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USGS2001

Shallow ground-water quality in the Boston, Massachusetts metropolitan area

Analyses of water samples collected from 29 wells across the Boston metropolitan area indicate that shallow ground water in recently urbanized settings often contains trace amounts of nutrients, fuel, and industrial-based organic compounds. Most of the samples that contained detectable amounts of organic compounds also had elevated levels of iron and total dissolved solids. Nitrate was detected in 83 percent of the samples, but the U.S. Environmental Protection Agency's (USEPA) drinking-water standard of 10 milligrams per liter nitrate was exceeded in just one sample. Low levels of volatile organic compounds (VOCs) were detected in 76 percent of the samples, with as many as 13 different VOCs detected in a single sample. The concentration of methyl-tert-butyl ether (MTBE) in one sample was 267 micrograms per liter, which exceeds the Massachusetts Department of Environmental Protection drinking-water guideline of 70 micrograms per liter. Chloroform and MTBE were the two most frequently detected VOCs. MTBE was detected at the same frequency in ground water in the Boston metropolitan area as in other urban areas of New England. Chloroform is detected at higher frequency in old, densely populated areas in New England than in more recently developed, less densely populated areas. Pesticide detections were few, but only at trace concentrations, and none of the concentrations exceeded any drinking-water standard.

Water-Resources Investigations Report↗
USGS2001

Sedimentation survey of Lago Caonillas, Puerto Rico, February 2000

Lago Caonillas, a reservoir owned by the Puerto Rico Electric Power Authority and located in the central part of Puerto Rico, is one of the two reservoirs (the other being Lago Dos Bocas) proposed to supply water for the Puerto Rico Aqueduct and Sewer Authority project called the Superaqueduct. The reservoir was impounded in 1948 and originally provided about 55 .66 million cubic meters of water for hydroelectric power generation. Sediment derived from the reservoir basin has been transported and deposited in the reservoir bottom, substantially decreasing the water storage capacity over time. Successive bathymetric surveys indicated that in 1990 the storage capacity was 49.25 million cubic meters, decreasing to 48.80 million cubic meters in 1995 and to 42.27 million cubic meters in 2000. This represents an overall storage loss of about 11.5 percent by 1990, 12.3 percent by 1995 and 24.1 percent by 2000. The long-term sedimentation rate of the reservoir was about 153,000 cubic meters per year in 1990, remaining almost constant at about 146,000 cubic meters per year in 1995, but nearly doubling to 258,000 cubic meters per year in 2000. The two-fold increase in sedimentation rate, and consequently, the reservoir storage capacity loss, can be attributed to Hurricane Hortense in September 1996 and Hurricane Georges in September 1998. Twenty-four percent of the original storage capacity of Lago Caonillas has been lost to sediment accumulation. About 49 percent of the reservoir sediment was deposited in the last five years, demonstrating the impact of these major storms on the reservoir. Based on the ratio of storage capacity to inflow rate, the estimated trapping efficiency of Lago Caonillas is about 93 percent for 2000. The sediment yield of the Lago Caonillas net sediment-contributing drainage area (total drainage area minus the reservoir surface area) of 218.74 square kilometers, is about 1 ,266 megagrams per square kilometer per year. This represents an increase of about 69 percent in the material transport and deposition process of the Lago Caonillas basin between 1990 and 2000. The life expectancy of Lago Caonillas was more than 300 years in 1995; however, at the storm-accelerated sedimentation rate, the life expectancy has decreased to about 164 years. This implies that the reservoir could be filled with sediments by the year 2164 if major hurricanes continue to pass through Puerto Rico regularly (every 2 to 4 years).

Puerto Rico↗
USGS2001

Analysis of ambient conditions and simulation of hydrodynamics, constituent transport, and water-quality characteristics in Lake Maumelle, Arkansas, 1991-92

