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Using subducting plate motion to constrain Cascadia slab geometry and interface strength

Subduction zones are home to multiple geohazards driven by the evolution of the regional tectonics, including earthquakes, volcanic eruptions and landslides. Past evolution builds the present-day structure of the margin, while the present-day configuration of the system determines the state-of-stress in which individual hazardous events manifest. Regional simulations of subduction zones provide a tool to synthesize the tectonic history of a region and investigate how geologic features lead to variations in the state of stress across the subduction system. However, it is challenging to design regional models that provide a force-balance that is consistent with the large-scale motion of surrounding tectonic plates while also not over-constraining the solution. Here, we present new models for the Cascadia subduction zone that meet these criteria and demonstrate how the motion of the subducting Juan de Fuca plate can be used to determine the along-strike variations in the viscous (long-term) coupling across the plate boundary. All successful models require lower viscous coupling in the northern section of the trench compared to the central and southern sections. However, due to uncertainties in the geometry of the Cascadia slab, we find that there is a trade-off between along-strike variation in viscous coupling and slab shape. Better constraints on the slab shape, and/or use of other observations are needed to resolve this trade-off. The approach presented here provides a framework for further exploring how geologic features in the overriding plate and the properties of the plate boundary region affect the state-of-stress across this and other subduction zones.

Cascadia subduction zone

The use of fluorite geochemistry and machine learning to identify critical mineral systems

Fluorite (CaF 2 ) is a potential pathfinder to critical mineral and rare earth element (REE) deposits but its application has been limited to a narrow range of mineralization types. I show that fluorite is a robust recorder of mineralization fertility by applying statistical and machine-learning methods to a new global fluorite geochemical database. Distinct median rare earth and trace element patterns are observed among deposit types and genetic environments. Fluorite associated with carbonatites and REE deposits are relatively enriched in Sr and have minimal Eu anomalies. These characteristics define new bivariate discrimination diagrams that correctly identify 78% of carbonatite-related fluorite and 88% of fluorite from REE deposits. Random forest classifiers were developed for a wide range of mineralization types and genetic settings. Trained solely on rare earth element patterns, these models achieve accuracies of 77–79%. Higher classification accuracies (up to 88–96%) are obtained when including elements such as Sr, highlighting the significance of trace elements for optimal fluorite classification. The recognition of diagnostic fluorite compositional fingerprints, particularly in REE-fertile systems, underscores its potential as a pathfinder and indicator for critical mineral exploration in F-bearing environments.

Mineralium Deposita

Bathymetric and velocimetric surveys at highway bridges crossing the Missouri and Mississippi Rivers on the periphery of Missouri, June 13–22, 2022

Bathymetric and velocimetric data were collected by the U.S. Geological Survey, in cooperation with the Missouri Department of Transportation, near seven bridges at six highway crossings of the Missouri and Mississippi Rivers on the periphery of Missouri from June 13–22, 2022. A multibeam echosounder mapping system was used to obtain channel-bed elevations for river reaches about 1,640 feet longitudinally and generally extending laterally across the active channel from bank to bank during minor flood-flow conditions. These surveys provided channel geometry and hydraulic conditions at the time of the surveys and provided characteristics of scour holes that may be useful in developing or verifying predictive guidelines or equations for computing potential scour depth. These data also may be useful to the Missouri Department of Transportation as a minor flood-flow assessment of the bridges for stability and integrity issues with respect to bridge scour during floods. Bathymetric data were collected around every in-channel pier. Scour holes were present at most piers for which bathymetry could be obtained, except those on banks or surrounded by riprap. Occasionally, scour holes were minor and difficult to discern from nearby dunes and ripples. All bridge sites in this study were surveyed and documented in previous studies. Although partial exposure of substructural support elements was observed at several piers, at most sites the exposure most likely is minimal compared to the overall substructure that remains buried in bed material at these piers. The notable exceptions are piers 12 and 13 at structure L0135 on State Highway 51 at Chester, Illinois, where the bedrock material was fully exposed around the piers. The average difference between the bathymetric surfaces between 2022 and 2018 varied from 0.41 foot higher to 1.86 feet lower. Between 2022 and 2014, the average difference between the bathymetric surfaces varied from 1.02 feet higher to 4.69 feet lower. Only the two sites on the Missouri River and the Caruthersville site were surveyed in 2011; for those sites, the average difference between the bathymetric surfaces varied from 5.83 feet higher to 1.34 feet lower. The most substantial overall net gain of sediment in a reach was between 2011 and 2022 at structure A1700 near Caruthersville, Mo. (site 38). This result was expected because structure A1700 is downstream from the confluences of the Missouri and Ohio Rivers, and therefore subject to the largest streamflows, the largest streamflow fluctuations, and the most substantial sediment flux, as has historically been observed at this site. The presence of riprap blankets, pier size and nose shape, and alignment to flow had a substantial effect on the size of the scour hole observed for a given pier. Piers that were surrounded by riprap blankets had scour holes that were substantially smaller (to nonexistent) compared to piers at which no rock or riprap were present. New riprap blankets were surveyed at pier 3 of structure L0098 at Brownville, Nebraska, and at piers 15–18 of structure A1700 near Caruthersville, Mo., that effectively mitigated the scour holes historically observed at these piers. Narrow piers having round or sharp noses that were aligned with flow often had scour holes that were difficult to discern from nearby bed features, whereas piers having wide or blunt noses resulted in larger, deeper scour holes. Several of the structures had piers that were skewed to primary approach flow. Scour holes near these piers consistently displayed greater depth on the side of the pier with impinging flow and deposition on the leeward side of the pier.

