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At least 793 records · Page 44Linked to original sources

Potential groundwater recharge rates for two subsurface-drained agricultural fields, southeastern Minnesota, 2016–18

Subsurface drainage is used to efficiently drain saturated soils to support productive agriculture in poorly drained terrains. Although subsurface drainage alters the water balance for agricultural fields, its effect on groundwater resources and groundwater recharge is poorly understood. In Minnesota, subsurface drainage has begun to increase in southeastern Minnesota, even though this part of the State is underlain by permeable karstic bedrock aquifers with only a thin layer of glacial sediments separating these aquifers from land surface. To gain a better understanding of groundwater recharge effects from subsurface drainage, the U.S. Geological Survey (USGS), in cooperation with the Legislative-Citizen Commission on Minnesota Resources, led a 2-year hydrologic study to investigate this connection for two agricultural fields in southeastern Minnesota with subsurface drainage. A total of three monitoring plots were used between the two agricultural fields: two monitoring plots that included an actively drained area with peripheral, undrained areas, and a third monitoring plot without any subsurface drainage. Multiple piezometer transects were set up across the three monitoring plots to characterize the unsaturated zone and shallow water-table flow using pressure transducers and soil moisture probes. From these piezometers, groundwater recharge rates were derived using two different methods: the RISE Water-Table Fluctuation (WTF) method and the DRAINMOD model. In addition to these two methods, the USGS Soil-Water-Balance (SWB) model was used to estimate potential recharge rates for three different monitoring plots. In addition to deriving groundwater recharge rates, the hydrologic budget was analyzed to interpret the water-table surface elevation and soil volumetric water content time series. At one of the two drained plots, the transects exhibited varying water-table surface elevation patterns. Frequent backflow from the adjacent ditch caused subsurface drainage flow to slow down or stop drainage through the main collector drain and cause pipe pressurization, so the closest transect appeared to be mostly controlled by the drain pressurization, whereas the farthest transect was more efficiently drained. Both of the drained monitoring plots had an elevation gradient parallel to the pattern tiles, sloping downward towards the collector drain that aggregated the parallel lines into a single drain. Because the transects were set at different gradients in the field, some of the water-table surface elevation differences were also attributed to lateral flow towards the lowest parts of the field. Three methods were used to derive potential groundwater recharge rates: the RISE WTF method, the USGS SWB model, and DRAINMOD-derived deep seepage rates. Potential groundwater recharge rates, using the RISE WTF method, across all piezometers were 1.55 and 1.94 inches per year, respectively, for water years 2017 and 2018. More differentiation of potential recharge rates between different piezometer types occurred for water year 2018. Although the difference was slightly more than 1 inch between the drained and nondrained piezometers for water year 2018, this difference was statistically significant based on a t-test with a p -value of 0.036 ( α =0.05). When looking at recharge based on distance from the drain, the subsurface drain did not affect potential recharge, although other factors such as variability in screen depths, well construction, and specific yield variability cannot be eliminated. The SWB model was also used to estimate potential recharge rates for water years 2017–18, with rates between 2.44 and 5.92 inches per year for the two drained sites, generally higher than the RISE WTF estimates. DRAINMOD-derived potential recharge rates were generally the highest of the three methods, with potential recharge rates varying from 2.07 to 9.49 inches per year. Overall, there was a lack of agreement between the three methods. These results were not remarkable, considering the fundamental differences in the methodology for each method. However, all methods did show a fundamental difference between piezometers within the drained area and piezometers outside the drained area, including the third undrained monitoring plot. The drained areas show a lower overall potential groundwater recharge compared to the nondrained areas for all three estimates. The difference for the 2018 recharge estimates was slightly higher than 1 inch for the RISE WTF method, the difference was almost double for the nine sites for the DRAINMOD model, and the difference between the drain and undrained plots was even more significant for the SWB model.

Minnesota↗

Characterization of stream water quality and groundwater levels in the Central Pine Barrens region, Suffolk County, New York, 2017–23

The area locally known as the “Central Pine Barrens” region, located in Suffolk County, New York, contains most of Long Island’s preserved and undeveloped land. This region overlays an aquifer system that provides potable groundwater for residents of Suffolk County. Between 2017 and 2023, the U.S. Geological Survey, in cooperation with the Central Pine Barrens Joint Planning & Policy Commission and the Town of Brookhaven, monitored groundwater levels and stream water quality in this region. Groundwater levels were measured monthly at five wells and continuously (15-minute intervals) at a sixth well. Water quality was monitored at five locations in the Carmans River and at two locations in the Peconic River, and samples were analyzed for major ions, trace elements, nutrients, pharmaceuticals, and pesticides. The major ion compositions at the sites were mainly sodium-chloride type waters, and compositions varied the most at the furthest upstream sites in both streams. Concentrations above aquatic-life criteria thresholds also occurred most frequently at the furthest upstream sites. The seasonal patterns of nutrient loads and concentrations varied between the Carmans and Peconic Rivers. Several organic compounds including pharmaceuticals, domestic use products, and pesticides were detected at low concentrations in both streams. Metformin was the most frequently detected pharmaceutical compound, and herbicides were the most frequently detected pesticide class. Water-quality conditions influenced by anthropogenic contributions are a result of current and historical land use, and these contributions include onsite wastewater disposal systems, commercial or domestic fertilizers and pesticides, and urban or industrial contaminants in road runoff. This study characterizes and improves understanding of the current hydrologic conditions in the Central Pine Barrens region and the study findings can help inform the development of plans to manage, protect, and restore water resources.