Lake Maumelle is the major drinking-water source for the Little Rock metropolitan area in central Arkansas. Urban and agricultural development has increased in the Lake Maumelle Basin and information is needed related to constituent transport and water quality response to changes in constituent loading or hydrologic regime. This report characterizes ambient conditions in Lake Maumelle and its major tributary, Maumelle River; describes the calibration and verification of a numerical model of hydrodynamics and water quality; and provides several simulations that describe constituent transport and water quality response to changes in constituent loading and hydrologic regime. Ambient hydrologic and water-quality conditions demonstrate the relatively undisturbed nature of Lake Maumelle and the Maumelle River. Nitrogen and phosphorus concentrations were low, one to two orders of magnitude lower than estimates of national background nutrient concentrations. Phosphorus and chlorophyll a concentrations in Lake Maumelle demonstrate its oligotrophic/mesotrophic condition. However, concentrations of chlorophyll a appeared to increase since 1990 within the upper and middle reaches of the reservoir. A two-dimensional, laterally averaged hydrodynamic and water-quality model developed and calibrated for Lake Maumelle simulates water level, currents, heat transport and temperature distribution, conservative material transport, and the transport and transformation of 11 chemical constituents. Simulations included the movement and dispersion of spills or releases in the reservoir during stratified and unstratified conditions, release of the fish nursery pond off the southern shore of Lake Maumelle, and algal responses to changes in external loading. The model was calibrated using 1991 data and verified using 1992 data. Simulated temperature and dissolved oxygen concentrations related well when compared to measured values. Simulated nutrient and algal biomass also related reasonably well when compared to measured values. A simulated spill of conservative material at the upper end of Lake Maumelle during a major storm event took less than 102 hours to disperse the entire length of the reservoir. Simulation of a nursery pond release into a tributary to Lake Maumelle demonstrated how the released water plunges within the receiving embayment and enters the main stem of the reservoir at mid depths. Simulations of algal response to increases of nitrogen and phosphorus loads demonstrate the phosphorus limiting condition in Lake Maumelle. Results from this study will provide water-resource management with information to better understand how changes in hydrology and water quality in the basin affects water quality in the reservoir. With this information, managers will be able to more effectively manage their drinking-water source supply.

Arkansas↗
USGS2002

Ecological effects on streams from forest fertilization: Literature review and conceptual framework for future study in the western Cascades

Fertilization of forests with urea-nitrogen has been studied numerous times for its effects on water quality. Stream nitrogen concentrations following fertilization are typically elevated during winter, including peaks in the tens-of-thousands of parts per billion range, with summer concentrations often returning to background or near-background levels. Despite these increases, water-quality criteria for nitrogen have rarely been exceeded. However, such criteria are targeted at fish toxicity or human health and are not relevant to concentrations that could cause ecological disturbances. Studies of the responses of stream biota to fertilization have been rare and have targeted either immediate, toxicity-based responses or used methods insensitive to ongoing ecological processes. This report reviews water-quality studies following forest fertilizations, emphasizing Cascade streams in the Pacific Northwest and documented biological responses in those streams. A conceptual model predicting potential ecological response to fertilization, which includes effects on algal growth and primary production, is presented. In this model, applied fertilizer nitrogen reaching streams is mostly exported during winter. However, some nitrogen retained in soils or stream and riparian areas may become available to aquatic biota during spring and summer. Biological responses may be minimal in small streams nearest to application because of light limitation, but may be elevated downstream where light is sufficient to allow algal growth. Ultimately, algal response could be greatest in downstream reaches, although ambient nutrient concentrations remain low due to uptake and benthic nutrient recycling. Ground-water flow paths and hyporheic processing could be critical in determining the fate of applied nitrogen. A framework is provided for testing this response in the Little River watershed, a tributary to the North Umpqua River, Oregon, at basic and intensive levels of investigation.

Oregon↗
USGS2001

Stream-water chemistry, nutrients, and pesticides in Town Brook, a headwater stream of the Cannonsville Reservoir Watershed, Delaware County, New York, 1999

