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At least 793 records · Page 44Linked to original sources
USGS2005

Forms and accumulation of soil P in natural and recently restored peatlands - Upper Klamath Lake, Oregon, USA

Forms, amounts, and accumulation of soil phosphorus (P) were measured in natural and recently restored marshes surrounding Upper Klamath Lake located in south-central Oregon, USA to determine rates of P accumulation in natural marshes and to assess changes in P pools caused by long-term drainage in recently restored marshes. Soil cores were collected from three natural marshes and radiometrically dated to determine recent (l37Cs-based) and long-term (210Pb-based) rates of peat accretion and P accumulation. A second set of soil cores collected from the three natural marshes and from three recently restored marshes was analyzed using a modification of the Hedley procedure to determine the forms and amounts of soil P. Total P in the recently restored marshes (222 to 311 ??g cm-3) was 2-3 times greater than in the natural marshes (103 to 117 ??g cm-3), primarily due to greater bulk density caused by soil subsidence, a consequence of long-term marsh drainage. Occluded Fe- and Al-bound Pi, calcium-bound Pi and residual P were 4 times, 22 times, and 5 times greater, respectively, in the recently restored marshes. More than 67% of the P pool in both the natural and recently restored marshes was present in recalcitrant forms (humic-acid P o and residual P) that provide long-term P storage in peat. Phosphorus accumulation in the natural marshes averaged 0.45 g m-2 yr-1 (137Cs) and 0.40 g m-2 yr-1 (210Pb), providing a benchmark for optimizing P sequestration in the recently restored marshes. Effective P sequestration in the recently restored marshes, however, will depend on re-establishing equilibrium between the P-enriched soils and the P concentration of floodwaters and a hydrologie regime similar to the natural marshes. ?? 2005, The Society of Wetland Scientists.

Wetlands↗
USGS2014

Ecological site-based assessments of wind and water erosion: informing accelerated soil erosion management in rangelands

Accelerated soil erosion occurs when anthropogenic processes modify soil, vegetation or climatic conditions causing erosion rates at a location to exceed their natural variability. Identifying where and when accelerated erosion occurs is a critical first step toward its effective management. Here we explore how erosion assessments structured in the context of ecological sites (a land classification based on soils, landscape setting and ecological potential) and their vegetation states (plant assemblages that may change due to management) can inform systems for reducing accelerated soil erosion in rangelands. We evaluated aeolian horizontal sediment flux and fluvial sediment erosion rates for five ecological sites in southern New Mexico, USA, using monitoring data and rangeland-specific wind and water erosion models. Across the ecological sites, plots in shrub-encroached and shrub-dominated vegetation states were consistently susceptible to aeolian sediment flux and fluvial sediment erosion. Both processes were found to be highly variable for grassland and grass-succulent states across the ecological sites at the plot scale (0.25 Ha). We identify vegetation thresholds that define cover levels below which rapid (exponential) increases in aeolian sediment flux and fluvial sediment erosion occur across the ecological sites and vegetation states. Aeolian sediment flux and fluvial erosion in the study area can be effectively controlled when bare ground cover is <20% of a site or the cover of canopy interspaces >100 cm in length is less than ~35%. Land use and management activities that alter cover levels such that they cross thresholds, and/or drive vegetation state changes, may increase the susceptibility of areas to erosion. Land use impacts that are constrained within the range of natural variability should not result in accelerated soil erosion. Evaluating land condition against the erosion thresholds identified here will enable identification of areas susceptible to accelerated soil erosion and the development of practical management solutions.

New Mexico↗
USGS2010

Micromorphology and stable-isotope geochemistry of historical pedogenic siderite formed in PAH-contaminated alluvial clay soils, Tennessee, U.S.A