New York↗

Unconventional shallow biogenic gas systems

Unconventional shallow biogenic gas falls into two distinct systems that have different attributes. Early-generation systems have blanketlike geometries, and gas generation begins soon after deposition of reservoir and source rocks. Late-generation systems have ringlike geometries, and long time intervals separate deposition of reservoir and source rocks from gas generation. For both types of systems, the gas is dominantly methane and is associated with source rocks that are not thermally mature. Early-generation biogenic gas systems are typified by production from low-permeability Cretaceous rocks in the northern Great Plains of Alberta, Saskatchewan, and Montana. The main area of production is on the southeastern margin of the Alberta basin and the northwestern margin of the Williston basin. The huge volume of Cretaceous rocks has a generalized regional pattern of thick, non-marine, coarse clastics to the west and thinner, finer grained marine lithologies to the east. Reservoir rocks in the lower part tend to be finer grained and have lower porosity and permeability than those in the upper part. Similarly, source beds in the units have higher values of total organic carbon. Patterns of erosion, deposition, deformation, and production in both the upper and lower units are related to the geometry of lineament-bounded basement blocks. Geochemical studies show that gas and coproduced water are in equilibrium and that the fluids are relatively old, namely, as much as 66 Ma. Other examples of early-generation systems include Cretaceous clastic reservoirs on the southwestern margin of Williston basin and chalks on the eastern margin of the Denver basin. Late-generation biogenic gas systems have as an archetype the Devonian Antrim Shale on the northern margin of the Michigan basin. Reservoir rocks are fractured, organic-rich black shales that also serve as source rocks. Although fractures are important for production, the relationships to specific geologic structures are not clear. Large quantities of water are coproduced with the gas, and geochemical data indicate that the water is fairly fresh and relatively young. Current thinking holds that biogenic gas was generated, and perhaps continues to be, when glacial meltwater descended into the plumbing system provided by fractures. Other examples of late-generation systems include the Devonian New Albany Shale on the eastern margin of the Illinois basin and the Tertiary coalbed methane production on the northwestern margin of the Powder River basin. Both types of biogenic gas systems have a similar resource development history. Initially, little technology is used, and gas is consumed locally; eventually, sweet spots are exploited, widespread unconventional reservoirs are developed, and transport of gas is interstate or international. However, drilling and completion techniques are very different between the two types of systems. Early-generation systems have water-sensitive reservoir rocks, and consequently water is avoided or minimized in drilling and completion. In contrast, water is an important constituent of late-generation systems; gas production is closely tied to dewatering the system during production. Existing production and resource estimates generally range from 10 to 100 tcf for both types of biogenic gas systems. Although both system types are examples of relatively continuous accumulations, the geologic frameworks constrain most-economic production to large geologic structures on the margins of basins. Shallow biogenic gas systems hold important resources to meet the increased domestic and international demands for natural gas.

American Association of Petroleum Geologists Bulle↗

Pore systems and organic petrology of cretaceous Mowry and Niobrara source-rock reservoirs, Powder River Basin, Wyoming, USA

The Powder River Basin (PRB) is a world-class oil province, in large part thanks to contributions from premier source rocks, Cretaceous Mowry and Niobrara shales. Both formations are also unconventional reservoirs. A critical aspect of evaluating production potential and finding sweet spots is the nature of the pore systems in these fine-grained source-rock reservoirs. Variation by stratigraphic interval is important for selecting optimum target zones for horizontal wells. Understanding variation in pore type, size, and connectivity and relationships with mineralogy and fabric help in determining prospectivity in different parts of the basin. Deciphering controls on pore-system development helps predict intervals and locations of optimum reservoir quality. Imaging of Niobrara and Mowry samples from a range of thermal maturities provided observations and data on pore systems, organic matter (OM) types and associations with mineralogy and fabric, wettability, and microporosity associated with both diagenetic and detrital clays. Imaging techniques included scanning electron microscopy, organic petrography and correlative scanning electron microscopy, and mapping of mineralogy through energy dispersive spectroscopy. Mean solid bitumen (BR o ) and vitrinite reflectance (VR o ) values indicate all samples are in the oil window with values ranging from 0.52 to 1.15%. Organic fluorescence is prominent in amorphous OM, solid bitumen and some vitrinite in the early oil window. The fluorescence is extinguished at higher thermal maturity. Carbonate pellets (in Niobrara) mainly contain migrated solid bitumen and residual live oil and little or no terrigenous OM (vitrinite and inertinite). However, terrigenous OM is common in siliceous/argillaceous laminae in both formations, where it occurs with amorphous OM, some of which has converted in situ to a solid bitumen petroleum residue. One key finding is the widespread presence of migrated OM at very early oil window maturity. Distribution of such OM and associated wettability alteration is fabric-controlled, at all levels of thermal maturity studied. Clay morphology and abundance and supporting rigid mineral grain framework strongly influence pore development, preservation, and connectivity in both formations. Carbonate content is a good proxy for reservoir quality in Niobrara intervals due to association of porous solid bitumen with calcareous fecal pellets. High recrystallized microquartz content is associated with the best reservoir intervals in the Mowry.

