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At least 793 records · Page 44Linked to original sources

Identifying the pollen of an extinct spruce species in the Late Quaternary sediments of the Tunica Hills region, south-eastern United States

Late Quaternary fluvial deposits in the Tunica Hills region of Louisiana and Mississippi are rich in spruce macrofossils of the extinct species Picea critchfieldii , the one recognized plant extinction of the Late Quaternary. However, the morphology of P. critchfieldii pollen is unknown, presenting a barrier to the interpretation of pollen spectra from the last glacial of North America. To address this issue, we undertook a morphometric study of Picea pollen from Tunica Hills. Morphometric data, together with qualitative observations of pollen morphology using Apotome fluorescence microscopy, indicate that Picea pollen from Tunica Hills is morphologically distinct from the pollen of P. glauca , P. mariana and P. rubens . Measurements of grain length, corpus width and corpus height indicate that Picea pollen from Tunica Hills is larger than the pollen of P. mariana and P. rubens , and is slightly larger than P. glauca pollen. We argue that the morphologically distinctive Tunica Hills Picea pollen was probably produced by the extinct spruce species P. critchfieldii . These morphological differences could be used to identify P. critchfieldii in existing and newly collected pollen records, which would refine its paleoecologic and biogeographic history and clarify the nature and timing of its extinction in the Late Quaternary.

Louisiana, Mississippi↗

Fluid flow in the resurgent dome of Long Valley Caldera: Implications from thermal data and deep electrical sounding

Temperatures of 100??C are measured at 3 km depth in a well located on the resurgent dome in the center of Long Valley Caldera, California, despite an assumed >800??C magma chamber at 6-8 km depth. Local downflow of cold meteoric water as a process for cooling the resurgent dome is ruled out by a Pecle??t-number analysis of temperature logs. These analyses reveal zones with fluid circulation at the upper and lower boundaries of the Bishop Tuff, and an upflow zone in the metasedimentary rocks. Vertical Darcy velocities range from 10 to 70 cm a-1. A 21-km-long geoelectrical profile across the caldera provides resistivity values to the order of 100 to >103 ??m down to a depth of 6 km, as well as variations of self-potential. Interpretation of the electrical data with respect to hydrothermal fluid movement confirms that there is no downflow beneath the resurgent dome. To explain the unexpectedly low temperatures in the resurgent dome, we challenge the common view that the caldera as a whole is a regime of high temperatures and the resurgent dome is a local cold anomaly. Instead, we suggest that the caldera was cooled to normal thermal conditions by vigorous hydrothermal activity in the past, and that a present-day hot water flow system is responsible for local hot anomalies, such as Hot Creek and the area of the Casa Diablo geothermal power plant. The source of hot water has been associated with recent shallow intrusions into the West Moat. The focus of planning for future power plants should be to locate this present-day flow system instead of relying on heat from the old magma chamber. ?? 2003 Elsevier B.V. All rights reserved.

Journal of Volcanology and Geothermal Research↗

Actual evapotranspiration and deficit: Biologically meaningful correlates of vegetation distribution across spatial scales

Correlative approaches to understanding the climatic controls of vegetation distribution have exhibited at least two important weaknesses: they have been conceptually divorced across spatial scales, and their climatic parameters have not necessarily represented aspects of climate of broad physiological importance to plants. Using examples from the literature and from the Sierra Nevada of California, I argue that two water balance parameters—actual evapotranspiration (AET) and deficit (D)—are biologically meaningful, are well correlated with the distribution of vegetation types, and exhibit these qualities over several orders of magnitude of spatial scale (continental to local). I reach four additional conclusions. (1) Some pairs of climatic parameters presently in use are functionally similar to AET and D; however, AET and D may be easier to interpret biologically. (2) Several well-known climatic parameters are biologically less meaningful or less important than AET and D, and consequently are poorer correlates of the distribution of vegetation types. Of particular interest, AET is a much better correlate of the distributions of coniferous and deciduous forests than minimum temperature. (3) The effects of evaporative demand and water availability on a site's water balance are intrinsically different. For example, the ‘dry’ experienced by plants on sunward slopes (high evaporative demand) is not comparable to the ‘dry’ experienced by plants on soils with low water-holding capacities (low water availability), and these differences are reflected in vegetation patterns. (4) Many traditional topographic moisture scalars—those that additively combine measures related to evaporative demand and water availability—are not necessarily meaningful for describing site conditions as sensed by plants; the same holds for measured soil moisture. However, using AET and D in place of moisture scalars and measured soil moisture can solve these problems.

