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Evidence that acidification-induced declines in plant diversity and productivity are mediated by changes in below-ground communities and soil properties in a semi-arid steppe

Anthropogenic acid deposition–induced soil acidification is one of the major threats to biodiversity, ecosystem functioning and services. Few studies, however, have explored in detail how above-ground changes in plant species richness and productivity resulting from soil acidification are mediated by effects on below-ground biota and soil properties. To increase our understanding of this linkage, we collected data on below- and above-ground communities and soil properties in a 3-year field experiment with seven levels of acid addition rate to build-up broad intensities of soil acidification in the semi-arid Inner Mongolian grassland. Acid addition directly elevated concentrations of soil Al 3+ ions, decreased the base cations Ca 2+ , Mg 2+ and Na + , and increased soil moisture and available phosphorus. Acid addition also appears to have altered the soil microbial community via changes in H + and Al 3+ ions and altered the nematode community via changes in H + ions and soil moisture. The observed changes in soil N availability (i.e. net N mineralization, NO 3 - -N and NH 4 + -N) could be explained by mediating changes in the H + and Al 3+ ions, microbial community (i.e. community structure, bacteria and fungi/bacteria as indicated by phospholipid fatty acids analysis) and the nematode community (i.e. total abundance, taxa richness and maturity index). Declines in plant species richness and productivity were greater at high intensities of soil acidification in the second sampling year than in the first sampling year. The changes in plant community observed were mostly explained by soil nutrient pathways (e.g. N availability or base mineral cations), which were in turn regulated by the soil microbial or nematode communities as well as by the direct effects of the increase in H + or Al 3+ ions. Synthesis. Our results suggest that the below-ground microbial and nematode communities are more sensitive to soil acidification than the plant communities are, and further that soil acidification–induced changes in plants are mediated by changes in below-ground communities and soil nutrients. These findings improve our understanding of the links between below- and above-ground communities in the Inner Mongolia grassland, especially in the context of anthropogenic acid enrichment.

Inner Mongolia↗

Mars Exploration Rover Athena Panoramic Camera (Pancam) investigation

The Panoramic Camera (Pancam) investigation is part of the Athena science payload launched to Mars in 2003 on NASA's twin Mars Exploration Rover (MER) missions. The scientific goals of the Pancam investigation are to assess the high‐resolution morphology, topography, and geologic context of each MER landing site, to obtain color images to constrain the mineralogic, photometric, and physical properties of surface materials, and to determine dust and aerosol opacity and physical properties from direct imaging of the Sun and sky. Pancam also provides mission support measurements for the rovers, including Sun‐finding for rover navigation, hazard identification and digital terrain modeling to help guide long‐term rover traverse decisions, high‐resolution imaging to help guide the selection of in situ sampling targets, and acquisition of education and public outreach products. The Pancam optical, mechanical, and electronics design were optimized to achieve these science and mission support goals. Pancam is a multispectral, stereoscopic, panoramic imaging system consisting of two digital cameras mounted on a mast 1.5 m above the Martian surface. The mast allows Pancam to image the full 360° in azimuth and ±90° in elevation. Each Pancam camera utilizes a 1024 × 1024 active imaging area frame transfer CCD detector array. The Pancam optics have an effective focal length of 43 mm and a focal ratio of f /20, yielding an instantaneous field of view of 0.27 mrad/pixel and a field of view of 16° × 16°. Each rover's two Pancam “eyes” are separated by 30 cm and have a 1° toe‐in to provide adequate stereo parallax. Each eye also includes a small eight position filter wheel to allow surface mineralogic studies, multispectral sky imaging, and direct Sun imaging in the 400–1100 nm wavelength region. Pancam was designed and calibrated to operate within specifications on Mars at temperatures from −55° to +5°C. An onboard calibration target and fiducial marks provide the capability to validate the radiometric and geometric calibration on Mars.