Missouri

Polystyrene microplastics alter the accumulation and elimination dynamics of silver nanoparticles in Daphnia magna

Rationale Microplastics (MPs) can interact with engineered nanomaterials and alter their environmental fate and bioavailability. However, their influence on the bioaccumulation dynamics of silver nanoparticles (AgNPs) in aquatic filter feeders under environmentally relevant conditions remains poorly understood. We hypothesized that polystyrene microplastics (PS-MPs) alter the uptake, elimination and overall bioaccumulation dynamics of AgNPs in Daphnia magna . Methodology Adult D. magna were exposed to isotopically labeled citrate-coated 109 AgNPs in the presence and absence of PS-MPs. Waterborne uptake, dietary uptake, assimilation efficiency, food ingestion and elimination were quantified experimentally and incorporated into a biodynamic model to predict steady-state silver (Ag) concentrations under environmentally relevant exposure scenarios. Results PS-MPs increased waterborne Ag accumulation by approximately eightfold compared with AgNPs exposure alone. However, Ag elimination was substantially faster, with 98% of accumulated Ag eliminated after five days of depuration compared with 66% without PS-MPs. PS-MPs also reduced food ingestion rates (IRs), while assimilation efficiency remained largely unchanged. Biodynamic modeling predicted that steady-state Ag accumulation was approximately fivefold greater in the presence of PS-MPs, with waterborne exposure becoming the dominant accumulation pathway. Discussion These findings suggest that PS-MPs alter bioaccumulation dynamics of AgNPs in filter-feeding organisms by enhancing organism-associated Ag during waterborne exposure while accelerating Ag elimination, likely through particle-associated transport and gut egestion. Collectively, these results underscore the complexity of Ag bioaccumulation processes when MPs and AgNPs interact and highlight the importance of studies conducted under environmentally relevant conditions.

Environmental Chemistry

Performance analysis of oil recovery and CO2 retention in a greenfield residual oil zone: CO2-EOR in Tall Cotton Field (Permian Basin, West Texas, USA)

