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USGS2009

Exploratory and spatial data analysis (EDA-SDA) for determining regional background levels and anomalies of potentially toxic elements in soils from Catorce-Matehuala, Mexico

The threshold between geochemical background and anomalies can be influenced by the methodology selected for its estimation. Environmental evaluations, particularly those conducted in mineralized areas, must consider this when trying to determinate the natural geochemical status of a study area, quantifying human impacts, or establishing soil restoration values for contaminated sites. Some methods in environmental geochemistry incorporate the premise that anomalies (natural or anthropogenic) and background data are characterized by their own probabilistic distributions. One of these methods uses exploratory data analysis (EDA) on regional geochemical data sets coupled with a geographic information system (GIS) to spatially understand the processes that influence the geochemical landscape in a technique that can be called a spatial data analysis (SDA). This EDA-SDA methodology was used to establish the regional background range from the area of Catorce-Matehuala in north-central Mexico. Probability plots of the data, particularly for those areas affected by human activities, show that the regional geochemical background population is composed of smaller subpopulations associated with factors such as soil type and parent material. This paper demonstrates that the EDA-SDA method offers more certainty in defining thresholds between geochemical background and anomaly than a numeric technique, making it a useful tool for regional geochemical landscape analysis and environmental geochemistry studies.

Applied Geochemistry↗

USGS1989

An analysis of trichloroethylene movement in groundwater at Castle Air Force Base, California

A trichloroethylene (TCE) plume has been identified in the groundwater under a U.S. Air Force Base in the Central Valley of California. An areal, two-dimensional numerical solute transport model indicates that the movement of TCE due to advection, dispersion, and linear sorption is simulated over a 25-year historic period. The model is used in several ways: (1) to estimate the extent of the plume; (2) to confirm the likely sources of contamination as suggested by a soil organic vapor survey of the site; and (3) to make predictions about future movement of the plume. Despite the noisy and incomplete data set, the model reproduces the general trends in contamination at a number of observation wells. The analysis indicates that soil organic vapor monitoring is an effective tool for identifying contaminant source locations. Leaky sewer pipes and underground tanks are the indicated pathways for TCE to have entered the groundwater system. The chemical mass balance indicates that a total of about 100 gallons of TCE - a relatively small amount of organic solvent - has created the observed groundwater plume.

California↗

USGS2019

Aluminum mobility in mildly acidic mine drainage: Interactions between hydrobasaluminite, silica and trace metals from the nano to the meso-scale

Aluminum precipitates control the hydrochemistry and mineralogy of a broad variety of environments on Earth (e.g., acid mine drainage, AMD, coastal wetlands, boreal and alpine streams, tropical acid sulfate soils, laterites and bauxites, …). However, the geochemical and mineralogical processes controlling Al (and other associated metals and metalloids) transport and removal in those environments are not fully understood. The geochemical system of Paradise Portal (Colorado, USA) comprises sulfate-rich mildly acidic waters, the hydrochemistry of which is directly controlled by the massive precipitation of hydrobasaluminite Al 4 (SO 4 )(OH) 10 ·12-36H 2 O. Three connected but discernible aluminum precipitation stages were identified and described: 1) nanoparticle formation and size decrease along the creek, 2) hydrobasaluminite neoformation on the riverbed, and 3) precipitate accretion and accumulation on the riverbed leading to Al and Fe banded formations. The co-occurrence of Al and Si in the system was observed, recording significant amounts of Si accompanying the three different components of the system (i.e., nanoparticles and fresh and aged Al-precipitates). Also, abrupt and minor changes in the sedimentary record were described and proposed to be the response of the system to seasonal and interannual changes in AMD chemistry. Concerning the mobility of other metals and metalloids, P, Th, V, W, Ti and B showed a tendency to be preferentially incorporated into hydrobasaluminite, while others like Be, As, Se or Ba tend to remain dissolved in the water.

