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At least 793 records · Page 44Linked to original sources
USGS1997

Strontium 87/strontium 86 as a tracer of mineral weathering reactions and calcium sources in an alpine/subalpine watershed, Loch Vale, Colorado

Sr isotopic ratios of atmospheric deposition, surface and subsurface water, and geologic materials were measured in an alpine/subalpine watershed to characterize weathering reactions and identify sources of dissolved Ca in stream water. Previous studies have noted an excess of Ca in stream water above that expected from stoichiometric weathering of the dominant bedrock minerals. Mixing calculations based on 87 Sr/ 86 Sr indicate that on an annual basis, 26 ± 7% of Ca export in streams is atmospherically derived, 23 ± 1% is from weathering of plagioclase, and the remainder is from weathering of calcite present in trace amounts in the bedrock. A potential source of error when applying Sr isotopes in catchment studies is determination of the 87 Sr/ 86 Sr of Sr released by mineral weathering, which is complicated by the wide range of mineral isotopic compositions, particularly in older rocks, and the variable rates at which the minerals weather. In this study, base-flow stream chemistry was used to represent the 87 Sr/ 86 Sr of Sr derived from mineral weathering because it effectively integrates the potentially variable isotopic composition of Sr released by weathering in the alpine environment.

Colorado↗
USGS2017

Platinum-group elements

The platinum-group elements (PGEs)—platinum, palladium, rhodium, ruthenium, iridium, and osmium—are metals that have similar physical and chemical properties and tend to occur together in nature. PGEs are indispensable to many industrial applications but are mined in only a few places. The availability and accessibility of PGEs could be disrupted by economic, environmental, political, and social events. The United States net import reliance as a percentage of apparent consumption is about 90 percent. PGEs have many industrial applications. They are used in catalytic converters to reduce carbon monoxide, hydrocarbon, and nitrous oxide emissions in automobile exhaust. The chemical industry requires platinum or platinum-rhodium alloys to manufacture nitric oxide, which is the raw material used to manufacture explosives, fertilizers, and nitric acid. In the petrochemical industry, platinum-supported catalysts are needed to refine crude oil and to produce aromatic compounds and high-octane gasoline. Alloys of PGEs are exceptionally hard and durable, making them the best known coating for industrial crucibles used in the manufacture of chemicals and synthetic materials. PGEs are used by the glass manufacturing industry in the production of fiberglass and flat-panel and liquid crystal displays. In the electronics industry, PGEs are used in computer hard disks, hybridized integrated circuits, and multilayer ceramic capacitors. Aside from their industrial applications, PGEs are used in such other fields as health, consumer goods, and finance. Platinum, for example, is used in medical implants, such as pacemakers, and PGEs are used in cancer-fighting drugs. Platinum alloys are an ideal choice for jewelry because of their white color, strength, and resistance to tarnish. Platinum, palladium, and rhodium in the form of coins and bars are also used as investment commodities, and various financial instruments based on the value of these PGEs are traded on major exchanges. PGEs are among the rarest metals; Earth’s upper crust contains only about 0.0005 part per million (ppm) platinum. Today, the average grade of PGEs in ores that are mined primarily for their PGE concentrations varies from 5 to 15 ppm, although the concentration of PGEs in hand-picked ore specimens may range from tens to hundreds of parts per million. More than 100 different minerals have one of the PGEs as an essential component. PGE minerals occur as native metals. They also occur as compounds with other transition metals (copper, iron, mercury, nickel, and silver), post-transition metals (bismuth, lead, and tin), metalloids (antimony, arsenic, and tellurium), and nonmetals (selenium and sulfur). From 1900 to 2011, approximately 14,200 metric tons of PGEs was produced, and roughly 95 percent of that production (13,500 metric tons) took place between 1960 and 2011. The breakdown of production by country shows that, since 1900, about 90 percent of the production came from South Africa and Russia. The secondary supply of platinum, palladium, and rhodium is obtained through the recycling of catalytic converters from end-of-life vehicles, jewelry, and electronic equipment. Recycled platinum, palladium, and rhodium provide a significant proportion of the world’s total supply; these secondary sources are sufficient to close the gap between world mine production and consumption. Exploration and mining companies report resources of about 104,000 metric tons of PGEs (including minor amounts of gold) in mineral deposits around the world that could be developed. For PGEs, almost all the reported production and identified resources are associated with deposits in three geologic features—the Bushveld Complex, which is a layered mafic-to-ultramafic intrusion in South Africa; the Great Dyke, which is a layered mafic-to-ultramafic intrusion in Zimbabwe; and sill-like intrusions associated with flood basalts in the Noril’sk-Talnakh area of Russia. The metallic forms of PGEs are generally considered to be inert. PGEs pose a risk to human health only in cases where individuals are occupationally exposed to synthetic PGE compounds, especially workers in precious-metal refineries. In the natural environment, background PGE concentrations are low in water, sediment, soil, and plants. Anthropogenic sources of PGEs in the environment include catalytic converters used in modern automobiles, platinum-based chemotherapy drugs, and smelter emissions. The abundance of sulfide minerals defines the environmental and geologic characteristics of PGE-enriched magmatic sulfide deposits; those deposits with the highest amount of sulfide minerals could have the highest environmental impact. Acid rock drainage from reef-type and contact-type deposits is unlikely because the ores and their host rocks contain low proportions of sulfide minerals. For some conduit-type orebodies with massive ores, mineral-processing techniques separate and produce concentrates of copper-, iron-, and nickel-bearing sulfide minerals; those with copper and nickel are processed to extract metal, but the iron-sulfide minerals, mainly pyrrhotite, are discarded as waste. This results in waste material with a high acid-generating potential. The most significant primary source of PGEs in the United States is a deposit in the Stillwater Complex, which is a layered igneous intrusion in Montana. Approximately 305 metric tons of platinum and palladium have been mined from the Stillwater Complex deposit since 1986. Exploration and development drilling indicate that another 2,200 metric tons are present. Mining has progressed to depths of 1,800 meters below the surface, but the bottom of the ore deposit has not been reached; geologic estimates suggest that another 1,000 to 6,200 metric tons of PGEs could be present at depth. In the future, PGEs may be mined from deposits found near the base of the Duluth Complex, which is a group of igneous intrusions in Minnesota.

