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USGS1957

Geology of possible petroleum provinces in Alaska

The history of petroleum exploration in Alaska and the geology of possible petroleum provinces in Alaska are reviewed. Maps showing Alaska's major Mesozoic and Tertiary tectonic elements, possible petroleum provinces, and indications of petrol, are included in this report. Annotated references in Geological Survey publications relating to petroleum and oil shale in Alaska are given at the end of the report. For the purpose of appraising its petroleum possibilities, Alaska is divided into the southern, central, and northern major geologic-physiographic regions. Southern Alaska includes the arcuate mountain chain formed by the Alaska and Aleutian Ranges and the Mentasta- Nutzotin Mountains, the coastal range and valley area to the south, and the southeastern Alaska "panhandle" -- an area of 185,000 square miles. Oil seeps on the west shore of Cook Inlet in southern Alaska were known as early as 1853, and claims were staked in this region in 1882. Drilling began near the oil seeps in the Katalla district about 1901, and this started Alaska's first period of oil activity. From 1902 to 1933 the Katalla field produced 154,000 barrels of oil from fractured shale and sandstone of Tertiary age the- first and only commercial production in Alaska. On the basis of geology, surficial indications of petroleum, and test wells drilled, six possible petroleum provinces are indicated in southern Alaska. They are Heceta Island area, Keku Islands area, Cook Inlet Mesozoic province, Gulf of Alaska Tertiary province, Cook Inlet Tertiary province, and Copper River basin. The exposed rocks in the Heceta Island area include lower Paleozoic graywacke-type sandstone, sandstone, conglomerate, and massive limestones with reeflike structures; igneous rocks are rare or lacking in much of the area. The Kosciusko-Tuxekan-Heceta synclinorium, the main structural feature, is modified by minor folds and faults. Some of the minor folds are reported to be broad and open, with flanks dipping 20°-145°. As far as known, the Heceta Island area has not heretofore been seriously considered as a possible petroleum province. Rocks of Silurian to Cretaceous age are exposed in the Keku Island area and include moderately folded and relatively unaltered limestone and other marine sedimentary rocks. The Cook Inlet Mesozoic province, a land area of approximately 18,500 square miles, includes a great thickness of unmetamorphosed marine sedimentary rocks of Jurassic and Cretaceous age. At least 23 test wells were drilled or started in this province by the end of 1955. Shows of oil and gas were encountered in many of these wells. During 1955 at least ten oil companies were active in this area and by the end of 1955 about 1 1/2 million acres were included in oil and gas leases applied for or granted. The Gulf of Alaska Tertiary province includes about 5,200 square miles in which rocks of Tertiary age are exposed or are believed to underlie Quaternary deposits. Between 1901 and the end of 1955 about 47 wells were drilled or started in this province. The Cook Inlet Tertiary province embraces an area of about 9,500 square miles, of which about 4,100 is covered by the shallow waters of Cook Inlet. Petroleum exploration has been in that part of the area which overlaps the Cook Inlet Mesozoic province. Eocene or younger Tertiary nonmarine sedimentary rocks are believed to underlie much of the province, and marine rocks of Tertiary age may also be present. The Copper River basin is a topographic basin underlain by unconsolidated deposits of Quaternary age. Tertiary rocks favorable for the accumulation of petroleum may underlie part of the basin but this is not believed likely. Except for some leasing activity no petroleum exploration has been recorded in the Copper River Basin to the end of 1955. Central Alaska is a region of about 275,000 square miles and consists of an irregular assemblage of intricately dissected uplands and alluvium-floored lowland basins. Scattered peaks of resistant intrusive igneous rocks surmount most of the upland areas. In the vast region of central Alaska only six test wells are known to have been drilled for the purpose of finding oil and gas. The maximum depth reached was 350 feet and the holes were mostly or entirely in Quaternary deposits. In recent years several oil companies have investigated some parts of the region and large areas in the Yukon-Koyukuk province are now under lease. Oil seeps, gas seeps, and other indications of petroleum have been reported from many localities; samples from two localities have been analyzed and reported to be petroleum. The geology of central Alaska is similar in a general