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At least 811 records · Page 45Linked to original sources

Could blackbird mortality from avicide DRC-1339 contribute to avian botulism outbreaks in North Dakota?

Blackbird (family lcteridae) depredation on sunflower (Helianthus annuus) crops in the prairie states of the United States has motivated the proposed use of an avicide, DRC-1339 (3-chloro-4-methylaniline), to decrease their numbers. The resulting mortality of blackbirds at wetland roosts could increase the potential of avian botulism occurring in affected marshes. To assess this possibility, we seeded (artificially placed) blackbird carcasses in selected wetlands in Stutsman County, North Dakota, during August-September 2000 and July-September 2001 to evaluate their rate of decomposition and role in initiating avian botulism outbreaks. We monitored carcasses to determine their persistence, the frequency and amount of maggots produced, and the presence of type C botulinum toxin. In 10 of our 12 study wetlands, blackbird carcasses were not rapidly removed by scavengers, thus providing substrate for maggot growth and potential production of Clostridium botulinum toxin. Decomposition of carcasses occurred rapidly, and maggot production averaged 4a??5 g per carcass within 9 days. We were unable to detect C. botulinum type C toxin in any of the 377 blackbird carcasses or the 112 samples of maggots we collected in 2000 or 2001. None of the 25 blackbird carcasses we tested contained botulinum spores, the most probable explanation for the absence of botulinum toxin production. Our results indicate that the likelihood of DRC-1339-poisoned blackbirds causing botulism outbreaks would be minimal in North Dakota wetlands during late summer and early autumn.

North Dakota, South Dakota↗

Tectonic controls on magmatism in the Geysers-Clear Lake region: Evidence from new geophysical models

In order to study magmatism and geothermal systems in The Geysers–Clear Lake region, we developed a detailed three-dimensional tomographic velocity model based on local earthquakes. This high-resolution model resolves the velocity structure of the crust in the region to depths of approximately 12 km. The most significant velocity contrasts in The Geysers–Clear Lake region occur in the steam production area, where high velocities are associated with a Quaternary granitic pluton, and in the Mount Hannah region, where low velocities occur in a 5-km-thick section of Mesozoic argillites. In addition, a more regional tomographic model was developed using traveltimes from earthquakes covering most of northern California. This regional model sampled the whole crust, but at a lower resolution than the local model. The regional model outlines low velocities at depths of 8–12 km in The Geysers–Clear Lake area, which extend eastward to the Coast Range thrust. These low velocities are inferred to be related to unmetamorphosed Mesozoic sedimentary rocks. In addition, the regional velocity model indicates high velocities in the lower crust beneath the Clear Lake volcanic field, which we interpret to be associated with mafic underplating. No large silicic magma chamber is noted in either the local or regional tomographic models. A three-dimensional gravity model also has been developed in the area of the tomographic imaging. Our gravity model demonstrates that all density contrasts can be accounted for in the upper 5–7 km of the crust. Two-dimensional magnetotelluric models of data from a regional, east-west profile indicate high resistivities associated with the granitic pluton in The Geysers production area and low resistivities in the low-velocity section of Mesozoic argillites near Mount Hannah. No indication of midcrustal magma bodies is present in the magnetotelluric data. On the basis of heat flow and geologic evidence, Holocene intrusive activity is thought to have occurred near the Northwest Geysers, Mount Hannah, Sulphur Bank Mine, and perhaps other areas. The geophysical data provide no conclusive evidence for such activity, but the detailed velocity model is suggestive of intrusive activity near Mount Hannah similar to that in the “felsite” of The Geysers production area. The geophysical models, seismicity patterns, distribution of volcanic vents, heat flow, and other data indicate that small, young intrusive bodies that were injected along a northeast trend from The Geysers to Clear Lake probably control the thermal regime.

Geological Society of America Bulletin↗

Isotopic and chemical evidence concerning the genesis and contamination of basaltic and rhyolitic magma beneath the Yellowstone Plateau Volcanic Field

Since 2.2 Ma, the Yellowstone Plateau volcanic field has produced ∼6000 km 3 of rhyolite tuffs and lavas in >60 separate eruptions, as well as ∼ 100 km 3 of tholeiitic basalt from >50 vents peripheral to the silicic focus. Intermediate eruptive products are absent. Large calderas collapsed at 2·0, 1·3, and 0·6 Ma on eruption of ash-flow sheets representing at least 2500, 280, and 1000 km 3 of zoned magma. Early postcollapse rhyolites show large shifts in Nd, Sr, Pb, and O isotopic compositions caused by assimilation of roof rocks and hydrothermal brines during collapse and resurgence. Younger intracaldera rhyolite lavas record partial isotopic recovery toward precaldera ration. Thirteen extracaldera rhyolites show none of these effects and have sources independent of the subcaldera magma system. Contributions from the Archaean crust have extreme values and wide ranges of Nd-, Sr-, and Pb-isotope ratios, but Yellowstone rhyolites have moderate values and limited ranges. This requires their deep-crustal sources to have been pervasively hybridized (and the Archaean components diluted) by distributed intrusion of Cenozoic basalt, most of which was probably contemporaneous with the Pliocene and Qualernary volcanism. In hybrid sources yielding magmas parental to the subcaldera rhyolites, half or more of the Nd and Sr may have been contributed by such young basalt. Parents for the extracaldera rhyolites, generated beyond the leading edge of the northeast-propagating focus of basaltic intrusion and deep-crustal mobilization, contained smaller fractions of mantle-derived components.