Journal of Geophysical Research E: Planets↗

Stress interaction between subduction earthquakes and forearc strike-slip faults: Modeling and application to the northern Caribbean plate boundary

Strike-slip faults in the forearc region of a subduction zone often present significant seismic hazard because of their proximity to population centers. We explore the interaction between thrust events on the subduction interface and strike-slip faults within the forearc region using three-dimensional models of static Coulomb stress change. Model results reveal that subduction earthquakes with slip vectors subparallel to the trench axis enhance the Coulomb stress on strike-slip faults adjacent to the trench but reduce the stress on faults farther back in the forearc region. In contrast, subduction events with slip vectors perpendicular to the trench axis enhance the Coulomb stress on strike-slip faults farther back in the forearc, while reducing the stress adjacent to the trench. A significant contribution to Coulomb stress increase on strike-slip faults in the back region of the forearc comes from "unclamping" of the fault, i.e., reduction in normal stress due to thrust motion on the subduction interface. We argue that although Coulomb stress changes from individual subduction earthquakes are ephemeral, their cumulative effects on the pattern of lithosphere deformation in the forearc region are significant. We use the Coulomb stress models to explain the contrasting deformation pattern between two adjacent segments of the Caribbean subduction zone. Subduction earthquakes with slip vectors nearly perpendicular to the Caribbean trench axis is dominant in the Hispaniola segment, where the strike-slip faults are more than 60 km inland from the trench. In contrast, subduction slip motion is nearly parallel to the Caribbean trench axis along the Puerto Rico segment, where the strike-slip fault is less than 15 km from the trench. This observed jump from a strike-slip fault close to the trench axis in the Puerto Rico segment to the inland faults in Hispaniola is explained by different distributions of Coulomb stress in the forearc region of the two segments, as a result of the change from the nearly trench parallel slip on the Puerto Rico subduction interface to the more perpendicular subduction slip beneath Hispaniola. The observations and modeling suggest that subduction-induced strike-slip seismic hazard to Puerto Rico may be smaller than previously assumed but the hazard to Hispaniola remains high. Copyright 2004 by the American Geophysical Union.

Puerto Rico↗

Overview of the Microscopic Imager Investigation during Spirit's first 450 sols in Gusev crater

The Microscopic Imager (MI) on the Mars Exploration Rover Spirit has returned images of Mars with higher resolution than any previous camera system, allowing detailed petrographic and sedimentological studies of the rocks and soils at the Gusev landing site. Designed to simulate a geologist's hand lens, the MI is mounted on Spirit's instrument arm and can resolve objects 0.1 mm in size or larger. This paper provides an overview of MI operations, data calibration, processing, and analysis of MI data returned during the first 450 sols (Mars days) of the Spirit landed mission. The primary goal of this paper is to facilitate further analyses of MI data by summarizing the methods used to acquire and process the data, the radiometric and geometric accuracy of MI data products, and the availability of archival products. In addition, scientific results of the MI investigation are summarized. MI observations show that poorly sorted soils are common in Gusev crater, although aeolian bedforms have well‐sorted coarse sand grains on their surfaces. Abraded surfaces of plains rocks show igneous textures, light‐toned veins or fracture‐filling minerals, and discrete coatings. The rocks in the Columbia Hills have a wide variety of granular textures, consistent with volcaniclastic or impact origins. Case hardening and submillimeter veins observed in the rocks as well as soil crusts and cemented clods imply episodic subsurface aqueous fluid movement, which has altered multiple geologic units in the Columbia Hills. The MI also monitored Spirit's solar panels and the magnets on the rover's deck.

Journal of Geophysical Research E: Planets↗

An examination of soil crusts on the floor of Jezero crater, Mars

Martian soils are critically important for understanding the history of Mars, past potentially habitable environments, returned samples, and future human exploration. This paper examines soil crusts on the floor of Jezero crater encountered during initial phases of the Mars 2020 mission. Soil surface crusts have been observed on Mars at other locations, starting with the two Viking Lander missions. Rover observations show that soil crusts are also common across the floor of Jezero crater, revealed in 45 of 101 locations where rover wheels disturbed the soil surface, 2 out of 7 helicopter flights that crossed the wheel tracks, and 4 of 8 abrasion/drilling sites. Most soils measured by the SuperCam laser-induced breakdown spectroscopy (LIBS) instrument show high hydrogen content at the surface, and fine-grained soils also show a visible/near infrared (VISIR) 1.9 µm H 2 O absorption feature. The Planetary Instrument for X-ray Lithochemistry (PIXL) and SuperCam observations suggest the presence of salts at the surface of rocks and soils. The correlation of S and Cl contents with H contents in SuperCam LIBS measurements suggests that the salts present are likely hydrated. On the “Naltsos” target, magnesium and sulfur are correlated in PIXL measurements, and Mg is tightly correlated with H at the SuperCam points, suggesting hydrated Mg-sulfates. Mars Environmental Dynamics Analyzer (MEDA) observations indicate possible frost events and potential changes in the hydration of Mg-sulfate salts. Jezero crater soil crusts may therefore form by salts that are hydrated by changes in relative humidity and frost events, cementing the soil surface together.

