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Agricultural pesticide applications and observed concentrations in surface waters from four drainage basins in the Central Columbia Plateau, Washington and Idaho, 1993-94

As part of the U.S. Geological Survey's National Water-Quality Assessment Program, the use and occurrence of agricultural pesticides were investigated in four drainage basins--two dominated by irrigated agriculture and two by dryland agriculture--in the Central Columbia Plateau of eastern Washington. For this study, 85 pesticides or pesticide metabolites were selected for analysis from a list of nearly 400 compounds commonly used in the United States. Pesticide-use data included estimates of the total quantity of herbicides, insecticides, and fungicides applied to croplands in each of the four drainage basins and reported times of application for selected pesticides. Pesticide-occurrence data included concentrations of pesticides in samples collected at one surface-water site at or near the outflow of each of the four drainage basins, where surface waters were sampled one to five times a month from March 1993 through May 1994. Of the 85 pesticides or pesticide metabolites targeted for analysis, a total of 45 different compounds were detected in samples from the four sites, ranging in concentration from at or near the limit of detection (as low as 0.001 microgram per liter) to a maximum of 8.1 micrograms per liter. None of the concentrations of pesticides exceeded the U.S. Environmental Protection Agency (USEPA) drinking water standards, but concentrations of five pesticides exceeded the USEPA freshwater-chronic criteria for the protection of aquatic life. Forty-one different pesticides or pesticide metabolites were detected in surface waters sampled at the two sites representing irrigated agriculture drainage basins. The herbicides atrazine, DCPA, and EPTC were detected most frequently at the two sampling sites. Not all pesticides that were applied were detected, however. For example, disulfoton, phorate, and methyl parathion accounted for 15 percent of the insecticides applied in the two irrigated drainage basins, yet none of these pesticides were detected in samples from the two irrigated-agricultural sites. Concentrations of pesticides found in surface waters at the two sites representing irrigated agriculture did not exceed drinking water standards, but some concentrations of the insecticides carbaryl, chlorpyrifos, diazinon, and azinphos-methyl exceeded the freshwater-chronic criteria for the protection of aquatic life. Twenty-three different pesticides or pesticide metabolites were detected in samples from the two sites representing dryland agricultural drainage basins. Herbicides were the type of pesticides most heavily applied in these drainage basins, and the herbicides atrazine, triallate, and simazine were detected most frequently in samples. Some herbicides, for example triallate in the Palouse River drainage basin, were both heavily applied and frequently detected. Others, like atrazine and simazine, were not typically applied to cropland, but were frequently detected in surface-water samples. Several insecticides (Lindane, ethoprop, carbaryl, and azinphos-methyl) were detected in samples from the two sites, although they were not reported as commonly applied to croplands in the dryland agricultural drainage basins. Concentrations of pesticides found in surface waters at the two sites did not exceed drinking water guidelines, but concentrations of the insecticides diazinon and azinphos-methyl and the herbicide triallate exceeded freshwater-chronic criteria for the protection of aquatic life.

Water-Resources Investigations Report↗

Evaluation of ground-water flow by particle tracking, Wright-Patterson Air Force Base, Ohio

The U.S. Geological Survey (USGS) and Wright-Patterson Air Force Base (WPAFB) began a Basewide Monitoring Program (BMP) in 1992. The purpose of the BMP was to establish a long-term ground-water and surface- water sampling network in order to (1) characterize current ground-water and surface-water quality; (2) describe water-quality changes as water enters, flows across, and exits Base boundaries; (3) conduct statistical analyses of water quality; and (4) estimate the effect of WPAFB on regional water quality. As part of the BMP, the USGS conducted ground-water particle-tracking analyses based on a ground-water-flow model produced during a previous USGS study. This report briefly describes the previous USGS study, the inherent assumptions of particle-tracking analyses, and information on the regional ground-water-flow field as inferred from particle pathlines. Pathlines for particles placed at the Base boundary and particles placed within identified Installation Restoration Program sites are described.