Journal of Petrology↗

Static stress changes and the triggering of earthquakes

To understand whether the 1992 M = 7.4 Landers earthquake changed the proximity to failure on the San Andreas fault system, we examine the general problem of how one earthquake might trigger another. The tendency of rocks to fail in a brittle manner is thought to be a function of both shear and confining stresses, commonly formulated as the Coulomb failure criterion. Here we explore how changes in Coulomb conditions associated with one or more earthquakes may trigger subsequent events. We first consider a Coulomb criterion appropriate for the production of aftershocks, where faults most likely to slip are those optimally orientated for failure as a result of the prevailing regional stress field and the stress change caused by the mainshock. We find that the distribution of aftershocks for the Landers earthquake, as well as for several other moderate events in its vicinity, can be explained by the Coulomb criterion as follows: aftershocks are abundant where the Coulomb stress on optimally orientated faults rose by more than one-half bar, and aftershocks are sparse where the Coulomb stress dropped by a similar amount. Further, we find that several moderate shocks raised the stress at the future Landers epicenter and along much of the Landers rupture zone by about a bar, advancing the Landers shock by 1 to 3 centuries. The Landers rupture, in turn, raised the stress at site of the future M = 6.5 Big Bear aftershock site by 3 bars. The Coulomb stress change on a specified fault is independent of regional stress but depends on the fault geometry, sense of slip, and the coefficient of friction. We use this method to resolve stress changes on the San Andreas and San Jacinto faults imposed by the Landers sequence. Together the Landers and Big Bear earthquakes raised the stress along the San Bernardino segment of the southern San Andreas fault by 2 to 6 bars, hastening the next great earthquake there by about a decade.

Bulletin of the Seismological Society of America↗

Stages and epochs of mineralization in the San Juan Mountains, Colorado, as shown at the Dunmore Mine, Ouray County, Colorado

The Dunmore lode is localized along a persistent fissure zone over two miles long and averaging nearly 100 feet in width along the length of the Dunmore claim. The fault in which the lode is located offset the pre-Cambrian quartzite and slate walls about 4,500 feet prior to deposition of the overlying thick San Juan tuff. Late Tertiary faulting extended the fissure into the San Juan tuff, dropping the south side about 80 feet. Although most of the lode crops out in the pre-Cambrian rocks, it extends upward across the profound unconformity into the tuff. The lode is complex, containing sharply marked fissure veins, sheared slate dragged into the fault zone, a sheared dike, breccia chimneys, and pebble dikes. An assemblage consisting of quartz, sericite, kaolin, and pyrite appears to be of early Tertiary age. The more productive part of the lode, however, is late Tertiary and consists of a hematite chimney inclosing a copper shoot, a tungsten chimney, and compound base-metal fissure veins. These chimneys and veins are mostly localized along early Tertiary structures, but their mineral sequences correlate them with the second stage of late Tertiary deposition recognized by Burbank in the adjoining Red Mountain and other districts. The Dunmore lode, however, is believed to have been deposited at greater depth and higher temperature and nearer to a source of supply than the lodes of these districts. In structure as well as mineral assemblages the Dunmore lode shows a connection between the chimneys and veins of the region.

Colorado↗

Reconnaissance investigation of ground-water supply for Dora Belle Campground, Shaver Lake, California

At the request of the United States Forest Service, the Ground Water Branch of the United Stated Geological Survey made a reconnaissance of the geologic features and water resources of the Dora Belle Campground in Sierra National Forest on the shore of Shaver Lake, Fresno County, California. Basically, the water-supply problem at Dora Belle Campground is that the present supply obtained from a spring is not adequate to meet the present summer demand, and is of poor quality. Plans call for a considerable increase in camping facilities.. This, it is imperative that the present supply be augmented or, preferably, be replaced entirely. the Forest Service estimated the future peak demand to be about 25,00 gallons per day. On October 28, 1957, the writer examined the are in the company of C. H. Fankboner, Assistant Forest Engineer, Sierra National Forest, and Ben Dix, Construction and Maintenance Foreman, Pine Ridge District. Field work, done on October 28th and 29th, consisted of a brief geologic reconnaissance to determine the rock types and geologic structure, and a hydrologic reconnaissance consisting of a partial inventory of water walls and springs in the vicinity of the campground. A spring box near the western edge of Bell Diamond Meadow was pumped out with a Forest Service pump truck to determine its rate of recovery and potential production.