Wyoming↗

Shallow stratigraphic control on pockmark distribution in north temperate estuaries

Pockmark fields occur throughout northern North American temperate estuaries despite the absence of extensive thermogenic hydrocarbon deposits typically associated with pockmarks. In such settings, the origins of the gas and triggering mechanism(s) responsible for pockmark formation are not obvious. Nor is it known why pockmarks proliferate in this region but do not occur south of the glacial terminus in eastern North America. This paper tests two hypotheses addressing these knowledge gaps: 1) the region's unique sea-level history provided a terrestrial deposit that sourced the gas responsible for pockmark formation; and 2) the region's physiography controls pockmarks distribution. This study integrates over 2500 km of high-resolution swath bathymetry, Chirp seismic reflection profiles and vibracore data acquired in three estuarine pockmark fields in the Gulf of Maine and Bay of Fundy. Vibracores sampled a hydric paleosol lacking the organic-rich upper horizons, indicating that an organic-rich terrestrial deposit was eroded prior to pockmark formation. This observation suggests that the gas, which is presumably responsible for the formation of the pockmarks, originated in Holocene estuarine sediments (loss on ignition 3.5–10%), not terrestrial deposits that were subsequently drowned and buried by mud. The 7470 pockmarks identified in this study are non-randomly clustered. Pockmark size and distribution relate to Holocene sediment thickness ( r 2 = 0.60), basin morphology and glacial deposits. The irregular underlying topography that dictates Holocene sediment thickness may ultimately play a more important role in temperate estuarine pockmark distribution than drowned terrestrial deposits. These results give insight into the conditions necessary for pockmark formation in nearshore coastal environments.

Maine;New Brunswick↗

Seismic evidence for the thickness of Cenozoic deposits in Mono Basin, California

From gravity and limited seismic data obtained in 1957, Pakiser and others (1960) reported a thickness of Cenozoic deposits in the deepest part of Mono Basin, California, of 5.5 ± 1.5 km. Later, in 1962, from a series of chemical explosions in the westernmost part of Mono Basin and outside the limits of the main depressed structure, the thickness of Cenozoic deposits was estimated to be 1.6 km. In 1966, a series of ten 1-ton chemical explosions was detonated in Mono Lake near the deepest part of the Mono Basin structure for the purpose of studying the relative effectiveness of different types of explosives in generating seismic energy. Seismic waves recorded at distances 25.0 to 92.3 km from the explosions were delayed by 1.43 seconds (referred to a shot on bedrock) as they descended through the low-velocity Cenozoic deposits of Mono Basin. By using the velocities of Cenozoic deposits as determined during the 1957 field season, the thickness of Cenozoic deposits required to account for the 1.43-second delay determined in 1966 has been estimated to be about 5 ± 1 km. The delay of seismic waves emerging in Long Valley was less than expected, indicating that they were propagated into Long Valley mainly through high-velocity rocks. From the rate of deposition of Cenozoic rocks in Mono Basin based on the age and depth of burial of the Bishop Tuff, it was estimated that Mono Basin began to subside in early or middle Pliocene time.

California↗

Natural offshore oil seepage and related tarball accumulation on the California coastline — Santa Barbara Channel and the southern Santa Maria Basin; source identification and inventory