Chemical Geology↗

USGS2003

A hydrologic network supporting spatially referenced regression modeling in the Chesapeake Bay watershed

The U.S. Geological Survey has developed a methodology for statistically relating nutrient sources and land-surface characteristics to nutrient loads of streams. The methodology is referred to as SPAtially Referenced Regressions On Watershed attributes (SPARROW), and relates measured stream nutrient loads to nutrient sources using nonlinear statistical regression models. A spatially detailed digital hydrologic network of stream reaches, stream-reach characteristics such as mean streamflow, water velocity, reach length, and travel time, and their associated watersheds supports the regression models. This network serves as the primary framework for spatially referencing potential nutrient source information such as atmospheric deposition, septic systems, point-sources, land use, land cover, and agricultural sources and land-surface characteristics such as land use, land cover, average-annual precipitation and temperature, slope, and soil permeability. In the Chesapeake Bay watershed that covers parts of Delaware, Maryland, Pennsylvania, New York, Virginia, West Virginia, and Washington D.C., SPARROW was used to generate models estimating loads of total nitrogen and total phosphorus representing 1987 and 1992 land-surface conditions. The 1987 models used a hydrologic network derived from an enhanced version of the U.S. Environmental Protection Agency's digital River Reach File, and course resolution Digital Elevation Models (DEMs). A new hydrologic network was created to support the 1992 models by generating stream reaches representing surface-water pathways defined by flow direction and flow accumulation algorithms from higher resolution DEMs. On a reach-by-reach basis, stream reach characteristics essential to the modeling were transferred to the newly generated pathways or reaches from the enhanced River Reach File used to support the 1987 models. To complete the new network, watersheds for each reach were generated using the direction of surface-water flow derived from the DEMs. This network improves upon existing digital stream data by increasing the level of spatial detail and providing consistency between the reach locations and topography. The hydrologic network also aids in illustrating the spatial patterns of predicted nutrient loads and sources contributed locally to each stream, and the percentages of nutrient load that reach Chesapeake Bay.

Environmental Monitoring and Assessment↗

USGS2009

Removal of organic wastewater contaminants in septic systems using advanced treatment technologies

The detection of pharmaceuticals and other organic wastewater contaminants (OWCs) in ground water and surface-water bodies has raised concerns about the possible ecological impacts of these compounds on nontarget organisms. On-site wastewater treatment systems represent a potentially significant route of entry for organic contaminants to the environment. In this study, effluent samples were collected and analyzed from conventional septic systems and from systems using advanced treatment technologies. Six of 13 target compounds were detected in effluent from at least one septic system. Caffeine, paraxanthine, and acetaminophen were the most frequently detected compounds, and estrogenic activity was detected in 14 of 15 systems. The OWC concentrations were significantly lower in effluent after sand filtration (p < 0.01) or aerobic treatment (p < 0.05) as compared with effluent that had not undergone advanced treatment. In general, concentrations in conventional systems were comparable to those measured in previous studies of municipal wastewater treatment plant (WWTP) influent, and concentrations in systems after advanced treatment were comparable to previously measured concentrations in WWTP effluent. These data indicate that septic systems using advanced treatment can reduce OWCs in treated effluent to similar concentrations as municipal WWTPs. Copyright ?? 2009 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America. All rights reserved.

Journal of Environmental Quality↗

USGS2008

Technical Manual for the Geospatial Stream Flow Model (GeoSFM)

The monitoring of wide-area hydrologic events requires the use of geospatial and time series data available in near-real time. These data sets must be manipulated into information products that speak to the location and magnitude of the event. Scientists at the U.S. Geological Survey Earth Resources Observation and Science (USGS EROS) Center have implemented a hydrologic modeling system which consists of an operational data processing system and the Geospatial Stream Flow Model (GeoSFM). The data processing system generates daily forcing evapotranspiration and precipitation data from various remotely sensed and ground-based data sources. To allow for rapid implementation in data scarce environments, widely available terrain, soil, and land cover data sets are used for model setup and initial parameter estimation. GeoSFM performs geospatial preprocessing and postprocessing tasks as well as hydrologic modeling tasks within an ArcView GIS environment. The integration of GIS routines and time series processing routines is achieved seamlessly through the use of dynamically linked libraries (DLLs) embedded within Avenue scripts. GeoSFM is run operationally to identify and map wide-area streamflow anomalies. Daily model results including daily streamflow and soil water maps are disseminated through Internet map servers, flood hazard bulletins and other media.