California↗

Geology of the Mackay 30-minute quadrangle, Idaho

The Jefferson Dolomite, Grand View Dolomite, and Three Forks Limestone, all of Devonian age, are the oldest rocks exposed in the quadrangle. Rocks that range from Mississippian to Permian in age are widespread; they are represented by the White Knob Limestone in the eastern part of the quadrangle and the Copper Basin Formation in the western part. The Copper Basin Formation, which is composed of non-carbonate detrital rocks, is interlayered with the White Knob Limestone near the middle of the quadrangle. This interlayering is herein interpreted to be the result of depositional interbedding, but it could be in part due to juxtaposition by faulting. The Challis Volcanics, of Tertiary age, cover much of the quadrangle, and except for a conspicuous basal conglomerate, lack distinctive subdivisions similar to those in neighboring areas. Alluvial deposits which may be in part as old as Pliocene are scattered through the quadrangle. Glaciation affected all higher parts of the quadrangle, and locally glacial deposits of at least three ages can be distinguished The latest two of these are probably of late Wisconsin Bull Lake and Pinedale ages. Basalt flows of probable Recent age extend into the southernmost part of the quadrangle and originate in part from vents there. Intrusive rocks, including plutons and related dikes of Tertiary age, are scattered throughout the quadrangle. They range from granite to quartz diorite in composition. The intrusive rocks seem to be related to the Challis Volcanics. The rocks of the quadrangle were strongly deformed and eroded prior to the deposition of the Challis Volcanics. No thrust faults have been recognized although such faults are plentiful in the adjacent region. Deformation has continued until recent times. All or parts of five mining districts are included in the quadrangle, and the total production probably exceeded $10,000,000. Mining has been quiet since World War II but activity has been renewed at times in the past and possibilities for the discovery of substantial new deposits seem promising. The mineral deposits formed largely by replacement, partly in areas of contact metamorphism. The metals present are varied but copper has been the main product. All of the deposits are believed to be related to the intrusions of Tertiary age.

Open-File Report↗

Preliminary map showing freshwater heads for the Mission Canyon and Lodgepole limestones and equivalent rocks of Mississippian age in the Northern Great Plains of Montana, North Dakota, South Dakota, and Wyoming

A potentiometric-surface map showing freshwater heads for the Mission Canyon and Lodgepole Limestones of Mississippian age has been prepared as part of a study to determine the water-resources potential of the Mississippian Madison Limestone and associated rocks in the Northern Great Plains of Montana, North and South Dakota, and Wyoming. Most of the data used to prepare the map are from drill-stem tests of exploration and development wells drilled by the petroleum industry from 1946 to 1978. Some data are also from cased oil wells, water-production wells, and springs. A short explanation describes the seven categories of reliability used to evaluate the drill-stem-test data and identifies several factors that might explain the apparent anomalous highs and lows on the potentiometric surface. The map is at a scale of 1:1,000,000 and the potentiometric contour intervals are 100, 200, and 500 feet. (USGS)

Open-File Report↗

Geology and ground-water resources of the Lake Dakota Plain area, South Dakota

The Lake Dakota plain area is a nearly flat surface that includes parts of Spink, Brown, Marshall, and Day Counties in northeastern South Dakota. Agriculture is the principal occupation. Because precipitation often is insufficient for maximum crop production, the U.S. Bureau of Reclamation has developed a plan for irrigation of the area. Most of the irrigation water would be conveyed by canal from a reservoir on the Missouri River, about 100 miles to the west, but some would be obtained locally from the James River. The surface of the Precambrian rocks, which underlie the area at a depth of 1,200 to 1,500 feet, is the lower limit to which water wells are drilled. Most of the producing wells in the area tap the Dakota sandstone, which has an average thickness of about 400 feet and rests on the Precambrian rocks. The Dakota is not recharged locally; water percolates into the Lake Dakota plain area principally from areas of recharge to the west. Because the aggregate discharge from wells tapping the Dakota exceeds the estimated rate of lateral percolation into the area, some of the discharged water probably is derived from storage. Although the artesian pressure is still sufficient to cause wells to flow, it is much less now than it was when the first wells were drilled in the 1880's. Water from the Dakota is highly mineralized; the specific conductance of water from 71 wells ranged from 2,590 to 4,380 micromhos per centimeter. Most of the water was of the sodium sulfate type and was soft. By recognized standards the water is chemically unsuitable for most uses, but for many years it has been the principal source of supply both on farms and in the municipalities. Use of the water for irrigation is reported to have made the soil unproductive. The Dakota is overlain by younger Cretaceous rocks aggregating 700 to 800 feet in thickness. These rocks, which consist of shale and limestone, generally are too nearly impermeable to be a source of water supply. Unconsolidated deposits of Quaternary age mantle the Cretaceous rocks. Although they consist mostly of material that is too fine grained to yield water freely to wells, the Quaternary deposits contain bodies of moderately to highly permeable material that yield water copiously. Such bodies may be located only by exploratory drilling or, possibly, geophysical methods. The water differs widely in amount of mineralization and in chemical composition; the specific conductance of water from 322 wells ranged from 246 to 13,300 micromhos per centimeter. In most of the report area the water is of unsuitable quality for irrigation and domestic use. The principal source of recharge to the Quaternary deposits is infiltrating precipitation. Evapotranspiration accounts for nearly all the water discharged; the amount of water discharging into stream channels and withdrawn from wells is almost negligible by comparison. Irrigation of the area would increase the rate of recharge to the Quaternary deposits and would cause the water table to rise. Probably it would also cause an increase in the concentration of dissolved minerals in much of the ground water. Artificial drainage would be necessary to prevent waterlogging of cropland.

