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Death Valley regional ground-water flow system, Nevada and California -- hydrogeologic framework and transient ground-water flow model

A numerical three-dimensional (3D) transient ground-water flow model of the Death Valley region was developed by the U.S. Geological Survey for the U.S. Department of Energy programs at the Nevada Test Site and at Yucca Mountain, Nevada. Decades of study of aspects of the ground-water flow system and previous less extensive ground-water flow models were incorporated and reevaluated together with new data to provide greater detail for the complex, digital model. A 3D digital hydrogeologic framework model (HFM) was developed from digital elevation models, geologic maps, borehole information, geologic and hydrogeologic cross sections, and other 3D models to represent the geometry of the hydrogeologic units (HGUs). Structural features, such as faults and fractures, that affect ground-water flow also were added. The HFM represents Precambrian and Paleozoic crystalline and sedimentary rocks, Mesozoic sedimentary rocks, Mesozoic to Cenozoic intrusive rocks, Cenozoic volcanic tuffs and lavas, and late Cenozoic sedimentary deposits of the Death Valley Regional Ground-Water Flow System (DVRFS) region in 27 HGUs. Information from a series of investigations was compiled to conceptualize and quantify hydrologic components of the ground-water flow system within the DVRFS model domain and to provide hydraulic-property and head-observation data used in the calibration of the transient-flow model. These studies reevaluated natural ground-water discharge occurring through evapotranspiration and spring flow; the history of ground-water pumping from 1913 through 1998; ground-water recharge simulated as net infiltration; model boundary inflows and outflows based on regional hydraulic gradients and water budgets of surrounding areas; hydraulic conductivity and its relation to depth; and water levels appropriate for regional simulation of prepumped and pumped conditions within the DVRFS model domain. Simulation results appropriate for the regional extent and scale of the model were provided by acquiring additional data, by reevaluating existing data using current technology and concepts, and by refining earlier interpretations to reflect the current understanding of the regional ground-water flow system. Ground-water flow in the Death Valley region is composed of several interconnected, complex ground-water flow systems. Ground-water flow occurs in three subregions in relatively shallow and localized flow paths that are superimposed on deeper, regional flow paths. Regional ground-water flow is predominantly through a thick Paleozoic carbonate rock sequence affected by complex geologic structures from regional faulting and fracturing that can enhance or impede flow. Spring flow and evapotranspiration (ET) are the dominant natural ground-water discharge processes. Ground water also is withdrawn for agricultural, commercial, and domestic uses. Ground-water flow in the DVRFS was simulated using MODFLOW-2000, a 3D finite-difference modular ground-water flow modeling code that incorporates a nonlinear least-squares regression technique to estimate aquifer parameters. The DVRFS model has 16 layers of defined thickness, a finite-difference grid consisting of 194 rows and 160 columns, and uniform cells 1,500 m on each side. Prepumping conditions (before 1913) were used as the initial conditions for the transient-state calibration. The model uses annual stress periods with discrete recharge and discharge components. Recharge occurs mostly from infiltration of precipitation and runoff on high mountain ranges and from a small amount of underflow from adjacent basins. Discharge occurs primarily through ET and spring discharge (both simulated as drains) and water withdrawal by pumping and, to a lesser amount, by underflow to adjacent basins, also simulated by drains. All parameter values estimated by the regression are reasonable and within the range of expected values. The simulated hydraulic heads of the final calibrated transient model gener

Scientific Investigations Report↗

Topographic Change Detection at Select Archeological Sites in Grand Canyon National Park, Arizona, 2006-2007

Topographic change of archeological sites within the Colorado River corridor of Grand Canyon National Park (GCNP) is a subject of interest to National Park Service managers and other stakeholders in the Glen Canyon Dam Adaptive Management Program. Although long-term topographic change resulting from a variety of natural processes is typical in the Grand Canyon region, a continuing debate exists on whether and how controlled releases from Glen Canyon Dam, located immediately upstream of GCNP, are impacting rates of site erosion, artifact transport, and the preservation of archeological resources. Continued erosion of archeological sites threatens both the archeological resources and our future ability to study evidence of past cultural habitation. Understanding the causes and effects of archaeological site erosion requires a knowledge of several factors including the location and magnitude of the changes occurring in relation to archeological resources, the rate of the changes, and the relative contribution of several potential causes, including sediment depletion associated with managed flows from Glen Canyon Dam, site-specific weather patterns, visitor impacts, and long-term climate change. To obtain this information, highly accurate, spatially specific data are needed from sites undergoing change. Using terrestrial lidar data collection techniques and novel TIN- and GRID-based change-detection post-processing methods, we analyzed topographic data for nine archeological sites. The data were collected using three separate data collection efforts spanning 16 months (May 2006 to September 2007). Our results documented positive evidence of erosion, deposition, or both at six of the nine sites investigated during this time interval. In addition, we observed possible signs of change at two of the other sites. Erosion was concentrated in established gully drainages and averaged 12 cm to 17 cm in depth with maximum depths of 50 cm. Deposition was concentrated at specific locations outside of drainages but generally was spread over larger areas (tens to hundreds of square meters). Maximum depths of deposition averaged 12 cm to 15 cm and reached as much as 35 cm. Overall, we found that the spatial distribution and magnitudes of surface change are specific to each site and that a thorough understanding of the geomorphology, weather, and sand supply is requisite for a complete understanding of the data. Additional work in combining these results with site-specific weather, hydrology, and geomorphology data will assist in the development of working models for determining the causes of the documented topographic changes.