Open-File Report↗

USGS2008

Water-quality effects and characterization of indicators of onsite wastewater disposal systems in the east-central Black Hills area, South Dakota, 2006-08

Onsite wastewater disposal systems (OWDS) are used extensively in the Black Hills of South Dakota where many of the watersheds and aquifers are characterized by fractured or solution-enhanced bedrock with thin soil cover. A study was conducted during 2006-08 to characterize water-quality effects and indicators of OWDS. Water samples were collected and analyzed for potential indicators of OWDS, including chloride, bromide, boron, nitrite plus nitrate (NO2+NO3), ammonia, major ions, nutrients, selected trace elements, isotopes of nitrate, microbiological indicators, and organic wastewater compounds (OWCs). The microbiological indicators were fecal coliforms, Escherichia coli (E. coli), enterococci, Clostridium perfringens (C. perfringens), and coliphages. Sixty ground-water sampling sites were located either downgradient from areas of dense OWDS or in background areas and included 25 monitoring wells, 34 private wells, and 1 spring. Nine surface-water sampling sites were located on selected streams and tributaries either downstream or upstream from residential development within the Precambrian setting. Sampling results were grouped by their hydrogeologic setting: alluvial, Spearfish, Minnekahta, and Precambrian. Mean downgradient dissolved NO2+NO3 concentrations in ground water for the alluvial, Spearfish, Minnekahta, and Precambrian settings were 0.734, 7.90, 8.62, and 2.25 milligrams per liter (mg/L), respectively. Mean downgradient dissolved chloride concentrations in ground water for these settings were 324, 89.6, 498, and 33.2 mg/L, respectively. Mean downgradient dissolved boron concentrations in ground water for these settings were 736, 53, 64, and 43 micrograms per liter (ug/L), respectively. Mean dissolved surface-water concentrations for NO2+NO3, chloride, and boron for downstream sites were 0.222 mg/L, 32.1 mg/L, and 28 ug/L, respectively. Mean values of delta-15N and delta-18O (isotope ratios of 14N to 15N and 18O to 16O relative to standard ratios) for nitrate in ground-water samples were 10.4 and -2.0 per mil (0/100), respectively, indicating a relatively small contribution from synthetic fertilizer and probably a substantial contribution from OWDS. The surface-water sample with the highest dissolved NO2+NO3 concentration of 1.6 mg/L had a delta-15N value of 12.36 0/100, which indicates warm-blooded animals (including humans) as the nitrate source. Fecal coliforms were detected in downgradient ground water most frequently in the Spearfish (19 percent) and Minnekahta (9.7 percent) settings. E. coli was detected most frequently in the Minnekahta (29 percent) and Spearfish (13 percent) settings. Enterococci were detected more frequently than other microbiological indicators in all four settings. Fecal coliforms and E. coli were detected in 73 percent and 95 percent of all surface-water samples, respectively. Enterococci, coliphages (somatic), and C. perfringens were detected in 50, 70, and 50 percent of surface-water samples, respectively. Of the 62 OWC analytes, 12 were detected only in environmental samples, 10 were detected in at least one environmental and one blank sample (not necessarily companion pairs), 2 were detected only in blank samples, and 38 were not detected in any blank, environmental, or replicate sample from either ground or surface water. Eleven different organic compounds were detected in ground-water samples at eight different sites. The most frequently occurring compound was DEET, which was found in 32 percent of the environmental samples, followed by tetrachloroethene, which was detected in 20 percent of the samples. For surface-water samples, 16 organic compounds were detected in 9 of the 10 total samples. The compound with the highest occurrence in surface-water samples was camphor, which was detected in 50 percent of samples. The alluvial setting was characterized by relatively low dissolved NO2+NO3 concentrations, detection of ammonia nitrogen, and relatively high concentr

South Dakota↗

USGS1995

Vulnerability of the uppermost ground water to contamination in the greater Denver area, Colorado