Oil spillage from natural sources is very common in the waters of southern California. Active oil extraction and shipping is occurring concurrently within the region and it is of great interest to resource managers to be able to distinguish between natural seepage and anthropogenic oil spillage. The major goal of this study was to establish the geologic setting, sources, and ultimate dispersal of natural oil seeps in the offshore southern Santa Maria Basin and Santa Barbara Basins. Our surveys focused on likely areas of hydrocarbon seepage that are known to occur between Point Arguello and Ventura, California. Our approach was to 1) document the locations and geochemically fingerprint natural seep oils or tar; 2) geochemically fingerprint coastal tar residues and potential tar sources in this region, both onshore and offshore; 3) establish chemical correlations between offshore active seeps and coastal residues thus linking seep sources to oil residues; 4) measure the rate of natural seepage of individual seeps and attempt to assess regional natural oil and gas seepage rates; and 5) interpret the petroleum system history for the natural seeps. To document the location of sub-sea oil seeps, we first looked into previous studies within and near our survey area. We measured the concentration of methane gas in the water column in areas of reported seepage and found numerous gas plumes and measured high concentrations of methane in the water column. The result of this work showed that the seeps were widely distributed between Point Conception east to the vicinity of Coal Oil Point, and that they by in large occur within the 3-mile limit of California State waters. Subsequent cruises used sidescan and high resolution seismic to map the seafloor, from just south of Point Arguello, east to near Gaviota, California. The results of the methane survey guided the exploration of the area west of Point Conception east to Gaviota using a combination of seismic instruments. The seafloor was mapped by sidescan sonar, and numerous lines of high -resolution seismic surveys were conducted over areas of interest. Biomarker and stable carbon isotope ratios were used to infer the age, lithology, organic matter input, and depositional environment of the source rocks for 388 samples of produced crude oil, seep oil, and tarballs mainly from coastal California. These samples were used to construct a chemometric fingerprint (multivariate statistics) decision tree to classify 288 additional samples, including tarballs of unknown origin collected from Monterey and San Mateo County beaches after a storm in early 2007. A subset of 9 of 23 active offshore platform oils and one inactive platform oil representing a few oil reservoirs from the western Santa Barbara Channel were used in this analysis, and thus this model is not comprehensive and the findings are not conclusive. The platform oils included in this study are from west to east: Irene, Hildago, Harvest, Hermosa, Heritage, Harmony, Hondo, Holly, Platform A, and Hilda (now removed). The results identify three “tribes” of 13 C-rich oil samples inferred to originate from thermally mature equivalents of the clayey-siliceous, carbonaceous marl, and lower calcareous-siliceous members of the Monterey Formation. Tribe 1 contains four oil families having geochemical traits of clay-rich marine shale source rock deposited under suboxic conditions with substantial higher-plant input. Tribe 2 contains four oil families with intermediate traits, except for abundant 28,30-bisnorhopane, indicating suboxic to anoxic marine marl source rock with hemipelagic input. Tribe 3 contains five oil families with traits of distal marine carbonate source rock deposited under anoxic conditions with pelagic but little or no higher-plant input. Tribes 1 and 2 occur mainly south of Point Conception in paleogeographic settings where deep burial of the Monterey Formation source rock favored generation from all three members or their equivalents. In this area, oil from the clayey-siliceous and carbonaceous marl members (Tribes 1 and 2) may overwhelm that from the lower calcareous-siliceous member (Tribe 3) because the latter is thinner and less oil-prone than the overlying members. Tribe 3 occurs mainly north of Point Conception, where shallow burial caused preferential generation from the underlying lower calcareous-siliceous member or another unit with similar characteristics. It is very desirable to be able to clearly distinguish the naturally occurring seep oils from the anthropogenically derived platform oils. Within the “training set” of oils and tars (388 samples), the biomarker parameters are sometimes sufficient to allow unique discrimination of individual platform oils. More often however, platform samples and seep samples with sources geographically close to each other are too similar to each other, with respect to the biomarker parameters, to definitively differentiate them on that basis alone. In some cases other parameters can be helpful. These other parameters are related to the degree of biogeochemical degradation or weathering that the oils or tars have experienced. These components include the typical oil distribution of n-alkane hydrocarbons and isoprenoids pristane and phytane. All of the platform oils in our sample set contain these components. On the other hand, the seep oils or tars have been exposed to significant biodegradation while in the near subsurface. The majority, but not all of seep oils or tars have been biodegraded up to or beyond the loss of n-alkanes and isoprenoids. Seep oils found in the vicinity of Coal Oil Point or Arroyo Burro are apparently the least weathered and are particularly likely to retain significant n-alkanes and isoprenoids. Therefore the combination of chemometric fingerprinting and the presence or absence of n-alkanes and isoprenoids help to differentiate anthropogenic production oils versus natural seeps oils and tars. The differentiation is not always definitive because of the close chemical similarity of some samples and the variability in the biodegradation progression. This is the case near Coal Oil Point, and near Platform A (Dos Cuadros Field) where seep oils and Platform Holly and Platform A oils are genetically very similar and cannot be definitively distinguished after a period of a few days of weathering. In contrast, oils from the Point Conception platforms can be distinguished on the basis of chemometric fingerprinting alone. In the middle of this spectrum are oils from Platforms Harmony, Heritage, and Hondo, where it is expected that oil weathering would take on the order of two weeks to a month to produce tarballs similar to those seen near Point Conception. In this case there is a much greater degree of weathering needed to proceed from produced oil to the biodegraded tar characteristic of tarball stranded on the beach. Tar deposition on beaches was monitored as part of cooperative with the County of Santa Barbara Energy Division and the U.S. Geological Survey during 2001-2003. We found tar deposition varies on a seasonal basis. In general, tarballs accumulate at a faster rate or remain longer on all beaches during the summer and fall months. The reasons for this are unclear based on our limited observations, however we speculate that factors such as prevailing winds and currents combined with more quiescent wave conditions favors the accumulation and preservation of tarballs on the beach during the summer and fall months. In contrast, winter storms, with much greater wave action remove beach sand and other materials, and stormy seas tend to break up oil that might weather into tarballs. Natural seepage is affected by the spring/neap tidal cycle; however, the link to tar deposition is unclear. Longer periods of monitoring are needed to address the variability in the data and provide a more robust statistical analysis.