Residual oil zones (ROZs) can offer significant oil resources via enhanced oil recovery (EOR) as well as subsurface carbon dioxide (CO 2 ) retention during injection. If injected CO 2 is anthropogenic, the ROZs can offer a substantial geologic storage potential. The ROZs below the oil/water contact (OWC) of main pay zones (MPZ) in conventional reservoirs or brownfields, are more commonly developed for CO 2 injection and oil production and reported in the literature. However, CO 2 -EOR in greenfield ROZs, reservoirs without a MPZ present, have rarely been developed for CO 2 -EOR operation. The Tall Cotton Field of West Texas, Permian Basin, which started production in 2015 (Phase 1) and expanded in 2017 (Phase 2) from the San Andres Limestone, is one of the first examples of greenfield ROZs developed for EOR by injecting CO 2 . This paper analyses EOR and CO 2 retention performance of Tall Cotton Field using allocated injection and production data from inverted 5-spot well patterns of Phase-1 and -2 developments. Production and injection data allocated to each of the 28 identified patterns (nine 20-acre patterns for Phase-1, three 20-acre and sixteen 10-acre patterns for Phase-2) were analyzed for historical and forecasted oil recovery using ratio-trend decline analysis, and for CO 2 retention performance of the patterns. The allocated data were further used to calculate injected reservoir pore volume and void replacement ratios (VRR) for the analysis period. Quantitative results indicated that oil recovery factors of the 5-spot patterns varied between 4–10 %, and 5–30 % between the end of injection and the forecast periods, respectively. Storage of CO 2 , on the other hand, increased to a mean value of ∼7130 MMscf per pattern in Phase-1 and to a mean storage of 3700 MMscf per pattern in Phase-2 until the end of injection, followed by a decline after the end of injection and into the forecast period. Resulting CO 2 utilization factors ∼6–50 Mscf/bbl were estimated at the end of injection. Overall, presented results suggested that developing greenfield ROZs for CO 2 -EOR can be as promising as brownfield ROZs and mature MPZs for EOR and underground storage of injected CO 2 . For Tall Cotton Field, results suggest that Phase-2 patterns generally outperformed Phase-1 for oil recovery factors, while Phase-1 performed better in CO 2 retention performance metrics. This is the first study in the literature that reports a detailed CO 2 -EOR performance analysis of a greenfield ROZ in the Permian Basin, which can potentially allow for comparison with MPZs and brownfield ROZs.

Texas

A temporal look at the influence of topographic amplification on earthquake-triggered landslides in 3D seismic simulations

Earthquakes are a primary trigger for landslides, often leading to catastrophic consequences. While numerous studies have explored the spatial distribution of earthquake-triggered landslides, understanding the interaction between seismic waves and topography remains a critical challenge. Topographic irregularities can cause seismic wave amplification, altering ground shaking, and can trigger landslides that are challenging for predictive models to anticipate. This study investigates the spatial and temporal evolution of topographically amplified landslides, focusing on coseismic landslides triggered by the Mw 7.5 mainshock of the 2018 Papua New Guinea earthquake and post-seismic landslides associated with its four aftershocks, each exceeding Mw 6.0. We employ low-frequency, three-dimensional numerical ground shaking simulations and data-driven multivariate analyses to examine how landslides evolved from the coseismic to post-seismic periods. Our findings reveal a spatial shift in landslide distribution, in which the mainshock triggered slope failures predominantly on steep hillslopes, and the aftershocks triggered landslides on gentler slopes, often near geologic boundaries. We attribute this transition partly to the earthquake legacy effect of the mainshock, where the mainshock caused weakening of these hillslopes, making them more prone to failure when aftershocks occur. Additionally, the concentration of failures along geologic contacts in the post-seismic phase suggests that site amplification, stemming from contrasts in subsurface materials, exerts a key influence on landslide occurrence. Although not explicitly captured in our current numerical simulations, this mechanism warrants further investigation for more accurate hazard modeling.

JGR Solid Earth

In-situ geochronology using LA-ICP-MS/MS: Application of the Lu-Hf system in carbonate, apatite and fluorite

Geochronology is a fundamental tool for reconstructing earth history and constraining the timing of ore deposit formation. Traditionally, U-rich minerals like zircon, titanite, monazite and apatite have been analysed to determine the timing of mineralization and alteration events. However, not all deposits or alteration assemblages contain these minerals, and the U-Pb system can be disturbed due to open system behaviour. We present a methodology for obtaining in-situ Lu-Hf dates from various minerals to demonstrate the potential for dating ore deposits that lack U-rich minerals. Carbonate, apatite and fluorite minerals from different tectonic settings and geological environments were analysed. We acquired Lu-Hf and REE (rare earth element) data from carbonate minerals from a carbonatite orebody and dike samples from the Mountain Pass REE carbonatite deposit in California, USA. We also tested a ‘double-dating’ method, where U-Th-Pb dates and Lu-Hf dates were obtained from the same analysis of apatite from rocks in the Michigan’s Great Lakes Tectonic Zone. Preliminary results for Lu-Hf dating of fluorite from carbonatite rocks in the Lemitar Mountains of New Mexico are also included. The analytical methodology shows promising results in each of these cases where there is sufficient parent Lu and U and measurable daughter Hf and Pb respectively.