South Dakota↗

Opal-A in glassy pumice, acid alteration, and the 1817 phreatomagmatic eruption at Kawah Ijen (Java), Indonesia

At Kawah Ijen (Indonesia), vigorous SO 2 and HCl degassing sustains a hyperacid lake (pH ~0) and intensely alters the subsurface, producing widespread residual silica and advanced argillic alteration products. In 1817, a VEI 2 phreatomagmatic eruption evacuated the lake, depositing a widespread layer of muddy ash fall, and sending lahars down river drainages. We discovered multiple types of opaline silica in juvenile low-silica dacite pumice and in particles within co-erupted laharic sediments. Most spectacular are opal-replaced phenocrysts of plagioclase and pyroxene adjacent to pristine matrix glass and melt inclusions. Opal-bearing pumice has been found at numerous sites, including where post-eruption infiltration of acid water is unlikely. Through detailed analyses of an initial sampling of 1817 eruption products, we find evidence for multiple origins of opaline materials in pumice and laharic sediments. Evidently, magma encountered acid-altered materials in the subsurface and triggered phreatomagmatic eruptions. Syn-eruptive incorporation of opal-alunite clasts, layered opal, and fragment-filled vesicles of opal and glass, all suggest magma-rock interactions in concert with vesiculation, followed by cooling within minutes. Our experiments at magmatic temperature confirm that the opaline materials would show noticeable degradation in time periods longer than a few tens of minutes. Some glassy laharic sedimentary grains are more andesitic than the main pumice type and may represent older volcanic materials that were altered beneath the lake bottom and were forcefully ejected during the 1817 eruption. A post-eruptive origin remains likely for most of the opal-replaced phenocrysts in pumice. Experiments at 25°C and 100°C reveal that when fresh pumice is bathed in Kawah Ijen hyperacid fluid for 6 weeks, plagioclase is replaced without altering either matrix glass or melt inclusions. Moreover, lack of evidence for high-temperature annealing of the opal suggests that post-eruption alteration of pumice is more likely than pre-eruption envelopment of euhedral opal-replaced phenocrysts in dacitic melt. At Ijen and elsewhere, the ascent of magma into hydrous acid-altered mineral assemblages (e.g., opal, kaolinite, alunite) could induce rapid dehydration of hydrous minerals and amorphous materials, generating considerable steam and contributing to magmatic-hydrothermal and phreatomagmatic explosions.

Kawah Ijen↗

Conventional rare earth element mineral deposits: The global landscape

Four conventional mineral deposit types—carbonatite, alkaline igneous, heavy mineral sand, and regolith-hosted ion-adsorption clay deposits—currently supply global markets with the rare earth elements (REEs) and rare earth oxides (REOs) necessary to meet the technological needs of global communities. The unique properties of REEs make them useful in a wide variety of applications, such as alloys, batteries, catalysts, magnets, phosphors, and polishing compounds. Rare earth element minerals are complex in both composition and structure. Carbonate, oxide, silicate, and phosphate-type minerals contain highly variable amounts of rare earths. Most rare earth-bearing minerals contain mainly lighter rare earths, a mixture of all the rare earths, or only the heavier rare earths. Diverse technological applications require the full range of light, middle, and heavy rare earths. The production of these elements, in particular the heavy rare earths, remains highly dependent on deposits from China. Diversification of rare earth supply chains is contingent on expanded knowledge of globally distributed resources and an understanding of the degree to which those resources have been explored and evaluated. The knowledge of tectonic setting, typical rock associations, deposit morphology, and deposit genesis has led to the discovery of many conventional-type rare earth deposit types. Recent developments are anticipated to result in further discoveries that have the potential to meet the ever-expanding applications of REEs and REOs to address modern societal needs.

Book chapter↗

Airborne radiometric data map alteration of porphyry copper systems in the Elkhorn district, MT

The Elkhorn district in southwestern Montana is known for past production of high-grade base and precious metals from skarn and carbonate replacement deposits. The district also hosts a porphyry Cu-Mo deposit. A radiometric survey flown over the district and surrounds provides maps of surficial concentrations of potassium, thorium, and uranium. Handheld gamma ray spectrometer measurements on altered and unaltered rocks in the district and surrounding region provide a means to ground truth the airborne data. We demonstrate that the airborne and ground-based measurements show similar map patterns. We calculate ratios of the radioelement concentrations and present a potassium enhancement map that combines potassium and ratios of potassium to thorium and uranium. The results highlight the rocks previously mapped as having K-feldspar-biotite and quartz-sericite alteration assemblages in the Elkhorn district and map additional hydrothermal systems in the region, including known alteration in the Radersburg district. The data enhancement techniques can be used as a screening tool for mapping additional porphyry copper systems.