California↗

Cores from marine geologic features in the western Gulf of Maine

Submerged geologic features located in the western Gulf of Maine between Cape Ann, Massachusetts and New Hampshire (fig. 1), were identified from high-resolution seismic-reflection data collected between 1979 and 1980. The features include the following. (1) A pair of end morained formed during the retreat of the Laurentide Ice Sheet from the Gulf of Maine (Oldale, 1985a). (2) A barrier spit and lagoon complex and (3) a paleodelta, both of which formed during a late Wisconsinan to early Holocene low relative sea-level stand (Oldale and others, 1983; Oldale, 1985b). (4) A wave-cut unconformity that was eroded as the sea transgressed to its present position. (5) A surficial sand depost that formed atop the unconformity in middle Holocene time. Vibracores (fig. 2) were taken in 1984 to corroborate the interpretations from the seismic data, to determine the sedimentary texture and structure of the features, to identify the nature of the unconformity, and to obtain material for 14 C dating,

Maine↗

Vertical profiles of streambed hydraulic conductivity determined using slug tests in central and western Nebraska

Many issues of water-resources management rely on modeling of ground-water/surfacewater interactions, and streambed hydraulic conductivity is a key parameter controlling the water fluxes across the stream/aquifer interface. However, in central and western Nebraska, this parameter is generally undefined. The U.S. Geological Survey, in cooperation with the Nebraska Platte River Cooperative Hydrology Study Group, performed slug tests at 15 stream sites in the Platte, Republican, and Little Blue River watersheds to determine the hydraulic conductivity of streambeds in central and western Nebraska. Slug tests were completed at several discrete depth intervals using pneumatic or mechanical methods, and the water-level response was monitored on site using a pressure transducer and laptop computer. Responses were analyzed using either the Bouwer and Rice or Springer and Gelhar methods. Vertical profiles of hydraulic conductivity with depth were developed and were compared to available information on lithology. The profiles and corresponding lithology showed that different types of streambeds were tested and suggested that some streambeds display a large variability in hydraulic conductivity with depth. In some cases, hydraulic conductivity values associated with nonstreambed materials could be identified from nearby lithologic descriptions. Seven of 15 sites had streambed values that ranged over more than 3 orders of magnitude, and that variability increased significantly when the measurements considered to be from nonstreambed materials were included. Streambed profiles from the Platte and South Platte River sites generally were more homogeneous and of larger hydraulic conductivity than the other sites. No restrictive layers were detected at any of the streambed sites on the main stems or the flood plains of the main stems of their respective watersheds. Alternatively, the profiles characterized by a restrictive streambed layer at some depth below the streambed surface were all from tributary sites out of the main-stem flood plain. These profiles can be used to represent the streambed hydraulic conductivity in central and western Nebraska in various applications, including modeling ground-water/surfacewater interactions.

Nebraska↗

Hydrogeologic characteristics of four public drinking-water supply springs in northern Arkansas

In October 2000, a study was undertaken by the U.S. Geological Survey (USGS) in cooperation with the Arkansas Department of Health to determine the hydrogeologic characteristics, including the extent of the recharge areas, for Hughes Spring, Stark Spring, Evening Shade Spring, and Roaring Spring, which are used for public-water supply in northern Arkansas. Information pertaining to each spring can be used to enable development of effective management plans to protect these water resources and public health. An integrated approach to determine the ground-water characteristics and the extent of the local recharge areas of the four springs incorporated tools and methods of hydrology, structural geology, geomorphology, geophysics, and geochemistry. Analyses of discharge, temperature, and water quality were completed to describe ground-water flow characteristics, source-water characteristics, and connectivity of the ground-water system with surface runoff. Water-level contour maps were constructed to determine ground-water flow directions and ground-water tracer tests were conducted to determine the extent of the recharge areas and ground-water flow velocities. Hughes Spring supplies water for the city of Marshall, Arkansas, and the surrounding area. The mean annual discharge for Hughes Spring was 2.9 and 5.2 cubic feet per second for water years 2001 and 2002, respectively. Recharge to the spring occurs mainly from the Boone Formation (Springfield Plateau aquifer). Ground-water tracer tests indicate the recharge area for Hughes Spring generally coincides with the surface drainage area (15.8 square miles) and that Hughes Spring is connected directly to the surface flow in Brush Creek. The geochemistry of Hughes Spring demonstrated variations with flow conditions and the influence of surface-runoff in the recharge area. Calcite saturation indices, total dissolved solids concentrations, and hardness demonstrate noticeable differences with flow conditions reflecting the reduced residence time and interaction of water with the source rock within the ground-water system at higher discharges for Hughes Spring. Concentrations of fecal indicator bacteria also demonstrated a substantial increase during high-flow conditions, suggesting that a non-point source of bacteria possibly from livestock may enter the system. Conversely, nutrient concentrations did not vary with flow and were similar to concentrations reported for undeveloped sites in the Springfield Plateau and Ozark aquifers in northern Arkansas and southern Missouri. Deuterium and oxygen-18 data show that the Hughes Spring discharge is representative of direct precipitation and not influenced by water enriched in oxygen-18 through evaporation. Discharge data show that Hughes Spring is dominated by conduit type ground-water flow, but a considerable component of diffuse flow also exists in the ground-water system. Carbon-13 data indicate a substantial component of the recharge water interacts with the surface material (soil and regolith) in the recharge area before entering the ground-water system for Hughes Spring. Tritium data for Hughes Spring indicate that the discharge water is a mixture of recent recharge and sub-modern water (recharged prior to 1952). Stark Spring supplies water for the city of Cushman, Arkansas, and the surrounding area. 2 Hydrogeologic Characteristics of Four Public Drinking-Water Supply Springs in Northern Arkansas The mean annual discharge for Stark Spring was 0.5 and 1.5 cubic feet per second for water years 2001 and 2002, respectively. The discharge and water-quality data show the ground-water system for Stark Spring is dominated by rapid recharge from surface runoff and mainly consists of a conduit- type flow system with little diffuse-type flow. Analyses of discharge data show that the estimated recharge area (0.79 square mile) is larger than the surface drainage area (0.34 square mile). Ground-water tracer tests and the outcrop of the