Conference Paper

New York and Landsat

From the iconic skyline of New York City to the forested landscapes of the Adirondack Mountains and the countryside of the Allegheny Plateau, the State of New York is overflowing with diversity and life. Bordered by the Atlantic Ocean on the east and two of the Great Lakes to the north and west, New York has more than 7,600 lakes, ponds, and reservoirs and more than 70,000 miles of rivers and streams. New York’s stewardship of its freshwater resources is fundamental to the health and well-being of all who work at, reside in, and visit the State’s landmarks and places. Harmful algal blooms in the State’s waterbodies are a growing concern and threaten the health of the region and its inhabitants. Images and data from Landsat satellites continue to provide critical information to scientists, public health officials, and resource managers who are studying the effects and risks of the problem.

New York

Simulation of groundwater flow in the Long Island, New York regional aquifer system for pumping and recharge conditions from 1900 to 2019

The U.S. Geological Survey has developed a transient, groundwater-flow model that simulates hydrologic conditions in the Long Island aquifer system as part of an ongoing (since 2016) multiyear, cooperative investigation with the New York State Department of Environmental Conservation. The goals of this investigation are to assist stakeholders and resource managers to evaluate the response of the hydrologic system to changes in future hydraulic stresses. Responses in the hydrologic system include changes in water levels in the hydrogeologic units; discharge to streams, coastal waters, and subsurface infrastructure; and the extent of saline groundwater in the aquifers. Hydraulic stresses include future water-supply management and changes in land use and infrastructure. The numerical model synthesizes a diverse set of physiographic, geologic, climatic, land-use, and historical population, water use, and infrastructure data to physically represent the Long Island aquifer system from land surface to bedrock and to simulate annual hydrologic conditions between 1900 and 2019. A three-dimensional hydrogeologic framework was developed from existing and recently collected borehole geologic and geophysical data collected as part of a companion drilling program. Water-transmitting properties of the principal aquifer sediments were defined in three dimensions from new and existing lithologic logs. The distribution of recharge from precipitation was estimated from landscape characteristics and climate data. Anthropogenic recharge from wastewater, leaky infrastructure, and storm runoff were estimated from population, infrastructure, and pumping data. Water-use data, including well locations, depths, and pumping rates, were obtained from historical sources and records and used to estimate pumping stresses continuously in time and space, at an annual average time scale. The data were incorporated into a three-dimensional numerical model using the U.S. Geological Survey finite difference modeling code MODFLOW 6; the model encompassed all of Long Island and surrounding surface waters and simulated historical hydrologic conditions from 1900 to 2019. The calibration process involved trial and error adjustments using prior knowledge to improve general fit to observations followed by an inverse calibration to update and optimize input parameters, using an iterative ensemble smoother algorithm implemented in PEST++ version 5.0. This resulted in a model that generally was in good agreement with observed, dynamically varying hydrologic conditions from 1900 to 2019. The calibrated model was used to develop two base-case models for scenario testing of future, hypothetical conditions where one represented average-annual conditions, and one represented average-seasonal conditions from 2010 to 2019. The model representing average-annual conditions was modified further to represent an alternate sea-level position of 6 feet above the North American Vertical Datum of 1988, and the model representing average-seasonal conditions was modified to represent the average seasonal effects of a 5-year drought imposed upon current hydrologic conditions. Recharge is the sole source of water to the aquifer system; groundwater discharges to coastal water and streams and is withdrawn by pumped wells. Model-estimated annual recharge ranged from about 11 inches in 1965 to 41 inches in 1983. On average, from 2010 to 2019, about 23 percent of water was pumped from wells, and about 47 and 27 percent discharged to coastal waters and streams, respectively; the remaining 4 percent was water that moved into storage in the aquifer matrix. Water levels on Long Island vary naturally during time in response to changes in recharge; the amount of variation is largest in the interior of the island, in areas with highest water table altitudes near groundwater divides and lowest near streams and the coastal waters. The total range of water table altitudes on Long Island between 1900 and 2019 ranged from near 0 to more than 70 feet in western parts of Long Island. The largest range in altitudes is in New York City and is associated with areas of large historical withdrawals between the 1920s and the late 1980s. Water table altitudes generally varied by less than 10 feet in eastern Suffolk County, where the aquifer is under more natural conditions. Saltwater intrusion is of great concern on Long Island, particularly in western Long Island where both the unconfined and confined parts of the aquifer system have been intruded in response to large-scale groundwater withdrawals; however, the volume of freshwater in the islandwide aquifer system only has changed by about 5 percent between 1900 and 2019. The decadal change in the freshwater volume was largest during the early and mid-20th century, corresponding to the largest historical pumping, but that volume change did not exceed 1 percent. The negligible change in freshwater volume suggests that saltwater intrusion as of 2019 was limited at an islandwide scale but continues to occur in local areas of Queens and Nassau Counties, adversely affecting current water supplies and limiting future water supplies for affected communities. The regional groundwater model developed for this investigation is a tool that can be used to help determine the viability of current and future water supplies at a regional scale and can be used to support development of additional models at finer scale to support more focused assessments of groundwater sustainability.