Journal of Biogeography↗

Climatic change and permafrost. Record from surficial deposits

The physical and chemical characteristics of surficial deposits and the floral and faunal remains they contain provide information that is useful for interpreting both paleoclimate and past permafrost conditions. Surficial deposits thus provide a record of climatic change and permafrost history. This record suggests that initiation of permafrost in lowland areas of the Southern Arctic Archipelago and continents of the northern hemisphere may have occurred about 2,400,000 years ago during the pronounced cooling that led to the first major glaciation of late Cenozoic time. Since then, climate has been relatively cold but cyclically variable, characterized by the growth and shrinkage of large, continental ice sheets. Permafrost has expanded and contracted in response to these climatic changes, and we can expect the present permafrost conditions to change in response to future climatic changes. To predict the response of permafrost and the landscape to future climatic change we should: (1) Define relations between climate and the modern landscape; (2) establish long‐term records of past climatic change and landscape response; and (3) determine the paleoenvironments of past warm periods as possible analogs for future global warming.

Journal of Cold Regions Engineering↗

Stratigraphic architecture and fluvial interpretations of the Upper Cretaceous (Turonian?) Middendorf Formation, Chesterfield County, South Carolina, U.S.A.

The Upper Cretaceous (Turonian?) Middendorf Formation is a sand-rich stratigraphic unit of fluvial origin that forms a large aquifer in the U.S. Atlantic Coastal Plain. In Chesterfield County (South Carolina), which is the site of the type locality, the formation ranges in thickness from 66.5 to > 119.7 meters. The base of the formation is an unconformity above Paleozoic metasiltstone, and the upper contact is an unconformity above which lies sand of the Quaternary Pinehurst Formation. Outcrops display the following five facies assemblages: 1) sandstone to conglomeratic sandstone (fluvial bar and channel deposits), 2) beds of alternating laminae of sandstone and mudstone (fluvial overbank or floodplain deposits), 3) ≥ 1 m-thick beds of clay (swamp deposits, floodplain deposits, and/or sediment that accumulated in abandoned fluvial channels), 4) 0.2–0.5 m-thick planar to slightly undulatory beds of framework-supported sandstone with a mud matrix (traction-dominated current deposits at the top of fluvial bars, upper-flow-regime bedform deposits in subsidiary fluvial channels, or coarse-grained overbank deposits), and 5) sandstone to conglomeratic sandstone cemented by iron (interpreted as fluvial bar and channel deposits, with the iron cement being a diagenetic “groundwater ferricrete” that formed via the circulation of shallow groundwater and the oxidation of iron-bearing minerals). Kaolinite in various forms is pervasive throughout the formation and is interpreted as an early diagenetic phenomenon that formed by prolonged postdepositional weathering and flushing by meteoric water under a warm and humid paleoclimate. The fluvial system that formed the Middendorf Formation prograded into the area from the west or northwest from uplifted margins of Mesozoic rift basins and/or the Appalachian Mountains. This progradation was a response to a base-level fall and the sediment accumulated during base-level lowstand and subsequent early transgression. In Chesterfield County, the Middendorf Formation can be subdivided into three fining-upward sequences. Each sequence consists predominantly of medium to coarse sand with a greater abundance of gravel in the lower part of the sequence and a greater abundance of clay and silt beds in the upper part. Each sequence is interpreted as either a response to autogenic processes or a response to allogenic sea-level changes, specifically a higher-order (higher-frequency) progression from relative lowstand conditions to early transgression whereby coarse sand and gravel (e.g., fluvial bar and channel deposits) were preserved during initial lowstand conditions and a greater proportion of mud and finer-grained sand (floodplain deposits) were preserved during subsequent early transgression. The Middendorf Formation is correlative with several other kaolinite-rich fluvial sandstones in North America including the Raritan Formation in New Jersey, the Tuscaloosa Formation of the eastern Gulf of Mexico (Alabama, Mississippi, Louisiana), the Woodbine Formation of the central Gulf of Mexico (Texas), and the Frontier Formation of Wyoming. The accumulation and preservation of these formations occurred in response to a Turonian eustatic sea-level fall and subsequent transgression, and the early diagenetic kaolinite in these formations is attributed to similar warm and humid paleoclimate conditions.

