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Regional ground-water flow and geochemistry in the midwestern Basins and Arches aquifer system in parts of Indiana, Ohio, Michigan, and Illinois

This report synthesizes information on the regional ground-water flow and geochemistry in the Midwestern Basins and Arches aquifer system in parts of Indiana, Ohio, Michigan, and Illinois. Aquifers that compose this water-table aquifer system include glacial aquifers and an underlying, areally extensive carbonate-rock aquifer. Water within the aquifers is most commonly a Ca-Mg-HCO 3 type or a Ca-Mg-SO 4 type. In general, the distribution of hydrochemical facies within the aquifer system is controlled by the mineralogy of the aquifer material, rather than by a chemical evolution of water along general directions of regional ground-water flow. Some ground-water flow systems within the aquifer system provide base flow to streams in response to ground-water recharge events. Other (often deeper) ground-water flow systems respond minimally to variations in ground-water recharge from precipitation and provide a fairly constant supply of water to streams. Streamflow hydrographs and base-flow duration curves were used to estimate such components of base flow in selected streams for long-term steady-state conditions in the aquifer system. Mean sustained ground-water discharge (discharge from fairly stable ground-water flow systems) ranges from 3 to 50 percent of mean ground-water discharge (discharge from all ground-water flow systems) to the selected stream reaches. These percentages indicate that 50 to 97 percent of base flow in the streams within the study area can be attributed to transient ground-water flow systems, which typically have a major component of local-scale flow. Because ground-water flow across the external boundaries of the aquifer system is minimal, such percentages indicate that most ground-water flow in the aquifer system is associated with seasonally transient local flow systems. Results of a ground-water flow model that was calibrated by use of regression methods and that simulates regional flow systems within the aquifer system (approximately 10 percent of total ground-water flow in the aquifer system) indicate that most water (99 percent) in simulated regional flow systems is from recharge at the water table. Most water (78 percent) discharges from simulated regional flow systems to the principal streams. Less than 3 percent of water in simulated regional flow systems discharges to the Ohio River, Lake Erie, or downdip areas in the Illinois (structural) Basin. Simulations also indicate that most of the Midwestern Basins and Arches aquifer system is characterized by alternating regional recharge and discharge areas at intervals of less than every 10 miles along the dominant regional trends of the potentiometric surfaces in the aquifers. Such alternating regional recharge and discharge areas result in the absence of long flow paths from the very highest regional potentiometric levels to the very lowest regional potentiometric levels. The presence of tritiated ground water (less than 50 years old) across most of the aquifer system also indicates that the aquifer system receives recharge across most of the study area. The northeastern part of the aquifer system near Lake Erie differs from the rest of the system with respect to regional ground-water flow and chemistry. Specifically, part of the northeastern part of the aquifer system can be characterized as a broad area (tens of miles) of weak regional discharge (less than 0.5 inch per year). Results of the regional ground-water flow model indicate that regional flow systems have a limited ability to carry ground water away from this area; thus precipitation is prevented from recharging the regional flow systems in this part of the aquifer system. Some ground water recharged during Pleistocene glaciation was found in this area.

Illinois, Indiana, Michigan, Ohio↗

Nitrogen species in soil, sediment, and ground water at a former sewage-treatment wastewater lagoon: Naval Air Station Whidbey Island, Island County, Washington