New York

Simulation of groundwater flow in the Silurian aquifer, eastern Iowa, 2020–45

The Silurian aquifer is an important water source for municipalities, industry, and rural households and communities in eastern Iowa, including Johnson County. Increasing demand for groundwater from the aquifer indicated that analytical tools may be beneficial to quantify groundwater resources and inform water-management decisions for the aquifer. The U.S. Geological Survey, in cooperation with the Johnson County Board of Supervisors, developed conceptual and numerical groundwater models to simulate water levels in the Silurian aquifer, determine groundwater budgets, and forecast changes in groundwater levels through 2045. A MODFLOW numerical model was constructed to match water levels for 2020 through 2022. Model performance was assessed by comparing simulated and observed water-level hydrographs at several pumping and monitoring wells. Hydrograph comparison indicates that the model simulates water levels accurately at monitoring wells that are not near areas of pumping and generally overpredicts water levels near pumping wells, while accurately simulating the drawdown trend over time at pumping wells. This transient model framework was then used to predict water levels through 2045 in a scenario of moderate drought and increased groundwater withdrawals. Results from the predictive model indicate as much as 13 meters of additional drawdown in 2045 from 2020 water levels in the area of pumping wells.

Iowa

Probabilistic assessment of postfire debris-flow inundation in response to forecast rainfall

Communities downstream of burned steep lands face increases in debris-flow hazards due to fire effects on soil and vegetation. Rapid postfire hazard assessments have traditionally focused on quantifying spatial variations in debris-flow likelihood and volume in response to design rainstorms. However, a methodology that provides estimates of debris-flow inundation downstream of burned areas based on forecast rainfall would provide decision-makers with information that directly addresses the potential for downstream impacts. We introduce a framework that integrates a 24 h lead-time ensemble precipitation forecast with debris-flow likelihood, volume, and runout models to produce probabilistic maps of debris-flow inundation. We applied this framework to simulate debris-flow inundation associated with the 9 January 2018 debris-flow event in Montecito, California, USA. When the observed debris-flow volumes were used to drive the probabilistic forecast model, analysis of the simulated inundation probabilities demonstrates that the model is both reliable and sharp. In the fully predictive model, however, in which debris-flow likelihood and volume were computed from the atmospheric model ensemble's predictions of peak 15 min rainfall intensity, I 15 , the model generally under-forecasted the inundation area. The observed peak I 15 lies in the upper tail of the atmospheric model ensemble spread; thus a large fraction of ensemble members forecast lower I 15 than observed. Using these I 15 values as input to the inundation model resulted in lower-than-observed flow volumes which translated into under-forecasting of the inundation area. Even so, approximately 94 % of the observed inundated area was forecast to have an inundation probability greater than 1 %, demonstrating that the observed extent of inundation was generally captured within the range of outcomes predicted by the model. Sensitivity analyses indicate that debris-flow volume and two parameters associated with debris-flow mobility exert significant influence on inundation predictions, but reducing uncertainty in postfire debris-flow volume predictions will have the largest impact on reducing inundation outcome uncertainty. This study represents a first step toward a near-real-time hazard assessment product that includes probabilistic estimates of debris-flow inundation and provides guidance for future improvements to this and similar model frameworks by identifying key sources of uncertainty.