South Carolina↗

High-resolution mapping of the freshwater-brine interface using deterministic and Bayesian inversion of airborne electromagnetic data at Paradox Valley, USA

Salt loads in the Colorado River Basin are a primary water quality concern. Natural groundwater brine discharge to the Dolores River where it passes through the collapsed salt anticline of the Paradox Valley in western Colorado is a significant source of salt to the Colorado River. An airborne electromagnetic survey of Paradox Valley has provided insights into the 3D distribution of brine in the surficial aquifer. A combination of stochastic and deterministic resistivity inversions were used to interpret the top of the freshwater-brine interface and to qualitatively describe the vertical salinity gradients across the interface. Low-resistivity regions indicative of brine occur near the land surface where brine discharges to the Dolores River and increase in depth several kilometers up-gradient along the axis of the valley. The most conductive parts of the brine plume are found in the areas below and adjacent to the river, suggesting that the brine becomes shallower and more concentrated as it reaches its natural discharge location. A significant freshwater lens overlying the brine west of the Dolores River is spatially correlated to the intermittent West Paradox Creek and agricultural irrigation. Below this lens, the transition from freshwater to brine appears to occur abruptly over a few meters and correlates to available well information. However, away from these regions and particularly with distance from the river, the freshwater-brine interface appears to be more diffuse.

Colorado↗

Paleoecology of Middle Pennsylvanian-age peat-swamp plants in Herrin coal, Kentucky, U.S.A.

To develop a method for quantifying the vegetation of Pennsylvania-age coal beds, of four coal-ball (permineralized peat) profiles and four coal column samples from the Herrin coal bed (Kentucky No. 11) Carbondale Formation in western Kentucky were compared. An estimated 89.5% of the coal can be identified botanically. Compaction ratios for individual tissues were estimated using point counts of organic matter in coal balls. The estimated abundances of major plant groups (lycopods, ferns, sphenopsids, and pteridosperms) in coal balls differ by less than 10% compared to coal after accounting for differential compaction of plant tissues. Standard deviations in taxonomic and maceral composition among coal columns are generally less than 2%. Consistent differences in botanical composition were found between benches showing that the method is consistent when applied to sufficient thicknesses of coal. It was not possible to make fine-scale correlations within the coal bed using the vegetational data; either the flora varied considerably from place to place or the method of quantification is unreliable for small increments of coal (5 cm or less). In the coal, pteridosperm abundance is positively correlated with underlying shale partings. This correlation suggests that pteridosperms are favored either by higher nutrient levels or disturbance. In the third of four benches in the Herrin coal bed, a succession from Sigillaria -containing zones to zones dominated by Lepidophloios hallii is interpreted as a shift towards wetter conditions. In the other benches, the main factors controlling the taxonomic composition appear to have been the relative abundance of nutrients and/or the frequency of disturbance as indicated by the relative abundance of partings. Criteria for distinguishing between domed and planar swamps are discussed. These include: distribution of partings, type of plant succession, and changes in plant diversity, average plant size, preservational quality and sporinite content. The infrequency of partings in bench C suggests a peat dome developed while the peat of that bench was accumulating but other evidence either fails to support the development of a peat dome or is ambiguous. The maceral composition resembles those of other Carboniferous coals which are thought to have formed from planar peat swamps. Formation of fusain bands appears to be associated with processes occurring above the peat surface, such as burning or prolonged oxidative exposure. Oxidation of accumulated peat is unlikely because fusain bands rarely include more than a single plant.