way to that of the area between the Rocky Mountains and Sierra-Cascade belts of the United States. Sedimentary rocks, probably equivalent to the Precambrian Belt series, and rocks of the Cambrian and all younger geologic systems have been recognized in central Alaska. The structure of the region is known to be complex, but except in local mineral districts, it has not been mapped in detail. Based on the limited amount of available information, the region cannot be regarded as distinctly favorable for significant accumulations of petroleum. However, three pre-Cenozoic provinces, the Yukon-Koyukuk, the Kobuk, and the Kandik, and several large Cenozoic basin provinces may be worthy of further investigation. Northern Alaska includes the Brooks Range and all the treeless tundra north to the Arctic Coast, an area of about 125,000 square miles. The presence of oil seeps along the Arctic Coast has been known at least since 1900 and a description of the Cape Simpson oil seeps vas published in 1909. Since then oil and gas seeps have been described from nine localities, and oil shales and oil-bearing sandstones are known from many localities in the Arctic Foothills province. Oil and gas deposits have been discovered and geologic conditions are favorable for oil and gas accumulations in approximately half of the region. In 1923 approximately 37,000 square miles in northern Alaska was reserved by Executive order as Naval Petroleum Reserve No. 4. In 1944 the U. S. Navy began a vast petroleum exploration program which was suspended in 1953. In the years 1945 through 1955, 37 test wells and 45 core tests were drilled on 18 structures. Three oil fields, Umiat, Simpson, and Fish Creek, and two gas fields, South Barrow and Gubik, were discovered. Total reserve estimates for all discoveries of oil to 1955 range from 30 to 100 million barrels, and for gas, from 370 billion to 900 billion cubic feet. All northern Alaska, with the exception of the Brooks Range, can be considered a possible petroleum province, but the region can be subdivided into provinces of somewhat different potentialities. These subdivisions roughly correspond with the geomorphic provinces and sections, which in turn reflect differences in geology. The known oil-bearing beds are of Mesozoic age, primarily Cretaceous, and thus the possible petroleum provinces could be designated as Mesozoic. However, Paleozoic and Cenozoic rocks with favorable reservoir characteristics are exposed in the region and possibly underlie, in favorable structural situations, some of the areas as yet not tested. The Arctic Coastal Plain province includes gently folded and flat-lying Mesozoic beds that overlie a basement complex of Paleozoic and early Mesozoic age. Near the southern edge of this province the basement rocks are at depths of at least 20,000 feet, and to the north these rocks rise to within 2,500 feet of the surface. The Teshukpuk Lake section of the Arctic Coastal plain includes many of the known oil seeps; it is the most accessible to sea transportation, and lies almost completely within NPR 4. Thirteen test wells and 35 core tests have been drilled here; one gas field and two (at present, noncommercial) oil fields have been discovered. The possibility of further discoveries may depend largely on locating porous sandstones in stratigraphic rather than anticlinal traps. The White Hills section is distinguished topographically from the Teshukpruk section by its white-gravel-covered hills and fever lakes, and geologically by the presence of Tertiary rocks, including 2,000 feet of nonmarine beds in the west and at least 7,000 feet of marine beds to the east, in the vicinity of Carter Creek. This section appears to be more complex structurally. No test wells have been drilled in the White Hills section. The Northern Foothills section includes many closed anticlines. Twenty-four test wells and ten core tests have been drilled on 11 structures and two discoveries have been made -the Umiat oil field and the Gubik gas field. All these tests have been drilled in Cretaceous rocks. The Southern Foothills section is structurally similar to the Alberta Foothills and to the northern part of the Brooks Range. Great thicknesses of marine shale of Lover Cretaceous, Jurassic, and Triassic age are exposed. The outcropping Mesozoic sandstones are generally poorly sorted, nonporous, and impermeable. To the south the section is bordered by mountainous exposures of Mississippian limestone, which probably underlie at least part of this section. The rocks that underlie the deeply eroded complex structures of the Brooks Range include schist, slate, argillite, and limestone. Some exposed limestones have a strong petroleum-like odor and contain traces of petroleum residues.