Scientific Investigations Report↗

A computer-aided approach for adapting stage-discharge ratings and characterizing uncertainties of streamflow data with discrete measurements

Relations between stage (water level) and discharge of streamflow through a natural channel are the result of time-varying processes, which are commonly described by time-varying stage-discharge ratings. Hydrographers with the U.S. Geological Survey successfully maintain the accuracy of streamflow data by manually applying time-tested approaches to adapt ratings to temporal changes in hydraulic conditions. The difficulty with the manual approach is that it is a subjective, time-consuming process that requires considerable skill and experience to implement. In addition, manual adjustments of ratings make quantification of resulting streamflow data uncertainties problematic. A computer-aided adaptive stage-discharge estimation approach is proposed to track sequential changes in the relation between stage and discharge at continuous-record streamgages. In this report, adaptations are based strictly on discrete measurement data that are then used to compute the magnitudes and uncertainties of streamflow. The approach entails the parameterization of a cubic regression spline (CRS) for the stage-discharge relation based on an existing rating or on a set of discrete measurements. A state-space model is then parameterized to track temporal changes in stage-discharge relations beginning with the initial CRS parameterization using discrete measurements. Finally, Kalman estimation is used with the state-space model to estimate the magnitude and uncertainty of flows. In a case study using data from streamgage U.S. Geological Survey 04122500 Marquette River at Scottville, Michigan, a five-parameter CRS model was estimated from data in an existing stage-discharge rating to provide an initial CRS parameter set for a state-space model. The initial CRS parameters were updated sequentially in a state-space model based on periodic discrete measurements of stage and discharge that spanned a 30-year period for this analysis. Additional analysis is needed to determine the timing of rapidly varying shifts more precisely in stage-discharge relations than the relatively infrequent discrete measurements currently enabled. Unit streamflow estimates based on flow in a local streamgaging network may provide a basis for adapting a stage-discharge rating at unit time intervals by augmenting discrete measurement data within the state-space model.

Michigan↗

Sedimentation History of Lago Dos Bocas, Puerto Rico, 1942-2005

The Lago Dos Bocas Dam, located in the municipality of Utuado in north central Puerto Rico, was constructed in 1942 for hydroelectric power generation. The reservoir had an original storage capacity of 37.50 million cubic meters and a drainage area of 440 square kilometers. In 1948, the construction of the Lago Caonillas Dam on the Rio Caonillas branch of Lago Dos Bocas reduced the natural sediment-contributing drainage area to 310 square kilometers; therefore, the Lago Caonillas Dam is considered an effective sediment trap. Sedimentation in Lago Dos Bocas reservoir has reduced the storage capacity from 37.50 million cubic meters in 1942 to 17.26 million cubic meters in 2005, which represents a storage loss of about 54 percent. The long-term annual water-storage capacity loss rate remained nearly constant at about 320,000 cubic meters per year to about 1997. The inter-survey sedimentation rate between 1997 and 1999, however, is higher than the long-term rate at about 1.09 million cubic meters per year. Between 1999 and 2005 the rate is lower than the long-term rate at about 0.13 million cubic meters per year. The Lago Dos Bocas effective sediment-contributing drainage area had an average sediment yield of about 1,400 cubic meters per square kilometer per year between 1942 and 1997. This rate increased substantially by 1999 to about 4,600 cubic meters per square kilometer per year, probably resulting from the historical magnitude floods caused by Hurricane Georges in 1998. Recent data indicate that the Lago Dos Bocas drainage area sediment yield decreased substantially to about 570 cubic meters per square kilometer per year, which is much lower than the 1942-1997 area normalized sedimentation rate of 1,235 cubic meters per square kilometer per year. The impact of Hurricane Georges on the basin sediment yield could have been the cause of this change, since the magnitude of the floods could have nearly depleted the Lago Dos Bocas drainage area of easily erodible and transportable bed sediment. This report summarizes the historical change in water-storage capacity of Lago Dos Bocas between 1942 and 2005.

Scientific Investigations Report↗

Low-flow characteristics of streams under natural and diversion conditions, Waipiʻo Valley, Island of Hawaiʻi, Hawaiʻi

Over the past 100 years, natural streamflow in Waipiʻo Valley has been reduced by the transfer of water out of the valley by Upper and Lower Hāmākua Ditches. The physical condition and diversion practices along the two ditch systems have varied widely over the years, and as a result, so have their effects on natural streamflow in Waipiʻo Valley. Recent renovation and improvements to Lower Hāmākua Ditch system, along with proposals for its future operation and water-diversion strategies, have unknown implications. The purpose of this report is to quantify the availability of streamflow and to determine the effects of current and proposed diversion strategies on the low-flow hydrology in Waipiʻo Valley. In this report, the low-flow hydrology of Waipiʻo Valley is described in terms of flow-duration statistics. Flow-duration statistics were computed for three locations in the Waipiʻo Valley study area where long-term surface-water gaging stations have been operated. Using a variety of streamflow record-extension techniques, flow-duration statistics were estimated at an additional 13 locations where only few historical data are available or where discharge measurements were made as part of this study. Flow-duration statistics were computed to reflect natural conditions, current (2000-2005) diversion conditions, and proposed future diversion conditions at the 16 locations. At the downstream limit of the study area, on Wailoa Stream at an altitude of 190 feet, a baseline for evaluating the availability of streamflow is provided by computed flow-duration statistics that are representative of natural, no-diversion conditions. At the Wailoa gaging station, 95- and 50-percentile discharges under natural conditions were determined to be 86 and 112 cubic feet per second, respectively. Under 1965-1969 diversion conditions, natural 95- and 50-percentile discharges were reduced by 52 and 53 percent, to 41 and 53 cubic feet per second, respectively. Under current (2000-2005) diversion conditions, natural 95- and 50-percentile discharges were reduced by 21 and 24 percent, to 68 and 85 cubic feet per second, respectively. Under proposed future diversion conditions, natural 95- and 50-percentile discharges would be reduced by 33 and 24 percent, to 58 and 85 cubic feet per second, respectively. Compared to discharges that reflect current (2000-2005) diversion conditions, proposed future diversion conditions would reduce 95-percentile discharges, which are representative of moderate drought levels in the stream, by 15 percent. No change would be expected in 50-percentile discharges, which are representative of normal conditions. The effects of current (2000-2005) and proposed future diversion conditions on the natural flow of streams in the Waipiʻo Valley study area differ, depending on the location. Under current (2000-2005) diversion conditions, reductions in natural 95- or 50-percentile discharges of greater than 30 percent were found in Kawainui Stream downstream from Upper Hamakua Ditch to an altitude of about 1,435 feet and in the reach of Waimā Stream between Upper and Lower Hāmākua Ditches. Under proposed future diversion conditions, reductions in natural 95- or 50-percentile discharges of greater than 30 percent were found in Kawainui Stream downstream from Upper Hamakua Ditch to an altitude of about 1,435 feet, in the reach of Waimā Stream between Upper and Lower Hāmākua Ditches, and along most stream reaches downstream from Lower Hāmākua Ditch, except for Waimā Stream.