California

Decadal trends in the quality of groundwater used for public drinking-water supply in California, 2004–23, California Groundwater Ambient Monitoring and Assessment Program, Priority Basin Project

This study provides a comprehensive assessment of decadal changes in the quality of groundwater used for public drinking-water supply at 444 monitoring sites across California during 2004–23. We assessed decadal step trends in groundwater quality for 145 water-quality constituents and geochemical indicators statewide and across geographic and land-use based network groups. We evaluated the statistical significance of directional changes (predominant increase or decrease of constituent concentrations) and the magnitude of those changes across all network groups. Uranium showed the most widespread directional and high-magnitude increases of all constituents with regulatory benchmarks statewide, particularly in the agriculture-dominated Central Valley as well as urban-and desert-dominated regions of Southern California. Fluoride and perchlorate showed the most widespread directional and high-magnitude decreases of all constituents with regulatory benchmarks statewide, which were also most pronounced in Southern California. Although arsenic and nitrate did not often register significant directional changes across network groups, they showed widespread, high-magnitude changes in both directions (increase and decrease) at levels often exceeding 10 percent of respective regulatory benchmarks statewide. Triazine herbicides (atrazine and simazine) and the gasoline oxygenate methyl tert -butyl ether showed significant directional decreases statewide, but not at levels considered to be of high magnitude compared to respective regulatory benchmarks. We observed significant directional and high-magnitude increases of total dissolved solids statewide, which were most pronounced in agricultural areas. Analysis of explanatory geochemical indicators indicated that prevalent statewide increases of alkalinity and calcium were the predominant components of the observed statewide increases in total dissolved solids by mass. Widespread increases in groundwater alkalinity and calcium across agricultural and urban areas may be related, in part, to warm-season irrigation and other anthropogenic factors that have shifted soil weathering dynamics over the long term. Increasing alkalinity concentrations were related to increasing uranium concentrations, particularly in areas with aquifer materials derived from granitic rocks. Conversely, increasing calcium concentrations were related to decreasing fluoride concentrations, particularly in areas where fluoride occurred naturally at elevated concentrations. Decrease of perchlorate, triazine herbicides, and methyl tert -butyl ether are likely related to decreased anthropogenic source inputs over time and natural attenuation in aquifers.

California

Evaluating Laramide orogenesis via flexural basin response in the San Juan basin, New Mexico and Colorado

A challenge in interpreting the location, timing, and magnitude of ancient orogenic events is that ongoing uplift and erosion in the hinterlands often destroys much of the primary record of these events. However, basin-thickness patterns in the sedimentary record can provide complimentary evidence of uplift via flexural effects. Here, we deploy well-log correlation, isochores, basin modeling, flexural modeling, and subcrop mapping to evaluate the Late Cretaceous to Paleogene basin response to Laramide tectonism in the San Juan basin. A wedge of upper Campanian to Maastrichtian sedimentary rock thickens from 200 to 800 meters from southeast to northwest in the basin. This pattern can be successfully simulated via flexural modeling if we infer early Laramide uplift along the northwest basin flank that produced a 0.8 km high topographic load. The Laramide unconformity bounds the top of this Upper Cretaceous sedimentary wedge and truncates progressively older strata to the east, further supporting a westward tilt of the basin. The onset of Campanian Laramide flexure may have also contributed to the profound transgression from the upper Menefee Formation to the Lewis Shale. The Paleocene isochore map displays an approximately symmetrical pattern, with thickening towards the center of the basin. This suggests the possibility of competing flexural loads. The base Eocene structure indicates an asymmetric deep on the northeast flank of the basin, providing flexural evidence of contemporaneous uplift/loading of the Nacimiento uplift and Archuleta arch; this has been modeled as ~2.1 km load height. Both Cretaceous and Paleocene sedimentary wedges are narrow, suggesting low flexural rigidity; modeled effective elastic thicknesses (EET) are 20-30 km, comparable to estimates of modern EET for the region.

Colorado, New Mexico

Correlation analysis of groundwater and hydrologic data, Kaloko-Honokōhau National Historical Park, Hawai‘i