Alluvial clay soil samples from six boreholes advanced to depths of 400-450 cm (top of limestone bedrock) from the Chattanooga Coke Plant (CCP) site were examined micromorphologically and geochemically in order to determine if pedogenic siderite (FeCO3) was present and whether siderite occurrence was related to organic contaminant distribution. Samples from shallow depths were generally more heavily contaminated with polycyclic aromatic hydrocarbons (PAHs) than those at greater depth. The upper 1 m in most boreholes consisted of mixtures of anthropogenically remolded clay soil fill containing coal clinker, cinder grains, and limestone gravel; most layers of coarse fill were impregnated with creosote and coal tar. Most undisturbed soil (below 1 m depth) consisted of highly structured clays exhibiting fine subangular blocky ped structures, as well as redox-related features. Pedogenic siderite was abundant in the upper 2 m of most cores and in demonstrably historical (< 100 years old) soil matrices. Two morphologies were identified: (1) sphaerosiderite crystal spherulites ranging from 10 to 200 um in diameter, and (2) coccoid siderite comprising grape-like "clusters" of crystals 5-20 ??n in diameter. The siderite, formed in both macropores and within fine-grained clay matrices, indicates development of localized anaerobic, low-Eh conditions, possibly due to microbial degradation of organic contaminants. Stable-isotope compositions of the siderite have ??13C values spanning over 25%o (+7 to - 18%o VPDB) indicating fractionation of DIC by multiple microbial metabolic pathways, but with relatively constant ??18O values from (-4.8 ?? 0.66%o VPDB) defining a meteoric sphaerosiderite line (MSL). Calculated isotope equilibrium water ??18O values from pedogenic siderites at the CCP site are from 1 to 5 per mil lighter than the groundwater ??18O values that we estimate for the site. If confirmed by field studies in progress, this observation might call for a reevaluation of low-temperature siderite-water 18O fractionations. Investigations at the CCP site thus provide valuable information on the geochemical conditions under which siderite can form in modern soils, and thus insight on controls on siderite formation in ancient soils. Copyright ?? 2010, SEPM (Society for Sedimentary Geology).

Journal of Sedimentary Research↗
USGS2014

Soil resources influence vegetation and response to fire and fire-surrogate treatments in sagebrush-steppe ecosystems

Current paradigm suggests that spatial and temporal competition for resources limit an exotic invader, cheatgrass ( Bromus tectorum L.), which once established, alters fire regimes and can result in annual grass dominance in sagebrush steppe. Prescribed fire and fire surrogate treatments (mowing, tebuthiuron, and imazapic) are used to reduce woody fuels and increase resistance to exotic annuals, but may alter resource availability and inadvertently favor invasive species. We used four study sites within the Sagebrush Steppe Treatment Evaluation Project (SageSTEP) to evaluate 1) how vegetation and soil resources were affected by treatment, and 2) how soil resources influenced native herbaceous perennial and exotic annual grass cover before and following treatment. Treatments increased resin exchangeable NH4 + , NO3 − , H2PO4 − , and K + , with the largest increases caused by prescribed fire and prolonged by application of imazapic. Burning with imazapic application also increased the number of wet growing degree days. Tebuthiuron and imazapic reduced exotic annual grass cover, but imazapic also reduced herbaceous perennial cover when used with prescribed fire. Native perennial herbaceous species cover was higher where mean annual precipitation and soil water resources were relatively high. Exotic annual grass cover was higher where resin exchangeable H 2 PO 4 − was high and gaps between perennial plants were large. Prescribed fire, mowing, and tebuthiuron were successful at increasing perennial herbaceous cover, but the results were often ephemeral and inconsistent among sites. Locations with sandy soil, low mean annual precipitation, or low soil water holding capacity were more likely to experience increased exotic annual grass cover after treatment, and treatments that result in slow release of resources are needed on these sites. This is one of few studies that correlate abiotic variables to native and exotic species cover across a broad geographic setting, and that demonstrates how soil resources potentially influence the outcome of management treatments.

Rangeland Ecology and Management↗
USGS2016

Determining the spatial variability of wetland soil bulk density, organic matter, and the conversion factor between organic matter and organic carbon across coastal Louisiana, U.S.A.

Soil bulk density (BD), soil organic matter (SOM) content, and a conversion factor between SOM and soil organic carbon (SOC) are often used in estimating SOC sequestration and storage. Spatial variability in BD, SOM, and the SOM–SOC conversion factor affects the ability to accurately estimate SOC sequestration, storage, and the benefits ( e.g., land building area and vertical accretion) associated with wetland restoration efforts, such as marsh creation and sediment diversions. There are, however, only a few studies that have examined large-scale spatial variability in BD, SOM, and SOM–SOC conversion factors in coastal wetlands. In this study, soil cores, distributed across the entire coastal Louisiana (approximately 14,667 km 2 ) were used to examine the regional-scale spatial variability in BD, SOM, and the SOM–SOC conversion factor. Soil cores for BD and SOM analyses were collected during 2006–09 from 331 spatially well-distributed sites in the Coastwide Reference Monitoring System network. Soil cores for the SOM–SOC conversion factor analysis were collected from 15 sites across coastal Louisiana during 2006–07. Results of a split-plot analysis of variance with incomplete block design indicated that BD and SOM varied significantly at a landscape level, defined by both hydrologic basins and vegetation types. Vertically, BD and SOM varied significantly among different vegetation types. The SOM–SOC conversion factor also varied significantly at the landscape level. This study provides critical information for the assessment of the role of coastal wetlands in large regional carbon budgets and the estimation of carbon credits from coastal restoration.