International Journal of Coal Geology↗

Aftershock triggering by complete Coulomb stress changes

We examine the correlation between seismicity rate change following the 1992, M 7.3, Landers, California, earthquake and characteristics of the complete Coulomb failure stress (CFS) changes (ΔCFS( t )) that this earthquake generated. At close distances the time-varying “dynamic” portion of the stress change depends on how the rupture develops temporally and spatially and arises from radiated seismic waves and from permanent coseismic fault displacement. The permanent “static” portion (ΔCFS) depends only on the final coseismic displacement. ΔCFS diminishes much more rapidly with distance than the transient, dynamic stress changes. A common interpretation of the strong correlation between ΔCFS and aftershocks is that load changes can advance or delay failure. Stress changes may also promote failure by physically altering properties of the fault or its environs. Because it is transient, ΔCFS( t ) can alter the failure rate only by the latter means. We calculate both ΔCFS and the maximum positive value of ΔCFS( t ) (peak ΔCFS( t )) using a reflectivity program. Input parameters are constrained by modeling Landers displacement seismograms. We quantify the correlation between maps of seismicity rate changes and maps of modeled ΔCFS and peak ΔCFS( t ) and find agreement for both models. However, rupture directivity, which does not affect ΔCFS, creates larger peak ΔCFS( t ) values northwest of the main shock. This asymmetry is also observed in seismicity rate changes but not in ΔCFS. This result implies that dynamic stress changes are as effective as static stress changes in triggering aftershocks and may trigger earthquakes long after the waves have passed.

Journal of Geophysical Research B: Solid Earth↗

Genetic structure of an expanding population of Humpback Chub in Grand Canyon

Objective Humpback Chub (HBC) Gila cypha in Grand Canyon declined in abundance and distribution over the latter part of the 20th century but have substantially increased in abundance and distribution over the past two decades. Although previous genetic work suggested that HBC in Grand Canyon belong to one genetic group, here we evaluate the genetic structure of HBC in Grand Canyon to determine whether relic populations in western Grand Canyon may have contributed unique variation to the recent population expansion or whether differences in behavior linked to migration in eastern Grand Canyon may promote assortative mating and heretofore unrecognized population structure. Methods Using fin clips collected from 167 individual HBC representing four sampling sites within Grand Canyon, we extracted DNA and developed data sets consisting of approximately 20,000 anonymous genomic loci. We quantified patterns of genetic diversity, and we accounted for outlier single-nucleotide polymorphisms to ensure that our interpretations of genetic patterns were not misled by adaptive processes and did not mask adaptively important genetic variation. Results Despite behavioral variation and the possibility that individuals with unique genetic variation survived in isolated warmwater sites within western Grand Canyon, HBC were not differentiated by sampling site or by differences in migratory behavior. Heterozygosity and nucleotide diversity were consistently high among sampling sites, and inbreeding coefficients were close to zero. Conclusions The HBC in Grand Canyon constitute a single genetic population. Our results do not preclude a genetic basis to migratory behavior, but our data suggest that this trait does not lead to assortative mating. Furthermore, while HBC may have survived in discontiguous warmwater refugia in western Grand Canyon during decades when the main stem was too cold for spawning, our data did not reveal any noticeable spatial variability in HBC genetics in the main stem after the recent HBC population expansion.