Water-Resources Investigations Report↗

Bounded fractional diffusion in geological media: Definition and Lagrangian approximation

Spatiotemporal Fractional-Derivative Models (FDMs) have been increasingly used to simulate non-Fickian diffusion, but methods have not been available to define boundary conditions for FDMs in bounded domains. This study defines boundary conditions and then develops a Lagrangian solver to approximate bounded, one-dimensional fractional diffusion. Both the zero-value and non-zero-value Dirichlet, Neumann, and mixed Robin boundary conditions are defined, where the sign of Riemann-Liouville fractional derivative (capturing non-zero-value spatial-nonlocal boundary conditions with directional super-diffusion) remains consistent with the sign of the fractional-diffusive flux term in the FDMs. New Lagrangian schemes are then proposed to track solute particles moving in bounded domains, where the solutions are checked against analytical or Eularian solutions available for simplified FDMs. Numerical experiments show that the particle-tracking algorithm for non-Fickian diffusion differs from Fickian diffusion in relocating the particle position around the reflective boundary, likely due to the non-local and non-symmetric fractional diffusion. For a non-zero-value Neumann or Robin boundary, a source cell with a reflective face can be applied to define the release rate of random-walking particles at the specified flux boundary. Mathematical definitions of physically meaningful nonlocal boundaries combined with bounded Lagrangian solvers in this study may provide the only viable techniques at present to quantify the impact of boundaries on anomalous diffusion, expanding the applicability of FDMs from infinite do mains to those with any size and boundary conditions.

Water Resources Research↗

Compression-cuticle relationship of seed ferns: Insights from liquid-solid states FTIR (Late Palaeozoic-Early Mesozoic, Canada-Spain-Argentina)

Cuticles have been macerated from suitably preserved compressed fossil foliage by Schulze's process for the past 150 years, whereas the physical-biochemical relationship between the "coalified layer" with preserved cuticle as a unit has hardly been investigated, although they provide complementary information. This relationship is conceptualized by an analogue model of the anatomy of an extant leaf: "vitrinite (mesophyll) + cuticle (biomacropolymer) = compression". Alkaline solutions from Schulze's process as a proxy for the vitrinite, are studied by means of liquid-solid states Fourier transform infrared spectroscopy (FTIR). In addition, cuticle-free coalified layers and fossilized cuticles of seed ferns mainly from Canada, Spain and Argentina of Late Pennsylvanian-Late Triassic age are included in the study sample. Infrared data of cuticle and alkaline solutions differ which is primarily contingent on the mesophyll +biomacropolymer characteristics. The compression records two pathways of organic matter transformation. One is the vitrinized component that reflects the diagenetic-post-diagenetic coalification history parallel with the evolution of the associated coal seam. The other is the cuticle that reflects the sum-total of evolutionary pathway of the biomacropolymer, its monomeric, or polymeric fragmentation, though factors promoting preservation include entombing clay minerals and lower pH conditions. Caution is advised when interpreting liquid-state-based FTIR data, as some IR signals may have resulted from the interaction of Schulze's process with the cuticular biochemistry. A biochemical-study course for taphonomy is suggested, as fossilized cuticles, cuticle-free coalified layers, and compressions are responses to shared physicogeochemical factors. ?? 2009 Elsevier B.V. All rights reserved.