Louisiana↗
USGS2004

Dissolved organic carbon and disinfection by-product precursor release from managed peat soils

A wetland restoration demonstration project examined the effects of a permanently flooded wetland on subsidence of peat soils. The project, started in 1997, was done on Twitchell Island, in the Sacramento-San Joaquin Delta of California. Conversion of agricultural land to a wetland has changed many of the biogeochemical processes controlling dissolved organic carbon (DOC) release from the peat soils, relative to the previous land use. Dissolved organic C in delta waters is a concern because it reacts with chlorine, added as a disinfectant in municipal drinking waters, to form carcinogenic disinfection byproducts (DBPs), including trihalomethanes (THMs) and haloacetic acids (HAAs). This study explores the effects of peat soil biogeochemistry on DOC and DBP release under agricultural and wetland management. Results indicate that organic matter source, extent of soil organic matter decomposition, and decomposition pathways all are factors in THM formation. The results show that historical management practices dominate the release of DOC and THM precursors. However, within-site differences indicate that recent management decisions can contribute to changes in DOC quality and THM precursor formation. Not all aromatic forms of carbon are highly reactive and certain environmental conditions produce the specific carbon structures that form THMs. Both HAA and THM precursors are elevated in the DOC released under wetland conditions. The findings of this study emphasize the need to further investigate the roles of organic matter sources, microbial decomposition pathways, and decomposition status of soil organic matter in the release of DOC and DBP precursors from delta soils under varying land-use practices.

California↗
USGS2009

Soil nitrogen balance under wastewater management: Field measurements and simulation results

The use of treated wastewater for irrigation of crops could result in high nitrate-nitrogen (NO3-N) concentrations in the vadose zone and ground water. The goal of this 2-yr field-monitoring study in the deep silty clay loam soils south of Dodge City, Kansas, was to assess how and under what circumstances N from the secondary-treated, wastewater-irrigated corn reached the deep (20-45 m) water table of the underlying High Plains aquifer and what could be done to minimize this problem. We collected 15.2-m-deep soil cores for characterization of physical and chemical properties; installed neutron probe access tubes to measure soil-water content and suction lysimeters to sample soil water periodically; sampled monitoring, irrigation, and domestic wells in the area; and obtained climatic, crop, irrigation, and N application rate records for two wastewater-irrigated study sites. These data and additional information were used to run the Root Zone Water Quality Model to identify key parameters and processes that influence N losses in the study area. We demonstrated that NO3-N transport processes result in significant accumulations of N in the vadose zone and that NO3-N in the underlying ground water is increasing with time. Root Zone Water Quality Model simulations for two wastewater-irrigated study sites indicated that reducing levels of corn N fertilization by more than half to 170 kg ha-1 substantially increases N-use efficiency and achieves near-maximum crop yield. Combining such measures with a crop rotation that includes alfalfa should further reduce the accumulation and downward movement of NO3-N in the soil profile. Copyright ?? 2009 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America. All rights reserved.

Journal of Environmental Quality↗
USGS2002

Lead isotopic analyses of selected soil samples from the USEPA Vasquez Blvd.-I-70 study area, Denver, CO