Montana↗

The ~400 yr B.P. eruption of Half Cone, a post-caldera composite cone within Aniakchak caldera, Alaska Peninsula

Aniakchak volcano is a historically active caldera located on the central Alaska Peninsula. The largest eruption from Aniakchak since the ~3,400 yr B.P. caldera-forming eruption occurred ~400 yr B.P. from Half Cone volcano, an intracaldera composite cone on the northwest floor of the Aniakchak caldera that was largely destroyed by the eruption. The ~400 yr B.P. eruption produced a widely dispersed pumice fall deposit known as the Pink and Brown Pumice. Following small phreatomagmatic explosions, a buoyant Plinian eruption column combined with southwesterly winds dispersed ~1.3 km3 of crystal-poor dacite (66.1–67.1% SiO2) Pink Pumice at least 70 km to the northeast from Half Cone (~0.05 km3 dense rock equivalent; DRE). Fluctuations in the diameters of pyroclasts and accidental lithics in the Pink Pumice indicate at least two cycles of waxing and waning mass flux at the Half Cone vent. This vent produced an eruption column that twice expanded and gained altitudes of ~15–20 km before weakening to lower altitudes. Brown Pumice scoria (58.2– 66.9% SiO2) as well as compositionally banded pyroclasts at the top of the Pink Pumice indicate that both dacite magma and an increasing amount of low-SiO2 (58.2–60.5% SiO2) andesite magma were erupted simultaneously during the transition to the Brown Pumice phase of the eruption. The reversely graded Brown Pumice fall deposit records an escalating Plinian column dominated by low-SiO2 Brown Pumice scoria that reached altitudes of ~20–24 km and led to the emplacement of least ~3.5 km3 of fall deposits up to at least 230 km to the northeast (~1 km3 DRE). Over time, the Brown Pumice eruption column repeatedly experienced partial collapse that ultimately produced thick pyroclastic density current deposits, most of which were confined to within the caldera. Lithic-rich agglutinate and spatter exposed in 60-m-thick deposits atop the severed flanks of Half Cone and within ~2 km of Half Cone were emplaced at the end of the Brown Pumice phase. Agglutinate deposits range from 58.6 to.64.8% SiO2, which generally falls in the compositional range between Brown and Pink Pumice compositional endmembers. Most of the Half Cone edifice was destroyed by the end of the Brown Pumice phase. The ~0.1 km3 crystal-rich dacitic Cobweb lava flow (64.8–65.8% SiO2) filled a basin left behind by the destruction of Half Cone as a series of radiating lobes. Subsequently, a small andesitic tuff cone (62.2–62.8% SiO2) formed over the Cobweb lava flow vent. In all, we estimate that at least ~5.4 km3 of tephra and ~0.1 km3 of lava erupted during the ~400 yr B.P. eruption, yielding a total magmatic volume (DRE) of ~1.3 km3. Titanomagnetite-ilmenite pairs in Pink and Brown Pumice samples record similar equilibrium temperature ranges (944–997 °C and 959–985 °C, respectively) but different fO2 conditions—Pink Pumice pairs plot between NNO and NNO +0.5, Brown Pumice pairs plot below the NNO buffer. Titanomagnetite-ilmenite pairs in Brown Pumice agglutinate record a wider range of temperatures than either Pink or Brown Pumice samples (899–1018 °C) but also show two populations of fO2—one that overlaps the Pink Pumice array at higher fO2 and one that overlaps the Brown Pumice array at lower fO2. Titanomagnetite-ilmenite pairs from the Cobweb lava flow have the largest fO2 range (NNO -0.5 to NNO +0.5), although most pairs overlap Brown Pumice samples at lower fO2 conditions near NNO -0.5. Pairs in Cobweb lava samples record temperatures from 837 to 1054 °C, which is the largest temperature range recorded in deposits emplaced during any phase of the ~400 yr B.P. eruption. Geothermometry results of titanomagnetite-ilmenite pairs in ≤3,400 yr B.P. samples erupted from Aniakchak volcano record a similar temperature range and the presence of two fO2 arrays as the ~400 yr B.P. samples, which implies the existence of two magma regions of the mush column; each the product of slightly different evolution. In addition, results from in situ compositional analyses of plagioclase suggest that the ~400 yr B.P. eruption may have been initiated, at least in part, by intrusion of basaltic magma, which ascended from the lower crust into the shallow subvolcanic magma mush column prior to and during eruption. The bimodal distribution of whole-rock compositions and the two plagioclase populations in the low-SiO2 Brown Pumice—one defined by An40–An60 cores and one defined by An79–An95 cores—is consistent with an abbreviated period of mixing between intruding basalt and resident dacite mush prior to eruption. Progressive mixing between mafic and felsic magmas during and after the eruption likely produced the subsequently erupted Cobweb lava flow, which has an intermediate composition with abundant mineral disequilibria. Aniakchak volcano continues to show episodic signs of unrest, suggesting that eruptions will occur in the future.