The potential for contamination of ground water from remnant sewage sludge in re-graded sediments of a deconstructed sewage-treatment lagoon was evaluated. Ground-water levels were measured in temporary drive-point wells, and ground-water samples were collected and analyzed for nutrients and other water-quality characteristics. Composite soil and sediment samples were collected and analyzed for organic carbon and nitrogen species. Multiple lines of evidence, including lack of appreciable organic matter in sediments of the former lagoon, agronomic analysis of nitrogen, the sequestration of nitrogen in the developing soils at the former lagoon, and likely occurrence of peat deposits within the aquifer material, suggest that the potential for substantial additions of nitrogen to ground water beneath the former sewage lagoon resulting from remnant sewage sludge not removed from the former lagoon are small. Concentrations of nitrogen species measured in ground-water samples were small and did not exceed the established U.S. Environmental Protection Agency’s maximum contaminant levels for nitrate (10 milligrams per liter). Concentrations of nitrate in ground-water samples were less than the laboratory reporting limit of 0.06 milligram per liter. Seventy to 90 percent of the total nitrogen present in ground water was in the ammonia form with a maximum concentration of 7.67 milligrams per liter. Concentrations of total nitrogen in ground water beneath the site, which is the sum of all forms of nitrogen including nitrate, nitrite, ammonia, and organic nitrogen, ranged from 1.15 to 8.44 milligrams per liter. Thus, even if all forms of nitrogen measured in ground water were converted to nitrate, the combined mass would be less than the maximum contaminant level. Oxidation-reduction conditions in ground water beneath the former sewage lagoon were reducing. Given the abundant supply of ambient organic carbon in the subsurface and in ground water at the former lagoon, any nitrate that may leach from residual sludge and be transported to ground water with recharge is expected to be quickly denitrified or transformed to nitrite and ammonia under the strongly reducing geochemical conditions that are present. Concentrations of organic carbon, the primary constituent of sewage sludge, in sediments of the former sewage lagoon were less than 1 percent, indicating a near absence of organic matter. The amount of total nitrogen present in the sediments at the former sewage lagoon was only about 25 percent of the amount typically present in developed agricultural soils. The lack of substantial carbon and nitrogen in sediments of the former sewage lagoon indicates that surficial sediments of the former lagoon are essentially devoid of residual sewage sludge. The largest concentration of total nitrogen measured in soil samples from the former sewage lagoon (330 milligrams per kilogram) was used to calculate an estimate of the amount of nitrogen that might be leached from residual sewage sludge by recharge. During the first two years following deconstruction of the former sewage lagoon, the concentration of total nitrogen in recharge leachate might exceed 10 milligrams per liter but the recharge leachate would not likely result in substantial increases in the nitrate concentration in ground water to concentrations greater than the drinking-water maximum contaminant level of 10 milligrams per liter.

Washington↗

Analog-model analysis of effect of wastewater management on the ground-water reservoir in Nassau and Suffolk Counties, New York: Report I: Proposed and current sewerage

By 1995, the water table may fall by as much as 5 metres (16 feet) in east-central Nassau County and as much as 1.8 metres (6 feet) in central Suffolk County as a result of proposed sewerage programs. similar, but generally slightly less, change may occur in the potentiometric head in the Magothy aquifer. Streamflow may decrease by as much as 55 percent in streams draining from Nassau County Sewage Disposal District 3 and as much as 56 percent in streams draining from the Huntington-Northport Sewer District.

Open-File Report↗

Ground-water data for Georgia, 1987

This report was prepared in cooperation with the State of Georgia; Chatham County; Glynn County; the cities of Brunswick and Valdosta; and the Albany Water, Gas, and Light Commission. This report is the culmination of a concerted effort by dedicated personnel of the U.S. Geological Survey who collected, compiled, analyzed, verified, and organized the data, and who edited and assembled the report. In addition to the authors, who had primary responsibility for assuring that the information contained herein is accurate, complete, and adheres to Geological Survey policy and established guidelines, the following individuals contributed significantly to the collection, processing, and tabulation of the data:

Georgia↗

U.S. Geological Survey Georgia Water Science Center and Albany Water, Gas, and Light Commission Cooperative Water Program— Summary of activities, July 2005 through June 2006

The U.S. Geological Survey (USGS) has been working with the Albany Water, Gas, and Light Commission to monitor ground-water quality and availability since 1977. This report presents the findings for July 2005 through June 2006 and summarizes the ground-water and surface-water conditions for 2005. Water levels in 14 wells were continuously monitored in Dougherty County, Georgia. Water levels in 12 of those wells were above normal, one was normal, and one was below normal. Ground-water samples collected from the Upper Floridan aquifer indicate that nitrate levels have increased in 13 wells and decreased in two wells from a year earlier. A sample also was collected from the Flint River. A trilinear diagram showing the percent composition of selected major cations and anions indicates that the ground-water quality of the Upper Floridan aquifer at the Albany wellfield is distinctly different from the water quality of the Flint River. To improve the understanding of the ground-water flow system and nitrate movement in the Upper Floridan aquifer, the USGS is developing a ground-water flow model in the southwest Albany area, Georgia.