Large amounts of arsenic contamination, in excess of 2000 ppm, have been found in some residential surface soils in northern Denver, Colorado (USEPA, 1999). Associated with the arsenic are elevated levels of metals such as lead, cadmium and mercury. Potential sources of this contamination include waste from smelters in the area and commercial herbicide containing arsenic trioxide and lead arsenate (USEPA, 1999). As a part of the U.S. Environmental Protection Agency’s Vasquez Boulevard-I-70 Project (VBI70 project; USEPA, 1999), lead isotopic analyses of selected soil samples, smelter waste, and a commercial herbicide and a commercial lead arsenate pesticide have been performed in order to constrain the possible sources of elevated lead, and by proxy arsenic, found in these residential soils. The isotopes of lead can be used as a natural tracer in determining sources of contaminants in soils and stream sediments (e.g. Church and others, 1997; Fey and others, 1999; Unruh and others, 2000). The element lead (Pb) consists of four naturally occurring and stable isotopes, 204Pb, 206Pb, 207Pb, and 208Pb. Three of these, 206Pb, 207Pb, and 208Pb are radiogenic decay products of naturally occurring 238U, 235U, and 232Th, respectively. Owing to variations among the U/Pb and Th/Pb elemental abundance ratios among different types of geologic materials, variations in the relative abundances of the Pb isotopes are produced among different materials during geologic time. In order for the Pb isotope method to be useful for determining possible contaminant sources, two important criteria must be met (e.g. Church and others 1997): (1) It must be possible to obtain and measure the Pb isotopic compositions in all potential contaminant sources and in uncontaminated material and (2) the Pb isotopic compositions of the potential contaminant sources must be distinctly different from one another and from uncontaminated background. Variations among the Pb isotopic ratios in selected samples can be correlated with potential sources of Pb with known isotopic compositions in order to determine the relative contribution of Pb from a specific source to the sample. The purpose of this study is to use Pb isotopic data obtained from a selected subset of samples to determine the Pb isotopic signatures of uncontaminated soils as well as those of potential sources of contamination. The data will eventually be used in conjunction with other geochemical data to help determine which source or sources of contamination are most likely responsible for the elevated arsenic levels in the residential soils.

Colorado↗
USGS2003

Soil organic carbon on lands of the Department of the Interior

The stocks of soil organic carbon (SOC) on the landscape are an important element in the global carbon cycle. Changes in soil carbon can change the concentrations of greenhouse gases in the atmosphere. If carbon dioxide from the atmosphere, captured through photosynthesis, is ultimately stored in the soil to an enhanced degree, the resulting soil carbon sequestration may help delay some of the undesirable consequences of global warming. If the conditions affecting the balance of photosynthesis and decomposition are changed to favor decomposition, then soil carbon can be released to the atmosphere as carbon dioxide or methane, contributing to greenhouse warming. The Department of the Interior (DOI) is the largest land management agency in the United States, with jurisdiction influencing more than 2 million square kilometers of land--about 22 percent of the total land area of the country. Estimates using available data indicate that the DOI lands have nearly 18 petagrams (Pg; 1 Pg = 1015 g = 1 gigaton) of SOC, which is about 22 percent of the estimate for the country (81 Pg). The distribution is not uniform, and few areas of DOI lands reflect “average” conditions. Large areas of land with low biological productivity occur in the conterminous U.S. part of the DOI lands, and substantial areas with high SOC occur in Alaska. About 74 percent of the SOC on DOI lands is in Alaska. Details on amounts of SOC by DOI Bureau and location are shown in a series of tables and maps. For the conterminous United States, statistics are given by land cover type and soil depth ranges.

Open-File Report↗
USGS2006

Salt marsh dieback in coastal Louisiana: Survey of plant and soil conditions in Barataria and Terrebonne basins, June 2000-September 2001

Sudden and extensive dieback of the perennial marsh grass, Spartina alterniflora Loisel (smooth cordgrass), which dominates regularly flooded salt marshes along the Gulf of Mexico and Atlantic coastlines, occurred in the coastal zone of Louisiana. The objectives of this study were to assess soil and plant conditions in dieback areas of the Barataria-Terrebonne estuarine system as well as vegetative recovery during and after this dieback event. Multiple dieback sites were examined along 100 km of shoreline from the Atchafalaya River to the Mississippi River during the period from June 2000 through September 2001. The species primarily affected was S. alterniflora; sympatric species such as Avicennia germinans (L.) Stearn (black mangrove) and Juncus roemerianus Scheele (needlegrass rush) showed no visible signs of stress. The pattern of marsh dieback was distinctive with greatest mortality in the marsh interior, suggesting a correlation with local patterns of soil chemistry and/or hydrology. Little or no expansion of dieback occurred subsequent to the initial event, and areas with 50 percent or less mortality in the fall of 2000 had completely recovered by April 2001. Recovery was slower in interior marshes with 90 percent or greater mortality initially. However, regenerating plants in dieback areas showing some recovery were robust, and reproductive output was high, indicating that the causative agent was no longer present and that post-dieback soil conditions were actually promoting plant growth. Stands of other species within or near some dieback sites remained largely unchanged or expanded (A. germinans) into the dead salt marsh. The cause of the dieback is currently unknown. Biotic agents and excessive soil waterlogging/high sulfide were ruled out as primary causes of this acute event, although they could have contributed to overall plant stress and/or interacted with the primary agent to cause plant mortality. Our observations over the 15 month study specifically do not support the contention that dieback was caused by excessive grazing by Littoraria irrorata (marsh periwinkle). Instead, the data show that snails were responding to plant mortality and played an important role in rapid degradation of dead material in some areas. The dieback event was coincident with an extreme drought, low river discharge, and low sea level. These conditions could have caused plant mortality by directly decreasing water availability, increasing salinity, and/or causing oxidation and acidification of soils. The latter scenario was supported by findings of higher pyrite and acid-extractable aluminum and iron, higher acidification potential of dieback soils, and higher concentrations of aluminum and iron in dieback plant tissues (indicating uptake of potentially toxic metals) when compared to reference marshes showing no dieback. The implication of these findings is that periodic weather extremes may play a greater role in shaping coastal plant communities than has previously been recognized. Although such events may not be controlled directly, the resilience and recovery of the system may be altered by management. Such considerations will become increasingly important as global climate changes and human pressures in the coastal zone grow.