Ohio↗

Acoustic velocity meter systems

Acoustic velocity meter (AVM) systems operate on the principles that the point-to-point upstream traveltime of an acoustic pulse is longer than the downstream traveltime and that this difference in traveltime can be accurately measured by electronic devices. An AVM system is capable of recording water velocity (and discharge) under a wide range of conditions, but some constraints apply: 1. Accuracy is reduced and performance is degraded if the acoustic path is not a continuous straight line. The path can be bent by reflection if it is too close to a stream boundary or by refraction if it passes through density gradients resulting from variations in either water temperature or salinity. For paths of less than 100 m, a temperature gradient of 0.1' per meter causes signal bending less than 0.6 meter at midchannel, and satisfactory velocity results can be obtained. Reflection from stream boundaries can cause signal cancellation if boundaries are too close to signal path. 2. Signal strength is attenuated by particles or bubbles that absorb, spread, or scatter sound. The concentration of particles or bubbles that can be tolerated is a function of the path length and frequency of the acoustic signal. 3. Changes in streamline orientation can affect system accuracy if the variability is random. 4. Errors relating to signal resolution are much larger for a single threshold detection scheme than for multiple threshold schemes. This report provides methods for computing the effect of various conditions on the accuracy of a record obtained from an AVM. The equipment must be adapted to the site. Field reconnaissance and preinstallation analysis to detect possible problems are critical for proper installation and operation of an AVM system.

Techniques of Water-Resources Investigations↗

Guidelines and standard procedures for continuous water-quality monitors: Site selection, field operation, calibration, record computation, and reporting

The U.S. Geological Survey uses continuous water-quality monitors to assess variations in the quality of the Nation's surface water. A common system configuration for data collection is the four-parameter water-quality monitoring system, which collects temperature, specific conductance, dissolved oxygen, and pH data, although systems can be configured to measure other properties such as turbidity or chlorophyll. The sensors that are used to measure these water properties require careful field observation, cleaning, and calibration procedures, as well as thorough procedures for the computation and publication of final records. Data from sensors can be used in conjunction with collected samples and chemical analyses to estimate chemical loads. This report provides guidelines for site-selection considerations, sensor test methods, field procedures, error correction, data computation, and review and publication processes. These procedures have evolved over the past three decades, and the process continues to evolve with newer technologies.

Water-Resources Investigations Report↗

Water and Streambed Sediment Quality, and Ecotoxicology of a Stream along the Blue Ridge Parkway, Adjacent to a Closed Landfill, near Roanoke, Virginia: 1999

A study was done of the effects of a closed landfill on the quality of water and streambed sediment and the benthic macroinvertebrate community of an unnamed stream and its tributary that flow through Blue Ridge Parkway lands in west-central Virginia. The primary water source for the tributary is a 4-inch polyvinyl chloride (PVC) pipe that protrudes from the slope at the base of the embankment bordering the landfill. An unusual expanse of precipitate was observed in the stream near the PVC pipe. Stream discharge was measured and water and streambed sediment samples were collected at a nearby reference site and at three sites downstream of the landfill in April and September 1999. Water samples were analyzed for major ions, nitrate, total and dissolved metals, total dissolved solids, total organic carbon, and volatile and semivolatile organic compounds, including organochlorine pesticides and polychlorinated biphenyls (PCBs). Streambed sediment samples were analyzed for total metals, total organic carbon, percent moisture, and volatile and semivolatile organic compounds, including organochlorine pesticides and PCBs. The benthic macroinvertebrate community within the stream channel also was sampled at the four chemical sampling sites and at one additional site in April and September. Each of the five sites was assessed for physical habitat quality. Water collected periodically at the PVC pipe discharge between November 1998 and November 1999 was used to conduct 48-hour acute and 7-day chronic toxicity tests using selected laboratory test organisms. Two 10-day chronic toxicity tests of streambed sediments collected near the discharge pipe also were conducted. Analyses showed that organic and inorganic constituents in water from beneath the landfill were discharged into the sampled tributary. In April, 79 percent of inorganic constituents detected in water had their highest concentrations at the site closest to the landfill; at the same site, 59 percent of inorganic constituents detected in streambed sediments were at their lowest concentration. The low dissolved-oxygen concentration and relatively low pH in ground water from beneath the landfill probably had a direct effect on the solubility of metals and other constituents, resulting in the high concentration of inorganic constituents in water, low concentration in sediment, and the development of the precipitate. Most constituents in water in April were progressively lower in concentration from the landfill site downstream. The highest concentrations for 59 percent of constituents detected in sediment were at the farthest downstream site, suggesting that the inorganic constituents came out of solution as the stream water was exposed to the atmosphere. In September, 52 percent of inorganic constituents detected in water were at their highest concentrations at the site nearest the landfill. Of inorganic constituents detected in streambed sediments in September, 60 percent were at their highest concentrations near the landfill. A storm that occurred a few days prior to the September sampling probably affected the preceding steady-state conditions and the distribution of constituents in sediment along the stream. Concentrations of many inorganic constituents in water remained elevated at the farthest downstream site in comparison to the reference site in April and September, indicating that concentrations did not return to background concentrations. In April and September, most of the 17 organic compounds detected in water, including volatile organic and semivolatile organic compounds, were collected in samples near the landfill, and most concentrations were below their respective reporting limits. Probably because of their volatility, few organic compounds were detected at sites downstream of that site. A total of 17 discrete organic compounds were detected in sediment samples in either April or September, including trichloroethene and tetrachloroethene along with their degrad