Professional Paper↗
USGS1996

Feruvite from the Sullivan Pb-Zn-Ag deposit, British Columbia

Feruvite, an uncommon Ca- and Fe2+-rich tourmaline species, has been discovered in the footwall of the Sullivan Pb-Zn-Ag deposit (British Columbia) near gabbro sills and dikes. Its chemical composition varies according to occurrence: feruvite from the shallow footwall has lower Ca, higher Al, and higher X-site vacancies than that from the deep footwall. The major chemical substitution involved in the feruvite is the exchange vector CaMgO???-1Al-1(OH)-1. The most important factor controlling feruvite formation at Sullivan is likely the reaction of Fe-rich hydrothermal fluids with Ca-rich minerals in gabbro and host rocks. This reaction led to the breakdown of Ca-rich minerals (plagioclase and hornblende), with release of Ca to solution and its incorporation into feruvite. This process probably postdated the main stages of formation of fine-grained, intermediate schorl-dravite in the tourmalinite pipe in the footwall, and is attributed to postore intrusion of gabbro and associated albite-chlorite-pyrite alteration.

Canadian Mineralogist↗
USGS2018

Sulfur cycle in the Valles Caldera volcanic complex, New Mexico – Letter 1: Sulfate sources in aqueous system, and implications for S isotope record in Gale Crater on Mars

Initial in situ sulfur (S) isotope measurements of the Martian bedrock in Gale Crater have revealed an unexpectedly wide range of δ 34 S values (−47 to +28%). Generally, it is unclear what processes could have contributed to these large isotope fractionations. Therefore, we studied S sources and aqueous SO 2− 4 cycling in the Valles Caldera volcanic complex, New Mexico to better understand S isotope fractionations related to S degassing, hydrothermal activity, and low-temperature processes in aqueous environment. Overall, our study demonstrates that volcanic systems show large spatial heterogeneity in δ 34 S. Magmatic S sources are obvious in steam-dominated H 2 S degassing and precipitation of secondary minerals from hydrothermal fluids with low δ 34 S values of +0.9 ±3%. Locally, however, hydrothermal processes have resulted in more negative δ 34 S values in sulfide minerals (−18 to −4%) and more positive δ 34 S values in sulfate minerals (−1 to +3%). Major aqueous SO 2− 4 sources are oxidation of H 2 S from modern hydrothermal gas emission, and oxidation and dissolution of sulfide and sulfate minerals present in the hydrothermally altered bedrock and crater-lake sediments. The δ 34 S of aqueous SO 2− 4 in surface water and groundwater varies widely (−8 to +5%) and is similar to major S endmembers that undergo oxidation and/or dissolution by active hydrological system. Minor SO 2− 4 contributions with more positive δ 34 S values (+9 to +14%) come from deeply circulating geothermal fluids and negligible amounts from atmospheric deposition (+5 to +7% in snow). Elevated SO 2− 4 contents are mainly associated with modern and past H 2 S emissions and oxidations near the surface. On regional scale, however, most of the intracaldera bedrock is S-depleted, thus the SO 2− 4 contents are usually low in the surface aquatic system and younger sedimentary lake deposits formed at times of negligible near surface hydrothermal activity. In general, magmatic-hydrothermal processes apparently cause the largest δ 34 S variation in S-bearing minerals on volcanic terrains. Therefore, we infer that the measured wide range of δ 34 S values in the Gale sediments by the Curiosity rover on Mars can be explained by S isotope composition of magmatic-hydrothermal sulfide and sulfate minerals that were present in the initial igneous/volcanic rocks prior to crater formation. Later aqueous processes involved oxidation and dissolution of S minerals initially present in these rocks and led to subsequent formation of diagenetic fluids and alteration products enriched in SO 2− 4 with relatively large δ 34 S variation. Additionally, physical erosion, transport and deposition of detrital hydrothermal S minerals from igneous/volcanic rocks might be in part responsible for the measured wide range of δ 34 S in Gale Crater. These unique S isotope results, measured in situ on another planet for the first time, imply the importance of magmatic-hydrothermal fluids in S transport on early Mars and their subsequent alteration in low-temperature aqueous environments.