Hawai?i↗

Groundwater quality, age, and susceptibility and vulnerability to nitrate contamination with linkages to land use and groundwater flow, Upper Black Squirrel Creek Basin, Colorado, 2013

The Upper Black Squirrel Creek Basin is located about 25 kilometers east of Colorado Springs, Colorado. The primary aquifer is a productive section of unconsolidated deposits that overlies bedrock units of the Denver Basin and is a critical resource for local water needs, including irrigation, domestic, and commercial use. The primary aquifer also serves an important regional role by the export of water to nearby communities in the Colorado Springs area. Changes in land use and development over the last decade, which includes substantial growth of subdivisions in the Upper Black Squirrel Creek Basin, have led to uncertainty regarding the potential effects to water quality throughout the basin. In response, the U.S. Geological Survey, in cooperation with Cherokee Metropolitan District, El Paso County, Meridian Service Metropolitan District, Mountain View Electric Association, Upper Black Squirrel Creek Groundwater Management District, Woodmen Hills Metropolitan District, Colorado State Land Board, and Colorado Water Conservation Board, and the stakeholders represented in the Groundwater Quality Study Committee of El Paso County conducted an assessment of groundwater quality and groundwater age with an emphasis on characterizing nitrate in the groundwater. Groundwater-quality samples were collected from 50 randomly selected wells between May and June 2013. The samples were analyzed for major ions, nutrients, dissolved gases, tritium ( 3 H), chlorofluorocarbons (CFC-11, CFC-12, and CFC-113), and fuel products (such as benzene, toluene, ethylbenzene, and xylenes). None of the groundwater samples exceeded the U.S. Environmental Protection Agency (EPA) National Primary Drinking Water Regulations for primary maximum contaminant levels (MCL) for major ions. Secondary maximum contaminant levels, which are not health concerns and affect mainly taste, color, or odor of the water, were observed in rare instances for pH (2 samples), chloride (1 sample), iron (3 samples), and manganese (8 samples). The secondary maximum contaminant level for total dissolved solids was also exceeded for two samples. Nitrate (nitrite plus nitrate as nitrogen in groundwater) was elevated above the estimated background concentration of natural recharge waters of 1 milligram per liter (mg/L) in 44 of the 50 wells sampled and showed a median concentration of 5.4 mg/L. Nitrate concentrations were above the MCL of 10 mg/L in 5 of the 50 wells sampled and above half of the EPA MCL (5 mg/L) in 27 of the 50 wells sampled, which included samples above the MCL. Dissolved-oxygen concentrations exceeded 0.5 mg/L in 95 percent of reported values (40 of 42 samples) and exceeded 2.0 mg/L in 90 percent of reported values (38 of 42 samples). The oxidized conditions observed in most areas indicate that nitrate from fertilizers and animal or human waste was geochemically stable and could persist in the groundwater for decades or perhaps longer. A historical analysis of median nitrate concentrations over nearly three decades showed an increase in nitrate of approximately 1 mg/L from 4.3 to 5.4 mg/L, although the increase was not determined to be significantly different using nonparametric statistical methods. Major-ion data indicate that groundwater representative of the primary aquifer was classified as calcium-sodium bicarbonate type water. Other water samples from wells located mainly along the periphery of the primary aquifer had cation-anion compositions consistent with distinct water sources, including groundwater contributions from the underlying bedrock aquifers. The areas with differentiable water sources were located mainly where alluvial deposits were thin and geologic contacts to the underlying bedrock aquifers were relatively shallow. Nitrate concentrations in the groundwater were evaluated for relations to land use. An agricultural region was defined using a sequence of land satellite imagery. Groundwater flow directions interpreted from median water-table elevations measured from 2000 to 2013 were used in conjunction with cropland locations to define the agricultural region boundaries by encompassing potential pathways of nitrate transport in the groundwater from nitrogen-based fertilizers. A statistically significant higher median nitrate concentration was observed for areas inside the agricultural region (6.7 mg/L) compared to areas outside the agricultural region (2.3 mg/L), although median concentrations in both areas were below the MCL (10 mg/L). Median nitrate concentration was also significantly greater in land parcels with septic use (4.9 mg/L) compared to nonseptic parcels (1.7 mg/L). In general, agriculture or septic use was identified as the primary source of nitrate, depending on location, while commercial, county, grazing, and residential land uses were generally secondary sources of nitrate. Apparent groundwater ages were estimated from chlorofluorocarbons (CFC-11, CFC-12, and CFC-113) and tritium ( 3 H) data using models that assumed piston flow and binary mixing (dilution of a young component with old, tracer-free water). The mean and median groundwater ages were about 30 years and the standard deviation was 6 years, indicating that most groundwater in the primary aquifer was “young” water that had recharged to the aquifer over the last few decades (post-1950s). The median fraction of young water was about 71 percent, and the standard deviation was 29 percent. The remaining water predated the 1950s, which may have originated from deeper geologic formations or may represent slow moving groundwater within the primary aquifer. Some of the oldest groundwater ages (older than 30 years) were observed in the upper reaches of the aquifer to the northwest where the primary aquifer is thin and intersects bedrock, supporting the hypothesis of geochemically distinct groundwater entering the primary aquifer from below. Groundwater that had reached the central part of the aquifer from upgradient areas of the basin was variable in age because of differences in flow paths and travel velocities. The groundwater age analysis showed that current (2013) land-use practices could affect water quality over decades to come, and that responses to remedial actions could be slow, especially for constituents, such as nitrate, that are stable under oxidized conditions. Fuel products (including acetone, benzene, diisopropyl ether, ethylbenzene, methyl acetate, methyl tertiary butyl ether (MTBE), methyl tert-pentyl ether, m- + p-xylene, o-xylene, tert-amyl alcohol, tert-butyl alcohol, tert-butyl ethyl ether, and toluene) were analyzed in groundwater from 49 of the 50 wells. Water from seven sites had detections for fuel compounds; all concentrations were below MCL. The results provided assurance of water quality and a valuable baseline to evaluate future trends of fuel constituents as the region is further developed. Probability maps were developed from logistic regression models to examine the likelihood that nitrate concentrations in groundwater exceeded specified levels. Susceptibility analysis examined relations between mid-level (5.0 mg/L) nitrate concentrations and climatic, hydrologic, and geologic variables; the significant variables were identified as depth to groundwater, soil organic matter, and soil water storage to 25-centimeter (cm) depth. The vulnerability assessments included natural factors driving susceptibility but also human factors related to land use and septic use. Vulnerability to low-level (2.5 mg/L) nitrate was related to depth to groundwater, septic zoning, and soil organic matter. The results highlighted that septic zoning affected low-level nitrate concentrations. Vulnerability to mid-level (5.0 mg/L) nitrate was examined using all 50 samples and also with two data outliers removed, which showed relatively high nitrate concentrations but also anomalous water chemistry or were located beyond the primary study area. Vulnerability to mid-level (5.0 mg/L) nitrate using all 50 samples was related to depth to groundwater, land use, septic use within a 500-meter (m) radius, soil water storage to a 25-cm depth, soil organic matter, and whether a location was within the agricultural region. The mid-level (5.0 mg/L) vulnerability model using 48 samples (two outliers removed) produced the best overall fit and was related to the same variables as when using all samples except septic use. The results for mid-level vulnerability provided additional support that septic use was associated with low levels of nitrate in the groundwater. Soil properties and land use were identified as the main drivers of moderate nitrate concentrations. Probabilities of exceeding low-level nitrate concentrations were high in most areas with the lowest probabilities usually to the northwest along thin geologic deposits in the upper part of the basin. The results of this investigation offer the foundational information needed for developing best management practices to mitigate nitrate contamination, basic concepts on water quality to aid public education, and information to guide regulatory measures if policy makers determine this is warranted. Science-based decision making will require continued monitoring and analysis of water quality in the future.