Water-Resources Investigations Report↗

Flood-prone areas of Jacksonville, Duval County, Florida

Floods in the consolidated city of Jacksonville, Duval County, Florida, are caused directly by rainfall which, when combined with storm driven tides, causes rivers or other bodies of water to flood the low lying parts of the county. This map report supplies information on areas subject to floods of 100-year frequency; the information will permit evaluation of alternative uses of such areas. The extent of the 100-year flood is shown on the large-scale map accompanying the report. Also included is an index map showing sections of Duval County where more detailed information on the 100-year flood can be obtained. The major flood of record in the county occurred in 1964 when Hurricane Dora crossed the area. (Woodard-USGS)

Florida↗

Geographic relations of landslide distribution and assessment of landslide hazards in the Blanco, Cibuco, and Coamo basins, Puerto Rico

Landslide occurrence is common in mountainous areas of Puerto Rico where mean annual rainfall and the frequency of intense storms are high and hillslopes are steep. Each year, landslides cause extensive damage to property and occasionally result in loss of life. Landslide maps developed from 1:20,000 scale aerial photographs in combination with a computerized geographic information system were used to evaluate the landslide potential in the Blanco, Cibuco, and Coamo Basins of Puerto Rico. These basins, ranging in surface area from 276 to 350 square kilometers, are described in this report. The basins represent a broad range of the climatologic, geographic, and geologic conditions that occur in Puerto Rico. In addition, a variety of landslide types were documented. Rainfall-triggered debris flows, shallow soil slips, and slumps were most abundant. The most important temporal control on landslide occurrence in Puerto Rico is storm rainfall. Forty-one storms triggered widespread landsliding about 1 to 2 times per year during the last three decades. These storms were frequently of 1 to 2 days duration in which, on average, several hundred millimeters of rainfall triggered tens to hundreds of landslides in the central mountains. Most of these storms were tropical disturbances that occurred during the hurricane season of June through November. Land use and the topographic characteristics of hillslope angle, elevation, and aspect are the most important spatial controls governing landslide frequency. Hillslopes in the study area that have been anthropogenically modified, exceed 12 degrees in gradient and about 350 meters in elevation, and face the east-northeast are most prone to landsliding. Bedrock geology and soil order seem less important in the determination of landslide frequency, at least when considered at a generalized level. A rainfall accumulation-duration relation for the triggering of numerous landslides throughout the central mountains, and a set of simplified matrices representing geographic conditions in the three river basins were developed and are described in this report. These two elements provide a basis for the estimation of the temporal and spatial controls on landslide occurrence in Puerto Rico. Finally, this approach is an example of a relatively inexpensive technique for landslide hazard analysis that may be applicable to other settings.