Alaska↗

Mineral-deposit model for lithium-cesium-tantalum pegmatites

Lithium-cesium-tantalum (LCT) pegmatites comprise a compositionally defined subset of granitic pegmatites. The major minerals are quartz, potassium feldspar, albite, and muscovite; typical accessory minerals include biotite, garnet, tourmaline, and apatite. The principal lithium ore minerals are spodumene, petalite, and lepidolite; cesium mostly comes from pollucite; and tantalum mostly comes from columbite-tantalite. Tin ore as cassiterite and beryllium ore as beryl also occur in LCT pegmatites, as do a number of gemstones and high-value museum specimens of rare minerals. Individual crystals in LCT pegmatites can be enormous: the largest spodumene was 14 meters long, the largest beryl was 18 meters long, and the largest potassium feldspar was 49 meters long. Lithium-cesium-tantalum pegmatites account for about one-fourth of the world’s lithium production, most of the tantalum production, and all of the cesium production. Giant deposits include Tanco in Canada, Greenbushes in Australia, and Bikita in Zimbabwe. The largest lithium pegmatite in the United States, at King’s Mountain, North Carolina, is no longer being mined although large reserves of lithium remain. Depending on size and attitude of the pegmatite, a variety of mining techniques are used, including artisanal surface mining, open-pit surface mining, small underground workings, and large underground operations using room-and-pillar design. In favorable circumstances, what would otherwise be gangue minerals (quartz, potassium feldspar, albite, and muscovite) can be mined along with lithium and (or) tantalum as coproducts. Most LCT pegmatites are hosted in metamorphosed supracrustal rocks in the upper greenschist to lower amphibolite facies. Lithium-cesium-tantalum pegmatite intrusions generally are emplaced late during orogeny, with emplacement being controlled by pre-existing structures. Typically, they crop out near evolved, peraluminous granites and leucogranites from which they are inferred to be derived by fractional crystallization. In cases where a parental granite pluton is not exposed, one is inferred to lie at depth. Lithium-cesium-tantalum LCT pegmatite melts are enriched in fluxing components including H2O, F, P, and B, which depress the solidus temperature, lower the density, and increase rates of ionic diffusion. This, in turn, enables pegmatites to form thin dikes and massive crystals despite having a felsic composition and temperatures that are significantly lower than ordinary granitic melts. Lithium-cesium-tantalum pegmatites crystallized at remarkably low temperatures (about 350–550 °C) in a remarkably short time (days to years). Lithium-cesium-tantalum pegmatites form in orogenic hinterlands as products of plate convergence. Most formed during collisional orogeny (for example, Kings Mountain district, North Carolina). Specific causes of LCT pegmatite-related magmatism could include: ordinary arc processes; over thickening of continental crust during collision or subduction; slab breakoff during or after collision; slab delamination before, during, or after collision; and late collisional extensional collapse and consequent decompression melting. Lithium-cesium-tantalum pegmatite deposits are present in all continents including Antarctica and in rocks spanning 3 billion years of Earth history. The global age distribution of LCT pegmatites is similar to those of common pegmatites, orogenic granites, and detrital zircons. Peak times of LCT pegmatite genesis at about 2640, 1800, 960, 485, and 310 Ma (million years before present) correspond to times of collisional orogeny and supercontinent assembly. Between these pulses were long intervals when few or no LCT pegmatites formed. These minima overlap with supercontinent tenures at ca. 2450–2225, 1625–1000, 875–725, and 250–200 Ma. Exploration and assessment for LCT pegmatites are guided by a number of observations. In frontier areas where exploration has been minimal at best, the key first-order criteria are an orogenic hinterland setting, appropriate regional metamorphic grades, and the presence of evolved granites and common granitic pegmatites. New LCT pegmatites are most likely to be found near known deposits. Pegmatites tend to show a regional mineralogical and geochemical zoning pattern with respect to the inferred parental granite, with the greatest enrichment in the more distal pegmatites. Mineral-chemical trends in common pegmatites that can point toward an evolved LCT pegmatite include: increasing rubidium in potassium feldspar, increasing lithium in white mica, increasing manganese in garnet, and increasing tantalum and manganese in columbite-tantalite. Most LCT pegmatite bodies show a distinctive internal zonation featuring four zones: border, wall, intermediate (where lithium, cesium, and tantalum are generally concentrated), and core. This zonation is expressed both in cross section and map view; thus, what may appear to be a common pegmatite may instead be the edge of a mineralized body. Neither lithium-cesium-tantalum pegmatites nor their parental granites are likely to cause serious environmental concerns. Soils and country rock surrounding a LCT pegmatite, as well as waste from mining operations, may be enriched in characteristic elements relative to global average soil and bedrock values. These elements may include lithium, cesium, tantalum, beryllium, boron, fluorine, phosphorus, manganese, gallium, rubidium, niobium, tin, and hafnium. Among this suite of elements, however, the only ones that might present a concern for environmental health are beryllium and fluorine, which are included in the U.S. Environmental Protection Agency drinking-water regulations with maximum contaminant levels of 4 micrograms per liter and 4 milligrams per liter, respectively.