Louisiana↗
USGS2008

Major- and trace-element concentrations in soils from northern California: Results from the Geochemical Landscapes Project pilot study

In 2004, the U.S. Geological Survey (USGS), the Geological Survey of Canada (GSC), and the Mexican Geological Survey (Servicio Geologico Mexicano, or SGM) initiated pilot studies in preparation for a soil geochemical survey of North America called the Geochemical Landscapes Project. The purpose of this project is to provide a better understanding of the variability in chemical composition of soils in North America. The data produced by this survey will be used to construct baseline geochemical maps for regions within the continent. Two initial pilot studies were conducted: (1) a continental-scale study involving a north-south and east-west transect across North America and (2) a regional-scale study. The pilot studies were intended to test and refine sample design, sampling protocols, and field logistics for the full continental soils geochemical survey. Smith and others (2005) reported the results from the continental-scale pilot study. The regional-scale California study was designed to represent more detailed, higher resolution geochemical investigations in a region of particular interest that was identified from the low-sample-density continental-scale survey. A 20,000-km2 area of northern California (fig. 1), representing a wide variety of topography, climate, and ecoregions, was chosen for the regional-scale pilot study. This study area also contains diverse geology and soil types and supports a wide range of land uses including agriculture in the Sacramento Valley, forested areas in portions of the Sierra Nevada, and urban/suburban centers such as Sacramento, Davis, and Stockton. Also of interest are potential effects on soil geochemistry from historical hard rock and placer gold mining in the foothills of the Sierra Nevada, historical mercury mining in the Coast Range, and mining of base-metal sulfide deposits in the Klamath Mountains to the north. This report presents the major- and trace-element concentrations from the regional-scale soil geochemical survey in northern California.

California↗
USGS2021

Initial estimates of net infiltration and irrigation from a soil-water-balance model of the Mississippi Embayment Regional Aquifer Study Area

The Mississippi embayment encompasses about 100,000 square miles and covers parts of eight States. In 2016, the U.S. Geological Survey began updating previous work for a part of the embayment known as the Mississippi Alluvial Plain to support informed water use and agricultural policy in the region. Groundwater, water use, economic, and other related models are being combined with field surveys and observations to create a quantitative framework for evaluating regional groundwater withdrawals and their effects on long-term water availability in the Mississippi Alluvial Plain. As part of this effort, the U.S. Geological Survey’s Soil-Water-Balance code (version 2.0) is being used to model potential groundwater recharge and irrigation water use, as necessary inputs to the long-term groundwater modeling efforts. The Soil-Water-Balance code is designed to estimate the distribution and timing of net infiltration leaving the root zone. Soil-Water-Balance makes use of gridded datasets of elevation, soils, land use (including specific crop types), and daily weather datasets to calculate other components of the root-zone water balance, including soil moisture, reference, actual evapotranspiration, snowfall, snowmelt, and canopy interception. Parameters on plant height and growing-season water needs are used to estimate crop-water demand and potential irrigation water use. This report documents the initial construction, calibration, and application of a Soil-Water-Balance model of the Mississippi Embayment Regional Aquifer Study area for simulations running from 1915 to 2017. Further refinements of the model calibration for an expanded model area are planned.