Stream-water chemistry was monitored from January 1 through December 31, 1999, in the Town Brook watershed (TBW) in Delaware County, N.Y. to provide a basis for future evaluation of the effectiveness of Best Management Practices (BMPs) in decreasing agricultural nutrient and pesticide leaching to receiving waters. Total runoff from the watershed during 1999 was 664 millimeters (mm). Annual nutrient export (in kilograms per hectare) values were: ammonia (NH 3 ), 0.25; nitrate (NO 3 - ), 4.3; total nitrogen (TN), 10.6; orthophosphate (OP), 0.26; total dissolved phosphorus (TDP), 0.30; and total phosphorus (TP), 1.2 during 1999. Streamwater samples were collected during baseflow, elevated baseflow, and stormflow conditions. Stormflow, which produced the greatest flowweighted mean nutrient concentrations, represented only 41 percent of the annual runoff but accounted from 49 to 68 percent of the annual nutrient export. The highest seasonal flow-weighted mean concentrations were measured during the summer; the highest concentrations occurred during a large storm on July 4, 1999 with a recurrence interval greater than 100 years. The greatest seasonal export of dissolved nutrients (NH 3 , NO 3 - , OP, and TDP) occurred during the winter, whereas the greatest export of TN and TP was during the summer. Most of the TN and TP export during the summer occurred during the July 4 storm. That storm, together with a second large storm on September 16, 1999, accounted for the following percentages of annual export: ammonia, 17 percent; NO 3 - , 21 percent; TN, 45 percent; OP, 21 percent; TDP, 21 percent; and TP, 56 percent. Although these results provide information on the quantity and timing of nutrient export, they do not indicate the nutrient source nor the transport mechanisms by which nutrients are delivered to the stream. Baseflow and stormflow samples were collected for pesticide analyses at the Town Brook watershed outlet from January through July 1999. Eight pesticides and pesticide metabolites (degradation products) were detected in the samples. Four compounds (metolachlor, atrazine, metolachlor ESA, and metolachlor OA) were detected in concentrations greater than 1 micrograms per liter (μg/L) in one or more samples. Two of these compounds.the herbicide metabolites metalochlor ESA and metalochlor OA.were detected in concentrations higher than those of the parent compound metolachlor. Only one sample, collected during the July 4 storm, exceeded New York State surface-water-quality standards for any pesticide (simazine); its concentration of 0.53 μg/L was 0.03 μg/L higher than the New York State standard (0.50 μg/L). No concentrations exceeded Federal water-quality standards. Pesticide and metabolite concentrations were as much as 25 times greater during stormflow than during baseflow. Stormflow pesticide concentrations were indicative of a spring 'flushing', in which stream pesticide concentrations are elevated from concentrations typical during the rest of the year during the first few storms after pesticide application. Pesticides and pesticide metabolites were detected in all stormflow samples. These results illustrate the need to include baseflow and stormflow in pesticide sampling routines. The results of this study emphasize the need for (1) baseflow and stormflow sampling to capture the range of nutrient and pesticide concentrations from agricultural watersheds, and (2) research to define the mechanisms of nutrient and pesticide export in agriculutral watersheds.

New York↗
USGS2001

Soil analyses for 1,3-dichloropropene (1,3-DCP), sodium n-methyldithiocarbamate (metam-sodium), and their degradation products near Fort Hall Idaho, September 1999 through March 2000

Between September 1999 and March 2000, soil samples from the Fort Hall, Idaho, area were analyzed for two soil fumigants, 1,3-dichloropropene (1,3-DCP) and sodium n-methyldithiocarbamate (metam-sodium), and their degradation products. Ground water is the only source of drinking water at Fort Hall, and the purpose of the investigation was to determine potential risk of ground-water contamination from persistence and movement of these pesticides in cropland soils. 1,3-DCP, metam-sodium, or their degradation products were detected in 42 of 104 soil samples. The samples were collected from 1-, 2-, and 3-foot depths in multiple backhoe trenches during four sampling events—before pesticide application in September; after application in October; before soil freeze in December; and after soil thaw in March. In most cases, concentrations of the pesticide compounds were at or near their laboratory minimum reporting limits. U.S. Environmental Protection Agency Method 5035 was used as the guideline for soil sample preparation and analyses, and either sodium bisulfate (NaHSO4), an acidic preservative, or pesticide-free water was added to samples prior to analyses. Addition of NaHSO4 to the samples resulted in a greater number of compound detections, but pesticide-free water was added to most samples to avoid the strong reactions of soil carbonate minerals with the NaHSO4. As a result, nondetection of compounds in samples containing pesticide-free water did not necessarily indicate that the compounds were absent. Detections of these compounds were inconsistent among trenches with similar soil characteristics and histories of soil fumigant use. Compounds were detected at different depths and different trench locations during each sampling event. Overall results of this study showed that the original compounds or their degradation products can persist in soil 6 months or more after their application and are present to at least 3 feet below land surface in some areas. A few of the soil analyses results were unexpected. Degradation products of metam-sodium were detected in samples from croplands with a history of 1,3-DCP applications only, and were not detected in samples from croplands with a history of metam-sodium applications. Although 1,2-dibromoethane (EDB) has not been used in the area for many years, EDB was detected in a few soil samples. The presence of EDB in soil could be caused by irrigation of croplands with EDBcontaminated ground water. Analyses of these soil samples resulted in many unanswered questions, and further studies are needed. One potential study to determine vertical extent of pesticide compound migration in sediments, for example, would include analysis of one or more columns of soil and sediments (land surface to ground water, about 35 to 50 feet below land surface) in areas with known soil contamination. Another study would expand the scope of soil contamination to include broader types of cropland conditions and compound analyses.