Scientific Investigations Report↗

Aluminum resources of Brazil

Large deposits of bauxite, the principal ore of aluminum, occur at several places in Brazil. The largest deposits now undergoing extensive exploration and development are in the eastern Amazon Basin. Most of these deposits are in the State of Para, but some are in Amazonas and Maranhao. Discovery of large-scale resources of bauxite in the Amazon Region is so recent that mining has not begun, but government geologists estimate the total resources in aluminum deposits in the lower Amazon to be in the multibillion ton range. The annual production rate of bauxite ore in Brazil, much of it from Pops de Caldas in Minas Gerais, is about 760,000 metric tons of ore from which about 100,000 tons of aluminum metal is produced, most of which is consumed by Brazilian industry. The Amazon bauxite deposits are on terraces formed on sedimentary rocks of Tertiary age; in Minas Gerais the deposits are formed on Precambrian metasedimentary rock, and at Poos de Caldas on a circular alkalic pluton of Cretaceous age.

Open-File Report↗

Geology of the Southern Appalachian Mountains

The Southern Appalachian Mountains includes the Blue Ridge province and parts of four other physiographic provinces. The Blue Ridge physiographic province is a high, mountainous area bounded by several named mountain ranges (including the Unaka Mountains and the Great Smoky Mountains) to the northwest, and the Blue Ridge Mountains to the southeast. Metamorphic rocks of the mountains include (1) fragments of a billion-year-old supercontinent, (2) thick sequences of sedimentary rock that were deposited in subsiding (sinking) basins on the continent, (3) sedimentary and volcanic rocks that were deposited on the sea floor, and (4) fragments of oceanic crust. Most of the rocks formed as sediments or volcanic rocks on ocean floors, islands, and continental plates; igneous rocks formed when crustal plates collided, beginning about 450 million years ago. The collision between the ancestral North American and African continental plates ended about 270 million years ago. Then, the continents began to be stretched, which caused fractures to open in places throughout the crust; these fractures were later filled with sediment. This product (U.S. Geological Survey Scientific Investigations Map 2830) consists of a geologic map of the Southern Appalachian Mountains overlain on a shaded-relief background. The map area includes parts of southern Virginia, eastern West Virginia and Tennessee, western North and South Carolina, northern Georgia and northeastern Alabama. Photographs of localities where geologic features of interest can be seen accompany the map. Diagrams show how the movement of continental plates over many millions of years affected the landscapes seen today, show how folds and faults form, describe important mineral resources of the region, and illustrate geologic time. This two-sided map is folded into a convenient size (5x9.4 inches) for use in the field. The target audience is high school to college earth science and geology teachers and students; staffs of educational and interpretive programs within Federal, State, and private agencies; and tourists and residents of the Southern Appalachian region who want to know more about the area. The map is companion to the DVD, 'The Southern Appalachians, a Changing World' (http://pubs.usgs.gov/gip/so_app/) and the Teacher's Guide and brochure, 'Birth of the Mountains' (http://pubs.usgs.gov/gip/birth). The map shows the location of sites that are featured in these publications.

Scientific Investigations Map↗

Status of and changes in water quality monitored for the Idaho statewide surface-water-quality network, 1989—2002

The Idaho statewide surface-water-quality monitoring network consists of 56 sites that have been monitored from 1989 through 2002 to provide data to document status and changes in the quality of Idaho streams. Sampling at 33 sites has covered a wide range of flows and seasons that describe water-quality variations representing both natural conditions and human influences. Targeting additional high- or low-flow sampling would better describe conditions at 20 sites during hydrologic extremes. At the three spring site types, sampling covered the range of flow conditions from 1989 through 2002 well. However, high flows at these sites since 1989 were lower than historical high flows as a result of declining ground-water levels in the Snake River Plain. Summertime stream temperatures at 45 sites commonly exceeded 19 and 22 degrees Celsius, the Idaho maximum daily mean and daily maximum criteria, respectively, for the protection of coldwater aquatic life. Criteria exceedances in stream basins with minimal development suggest that such high temperatures may occur naturally in many Idaho streams. Suspended-sediment concentrations were generally higher in southern Idaho than in central and northern Idaho, and network data suggest that the turbidity criteria are most likely to be exceeded at sites in southern Idaho and other sections of the Columbia Plateaus geomorphic province. This is probably because this province has more fine-grained soils that are subject to erosion and disturbance by land uses than the Northern Rocky Mountains province of northern and central Idaho has. Although erodable soils are likely a cause of elevated turbidities, suspended-sediment concentrations were not strongly correlated with turbidities. Dissolved-solids and hardness concentrations were strongly correlated. This is probably because the limestones present in some basins are more soluble than the igneous rocks that predominate in others. Low hardness in streams of northern Idaho, where watersheds are underlain by resistant igneous rocks, enhances the toxicity of some trace elements to aquatic life in these streams. Only a few measurements of dissolved-oxygen concentrations at six sites were less than 6.0 milligrams per liter, the Idaho minimum criterion for protection of aquatic organisms. High supersaturations of dissolved oxygen at four sites suggest excessive photosynthetic activity by algal communities. Nighttime monitoring would help determine whether dissolved-oxygen concentrations at these sites might fall below the Idaho criterion. Data from four sites suggest that dissolved-oxygen concentrations may have decreased over time. The pH at 15 sites sometimes fell outside the range specified (6.5-9.0) for the protection of aquatic organisms in Idaho streams. Values exceeded 9.0 at 10 sites, probably because of excessive algal photosynthetic activity in waters where carbonate rocks are present. Values were sometimes less than 6.5 at five sites in areas of mountain bedrock geology where pH is likely to be naturally low. Mining activities also may contribute to low pH at some of these sites. Inorganic nitrogen and total phosphorus concentrations commonly exceeded those considered sufficient for supporting excess algal production (0.3 and 0.1 milligrams per liter, respectively). Data from a few sites suggest that nitrogen and(or) phosphorus concentrations might be changing over time. Low concentrations of nitrogen and phosphorus at six sites, most representing forested basins, might make them good candidates as reference sites that represent naturally occurring nutrient concentrations. Trace elements examined for this report were cadmium, copper, lead, mercury, selenium, and zinc. In water, many trace-element concentrations were below the minimum analytical reporting levels. Concentrations of cadmium, copper, lead, and zinc generally were highest in mined and other mineral-rich basins in northern Idaho. Concentrations of mercury were