Georgia↗

Flow characteristics of the Snake River and water budget for the Snake River plain, Idaho and eastern Oregon

This report is one in a series resulting from the U.S. Geological Survey's Snake River Plain Rasa (Regional Aquifer System Analysis) study that was initiation in October 1979. Purposes of the RASA study were to (1) refine knowledge of the regional ground-water flow system, (2) determine effects of conjunctive use of ground water and surface water, and (3) describe water chemistry. This purpose of this report is to describe flow characteristics of the Snake River and tributaries and to develop a water budget for the Snake River Plain. Data and interpretation in this report will be used in development of ground-water flow models.

Idaho, Oregon↗

SutraGUI, a graphical-user interface for SUTRA, a model for ground-water flow with solute or energy transport

This report describes SutraGUI, a flexible graphical user-interface (GUI) that supports two-dimensional (2D) and three-dimensional (3D) simulation with the U.S. Geological Survey (USGS) SUTRA ground-water-flow and transport model (Voss and Provost, 2002). SutraGUI allows the user to create SUTRA ground-water models graphically. SutraGUI provides all of the graphical functionality required for setting up and running SUTRA simulations that range from basic to sophisticated, but it is also possible for advanced users to apply programmable features within Argus ONE to meet the unique demands of particular ground-water modeling projects. SutraGUI is a public-domain computer program designed to run with the proprietary Argus ONE? package, which provides 2D Geographic Information System (GIS) and meshing support. For 3D simulation, GIS and meshing support is provided by programming contained within SutraGUI. When preparing a 3D SUTRA model, the model and all of its features are viewed within Argus 1 in 2D projection. For 2D models, SutraGUI is only slightly changed in functionality from the previous 2D-only version (Voss and others, 1997) and it provides visualization of simulation results. In 3D, only model preparation is supported by SutraGUI, and 3D simulation results may be viewed in SutraPlot (Souza, 1999) or Model Viewer (Hsieh and Winston, 2002). A comprehensive online Help system is included in SutraGUI. For 3D SUTRA models, the 3D model domain is conceptualized as bounded on the top and bottom by 2D surfaces. The 3D domain may also contain internal surfaces extending across the model that divide the domain into tabular units, which can represent hydrogeologic strata or other features intended by the user. These surfaces can be non-planar and non-horizontal. The 3D mesh is defined by one or more 2D meshes at different elevations that coincide with these surfaces. If the nodes in the 3D mesh are vertically aligned, only a single 2D mesh is needed. For nonaligned meshes, two or more 2D meshes of similar connectivity are used. Between each set of 2D meshes (and model surfaces), the vertical space in the 3D mesh is evenly divided into a user-specified number of layers of finite elements. Boundary conditions may be specified for 3D models in SutraGUI using a variety of geometric shapes that may be located freely within the 3D model domain. These shapes include points, lines, sheets, and solids. These are represented by 2D contours (within the vertically-projected Argus ONE view) with user-defined elevations. In addition, boundary conditions may be specified for 3D models as points, lines, and areas that are located exactly within the surfaces that define the model top and the bottoms of the tabular units. Aquifer properties may be specified separately for each tabular unit. If the aquifer properties vary vertically within a unit, SutraGUI provides the Sutra_Z function that can be used to specify such variation.

Open-File Report↗

Occurrence and distribution of volatile organic compounds and pesticides in ground water in relation to hydrogeologic characteristics and land use in the Santa Ana basin, southern California