Information about vulnerability of ground water to contamination is needed to facilitate ground-water management. Vulnerability of ground water refers to the intrinsic characteristics that determine the sensitivity of the water to being adversely affected by an imposed contaminant load. Within the greater Denver area, vulnerability of the uppermost ground water to contamination from the surface was assessed by considering the intrinsic characteristics included in a method developed by the U.S. Environmental Protection Agency and the National Water Well Association, the DRASTIC method. The seven geohydrologic characteristics considered are: (1) Aquifer media, (2) hydraulic conductivity, (3) unsaturated media, (4) depth to water, (5) recharge, (6) soil media, and (7) land-surface slope. Recharge from precipitation generally is less than 2 inches per year; no effort was made to quantify the variation of recharge throughout the study area. Data for geology, depth to water, soils, and elevation were obtained and processed to produce maps of the other six characteristics. Spatial and attribute data for these maps were stored and processed by geographic-information-system software to produce a map showing vulnerability of the uppermost ground water to contamination from the surface. This report describes the assessment of each geohydrologic characteristic and the 157 vulnerability response units that were delineated within the greater Denver area. These response units are unique with respect to the geohydrologic characteristics considered. The uppermost ground water within each of the vulnerability response units are described in a series of tables, which include qualitative and selected quantitative data and the vulnerability rating assigned for each of the seven geohydrologic characteristics.

Water-Resources Investigations Report↗

USGS1996

Water Budget for the Lahaina District, Island of Maui, Hawaii

Ground-water recharge is estimated as the residual component of a monthly water budget calculated using long-term average rainfall, streamflow, irrigation, pan-evaporation data, and soil characteristics. The water-budget components are defined seasonally, through the use of monthly data, and spatially by topographic and geologic areas, through the use of a geographic information system model. The long-term average ground-water recharge for the Lahaina District was estimated for three scenarios using 1923-78 land-use and irrigation data, 1986-93 land-use and irrigation data, and natural conditions. The average annual ground-water recharge rate for 1923-78 conditions is 190 million gallons per day, which is 45 percent of the sum of rainfall and irrigation. The recharge rate for 1986-93 conditions is 163 million gallons per day, which is 42 percent of rainfall plus irrigation. The recharge rate for natural conditions is 145 million gallons per day, which is 44 percent of rainfall.

Water-Resources Investigations Report↗

USGS1981

Establishment of seeded grasslands for wildlife habitat in the prairie pothole region

Techniques are described for establishment of seeded grasslands on cultivated soils to provide wildlife habitat within the glaciated prairie pothole region in the north-central United States. Management of grassland habitats on a sound ecological basis is an important wildlife management activity in the region. The primary purpose of the guidelines in this publication is to help managers establish and maintain good stands of seeded cover for waterfowl nesting and use by other prairie wildlife. Several options are available for selecting a type of cover to be established. The following seeded grassland types are described: (1) introduced cool-season grasses and legumes; (2) tall, warm-season native grasses; and (3) mixed-grass prairie grasses. Major vegetative species recommended for (1) are tall wheatgrass (Agropyron elongatum), intermediate wheatgrass (A. intermedium), alfalfa (Medicago sativa), and sweetclover (Melilotus spp.); for (2) are big bluestem (Andropogon gerardi), indiangrass (Sorghastrum nutans), and switchgrass (Panicum virgatum); for (3) are green needlegrass (Stipa viridula), little bluestem (Andropogon scoparius), western wheatgrass (Agropyron smithii), and sideoats grama (Bouteloua curtipendula). Important factors that affect the success of establishment of seeded grasslands include site adaptability, site preparation, seedbed preparation, planting equipment and methods, rates and dates of seeding, and seed sources. A management goal for seeded grasslands intended to provide optimum habitat for dabbling duck nesting should be to maintain vigorous stands of vegetation with the tallest, most dense cover form that is possible under prevailing soil and climatic conditions. Grassland management is a never-ending job and seeded grasslands require periodic rejuvenation to maintain them in an optimum condition. Prescribed burning and planned grazing systems are acceptable methods for periodically rejuvenating seeded native grasses. Stands of introduced grasses and legumes are best maintained by mechanical tillages; reseeding is often necessary after 1 or 2 years of grain farming. The need for good management of all areas dedicated to wildlife habitat is emphasized by the rate of destruction and degradation of grassland habitats. Desirable wildlife populations can be benefited by establishment and maintenance of high-quality stands of seeded grasslands.