Water-Resources Investigations Report↗

Estimation of flood-frequency characteristics of small urban streams in North Carolina

A statewide study was conducted to develop methods for estimating the magnitude and frequency of floods of small urban streams in North Carolina. This type of information is critical in the design of bridges, culverts and water-control structures, establishment of flood-insurance rates and flood-plain regulation, and for other uses by urban planners and engineers. Concurrent records of rainfall and runoff data collected in small urban basins were used to calibrate rainfall-runoff models. Historic rain- fall records were used with the calibrated models to synthesize a long- term record of annual peak discharges. The synthesized record of annual peak discharges were used in a statistical analysis to determine flood- frequency distributions. These frequency distributions were used with distributions from previous investigations to develop a database for 32 small urban basins in the Blue Ridge-Piedmont, Sand Hills, and Coastal Plain hydrologic areas. The study basins ranged in size from 0.04 to 41.0 square miles. Data describing the size and shape of the basin, level of urban development, and climate and rural flood charac- teristics also were included in the database. Estimation equations were developed by relating flood-frequency char- acteristics to basin characteristics in a generalized least-squares regression analysis. The most significant basin characteristics are drainage area, impervious area, and rural flood discharge. The model error and prediction errors for the estimating equations were less than those for the national flood-frequency equations previously reported. Resulting equations, which have prediction errors generally less than 40 percent, can be used to estimate flood-peak discharges for 2-, 5-, 10-, 25-, 50-, and 100-year recurrence intervals for small urban basins across the State assuming negligible, sustainable, in- channel detention or basin storage.

North Carolina↗

Preliminary hydrogeologic assessment and study plan for a regional ground-water resource investigation of the Blue Ridge and Piedmont provinces of North Carolina