This report presents an evaluation of the occurrence and distribution of VOCs and pesticides in the Santa Ana ground-water basins in relation to two types of explanatory factors: hydrogeologic characteristics and land use. The Santa Ana Basin is subdivided into the San Jacinto, the Inland, and the Coastal ground-water basins. Most wells sampled were deep and used for public supply. Data from regional studies were used to evaluate the occurrence and distribution of pesticides and volatile organic compounds (VOCs) in relation to hydrogeologic characteristics and land uses that could potentially explain variations between basins. Additional data from special studies (flow path and aquifer susceptibility) were used to evaluate potential factors affecting water quality for individual basins. The hydrogeologic characteristics evaluated in this report were hydrogeologic setting, ground-water age, depth to the top of the well screen (top of well perforations), and proximity to engineered recharge facilities. Urban land use, agricultural land use, and population density were characterized within a 500-meter radius of sampled wells and at the basin scale. Aquifers in the San Jacinto Basin are generally unconfined, and major land-use categories are urban (33 percent), agricultural (37 percent), and undeveloped (25 percent). Recharge is primarily from the overlying landscape, but engineered recharge is locally important in the Hemet area. VOCs and pesticides were detected more frequently in younger ground water (less than 50 years old) than in older ground water, and more frequently in shallower wells than deeper wells; the numbers of VOCs and pesticides detected also were significantly higher in the younger ground water and in the shallower wells. In the Hemet area of the San Jacinto Basin, VOCs and pesticides were detected more frequently in wells proximal to engineered recharge facilities than in distal wells. These patterns illustrate the importance of proximity to sources of recharge in relation to the occurrence and distribution of VOCs and pesticides in ground water. Aquifers in the Inland Basin also are generally unconfined, and the major land-use category is urban (58 percent), with lesser amounts of agricultural (13 percent) and undeveloped (28 percent) land. Recharge is from engineered facilities that utilize local runoff and imported water and from vertical infiltration. VOCs and pesticides were detected more frequently in younger ground water than in older ground water, and more frequently in shallower wells than deeper wells. The number of VOCs detected per well also was significantly higher in the younger ground water and in the shallower wells. Several solvent plumes extending between 5 and 10 kilometers illustrate the large distances that contaminants travel in basins with intensive use of ground water. Aquifers in the Coastal Basin, in contrast to the other basins, are generally confined. Land use in the basin is largely urban (80 percent), with lesser amounts of agricultural (7 percent) and undeveloped (12 percent) land. Recharge is primarily from engineered facilities that utilize water diverted from the Santa Ana River and imported water. Consequently, VOCs and pesticides were detected more frequently in wells proximal to engineered recharge facilities than in distal wells. These compounds were also detected more frequently in the unconfined area than in the confined area of the basin. In the confined area, the numbers of VOCs and pesticides detected per well were not significantly different in wells with shallower and deeper screens. This distribution reflects the dominance of lateral flow and insulation from overlying land use in the confined aquifers of the Coastal Basin. In the unconfined area of the Coastal Basin, the numbers of VOCs and pesticides detected per well were significantly higher in shallower wells than in deeper wells. VOC and pesticide detections were not statist

Scientific Investigations Report↗

Guidelines and standard procedures for studies of ground-water quality; selection and installation of wells, and supporting documentation

This is the first of a two-part report to document guidelines and standard procedures of the U.S. Geological Survey for the acquisition of data in ground-water-quality studies. This report provides guidelines and procedures for the selection and installation of wells for water-quality studies/*, and the required or recommended supporting documentation of these activities. Topics include (1) documentation needed for well files, field folders, and electronic files; (2) criteria and information needed for the selection of water-supply and observation wells, including site inventory and data collection during field reconnaissance; and (3) criteria and preparation for installation of monitoring wells, including the effects of equipment and materials on the chemistry of ground-water samples, a summary of drilling and coring methods, and information concerning well completion, development, and disposition.

Water-Resources Investigations Report↗

Hydrogeologic data for the lower Connecticut River basin, Connecticut

This report contains geologic, ground-water, and miscellaneous data on the quality of surface water collected for a water-resources inventory of the lower Connecticut River basin, Connecticut. The study was made by the U.S. Geological Survey in fiscal cooperation with the Connecticut Department of Environmental Protection. A companion report (Connecticut Water Resources Bulletin No. 31, in preparation) interprets the factual information presented here or otherwise collected for the study.

Connecticut↗

Hydrogeologic data for the lower Connecticut River basin, Connecticut

This report contains geologic, ground-water, and miscellaneous data on the quality of surface water collected for a water-resources inventory of the lower Connecticut River basin, Connecticut. The study was made by the U.S. Geological Survey in fiscal cooperation with the Connecticut Department of Environmental Protection. A companion report (Connecticut Water Resources Bulletin No. 31, in preparation) interprets the factual information presented here or otherwise collected for the study.