Colorado↗

Geochemistry of groundwater in the Beaver and Camas Creek drainage basins, eastern Idaho

The U.S. Geological Survey (USGS), in cooperation with the U.S. Department of Energy, is studying the fate and transport of waste solutes in the eastern Snake River Plain (ESRP) aquifer at the Idaho National Laboratory (INL) in eastern Idaho. This effort requires an understanding of the natural and anthropogenic geochemistry of groundwater at the INL and of the important physical and chemical processes controlling the geochemistry. In this study, the USGS applied geochemical modeling to investigate the geochemistry of groundwater in the Beaver and Camas Creek drainage basins, which provide groundwater recharge to the ESRP aquifer underlying the northeastern part of the INL. Data used in this study include petrology and mineralogy from 2 sediment and 3 rock samples, and water-quality analyses from 4 surface-water and 18 groundwater samples. The mineralogy of the sediment and rock samples was analyzed with X-ray diffraction, and the mineralogy and petrology of the rock samples were examined in thin sections. The water samples were analyzed for field parameters, major ions, silica, nutrients, dissolved organic carbon, trace elements, tritium, and the stable isotope ratios of hydrogen, oxygen, carbon, sulfur, and nitrogen. Groundwater geochemistry was influenced by reactions with rocks of the geologic terranes—carbonate rocks, rhyolite, basalt, evaporite deposits, and sediment comprised of all of these rocks. Agricultural practices near and south of Dubois and application of road anti-icing liquids on U.S. Interstate Highway 15 were likely sources of nitrate, chloride, calcium, and magnesium to groundwater. Groundwater geochemistry was successfully modeled in the alluvial aquifer in Camas Meadows and the ESRP fractured basalt aquifer using the geochemical modeling code PHREEQC. The primary geochemical processes appear to be precipitation or dissolution of calcite and dissolution of silicate minerals. Dissolution of evaporite minerals, associated with Pleistocene Lake Terreton, is an important contributor of solutes in the Mud Lake-Dubois area. Oxidation-reduction reactions are important influences on the chemistry of groundwater at Camas Meadows and the Camas National Wildlife Refuge. In addition, mixing of different groundwaters or surface water with groundwater appears to be an important physical process influencing groundwater geochemistry in much of the study area, and evaporation may be an important physical process influencing the groundwater geochemistry of the Camas National Wildlife Refuge. The mass-balance modeling results from this study provide an explanation of the natural geochemistry of groundwater in the ESRP aquifer northeast of the INL, and thus provide a starting point for evaluating the natural and anthropogenic geochemistry of groundwater at the INL.

Idaho↗

Strandlines from large floods on the Colorado River in Grand Canyon National Park, Arizona

Strandlines of peak-stage indicators (such as driftwood logs, woody debris, and trash) provide valuable data for understanding the maximum stage and extent of inundation during floods. A series of seven strandlines have been preserved along the Colorado River in Grand Canyon National Park, Arizona, USA. A survey and analysis of these strandlines was completed from the Colorado River at Lees Ferry, Ariz., gaging station to the Colorado River near Grand Canyon, Ariz., gaging station. Owing to the longitudinally discontinuous nature of the strandlines, several lines of evidence were used to determine the year of the flood associated with each strandline segment. This evidence included strandline relative vertical position, degree of peak-stage indicator weathering, datable trash drift, and map-view location. The seven distinct strandlines identified were deposited during floods with the following peak discharges (in cubic feet per second [ft 3 /s]) at the Colorado River at Lees Ferry, Ariz., gaging station (year of flood in parentheses): 210,000 ft 3 /s (1884), 170,000 ft 3 /s (1921), 125,000 ft 3 /s (1957), 108,000 ft 3 /s (1958), 97,000 ft 3 /s (1983), 52,500 ft 3 /s (1986), and 45,000 ft 3 /s (multiple events between 1996 and 2012). Stage-discharge relations were developed in areas where all, or most of the strandlines were present, and were compared to predicted stage-discharge relations from a one-dimensional flow model. River width exerted a strong control on these relations, with much greater stage change occurring for a given discharge change in narrower bedrock-dominated reaches than in wider reaches with more extensive channel-margin alluvium. This comprehensive dataset allows for the verification of model-predicted flood stage along the Colorado River in Grand Canyon National Park.

Arizona↗

Characterization of water quality in Government Highline Canal at Camp 7 Diversion and Highline Lake, Mesa County, Colorado, July 2000 through September 2003