Journal of Geophysical Research: Planets↗

Confocal laser-scanning microscopy (CLSM)-based thermal maturity of Tasmanites and progress in standardization of fluorescence microspectrometry

Evaluation of thermal maturity in vitrinite-free or vitrinite-deficient sediments via fluorescence microspectrometry can provide relevant information related to petroleum exploration and thermal history assessment. However, variation in spectral fluorescence properties of alginite macerals with increasing thermal maturity is largely underexplored. Here, authors of this study have applied confocal laser-scanning microscopy (CLSM) in conjunction with fluorescence microspectrometry to a maturity series of marine Upper Devonian Tasmanites algae from the Ohio Shale (Huron Member) and a single sample from the Marcellus Formation of the Appalachian Basin. Spectral fluorescence properties of Tasmanites were evaluated in relation to orientation, measurement location, and the number of measurements per sample, and were compared to published literature. Emission spectra of Tasmanites from continuous wave laser excitation (405 nm) were acquired from sections perpendicular and parallel to bedding and at different positions within individual Tasmanites bodies. The results showed a progressive red-shift in emission maxima (λ max ) in a large sample sized maturity series ( N = 19), e.g., 493 to 578 nm for the perpendicular section at middle position. Further, blue-shifted apex and mineral-adjacent positions within sections perpendicular to bedding were observed, with the latter being reported here for the first time. While blue-shift at apex positions can be attributed to mechanical deformation-induced reorientation of photoselected fluorophores, the blue-shifted mineral-adjacent positions could result from strain loading and development of a plastic deformation region at the mineral contact zone with Tasmanites . A decrease in standard deviation with increasing number of measured emission maxima is well-observed, and 15 to 20 individual measurements per sample appears sufficient for low standard deviation and coefficient of variance. CLSM-derived thermal maturity parameters indicated that a moderate positive correlation of red/green quotient (Q 650/500 ; R 2 = 0.67) with solid bitumen reflectance (BR o in %) exists. For reproducible results, the determination of λ max and Q 650/500 should be conducted exclusively in the middle position at perpendicular and parallel sections of the polished whole-rock pellets, where the lowest standard deviation in measurement was observed. These results strengthen the suitability and relevance of the CLSM technique in thermal maturity studies of dispersed organic matter (DOM) and contribute to the standardization of fluorescence microspectrometry methods in organic petrology investigation.

Kentucky, Ohio, Virginia, West Virginia↗

Overview of the Opportunity Mars Exploration Rover Mission to Meridiani Planum: Eagle Crater to Purgatory Ripple

The Mars Exploration Rover Opportunity touched down at Meridiani Planum in January 2004 and since then has been conducting observations with the Athena science payload. The rover has traversed more than 5 km, carrying out the first outcrop‐scale investigation of sedimentary rocks on Mars. The rocks of Meridiani Planum are sandstones formed by eolian and aqueous reworking of sand grains that are composed of mixed fine‐grained siliciclastics and sulfates. The siliciclastic fraction was produced by chemical alteration of a precursor basalt. The sulfates are dominantly Mg‐sulfates and also include Ca‐sulfates and jarosite. The stratigraphic section observed to date is dominated by eolian bedforms, with subaqueous current ripples exposed near the top of the section. After deposition, interaction with groundwater produced a range of diagenetic features, notably the hematite‐rich concretions known as “blueberries.” The bedrock at Meridiani is highly friable and has undergone substantial erosion by wind‐transported basaltic sand. This sand, along with concretions and concretion fragments eroded from the rock, makes up a soil cover that thinly and discontinuously buries the bedrock. The soil surface exhibits both ancient and active wind ripples that record past and present wind directions. Loose rocks on the soil surface are rare and include both impact ejecta and meteorites. While Opportunity's results show that liquid water was once present at Meridiani Planum below and occasionally at the surface, the environmental conditions recorded were dominantly arid, acidic, and oxidizing and would have posed some significant challenges to the origin of life.

