need for developing multiple local models. This finding also highlights how machine learning can capture complex spatial and temporal relationships to generate accurate water level predictions on a regional scale.

Florida↗