Arizona↗

Accumulation of dechlorination daughter products: A valid metric of chloroethene biodegradation

In situ reductive dechlorination of perchloroethene (PCE) and trichloroethene (TCE) generates characteristic chlorinated (cis-dichloroethene [cis-DCE] and vinyl chloride [VC]) and nonchlorinated (ethene and ethane) products. The accumulation of these daughter products is commonly used as a metric for ongoing biodegradation at field sites. However, this interpretation assumes that reductive dechlorination is the only chloroethene degradation process of any significance in situ and that the characteristic daughter products of chloroethene reductive dechlorination persist in the environment. Laboratory microcosms, prepared with aquifer and surface-water sediments from hydrologically diverse sites throughout the United States and amended with [1,2- 14 C] TCE, [1,2- 14 C] DCE, [1,2- 14 C] DCA, or [1,2- 14 C] VC, demonstrated widely variable patterns of intermediate and final product accumulation. In predominantly methanogenic sediment treatments, accumulation of 14 C-DCE, 14 C-VC, 14 C-ethene, and 14 C-ethane predominated. Treatments characterized by significant Fe(III) and/or Mn(IV) reduction, on the other hand, demonstrated substantial, and in some cases exclusive, accumulation of 14 CO 2 and 14 CH 4 . These results suggest that relying on the accumulation of cis-DCE, VC, ethene, and ethane may substantially underestimate overall chloroethene biodegradation at many sites.

Remediation Journal↗

Light-toned salty soils and co-existing Si-rich species discovered by the Mars Exploration Rover Spirit in Columbia Hills

Light-toned soils were exposed, through serendipitous excavations by Spirit Rover wheels, at eight locations in the Columbia Hills. Their occurrences were grouped into four types on the basis of geomorphic settings. At three major exposures, the light-toned soils are hydrous and sulfate-rich. The spatial distributions of distinct types of salty soils vary substantially: with centimeter-scaled heterogeneities at Paso Robles, Dead Sea, Shredded, and Champagne-Penny, a well-mixed nature for light-toned soils occurring near and at the summit of Husband Hill, and relatively homogeneous distributions in the two layers at the Tyrone site. Aeolian, fumarolic, and hydrothermal fluid processes are suggested to be responsible for the deposition, transportation, and accumulation of these light-toned soils. In addition, a change in Pancam spectra of Tyrone yellowish soils was observed after being exposed to current Martian surface conditions for 175 sols. This change is interpreted to be caused by the dehydration of ferric sulfates on the basis of laboratory simulations and suggests a relative humidity gradient beneath the surface. Si-rich nodules and soils were observed near the major exposures of S-rich soils. They possess a characteristic feature in Pancam visible near-infrared (Vis-NIR) spectra that may be diagnostic of hydrated species, and this spectral feature can be used to search for additional Si-rich species. The exposures of hydrated salty soils within various geomorphic settings imply the potential existence of hydrous minerals in similar settings over a much wider area. Hydrous sulfates represent one of the candidates that may contribute the high level of water equivalent hydrogen in equatorial regions detected by the Neutron Spectrometer on Mars Odyssey.

Journal of Geophysical Research↗

Gravity survey of the Mount Toondina impact structure, South Australia

Gravity and seismic reflection data, together with geologic mapping, indicate that the Mount Toondina feature in South Australia is best interpreted as an eroded 4-km-diameter impact structure consisting of a ring structural depression surrounding a pronounced central uplift. Beds at the center of the structure within the central uplift have been raised as much as 200 m from depth and deformed by convergent flow. Seismic reflection data indicate that deformation extends to depths of only ≈800 m; at greater depths the reflectors are nearly flat lying, indicating little or no deformation. Gravity data show residual anomalies of +1.0 mGal coincident with the central uplift and a −0.5 Mgal low associated with the ring structural depression. Modeling of the gravity data indicates that relatively high-density material occurs within the central uplift, whereas the ring depression is filled with low-density material. The deformation at Mount Toondina is typical of a complex impact crater; the 4-km diameter is consistent with the expected threshold size for complex craters formed in weak to moderate strength sedimentary rocks.