International Journal of Coal Geology↗

Basin geometry and cumulative offsets in the Eastern Transverse Ranges, southern California: Implications for transrotational deformation along the San Andreas fault system

The Eastern Transverse Ranges, adjacent to and southeast of the big left bend of the San Andreas fault, southern California, form a crustal block that has rotated clockwise in response to dextral shear within the San Andreas system. Previous studies have indicated a discrepancy between the measured magnitudes of left slip on through-going east-striking fault zones of the Eastern Transverse Ranges and those predicted by simple geometric models using paleomagnetically determined clockwise rotations of basalts distributed along the faults. To assess the magnitude and source of this discrepancy, we apply new gravity and magnetic data in combination with geologic data to better constrain cumulative fault offsets and to define basin structure for the block between the Pinto Mountain and Chiriaco fault zones. Estimates of offset from using the length of pull-apart basins developed within left-stepping strands of the sinistral faults are consistent with those derived by matching offset magnetic anomalies and bedrock patterns, indicating a cumulative offset of at most ???40 km. The upper limit of displacements constrained by the geophysical and geologic data overlaps with the lower limit of those predicted at the 95% confidence level by models of conservative slip located on margins of rigid rotating blocks and the clockwise rotation of the paleomagnetic vectors. Any discrepancy is likely resolved by internal deformation within the blocks, such as intense deformation adjacent to the San Andreas fault (that can account for the absence of basins there as predicted by rigid-block models) and linkage via subsidiary faults between the main faults. ?? 2009 Geological Society of America.

Geosphere↗

Channel migration of the White River in the eastern Uinta Basin, Utah and Colorado

The White River is the largest stream in the southeastern part of the Uinta Basin in Utah and Colorado. This map shows the changes that have occurred in the location of the main channel of the river from 1936 to 1974. The map indicated that certain reaches of the river are subject to different rates of channel migration. Also shown is the boundary of the flood plain, which is mapped at the point of abrupt break in slope. This map documents the position of the river channel prior to any withdrawals of water or alteration of the flow characteristics of the white river that may occur in order to meet water requirements principally associated with the proposed oil-shale industry or other development in the area. The channel locations were determined from aerial photographs taken at four different time periods for the following Federal agencies: In 1936, U.S. Soil Conservation Services; 1953, U.S. Corps of Engineers; 1965, U.S. Geological Survey; and in 1974, U.S. Bureau of Land Management. The 1936 delineation, which is actually based upon photographs that were taken in 1936 and 1937, was made by projection of the original photographs on a base map that was prepared from 1:24,000 scale topographic maps. The 1953, 1965, and 1974 delineations were produced from stereographic models. The 1965 delineation was compiled from photographs that were taken during 1962-65. The delineation is labeled as 1965 for simplicity, however, because the photographs for 1965 cover about 60 percent of the study read of the river, and because no changed were discernable in those areas of repetitive photographic coverage.

Colorado, Utah↗

Ground-water/surface-water relations along Honey Creek, Washtenaw County, Michigan, 2003

The U.S. Geological Survey (USGS), in cooperation with the city of Ann Arbor, Mich., investigated the ground-water/ surface-water relations along the lower reaches of Honey Creek, Washtenaw County, Mich., and an unnamed tributary to Honey Creek (the discharge tributary) from June through October 2003. Streamflow in these reaches was artificially high during a naturally low-flow period due to an anthropogenic discharge. Ground-water/surface-water relations were examined by seepage runs (series of streamflow measurements for the computation of streams gains or losses) and measurements of the difference in head between the stream surface and shallow aquifer. Specific conductance and water-temperature measurements were used as ancillary data to help identify gaining and losing reaches. Three seepage runs and four runs in which hydraulic-head differences between the stream and shallow aquifer were measured (piezometer runs) were made during periods of base flow. Streamflow measurements were made at 18 sites for the seepage runs. Instream piezometers were installed at 16 sites and bank piezometers were installed at 2 sites. Two deeper instream piezometers were installed at site 13 on September 4, 2003 to collect additional data on the ground-water/surface-water relations at that site. The seepage runs indicate that the main stem of Honey Creek and the discharge tributary in the study area are overall gaining reaches. The seepage runs also indicate that smaller reaches of Honey Creek and the discharge tributary may be losing reaches and that this relation may change over time with changing hydraulic conditions. The piezometer-run measurements support the seepage-run results on the main stem, whereas piezometer-run measurements both support and conflict with seepage-run measurements on the discharge tributary. Seepage runs give an average for the reach, whereas piezometer head-difference measurements are for a specific area around the piezometer. Data that may appear to be conflicting actually may be showing that within a gaining reach there are localized areas that lose streamflow. The overall gain in streamflow along with specific measurements of head differences, specific conductance, and water temperature indicate that ground water is discharging to Honey Creek and the discharge tributary. Although reaches and areas that lose streamflow have been identified, data collected during this study cannot confirm or disprove that the loss is to the regional ground-water system.

Michigan↗

Hydrologic, water-quality, and biological characteristics of the North Fork Flathead River, Montana, water years 2007-2008

In water year 2007, the U.S. Geological Survey, in cooperation with the National Park Service, began a 2-year study to collect hydrologic, water-quality, and biological data to provide a baseline characterization of the North Fork Flathead River from the United States-Canada border to its confluence with the Middle Fork of the Flathead River near Columbia Falls, Montana. Although mining in the Canadian portion of the North Fork Basin was banned in 2010 by a Memorandum of Understanding issued by the Province of British Columbia, baseline characterization was deemed important for the evaluation of any potential future changes in hydrology, water quality, or aquatic biology in the basin. The North Fork Basin above Columbia Falls (including Canada) drains an area of 1,564 square miles, and the study area encompasses the portion of the basin in Montana, which is 1,126 square miles. Seasonal patterns in the hydrology of the North Fork are dominated by the accumulation and melting of seasonal snowpack in the basin. Low-flow conditions occurred during the late-summer, fall, and winter months, and high-flow conditions coincided with the spring snowmelt. Substantial gains in streamflow occurred along the study reach of the North Fork, 85 percent of which were accounted for by tributary inflows during low-flow conditions, indicating unmeasured streamflow inputs along the main stem were 15 percent or less.