Journal of Geophysical Research E: Planets↗

Multi-scale occupancy estimation and modelling using multiple detection methods

Occupancy estimation and modelling based on detection–nondetection data provide an effective way of exploring change in a species’ distribution across time and space in cases where the species is not always detected with certainty. Today, many monitoring programmes target multiple species, or life stages within a species, requiring the use of multiple detection methods. When multiple methods or devices are used at the same sample sites, animals can be detected by more than one method. We develop occupancy models for multiple detection methods that permit simultaneous use of data from all methods for inference about method-specific detection probabilities. Moreover, the approach permits estimation of occupancy at two spatial scales: the larger scale corresponds to species’ use of a sample unit, whereas the smaller scale corresponds to presence of the species at the local sample station or site. We apply the models to data collected on two different vertebrate species: striped skunks Mephitis mephitis and red salamanders Pseudotriton ruber . For striped skunks, large-scale occupancy estimates were consistent between two sampling seasons. Small-scale occupancy probabilities were slightly lower in the late winter/spring when skunks tend to conserve energy, and movements are limited to males in search of females for breeding. There was strong evidence of method-specific detection probabilities for skunks. As anticipated, large- and small-scale occupancy areas completely overlapped for red salamanders. The analyses provided weak evidence of method-specific detection probabilities for this species. Synthesis and applications. Increasingly, many studies are utilizing multiple detection methods at sampling locations. The modelling approach presented here makes efficient use of detections from multiple methods to estimate occupancy probabilities at two spatial scales and to compare detection probabilities associated with different detection methods. The models can be viewed as another variation of Pollock's robust design and may be applicable to a wide variety of scenarios where species occur in an area but are not always near the sampled locations. The estimation approach is likely to be especially useful in multispecies conservation programmes by providing efficient estimates using multiple detection devices and by providing device-specific detection probability estimates for use in survey design.

Journal of Applied Ecology↗

Hematite spherules at Meridiani: results from MI, Mini-TES, and Pancam

We report on observations of hematite‐bearing spherules at Meridiani Planum made using the Microscopic Imager (MI), Mini‐Thermal Emission Spectrometer (Mini‐TES), and Panoramic Camera (Pancam) instruments on the Mars Exploration Rover Opportunity. Spherules were observed on soil surfaces and in outcrop rocks, both on undisturbed surfaces and in abraded surfaces ground using the Rock Abrasion Tool (RAT). Spherule size and shape change little along the 850 m eastward traverse from Eagle Crater to Endurance Crater, but spherules decrease and then slightly increase in size along the 6 km traverse from Endurance south to Victoria Crater. Local populations range from submillimeters to several millimeters in diameter. An additional small diameter (100 μ m) size population is possible. An increase in irregular shapes is found near Victoria Crater. This, combined with the size decrease south of Endurance, suggests either a changing depositional environment, or variation in the duration and timing of diagenetic events. The dominant smaller size population observed early in the mission in aeolian areas and ripple crests is observed as the primary size population in abraded outcrop farther south. This suggests that successively younger beds are exposed at the surface along the southward traverse. Stratigraphically higher units removed by erosion could be recorded by the present surface lag deposit. Coordinated systematic observations are used to determine optical and infrared hematite indices of the surface soils in Pancam and Mini‐TES. In spite of the systematic variation seen in MI, both Pancam and Mini‐TES indices are highly variable based on the local surface, and neither show systematic trends south of Endurance. The lack of a 390 cm −1 feature in Mini‐TES spectra suggests concentric or radial interior structure within the spherules at scales too fine for MI to observe. Mini‐TES does not detect any silicate component in the spherules. A bound water component in soils or in exchange with the atmosphere is observed. These spherules have been previously interpreted as concretions formed within what were once water‐saturated, diagenetically altered “dirty evaporate” sandstone sediments. Our observations support this interpretation; however, no single terrestrial analog provides a model that can account for all attributes of the spherules on Mars.

Journal of Geophysical Research↗

Optimal population prediction of sandhill crane recruitment based on climate-mediated habitat limitations