Prairie pothole region↗

USGS2008

A characterization of non-biotic environmental features of prairies hosting the Dakota Skipper (Hesperia dacotae, Hesperiidae) across its remaining U.S. range

Within the United States, the Dakota Skipper now occurs only in Minnesota, North Dakota, and South Dakota. In these states it has been associated with margins of glacial lakes and calcareous mesic prairies that host warm-season native grasses. Preliminary geographic information system (GIS) analysis in North Dakota has indicated a close congruency between historic distribution of the Dakota Skipper and that of specific near-shore glacial lake features and related soil associations. This study analyzed humidity-related non-biotic microhabitat characteristics within three remaining occupied Dakota Skipper sites in each state during the larval growth period in 2000. Measured parameters included topographic relief, soil compaction, soil pH, moisture, and temperature at various depths, soil bulk density, soil texture, and temperature and humidity within the larval nest zone. Results of these efforts reveal two distinctive habitat substrates, one of relatively low surface relief with dense but relatively less compact soils, and another of relatively high relief with less dense but more compact soils. In the low-relief habitat, grazing appears to compact soils unfavorably in otherwise similar prairies in the more xeric western portion of the range, potentially by affecting ground-water buffering of larval nest zone humidity.

Journal of the Lepidopterists' Society↗

USGS2009

Regional variations in water quality and relationships to soil and bedrock weathering in the southern Sacramento Valley, California, USA

Regional patterns in ground- and surface-water chemistry of the southern Sacramento Valley in California were evaluated using publicly available geochemical data from the US Geological Survey's National Water Information System (NWIS). Within the boundaries of the study area, more than 2300 ground-water analyses and more than 20,000 surface-water analyses were available. Ground-waters from the west side of the Sacramento Valley contain greater concentrations of Na, Ca, Mg, B, Cl and SO 4 , while the east-side ground-waters contain greater concentrations of silica and K. These differences result from variations in surface-water chemistry as well as from chemical reactions between water and aquifer materials. Sediments that fill the Sacramento Valley were derived from highlands to the west (the Coast Ranges) and east (the Sierra Nevada Mountains), the former having an oceanic provenance and the latter continental. These geologic differences are at least in part responsible for the observed patterns in ground-water chemistry. Thermal springs that are common along the west side of the Sacramento Valley appear to have an effect on surface-water chemistry, which in turn may affect the ground-water chemistry.

Applied Geochemistry↗

USGS2009

Indicators of biodiversity and ecosystem services: A synthesis across ecosystems and spatial scales

According to the Millennium Ecosystem Assessment, common indicators are needed to monitor the loss of biodiversity and the implications for the sustainable provision of ecosystem services. However, a variety of indicators are already being used resulting in many, mostly incompatible, monitoring systems. In order to synthesise the different indicator approaches and to detect gaps in the development of common indicator systems, we examined 531 indicators that have been reported in 617 peer-reviewed journal articles between 1997 and 2007. Special emphasis was placed on comparing indicators of biodiversity and ecosystem services across ecosystems (forests, grass- and shrublands, wetlands, rivers, lakes, soils and agro-ecosystems) and spatial scales (from patch to global scale). The application of biological indicators was found most often focused on regional and finer spatial scales with few indicators applied across ecosystem types. Abiotic indicators, such as physico-chemical parameters and measures of area and fragmentation, are most frequently used at broader (regional to continental) scales. Despite its multiple dimensions, biodiversity is usually equated with species richness only. The functional, structural and genetic components of biodiversity are poorly addressed despite their potential value across habitats and scales. Ecosystem service indicators are mostly used to estimate regulating and supporting services but generally differ between ecosystem types as they reflect ecosystem-specific services. Despite great effort to develop indicator systems over the past decade, there is still a considerable gap in the widespread use of indicators for many of the multiple components of biodiversity and ecosystem services, and a need to develop common monitoring schemes within and across habitats. Filling these gaps is a prerequisite for linking biodiversity dynamics with ecosystem service delivery and to achieving the goals of global and sub-global initiatives to halt the loss of biodiversity. ?? 2009 Oikos.