South Australia↗

Historical seismograms for unravelling a mysterious earthquake: The 1907 Sumatra Earthquake

History of instrumental seismology is short. Seismograms are available only for a little more than 100 years; high-quality seismograms are available only for the last 50 years and the seismological database is very limited in time. To extend the database, seismograms of old events are of vital importance. Many unusual earthquakes are known to have occurred, but their seismological characteristics are poorly known. The 1907 Sumatra earthquake is one of them (1907 January 4, M = 7.6). Gutenberg and Richter located this event in the outer-rise area of the Sunda arc. This earthquake is known to be anomalous because of its extensive tsunami, which is disproportionate of its magnitude. The tsunami affected the coastal areas over 950 km along the Sumatran coast. We investigated this earthquake using the historical seismograms we could collect from several seismological observatories. We examined the P -wave arrival times listed in the Strassburg Bulletin (1912) and other station bulletins. The scatter of the Observed−Computed traveltime residuals ranges from –30 to 30 s, too large to locate the event accurately. The uncertainty of the epicentre estimated from an S-P grid-search relocation study is at least 1° (∼110 km). We interpreted the Omori seismograms from Osaka, Mizusawa and Tokyo, and the Wiechert seismograms from Göttingen and Uppsala by comparing them with the seismograms simulated from modern broad-band seismograms of the 2002, 2008 and two 2010 Sumatra earthquakes which occurred near the 1907 earthquake. From the amplitude of Rayleigh waves recorded on the Omori seismograms we conclude that the magnitude of the 1907 earthquake at about 30 to 40 s is about 7.8 (i.e. 7.5 to 8.0). The SH waveforms recorded on the Göttingen and Uppsala seismograms suggest that the 1907 earthquake is a thrust earthquake at a shallow depth around 30 km. The most likely scenario is that the 1907 earthquake initiated on the subduction interface, and slowly ruptured up-dip into the shallow sediments and caused the extensive tsunami. Although their quantity and quality are limited, historical seismograms provide key quantitative information about old events that cannot be obtained otherwise. This underscores the importance of preserving historical seismograms.

Geophysical Journal International↗

Paleohydrology and paleochemistry of Lake Manitoba, Canada: the isotope and ostracode records

Lake Manitoba, the largest lake in the Prairie region of North America, contains a fine-grained sequence of late Pleistocene and Holocene sediment that documents a complex postglacial history. This record indicates that differential isostatic rebound and changing climate have interacted with varying drainage basin size and hydrologic budget to create significant variations in lake level and limnological conditions. During the initial depositional period in the basin, the Lake Agassiz phase (???12-9 ka), ??18O of ostracodes ranged from -16??? to -5??? (PDB), implying the lake was variously dominated by cold, dilute glacial meltwater and warm to cold, slightly saline water. Candona subtriangulata, which prefers cold, dilute water, dominates the most negative ??18O intervals, when the basin was part of proglacial Lake Agassiz. At times during this early phase, the ??18O of the lake abruptly shifted to higher values; euryhaline taxa such as C. rawsoni or Limnocythere ceriotuberosa, and halobiont taxa such as L. staplini or L. sappaensis are dominant in these intervals. This positive covariance of isotope and ostracode records implies that the lake level episodically fell, isolating the Lake Manitoba basin from the main glacial lake. ??18O values from inorganic endogenic Mg-calcite in the post-Agassiz phase of Lake Manitoba trend from -4??? at 8 ka to -11??? at 4.5 ka. We interpret that this trend indicates a gradually increasing influence of isotopically low (-20??? SMOW) Paleozoic groundwater inflow, although periods of increased evaporation during this time may account for zones of less negative isotopic values. The ??18O of this inorganic calcite abruptly shifts to higher values (-6???) after ???4.5 ka due to the combined effects of increased evaporative enrichment in a closed basin lake and the increased contribution of isotopically high surface water inflow on the hydrologic budget. After ???2 ka, the ??18O of the Mg-calcite fluctuates between -13??? and -7???, implying short-term variability in the lake's hydrologic budget, with values indicating the lake varied from outflow-dominated to evaporation-dominated. The ??13C values of Mg-calcite remain nearly constant from 8 to 4.5 ka and then trend to higher values upward in the section. This pattern suggests primary productivity in the lake was initially constant but gradually increased after 4.5 ka. ?? 1994 Kluwer Academic Publishers.