New Mexico↗
USGS1936

The Battle Branch gold mine, Auraria, Georgia

The Battle Branch mine, in north-central Georgia, is well known locally for its pockets of exceptionally rich gold ore. During the period from May 24, 1934, to May 20, 1935, 781.97 ounces of bullion, of an average fineness of about 850, was shipped to the mint. The deposit is of the lode type; it consists of many quartz stringers and lenses grouped in three zones in a schistose phase of the Carolina gneiss. Three stages of mineralization are recognized. An early high-temperature stage produced coarsely crystalline silicates, such as garnet, kyanite, tourmaline, biotite, and muscovite, which were probably formed by a recrystallization of the minerals in the country rock. During the intermediate stage ankerite, quartz, and pyrrhotite were formed. The last stage was marked by chlorite, galena, and gold. Throughout the period of mineralization minor amounts of movement in and across the lode occurred. The distribution of the ore shoots is dependent to a large extent upon the distribution of the cross fractures. The ore shoots are pod-shaped bodies, which pinch and swell abruptly. The gold in the rich shoots is contemporaneous with galena and is clearly of hypogene origin.

Georgia↗
USGS1974

The diorite at West Warren, south-central Massachusetts

Follated, syntectonic, concordant intrusive bodies of mostly diorite and meladiorite with less abundant quartz diorite and norite have been mapped in the West Warren area of south-central Massachusetts. The rocks of the pluton range from a medium colored phase of diorite and quartz diorite to a dark colored phase of meladiorite and norite. Major minerals In the dioritic rocks are calcic andesine, green hornblende, brown biotite, and hypersthene. Igneous textures are dominant, and retrograde or deuteric effects are generally minor. Silica and alumina contents of the dioritic rocks are somewhat higher than for average diorites; conversely, the oxides of iron, magnesium, and calcium are generally lower. Normative quartz, albite, and anorthite are higher and orthoclase is lower in the samples than In the average diorite. Sizeable plutons of diorite-norite are uncommon in central Massachusetts. The West Warren body, roughly 26 km2 (10 square miles) in area, bears little petrochemical relation to adjacent rock units. The pluton can be construed as belonging to a belt of intrusive mafic rocks which stretches from southeastern New York to coastal Maine.

Open-File Report↗
USGS1967

Sulfides associated with the Salton Sea geothermal brine

Concentrated saline brine tapped by a deep well drilled for geothermal power near the Salton Sea, California, deposited metal-rich siliceous scale at the rate of 2 to 3 tons per month. The iron-rich opaline scale contains an average of 20% Cu and up to 6% Ag present in bornite, digenite, chalcopyrite, a new dense polymorph of chalcocite, stromeyerite, and native silver.The brines are in equilibrium with an assemblage of sulfide minerals in the reservoir rocks. Sphalerite containing 16.6 mol % FeS is in equilibrium with the brine in which the activity of sulfur (a (sub s 2 ) ) is estimated at 10 (super -10.2) at 325 degrees C. This is in good agreement with the projected high-temperature data of Barton and Toulmin (2) for the system Fe-Zn-S. Other sulfides identified in the reservoir rocks are pyrite, pyrrhotite, chalcopyrite, and galena.The heavy metals in solution are apparently derived from the sediments of the brine reservoir, being released from the silicate minerals in which they occur in trace amounts, as metamorphism of the sediment proceeds. Although the total of the heavy metals in solution greatly exceeds the sulfur, on a molal basis, the brine is saturated with respect to sulfide components and addition of more sulfide ion would only cause precipitation of sulfides.