Idaho↗
USGS2001

Indications and potential sources of change in sand transport in the Brazos River, Texas

Changes in the capacity of the Brazos River to transport sand can be identified within the context of Lane’s relation through changes in channel geometry, changes in the characteristics of suspended loads, and changes in discharge. The Brazos River channel has been undergoing continual adjustment since the 1940s. For a discharge of 5,000 cubic feet per second, the watersurface altitude has decreased 2 to 4 feet at the Hempstead and Richmond streamflow-gaging stations between 1940 and 1995. The characteristics of suspended-sediment samples at the Richmond streamflow-gaging station have changed between the periods 1969–81 and 1982– 95. The amount of sand-size sediment transported in suspension has decreased. The distribution of both daily and annual-peak discharges has changed. However, the computed annual loads of suspended sand indicate no statistically significant change in the median annual load. The transport of sand in the Brazos River depends on a complex set of factors, most of which are continually changing. Potential sources of change in sand transport in the Brazos River include the effects of reservoir construction, changes in land use, and instream sand and gravel mining. Extensive reservoir construction in the Brazos River Basin has reduced sand transport by trapping sediment and by reducing the magnitude of peak discharges. However, reductions in sand transport associated with reservoir construction apparently are compensated for by increases associated with tributary sediment inflow and localized bank erosion. The total area of harvested acres of non-hay crops in the lower Brazos River Basin during 1924–92 decreased more than 75 percent from about 32 percent to about 8 percent of the total area. Correspondingly, erosion potential has decreased substantially. Several sand and gravel mining sites are located on the Brazos River between Hempstead and Rosharon. The quantity of sediment extracted by instream sand and gravel mining operations could represent from 11 to 25 percent of the total sand transported by the Brazos River. The effects of mining on sand transport could not be quantified.

Texas↗
USGS2001

User's guide for polyethylene-based passive diffusion bag samplers to obtain volatile organic compound concentrations in wells. Part I, Deployment, recovery, data interpretation, and quality control and assurance

Diffusion samplers installed in observation wells were found to be capable of yielding representative water samples for chlorinated volatile organic compounds. The samplers consisted of polyethylene bags containing deionized water and relied on diffusion of chlorinated volatile organic compounds through the polyethylene membrane. The known ability of polyethylene to transmit other volatile compounds, such as benzene and toluene, indicates that the samplers can be used for a variety of volatile organic compounds. In wells at the study area, the volatile organic compound concentrations in water samples obtained using the samplers without prior purging were similar to concentrations in water samples obtained from the respective wells using traditional purging and sampling approaches. The low cost associated with this approach makes it a viable option for monitoring large observation-well networks for volatile organic compounds.

Water-Resources Investigations Report↗
USGS2001

User's guide for polyethylene-based passive diffusion bag samplers to obtain volatile organic compound concentrations in wells. Part 2, Field tests

Diffusion samplers installed in observation wells were found to be capable of yielding representative water samples for chlorinated volatile organic compounds. The samplers consisted of polyethylene bags containing deionized water and relied on diffusion of chlorinated volatile organic compounds through the polyethylene membrane. The known ability of polyethylene to transmit other volatile compounds, such as benzene and toluene, indicates that the samplers can be used for a variety of volatile organic compounds. In wells at the study area, the volatile organic compound concentrations in water samples obtained using the samplers without prior purging were similar to concentrations in water samples obtained from the respective wells using traditional purging and sampling approaches. The low cost associated with this approach makes it a viable option for monitoring large observation-well networks for volatile organic compounds.