Montana↗

Diagenetic alteration of impact spherules in the Neoarchean Monteville layer, South Africa

Intercontinental correlation of distal Archean impact ejecta layers can be used to help create a global time-stratigraphic framework for early Earth events. For example, an impact spherule layer in the Neoarchean Monteville Formation (Griqualand West Basin, South Africa) may be correlated with layers in one or more formations in Western Australia. To help assess the degree to which diagenetic alteration would hinder such correlations, we performed a petrographic study of spherules in the Monteville layer. Most of the spherules in the Monteville layer have botryoidal rims composed of radial-fibrous K-feldspar, but compaction and replacement have greatly altered their appearance and mineralogy. Moreover, the Monteville spherule layer consists of three main subunits, and spherule compaction varies between subunits as well as across the Griqualand West region. Compaction is about three times greater in a medial spherulerich subunit as compared to a basal subunit rich in large intraclasts, resulting in better preservation of the shapes of melt particles in the latter. However, spherule rims have omparable numbers of fractures in both subunits, indicating the melt particles were fractured prior to compaction. Some spherules contain mica ribbons with a septarian geometry. Fracturing via rapid thermal quenching could help explain all of these features. f hot spherules possessing crystalline rims were thermally shocked when they hit the ocean, fractures would have the observed geometries and provide pathways for fluid infiltration and local replacement of glass by mica. Although heavily distorted, impact spherules in the Monteville layer are very similar to those in the Hesta occurrence of the Neoarchean Jeerinah spherule layer of the Hamersley Basin, even showing similar diagenetic histories. In this instance, diagenetic alteration may actually help rather than hinder intercontinental correlation of impact spherule layers. ??2006 Geological Society of America.

Special Paper of the Geological Society of America↗

Water resources of Carbon County, Wyoming

Carbon County is located in the south-central part of Wyoming and is the third largest county in the State. A study to describe the physical and chemical characteristics of surface-water and ground-water resources in Carbon County was conducted by the U.S. Geological Survey in cooperation with the Wyoming State Engineer's Office. Evaluations of streamflow and stream-water quality were limited to analyses of historical data and descriptions of previous investigations. Surface-water data were not collected as part of the study. Forty-five ground-water-quality samples were collected as part of the study and the results from an additional 618 historical ground-water-quality samples were reviewed. Available hydrogeologic characteristics for various aquifers in hydrogeologic units throughout the county also are described. Flow characteristics of streams in Carbon County vary substantially depending on regional and local basin char-acteristics and anthropogenic factors. Precipitation in the county is variable with high mountainous areas receiving several times the annual precipitation of basin lowland areas. For this reason, streams with headwaters in mountainous areas generally are perennial, whereas most streams in the county with headwaters in basin lowland areas are ephemeral, flowing only as a result of regional or local rainfall or snowmelt runoff. Flow characteristics of most perennial streams are altered substantially by diversions and regulation. Water-quality characteristics of selected streams in and near Carbon County during water years 1966 through 1986 varied. Concentrations of dissolved constituents and suspended sediment were smallest at sites on streams with headwaters in mountainous areas because of resistant geologic units, large diluting streamflows, and increased vegetative cover compared to sites on streams with headwaters in basin lowlands. Both water-table and artesian conditions occur in aquifers within the county. Shallow ground water is available throughout the county, although much of it is only marginally suitable or is unsuitable for domestic and irrigation uses mainly because of high total dissolved solids (TDS) concentrations. Suitable ground water for livestock use is available in most areas of the county. Ground-water quality tends to deteriorate with increasing distance from recharge areas and with increasing depth below land surface. Ground water from depths greater than a few thousand feet tends to have TDS concentrations that make it moderately saline to briny. In some areas, even shallow ground water is moderately saline. Specific constituents in parts of some aquifers in the county occur in relatively high concentrations when compared to U.S. Environmental Protection Agency drinking-water standards; for example, relatively high concentrations of sulfate, chloride, fluoride, boron, iron, manganese, and radon were found in several aquifers. The estimated mean daily water use in Carbon County in 2000 was about 320 million gallons per day. Water used for irrigation accounted for about 98 percent of this total. About 98 percent of the total water used was supplied by surface water and about 2 percent by ground water. Excluding irrigation, ground water comprised about 78 percent of total water use in Carbon County. Although ground water is used to a much lesser extent than surface water, in many areas of the county it is the only available water source.

Scientific Investigations Report↗