Prediction is fundamental to scientific enquiry and application; however, ecologists tend to favour explanatory modelling. We discuss a predictive modelling framework to evaluate ecological hypotheses and to explore novel/unobserved environmental scenarios to assist conservation and management decision-makers. We apply this framework to develop an optimal predictive model for juvenile (<1 year old) sandhill crane Grus canadensis recruitment of the Rocky Mountain Population (RMP). We consider spatial climate predictors motivated by hypotheses of how drought across multiple time-scales and spring/summer weather affects recruitment. Our predictive modelling framework focuses on developing a single model that includes all relevant predictor variables, regardless of collinearity. This model is then optimized for prediction by controlling model complexity using a data-driven approach that marginalizes or removes irrelevant predictors from the model. Specifically, we highlight two approaches of statistical regularization, Bayesian least absolute shrinkage and selection operator (LASSO) and ridge regression. Our optimal predictive Bayesian LASSO and ridge regression models were similar and on average 37% superior in predictive accuracy to an explanatory modelling approach. Our predictive models confirmed a priori hypotheses that drought and cold summers negatively affect juvenile recruitment in the RMP. The effects of long-term drought can be alleviated by short-term wet spring–summer months; however, the alleviation of long-term drought has a much greater positive effect on juvenile recruitment. The number of freezing days and snowpack during the summer months can also negatively affect recruitment, while spring snowpack has a positive effect. Breeding habitat, mediated through climate, is a limiting factor on population growth of sandhill cranes in the RMP, which could become more limiting with a changing climate (i.e. increased drought). These effects are likely not unique to cranes. The alteration of hydrological patterns and water levels by drought may impact many migratory, wetland nesting birds in the Rocky Mountains and beyond. Generalizable predictive models (trained by out-of-sample fit and based on ecological hypotheses) are needed by conservation and management decision-makers. Statistical regularization improves predictions and provides a general framework for fitting models with a large number of predictors, even those with collinearity, to simultaneously identify an optimal predictive model while conducting rigorous Bayesian model selection. Our framework is important for understanding population dynamics under a changing climate and has direct applications for making harvest and habitat management decisions.

Journal of Animal Ecology↗

Fault locking, block rotation and crustal deformation in the Pacific Northwest

We interpret Global Positioning System (GPS) measurements in the northwestern United States and adjacent parts of western Canada to describe relative motions of crustal blocks, locking on faults and permanent deformation associated with convergence between the Juan de Fuca and North American plates. To estimate angular velocities of the oceanic Juan de Fuca and Explorer plates and several continental crustal blocks, we invert the GPS velocities together with seafloor spreading rates, earthquake slip vector azimuths and fault slip azimuths and rates. We also determine the degree to which faults are either creeping aseismically or, alternatively, locked on the block-bounding faults. The Cascadia subduction thrust is locked mainly offshore, except in central Oregon, where locking extends inland. Most of Oregon and southwest Washington rotate clockwise relative to North America at rates of 0.4–1.0 ° Myr −1 . No shear or extension along the Cascades volcanic arc has occurred at the mm/yr level during the past decade, suggesting that the shear deformation extending northward from the Walker Lane and eastern California shear zone south of Oregon is largely accommodated by block rotation in Oregon. The general agreement of vertical axis rotation rates derived from GPS velocities with those estimated from palaeomagnetic declination anomalies suggests that the rotations have been relatively steady for 10–15 Ma. Additional permanent dextral shear is indicated within the Oregon Coast Range near the coast. Block rotations in the Pacific Northwest do not result in net westward flux of crustal material—the crust is simply spinning and not escaping. On Vancouver Island, where the convergence obliquity is less than in Oregon and Washington, the contractional strain at the coast is more aligned with Juan de Fuca—North America motion. GPS velocities are fit significantly better when Vancouver Island and the southern Coast Mountains move relative to North America in a block-like fashion. The relative motions of the Oregon, western Washington and Vancouver Island crustal blocks indicate that the rate of permanent shortening, the type that causes upper plate earthquakes, across the Puget Sound region is 4.4 ± 0.3 mm yr −1 . This shortening is likely distributed over several faults but GPS data alone cannot determine the partitioning of slip on them. The transition from predominantly shear deformation within the continent south of the Mendocino Triple Junction to predominantly block rotations north of it is similar to changes in tectonic style at other transitions from shear to subduction. This similarity suggests that crustal block rotations are enhanced in the vicinity of subduction zones possibly due to lower resisting stress.

