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At least 793 records · Page 44Linked to original sources
USGS2000

Reconnaissance of the hydrology, water quality, and sources of bacterial and nutrient contamination in the Ozark Plateaus aquifer system and Cave Springs Branch of Honey Creek, Delaware County, Oklahoma, March 1999-March 2000

A reconnaissance investigation of hydrology and water quality was conducted to evaluate possible sources of bacteria and nutrient contamination in the Cave Springs Branch basin and the underlying karstic Ozark Plateau aquifer system. Objectives were to: (1) determine the directions of ground-water flow in the basin and determine whether Cave Springs Branch interacts with ground water, (2) compare water quality in Cave Springs Branch with water quality in nearby wells to determine whether the stream is contaminating nearby wells, and (3) determine sources of fecal coliform bacteria and nitrate contamination in Cave Springs Branch and ground water. Potential sources of bacteria and nitrate in the area include cultivated agriculture, cow and horse on pasture, poultry production, households, and wildlife. Presence of fecal coliform and fecal streptococcal bacteria directly indicate fecal contamination and the potential for the presence of other pathogenic organisms in a water supply. Nitrate in drinking water poses health risks and may indicate the presence of additional contaminants. Fecal coliform bacteria colony counts were least in wells, intermediate in the poultry-processing plant wastewater outfall and Honey Creek above the confluence with Cave Springs Branch, and greatest in Cave Springs Branch. Bacteria strains and resistance to antibiotics by some bacteria indicate that livestock may have been sources of some bacteria in the water samples. Multiple antibiotic resistances were not present in the isolates from the water samples, indicating that the bacteria may not be from human or poultry sources. Ribotyping indicates that Escherichia coli bacteria in water samples from the basin were from bird, cow, horse, dog, deer, and human sources. The presence of multiple ribotypes from each type of animal source except bird indicates that most of the bacteria are from multiple populations of source animals. Identifiable sources of bacteria in Cave Springs Branch at the state line were dominantly cow and horse with one ribotype from bird. Escherichia coli was detected in only one well sample. Bacterial ribotypes in water from that upgradient well indicated human and dog feces as sources for bacteria, and that on site wastewater treatment may not always be adequate in these highly permeable soils. Greater concentrations of nitrate in Cave Springs Branch and O'Brien Spring relative to the poultry-processing plant wastewater outfall may be due, in part, to conversion of ammonia from poultry processing plant wastewater. The poultry-processing plant wastewater outfall sample collected in March 2000 contained greater concentrations of ammonia and total organic nitrogen plus ammonia than the spring, stream, and well samples collected during August 1999. Cave Springs Branch and Honey Creek contributed approximately equal loads of nitrogen to Honey Creek below the confluence and the greatest loads of nitrogen were introduced to Cave Springs Branch by the poultry processing plant wastewater outfall and O'Brien Spring. Nitrate concentrations in upgradient well samples ranged from 0.38 to 4.60 milligrams per liter, indicating that there are sources of ground-water nitrogen other than Cave Springs Branch, such as animal waste, fertilizer, or human waste. Nitrogen compounds in water from wells downgradient of Cave Springs Branch may be from Cave Springs Branch, fertilizers, animal waste, or human waste.

Oklahoma↗
USGS2008

Simulations of Ground-Water Flow, Transport, Age, and Particle Tracking near York, Nebraska, for a Study of Transport of Anthropogenic and Natural Contaminants (TANC) to Public-Supply Wells