Water-Resources Investigations Report↗
USGS2001

Ammonia in ground water from the Mississippi River alluvium, Fort Madison, Iowa

The U.S. Geological Survey, in cooperation with the City of Fort Madison, conducted a study of the potential sources and possible processes that might produce ammonia in ground water from the Mississippi River alluvium near Fort Madison, Iowa. High ammonia concentrations of 3.0 to 6.4 milligrams per liter were detected in water produced from municipal well Fort Madison #4 from 1992 through 1996. Total organic carbon concentrations of about 5 milligrams per liter were also reported during the same time period. Water-level measurements from two municipal wells and one well at Iowa State Penitentiary were used to determine that the general direction of ground-water flow during the two days of sampling was from northeast to southwest toward wells Fort Madison #4 and Fort Madison #5. Continuous pumping of other nearby wells probably influenced the direction of ground-water flow on these days. Because of a till confining unit separating the Mississippi River and the alluvial aquifer, it is uncertain to what extent induced recharge occurs to the alluvial aquifer from the river. Water samples were collected from three municipal wells, two industrial wells, one watersupply well at the Iowa State Penitentiary, one domestic well, two creeks, and the Mississippi River. Tritium analytical results indicate that the time of recharge was after 1953 for water from the municipal wells (where tritium samples were collected). The ammonia concentration, 5.1 milligrams per liter, was considerably higher in ground water collected from well Fort Madison #4 compared to samples collected from other wells. The dissolved organic carbon concentration was also highest in ground water collected from well Fort Madison #4 (5.5 milligrams per liter) although samples from other wells were also relatively high, 2.6 to 5.3 milligrams per liter. The most likely process producing the high ammonia concentration in ground water in the vicinity of well Fort Madison #4 is decomposition of organic matter (ammonification). Nitrogen isotope values, when compared to nitrogen isotope values found in ground water in the vicinity of some of the other wells, indicate the possibility that a higher percentage of the ammonia found in ground water in the vicinity of well Fort Madison #4 may be from human and(or) other animal wastes. Higher concentrations of dissolved phosphorus, orthophosphate, and a higher chloride-to-sodium mole ratio found in ground water sampled from well Fort Madison #4 could be indicative of a sewage or septic source. Potential sources include existing or abandoned septic systems, leaking sanitary sewer lines, commercial or residential waste-disposal sites, and agricultural runoff upgradient from well Fort Madison #4, or possibly, bed sediments of the Mississippi River.

Iowa↗
USGS2001

Hydrogeologic framework and potentiometric surface of the Williamson Creek Aquifer "B" sand in the Fort Polk area, Vernon Parish, Louisiana, March 1997

The Fort Polk Military Reservation(hereinafter referred to as the Reservation) in Vernon Parish, Louisiana, occupies 107,024 acres of lands; 66,998 acres are owned by the U.S. Army, and 40,026 acres are owned by the U.S. Forest Service (Dan Nance, Fort Polk Public Affairs office, written commun., 1998). Some areas of the Reservation, such as an artillery impact area, live-firm areas, and special purpose training areas, are restricted to military personnel. The Williamson Creek and Carnahan Bayou aquifers are major sources of freshwater for the Reservation. IN 1996, the Reservation's total water pumpage from the Williamson Creek aquifer for public supply was approxiamately 2.4 million gallons per day (Edward Ducote, Water and Wastewater Branch, Directorate of Public Works, Fort Polk, written commun., 1998). In 1997, the water withdrawl rate for public supply was approzimately 1.88 million gallons per day from 11 wells completed in the Williamson Creek aquifer. Almost all of the water was withdrawn from the "B" sand, which is the predominant sand layer of the Williamson Creek aquifer in the study area. In 1997, nearby Leesville, the seat of Vernon Parish, withdrew all its water for public supply from the deeper Carnahan Bayou aquifer.

Louisiana↗
USGS2001

Herbicide use in the management of roadside vegetation, western Oregon, 1999-2000; effects on the water quality of nearby streams