Prolonged drought, allocation of surface-water flow, and increased demands on ground-water supplies resulting from population growth are focuses for the need to evaluate ground-water resources in the Blue Ridge and Piedmont Provinces of North Carolina. Urbanization and certain aspects of agricultural production also have caused increased concerns about protecting the quality of ground water in this region. More than 75 percent of the State's population resides in the Blue Ridge and Piedmont Provinces in an area that covers 30,544 square miles and 65 counties. Between 1940 and 2000, the population in the Piedmont and Blue Ridge Provinces increased from 2.66 to 6.11 million; most of this increase occurred in the Piedmont. Of the total population, an estimated 1.97 million people, or 32.3 percent (based on the 1990 census), relied on ground water for a variety of uses, including commercial, industrial, and most importantly, potable supplies. Ground water in the Blue Ridge and Piedmont traditionally has not been considered as a source for large supplies, primarily because of readily available and seemingly limitless surface-water supplies, and the perception that ground water in the Blue Ridge and Piedmont Provinces occurs in a complex, generally heterogeneous geologic environment. Some reluctance to use ground water for large supplies derives from the reputation of aquifers in these provinces for producing low yields to wells, and the few high-yield wells that are drilled seem to be scattered in areas distant from where they are needed. Because the aquifers in these provinces are shallow, they also are susceptible to contamination by activities on the land surface. In response to these issues, the North Carolina Legislature supported the creation of a Resource Evaluation Program to ensure the long-term availability, sustainability, and quality of ground water in the State. As part of the Resource Evaluation Program, the North Carolina Division of Water Quality, Groundwater Section, in cooperation with the U.S. Geological Survey, initiated a multiyear study of ground water in the Blue Ridge and Piedmont Provinces. The study began in 1999. Most of the study area is underlain by a complex, two-part, regolith-fractured crystalline rock aquifer system. Thickness of the regolith throughout the study area is highly variable and ranges from 0 to more than 150 feet. The regolith consists of an unconsolidated or semiconsolidated mixture of clay and fragmental material ranging in grain size from silt to boulders. Because porosities range from 35 to 55 percent, the regolith provides the bulk of the water storage within the Blue Ridge and Piedmont ground-water system. At the base of the regolith is the transition zone where saprolite grades into unweathered bedrock. The transition zone has been identified as a potential conduit for rapid ground-water flow. If this is the case, the transition zone also may serve as a conduit for rapid movement of contaminants to nearby wells or to streams with channels that cut into 1 U.S. Geological Survey, Raleigh, North Carolina. 2 North Carolina Department of Environment and Natural Resources, Division of Water Quality, Groundwater Section. or through the transition zone. How rapidly a contaminant moves through the system largely may be a function of the characteristics of the transition zone. The transition zone is one of several topics identified during the literature review and data synthesis, for which there is a deficiency in data and understanding of the processes involved in the movement of ground water to surface water. Because the Blue Ridge and Piedmont study area is so large, and the hydrogeology diverse, it is not feasible to study all of the area in detail. A more feasible approach is to select areas that are most representative of the land use, geology, and hydrology to obtain an understanding of the hydrologic processes in the selected areas, and transfer the knowledge from these local "type areas" to similar regional hydrogeologic areas. For the purpose of this study, the term "type area" applies to a 10- to 100-square mile area within a hydrogeologic terrane where information is sufficient to develop and test a concept of ground-water flow by using analytical or numerical methods that can be validated by field measurements. Ideally, these type areas are selected to be representative of the flow system that is present wherever a particular hydrogeologic terrane is present. This report consists of two basic parts. The first part describes the results of a comprehensive review and synthesis of information and literature that provides the basic background for the study. This includes current (2002) knowledge regarding general geology and the hydrogeologic framework of the fractured-rock aquifer system that underlies the Blue Ridge and Piedmont Provinces. In spite of the quantity of information identified during the literature review and the amount of past work that has been documented, there are still research needs to be met. The second part of the report describes State ground-water issues and problems, available data, and data deficiencies. It also describes the design and implementation of efforts to characterize ground-water quality and to quantify factors that influence the movement and availability of ground water in the hydrogeologic terranes characterized by (1) massive or foliated crystalline rocks overlain by thick regolith and (2) massive or foliated crystalline rocks overlain by thin regolith. As of September 2001, seven sites had been identified as potential study sites to be used to characterize the hydrogeology and water quality of ype areas considered representative of the larger terranes. Detailed geologic mapping, core drilling, well installation, and surface and borehole geophysical surveys are in progress at four of the sites.

North Carolina↗

Availability and quality of ground water in the Drain-Yoncalla area, Douglas County, Oregon

The purpose of this report is to present information that may enable water users, potential water users, and planners to estimate the likelihood of obtaining ground water in adequate quantity and of suitable quality at desired locations within the study area. The Drain-Yoncalla area is in Douglas County in southwestern Oregon, includes about 340 mi 2 (880 km 2 ), and lies within the Umpqua River drainage basin.

Oregon↗

The computer program estimate trend (ESTREND), a system for the detection of trends in water-quality data

Computerized statistical and graphical procedures were developed for use in U.S. Geological Survey (USGS) investigations of trend in stream water-quality data. These procedures, identified as EStimate TREND (ESTREND), are described in this paper to assist USGS investigators involved in multiple-station studies of water-quality trends. Additional discussion focuses on certain statistical and operational decisions required in multiple-station analysis of trends. The statistical methods used in ESTREND overcome common statistical problems encountered by conventional statistical trend techniques in the analysis of water-quality data. The problems include data that are non-normal and seasonally varying and water-quality records with missing values, 'less-than' (censored) values, and outliers, all of which adversely affect the performance of conventional statistical techniques. Parametric and nonparametric statistical trend tests are used in ESTREND. A nonparametric method, the Seasonal Kendall test, is used for data that have few less-than values or data that have been censored at only one reporting limit. A parametric test for trend involving a maximum likelihood estimation method is used for data that have been censored at multiple reporting limits. The Seasonal Kendall test for uncensored data allows for the removal of flow variability in water-quality data which improves the performance of the statistical trend tests. Menu-driven procedures in ESTREND allow the user to easily retrieve water-quality data, analyze data for trend, and view tabular and graphical results of analyses.