Alaska↗

USGS1981

Gulf of Mexico summary report 2, August 1981: A revision of Outer Continental Shelf oil and gas activities in the Gulf of Mexico and their onshore impacts: A summary report, September 1980

The Gulf of Mexico Outer Continental Shelf (OCS) continues to be the most intensively developed offshore oil- and gas-producing region in the world. With the development of technology, exploration, development, and production are being extended to include areas off the coast of southwest Florida and deep-water areas near the Mississippi River Delta. Development in both areas requires careful analyses of local considerations. The hydrocarbon potential of the region, while not well established in the frontier portions, generally remains favorable. A total of 482 fields have been discovered to date in the federally regulated part of the Gulf of Mexico. Reserve estimates have been made for the 435 producing fields in the region. Through December 31, 1980, those fields have produced 5.0 billion barrels of oil and condensate, and 48.7 trillion cubic feet of gas. Remaining recoverable reserves are 3.1 billion barrels of oil and 40.2 trillion cubic feet of gas. Estimates of undiscovered recoverable resources for the Gulf of Mexico are 6.6 billion barrels of oil and 71.9 trillion cubic feet of gas. Since enactment of the Outer Continental Shelf Lands Act in 1953, there have been 42 oil and gas lease sales in the Gulf of Mexico. An average of three lease sales per year are scheduled through 1986. Since 1953, the Bureau of Land Management (BLM) has leased 3,119 tracts in the Gulf of Mexico; 1,825 leases are currently active. The distribution of leased tracts exhibits a regionwide pattern as shown by Lease Sales A62, 62, A66, and 66. Proposed Lease Sales 67, 69, 72, and 74 will probably continue that pattern. Tracts off the coast of southwest Florida in the Charlotte Harbor, Howell Hook, and Pulley Ridge Areas will be offered in upcoming sales. Operations on tracts in deepwater areas slated for future sales may require additional technology. Exploration, development, and production in the Gulf of Mexico Region are continuing at a rapid pace throughout the Gulf of Mexico. Between January 1, 1980, and April 15, 1981, 197 initial plans of exploration and 165 supplemental plans of exploration were submitted to the U.S. Geological Survey (USGS). During the same period, 107 initial and 131 supplemental plans of development/production were submitted to the USGS. As of May 1981, there were 121 offshore mobile drilling units operating in the Gulf of Mexico. Pipelines continue to be the preferred mode of transport for Gulf of Mexico OCS oil and gas production. Pipeline additions to the existing network average 69 miles (111 km) per month. At any given time, numerous pipeline projects are under way in the Gulf of Mexico. To supplement OCS oil and gas production several deepwater port projects, designed to handle imported crude oil, are being planned or constructed in the region. The process of transportation planning in the Gulf of Mexico is done by industry and government through BLM's Intergovernmental Planning Program and its Regional Technical Working Group (RTWG). The RTWG has completed the First Edition Gulf of Mexico Regional Transportation Management Plan. The nearshore and onshore facilities in the Gulf of Mexico service both the domestic onshore and offshore oil and gas industry as well as the global market. Most of the major centers along the Gulf Coast, including Houston, Corpus Christi, Galveston, Beaumont, Port Arthur, and Freeport, Texas; New Orleans, Lake Charles, Lafayette, Baton Rouge, Morgan City, and Houma, Louisiana; Pascagoula, Mississippi; Mobile, Alabama; and Port Manatee, Florida, have ties to the offshore industry. A wide array of services and support industries, ranging from small independent vendors to major international manufacturing contractors, can be found within the region. Profiles of selected centers reveal typical industries and patterns of activity that are characteristic throughout the Gulf Coast region.