California↗
USGS1968

A lead isotope study of galenas and selected feldspars from mining Districts in Utah

The leads in feldspars from the main Tertiary intrusive bodies in each of three mining regions in Utah are isotopically similar to the lead deposits immediately associated with them. These deposits are the largest and also the least radiogenic in each region, whereas the smaller deposits are more radiogenic. Throughout each region the 'ore leads appear to be mixtures in various proportions of lead derived from the intrusive magma and a radiogenic lead component derived from the upper crustal rocks through which the mineralizing fluids passed. Linear relationships are exhibited between the lead isotope ratios within each mining region, and these enable the ages of the upper crustal basement rocks to be determined. A simple tvo-stage model theory for the development of the lead ores yields the folloving data: Oquirrh Mountains region, t 1,650 4-150 m.y., p-Cottonwood-Park City region, t = 2,415 4-30 m.y., p- = 8.87. Tintlc region, t 2,075 4-30 m.y., Milford region, t 1 765 4-70 m.y., p-T ( Us ) = , = 8.83. An alternative "mixing" model is also proposed which requires only 1,650-m.y. and 2,400-m.y. events in these regions. In either case these ages confirm and supplement our present geochronological knowledge of the basement rocks of Utah .

Utah↗
USGS2019

Geological and geophysical data for a three-dimensional view—Inside the San Juan and Silverton Calderas, Southern Rocky Mountains Volcanic Field, Silverton, Colorado

Introduction The San Juan-Silverton caldera complex located near Silverton, Colorado, in the Southern Rocky Mountains volcanic field is an ideal natural laboratory for furthering the understanding of shallow-to-deep volcanic-related mineral systems. Recent advances in geophysical data processing and three-dimensional (3D) model construction will help to characterize shallow properties important for understanding surface water and groundwater quality issues and will also improve knowledge of deep geological structures that may have been conduits for hydrothermal fluids that formed mineral deposits. The study has general applications to mineral resource assessments in other areas of the world and to identifying possible groundwater flow paths and associated geochemistry important in abandoned mine lands cleanup. Silverton, Colorado, is the site of a spectacular succession of igneous rocks that formed beginning about 35 million years ago (Ma). Base metals (copper, lead, and zinc) and precious metals (silver and gold) mined from the late 1870s to 1991 owe their existence to a 25-million-year cycle of igneous activity. The presence of economic, base, and precious metal deposits within a complex geological setting were largely responsible for stimulating studies by the U.S. Geological Survey (USGS) conducted during the early 20th century. The focus of investigations in the late 20th and 21st centuries have broadened in scope to include abandoned mine lands (AML) investigations. The legacy of hard rock mining in headwater catchment areas caused environmental challenges for local communities and downstream water resource users. The Gold King Mine, located a few kilometers north of Silverton, illustrates the potential environmental effects of abandoned mines. On August 5, 2015, during reclamation efforts at the Gold King Mine, a breach of collapsed workings sent approximately 3 million gallons of acidic and metal-rich mine water into the upper Animas River, a tributary to the Colorado River Basin. Mining-related sources of metals and acidity add to geological sources of metals in surface water and groundwater. Weathering processes of altered and mineralized rock have been a source of acid rock drainage that have been ongoing for millennia.

Colorado↗
USGS1999

Composition and origin of Early Cambrian Tiantaishan phosphorite-Mn carbonate ores, Shaanxi Province, China

The Tiantaishan phosphorite-Mn carbonate ores occur in the Early Cambrian Tananpo Formation in complexly folded and faulted rocks located in southern Shaanxi Province. About 65 x 106 tonnes of 17% P2O5 ore reserves exist and Mn-ore reserves are about 8.3 x 106 tonnes of +18% Mn. The stratigraphic sequence in ascending order consists of black phyllite, black to gray phosphorite ore, black phyllite, rhodochrostone ore, Mn mixed-carbonates, and dolostone. Data are presented from microprobe mineral chemistry, whole-rock chemistry, stable isotopes of carbonates, X-ray mineralogy, petrographic and SEM observations, and statistical analysis of chemical data. The dominant ore-forming minerals are hydroxy- and carbonate fluorapatite and Ca rhodochrosite, with Mg kutnahorite and dolomite comprising the Mn mixed-carbonate section. Pyrite occurs in all rock types and alabandite (MnS) occurs throughout the rhodochrostone section. The mean P2O5 content of phosphorite is 31% and argillaceous phosphorite is 16%, while the mean MnO content of rhodochrostone ore is 37%. Phosphorite ores are massive, spheroidal, laminated, and banded, while rhodochrostone ores have oolitic, spheroidal, and granular fabrics. The most distinguishing characteristics of the ores are high total organic carbon (TOC) contents (mean 8.4%) in the phosphorite and high P2O5 contents (mean 2.7%) in the rhodochrostone ore. The atypically high TOC contents in the Tiantaishan phosphorite probably result from very strong productivity leading to high sedimentation rates accompanied by weak reworking of sediments; poor utilization of the organic matter by bacteria; and/or partial replacement of bacterial or algal mats by the apatite. The depositional setting of the ores was the margin of an epicontinental seaway created as a direct consequence of global processes that included break-up of a supercontinent, formation of narrow seaways, creation of extensive continental shelves, overturn of stagnant, metal-rich deep-ocean waters, and marine transgression. Water depth increased from deposition of the black phyllite sequence through deposition of the Mn mixed-carbonate sequence, then shallowed again during deposition of the overlying dolostone sequence. Bottom waters were mostly dysoxic to suboxic, but fluctuated from oxic to anoxic. Productivity was high during deposition of the black phyllite sequence, increased during precipitation of phosphorite, and then decreased to moderate levels during precipitation of rhodochrostone ores. Biosilica contributions occur in each lithology, but are greatest in rhodochrostone. Changes in sedimentation were determined by changes in water depth, productivity, upwelling, sea-level change, and ventilation of the depositional basin. The source of the phosphorus was organic matter produced in great quantities during deposition of the black phyllite and phosphorite sequences in a zone of coastal upwelling. Organic matter accumulation was rapid. Globally, Mn was supplied by overturn of stagnant, metal-rich deep-ocean waters, which were redistributed to areas of coastal upwelling and seaways; that process may have been initiated by latest Proterozoic glaciations which would have promoted density stratification and accumulation and storage of metals. Regionally, Mn was supplied by terrigenous input into the shallow seaway and hydrothermal input into the deeper water parts of that seaway. Locally, Mn sources included leaching and transport of metals from the sediment column. Manganese was stored locally in low-oxygen (not anoxic) seawater prior to Mn-ore formation. The source of the carbon in the Mn carbonates and dolostones was predominantly seawater bicarbonate and secondarily CO2 derived from the oxidation of organic matter in the bacterially mediated diagenetic zone of sulfate reduction.