Geophysical Journal International↗

Low streamflow trends at human-impacted and reference basins in the United States

We present a continent-scale exploration of trends in annual 7-day low streamflows at 2482 U.S. Geological Survey streamgages across the conterminous United States over the past 100, 75, and 50 years (1916–2015, 1941–2015 and 1966–2015). We used basin characteristics to identify subsets of study basins representative of reference basins with streamflow relatively free from human effects (n = 259), and predominantly agricultural basins (n = 78), regulated basins (n = 220), and urban basins (n = 121). Trend significance was computed using the Mann-Kendall test considering short- and long-term persistence. Lag-one autocorrelation tests of detrended 7-day low streamflows for all gage classes show that time-series independence is not an appropriate assumption for annual low streamflow data at many basins. Among all study gages, upward trends (wetter conditions) in 7-day low streamflows outnumbered downward trends (drier conditions) approximately 2–1 for the 75- and 100-year trend periods—50-year trends indicated roughly equal numbers of increases and decreases. Increases in 7-day low streamflow were consistently observed for all time periods throughout much of the northeastern quadrant of the conterminous U.S. including western New England and the Mid-Atlantic, the southeastern Great Lakes basin, northern Ohio River basin, and the Upper Mississippi River and eastern Missouri River basins. Decreases in 7-day low streamflow were consistently observed for all time periods at many gages in the southeastern U.S. and in the northwestern U.S. in much of Idaho and northwestern Washington. Overall, we observed greater percentages of statistically significant trends at gages with human-induced influences than at reference gages. Low-flow trends at agricultural gages were regionally consistent with trends at reference gages. Regulated basins had many statistically significant upward trends for all three time periods tested, which may be attributed in part to substantial increases in dam-related storage prior to 1970. Urban gages had the greatest percentage of significant decreases in 7-day low flows compared to all other gage classes even though most urban gages saw upward trends in mean annual flows. Urban gages also had the greatest percentage of significant increases in low flows second only to regulated gages, highlighting that urban development can increase or decrease low streamflows depending on the basin-specific development.

Conterminous United States↗

Scientific results of the Hydrate-01 Stratigraphic Test Well Program, Western Prudhoe Bay Unit, Alaska North Slope

The United States Department of Energy, the MH21-S Research Consortium of Japan, and the United States Geological Survey are collaborating to enable gas hydrate scientific drilling and extended-duration reservoir response testing on the Alaska North Slope. To feasibly execute such a test, a location is required that is accessible from existing roads and gravel pads and that can be occupied without disrupting ongoing industry operations. A review of potential locations meeting these criteria determined the likely occurrence of gas hydrate in two fine-grained marginal-marine sands of Tertiary age in the vicinity of the inactive “Kuparuk State 7-11-12” exploration pad in the western Prudhoe Bay Unit (PBU). Existing well and seismic data for that site were insufficient to preclude the potential for free gas occurrence within the deeper (and most prospective) target sand. Therefore, with support from the PBU Working Interest Owners, Alaska Department of Natural Resources, and Petrotechnical Resources Alaska, the Hydrate-01 Stratigraphic Test Well (STW) was drilled in December 2018 to confirm the suitability of the site for future gas hydrate scientific testing. The Hydrate-01 well was successfully drilled to −3290 ft (1003 m) subsea vertical depth at a bottom hole location of approximately 900 ft (∼275 m) east of the surface location. The drilling program featured acquisition of a full suite of logging while drilling data, the collection of side-wall pressure cores, and the installation of distributed temperature and distributed acoustic sensor fiber-optic cables. The log data acquired confirmed the occurrence of gas hydrate at high saturation in two target sands. Integrated evaluation of log and sidewall core data provide petrophysical and geomechanical property information that allow for potential reservoir response to depressurization to be simulated. The deeper “B1 sand” is deemed to be most favorable for reservoir response testing as a result of confirmed gas hydrate occurrence in sediments of high intrinsic permeability, location within 100 ft (30 m) of the base of gas hydrate stability, and minimal risk for direct communication with permeable water-bearing (hydrate-free) zones. The shallower “D1 sand” provides a secondary target that is differentiated by colder in situ temperatures and the interpreted direct hydraulic communication to a lower section of non-hydrate-bearing, water-saturated sand. The Hydrate-01 log data also confirm the occurrence of at least one sub-seismic fault in close proximity to the B1 sand reservoir. To better image the distribution of the gas-hydrate-bearing reservoir sections and associated faults, a three-dimensional (3D) vertical seismic profile was conducted in early 2019 using the distributed acoustic sensors installed as part of the Hydrate-01 STW completion. Detailed two-dimensional (2D) and 3D geologic models have been constructed to enable numerical simulations to inform the planning for potential future scientific tests of reservoir response to depressurization at the site.