Contamination of public-supply wells has resulted in public-health threats and negative economic effects for communities that must treat contaminated water or find alternative water supplies. To investigate factors controlling vulnerability of public-supply wells to anthropogenic and natural contaminants using consistent and systematic data collected in a variety of principal aquifer settings in the United States, a study of Transport of Anthropogenic and Natural Contaminants to public-supply wells was begun in 2001 as part of the U.S. Geological Survey National Water-Quality Assessment Program. The area simulated by the ground-water flow model described in this report was selected for a study of processes influencing contaminant distribution and transport along the direction of ground-water flow towards a public-supply well in southeastern York, Nebraska. Ground-water flow is simulated for a 60-year period from September 1, 1944, to August 31, 2004. Steady-state conditions are simulated prior to September 1, 1944, and represent conditions prior to use of ground water for irrigation. Irrigation, municipal, and industrial wells were simulated using the Multi-Node Well package of the modular three-dimensional ground-water flow model code, MODFLOW-2000, which allows simulation of flow and solutes through wells that are simulated in multiple nodes or layers. Ground-water flow, age, and transport of selected tracers were simulated using the Ground-Water Transport process of MODFLOW-2000. Simulated ground-water age was compared to interpreted ground-water age in six monitoring wells in the unconfined aquifer. The tracer chlorofluorocarbon-11 was simulated directly using Ground-Water Transport for comparison with concentrations measured in six monitoring wells and one public supply well screened in the upper confined aquifer. Three alternative model simulations indicate that simulation results are highly sensitive to the distribution of multilayer well bores where leakage can occur and that the calibrated model resulted in smaller differences than the alternative models between simulated and interpreted ages and measured tracer concentrations in most, but not all, wells. Results of the first alternative model indicate that the distribution of young water in the upper confined aquifer is substantially different when well-bore leakage at known abandoned wells and test holes is removed from the model. In the second alternative model, simulated age near the bottom of the unconfined aquifer was younger than interpreted ages and simulated chlorofluorocarbon-11 concentrations in the upper confined aquifer were zero in five out of six wells because the conventional Well Package fails to account for flow between model layers though well bores. The third alternative model produced differences between simulated and interpreted ground-water ages and measured chlorofluorocarbon-11 concentrations that were comparable to the calibrated model. However, simulated hydraulic heads deviated from measured hydraulic heads by a greater amount than for the calibrated model. Even so, because the third alternative model simulates steady-state flow, additional analysis was possible using steady-state particle tracking to assess the contributing recharge area to a public supply well selected for analysis of factors contributing to well vulnerability. Results from particle-tracking software (MODPATH) using the third alternative model indicates that the contributing recharge area of the study public-supply well is a composite of elongated, seemingly isolated areas associated with wells that are screened in multiple aquifers. The simulated age distribution of particles at the study public-supply well indicates that all water younger than 58 years travels through well bores of wells screened in multiple aquifers. The age distribution from the steady-state model using MODPATH estimates the youngest 7 percent of the water to have a flow-weighted mean age

Scientific Investigations Report↗
USGS1985

Chemical quality of ground water in Yolo and Solano counties, California

Ground-water-quality conditions were investigated in Yolo and Solano Counties during the summers of 1980 and 1981 by sampling 188 representative wells. Chemical analyses of the water samples show that the ground water is suitable for domestic and most agricultural purposes. Water samples from wells near the Sacramento River generally contained lower concentrations of dissolved solids and higher concentrations of trace elements than the rest of the study area. Ninety percent of the water sampled had a dissolved-solids concentration of less than 850 milligrams per liter. Chemical water types varied, with 72 percent of the wells sampled containing either sodium bicarbonate, magnesium bicarbonate, sodium-magnesium bicarbonate , or magnesium-sodium bicarbonate type water. A large part of the study area contains ground water with boron concentrations that exceed tolerance levels for many crops. Other toxic trace elements were present in negligible amounts. (USGS)

Water-Resources Investigations Report↗
USGS2023

Comprehensive water-quality trend analysis for selected sites and constituents in the International Souris River Basin, Saskatchewan and Manitoba, Canada, and North Dakota, United States, 1970–2020