Ore Geology Reviews↗
USGS1950

Alteration and metallization in the Bagdad porphyry copper deposit, Arizona

The porphyritic to seriate-textured quartz monzonite host-rock at Bagdad was changed by hypogene alteration to a granular rock in which the plagioclase became albitic, orthoclase and quartz increased in amount, and hornblende and book-biotite were recrystallized to pale brown leafy biotite. Hypogene sulfides, pyrite and chalcopyrite, were added during the process of alteration, accompanied in part by sericite. Molybdenite is younger than the chalcopyrite. Locally, the host rock was altered to a quartz-orthoclase-sericite facies containing more quartz and orthoclase than is found in the main alteration facies. Chemical analyses indicate that alteration and mineralization of the host rock resulted in loss of iron, lime, and soda, and addition of sulfur, copper, and potash.Supergene changes include the formation of a chalcocite blanket in late Pliocene or early Pleistocene time. Chalcocite replaced chalcopyrite in preference to pyrite. The chalcocite blanket is truncated by the present erosion surface and its distribution can be recognized from the character of the iron oxide left in the leached cavities. Along some of the fractures and faults, supergene clay is present, consisting of kaolinite and a member of the saponite-montmorillonite group.

Arizona↗
USGS1986

RELATION BETWEEN SURFACE-WATER QUALITY AND THE COMPOSITION OF COAL IN PIKE COUNTY, KENTUCKY.

The quality of surface water in Pike County, Kentucky, seems to reflect the composition of coals in the county. Groundwater acquires mineral concentration characteristics of the rocks through which it moves. When groundwater is discharged to streams the mineral concentrations in streams, especially during low flow periods, are characteristic of several coal beds that are a part of the aquifier system contributing water to the streams. A regression analysis was also performed to develop statistical models to estimate the quality of surface water based on the composition of the coals. Twenty models consisting of 10 two-variable models and 10 three-variable models were developed for the maximum values.

Conference Paper↗
USGS2023

Geology and undiscovered resource assessment of the potash-bearing, Middle Devonian (Givetian), Prairie Evaporite, Elk Point Basin, Canada and United States