Alabama, Florida, Louisiana, Mississippi, Texas↗

USGS1906

The geography and geology of Alaska; a summary of existing knowledge, with a section on climate, and a topographic map and description thereof

Alaska, the largest outlying possession of the United States, is that great land mass forming the northwestern extremity of the North American continent, whose western point is within 60 miles of the Asiatic coast (PI. II). About one-quarter of this area lies within the Arctic Circle, and from the standpoint of geographic position must be regarded as an arctic province; but the southern seaboard, exposed to the warm winds and waters of the Pacific, gives to the entire southern portion of the territory" a comparatively warm climate. It is not generally realized that the range of climate in Alaska is greater than that between Florida and Maine. At the southernmost point of the Pacific coast the mean annual temperature is not far from that of the city of Washington, the winters being warmer and characterized by less snowfall; the Yukon Valley on the other hand has a winter climate similar to that of northern Montana and Dakota; while in the extreme northern part of the territory the meteorologic conditions are invariably arctic. Though as yet only sparsely settled, Alaska's vast area and great resources make it one of the most important possessions of the United States and promise its rapid development. During the years 1890 to 1900 the population increased from 32,052* to 63,592. The mineral output, which in 1890 was valued at less than $800,000, exceeded $9,000,000 in 1904, and the fisheries show a corresponding growth. This rapid development has attracted public attention and led to urgent demand for explorations, surveys, and other investigations. So actively has this work been pushed, both by public and private enterprise, that exact knowledge of the geography, geology, and mineral resources of the interior has made greater strides within the last eight years than during the preceding thirty-one years since the acquisition of Alaska. The facts regarding the geography and geology, scattered as they are through the many books and reports of this period, are not always readily accessible, and the time seems ripe to present them in a summarized form. The topography of Alaska is varied and complex (see PI. I), and it is not easy to present briefly even the salient features. The limited number of pages here devoted to the subject precludes the possibility of detailed treatment, even if the facts were available. Much of the description has been taken from the results attained by other investigators, the writer being personally familiar with only a part of this large province. A list of the publications consulted is appended. The larger geographic features of Alaska are now fairly well known, though the detailed surveys which are demanded by the development of many localities have hardly been begun. Preliminary surveys have been completed of all but three 8 of the larger rivers. The most important mountain ranges have been at least outlined (fig. 3). Only three large areas remain almost entirely unmapped: One in southwestern Alaska, between Cook Inlet and the lower Kuskokwim, and the others in northern Alaska, embracing the Arctic watershed east and west of the Colville River. Nearly all the surveys of the interior, however, have been of a preliminary and exploratory character, and to meet the requirements of exact geography must be followed by more detailed mensuration. Though the coast line has been fairly well known for more than half a century, knowledge of the interior has been gained chiefly within the last two decades. This has not yet found its way into text-books and has too often been entirely ignored by cartographers. If facts are presented which may seem elementary, it is because even well-informed people have been known to harbor misconceptions in regard to the orographic features, climate, and general character of Alaska. Those who read of the perils and privations of winter travel and explorations are apt to picture a region of ice and snow; others, again, who have personal knowledge of the tourist route of southeastern Alaska, regard the whole district as one of rugged mountains and glaciers. In point of fact, glaciers are now nearly limited to the ranges bordering the Pacific and to the two slopes of the Alaska range; and even during the greatest development of glaciers but a small portion of Alaska was under ice (see map, PI. XXII). As a treatise on geography would hardly be complete without some discussion of the climate, meteorologic data have been