The Souris River Basin is an international basin in southeast Saskatchewan, north-central North Dakota, and southwest Manitoba. Sustained exceedances of water-quality objectives for total phosphorus, sodium, sulfate, total dissolved solids, and total iron have been reported since the late 1990s at the two binational sites on the Souris River (Souris River near Sherwood, North Dakota [U.S. Geological Survey station 05114000] and Souris River near Westhope, N. Dak. [U.S. Geological Survey station 05124000]). To understand conditions at the binational sites, it is important to understand water-quality changes on a basin-wide scale. Because streamflow is highly variable in the basin and changes in streamflow affect water-quality conditions, it is particularly important to use a trend-analysis method that accounts for changes in streamflow. Trends in water-quality concentrations can be affected by human-induced changes on the landscape or natural changes in land-runoff interactions that are driven by climate patterns and reflected by changes in streamflow (commonly referred to as “hydroclimatic variability”). In the primarily agricultural Souris River Basin, human-induced changes that are likely to affect trends are widespread changes in agricultural management such as fertilizer application, tilling practices, and crop types, as well as dam emplacement and artificial drainage. Around 1970, there was a long-term natural (hydroclimatic) change in the basin in which a significant transition from a dry climate state to a wet climate state resulted in higher streamflow in the basin. To assist the International Souris River Board in assessing current water-quality conditions in the Souris River Basin and exceedances of water-quality objectives at the binational sites, the U.S. Geological Survey, in cooperation with the International Joint Commission, completed a comprehensive analysis for selected ions, nutrients, and trace metals for many sites in the basin that included descriptive water-quality statistics, trend analysis using a trend method that considers interannual hydroclimatic variability, and an assessment of exceedances of the water-quality objectives for the binational sites. Water-quality and streamflow or reservoir inflow or outflow data were compiled for 34 sites (30 stream sites and four reservoir sites) and 23 constituents with established water-quality objectives from 1970 to 2020 in the Souris River Basin and were used for descriptive statistics and water-quality trend analysis. Median total dissolved solids, sulfate, and sodium concentrations were low in the headwaters of the Souris River and some of the highest median concentrations were measured in the upper basin. At main-stem Souris River sites, all median sodium concentrations were greater than the binational water-quality objective. Median total phosphorus concentrations in the Souris River Basin were highest in the headwaters of the Souris River and all sites had median concentrations greater than the water-quality objective. Median total iron concentrations were highly variable across the basin, and for most main-stem sites, median concentrations were greater than or equal to the water-quality objective. During the recent period (2009–19), the annual flow-averaged concentrations of total dissolved solids and sulfate increased for nearly all stream sites with most sites having mildly significant or significant increases. One-half of the sites had an annual flow-averaged geometric mean concentration greater than the total dissolved solids water-quality objective, and four sites had sulfate increases greater than 100 milligrams per liter. Trends in annual flow-averaged concentrations of sodium and chloride generally were small and nonsignificant. Most sites had concentrations greater than the sodium water-quality objective, whereas all sites had concentrations much less than the chloride water-quality objective. Annual flow-averaged geometric mean concentration of total phosphorus decreased for nearly all sites across the Souris River Basin, but all sites had concentrations greater than the total phosphorus water-quality objective for the entire period. Small and nonsignificant changes in annual flow-averaged geometric mean concentration of total iron were detected at all sites but the binational site at Sherwood, N. Dak., and by 2019 all sites had concentrations greater than the total iron water-quality objective. For the reservoir sites, during 2000–15, mostly significant increases for total dissolved solids, sulfate, and sodium were detected, whereas changes in total phosphorus and total iron were mixed. During the historical period (1976–2019), large and consistent increases in total dissolved solids and sulfate have occurred since the late 1980s, with the largest increases and the most sites with mildly significant or significant increases generally occurring during the middle period (1988–2005). Large and significant or mildly significant increases in sodium concentrations occurred at eight of 10 sites in the middle period (1988–2005), and by the late period (2005–19) changes were small and nonsignificant. Similar to other basins in the region, such as the Red River of the North and Heart River, large and overall consistent increases since the late 1980s in total dissolved solids and sulfate in the Souris River Basin suggest that long-term natural (hydroclimatic) processes are large contributors to increases in the concentration of salts in streams and reservoirs associated with the onset of wetter conditions. The concurrent increases in sulfate and sodium concentrations at all sites during the middle period (1988–2005) suggest that sodium-sulfate evaporite dissolution may be a factor contributing to increases. Total phosphorus concentrations oscillated between increasing and decreasing during the historical period, with concentrations increasing during the first trend period (1976–88) and decreasing in the fourth trend period (2009–19) to the lowest flow-averaged geometric mean concentration by 2019 for most sites. During the historical period, changes in total iron concentrations were mostly nonsignificant and generally small, and variability in total iron concentrations likely affected the ability to detect statistically significant changes in concentration. The probability of exceeding the water-quality objective for total dissolved solids, sulfate, and sodium increased between 1976 and 2019 for the binational sites, especially for sulfate, which more than doubled for Souris River near Sherwood, N. Dak. and increased more than seven times for Souris River near Westhope, N. Dak. Total phosphorus and total iron concentrations for the binational sites were likely to exceed the water-quality objective for most of the year, but seasonal patterns of total phosphorus and total iron concentrations were different between the sites, suggesting that different factors may affect concentrations at different times of the year. For sodium, total phosphorus, and total iron, exceedance of the water-quality objective most of the time is not unexpected given that the flow-averaged geometric mean concentration for these three constituents for most sites across the basin are greater than the water-quality objective for most of the period. If natural processes are affecting total dissolved solids and sulfate concentrations, concentrations would be expected to vary with time, and as a result, extended periods of concentrations greater or less than the water-quality objective are likely to occur depending upon climatic conditions. A better understanding of the state of water quality across the Souris River Basin is beneficial to understanding and interpreting water-quality conditions at the two Souris River binational sites. The most consistent spatial and temporal change observed for this study was large and consistent increases in sulfate and total dissolved solids among tributary and main-stem sites since the late 1980s. For sulfate and total dissolved solids, wetter climatic conditions combined with naturally occurring and abundant sources of sulfate likely contributed to sustained exceedances of water-quality objectives in recent decades, and extended periods of concentrations greater than or less than the water-quality objective are likely to occur depending on climatic conditions. For sodium, total iron, and total phosphorus, sustained exceedances of the current water-quality objective likely will continue because most sites across the basin had flow-averaged geometric mean concentrations greater than the water-quality objective; and during the 43-year period of analysis, regardless of climatic conditions, exceedances were consistently greater than the water-quality objective. Further investigation into the factors causing increasing sulfate concentrations and a better understanding of reservoir dynamics would enhance the understanding of changes in water-quality conditions in the Souris River Basin. The basin-wide approach of this report provided an improved understanding of water-quality conditions in the Souris River Basin, and results can be used to inform the current water-quality objectives, inform potential changes to water management in the basin, and serve as a starting point for tracking future progress. Gaps in understanding of water-quality conditions can be closed through continued monitoring and further investigation into causes behind changes in water-quality conditions identified in this report.