The U.S. Geological Survey (USGS) assessed undiscovered potash resources in the Elk Point Basin in Canada and the United States as part of a global mineral resource assessment. The Elk Point Basin is a large, Middle Devonian (Givetian) intracratonic evaporite basin covering approximately 1,200,000 square kilometers (km 2 ) and filled mainly with marine evaporite and minor clastic sedimentary rocks that contain stratabound potash-bearing salt. The potash-bearing salt is concentrated in four stratigraphic members (Patience Lake, Belle Plaine, White Bear, and Esterhazy) in the upper 100 meters (m) of the Prairie Evaporite and are separated by beds of halite (NaCl) that contain lesser—presently non-economic—amounts of sylvite (KCl) and carnallite (KMgCl 3 ·6H 2 O). The principal ore-bearing salt contains mainly sylvite. Four permissive tracts were defined that permit the presence of undiscovered stratabound potash (both sylvite- and carnallite-bearing salt) using geological criteria. Permissive tracts are defined by the spatial extent of each stratigraphic member that is at least 1 m thick, are less than 3 kilometers (km) from the surface, contain at least 4 percent equivalent potassium oxide (K 2 O), and contain the currently known resources. The permissive tracts include known potash deposits and potash occurrences as wells or mines not in production and show where undiscovered potash resources may be present. Well data are used to define the extent, thickness, average K 2 O equivalent grades, and volumes of each member. Data were supplied by the Saskatchewan Geological Survey or were obtained from published National Instrument (NI) 43-101 technical reports and other published reports, such as annual 10-K reports or news releases. The Elk Point Basin is the world’s largest source of potash, producing 23.0 million metric tons (Mt) of potassium chloride (KCl) (the equivalent of about 14.4 Mt of K 2 O) in 2018. In terms of global importance, the Elk Point Basin may contain 40 to greater than 50 percent of the world’s potash resources. Since 1962, potash companies have mined more than 1.5 trillion metric tons of ore containing 605 Mt of KCl (the equivalent of about 380 Mt of K 2 O). The total value of the ore produced through 2018 is on the order of $70 trillion (CAD). Potash is currently produced from eight conventional and three underground solution mines at depths ranging from 900 m to nearly 1,800 m. Estimates of the amount of potash in the Elk Point Basin vary considerably and the data and methods used in those estimations are not well documented. Known potash resources are approximately 99 billion metric tons (Bt) of ore containing 22 Bt of K 2 O equivalent. As a result of new mine openings and increased production capacity at existing mines, the total production capacity of mines in the Elk Point Basin has increased significantly (to about 32.8 Mt of KCl or 22.8 Mt of K 2 O equivalent per year). Additional production capacity of about 31 Mt of KCl (or 17 Mt of K 2 O equivalent) per year could be realized over the next decade if several current (as of 2019) exploration and development projects reach production status. Stratabound potash-bearing salt of the Prairie Evaporite presently underlies a total area of about 188,000 km 2 and has a total volume of about 2,690 cubic kilometers (km 3 ). Post-depositional solution processes considerably modified the mineralogy and presence of the potash-bearing salt. These changes had a profound effect on the volume and grade of potash resources that remained in the Prairie Evaporite and are a major consideration of exploration and mining operations as well as in this assessment of undiscovered potash resources. This USGS assessment includes the locations and possible amounts of undiscovered potash resources in the Prairie Evaporite. Volumes for each stratigraphic member were computed using member thicknesses and areal extent modified by actual, estimated geologic loss owing to salt dissolution and extraction ratios, as well as estimated distribution of carnallite and sylvite. Both sylvite- and carnallite-bearing salts were assessed for potash in this study. The assessment uses modern published grade and tonnage data. The amount of undiscovered potash is estimated by using Monte Carlo simulations to combine volume estimates of the potash-bearing members with probability distributions for average grade and bulk density. Mean potash grades (expressed as percentage of K 2 O equivalent) calculated using drill core analyses are 17.76 for the Patience Lake Member, 15.98 for the Belle Plaine Member, 10.66 for the White Bear Member, and 15.30 for the Esterhazy Member. Geologic losses reported as extraction ratios during mining may range from 27.5 to 41.6 percent and are dependent on mining method and local geologic conditions. The assessment determined that mean estimated undiscovered K 2 O equivalent resources for the Patience Lake, Belle Plaine, White Bear, and Esterhazy Members are 340, 220, 34, and 190 Bt, respectively, and estimated a total mean of 790 Bt for the entire Prairie Evaporite above a depth of 3 km. The total mineralized rock tonnage is estimated to be about 5,000 Bt. Most of the assessed potash is located within Saskatchewan with lesser amounts in Alberta and Manitoba as well as Montana and North Dakota within the United States. Although carnallite is mined for potash in Europe, it has historically been avoided in mining plans for potash-producing companies in Saskatchewan because of mining, processing, and grade considerations. Carnallite-rich salt is locally present in concentrations and volumes that could be a significant resource of magnesium chloride (MgCl 2 ) obtained as a byproduct of processing the carnallite for potash. Previously estimated reserves (not NI 43-101 compliant) of mineralized material from 1955 to 2019 are 695 Mt at 22.1 percent MgCl 2 . The total amount of K 2 O equivalent as carnallite was estimated during this USGS assessment to be about 120 Bt (or 180 Bt KCl). With uncertainties in defining the areal extent of carnallite in each of the potash-bearing members, the amount of MgCl 2 as carnallite in the Elk Point Basin could be approximately 180 Bt.

Elk Point basin↗
USGS2013

Prolonged magmatic activity on Mars inferred from the detection of felsic rocks

Rocks dominated by the silicate minerals quartz and feldspar are abundant in Earth’s upper continental crust. Yet felsic rocks have not been widely identified on Mars, a planet that seems to lack plate tectonics and the associated magmatic processes that can produce evolved siliceous melts on Earth. If Mars once had a feldspar-rich crust that crystallized from an early magma ocean such as that on the Moon, erosion, sedimentation and volcanism have erased any clear surface evidence for widespread felsic materials. Here we report near-infrared spectral evidence from the Compact Reconnaissance Imaging Spectrometer for Mars onboard the Mars Reconnaissance Orbiter for felsic rocks in three geographically disparate locations on Mars. Spectral characteristics resemble those of feldspar-rich lunar anorthosites, but are accompanied by secondary alteration products (clay minerals). Thermodynamic phase equilibrium calculations demonstrate that fractional crystallization of magma compositionally similar to volcanic flows near one of the detection sites can yield residual melts with compositions consistent with our observations. In addition to an origin by significant magma evolution, the presence of felsic materials could also be explained by feldspar enrichment by fluvial weathering processes. Our finding of felsic materials in several locations on Mars suggests that similar observations by the Curiosity rover in Gale crater may be more widely applicable across the planet.