Connecticut↗

Potential for using the Upper Coachella Valley ground-water basin, California, for storage of artificially recharged water

This report presents a preliminary evaluation of the geohydrologic factors affecting storage of water by artificial recharge in the upper Coachella Valley, Calif. The ground-water basin of the upper Coachella Valley seems to be geologically suitable for large-scale artificial recharge. A minimum of 900 ,000 acre-feet of water could probably be stored in the basin without raising basinwide water levels above those that existed in 1945. Preliminary tests indicate that a long-term artificial recharge rate of 5 feet per day may be feasible for spreading grounds in the basin if such factors as sediment and bacterial clogging can be controlled. The California Department of Water Resources, through the Future Water Supply Program, is investigating the use of ground-water basins for storage of State Water Project water in order to help meet maximum annual entitlements to water project contractors. (USGS)

Open-File Report↗

Interaction between ground water and surface water in Taylor Slough and vicinity, Everglades National Park, South Florida: Study methods and appendixes

The data presented in this report are products of an investigation that quantified interactions between ground water and surface water in Taylor Slough in Everglades National Park. Determining the extent of hydrologic interactions between wetland surface water and ground water in Taylor Slough is important because the balance of freshwater flow in the lower part of the Slough is uncertain. Although freshwater flows through Taylor Slough are quite small in comparison to Shark Slough (the larger of the two major sloughs in Everglades National Park), flows through Taylor Slough are especially important to the ecology of estuarine mangrove embayments of northeastern Florida Bay. Also, wetland and ground- water interactions must be quantified if their role in affecting water quality is to be determined. In order to define basic hydrologic characteristics of the wetland, depth of wetland peat was mapped, and hydraulic conductivity and vertical hydraulic gradients in peat were determined. During specific time periods representing both wet and dry conditions in the area, the distribution of major ions, nutrients, and water stable isotopes throughout the slough were determined. The purpose of chemical measurements was to identify an environmental tracer could be used to quantify ground-water discharge.

Florida↗

Estimated short-term yields of and quality of ground water in stratified-drift aquifer areas in the Neponset River Basin, Massachusetts

This report presents the estimated short-term yields and quality of ground water in stratifieddrift aquifer areas in the Neponset River Basin, Massachusetts. Stratified glacial drift forms the major aquifer areas in the basin. These thin valley-fill aquifer areas of sand and gravel have saturated thicknesses of as much as 130 feet and widths that reach a maximum of 8,000 feet in some of the bedrock valleys. For 14 selected aquifer areas, estimated shortterm yields from aquifer storage, which is repre- sentative of short-term duration yield available during severe drought conditions, ranged from 2.1 to 12.4 cubic feet per second after 30 days of pumping and from 0.3 to 7.1 cubic feet per second after 180 days of pumping. Ground water in the basin tends to be slightly acidic, of low to moderate hardness, and hasrelatively low concentrations of dissolved solids. Sodium is the dominant cation and chloride the dominant anion. In one-half of the wells sampled, iron and manganese concentrations exceeded the U.S. Environmental Protection Agency Secondary Maximum Contaminant Levels (SMCL's) of 300 and 50 micrograms per liter, respectively.

Water-Resources Investigations Report↗

Ground water in the Raft River Basin, Idaho, with special reference to irrigation use, 1956-60

In the Raft River basin in south-central Idaho, ground-water withdrawals for irrigation have more than doubled since 1955, when data were compiled for a comprehensive report on the area. The present report summerizes data on the ground-water use and changes in the water regimen during the intervening 5 years. Water levels have declined 10 to 20 feet in the areas of heaviest pumping and 3 to 5 feet throughout the remainder of the area. These water-level declines are related to increased ground-water pumpage and below-normal precipitation in the basin. The total pumpage during the 1960 irrigation season is estimated to be about 127,000 acre-feet, of which about half was consumed by crops or evaporated. The remainder returned to the aquifer. Irrigation development is acting to reduce the amount of underflow out of the basin. The water table can be lowered considerably more before underflow from the basin would be reduced substantially.