Manitoba, North Dakota, Saskatchewan↗
USGS2009

Investigating hydraulic connections and the origin of water in a mine tunnel using stable isotopes and hydrographs

Turquoise Lake is a water-supply reservoir located north of the historic Sugarloaf Mining district near Leadville, Colorado, USA. Elevated water levels in the reservoir may increase flow of low-quality water from abandoned mine tunnels in the Sugarloaf District and degrade water quality downstream. The objective of this study was to understand the sources of water to Dinero mine drainage tunnel and evaluate whether or not there was a direct hydrologic connection between Dinero mine tunnel and Turquoise Lake from late 2002 to early 2008. This study utilized hydrograph data from nearby draining mine tunnels and the lake, and stable isotope (δ 18 O and δ 2 H) data from the lake, nearby draining mine tunnels, imported water, and springs to characterize water sources in the study area. Hydrograph results indicate that flow from the Dinero mine tunnel decreased 26% (2006) and 10% (2007) when lake elevation (above mean sea level) decreased below approximately 3004 m (approximately 9855 feet). Results of isotope analysis delineated two meteoric water lines in the study area. One line characterizes surface water and water imported to the study area from the western side of the Continental Divide. The other line characterizes groundwater including draining mine tunnels, springs, and seeps. Isotope mixing calculations indicate that water from Turquoise Lake or seasonal groundwater recharge from snowmelt represents approximately 10% or less of the water in Dinero mine tunnel. However, most of the water in Dinero mine tunnel is from deep groundwater having minimal isotopic variation. The asymmetric shape of the Dinero mine tunnel hydrograph may indicate that a limited mine pool exists behind a collapse in the tunnel and attenutates seasonal recharge. Alternatively, a conceptual model is presented (and supported with MODFLOW simulations) that is consistent with current and previous data collected in the study area, and illustrates how fluctuating lake levels change the local water-table elevation which can affect discharge from the Dinero mine tunnel without physical transfer of water between the two locations.

Colorado↗
USGS2014

Investigations of the fluctuations of the ground‐water table in Pennsylvania

Hydraulic engineers are interested in ground ‐ water as a source of water supply and also as it affects stream‐flow. The stream‐flow is especially valuable at low stages and it is at the low stages that it is most closely related to the ground ‐ water conditions. For several years the Pennsylvania Topographic and Geologic Survey and the United States Geological Survey have cooperated in making a comprehensive study of the ground ‐ water resources of Pennsylvania , but no adequate records of ground ‐ water levels have in the past been obtained. Recently, however, a project for obtaining systematic records in Pennsylvania has been started. ©1932. American Geophysical Union.

Pennsylvania↗
USGS2014

Ground‐water inventory in the Upper Gila River Valley, New Mexico and Arizona: Scope of investigation and methods used

The Division of Ground Water of the Geological Survey, United States Department of the Interior, has been making an inventory of the water‐resources of the upper Gila River since January 1, 1940. Funds for the project are furnished under a cooperative agreement with the Arizona State Water Commissioner, supplemented by a substantial grant from the United States Engineer Office of the War Department. The State of Arizona wants information regarding the quantity of ground‐water available to supplement surface‐water irrigation. The Army Engineers would like to know the effect that flood‐control structures which may be built on the upper Gila will have on existing relations between river‐flow and ground‐water storage.

Eos, Transactions, American Geophysical Union↗
USGS2012

Hydrologic data for an investigation of the Smith River Watershed through water year 2010

Hydrologic data collected through water year 2010 and compiled as part of a U.S. Geological Survey study of the water resources of the Smith River watershed in west-central Montana are presented in this report. Tabulated data presented in this report were collected at 173 wells and 65 surface-water sites. Figures include location maps of data-collection sites and hydrographs of streamflow. Digital data files used to construct the figures, hydrographs, and data tables are included in the report. Data collected by the USGS are also stored in the USGS National Water Information System database and are available through the USGS National Water Information System Water Data for Montana Web page at http://waterdata.usgs.gov/mt/nwis/ .