The Oregon Department of Transportation (ODOT) uses the herbicides Krovar (active ingredients diuron and bromacil), Oust (active ingredient sulfometuron-methyl) and Roundup (active ingredient glyphosate) to control roadside vegetation. The purpose of this study was to assess whether the use of these herbicides could contribute to the load of herbicides carried by Oregon streams. In spring of 1999, three test plots were constructed on a road shoulder near a crossing of Bull Creek, a small stream near Colton, Oregon, in the Willamette Valley. Simulated rainfall of 0.3 in/hr was applied to the experimental plots 1 day, 1 week, and 2 weeks after herbicide application. The simulated rainfall experiments yielded an upper limit concentration of 1 mg/L (milligram per liter, or parts per million) glyphosate and diuron, and of a few hundred micrograms per liter (µg/L, or parts per billion) of sulfometuron-methyl in runoff from the roadside when rainfall was applied 24 hr after spraying. Concentrations in the ditch itself would be less under natural conditions because of dilution by drainage water from the entire contributing drainage area. The road shoulder was resprayed at the end of September, and data were collected from late October 1999 through early January 2000, during natural rainfall. Diuron concentrations in the direct runoff from the road shoulder ranged from 1 to 10 µg/L throughout the 3-month sampling period; during the period, concentrations in the roadside ditch decreased from about 10 µg/L in October to about 0.1 µg/L in January, indicating progressive dilution of the roadside herbicide runoff during the fall/winter rainy season. No diuron was detected in Bull Creek downstream from the drainage ditch. A mass balance calculation confirmed that the load to Bull Creek from the drainage ditch was too low to result in detectable concentrations in the stream during October to January. Sulfometuron-methyl concentrations in runoff from the road shoulder ranged from 0.1 to 1 µg/L throughout the 3-month sampling period, and in the drainage ditch decreased from about 1 µg/L in October and November to about 0.2 µg/L in January. It was never detected in Bull Creek. Bromacil concentrations were similar to those of diuron. Glyphosate was never detected in fall samples from the road shoulder, the drainage ditch, or the stream.

Water-Resources Investigations Report↗
USGS2001

Pesticides in streams in the Tar-Pamlico drainage basin, North Carolina, 1992–94

From 1992 to 1994, 147 water samples were collected at 5 sites in the Tar-Pamlico drainage basin in North Carolina and analyzed for 46 herbicides, insecticides, and pesticide metabolites as part of the U.S. Geological Survey's National Water-Quality Assessment Program. Based on a common adjusted detection limit of 0.01 microgram per liter, the most frequently detected herbicides were metolachlor (84 percent), atrazine (78 percent), alachlor (72 percent), and prometon (57 percent). The insecticides detected most frequently were carbaryl (12 percent), carbofuran (7 percent), and diazinon (4 percent). Although the pesticides with the highest estimated uses generally were the compounds detected most frequently, there was not a strong correlation between estimated use and detection frequency. The development of statistical correlations between pesticide use and detection frequency was limited by the lack of information on pesticides commonly applied in urban and agricultural areas, such as prometon, chlorpyrifos, and diazinon, and the small number of basins included in this study. For example, prometon had the fourth highest detection frequency, but use information was not available. Nevertheless, the high detection frequency of prometon indicates that nonagricultural uses also contribute to pesticide levels in streams in the Tar-Pamlico drainage basin. Concentrations of the herbicides atrazine, alachlor, and trifluralin varied seasonally, with elevated concentrations generally occurring in the spring, during and immediately following application periods, and in the summer. Seasonal concentration patterns were less evident for prometon, diazinon, and chlorpyrifos. Alachlor is the only pesticide detected in concentrations that exceeded current (2000) drinking-water standards.

North Carolina↗
USGS2001

Habitat, biota, and sediment characteristics at selected stations in the lower Illinois River Basin, Illinois, 1996-98

Data collection for the lower Illinois River Basin (LIRB) National Water-Quality Assessment (NAWQA) program began in 1996. Data on habitat, fish, benthic macroinvertebrates, and sediment were collected at eight stations on six streams in the basin--Illinois River, Panther Creek, Mackinaw River, Indian Creek, Sangamon River, and La Moine River. These streams typically flow through agricultural lands with very low gradients. Substrates typically are clay to gravel with areas of cobble. Banks are high, steep, and sparsely vegetated. Topographic surveys provide illustrations of the geometry that promote understanding of channel geometry and a data set that, in the future, can be used by others to assess stream changes. Suspended-sediment particle size, woody debris, and stream velocity are important to fish and benthic macroinvertebrate communities. Fine particles (silts and clays) were abundant in suspended sediment and stream banks, and fish insectivorous cyprinid community composition increased with decreases in the concentration of these suspended fines. Suckers were prevalent in stream reaches with abundant woody-snag cover, whereas sunfish communities were most abundant in areas with slow water velocities. Hydropsychidae, Chironomidae, and Baetidae were the most abundant benthic macroinvertebrate families collected throughout the region, but stream size and water velocity were important to benthic macroinvertebrate community composition. Tricorythodes mayflies and Elmidae had higher relative abundance at sites in small- and moderate-size drainage basins, and Baetidae density was greatest in reaches with highest water velocity.