Water-Resources Investigations Report↗

Quality of Water from Shallow Wells in Urban Residential and Light Commercial Areas in Lafayette Parish, Louisiana, 2001 through 2002

In 2001-02, the U.S. Geological Survey installed and sampled 28 shallow wells in urban residential and light commercial areas in Lafayette Parish, Louisiana, for a land-use study in the Acadian-Pontchartrain Study Unit of the National Water-Quality Assessment (NAWQA) Program. The wells were installed in the Chicot aquifer system, the primary source of water for irrigation and public-water supplies in southwestern Louisiana. The purpose of this report is to describe the quality of water from the 28 shallow wells and to relate that water quality to natural factors and to human activities. Ground-water samples were analyzed for general ground-water properties and about 240 water-quality contituents, including dissolved solids, major inorganic ions, trace elements, nutrients, dissolved organic carbon (DOC), radon, chlorofluorocarbons, selected stable isotopes, pesticides, pesticide degradation products, and volatile organic compounds (VOC's).

Water-Resources Investigations Report↗

Occurrence of phosphorus, nitrate, and suspended solids in streams of the Cheney Reservoir Watershed, south-central Kansas, 1997–2000

Improving water quality of Cheney Reservoir in south-central Kansas is an important objective of State and local water managers. The reservoir serves as a water supply for about 350,00 people in the Wichita area and an important recreational resource for the area. In 1992, a task force was formed to study and prepare a plan to identify and mitigate potential sources of stream contamination in the Cheney Reservoir watershed. This task force was established to develop stream-water-quality goals to aid in the development and implementation of best-management practices in the watershed. In 1996, the U.S. Geological Survey entered into a cooperative study with the city of Wichita to assess the water quality in the Cheney Reservoir watershed. Water-quality constituents of particular concern in the Cheney Reservoir watershed are phosphorus, nitrate, and total suspended solids. Water-quality samples were collected at five streamflow-gaging sites upstream from the reservoir and at the outflow of the reservoir. The purpose of this report is to present the results of a 4-year (1997-2000) data-collection effort to quantify the occurrence of phosphorus, nitrate, and suspended solids during base-flow, runoff, and long-term streamflow conditions (all available data for 1997-2000) and to compare these results to stream-water-quality goals established by the Cheney Reservoir Task Force. Mean concentrations of each of the constituents examined during this study exceeded the Cheney Reservoir Task Force stream-water-quality goal for at least one of the streamflow conditions evaluated. Most notably, mean base-flow and mean long-term concentrations of total phosphorus and mean base-flow concentrations of dissolved nitrate exceeded the goals of 0.05, 0.10, and 0.25 milligram per liter, respectively, at all five sampling sites upstream from the reservoir. Additionally, the long-term stream-water-quality goal for dissolved nitrate was exceeded by the mean concentration at one upstream sampling site, and the base-flow total suspended solids goal (20 milligrams per liter) and long-term total suspended solids goal (100 milligrams per liter) were each exceeded by mean concentrations at three upstream sampling sites. Generally, it seems unlikely that water-quality goals for streams in the Cheney Reservoir watershed will be attainable for mean base-flow and mean long-term total phosphorus and total suspended solids concentrations and for mean base-flow dissolved nitrate concentrations as long as current (2001) watershed conditions and practices persist. However, future changes in these conditions and practices that mitigate the transport of these consitutents may modify this conclusion.

Kansas↗

Water, ice, and meteorological measurements at South Cascade Glacier, Washington, 1986-1991 balance years

Mass balance and climate variables are reported for South Cascade Glacier, Washington, for the years 1986-91. These variables include air temperature, precipitation, water runoff, snow accumulation, snow and ice melt terminus position, surface level, and ice speed. Data are reduced to daily and monthly values where appropriate. The glacier-averaged values of spring snow accumulation and fall net balance given in this report differ from previous results because amore complete analysis is made. Snow accumulation values for the1986-91 period ranged from 3.54 (water equivalent) meters in 1991 to2.04 meters in 1987. Net balance values ranged from 0.07 meters in1991 to -2.06 meters in 1987. The glacier became much smaller during the 1986-91 period and retreated a cumulative 50 meters.