Designated in 1978, Kaloko-Honokōhau National Historical Park is located on the west coast of the Island of Hawaiʻi. The Kaloko-Honokōhau National Historical Park encompasses about 1,200 acres of coastal land and nearshore ecosystems, which include wetlands, anchialine pools (landlocked bodies of brackish water with hydrologic connections to the ocean), fishponds, a fishtrap, and coral reefs. These nearshore ecosystems are dependent on groundwater discharge with a freshwater component and provide habitat for threatened and endangered, endemic species, such as the orangeblack Hawaiian damselfly ( Megalagrion xanthomelas ) and the Hawaiian coot (ʻAlae keʻokeʻo, Fulica alai ). The populations of these native species, however, are threatened because of habitat loss related to urban development and environmental changes. Kaloko-Honokōhau National Historical Park is within the Keauhou aquifer system and the North Kona District, which experienced a 52 percent resident-population increase between 2000 and 2020 and a 41 percent visitor increase between 2008 and 2019. To support the current water demand associated with this growing population, groundwater is the primary source of freshwater used in the North Kona District, with about 15 million gallons of groundwater withdrawn from the Keauhou aquifer system per day since 2009. With anticipated development, future (2015–35) groundwater withdrawal from the Keauhou aquifer system is projected to be about 55 percent greater than recent (2012–14) withdrawal. Because Kaloko-Honokōhau National Historical Park is located within a coastal aquifer, natural and human-induced changes can affect the quality and quantity of groundwater, which can threaten groundwater-dependent ecosystems. To improve understanding of recent groundwater conditions, the U.S. Geological Survey, in cooperation with the National Park Service, undertook this study to document correlations between hydrologic time-series datasets from sites in and near Kaloko-Honokōhau National Historical Park using the nonparametric (distribution-free) Kendall’s tau statistical test. For the statistical analyses, dependent variables representing the groundwater system include groundwater level, the groundwater-level difference between pairs of sites, and specific conductance, and independent variables include datasets of sea level, rainfall, and groundwater withdrawal. About 34 percent of the 140 non-time-lagged Kendall’s tau statistical tests evaluated in this report are statistically significant ( p -value ≤ 0.050) with generally weak (0.1 ≤ tau ≤ 0.2) to moderate (0.2 ≤ tau ≤ 0.3) correlations. Groundwater levels measured at monitoring sites have the strongest correlation with the multivariate El Niño–Southern Oscillation index and withdrawal from production wells at the nearby Kohanaiki Private Club Community. Specific conductance is not consistently and significantly correlated with the independent hydrologic variables investigated in this report. Because the relations between hydrologic variables are commonly not instantaneous, a second set of correlations was evaluated after applying a range of time lags to the independent variable datasets. Relative to the non-time-lagged case (the set of correlations that did not use time-lagged independent variables), some of the time-lagged independent variables improved correlations with some of the dependent variables. For a particular independent variable, similar time lags were expected between the independent variable and dependent variable at all four monitoring sites. However, different time lags among the four sites sometimes produced the strongest correlations. This study identified several correlations that are statistically significant and hydrologically plausible, but the correlations could indicate that multiple concurrent factors are controlling the observed groundwater-system response, which might be better addressed using multivariate analyses. This study only investigates bivariate correlations, which may not explain all the variance in the data. The correlations analyzed in this report are limited by the quantity of available hydrologic data in the area near Kaloko-Honokōhau National Historical Park and are based on 14 years of time-series data, which were aggregated to a relatively coarse monthly temporal resolution that represents the minimum resolution common to all datasets.

Hawaii

Comparing magmatism and hydrothermal alteration using magnetic modelling and stable isotopes at the Clementine porphyry copper prospect, Montana, USA

Recent mapping of the underexplored Clementine prospect in southwestern Montana has revealed evidence of hydrothermal alteration and mineralized breccia vein gossan interpreted to represent the upper expression of a Cretaceous, sediment-hosted copper porphyry system. The prospect is at the nexus of several Cretaceous granites, including the pre-mineralization Butte Granite and Big Hole Canyon plutons and local pre- to post-mineralization granite intrusions. Here, 3D magnetic inversions and stable isotope data are used to evaluate the spatial and genetic relationship of mineralization and Cretaceous magmatism. Magnetic inversions reveal a zone of high magnetic susceptibility beneath the prospect that is related to an exposure of unaltered, likely post-mineralization granite. The granite appears to connect to the Big Hole Canyon pluton at depth, suggesting it is a late-stage differentiate of the cooling, pre-mineralization pluton that may have been one of several potential heat sources for the mineral system at Clementine. This is supported by carbon isotope values of graphite that indicate organic material in shale of the Cretaceous Kootenai Formation was subject to metamorphism. Preliminary light hydrogen isotope values of actinolite hydrothermal orbs suggest formation following magmatic outgassing during thermal advection from an underlying intrusion.