compiled by Mr. Cleveland Abbe, jr., but the discussion of this does not pretend to be more than a cursory treatment of the subject. The scope of the paper seems to require also a brief summary of the development of geographic knowledge of Alaska. This subject, with its many ramifications, is of fascinating interest and offers a magnificent field for the trained historian. If the accompanying sketch of discovery and exploration awakens any measure of popular interest the writer will feel amply rewarded for having attacked a theme which hardly falls within the scope of his investigations. When this compilation was begun it was intended to be chiefly a description of the topography of Alaska, as illustrated by the accompanying map (PI. XXXIV, in pocket), which was compiled under the direction of the late R. U. Goode. In the course of the work there accumulated much geologic as well as geographic material which seemed worthy of inclusion in the report. As no comprehensive statement of the geology of Alaska has been made since the modern epoch of investigation was begun, an attempt will be made to give a summary of all results achieved. Since the writer has obtained much of his knowledge of the facts from the work of others, he disclaims any pretense of making an entirely original contribution to geologic science. He feels, however, that a personal familiarity with a considerable part of the province, gained during seven consecutive seasons of field work, will justify Mm in presenting conclusions which may in some cases be at variance with those in the reports on which he must draw for his facts. Throughout this report attempt will be made to credit borrowed material to the source from which it is drawn. Where such matter has been obtained entirely from published reports there is no difficulty in so doing; but as regards investigators of the Geological Survey, with whom the writer has collaborated both in field and in office, the case is somewhat different, for it is not always possible to know whether this or that theory originated with the writer or with one of his colleagues. It will, then, perhaps suffice to state that this report could not have been prepared without the explorations and researches of the geologists, F. C. Schrader, Walter C. Mendenhall, Arthur J. Collier, J. E. Spurr, and Arthur C. Spencer; and the surveys of the topographers, T. G. Gerdine, D. C. Witherspoon, D. L. Reaburn, W. J. Peters, and E. C. Barnard. Each of these men, in the course of from two to six years of field work, has made important contributions to the knowledge of the geography and geology of Alaska, and not all of these results have yet been put in print. In the last season (1903) L. M. Prindle, C. W. Wright, Arthur Hollick, G. C. Martin, F. L. Hess, and Fred H. Moffit have carried on geologic work in Alaska, and the writer has made use of their work now in course of publication. He has also been fortunate in having access to the manuscript reports of Walter C. Mendenhall and F. C. Schrader on the Copper River basin, to which references will be made. The matter here presented should be credited in a measure to all of these investigators, but for many of the theories advanced the writer alone is responsible. As this manuscript goes to press there has been opportunity to incorporate some of the results of the field work of 1904. As far as possible these have been embodied in the text, but in some instances it has been found advisable to add them only as footnotes. During the past summer F. E. and C. W. Wright extended the geologic reconnaissance in southeastern Alaska. In southwestern Alaska G. C. Martin and T. W. Stanton have determined the general Mesozoic section, while F. H. Moffit has made a reconnaissance of the northern part of the Kenai Peninsula. A. J. Collier has mapped the geology of the Cape Lisburne region, and L. M. Prindle and F. L. Hess have made contributions to the knowledge of the metamorphic terranes of the Yukon-Tanana district. It is the writer's purpose to describe in nontechnical language the larger geographic features and discuss their relation as far as the data available will permit. In the treatment of the geology, however, less effort will be made to make the matter acceptable to the lay reader. It is hoped, however, that a brief summary of the salient features of the geologic history' may be not without interest to the general public. If this paper serves in some measure to dispel the popular fallacies regarding Alaska and to disseminate more accurate knowledge of its geographic and geologic features, the purpose of its publication will be accomplished.