The U.S. Geological Survey, in cooperation with the Colorado Division of Parks and Recreation, collected and analyzed water-quality data for the Government Highline Canal and Highline Lake from July 2000 through September 2003. Implementation of modernization strategies for the canal, which supplies most of the water to the lake, would decrease the amount of water spilled to Highline Lake from August through October. A reduction in spill water into Highline Lake could adversely affect the recreational uses of the lake. To address this concern and to characterize the water quality in the Government Highline Canal and Highline Lake, the U.S. Geological Survey conducted a study to evaluate limnological conditions prior to implementation of the modernization strategies. This report characterizes the water quality of inflow from the Government Canal and in Highline Lake prior to implementation of modernization strategies in the Government Canal. Flow entering the lake from the Government Canal was characterized using field properties and available chemical, sediment, and bacteria concentrations. Data collected at Highline Lake were used to characterize the seasonal stratification patterns, water-quality chemistry, bacteria populations, and phytoplankton community structure in the lake. Data used for this report were collected at one inflow site to the lake and four sites in Highline Lake. Highline Lake is a mesotrophic/eutrophic lake that has dimictic thermal stratification patterns. Samples collected in the photic zone indicated that there was little physical, chemical, or biological variability at this depth at any of the sampled sites in Highline Lake. Strong thermal and dissolved-oxygen stratification patterns were observed during summer. Dissolved-oxygen concentrations of less than 1 milligram per liter were observed during the summer. Ammonia likely was released from the bottom sediments of Highline Lake. The limiting nutrient in Highline Lake could be nitrogen or phosphorus. In general, the seasonal succession of phytoplankton was similar to that of other lakes in the temperate zone. Several types of algae associated with taste and odor issues were identified in samples, but critical concentrations were not exceeded for any listed algal group with the exception of the diatom genus Cyclotella in one sample. Bacteria concentrations were determined at the public swim beach at Highline Lake. E. coli samples were collected periodically by the USGS and weekly by the Colorado Division of Parks and Recreation. During the study period, no reported E. coli concentration exceeded the standard for natural swimming areas. Inflow water quality was characterized by samples collected at the Camp 7 check structure on the Government Canal. Inflow water temperatures reflected the seasonal patterns of the source water in the Colorado River. The water was well oxygenated. Nitrogen and phosphorus concentrations were low, and concentrations did not differ substantially from year to year or seasonally within a year. All samples had reportable numbers of fecal streptococcus. The maximum reported concentration of E. coli was reported at 77 colonies per 100 milliliters of sample. Suspended-sediment concentrations were relatively low.

Scientific Investigations Report↗

Assessment, water-quality trends, and options for remediation of acidic drainage from abandoned coal mines near Huntsville, Missouri, 2003-2004

Water from abandoned underground coal mines acidifies receiving streams in the Sugar Creek Basin and Mitchell Mine Basin near Huntsville, Missouri. A 4.35-kilometer (2.7-mile) reach of Sugar Creek has been classified as impaired based on Missouri's Water Quality Standards because of small pH values [< (less than) 6.5]. Samples collected from Sugar Creek from July 2003 to June 2004 did not have pH values outside of the specified range of 6.5 to 9.0. However, large concentrations of iron [416 to 2,320 mg/L (milligrams per liter)], manganese (8.36 to 33.5 mg/L), aluminum (0.870 to 428 mg/L), and sulfate (2,990 to 13,700 mg/L) in acidic mine drainage (AMD) from two mine springs as well as small and diffuse seeps were observed to have an effect on water quality in Sugar Creek. Metal and sulfate loads increased and pH decreased immediately downstream from Sugar Creek's confluence with the Calfee Slope and Huntsville Gob drainages that discharge AMD into Sugar Creek. Similar effects were observed in the Mitchell Mine drainage that receives AMD from a large mine spring. Comparisons of water-quality samples from this study and two previous studies by the U.S. Geological Survey in 1987-1988 and the Missouri Department of Natural Resources in 2000-2002 indicate that AMD generation in the Sugar Creek Basin and Mitchell Mine Basin is declining, but the data are insufficient to quantify any trends or time frame. AMD samples from the largest mine spring in the Calfee Slope subbasin indicated a modest but significant increase in median pH from 4.8 to 5.2 using the Wilcoxan rank-sum test (p <0.05) and a decrease in median specific conductance from 5,000 to 3,540 ?S/cm (microsiemens per centimeter at 25 degrees Celsius) during a 17-year period. AMD samples from the largest mine spring in the Mitchell Mine Basin indicated an increase in median pH values from 5.6 to 6.0 and a decrease in median specific conductance from 3,050 to 2,450 ?S/cm during the same period. Remediation of AMD at or near the sites of the three largest mine springs is geochemically feasible based on alkalinity addition rates and increased pH determined by cubitainer experiments and geochemical mixing experiments using the computer model PHREEQCI. Alkalinity values for seven cubitainer experiments conducted to simulate anoxic treatment options exceeded the targeted value for alkalinity [90 mg/L as calcium carbonate (CaCO3)] specified in Missouri's Total Maximum Daily Load program by 18 percent or more, but maximum pH values were between 6.2 and 6.3, which is less than the targeted pH value of 6.5. Treatment of AMD by mixing with stream water or sewage effluent can further increase pH as indicated by geochemical modeling, but will not totally achieve water-quality goals because of limited discharges. A combination of treatments including settling ponds, oxic or anoxic limestone drains, and possibly successive alkalinity producing systems to remediate AMD will likely be required in the Sugar Creek Basin and Mitchell Mine Basin to consistently meet Missouri's Water Quality Standards.

Scientific Investigations Report↗

Temporal changes in nutrient concentrations in the Lower Grand River and selected drainage basins, Missouri and Iowa, during the Mississippi River Basin Healthy Watersheds Initiative (2010–23)

This report describes a cooperative study by the U.S. Geological Survey and Missouri Department of Natural Resources that evaluated temporal changes in total nitrogen (TN) and total phosphorus (TP) concentrations in the Lower Grand River hydrologic unit. The study focused on trends since 2010, when the basin was designated as a priority drainage basin of the Mississippi River Basin Healthy Watersheds Initiative (MRBI). At three local drainage basins within the Lower Grand hydrological unit (MRBI sites), stream nutrient trends were evaluated using flow-adjusted (FA) TN and TP concentrations for water years 2011 through 2023. FATN concentration trends were not statistically significant for any MRBI site. One site (site 2) showed a statistically significant increasing trend in FATP concentration, indicating a possible increase in phosphorus sources in parts of the basin. Overall, streamflow variability appeared to be the dominant factor affecting nutrient concentrations at MRBI sites. At five regional drainage basins, including the Grand River and nearby rivers with data from 1994 through 2023 (long-term sites), annual flow-normalized (FN) TN and TP concentrations were evaluated for trends before (water years 2000–10) and during (water years 2010–23) the MRBI. For water years 2010 through 2023, annual FNTN and FNTP concentrations decreased in the Grand River, as well as in the Nodaway and Chariton Rivers, which were not targeted by the MRBI. The Grand River (site 9) reversed from increasing to decreasing FNTP concentrations after 2010, with a 26-percent reduction. Annual FNTN and FNTP concentrations also decreased at the Missouri River sites. While nutrient reductions in the Grand River may reflect the effects of implemented conservation practices, similar trends in nearby, nontargeted rivers and the absence of strong decreasing trends at MRBI sites suggest that broader regional factors, instead of or in addition to MRBI efforts, may have contributed to nutrient reductions in the Grand River.