Nature Geoscience↗
USGS2014

Porphyry copper assessment of East and Southeast Asia: Philippines, Taiwan (Republic of China), Republic of Korea (South Korea), and Japan

The U.S. Geological Survey collaborated with member countries of the Coordinating Committee for Geoscience Programmes in East and Southeast Asia (CCOP) on an assessment of the porphyry copper resources of East and Southeast Asia as part of a global mineral resource assessment. The assessment covers the Philippines in Southeast Asia, and the Republic of Korea (South Korea), Taiwan (Province of China), and Japan in East Asia. The Philippines host world class porphyry copper deposits, such as the Tampakan and Atlas deposits. No porphyry copper deposits have been discovered in the Republic of Korea (South Korea), Taiwan (Province of China), or Japan. Thirteen geographic areas were delineated as tracts that are permissive for porphyry copper deposits in the assessed area. Individual tracts range from about 3,000 to 100,000 square kilometers in area. Permissive tracts are delineated on the basis of mapped distributions of igneous rocks of specific age ranges that define subduction-related magmatic arcs or magmatic belts that might contain porphyry copper deposits. Most of these magmatic arcs are subduction related, although some porphyry deposits and prospects are present in back-arc or poorly understood tectonic settings. Maps at various scales were used in the compilation; however, the final tract boundaries are intended for use at a scale of 1:1,000,000. Numbers of undiscovered deposits were estimated at different levels of confidence for 10 permissive tracts in the Philippines including one area that extends to eastern Taiwan (Republic of China); permissive tracts in South Korea and Japan are discussed qualitatively. Estimates of numbers of undiscovered deposits were combined with grade and tonnage models using Monte Carlo simulation to estimate amounts of undiscovered resources. Grades and tonnages of known porphyry copper deposits in the study area were compared with global grade and tonnage models to determine the appropriate model for simulation of undiscovered resources. Most of the known deposits are best described as copper-gold subtypes of porphyry copper deposits. For some permissive tracts, a general porphyry copper-gold-molybdenum model was used. Thirty-eight porphyry copper deposits are known in the Philippines; the mean number of undiscovered deposits was estimated to be 28. Mean (arithmetic) resources that could be associated with the undiscovered deposits are 90 million metric tons of copper and 5,800 metric tons of gold, as well as byproduct molybdenum and silver. Additional resources that could be discovered in extensions to known deposits were not evaluated. Assessment results, presented in tables and graphs, indicate expected amounts of total contained metal and mineralized rock in undiscovered deposits at different quantile levels, as well as the arithmetic mean for each tract. The Philippines have a long history of porphyry exploration cycles and mine development, interrupted at times by political and social unrest, environmental concerns, and natural disasters. Changes in mining laws within the region and the recent high price of gold on the world market have prompted renewed interest in porphyry copper deposits in the region. South Korea and Japan have been thoroughly explored for many types of mineral deposits. Available data suggest that the permissive rocks in South Korea typically are too deeply eroded to preserve porphyry copper deposits. Porphyry copper systems may be present in Japan, but are likely to lie at depths greater than the 1 kilometer from the surface protocol adopted for this study. Descriptions of the geologic basis for delineating each tract, the data used, the geologic criteria and rationale for the assessment, and results of the assessment are included in appendixes along with the description of a geographic information system (GIS) that includes tract boundaries, known porphyry copper deposits and significant prospects, and assessment results.

Scientific Investigations Report↗
USGS1981

Map showing mineral-resource potential of the King Range and Chemise Mountain Instant Study Areas, Humboldt and Mendocino counties, California