Alaska↗

USGS2010

Global mineral resource assessment: porphyry copper assessment of Mexico: Chapter A in Global mineral resource assessment

Mineral resource assessments provide a synthesis of available information about distributions of mineral deposits in the Earth’s crust. A probabilistic mineral resource assessment of undiscovered resources in porphyry copper deposits in Mexico was done as part of a global mineral resource assessment. The purpose of the study was to (1) delineate permissive areas (tracts) for undiscovered porphyry copper deposits within 1 km of the surface at a scale of 1:1,000,000; (2) provide a database of known porphyry copper deposits and significant prospects; (3) estimate numbers of undiscovered deposits within those permissive tracts; and (4) provide probabilistic estimates of amounts of copper (Cu), molybdenum (Mo), gold (Au), and silver (Ag) that could be contained in undiscovered deposits for each permissive tract. The assessment was conducted using a three-part form of mineral resource assessment based on mineral deposit models (Singer, 1993). Delineation of permissive tracts primarily was based on distributions of mapped igneous rocks related to magmatic arcs that formed in tectonic settings associated with subduction boundary zones. Using a GIS, map units were selected from digital geologic maps based on lithology and age to delineate twelve permissive tracts associated with Jurassic, Laramide (~90 to 34 Ma), and younger Tertiary magmatic arcs. Stream-sediment geochemistry, mapped alteration, regional aeromagnetic data, and exploration history were considered in conjunction with descriptive deposit models and grade and tonnage models to guide estimates. The 12 permissive tracts delineated for this assessment are grouped by age (Jurassic-Early Cretaceous, Laramide (~90 to 34 Ma), Tertiary) and range in size from ~3,000 to 184,000 km 2 . Probabilistic estimates of numbers of undiscovered deposits were made for 10 tracts. A qualitative discussion is included for one Jurassic tract that extends into the U.S. from northern Mexico, and a preliminary outline of the northernmost part of a Tertiary tract that continues well to the south of Mexico is included in summary figures for reference. This assessment estimates that 39 undiscovered deposits contain an arithmetic mean estimate of ~144 million metric tons of copper or more in ten tracts for which probabilistic estimates were made, in addition to 21 porphyry copper deposits that contain identified resources of ~52 million metric tons of copper. Approximately 70 percent of the estimated mean undiscovered copper resources are associated with permissive tracts that contain identified resources; the remaining estimated resources are associated with permissive tracts with no reported porphyry copper resources. In addition to copper, the mean expected values of undiscovered byproduct resources predicted by the simulation are ~4 million metric tons of molybdenum, ~48 thousand metric tons of silver, and 4 thousand metric tons of gold. The probability associated with these arithmetic means is on the order of 30 percent. Median expected amounts of metals predicted by the simulations may be ~50 percent lower than mean estimates, and in some cases, zero. For tracts that contain identified resources, the ratios of undiscovered to identified copper resources indicate that: Jurassic-Early Cretaceous tracts MX-J1 and MX-J2 contain fewer estimated undiscovered copper resources (ratios <1) than identified resources; Laramide tract MX-L1 may contain significantly more copper than has been identified; Laramide tract MX-L2, the tract that contains most of the known deposits in Mexico, including the world-class deposits at Cananea and La Caridad, may contain about as much copper, molybdenum, and silver in undiscovered deposits and more gold than has been identified; Tertiary tracts MX-T1 and MX-T2, where no porphyry copper deposits are known, may contain undiscovered deposits; Tertiary tract MX-T3 may contain about three times more copper than has been identified; and Permissive tracts with no known deposits (MX-J3, MX-J5, MX-L3, MX-T1, MX-T2) contain approximately 30 percent of the total estimated undiscovered copper resources. Most porphyry copper exploration in Mexico focused on the exposed northern parts of the Laramide arc. This assessment suggests that the exposed and shallowly buried (<1 km) parts of the Laramide and Tertiary arcs delineated as permissive tracts are more likely to contain undiscovered deposits than are older (Jurassic-Early Cretaceous) arc segments. Interest in gold has prompted exploration of historical precious metal prospects and small mines in Mexico, some of which may represent high-sulfidation epithermal systems overlying or adjacent to porphyry copper systems. This report includes a brief overview of porphyry copper deposits in Mexico, a description of the assessment process used, a summary of results, and appendixes. Appendixes A through K contain summary information for each tract, as follows: location, the geologic feature assessed, the rationale for tract delineation, tables and descriptions of known deposits and significant prospects, exploration history, model selection, rationale for the estimates, assessment results, and references. The accompanying digital map files (shapefiles) provide permissive tract outlines, assessment results, and data for deposits and prospects in a GIS format (appendix L).

Scientific Investigations Report↗

USGS1993

Application of ground-penetrating radar methods in determining hydrogeologic conditions in a karst area, west-central Florida

Ground-penetrating radar (GPR) is useful as a surface geophysical method for exploring geology and subsurface features in karst settings. Interpretation of GPR data was used to infer lithology and hydrogeologic conditions in west-central Florida. This study demonstrates how GPR methods can be used to investigate the hydrogeology of an area. GPR transmits radio- frequency electromagnetic waves into the ground and receives reflected energy waves from subsurface interfaces. Subsurface profiles showing sediment thickness, depth to water table and clay beds, karst development, buried objects, and lake-bottom structure were produced from GPR traverses obtained during December 1987 and March 1990 in Pinellas, Hillsborough, and Hardee Counties in west-central Florida. Performance of the GPR method is site specific, and data collected are principally affected by the sediment and pore fluids, conductances and dielectric constants. Effective exploration depths of the GPR surveys through predominately unsaturated and saturated sand and clay sediments at five study sites ranged from a few feet to greater than 50 feet below land surface. Exploration depths were limited when high conductivity clay was encountered, whereas greater exploration depths were possible in material composed of sand. Application of GPR is useful in profiling subsurface conditions, but proper interpretation depends upon the user's knowledge of the equipment and the local hydrogeological setting, as well as the ability to interpret the graphic profile.