Water-Resources Investigations Report↗

Klamath River Basin Hydrologic Conditions Prior to the September 2002 Die-Off of Salmon and Steelhead

More than 33,000 salmon and steelhead died in the lower Klamath River in late September 2002 on their way to spawning areas upstream. According to the California Department of Fish and Game, the cause of death was infection by protozoan and bacterial pathogens. Two factors that may have contributed to the disease incidence are low streamflow and high water temperature. September streamflows throughout the Klamath Basin were low, among the four lowest September flows recorded on the main stem since 1960. The low streamflows were caused by below-average snowpack and long-term drought, with resulting reduced ground-water discharge to streams. On the basis of historical climate data from the Klamath Basin and historical water temperature data from an adjacent basin, September 2002 water temperatures were above the long-term average. Temperatures in the Klamath River above the fish die-off reach exceeded 65 degrees Fahrenheit for nearly all of September; multiple days of exposure by fish to temperatures at or above that level can greatly increase disease incidence. This report characterizes streamflow and water temperature conditions during the period leading up to the die-off and compares them to historical conditions in the Klamath River. This report is not an exploration of the causative mechanism of the die-off; rather, it is intended to provide detailed documentation of these conditions to be used by those examining the cause(s) of the die-off and to provide information that can contribute to decisions about future water management in the Klamath Basin.

Water-Resources Investigations Report↗

Occurrence of selenium and mercury in surface water, Wind River Indian Reservation, Wyoming, 1995

Surface-water samples for chemical analyses were collected during May and August 1995 from 13 sites in an irrigated area of the Wind River Federal Irrigation Project, Wind River Indian Reservation, Wyoming. Sites included irrigation drains, ponds, and streams in an irrigated area partially underlain by seleniferous geologic materials described as having the potential to support vegetation that may be toxic to animals. Samples were analyzed for dissolved selenium, mercury, and other inorganic constituents. The study was done in cooperation with the Shoshone Tribe and the Northern Arapaho Tribe. Six samples analyzed from the May sampling period had dissolved selenium concentrations greater than the aquatic-life chronic criterion of 5 μg/L (micrograms per liter) established by the U.S. Environmental Protection Agency (USEPA). The largest dissolved selenium concentration (49 μg/L) exceeded the aquatic-life acute criterion of 20 μg/L established by the USEPA. Selenium concentrations in all 12 samples collected during the August sampling period were less than the laboratory minimum reporting level of 5 μg/L. The Goose Pond Drain site was dry in August. The dissolved solids concentrations were larger in samples collected in May than in August from all but two sites. The large dissolved selenium concentrations in the May samples, collected prior to the start of the irrigation season, were associated with large dissolved solids concentrations. Dissolved mercury concentrations were less than the minimum reporting level of 0.1 jig/L for 24 of the 25 samples collected during May and August. One sample collected in May had a concentration of 0.3 μg/L. This concentration was less than the aquatic-life acute criterion of 2.4 μg/L for mercury established by the USEPA.

Wyoming↗

Characterization of water resources in the Big Lost River Basin, south-central Idaho

Water resources in the Big Lost River Basin, Idaho are vital to irrigated agriculture, domestic, municipal and other uses but declining groundwater levels, diminished streamflows, and concern about drought motivated an evaluation of water resources in the basin. This multichapter volume documents the findings of a hydrogeologic investigation of the Big Lost River Basin that was jointly conducted by the U.S. Geological Survey, Idaho Department of Water Resources, and Idaho Geological Survey from 2018 through 2021. Chapter A (Zinsser, 2021) describes the hydrogeologic framework of the Big Lost River Basin. The framework presents a conceptual definition of four hydrogeologic units, a three-dimensional hydrogeologic framework model representing the spatial occurrence of the hydrogeologic units, and a description of groundwater occurrence and movement. Chapter B (Dudunake and Zinsser, 2021) describes streamflow gains from and losses to groundwater in the Big Lost River between Mackay Reservoir and south of Arco. Streamflow losses and gains were estimated from a series of four measurement events completed during spring and fall conditions from 2019 to 2021. Chapter C (Clark, 2022) describes budgets for the Big Lost River Basin from 2000 to 2019. The groundwater budgets provide annual estimates for aquifer inflows and outflows and include representations of average, wet, and dry conditions. Collectively, these reports present a characterization of water resources in the Big Lost River Basin that will help address current challenges in water-resources management.