The potential for economic development of energy-related or metallic mineral resources in the King Range and Chemise Mountain Instant Study Areas is low to moderate as indicated by geologic, geophysical, and geochemical investigations. No oil or gas seeps or coal seams were detected within the King Range or Chemise Mountain Study Area. The low porosity and permeability of the Franciscan sandstones that underlie these areas indicate a very low potential for oil or gas. The geothermal resource potential of these areas also is low. Minor manganese resources occur adjacent to the southeast corner of the King Range Instant Study Area near Queen Peak. The manganese forms small stratabound deposits associated with radiolarian chert and pillow basalt. The known deposits are too small and the manganese too low in concentration for further economic exploitation. Similar manganese mineralization may be within the belt of melange in the southeast corner of the King Range area and within the Chemise Mountain Instant Study Area, but economic deposits are unlikely. Although there has been historical base- and precious-metal exploration activity north of the King Range in the Mattole River drainage, our geologic and geochemical field data indicate almost no gold potential and low potentials for lead, zinc, copper, and silver. During this investigation, one high-grade vein and several minor veins containing lead, zinc, copper, and silver were discovered at Point Delgada immediately south of the King Range Instant Study Area. The vein mineralization is Miocene and cuts Cretaceous basalt flows, dikes, flow breccia, and younger overlying sedimentary rocks of the King Range. The vein mineralization at Point Delgada could be remobilized from more extensive unexposed stratabound base-metal mineralization at depth. Traces of lead and zinc detected within the King Range Instant Study Area may have similar stratabound or vein origins, but no resource potential is indicated. Minor copper mineralization with associated lead, zinc, and manganese anomalies within the Chemise Mountain Instant Study Area is of low economic potential because of the shearing, isolation, and lenticularity of the basaltic and cherty rocks within the melange mineralization.

California↗
USGS2011

Structural controls and evolution of gold-, silver-, and REE-bearing copper-cobalt ore deposits, Blackbird district, east-central Idaho: Epigenetic origins

The Cu-Co ± Au (± Ag ± Ni ± REE) ore deposits of the Blackbird district, east-central Idaho, have previously been classified as Besshi-type VMS, sedex, and IOCG deposits within an intact stratigraphic section. New studies indicate that, across the district, mineralization was introduced into the country rocks as a series of structurally controlled vein and alteration systems. Quartz-rich and biotite-rich veins (and alteration zones) and minor albite and siderite veinlets maintain consistent order and sulfide mineral associations across the district. Both early and late quartz veins contain chalcopyrite and pyrite, whereas intermediate-stage tourmaline-biotite veins host the cobaltite. Barren early and late albite and late carbonate (generally siderite) form veins or are included in the quartz veins. REE minerals, principally monazite, allanite, and xenotime, are associated with both tourmaline-biotite and late quartz veins. The veins are in mineralized intervals along axial planar cleavage, intrafolial foliation, and shears. Mineralized intervals are hosted by a variety of metasedimentary rocks, including three phyllitic units of Mesoproterozoic age and two schistose units. All of these units are S-tectonites in the footwall of a regional thrust fault. Specifically, the district lies within an oblique thrust ramp containing a series of structural horses (three domains) in a duplex system. The deposits span the three domains and are hosted by metamorphic rocks that range from lower amphibolite facies in the structurally upper domain to lower-middle greenschist facies in the lower domain (an inverted metamorphic sequence). Early quartz and biotite veins were introduced during progressive folding and prolonged peak metamorphic conditions and they underwent late-tectonic retrograde recrystallization and metamorphic mineral growth, to the same extent as the country rocks in each domain. Where little subsequent deformation occurred, early veins are discordant to bedding but, where folding was polyphase and fabrics are penetrative, mineralized zones are concordant with metamorphic compositional layering. Late quartz veins in the zones are associated with retrograde minerals and textures and are only locally deformed. 40 Ar/ 39 Ar dating of unoriented muscovite from the selvage of a late quartz vein yields a Late Cretaceous age of about 83 Ma, the time of retrograde metamorphism associated with introduction of late quartz veins. Textural data at all scales indicate that the host sites for veins and the tectonic evolution of both host rocks and mineral deposits were kinematically linked to Late Cretaceous regional thrust faulting. Heat, fluids, and conduits for generation and circulation of fluids were part of the regional crustal thickening. The faulting also juxtaposed metaevaporite layers in the Mesoproterozoic Yellowjacket Formation over Blackbird district host rocks. We conclude that this facilitated chemical exchange between juxtaposed units resulting in leaching of critical elements (Cl, K, B, Na) from metaevaporites to produce brines, scavenging of metals (Co, Cu, etc) from rocks in the region, and, finally, concentrating metals in the lower-plate ramp structures. Although the ultimate source of the metals remains undetermined, the present Cu-Co ± Au (± Ag ± Ni ± REE) Blackbird ore deposits formed during Late Cretaceous compressional deformation .

Idaho↗
USGS1988

Hydrothermal alteration patterns in the Breitenbush Hot Springs area, Cascade Range, Oregon

Rocks of early Miocene age in the Breitenbush Hot Springs area have been affected by at least two major episodes of hydrothermal alteration, one of which had temperatures in excess of 200??C. Alteration minerals in younger Tertiary rocks are characteristic of temperatures below 100??C. The most important factor in controlling alteration is fracture permeability. The best guide to interpreting alteration is secondary mineralogy of volcaniclastic and pyroclastic rocks, flow breccia, and vesiculated or fractured lavas; alteration effects in interbedded massive lava flows are much more subtle.

Conference Paper↗