Oikos↗

USGS2011

Characterizing near-surface CO2 conditions before injection - Perspectives from a CCS project in the Illinois Basin, USA

The Midwest Geological Sequestration Consortium is conducting a large-scale carbon capture and storage (CCS) project in Decatur, Illinois, USA to demonstrate the ability of a deep saline formation to store one million tonnes of carbon dioxide (CO 2 ) from an ethanol facility. Beginning in early 2011, CO 2 will be injected at a rate of 1,000 tonnes/day for three years into the Mount Simon Sandstone at a depth of approximately 2,100 meters. An extensive Monitoring, Verification, and Accounting (MVA) program has been undertaken for the Illinois Basin Decatur Project (IBDP) and is focused on the 0.65 km2 project site. Goals include establishing baseline conditions to evaluate potential impacts from CO 2 injection, demonstrating that project activities are protective of human health and the environment, and providing an accurate accounting of stored CO 2 . MVA efforts are being conducted pre-, during, and post- CO 2 injection. Soil and net CO 2 flux monitoring has been conducted for more than one year to characterize near-surface CO 2 conditions. More than 2,200 soil CO 2 flux measurements have been manually collected from a network of 118 soil rings since June 2009. Three ring types have been evaluated to determine which type may be the most effective in detecting potential CO 2 leakage. Bare soil, shallow-depth rings were driven 8 cm into the ground and were prepared to minimize surface vegetation in and near the rings. Bare soil, deep-depth rings were prepared similarly, but were driven 46 cm. Natural-vegetation, shallow-depth rings were driven 8 cm and are most representative of typical vegetation conditions. Bare-soil, shallow-depth rings had the smallest observed mean flux (1.78 μmol m −2 s −1 ) versus natural-vegetation, shallow-depth rings (3.38 μmol m −2 s −1 ). Current data suggest bare ring types would be more sensitive to small CO 2 leak signatures than natural ring types because of higher signal to noise ratios. An eddy covariance (EC) system has been in use since June 2009. Baseline data from EC monitoring is being used to characterize pre-injection conditions, and may then be used to detect changes in net exchange CO 2 fluxes (Fc) that could be the result of CO 2 leakage into the near-surface environment during or following injection. When injection at IBDP begins, soil and net CO 2 monitoring efforts will have established a baseline of near-surface conditions that will be important to help demonstrate the effectiveness of storage activities.

Illinois↗

USGS1993

Numerical simulation of ground-water flow in the central part of the western San Joaquin Valley, California