Journal of Paleolimnology↗

The use of MAGSAT data to determine secular variation

A combined spatial and secular variation model of the geomagnetic field, labeled M061581, is derived from a selection of Magsat data. Secular variation (SV) data computed from linear fits to midnight hourly values from 19 magnetic observatories were also included in the analysis but were seen to have little effect on the model. The SV patterns from this new model are compared with those from the 1980 IGRF and with those for 1970 computed by the DGRF and with the 1960 patterns computed using the GSFC(12/66) model. Most of the features of the M061581 are identical in location and level with those of the 1980 IGRF. Together they confirm that the reversals in sign of field change seen over Asia and North America between 1965 and 1975 are reverting to the pre-1965 states. The M061581 model gives −32 nT/yr for the dipole decay rate, larger than the 70% increase already reported since 1965. This abnormally high value is interpreted as being a defect of the model because it appears to result from a much larger (−100 nT/yr) drop in field over the polar regions not indicated by the 1980 IGRF. This north polar decrease is shown to be of external origin as the result of a combination of the seasonal effect of the north polar ionospheric (counterclockwise) afternoon Sq p cell increasing in intensity from the beginning (November 1979) to the end (June 1980) of the Magsat data collection period, coupled with an enhancement of its effect as the orbit lowered from the 350– 550 km initial altitudes to near 200 km just prior to burnup. This experiment indicates that secular variation can be obtained from satellite data for intervals of less than a full year if corrections can be made for seasonal effects and that ‘annual snapshots’ of the field by a satellite would allow easy and accurate models of secular change without the use of any surface data.

Journal of Geophysical Research Solid Earth↗

Characterization of coal-derived hydrocarbons and source-rock potential of coal beds, San Juan Basin, New Mexico and Colorado, U.S.A.

Coal beds are considered to be a major source of nonassociated gas in the Rocky Mountain basins of the United States. In the San Juan basin of northwestern New Mexico and southwestern Colorado, significant quantities of natural gas are being produced from coal beds of the Upper Cretaceous Fruitland Formation and from adjacent sandstone reservoirs. Analysis of gas samples from the various gas-producing intervals provided a means of determining their origin and of evaluating coal beds as source rocks. The rank of coal beds in the Fruitland Formation in the central part of the San Juan basin, where major gas production occurs, increases to the northeast and ranges from high-volatile B bituminous coal to medium-volatile bituminous coal ( R m values range from 0.70 to 1.45%). On the basis of chemical, isotopic and coal-rank data, the gases are interpreted to be thermogenic. Gases from the coal beds show little isotopic variation ( δ 13 C 1 values range −43.6 to −40.5 ppt), are chemically dry (C 1 /C 1–5 values are > 0.99), and contain significant amounts of CO 2 (as much as 6%). These gases are interpreted to have resulted from devolatilization of the humic-type bituminous coal that is composed mainly of vitrinite. The primary products of this process are CH 4 , CO 2 and H 2 O. The coal-generated, methane-rich gas is usually contained in the coal beds of the Fruitland Formation, and has not been expelled and has not migrated into the adjacent sandstone reservoirs. In addition, the coal-bed reservoirs produce a distinctive bicarbonate-type connate water and have higher reservoir pressures than adjacent sandstones. The combination of these factors indicates that coal beds are a closed reservoir system created by the gases, waters, and associated pressures in the micropore coal structure. In contrast, gases produced from overlying sandstones in the Fruitland Formation and underlying Pictured Cliffs Sandstone have a wider range of isotopic values ( δ 13 C 1 values range from −43.5 to −38.5 ppt), are chemically wetter (C 1 /C 1–5 values range from 0.85 to 0.95), and contain less CO 2 (< 2%). These gases are interpreted to have been derived from type III kerogen dispersed in marine shales of the underlying Lewis Shale and nonmarine shales of the Fruitland Formation. In the underlying Upper Cretaceous Dakota Sandstone and Tocito Sandstone Lentil of the Mancos Shale, another gas type is produced. This gas is associated with oil at intermediate stages of thermal maturity and is isotopically lighter and chemically wetter at the intermediate stage of thermal maturity as compared with gases derived from dispersed type III kerogen and coal; this gas type is interpreted to have been generated from type II kerogen. Organic matter contained in coal beds and carbonaceous shales of the Fruitland Formation has hydrogen indexes from Rock-Eval pyrolysis between 100 and 350, and atomic H:C ratios between 0.8 and 1.2. Oxygen indexes and atomic O:C values are less than 24 and 0.3, respectively. Extractable hydrocarbon yields are as high as 7,000 ppm. These values indicate that the coal beds and carbonaceous shales have good potential for the generation of liquid hydrocarbons. Voids in the coal filled with a fluorescent material that is probably bitumen is evidence that liquid hydrocarbon generation has taken place. Preliminary oil-source rock correlations based on gas chromatography and stable carbon isotope ratios of C 15+ hydrocarbons indicate that the coals and (or) carbonaceous shales in the Fruitland Formation may be the source of minor amounts of condensate produced from the coal beds at relatively low levelsof thermal maturity ( R m =0.7).