Montana

Storm impact scale for barrier islands

A new scale is proposed that categorizes impacts to natural barrier islands resulting from tropical and extra-tropical storms. The proposed scale is fundamentally different than existing storm-related scales in that the coupling between forcing processes and the geometry of the coast is explicitly included. Four regimes, representing different levels of impact, are defined. Within each regime, patterns and relative magnitudes of net erosion and accretion are argued to be unique. The borders between regimes represent thresholds defining where processes and magnitudes of impacts change dramatically. Impact level 1 is the 'swash' regime describing a storm where runup is confined to the foreshore. The foreshore typically erodes during the storm and recovers following the storm; hence, there is no net change. Impact level 2 is the 'collision' regime describing a storm where the wave runup exceeds the threshold of the base of the foredune ridge. Swash impacts the dune forcing net erosion. Impact level 3 is the 'overwash' regime describing a storm where wave runup overtops the berm or, if present, the foredune ridge. The associated net landward sand transport contributes to net migration of the barrier landward. Impact level 4 is the 'inundation' regime describing a storm where the storm surge is sufficient to completely and continuously submerge the barrier island. Sand undergoes net landward transport over the barrier island; limited evidence suggests the quantities and distance of transport are much greater than what occurs during the 'overwash' regime.

Journal of Coastal Research

The δ13C signature of dissolved organic and inorganic carbon reveals complex carbon transformations within a salt marsh

Coastal wetlands have high rates of atmospheric CO 2 uptake, which is subsequently respired back to the atmosphere, stored as organic matter within flooded, anoxic soils, or exported to the coastal ocean. Transformation of fixed carbon occurs through a variety of subsurface aerobic and anaerobic microbial processes, and results in a large inventory of dissolved carbon. Carbon source and the roles of aerobic respiration, sulfate reduction, and methane cycling were evaluated within salt marsh peat and the underlying sandy subterranean estuary. There is a large increase in dissolved inorganic carbon (DIC, 7,350 ± 3,900 μmol L −1 ), dissolved organic carbon (DOC, 1,040 ± 1,480 μmol L −1 ) and CH 4 (14.5 ± 33.3 μmol L −1 ) within the marsh porewaters compared to creek waters. Alkalinity production (5,730 ± 2,170 μeq L −1 ) and sulfate removal (1,810 ± 1,970 μmol L −1 ) indicate anaerobic respiration, however, relative contributions from the various decomposition pathways cannot be identified due to overlapping geochemical signatures. The δ 13 C of the DOC (−29.0 ± 3.7‰) and DIC (−11.2 ± 1.1‰) produced within the marsh differed from the bulk soil organic matter δ 13 C (−14.5 ± 0.2‰). We explore a variety of mechanisms that could result in co-occurring depleted δ 13 C-DOC and enriched δ 13 C-DIC compared to the bulk soil organic carbon pool and salt marsh vegetation, including selective mineralization, production of δ 13 C-depleted bacterial biomass, and methane-derived DOC. While important questions remain about carbon cycling pathways, we found evidence of a cryptic methane cycle. Alteration of the δ 13 C of carbon species complicates source attribution in solid and dissolved phases and careful consideration should be used when carbon is partitioned between in situ salt marsh production and external marine and terrestrial sources.

Massachusetts

Evaluation of models for estimating hydraulic conductivity in glacial aquifers from NMR logging

Nuclear magnetic resonance (NMR) logging is a promising method for estimating hydraulic conductivity ( K ). During the past ∼60 years, NMR logging has been used for petroleum applications, and different models have been developed for deriving estimates of permeability. These models involve calibration parameters whose values were determined through decades of research on sandstones and carbonates. We assessed the use of five models to derive estimates of K in glacial aquifers from NMR logging data acquired in two wells at each of two field sites in central Wisconsin, USA. Measurements of K , obtained with a direct push permeameter (DPP), K DPP , were used to obtain the calibration parameters in the Schlumberger-Doll Research, Seevers, Timur-Coates, Kozeny-Godefroy, and sum-of-echoes (SOE) models so as to predict K from the NMR data; and were also used to assess the ability of the models to predict K DPP . We obtained four well-scale calibration parameter values for each model using the NMR and DPP measurements in each well; and one study-scale parameter value for each model by using all data. The SOE model achieved an agreement with K DPP that matched or exceeded that of the other models. The Timur-Coates estimates of K were found to be substantially different from K DPP . Although the well-scale parameter values for the Schlumberger-Doll, Seevers, and SOE models were found to vary by less than a factor of 2, more research is needed to confirm their general applicability so that site-specific calibration is not required to obtain accurate estimates of K from NMR logging data.

Wisconsin