The occurrence of selenium in agricultural drain water in the central part of the western San Joaquin Valley, California, has focused concern on strategies for managing shallow, saline ground water. To assess alternatives to agricultural drains, a three-dimensional, finite-difference numerical model of the regional groundwater flow system was developed. This report documents the mathematical approach used to model the flow system, the data base on which the model is based, and the methods used to calibrate the model. The 550-square-mile study area includes parts of the Panoche Creek alluvial fan and parts of the Little Panoche Creek and Cantua Creek alluvial fans. The model simulates transient flow in the semiconfined and confined zones above and below the Corcoran Clay Member of the Tulare Formation of Pleistocene age. The model incorporates areally distributed ground-water recharge, areally and vertically distributed pumping, regional-collector drains in the Wesdands Water District (operative from 1980 to 1985), on-farm drains in parts of the Panoche, Broadview, and Firebaugh Water Districts, and bare-soil evaporation (which occurs if the water table is within 7 feet of land surface). The model also incorporates texture-based estimates of hydraulic conductivity, where texture is defined as the fraction of coarse-grained deposits present in a given subsurface interval. The numerical model was developed using hydrologic data from 1972 to 1988. Most of the parameters incorporated into the model were evaluated independently of the model, including system geometry, the distribution of texture, the altitudes of the water table and potentiometric surface of the confined zone in 1972 (initial condition), the hydraulic conductivity of coarse-grained deposits derived from the Coast Ranges, the hydraulic conductivity of coarse-grained deposits derived from the Sierra Nevada, specific storage, recharge, pumping, and parameters needed to incorporate drains and bare-soil evaporation. Four parameters were calibration variables: the hydraulic conductivity of fine-grained deposits in the semiconfined zone, the hydraulic conductivity of the Corcoran Clay Member, specific yield, and the transmissivity of the confined zone. The model was calibrated in two phases. In the first phase, a steady-state model of the ground-water flow system in 1984 was used to constrain the relation between the hydraulic conductivity of fine-grained deposits in the semiconfined zone and the hydraulic conductivity of the Corcoran Clay Member, thus reducing the number of independent variables from four to three. In the second phase of calibration, the change in altitude of the water table from 1972 to 1984, the change in altitude of the potentiometric surface of the confined zone from 1972 to 1984, and the number of model cells subject to bare-soil evaporation from 1972 to 1988 were used to evaluate the remaining three variables. The calibrated model reproduces the average change in water-table altitude (1972-84) to within 0.4 foot (average measured change 11.5 feet) and the average change in confined zone head (1972- 84) to within 19 feet (average measured change 120 feet). The simulated time-series record of the total number of model cells subject to bare-soil evaporation (each cell is 1 mile square) is within the range of the measured data. The measured values are at a minimum in October and a maximum in July. The October values ranged from 103 in 1972 to 132 in 1984 (the drains were closed in 1985) to 151 in 1988. The July values ranged from 144 in 1973 to 198 in 1984, to 204 in 1988. The simulated values ranged from 103 in 1972 to 161 in 1984, to 208 in 1988.

Water Supply Paper↗

USGS2000

Regional evaluation of evapotranspiration in the Everglades

Nine sites in the Florida Everglades were selected and instrumented for collection of data necessary for evapotranspiration-determination using the Bowen-ratio energy-budget method. The sites were selected to represent the sawgrass or cattail marshes, wet prairie, and open-water areas that constitute most of the natural Everglades system. At each site, measurements necessary for evapotranspiration (ET) calculation and modeling were automatically made and stored on-site at 15- or 30-minute intervals. Data collected included air temperature and humidity at two heights, wind speed and direction, incoming solar radiation, net solar radiation, water level and temperature, soil moisture content, soil temperature, soil heat flux, and rainfall. Data summarized in this report were collected from January 1996 through December 1997, and the development of site-specific and regional models of ET for this period is described. Latent heat flux is the energy flux density equivalent of the ET rate. Modified Priestley-Taylor models of latent heat flux as a function of selected independent variables were developed at each site. These models were used to fill in periods of missing latent heat flux measurement, and to develop regional models of the entire Everglades region. The regional models may be used to estimate ET in wet prairie, sawgrass or cattail marsh, and open-water portions of the natural Everglades system. The models are not applicable to forested areas or to the brackish areas adjacent to Florida Bay. Two types of regional models were developed. One type of model uses measurements of available energy at a site, together with incoming solar energy and water depth, to estimate hourly ET. This available-energy model requires site data for net radiation, water heat storage, and soil heat flux, as well as data for incoming solar radiation and water depth. The other type of model requires only incoming solar energy, air temperature, and water depth data to provide estimates of hourly ET. The second model thus uses data that are more readily available than the data required for the available-energy model. Computed ET mean annual totals for all nine sites for the 1996-97 period ranged from 42.4 inches per year at a site where the water level is below land surface for several months each year to 57.4 inches per year at an open-water site with no emergent vegetation. Although the density of photosynthetically-active plant leaves has been shown to relate directly to ET in some studies, it does not appear to relate directly to ET in the Everglades, based on comparison of annual ET data with leaf-area index, defined as the Normalized Difference Vegetation Index (NDVI), data from satellite imagery. NDVI and ET appear to be inversely related in the Everglades. The greatest ET rates occurred at open-water sites where the NDVI data indicated the lowest leaf-area index. Among the remaining vegetated sites, there is no clear relation between ET and NDVI, though the highest ET rate corresponded to the lowest NDVI and one of the lowest ET rates corresponded to the highest NDVI value. The variation in ET follows a seasonal pattern, with lowest monthly ET totals occurring in December through February, and highest ET occurring in May through August. The greatest range in monthly ET among all nine sites for the 2-year period occurred at site 3: from 1.81 inches in December 1997 to 6.84 inches in July 1996. A study to compare the Bowen-ratio/energy balance method of ET measurement with the eddy-correlation method was done at one site from June 22, 1998, through September 28, 1998. This comparison indicated that both methods gave comparable values of the Bowen ratio, but there was a considerable difference in available energy measured by the two methods. The mean of all 30-minute measured turbulent heat fluxes from the eddy-correlation apparatus for June 22 through September 29, 1998, was 137.4 watts per square meter, and the mean of the corresponding measured energy was 163.6 watts per square meter, or about 20 percent greater. The disagreement in mean energy fluxes measured by the two methods is problematical and is not fully understood. Although the difference seems to be related to friction velocity, and is practically non-existent at values of friction velocity greater than 0.3 meter per second, the "correctness" of either method cannot be determined with the data available.