Montana↗
USGS2015

Geophysical investigation of the pressure field produced by water guns at a pond site in La Crosse, Wisconsin

Three different geophysical sensor types were used to characterize the underwater pressure waves generated by the underwater firing of a seismic water gun and their suitability for establishing a pressure barrier to potentially direct or prevent the movement of the Asian carps. The sensors used to collect the seismic information were blast rated hydrophones and underwater blast sensors. Specific location information for the water guns and the sensors was obtained using either laser rangefinders or differentially corrected global positioning systems (GPS). Two separate studies are discussed in this report. The two studies were completed during September 2012 and July 2013. Both of these studies took place in an earthen testing pond on the campus of Upper Midwest Environmental Sciences Center (UMESC) in La Crosse, Wisconsin. Previous studies had identified 5 pounds per square inch (lb/in 2 ) as a target value for the successful operation of a water gun barrier. The September 2012 study evaluated the performance of 1-cubic-inch (in 3) and 80-in 3 water guns. Data from the 1-in 3 gun showed that it produces a very planar wave with limited effect on the depths above and below its gun ports. The 1-in 3 gun did not produce the 5-lb/in 2 target pressure at a sufficient distance to be considered effective. The 80-in 3 gun produced a bowl-shaped pressure field with the 5-lb/in 2 target radius at the surface extending to 45 feet. The July 2013 study consisted of three scenarios: fish behavior, single gun assessment, and experimental barrier evaluation. The fish behavior scenario simulated the pond conditions from previous studies. Two 80-in 3 water guns were fired in the south end of the testing pond. Pressures essentially doubled from the testing of the single 80-in 3 water gun. The single gun assessment scenario sought to replicate the setup of the 80-in 3 scenario in September 2012, but with additional sensors to better define the pressure field. The 5-lb/in 2 target pressure field continued to show a radius ranging from 40 to 45 feet, dependent on the pressure of the input air. The final scenario, the experimental barrier evaluation, showed that a two-dimensional continuous plane of 5 lb/in 2 can be created between two 80-in 3 water guns to a separation of 99 feet and a depth of 6.5 feet with 1,500 lb/in 2 of input air.

Wisconsin↗
USGS1994

Multipurpose Wetlands Phase II/III: final design and ongoing research investigations

The Eastern Municipal Water District (EMWD), the Bureau of Reclamation (USBR), and the National Biological Survey (NBS), in consultation with other governmental agencies, the academic community, and environmental groups, are involved in a cooperative wetlands research and demonstration effort. This report reflects progress through the first 3 years of a 5-year program. The goal of the Multipurpose Wetlands Research and Demonstration Project is to evaluate and expand the use of reclaimed water and contaminated ground water through the incorporation of multipurpose constructed wetlands into EMWD's total water resources management program. The focus of the wetlands is the development of design, construction, and operation criteria that will provide a cost-effective and innovative alternative for managing water resources and provide other public benefits in arid areas. The program also recognizes the fact that naturally-occurring wetlands, both coastal and inland, have been disappearing at an alarming rate.

Report↗
USGS1978

Summary of U.S. Geological Survey investigations and hydrologic conditions in the Southwest Florida Water Management District for 1977

This report summarizes the activities of the Southwest Florida Subdistrict of the U.S. Geological Survey, Water Resources Division for fiscal year 1977. The organization and mission of the subdistrict office are described. The cooperative program for fiscal year 1977 included 41 interpretive investigations. Abstracts of twenty reports released by the subdistrict during 1977 and an extensive bibliography of reports released from 1933 to 1977 are included. The hydrologic setting of southwest Florida is outlined followed by discussions of surface-water, ground-water, and quality-of-water conditions. Hydrologic conditions in southwest Florida in 1977 are shown by the presentation of hydrographs from selected surface-water, ground-water, and lake-stage data collection sites.

Florida↗
USGS2001

Evaluation of ground-water/surface-water relations, Chapman Creek,West-Central Ohio, by means of multiple methods

Chapman Creek, a tributary to the Mad River, passes within about 500 feet of a landfill near Tremont City, in Clark County, west-central Ohio. In autumn 2000, the ground-water/surface-water relation was investigated by use of piezometers, seepage meters, temperature monitors, and a gain-loss study. Four piezometers were installed in the streambed along about a 1-mile reach, inclusive of the landfill. Four seepage-meter tests were done at locations near two of the piezometers. Four temperature-monitoring stations were established along a reach of about 700 feet near the landfill. A fifth temperature station was located near a piezometer about 3,000 feet downstream from the landfill. A streamflow gain-loss study was done over a 3-mile reach that included the reaches studied with the other methods. The data from the piezometers, seepage meters, and temperature monitors indicated an apparent change from losing to gaining and back again several times over fairly short distances. The gain-loss data indicated that the creek was consistently a gaining stream over the 3-mile reach. Investigation of streambed conditions and local geology revealed that the streambed consists of sand and gravel overlying a finegrained till layer. The stream water readily moves in and out of the coarse streambed such that the piezometers, seepage meters, and temperature monitors measured the local flow in the streambed; therefore, these data did not reflect the true relation between the creek and ground water. On the other hand, the gain-loss study, less affected by the movement of water in the streambed, showed that Chapman Creek probably is a gaining stream throughout the 3-mile reach.