Idaho↗

Water and bed-material quality of selected streams and reservoirs in the Research Triangle area of North Carolina, 1988-94

The Triangle Area Water Supply Monitoring Project was formed by a consortium of local governments and governmental agencies in cooperation with the U.S. Geological Survey to supplement existing data on conventional pollutants, nutrients, and metals to enable eventual determination of long-term trends; to examine spatial differences among water supplies within the region, especially differences between smaller upland sources, large multipurpose reservoirs, and run-of-river supplies; to provide tributary loading inlake data for predictive modeling of Falls of the Neuse and B. Everett Jordan reservoirs; and to establish a database for synthetic organic compounds. Water-quality sampling began in October 1988 at 35 sites located on area run-of-river and reservoir water supplies and their tributaries. Sampling has continued through 1994. Samples were analyzed for major ions, nutrients, trace metals, pesticides, and semivolatile and volatile organic compounds. Monthly concentration data, high-flow concentration data, and data on daily mean streamflow at most stream sites were used to calculate loadings of nitrogen, phosphorus, suspended sediment, and trace metals to reservoirs. Stream and lake sites were assigned to one of five site categories-- (1) rivers, (2) large multipurpose reservoirs, (3) small water-supply reservoirs, (4) streams below urban areas and wastewater-treatment plants, and (5) headwater streams--according to general site characteristics. Concentrations of nitrogen species, phosphorus species, and selected trace metals were compared by site category using nonparametric analysis of variance techniques and qualitatively (trace metals). Wastewater-treatment plant effluents and urban runoff had a significant impact on water quality compared to reservoirs and headwater streams. Streams draining these areas had more mineralized water than streams draining undeveloped areas. Moreover, median nitrogen and nitrite plus nitrate concentrations were significantly greater than all other site categories. Phosphorus was significantly greater than for reservoir sites or headwater streams. Few concentrations of trace metals were greater than the minimum reporting limit, and U.S. Environmental Protection Agency drinking-water standards were rarely exceeded. Detections, when they occurred, were most frequent for sites below urban areas and wastewater-treatment plant effluents. A small number of samples for analysis of acetanilide, triazine, carbamate, and chlorophenoxy acid pesticides indicate that some of these compounds are generally present in area waters in small concentrations. Organochlorine and organophosphorus pesticides are ubiquitous in the study area in very small concentrations. Trihalomethanes were detected at sites below urban areas and wastewater-treatment plants. Otherwise, volatile organic compounds and semivolatile compounds were generally not detected. Suspended-sediment, nitrogen, phosphorus, lead, and zinc loads into Falls Lake, Jordan Lake, University Lake, Cane Creek Reservoir, Little River Reservoir, and Lake Michie were calculated. In general, reservoirs act as traps for suspended sediment and constituents associated with suspended sediments. During 1989-94, annual suspended-sediment load to Falls Lake ranged from 29,500 to 88,200 tons. Because Lake Michie trapped from 83 to 93 percent of the suspended sediment delivered by Flat River, Flat River is a minor contributor of suspended sediment to Falls Lake. Yields of suspended sediment from Little River, Little Lick Creek, and Flat River Basins were between 184 and 223 tons per square mile and appear to have increased increased slightly from yields reported in a study for the period 1970-79. Annual suspended-sediment load to Jordan Lake ranged from 271,000 to 622,000 tons from 1989 through 1994 water years. The Haw River contributed more than 75 percent of the tota load to Jordan Lake. The suspended-sediment yields for Haw River and Northeast Cree

North Carolina↗