Alabama, Arkansas, Illinois, Kentucky, Louisiana, ↗
USGS1976

Soil moisture in the Black River Basin, New York, during 1972-73: International Field Year for the Great Lakes (IFYGL)

Soil-moisture data were collected and analyzed to provide an estimate of the quantity of water in temporary storage in the Black River Basin, New York, during the International Field Year for the Great Lakes (IFYGL) (April 1, 1972 to March 31, 1973). A portable neutron logger was used to record monthly soil-moisture profiles in the unsaturated zone at 11 sites in the basin. Moisture content, computed in inches of depth over the basin, ranged from 51.41 inches in April to 37.62 inches in August. Thickness of the unsaturated zone was greatest in April and was least in June. The observed absence of a pulse, or wave, of moisture moving down through the soil at most sites may be due to the infrequency of measurements, the location of sites in sandy, well-drained areas, and a relatively constant source of moisture (precipitation) at the surface. The study does not indicate a strong correlation between volume of snowmelt and soil-moisture; this may be due to the high porosity and permeability of soil material at the observation sites. Although nine pairs of monthly basin runoff and soil-moisture content data during IFYGL has a linear correlation coefficient of 0.82, too few data are available to develop a statistical relationship. (Woodard-USGS)

Open-File Report↗
USGS1979

The use of soil-gas helium concentrations for earthquake prediction: Studies of factors causing diurnal variation

The diurnal variation in the soil-gas helium concentration was monitored at depths of 0.5-2 m. Barometric pressure, air temperature, wind speed, soil temperature, soil moisture, relative humidity, and precipitation were also monitored. The helium variation below a 1-m sampling depth usually did not exceed the analytical sensitivity limit of +10 ppb helium. The meteorological parameters that had the greatest effect on the helium variation is wind speed and precipitation; another factor causing variations was the atmospheric pumping created by air-temperature changes and its associated effect on the near-surface soil moisture content. The absolute helium variation rarely exceeded 1 percent of the background helium concentration in air. This minor variation could be corrected because it followed a regular daily pattern. Diurnal changes in the soil-gas helium concentration did not impose any severe limitations on the use of helium soil-gas data collected for earthquake prediction purposes.

Open-File Report↗
USGS1982

An empirical method for determining average soil infiltration rates and runoff, Powder River structural basin, Wyoming

This report describes a method to estimate infiltration rates of soils for use in estimating runoff from small basins. Average rainfall intensity is plotted against storm duration on log-log paper. All rainfall events are designated as having either runoff or nonrunoff. A power-decay-type curve is visually fitted to separate the two types of rainfall events. This separation curve is an incipient-ponding curve and its equation describes infiltration parameters for a soil. For basins with more than one soil complex, only the incipient-ponding curve for the soil complex with the lowest infiltration rate can be defined using the separation technique. Incipient-ponding curves for soils with infiltration rates greater than the lowest curve are defined by ranking the soils according to their relative permeabilities and optimizing the curve position. A comparison of results for six basins produced computed total runoff for all events used ranging from 16.6 percent less to 2.3 percent more than measured total runoff. (USGS)

Water-Resources Investigations Report↗
USGS1991

Delineation of ground-water contamination using soil-gas analyses near Jackson, Tennessee

An investigation of the ground-water resources near Jackson, West Tennessee, was conducted during 1988-89. The study included determination of the occurrence of contaminants in the shallow aquifer using soil-gas analyses in the unsaturated zone. Between 1980 and 1988, an underground fuel-storage tank leaked about 3,000 gallons of unleaded fuel to the water table about 4 feet below land surface. A survey of soil gas using a gas chromatograph equipped with a photoionization detector showed concentrations of volatile organic compounds greater than IO, 000 parts per million near the leak These compounds were detected in an area about 240 feet long and 110 feet wide extending west from the point source. The chromatograms provided two distinct 'fingerprints' of volatile organic compounds. The first revealed the presence of benzene, toluene, andxylenes, which are constituents of unleaded fuel, in addition to other volatile compounds, in soil gas in the area near the leak The second did not reveal any detectable benzene, toluene, or xylenes in the soil-gas samples, but showed the presence of other unidentified volatile organic compounds in soil gas north of the storage tank. The distribution of total concentrations of volatile organic compounds in the unsaturated zone indicated that a second plume about 200 feet long and 90 feet wide was present about 100 feet north of the storage tank The second plume could have been the result of previous activities at this site during the 1950's or earlier. Activities at the site are believed to have included storage of solvents used at the nearby railyard and flushing of tanks containing tar onto a gravel-covered parking area. The delineation of these plumes has shown that soil-gas analyses can be a useful technique for identifying areas of contamination with volatile organic compounds in shallow water-table aquifers and may have broad applications in similar situations where the water table is relatively close to the surface.