Water-Resources Investigations Report↗
USGS2001

Water quality of the Delaware and Raritan Canal, New Jersey, 1998-99

Since 1934, the Delaware and Raritan Canal has been used to transfer water from the Delaware River Basin to the Raritan River Basin. The water transported by the Delaware and Raritan Canal in New Jersey is used primarily for public supply after it has been treated at drinking-water treatment plants located in the Raritan River Basin. Recently (1999), the raw water taken from the canal during storms has required increased amounts of chemical treatments for removal of suspended solids, and the costs of removing the additional sludge or residuals generated during water treatment have increased. At present, action to control algae is unnecessary. The water quality of the Delaware and Raritan Canal was studied for approximately 16.5 months from mid-January 1998 through May 1999 to determine whether changes in water quality along the length of the canal are associated with storms. Nine water-quality constituents, and field measured specific conductance and turbidity were statistically tested. Instantaneous or grab samples of water were collected from the Delaware and Raritan Canal after five storms and during four nonstorm events. Median values of water-quality constituents in samples collected immediately after storms and during nonstorm conditions when statistically compared by sampling location were not significantly different. Therefore, the data were combined or aggregated to eliminate one of the two explanatory variables, either individual sampling sites or the two types of sampling events, in order to generate a sample population large enough to show statistically significant differences. After combining sampling events, only the median concentration of suspended organic carbon, and field measured specific conductance and turbidity, were significantly different among sampling sites. Median concentrations of total and filtered ammonia plus organic nitrogen, total phosphorous, turbidity, ultraviolet absorbance at 254 nanometers, and dissolved organic carbon in samples collected after storms were significantly greater than in samples collected during nonstorm conditions, when the sampling locations were aggregated in the statistical analysis. Methyl tert-butyl ether, the most frequently detected volatile organic compound (VOC), was detected in 55 of 80 samples. The highest concentration of methyl tert-butyl ether, 3.2 micrograms per liter, was measured in a sample collected during nonstorm conditions. The median of the continuously monitored specific conductance during nonstorm conditions at Port Mercer, N.J., increased by approximately 3 to 4 ?S/cm (microsiemens per centimeter) (1.5 to 2 percent of the median specific conductance) relative to that at the nearest upstream site, at Lower Ferry Road. The land use in the influent basins for this reach of the Delaware and Raritan Canal is primarily urban. One possible source of water with high specific conductance is either domestic or industrial wastewater that continuously discharges into pipes, then empties into the canal. Another possible source is ground water from an area within this reach where the elevation of the water table is higher than that of the water surface of the Delaware and Raritan Canal. The median continuously monitored specific conductance measured during nonstorm conditions at the Route 18 Spillway site increased relative to that of the nearest upstream site, Ten Mile Lock, by approximately 3 to 4 ?S/cm. The mean net change in continuously monitored specific conductance for this reach during storms also increased. Land use in the two largest influent basins within this reach, the Borough of South Bound Brook and Als Brook, is predominantly urban. The mean and median of continuously monitored turbidity varied along the length of the canal. In the reach between Raven Rock and Lower Ferry Road, the mean and median for continuously monitored turbidity during the study period increased by 7.2 and 6.2 NTU (nephelometric turbidity units), respectively. The mean of continuously monitored turbidity decreased downstream from Lower Ferry Road to Ten Mile Lock. Turbidity could increase locally downstream from influent streams or outfalls, but because the average velocity of water in the canal is low, particles that cause turbidity are not transported appreciable distances. In the reach between Ten Mile Lock and the Route 18 Spillway, the mean and median of the continuously monitored turbidity changed less than 0.5 NTU during the period of record. The small change in turbidity in this reach is not consistent with an average velocity for the reach; the average velocity in this reach was the lowest in all of the reaches studied. The expected decrease in turbidity due to settling of suspended solids is likely offset by turbid water entering the canal from influent streams or discharges from storm drains. Field observation of a sand bar immediately downstream from the confluence of Als Brook and the canal confirmed that the Als Brook drainage basin has contributed stormwatergenerated sediment to the canal that could reach the monitor located at the Route 18 Spillway and the raw water intakes for two drinking-water treatment plants.

New Jersey↗