Ohio↗
USGS2012

Hydrogeology, water chemistry, and transport processes in the zone of contribution of a public-supply well in Albuquerque, New Mexico, 2007-9

The National Water-Quality Assessment Program (NAWQA) of the U.S. Geological Survey began a series of groundwater studies in 2001 in representative aquifers across the Nation in order to increase understanding of the factors that affect transport of anthropogenic and natural contaminants (TANC) to public-supply wells. One of 10 regional-scale TANC studies was conducted in the Middle Rio Grande Basin (MRGB) in New Mexico, where a more detailed local-scale study subsequently investigated the hydrogeology, water chemistry, and factors affecting the transport of contaminants in the zone of contribution of one 363-meter (m) deep public-supply well in Albuquerque. During 2007 through 2009, samples were collected for the local-scale study from 22 monitoring wells and 3 public-supply (supply) wells for analysis of major and trace elements, arsenic speciation, nutrients, dissolved organic carbon, volatile organic compounds (VOCs), dissolved gases, stable isotopes, and tracers of young and old water. To study groundwater chemistry and ages at various depths within the aquifer, the monitoring wells were divided into three categories: (1) each shallow well was screened across the water table or had a screen midpoint within 18.3 m of the water level in the well; (2) each intermediate well had a screen midpoint between about 27.1 and 79.6 m below the water level in the well; and (3) each deep well had a screen midpoint about 185 m or more below the water level in the well. The 24-square-kilometer study area surrounding the "studied supply well" (SSW), one of the three supply wells, consists of primarily urban land within the MRGB, a deep alluvial basin with an aquifer composed of unconsolidated to moderately consolidated deposits of sand, gravel, silt, and clay. Conditions generally are unconfined, but are semiconfined at depth. Groundwater withdrawals for public supply have substantially changed the primary direction of flow from northeast to southwest under predevelopment conditions, to west to east under modern conditions. Analysis of age tracers indicates that groundwater from most sampled wells is dominated by old (pre-1950) water, ranging in mean age from about 4,000 years to more than 22,000 years, but includes a fraction of young (post-1950) recharge. Patterns in chemical and isotopic data are consistent with the conclusions that shallow groundwater in the area typically includes a fraction that evaporated prior to recharge and (or) flushed accumulated solutes out of the unsaturated zone during recharge, and that shallow groundwater has mixed to deeper parts of the aquifer, which receives recharge mainly by seepage from the Rio Grande. Among shallow and intermediate wells that produced water with a fraction of young recharge, that fraction ranged between 1.5 and 46 percent. Samples from the two deep wells had groundwater ages exceeding 18,000 years, with no fraction of young recharge. Two supply wells (including the SSW) had a fraction of young recharge, which ranged between about 3 and 11 percent, despite mean groundwater ages exceeding 10,000 years. The fraction of young recharge to the SSW varied seasonally, probably because seasonal pumping patterns affected local hydraulic gradients and (or) because of flow through the well bore when the SSW is not pumping. Well-bore flow data collected during winter (low-pumping season) indicated that about 61 percent of the water pumped from the SSW entered the well from the intermediate part of the aquifer, and that the remaining 39 percent entered from the deep part of the aquifer. Volatile organic compounds (VOCs) were detected in samples from most shallow and intermediate monitoring wells and from two of three supply wells, including the SSW. Detected VOCs were primarily chlorinated solvents or their degradation products. Many of the wells in which most of these VOCs were detected are located near known sites of solvent contamination that were targeted for sampling because trichloroethylene (TCE) and cis-1,2-dichloroethylene had been detected in the SSW, and several of these wells may have become contaminated at least partly because of enhanced vertical migration associated with the pumping of and (or) direct migration down deep well bores. Except for TCE in the sample from a shallow monitoring well, all detections of VOCs were at concentrations below Maximum Contaminant Levels (MCLs) set by the U.S. Environmental Protection Agency. Concentrations of all VOCs detected in the supply wells were less than one-tenth of the corresponding MCLs. However, the presence of VOCs in all but deep groundwater, including the detection of chloroform (a chlorination byproduct) in several shallow wells, indicates that groundwater in the study area commonly is affected by human activities, even to substantial depths. The only natural contaminant detected at concentrations near or above its MCL was arsenic, which has been detected at elevated concentrations across broad areas of the MRGB. Concentrations of arsenic, present primarily as arsenate, exceeded the MCL of 10 micrograms per liter (μg/L) in water from the two deep wells (one of which had the highest concentration, 35 μg/L), from one intermediate well, and from two supply wells, including the SSW. Water-quality and solid-phase data from this study are consistent with elevated arsenic concentrations in groundwater being related to pH-dependent desorption of arsenic from ferric oxyhydroxides in sediments in deep parts of the aquifer. Concentrations of nitrate ranged between 1.3 and 5.4 milligrams per liter (mg/L) in water from shallow wells screened across the water table, but were less than 0.9 mg/L in water from all but one deeper well. Nitrogen isotopes and chloride/bromide ratios for shallow wells were consistent with natural soil nitrogen. Nitrate concentrations and nitrogen isotopes indicated that denitrification is occurring at intermediate aquifer depths, and that the progress of the denitrification reaction typically is greatest for wells that include a fraction of groundwater associated with particular recharge sources or with known sites of contamination contributing organic compounds that can provide a carbon source for microbial respiration. Overall, hydrologic and chemical data from the study area indicate that young recharge is reaching the aquifer across broad areas and is migrating from shallow to intermediate depths of the aquifer as a result of mixing that is associated with human development of groundwater. Consequently, groundwater that human activities in the urban study area have affected is present at depths that are within the screened intervals of public-supply wells, resulting in detections of VOCs and implying greater vulnerability to anthropogenic contamination than might be assumed based on the dominantly old age of the regional groundwater. However, the fractions of old groundwater that public-supply wells produce substantially dilute the anthropogenic contaminants, while contributing natural contaminants (primarily arsenic) to the wells. Based on data from the SSW, vulnerability of public-supply wells to natural and anthropogenic contaminants in the area changes through time, including with seasonal changes in pumping stresses that alter the fractions of young and old water being contributed to wells.