Idaho↗

Water-quality assessment of part of the Upper Mississippi River Basin, Minnesota and Wisconsin - Ground-water quality in three different land-use areas, 1996-98

The surficial sand and gravel aquifer is susceptible to effects from land-use in the Upper Mississippi River Basin study unit of the National Water-Quality Assessment (NAWQA) Program. The purpose of this report is to describe the ground-water quality and the assessment of how different land-uses affect the shallow ground-water quality in the surficial sand and gravel aquifer. Ground-water quality was compared in three different land-use areas; an urban residential/commercial area on the edge of the Anoka Sand Plain in a portion of the Twin Cities metropolitan area (urban study), an intensive agricultural area in the Anoka Sand Plain (agricultural study), and a forested area in the Bemidji-Bagley Sand Plain (forested study). Ground water was sampled and analyzed for about 200 constituents, including physical parameters, major ions, selected trace elements, nutrients, dissolved organic carbon, selected pesticides, selected volatile organic compounds (VOCs), and tritium. The urban study wells were sampled during June and July 1996. The agricultural study wells were sampled during May and September 1998. The forested study wells were sampled during June 1998. The depth to water below the land surface generally was less than 20 ft in all three land-use studies. The median pH value in the urban study was 7.2, with medians in the agricultural and forested studies at 7.4 and 7.5, respectively. The median specific conductance was significantly greater in the urban study than in the agricultural and forested studies (914, 553, and 487 µS/cm respectively). The median dissolved oxygen concentration in the urban study (0.9 mg/L) was significantly less than the median in the agricultural or forested studies (5.3 and 2.3 mg/L respectively). Alkalinities in the agricultural study, with a median of 178 mg/L as CaCO 3 , were significantly less than medians in the urban or forested studies (261 and 246 mg/L as CaCO 3 , respectively). The water composition in the surficial aquifer in all three land-use studies is dominated by calcium, magnesium, and bicarbonate. Sulfate and chloride concentrations in water samples were significantly greater in the urban study than in the agricultural or forested studies, and concentrations in the forested study were least. Most of the water samples in all three land-use studies were very hard (greater than 180 mg/L as CaCO 3 ). Nitrate-nitrogen concentrations were greatest in the agricultural study, in which 38 percent of water samples exceeded the U.S. Environmental Protection Agency’s maximum contaminant level (MCL) for nitrate-nitrogen. Nitrate-nitrogen was greater than the MCL in 3 percent of urban study samples. None of the forested study samples exceeded the MCL for nitrate-nitrogen. Concentrations of phosphorus generally were less than 0.05 mg/ L, with no significant differences between the land-uses. A total of 19 pesticides were detected in water samples from one or more land-use study wells, with 11 pesticides detected in the urban study, 14 detected in the agricultural study, and 4 detected in the forested study. Atrazine, deethylatrazine, and simazine were the only pesticides detected in all three land-use studies. A significantly greater percentage of pesticide detections were present in water samples from the agricultural study than from the urban or forested studies (86.2, 56.7, and 46.7 percent, respectively). Prometon was the most frequently detected pesticide in the urban study. Atrazine and deethylatrazine were the most frequently detected pesticides in the agricultural and forested studies. Twenty-one VOCs were detected in water samples from one or more land-use study wells, with 19 detected in the urban study, 7 detected in the agricultural study, and none detected in the forested study. Chloromethane, trichloromethane, methylbenzene, trichlorofluoromethane, and benzene were all detected in both the urban and agricultural studies. A significantly greater percentage of VOC detections were present in water samples from the urban study than from the agricultural study (90 and 50 percent, respectively). Carbon disulfide was the most frequently detected VOC in the urban study. The compound 1,2,3,4-tetramethyl benzene was the most frequently detected VOC in the agricultural study. Tritium concentrations indicate that the water in the surficial sand and gravel aquifer has been recharged since 1953. Median tritium concentrations ranged from 11.6 to 12.8 tritium units. No significant difference in tritium concentrations was present between the three land-use studies. Comparisons of previous land-use studies in Minnesota with the three NAWQA land-use studies generally indicated the same patterns. Ground-water quality in surficial sand and gravel aquifers is affected by land-use practices. Ground water in urban studies has greater specific conductances, alkalinities, chloride, sodium, sulfate, and dissolved solid concentrations than agricultural or forested/undeveloped studies. Nitrate-nitrogen was detected in greater concentrations in agricultural studies than in urban studies, with concentrations in the forested/undeveloped studies less than in the agricultural or the urban studies. Agricultural studies have the greatest detection rates, numbers, and total concentrations of pesticides. Pesticide detection rates and total pesticide concentrations in the urban studies were less than in the agricultural studies, with the most frequently detected pesticides (prometon and dicamba) different than those in the agricultural studies (atrazine and deethylatrazine). A greater number of VOCs were detected in urban studies and at greater concentrations than in agricultural studies. Few pesticides or VOCs were detected in forested/undeveloped studies.