Tennessee↗
USGS1995

Data and statistical summaries of background concentrations of metals in soils and streambed sediments in part of Big Soos Creek drainage basin, King County, Washington

Twenty-nine soil samples from 14 holes at 9 sites in part of the Big Soos Creek drainage basin in southwest King County, Washington, were collected and analyzed to obtain data on the magnitude and variability of background concentrations of metals in soils. Seven streambed-sediment samples and three streamwater samples from three sites also were collected and analyzed. These data are needed by regulating government agencies to determine if soils at sites of suspected contamination have elevated concentrations of metals, and to evaluate the effectiveness of remediation at sites with known contamination. Concentrations of 43 metals were determined by a total method, and concentrations of 17 metals were determined by a total-recoverable method and two different leaching methods. Metals analyzed for by all methods included most of those on the U.S. Environmental Protection agency list of priority pollutants, plus alluminum, iron, and manganese. Ranges of concentrations of metals determined by the total method are within ranges found by others for the conterminous United States. Concentrations of mercury, manganese, phosphorus, lead, selenium, antimony, and zinc as determined by the total method, and of some of these plus other metals as determined by the other methods were larger in shallow soil (less than 12 inches deep) than in deep soil (greater than 12 inches). Concentrations of metals in streambed sediments were more typical of shallow than deep soils.

Water-Resources Investigations Report↗
USGS1995

Radon-222 concentrations in ground water and soil gas on Indian reservations in Wisconsin

The weighted average radon-222 concentration of indoor air in homes located on Wisconsin Indian Reservations is 5.8 picocuries per liter, which exceeds the U.S. Environmental Protection Agency action limit of 4 picocuries per liter. Ground water is the principle source of drinking water on Wisconsin Indian Reservations and generally accounts for about 5 percent of the total indoor air radon-222 concentrations found in homes. To determine the distribution of radon-222, ground water from 29 private and community Wisconsin Indian Reservation wells and soil gas at a depth of about 3 feet below land surface adjacent to the wells were sampled. Sites with wells were distributed among the 11 Wisconsin Indian Reservations so that each Reservation contained at least 2 sites. The remaining seven sites were divided among the Reservation by acreage held by each tribe. Ground-water samples were collected using a syringe technique after the wells had been purged sufficiently to reach chemical stability. Samples were then sent by overnight mail to the U.S. Geological Survey, National Water Quality Lab for analysis by liquid scintillation counting. Soil gas was collected in Lucas cells, using a small-diameter soil probe and peristaltic pump. The cells were then analyzed by Lucas cell alpha scintillation counting with a portable radon detector. The highest radon-222 concentrations in ground water and soil gas are from sites with wells finished in the crystalline bedrock aquifer. Radon-222 concentrations in 29 ground-water samples collected from the sand and gravel and sedimentary and crystalline bedrock aquifers range from 260 to 22,000 picocuries per liter with a median concentration of 560 picocuries per liter. Only 2 of the 29 ground-water samples have radon-222 concentrations less than the U.S. Environmental Protection Agency proposed standard of 300 picocuries per liter. The highest radon-222 concentrations were found in ground water from wells in Shawano, Menominee, Forest, and Marathon counties. Radon-222 concentrations in soil gas range from 130 to 7,810 picocuries per liter with a median concentration of 560 picocuries per liter. For sites with wells finished in the sand and gravel aquifer, the coefficient of determination (R2) of the regression of concentration of radon-222 in ground water as a function of well depth is 0.003 and the significance level is 0.32, which indicates that there is not a statistically significant relation between radon-222 concentrations in ground water and well depth. The coefficient of determination of the regression of radon-222 in ground water and soil gas is 0.19 and the root mean square error of the regression line is 271 picocuries per liter. Even though the significance level (0.036) indicates a statistical relation, the root mean square error of the regression is so large that the regression equation would not give reliable predictions. Because of an inadequate number of samples, similar statistical analyses could not be performed for sites with wells finished in the crystalline and sedimentary bedrock aquifers.

Wisconsin↗