Alaska↗

Classification tree and minimum-volume ellipsoid analyses of the distribution of ponderosa pine in the western USA

Aim? Ponderosa pine (Pinus ponderosa Douglas ex Lawson & C. Lawson) is an economically and ecologically important conifer that has a wide geographic range in the western USA, but is mostly absent from the geographic centre of its distribution - the Great Basin and adjoining mountain ranges. Much of its modern range was achieved by migration of geographically distinct Sierra Nevada (P. ponderosa var. ponderosa) and Rocky Mountain (P. ponderosa var. scopulorum) varieties in the last 10,000 years. Previous research has confirmed genetic differences between the two varieties, and measurable genetic exchange occurs where their ranges now overlap in western Montana. A variety of approaches in bioclimatic modelling is required to explore the ecological differences between these varieties and their implications for historical biogeography and impending changes in western landscapes. Location? Western USA. Methods? We used a classification tree analysis and a minimum-volume ellipsoid as models to explain the broad patterns of distribution of ponderosa pine in modern environments using climatic and edaphic variables. Most biogeographical modelling assumes that the target group represents a single, ecologically uniform taxonomic population. Classification tree analysis does not require this assumption because it allows the creation of pathways that predict multiple positive and negative outcomes. Thus, classification tree analysis can be used to test the ecological uniformity of the species. In addition, a multidimensional ellipsoid was constructed to describe the niche of each variety of ponderosa pine, and distances from the niche were calculated and mapped on a 4-km grid for each ecological variable. Results? The resulting classification tree identified three dominant pathways predicting ponderosa pine presence. Two of these three pathways correspond roughly to the distribution of var. ponderosa, and the third pathway generally corresponds to the distribution of var. scopulorum. The classification tree and minimum-volume ellipsoid model show that both varieties have very similar temperature limitations, although var. ponderosa is more limited by the temperature extremes of the continental interior. The precipitation limitations of the two varieties are seasonally different, with var. ponderosa requiring significant winter moisture and var. scopulorum requiring significant summer moisture. Great Basin mountain ranges are too cold at higher elevations to support either variety of ponderosa pine, and at lower elevations are too dry in summer for var. scopulorum and too dry in winter for var. ponderosa. Main conclusions? The classification tree analysis indicates that var. ponderosa is ecologically as well as genetically distinct from var. scopulorum. Ecological differences may maintain genetic separation in spite of a limited zone of introgression between the two varieties in western Montana. Two hypotheses about past and future movements of ponderosa pine emerge from our analyses. The first hypothesis is that, during the last glacial period, colder and/or drier summers truncated most of the range of var. scopulorum in the central Rockies, but had less dramatic effects on the more maritime and winter-wet distribution of var. ponderosa. The second hypothesis is that, all other factors held constant, increasing summer temperatures in the future should produce changes in the distribution of var. scopulorum that are likely to involve range expansions in the central Rockies with the warming of mountain ranges currently too cold but sufficiently wet in summer for var. scopulorum. Finally, our results underscore the growing need to focus on genotypes in biogeographical modelling and ecological forecasting.

Journal of Biogeography↗

Biogenic origin of coalbed gas in the northern Gulf of Mexico Coastal Plain, U.S.A

New coal-gas exploration and production in northern Louisiana and south-central Mississippi, Gulf of Mexico Basin, is focused on the Wilcox Group (Paleocene–Eocene), where the depth to targeted subbituminous C to high volatile C bituminous coal beds ranges from 300 to 1680 m, and individual coal beds have a maximum thickness of about 6 m. Total gas content (generally excluding residual gas) of the coal beds ranges from less than 0.37 cm 3 /g (as-analyzed or raw basis; 1.2 cm 3 /g, dry, ash free basis, daf) at depths less than 400 m, to greater than 7.3 cm 3 /g (as-analyzed basis; 8.76 cm 3 /g, daf) in deeper (> 1,500 m) parts of the basin. About 20 Wilcox coal-gas wells in northern Louisiana produce from 200 to 6485 m 3 of gas/day and cumulative gas production from these wells is approximately 25 million m 3 (as of December, 2006). U.S. Geological Survey assessment of undiscovered, technically recoverable gas resources in the Gulf of Mexico Coastal Plain, including northern and south-central Mississippi, indicates that coal beds of the Wilcox Group contain an estimated mean total 109.3 million m 3 (3.86 trillion ft 3 ) of producible natural gas. To determine the origin of the Wilcox Group coal gases in northern Louisiana, samples of gas, water, and oil were collected from Wilcox coal and sandstone reservoirs and from under- and overlying Late Cretaceous and Eocene carbonate and sandstone reservoirs. Isotopic data from Wilcox coal-gas samples have an average δ 13 C CH4 value of − 62.6‰ VPDB (relative to Vienna Peedee Belemnite) and an average δ D CH4 value of − 199.9‰ VSMOW (relative to Vienna Standard Mean Ocean Water). Values of δ 13 C CO2 range from − 25.4 to 3.42‰ VPDB. Produced Wilcox saline water collected from oil, conventional gas, and coalbed gas wells have δ D H2O values that range from − 27.3 to − 18.0‰ VSMOW. These data suggest that the coal gases primarily are generated in saline formation water by bacterial reduction of CO 2 . Shallow (< 150 m) Wilcox coal beds containing freshwater have little or no biogenic gas. Molecular and isotopic analyses of gas samples collected from conventional gas and oil wells suggests that both biogenic and thermogenic gases are present in and adjacent to the Wilcox intervals that contain biogenic coal gases. Oil, probably sourced from thermally mature, down-structural-dip parts of the Wilcox Group, is produced from sandstones within the coal-bearing interval. Gas chromatograms of C 10+ saturated hydrocarbons from Wilcox oils show a depletion of n -alkanes probably resulting from biodegradation of the oil. Isotopic composition of the gases associated with the oils is of mixed themogenic and biogenic origin (average δ 13 C CH4 = − 44.4‰ VPDB, and average δ D CH4 = − 182.4‰ VSMOW).