Idaho↗

Mineral thermometry and fluid inclusion studies of the Pea Ridge iron oxide-apatite–rare earth element deposit, Mesoproterozoic St. Francois Mountains Terrane, southeast Missouri, USA

Mineral thermometry and fluid inclusion studies were conducted on variably altered and mineralized samples from the Mesoproterozoic Pea Ridge iron oxide-apatite (IOA)-rare earth element (REE) deposit in order to constrain P-T conditions, fluid chemistry, and the source of salt and volatiles during early magnetite and later REE mineralization. Scanning electron microscopy (SEM)-cathodoluminescence and SEM-backscatter electron images show that quartz and rutile precipitated before, during, and after magnetite and REE mineral growth. Ti-in-quartz and Zr-in-rutile equilibration temperatures range from ≤350° to 750°C in the amphibole, magnetite, hematite, and silicified zones where T increased during magnetite and quartz growth and dropped precipitously after fracturing and brecciation. Late drusy quartz cements within a REE-rich breccia pipe record the lowest T (≤315°–400°C). Liquid-, vapor-rich, and hypersaline (±hematite, calcite) fluid inclusions are common and liquid CO 2 is present locally. Salinities define three populations: saline (10–27 wt % NaCl equiv), hypersaline (34–>60 wt % NaCl equiv), and dilute (0–10 wt % NaCl equiv ). The wide range of eutectic melting temperatures (−67° to −19°C) suggests that saline inclusions trapped variable proportions of a CaCl-MgCl-FeCl-bearing fluid end member and an NaCl-KCl fluid end member. Homogenization temperatures and pressures of these saline inclusions suggest they were trapped when fluids unmixed into brine and vapor at T <350°C, P <15 MPa, and a depth of ~1.5 km. Hypersaline inclusions were trapped at low T and P (~200°C and ~1 MPa) along the V + L + H curve when the system vented to the paleosurface. Data for dilute inclusions in late drusy quartz from the REE-rich breccia pipe are indicative of a boiling epithermal environment. The Na/Cl, Na/K, and Cl/Br ratios of fluid inclusion extracts provide evidence for mixtures of magmatic hydrothermal fluids and evaporated seawater. Extracts from magnetite, hematite, and pyrite plot in the magmatic-hydrothermal field, indicating that Fe was derived from a magmatic source. Their enrichments in Mg and Ca are consistent with a mafic magmatic source. The positive correlation between Na/Mg and Na/Ca ratios may be due to halite saturation or albitization of igneous rocks. Extracts from barite in the REE-rich breccia pipes are enriched in Na and Br and plot near the seawater evaporation trend. He is highly enriched relative to Ne and Ar in fluid inclusion extracts, which precludes air as a source of He. Although the He is mostly of crustal origin, pyrite with a 3 He/ 4 He (R/R A ) of 0.1 contains up to 12% mantle He. Many extracts have low 20 Ne/ 22 Ne ratios due to nucleogenic production of 22 Ne in high F/O minerals such as fluorapatite or F biotite. The arrays of data for 3 He/ 4 He (R/R A ) and 22 Ne/ 20 Ne suggest that volatiles were derived from two sources, a moderate F mafic magma containing mantle He and a high F silicic magma with crustal He. Together with other evidence cited in this report, these data (1) support a magmatic hydrothermal origin for the Mesoproterozoic magnetite-apatite deposit with ore fluids derived from a concealed mafic to intermediate-composition intrusion, (2) suggest that the REE minerals in breccia pipes were either derived from apatite or precipitated in response to decompression and cooling during breccia pipe formation, (3) provide evidence for the influx of basinal brine, magmatic fluids from granitic intrusions, and meteoric water after breccia pipe formation, and (4) show that Pea Ridge was relatively unaffected by the late Paleozoic Mississippi Valley-type (MVT) Pb-Zn system in overlying Cambrian sedimentary rocks.

Missouri↗