New Mexico↗
USGS2015

Surface-water quality in agricultural watersheds of the North Carolina Coastal Plain associated with concentrated animal feeding operations

The effects of concentrated animal feeding operations (CAFOs) on water quality were investigated at 54 agricultural stream sites throughout the North Carolina Coastal Plain during 2012 and 2013. Three general watershed land-use types were examined during the study, including 18 background watersheds with no active CAFOs (BK sites), 18 watersheds with one or more active swine CAFOs but no poultry CAFOs (SW sites), and 18 watersheds with at least one active swine CAFO and one active dry-litter poultry CAFO (SP sites). The watershed drainage areas for these 54 stream sites ranged from 1.2 to 17.5 square miles. Conventional fertilizers used for crop production are the primary source of nutrients at the BK sites. Animal-waste manures represent an additional source of nutrients at the SW and SP study sites. Land cover, soil drainage, and CAFO attributes were compiled for each watershed. Water-quality field measurements were made and samples were collected at the 54 primary sites during 6 bimonthly sampling periods from June 2012 to April 2013. An additional 23 secondary sites were sampled once during April 2013 to provide supplemental data at stream locations directly adjacent or in close proximity to swine CAFOs and (or) background agricultural areas within 9 of the primary watersheds. The watershed drainage areas for the 23 secondary sites ranged from 0.2 to 8.9 square miles. Water temperature, specific conductance, dissolved-oxygen concentration, and pH were measured directly in the streams. Water samples were analyzed for major ions, nutrients, and stable isotopes, including delta hydrogen-2 (δ 2 H) and delta oxygen-18 (δ 18 O) of water and delta nitrogen-15 (δ 15 N) and δ 18 O of dissolved nitrate plus nitrite. Most of the water-quality properties and constituents varied significantly among the six sampling periods, changing both seasonally and in response to hydrologic conditions. The differences noted among the sampling periods indicate that the interactions between seasonal climatic differences, streamflow conditions, and instream biotic and abiotic processes are complex and their integrated effects can have varying degrees of influence on individual nutrients. Water-quality differences were noted for the SW and SP land-use groups relative to the BK group. Median values of specific conductance, several major ions (magnesium, sodium, potassium, and chloride), and nitrogen fractions (ammonia plus organic nitrogen, ammonia, nitrate plus nitrite, total nitrogen, and δ 15 N of nitrate plus nitrite) were higher for the SW and SP groups compared to the BK group. No significant differences in water temperature, dissolved oxygen, calcium, total organic nitrogen, orthophosphate, total phosphorus, or δ 18 O of nitrate plus nitrite were noted among the land-use groups. When compared on the basis of land-use type, there was an overall measurable effect of CAFO waste manures on stream water quality for the SW and SP watershed groups. Some individual sites within the SW and SP groups showed no measurable CAFO effects on water quality despite having CAFOs present upstream. An evaluation of sodium plus potassium concentrations coupled with δ 15 N values of nitrate plus nitrite proved valuable for distinguishing which SW and SP sites had a water-quality signature indicative of CAFO waste manures. Sites with CAFO manure effects were characterized by higher sodium plus potassium concentrations (commonly between 11 and 33 milligrams per liter) and δ 15 N values of nitrate plus nitrite (commonly between 11 and 26 parts per thousand) relative to sites reflecting background agricultural conditions, which commonly had sodium plus potassium concentrations between 6 and 14 milligrams per liter and δ 15 N values of nitrate plus nitrite between 6 and 15 parts per thousand. On the basis of the results of this study, land applications of waste manure at swine CAFOs influenced ion and nutrient chemistry in many of the North Carolina Coastal Plain streams that were studied. A classification tree model was developed to examine relations of watershed environmental attributes among the study sites with and without CAFO manure effects. Model results indicated that variations in swine barn density, percentage of wetlands, and total acres available for applying swine-waste manures had an important influence on those watersheds where CAFO effects on water quality were either evident or mitigated. Measurable effects of CAFO waste manures on stream water quality were most evident in those SW and SP watersheds having lower percentages of wetlands combined with higher swine barn densities and (or) higher total acres available for applying waste manure at the swine CAFOs. Stream water quality was similar to background agricultural conditions in SW and SP watersheds with lower swine barn densities coupled with higher percentages of wetlands or lower acres available for swine manure applications. The model provides a useful tool for exploring and identifying similar, unmonitored watersheds in the North Carolina Coastal Plain with potential CAFO manure influences on water quality that might warrant further examination.