Iowa, Missouri↗

Community estimate of global glacier mass changes from 2000 to 2023

Glaciers are indicators of ongoing anthropogenic climate change 1 . Their melting leads to increased local geohazards 2 , and impacts marine 3 and terrestrial 4 , 5 ecosystems, regional freshwater resources 6 , and both global water and energy cycles 7 , 8 . Together with the Greenland and Antarctic ice sheets, glaciers are essential drivers of present 9 , 10 and future 11 , 12 , 13 sea-level rise. Previous assessments of global glacier mass changes have been hampered by spatial and temporal limitations and the heterogeneity of existing data series 14 , 15 , 16 . Here we show in an intercomparison exercise that glaciers worldwide lost 273 ± 16 gigatonnes in mass annually from 2000 to 2023, with an increase of 36 ± 10% from the first (2000–2011) to the second (2012–2023) half of the period. Since 2000, glaciers have lost between 2% and 39% of their ice regionally and about 5% globally. Glacier mass loss is about 18% larger than the loss from the Greenland Ice Sheet and more than twice that from the Antarctic Ice Sheet 17 . Our results arise from a scientific community effort to collect, homogenize, combine and analyse glacier mass changes from in situ and remote-sensing observations. Although our estimates are in agreement with findings from previous assessments 14 , 15 , 16 at a global scale, we found some large regional deviations owing to systematic differences among observation methods. Our results provide a refined baseline for better understanding observational differences and for calibrating model ensembles 12 , 16 , 18 , which will help to narrow projection uncertainty for the twenty-first century 11 , 12 , 18 .

Nature↗

Topographic change detection at select archeological sites in Grand Canyon National Park, Arizona, 2007-2010

Human occupation in Grand Canyon, Arizona, dates from at least 11,000 years before present to the modern era. For most of this period, the only evidence of human occupation in this iconic landscape is provided by archeological sites. Because of the dynamic nature of this environment, many archeological sites are subject to relatively rapid topographic change. Quantifying the extent, magnitude, and cause of such change is important for monitoring and managing these archeological sites. Such quantification is necessary to help inform the continuing debate on whether and how controlled releases from Glen Canyon Dam, located immediately upstream of Grand Canyon National Park, are affecting site erosion rates, artifact transport, and archeological resource preservation along the Colorado River in Grand Canyon. Although long-term topographic change resulting from a variety of natural processes is inherent in the Grand Canyon region, continued erosion of archeological sites threatens both the archeological resources and our future ability to study evidence of past cultural habitation. Thus, this subject is of considerable interest to National Park Service managers and other stakeholders in the Glen Canyon Dam Adaptive Management Program. Understanding the causes and effects of archeological site erosion requires a knowledge of several factors, including the location, timing, and magnitude of the changes occurring in relation to archeological resources, the rates of change, and the relative contribution of potential causes. These potential causes include sediment depletion associated with managed flows from Glen Canyon Dam, site-specific weather and overland flow patterns, visitor impacts, and long-term regional climate change. To obtain this information, highly accurate, spatially specific data are needed from sites undergoing change. Using terrestrial lidar techniques, and building upon three previous surveys of archeological sites performed in 2006 and 2007, we collected two new datasets in April and September 2010 and processed and improved upon existing methods to generate high-accuracy (3 to 5 cm vertical change threshold) topographic change-detection maps for 10 survey areas encompassing 9 archeological sites along the Colorado River corridor. We also used terrestrial lidar techniques to investigate several other metrics for studying archeological site stability, including monitoring cultural structures and artifacts and remotely measuring cryptobiotic soil crust areas. Our topographic change results indicate that 9 of 10 survey areas showed signs of either erosion, deposition, or both during the 2007&ndash;2010 time interval and that these changes can be linked to a variety of geomorphic processes, primarily overland flow gullying and aeolian sand transport. In several cases, large (>50 cm) vertical change occurred, and in one case, more than 100 m 3 of sediment was eroded. Further, for all sites monitored throughout the river corridor during this time period, the overall signal was related to erosion rather than deposition. These results highlight the potential for rapid archeological site change in Grand Canyon. Whereas the topographic change results presented herein provide the highest level of change detection yet performed on entire archeological sites in Grand Canyon, additional work in combining these results with site-specific weather, hydrology, and geomorphology data is needed to provide a more thorough understanding of the causes of the documented topographic changes. Linking lidar-derived measurements of topographic changes with these other data sources should provide land managers with a scientific basis for making management decisions regarding archeological resources in Grand Canyon National Park and assist in answering open questions regarding the influence that sediment-depleted flows from Glen Canyon Dam have on archeological site stability.

Arizona↗

Framework for regional synthesis of water-quality data for the glacial aquifer system in the United States