International Journal of Coal Geology↗

Application of environmental tracers to mixing, evolution, and nitrate contamination of ground water in Jeju Island, Korea

Tritium/helium-3 ( 3 H/ 3 He) and chlorofluorocarbons (CFCs) were investigated as environmental tracers in ground water from Jeju Island (Republic of Korea), a basaltic volcanic island. Ground-water mixing was evaluated by comparing 3 H and CFC-12 concentrations with lumped-parameter dispersion models, which distinguished old water recharged before the 1950s with negligible 3 H and CFC-12 from younger water. Low 3 H levels in a considerable number of samples cannot be explained by the mixing models, and were interpreted as binary mixing of old and younger water; a process also identified in alkalinity and pH of ground water. The ground-water CFC-12 age is much older in water from wells completed in confined zones of the hydro-volcanic Seogwipo Formation in coastal areas than in water from the basaltic aquifer. Major cation concentrations are much higher in young water with high nitrate than those in uncontaminated old water. Chemical evolution of ground water resulting from silicate weathering in basaltic rocks reaches the zeolite–smectite phase boundary. The calcite saturation state of ground water increases with the CFC-12 apparent (piston flow) age. In agricultural areas, the temporal trend of nitrate concentration in ground water is consistent with the known history of chemical fertilizer use on the island, but increase of nitrate concentration in ground water is more abrupt after the late 1970s compared with the exponential growth of nitrogen inputs.

Jeju Island↗

Seismicity and detection/location threshold in the southern Great Basin seismic network

A spatially varying model of the detection/location capabilities of the Southern Great Basin seismic network (SGBSN) has been derived that is based on simple empirical relations and statistics. This permits use of almost all the catalog data gathered; instead of ignoring data that are below the threshold of completeness, a spatially varying threshold model is developed so that subregions having lower completeness levels than the network as a whole can be outlined and the completeness level of each sub-region determined. Such a model is required to unambiguously identify regions that are aseismic due to natural processes rather than to limited detection and/or location capabilities. Accounting for spatial variations in detection/location threshold is also important for studies in which magnitude-frequency distributions are interpreted in terms of source scaling properties. The characteristics of the spatial distribution of earthquakes, where earthquake clusters and aseismic regions locate, appear to be stable at all magnitude levels so that inferences about where strain is being accommodated will be the same whether numbers of earthquakes or strain estimated from seismic moments are examined. For the southern Great Basin region these principal characteristics include clusters at the northern end of the Furnace Creek fault and in the Pahranagat Shear Zone, and a relatively large number of earthquakes in the northern and southeastern portions of the Nevada Test Site. These clusters cover regions much larger than the surface projections of any of the mapped faults. The extent to which seismicity is induced by nuclear testing is unclear. The predominantly aseismic regions include the area west of the Death Valley/Furnace Creek fault system and an almost complete absence of events at Yucca Mountain. Finally, a considerable number of isolated events in the SGBSN catalog cannot be correlated with mapped faults.

Journal of Geophysical Research↗