North Carolina↗
USGS1986

Estimating ground-water influx to a portion of the Rio Grande de Manati River basin in Puerto Rico through the measurement of 222Rn

Water has become a critical commodity in the Caribbean Region. In spite of a relative abundance of rainfall even on the smaller islands , the region is faced with severe seasonal shortages as well as increasing water quality problems. The supply of the water needs in the area will become even more critical as economic development accelerates and the population continues to increase. The development of the necessary infrastructure to supply the water needs of the next 30 years will require large capital investments. Perhaps even more important, it will require training of scientists and technicians in the investigation and management of the limited water resources . The lack of trained personnel could be the most important factor in the solution of the water resources problems in the region. The principal objectives of this ' Third Caribbean Islands Water Resources Congress ', were to provide a focus for the transfer of technology on hydrology and water resources investigations in the region. The severe quality problems that affect water supplies in the U.S. Virgin Islands are the subject of two papers. The importance of a reliable data base on water use in small islands is considered in a paper on water use in St. Croix. Advanced techniques are discussed on how to measure groundwater contributions to runoff, use of geochemical techniques for interpretation of water quality characteristics, use of dye tracers in karst areas, simulation of small island 's aquifers, and use of borehole geophysical tools to estimate moisture. The contamination of groundwater resources is discussed in several papers focusing on monitoring, sludge management, and environmental assessment. (See W89-04666 thru W89-04682) (Lantz-PTT)

Conference Paper↗
USGS1976

Water-quality study of a reach of the Merced River in Yosemite National Park and vicinity, California, April 1973 through September 1974

A 25-mile (40-kilometre) reach of the Merced River was studied to provide the National Park Service with water-quality data prior to the operation of a new sewage-treatment plant. Data were collected periodically at four Merced River and two inflow stations. Discharge varied seasonally with highest flow occurring at the time of spring snowmelt runoff. Lowest flow occurred during late summer, coinciding with high park visitor use and elevated water temperature. Water-quality variables investigated were discharge, temperature, major chemical constituents, selected trace metals, specific conductance, suspended sediment, turbidity, dissolved oxygen, pH, alkalinity, carbon dioxide, total organic carbon, nitrogen, phosphorus, algal growth potential, coliform bacteria, periphyton, and benthic invertebrates. Diel measurements were made at some stations to delineate daily fluctuations in selected water-quality variables. Results indicate that water in the reach of the Merced River studied was of good quality. The river had low concentrations of dissolved solids (8 to 41 milligrams per litre) and low alkalinity values (2 to 24 milligrams per litre of alkalinity as CaCO 3 ). Mean concentrations of nitrogen and phosphorus were highest in the Merced River at Rancheria Flat. Algal growth potential tests showed that phosphorus was limiting algal growth at Happy Isles Bridge, El Capitan Bridge, and South Fork Merced River, whereas nitrogen was limiting growth at Rancheria Flat. Input of excessive nitrogen and phosphorus concentrations in the Merced River during the summer low-flow period, and mixing with warm tributary inflow could cause excessive algal growth and production. The algal types found were diatoms, green algae, and blue-green algae. Biomass/chlorophyll a ratios in the Merced River were low (0.3 to 7.7). Benthic invertebrates consisted chiefly of Diptera, Ephemeroptera, and Plecoptera.

California↗