The glacial aquifer system is the largest principal aquifer in aerial extent and ground-water use for public supply in the United States. A principal aquifer is defined as a regionally extensive aquifer or aquifer system that has the potential to be used as a source of potable water (U.S. Geological Survey, 2003). Multiple aquifers often are grouped into large, extensive aquifer systems such as the glacial aquifer system. The glacial aquifer system is considered here to include all unconsolidated aquifers above bedrock north of the line of continental glaciation throughout the country (fig. 1). Total withdrawals from the glacial aquifer system were 3,560 million gallons per day in 2000, which constitutes almost 5 percent of total withdrawals from all aquifers in the United States (Maupin and Barber, 2005). Approximately 41 million people relied on the glacial aquifer for public supply and domestic use in 2000. The U.S. Geological Survey National Water-Quality Assessment (NAWQA) Program began assessing the glacial aquifer system in 1991. The assessment of water-quality data on a regional scale, such as the glacial aquifer system, is coincident with the regional framework established by the Regional Aquifer-System Analysis Program (RASA) (Sun and others, 1997). From 1978 to 1995, the RASA Program systematically evaluated 25 of the Nation's most important groundwater systems including studies in the glacial aquifer system in the northeast, Midwest, and northern Midwest United States. The NAWQA Program is building on the work of the RASA Program to study the water quality of 16 of the most important ground-water systems (Lapham and others, 2005). Over 1,700 water-quality samples have been collected by the NAWQA Program from 1991 to 2004 to assess the glacial aquifer system. This large data set is unique in that the samples have been collected using a consistent sampling protocol, and multiple nested samples. The nested samples address the recently recharged shallow ground water, deeper water from principal aquifers often used for domestic supply, and source water used for public supplies within the glacial aquifer system. Information concerning the NAWQA Program including study unit boundaries is shown in figure 1 (Lapham and others, 2005). A framework for comparison of water quality across the glacial aquifer system has been developed based on two primary characteristics: intrinsic susceptibility and vulnerability. Intrinsic susceptibility, which is a measure of the ease at which water enters and moves through aquifer material, is a characteristic of the aquifer and overlying material and of the hydrologic conditions. Intrinsic susceptibility is independent of the chemical characteristics of the contaminant and its sources. In this way, intrinsic susceptibility assessments do not target specific natural or anthropogenic sources of contamination but instead consider only the physical factors affecting the flow of water to, and through the ground-water resource (Focazio and others, 2002). On a regional scale, intrinsic susceptibility is represented by the spatial distribution of fine- or coarse-grained material at the land surface, and the physical setting of the aquifer system. Vulnerability, which is a function of both intrinsic susceptibility and the proximity and characteristics of contaminant sources, includes consideration of features related to anthropogenic sources of contaminants, such as the character of the upgradient land use (for example, urban, agricultural, undeveloped, and others); as well as features related to natural sources of contaminants, such as the mineralogy of the aquifer material or the geochemical conditions within the aquifer system. The framework helps categorize this large region into areas of similar hydrogeologic characteristics for which water quality can be compared. The purpose of this report is to describe this framework and how it will be used for regional synthesis of water-quality da

Scientific Investigations Report↗

Method for estimating potential wetland extent by utilizing streamflow statistics and flood-inundation mapping techniques: Pilot study for land along the Wabash River near Terre Haute, Indiana

Potential wetland extents were estimated for a 14-mile reach of the Wabash River near Terre Haute, Indiana. This pilot study was completed by the U.S. Geological Survey in cooperation with the U.S. Department of Agriculture, Natural Resources Conservation Service (NRCS). The study showed that potential wetland extents can be estimated by analyzing streamflow statistics with the available streamgage data, calculating the approximate water-surface elevation along the river, and generating maps by use of flood-inundation mapping techniques. Planning successful restorations for Wetland Reserve Program (WRP) easements requires a determination of areas that show evidence of being in a zone prone to sustained or frequent flooding. Zone determinations of this type are used by WRP planners to define the actively inundated area and make decisions on restoration-practice installation. According to WRP planning guidelines, a site needs to show evidence of being in an "inundation zone" that is prone to sustained or frequent flooding for a period of 7 consecutive days at least once every 2 years on average in order to meet the planning criteria for determining a wetland for a restoration in agricultural land. By calculating the annual highest 7-consecutive-day mean discharge with a 2-year recurrence interval (7MQ2) at a streamgage on the basis of available streamflow data, one can determine the water-surface elevation corresponding to the calculated flow that defines the estimated inundation zone along the river. By using the estimated water-surface elevation ("inundation elevation") along the river, an approximate extent of potential wetland for a restoration in agricultural land can be mapped. As part of the pilot study, a set of maps representing the estimated potential wetland extents was generated in a geographic information system (GIS) application by combining (1) a digital water-surface plane representing the surface of inundation elevation that sloped in the downstream direction of flow and (2) land-surface elevation data. These map products from the pilot study will aid the NRCS and its partners with the onsite inundation-zone verification in agricultural land for a potential restoration and will assist in determining at what elevation to plant hardwood trees for increased survivability on ground above frequently flooded terraces.

Indiana↗

Comparison of Hydrologic and Water-Quality Characteristics of Two Native Tallgrass Prairie Streams with Agricultural Streams in Missouri and Kansas

This report presents the results of a study by the U.S. Geological Survey, in cooperation with the Missouri Department of Natural Resources, to analyze and compare hydrologic and water-quality characteristics of tallgrass prairie and agricultural basins located within the historical distribution of tallgrass prairie in Missouri and Kansas. Streamflow and water-quality data from two remnant, tallgrass prairie basins (East Drywood Creek at Prairie State Park, Missouri, and Kings Creek near Manhattan, Kansas) were compared to similar data from agricultural basins in Missouri and Kansas. Prairie streams, especially Kings Creek in eastern Kansas, received a higher percentage of base flow and a lower percentage of direct runoff than similar-sized agricultural streams in the region. A larger contribution of direct runoff from the agricultural streams made them much flashier than prairie streams. During 22 years of record, the Kings Creek base-flow component averaged 66 percent of total flow, but base flow was only 16 to 26 percent of flows at agricultural sites of various record periods. The large base-flow component likely is the result of greater infiltration of precipitation in prairie soils and the resulting greater contribution of groundwater to streamflow. The 1- and 3-day annual maximum flows were significantly greater at three agricultural sites than at Kings Creek. The effects of flashier agricultural streams on native aquatic biota are unknown, but may be an important factor in the sustainability of some native aquatic species. There were no significant differences in the distribution of dissolved-oxygen concentrations at prairie and agricultural sites, and some samples from most sites fell below the 5 milligrams per liter Missouri and Kansas standard for the protection of aquatic life. More than 10 percent of samples from the East Drywood Creek prairie stream were less than this standard. These data indicate low dissolved-oxygen concentrations during summer low-flow periods may be a natural phenomenon for small prairie streams in the Osage Plains. Nutrient concentrations including total nitrogen, ammonia, nitrate, and total phosphorus were significantly less in base-flow and runoff samples from prairie streams than from agricultural streams. The total nitrogen concentration at all sites other than one of two prairie sampling sites were, on occasion, above the U.S. Environmental Protection Agency recommended criterion for total nitrogen for the prevention of nutrient enrichment, and typically were above this recommended criterion in runoff samples at all sites. Nitrate and total phosphorus concentrations in samples from the prairie streams generally were below the U.S. Environmental Protection Agency recommended nutrient criteria in base-flow and runoff samples, whereas samples from agricultural sites generally were below the criteria in base-flow samples and generally above in runoff samples. The lower concentrations of nutrient species in prairie streams is likely because prairies are not fertilized like agricultural basins and prairie basins are able to retain nutrients better than agricultural basins. This retention is enhanced by increased infiltration of precipitation into the prairie soils, decreased surface runoff, and likely less erosion than in agricultural basins. Streamflow in the small native prairie streams had more days of zero flow and lower streamflow yields than similar-sized agricultural streams. The prairie streams were at zero flow about 50 percent of the time, and the agricultural streams were at zero flow 25 to 35 percent of the time. Characteristics of the prairie basins that could account for the greater periods of zero flow and lower yields when compared to agricultural streams include greater infiltration, greater interception and evapotranspiration, shallower soils, and possible greater seepage losses in the prairie basins. Another difference between the prairie and agricultural strea