International Journal of Coal Geology↗

Organic petrology and geochemistry of mudrocks from the lacustrine Lucaogou Formation, Santanghu Basin, northwest China: Application to lake basin evolution

Exploration for tight oil in the frontier Santanghu Basin of northwest China has resulted in recent commercial discoveries sourced from the lacustrine Upper Permian Lucaogou Formation, already considered a “world class source rock” in the Junggar Basin to the west. Here we apply an integrated analytical program to carbonate-dominated mudrocks from the Lucaogou Formation in Santanghu Basin to document the nature of organic matter (OM) in the context of an evolving lake system. The organic-rich samples (TOC 2.8–11.4 wt%; n = 10) were widely spaced from an ~ 200 m cored section, interpreted from textural and mineralogical evidence to document transition from a lower under-filled to an overlying balanced-filled lake. Organic matter is dominated by moderate to strongly fluorescent amorphous material with Type I geochemical signature (HI values 510–755; n = 10) occurring in a continuum from lamellar stringers, 10–20 μm thick, some ≥ 1 mm in length (possible microbial mat; preserved only in lower under-filled section) to finely-disseminated amorphous groundmass intimately intermixed with mineral matrix. Biomarkers for methanotrophs and photosynthetic cyanobacteria indicate a complex microbial consortium. A unicellular prasinophyte green alga(?), similar to Tasmanites in marine rocks, is present as discrete flattened discs 50–100 μm in diameter. Type III OM including vitrinite (some fluorescent) and inertinite also is abundant. Solid bitumen, indicating local kerogen conversion, fills voids and occurs throughout the cored section. Vitrinite reflectance values are 0.47–0.58%, consistent with strong OM fluorescence but may be “suppressed”. Other proxies, e.g., biomarker parameters, indicate the Lucaogou Formation is in the early oil window at this location. On average, slightly more amorphous OM and telalginite are present in the lower section, consistent with a shallow, stratified, saline environment with low sediment dilution. More inertinite is present in the upper section, indicating greater terrestrial influx and consistent with higher quartz and plagioclase content (dominantly authigenic chalcedony and albite). Laminated mudstones in the upper section indicate anoxia prevented bioturbation from benthic grazing, also indicating stratified water column conditions. A decrease upsection in authigenic dolomite with reciprocal increase of ankerite/siderite is consistent with decreasing salinity, as is an overall decrease in gammacerane index values. These observations suggest evolution from a shallow, stratified evaporative (saline) setting to a deeper, stratified freshwater basin with higher water input during Lucaogou deposition. The evolution from an under-filled to balance-filled lake in Santanghu Basin is similar to Lucaogou deposition in Junggar Basin, suggesting similar tectonic and climatic controls. Paleoclimate interpretations from other researchers in this area suggested an evolution from semi-arid to humid conditions during the Roadian; we interpret that the evolution from an under-filled to balanced-filled lake seen in our data is in response to climate change, and may represent increased groundwater delivery to the Santanghu Basin.

International Journal of Coal Geology↗