Florida↗

USGS2005

Managing vegetation in surface-flow wastewater-treatment wetlands for optimal treatment performance

Constructed wetlands that mimic natural marshes have been used as low-cost alternatives to conventional secondary or tertiary wastewater treatment in the U.S. for at least 30 years. However, the general level of understanding of internal treatment processes and their relation to vegetation and habitat quality has not grown in proportion to the popularity of these systems. We have studied internal processes in surface-flow constructed wastewater-treatment wetlands throughout the southwestern U.S. since 1990. At any given time, the water quality, hydraulics, water temperature, soil chemistry, available oxygen, microbial communities, macroinvertebrates, and vegetation each greatly affect the treatment capabilities of the wetland. Inside the wetland, each of these components plays a functional role and the treatment outcome depends upon how the various components interact. Vegetation plays a uniquely important role in water treatment due to the large number of functions it supports, particularly with regard to nitrogen transformations. However, it has been our experience that vegetation management is critical for achieving and sustaining optimal treatment function. Effective water treatment function and good wildlife quality within a surface-flow constructed wetland depend upon the health and sustainability of the vegetation. We suggest that an effective tool to manage and sustain healthy vegetation is the use of hummocks, which are shallow emergent plant beds within the wetland, positioned perpendicular to the water flow path and surrounded by water sufficiently deep to limit further emergent vegetation expansion. In this paper, we describe the use of a hummock configuration, in conjunction with seasonal water level fluctuations, to manage the vegetation and maintain the treatment function of wastewater-treatment wetlands on a sustainable basis.

Ecological Engineering↗

USGS1996

Quantification of natural vapor fluxes of trichloroethene in the unsaturated zone at Picatinny Arsenal, New Jersey

The upward flux of trichloroethene (TCE) vapor through the unsaturated zone above a contaminated, water-table aquifer at Picatinny Arsenal, New Jersey, has been studied under natural conditions over a 12-month period. Vertical gas-phase diffusion fluxes were estimated indirectly by measuring the TCE vapor concentration gradient in the unsaturated zone and using Fick's law to calculate the flux. The total gas-phase flux (e.g., the sum of diffusion and advection fluxes) was measured directly with a vertical flux chamber (VFC). In many cases, the upward TCE vapor flux was several orders of magnitude greater than the upward TCE diffusion flux, suggesting that mechanisms other than steady-state vapor diffusion are contributing to the vertical transport of TCE vapors through the unsaturated zone. The measured total flux of TCE vapor from the subsurface to the atmosphere is approximately 50 kg/yr and is comparable in magnitude to the removal rate of TCE from the aquifer by an existing pump-and-treat system and by discharge into a nearby stream. The net upward flux of TCE is reduced significantly during a storm event, presumably due to the mass transfer of TCE from the soil gas to the infiltrating rainwater and its subsequent downward advection. Several potential problems associated with the measurement of total gas-phase fluxes are discussed.

Environmental Science & Technology↗