Scientific Investigations Report↗

Water quality of streams draining abandoned and reclaimed mined lands in the Kantishna Hills area, Denali National Park and Preserve, Alaska, 2008–11

The Kantishna Hills are an area of low elevation mountains in the northwest part of Denali National Park and Preserve, Alaska. Streams draining the Kantishna Hills are clearwater streams that support several species of fish and are derived from rain, snowmelt, and subsurface aquifers. However, the water quality of many of these streams has been degraded by mining. Past mining practices generated acid mine drainage and excessive sediment loads that affected water quality and aquatic habitat. Because recovery through natural processes is limited owing to a short growing season, several reclamation projects have been implemented on several streams in the Kantishna Hills region. To assess the current water quality of streams in the Kantishna Hills area and to determine if reclamation efforts have improved water quality, a cooperative study between the U.S. Geological Survey and the National Park Service was undertaken during 2008-11. High levels of turbidity, an indicator of high concentrations of suspended sediment, were documented in water-quality data collected in the mid-1980s when mining was active. Mining ceased in 1985 and water-quality data collected during this study indicate that levels of turbidity have declined significantly. Turbidity levels generally were less than 2 Formazin Nephelometric Units and suspended sediment concentrations generally were less than 1 milligram per liter during the current study. Daily turbidity data at Rock Creek, an unmined stream, and at Caribou Creek, a mined stream, documented nearly identical patterns of turbidity in 2009, indicating that reclamation as well as natural revegetation in mined streams has improved water quality. Specific conductance and concentrations of dissolved solids and major ions were highest from streams that had been mined. Most of these streams flow into Moose Creek, which functions as an integrator stream, and dilutes the specific conductance and ion concentrations. Calcium and magnesium are the dominant cations, and bicarbonate and sulfate are the dominant anions. Water samples indicate that the water from Rock Creek, Moose Creek, Slate Creek, and Eldorado Creek is a calcium bicarbonate-type water. The remaining sites are a calcium sulfate type water. U.S. Environmental Protection Agency guidelines for arsenic and antimony in drinking water were exceeded in water at Slate Creek and Eureka Creek. Concentrations of arsenic, cadmium, chromium, copper, lead, nickel, and zinc in streambed sediments at many sites exceed sediment quality guideline thresholds that could be toxic to aquatic life. However, assessment of these concentrations, along with the level of organic carbon detected in the sediment, indicate that only concentrations of arsenic and chromium may be toxic to aquatic life at many sites. In 2008 and 2009, 104 macroinvertebrate taxa and 164 algae taxa were identified from samples collected from seven sites. Of the macroinvertebrates, 86 percent were insects and most of the algae consisted of diatoms. Based on the National Community Index, Rock Creek, a reference site, and Caribou Creek, and a mined stream that had undergone some reclamation, exhibited the best overall stream conditions; whereas Slate Creek and Friday Creek, two small streams that were mined extensively, exhibited the worst stream conditions. A non-metric multi-dimensional scaling analysis of the macroinvertebrate and algae data showed a distinct grouping between the 2008 and 2009 samples, likely because of differences between a wet, cool summer in 2008 and a dry, warm summer in 2009.

Alaska↗

Predicted nitrate and arsenic concentrations in basin-fill aquifers of the Southwestern United States

The National Water-Quality Assessment (NAWQA) Program of the U.S. Geological Survey (USGS) is conducting a regional analysis of water quality in the principal aquifer systems across the United States. The Southwest Principal Aquifers (SWPA) study is building a better understanding of the susceptibility and vulnerability of basin-fill aquifers in the region to groundwater contamination by synthesizing baseline knowledge of groundwater-quality conditions in 16 basins previously studied by the NAWQA Program. The improved understanding of aquifer susceptibility and vulnerability to contamination is assisting in the development of tools that water managers can use to assess and protect the quality of groundwater resources. Human-health concerns and economic considerations associated with meeting drinking-water standards motivated a study of the vulnerability of basin-fill aquifers to nitrate con­tamination and arsenic enrichment in the southwestern United States. Statistical models were developed by using the random forest classifier algorithm to predict concentrations of nitrate and arsenic across a model grid that represents about 190,600 square miles of basin-fill aquifers in parts of Arizona, California, Colorado, Nevada, New Mexico, and Utah. The statistical models, referred to as classifiers, reflect natural and human-related factors that affect aquifer vulnerability to contamina­tion and relate nitrate and arsenic concentrations to explana­tory variables representing local- and basin-scale measures of source, aquifer susceptibility, and geochemical conditions. The classifiers were unbiased and fit the observed data well, and misclassifications were primarily due to statistical sampling error in the training datasets. The classifiers were designed to predict concentrations to be in one of six classes for nitrate, and one of seven classes for arsenic. Each classification scheme allowed for identification of areas with concentrations that were equal to or exceeding the U.S. Environmental Protection Agency drinking-water standard. Whereas 2.4 percent of the area underlain by basin-fill aquifers in the study area was predicted to equal or exceed this standard for nitrate (10 milligrams per liter as N; mg/L), 42.7 percent was predicted to equal or exceed the standard for arsenic (10 micrograms per liter; μg/L). Areas predicted to equal or exceed the drinking-water standard for nitrate include basins in central Arizona near Phoenix; the San Joaquin, Inland, and San Jacinto basins of California; and the San Luis Valley of Colorado. Much of the area predicted to equal or exceed the drinking-water standard for arsenic is within a belt of basins along the western portion of the Basin and Range Physiographic Province in Nevada, California, and Arizona. Predicted nitrate and arsenic concentrations are substantially lower than the drinking-water standards in much of the study area—about 93.0 percent of the area underlain by basin-fill aquifers was less than one-half the standard for nitrate (5.0 mg/L), and 50.2 percent was less than one-half the standard for arsenic (5.0 μg/L).

Arizona, California, Colorado, Nevada, New Mexico,↗