Minnesota↗

Simulations of Ground-Water Flow, Transport, Age, and Particle Tracking near York, Nebraska, for a Study of Transport of Anthropogenic and Natural Contaminants (TANC) to Public-Supply Wells

Contamination of public-supply wells has resulted in public-health threats and negative economic effects for communities that must treat contaminated water or find alternative water supplies. To investigate factors controlling vulnerability of public-supply wells to anthropogenic and natural contaminants using consistent and systematic data collected in a variety of principal aquifer settings in the United States, a study of Transport of Anthropogenic and Natural Contaminants to public-supply wells was begun in 2001 as part of the U.S. Geological Survey National Water-Quality Assessment Program. The area simulated by the ground-water flow model described in this report was selected for a study of processes influencing contaminant distribution and transport along the direction of ground-water flow towards a public-supply well in southeastern York, Nebraska. Ground-water flow is simulated for a 60-year period from September 1, 1944, to August 31, 2004. Steady-state conditions are simulated prior to September 1, 1944, and represent conditions prior to use of ground water for irrigation. Irrigation, municipal, and industrial wells were simulated using the Multi-Node Well package of the modular three-dimensional ground-water flow model code, MODFLOW-2000, which allows simulation of flow and solutes through wells that are simulated in multiple nodes or layers. Ground-water flow, age, and transport of selected tracers were simulated using the Ground-Water Transport process of MODFLOW-2000. Simulated ground-water age was compared to interpreted ground-water age in six monitoring wells in the unconfined aquifer. The tracer chlorofluorocarbon-11 was simulated directly using Ground-Water Transport for comparison with concentrations measured in six monitoring wells and one public supply well screened in the upper confined aquifer. Three alternative model simulations indicate that simulation results are highly sensitive to the distribution of multilayer well bores where leakage can occur and that the calibrated model resulted in smaller differences than the alternative models between simulated and interpreted ages and measured tracer concentrations in most, but not all, wells. Results of the first alternative model indicate that the distribution of young water in the upper confined aquifer is substantially different when well-bore leakage at known abandoned wells and test holes is removed from the model. In the second alternative model, simulated age near the bottom of the unconfined aquifer was younger than interpreted ages and simulated chlorofluorocarbon-11 concentrations in the upper confined aquifer were zero in five out of six wells because the conventional Well Package fails to account for flow between model layers though well bores. The third alternative model produced differences between simulated and interpreted ground-water ages and measured chlorofluorocarbon-11 concentrations that were comparable to the calibrated model. However, simulated hydraulic heads deviated from measured hydraulic heads by a greater amount than for the calibrated model. Even so, because the third alternative model simulates steady-state flow, additional analysis was possible using steady-state particle tracking to assess the contributing recharge area to a public supply well selected for analysis of factors contributing to well vulnerability. Results from particle-tracking software (MODPATH) using the third alternative model indicates that the contributing recharge area of the study public-supply well is a composite of elongated, seemingly isolated areas associated with wells that are screened in multiple aquifers. The simulated age distribution of particles at the study public-supply well indicates that all water younger than 58 years travels through well bores of wells screened in multiple aquifers. The age distribution from the steady-state model using MODPATH estimates the youngest 7 percent of the water to have a flow-weighted mean age

Scientific Investigations Report↗