Water-Resources Investigations Report↗

USGS2023

A novel non-destructive workflow for examining germanium and co-substituents in ZnS

A suite of complementary techniques was used to examine germanium (Ge), a byproduct critical element, and co-substituent trace elements in ZnS and mine wastes from four mineral districts where germanium is, or has been, produced within the United States. This contribution establishes a comprehensive workflow for characterizing Ge and other trace elements, which captures the full heterogeneity of samples through extensive pre-characterization. This process proceeded from optical microscopy, to scanning electron microscopy and cathodoluminescence (CL) imaging, to electron microprobe analysis, prior to synchrotron-based investigations. Utilizing non-destructive techniques enabled reanalysis, which proved essential for verifying observations and validating unexpected results. In cases where the Fe content was <0.3 wt% in ZnS, cathodoluminescence imaging proved to be an efficient means to qualitatively identify trace element zonation that could then be further explored by other micro-focused techniques. Micro-focused X-ray diffraction was used to map the distribution of the non-cubic ZnS polymorph, whereas micro-focused X-ray fluorescence (μ-XRF) phase mapping distinguished between Ge 4+ hosted in primary ZnS and a weathering product, hemimorphite [Zn 4 Si 2 O 7 (OH) 2 ·H 2 O]. Microprobe data and μ-XRF maps identified spatial relationships among trace elements in ZnS and implied substitutional mechanisms, which were further explored using Ge and copper (Cu) X-ray absorption near-edge spectroscopy (XANES). Both oxidation states of Ge (4+ and 2+) were identified in ZnS along with, almost exclusively, monovalent Cu. However, the relative abundance of Ge oxidation states varied among mineral districts and, sometimes, within samples. Further, bulk XANES measurements typically agreed with micro-focused XANES (μ-XANES) spectra, but unique micro-environments were detected, highlighting the importance of complementary bulk and micro-focused measurements. Some Ge μ-XANES utilized a high energy resolution fluorescence detector, which improved spectral resolution and spectral signal-to-noise ratio. This detector opens new opportunities for exploring byproduct critical elements in complex matrices. Overall, the non-destructive workflow employed here can be extended to other byproduct critical elements to more fully understand fundamental ore enrichment processes, which have practical implications for critical element exploration, resource quantification, and extraction.

Frontiers in Earth Science↗

USGS1976

Geothermal handbook

The Bureau of Land Management offered over 400,000 hectares (one million acres) for geothermal exploration and development in 1975, and figure is expected to double this year. The Energy Research and Development Administration hopes for 10-15,000 megawatts of geothermal energy by 1985, which would require, leasing over 16.3 million hectares (37 million acres) of land, at least half of which is federal land. Since there is an 8 to 8-1/2 year time laf between initial exploration and full field development, there would have to be a ten-fold increase in the amount of federal land leased within the next three years. Seventy percent of geothermal potential, 22.3 million hectares (55 million acres), is on federal lands in the west. The implication for the Service are enormous and the problems immediate. Geothermal resource are so widespread they are found to some extent in most biomes and ecosystems in the western United States. In most cases exploitation and production of geothermal resources can be made compatible with fish and wildlife management without damage, if probable impacts are clearly understood and provided for before damage has unwittingly been allowed to occur. Planning for site suitability and concern with specific operating techniques are crucial factors. There will be opportunities for enhancement: during exploration and testing many shallow groundwater bodies may be penetrated which might be developed for wildlife use. Construction equipment and materials needed for enhancement projects will be available in areas heretofore considered remote projects will be available in areas heretofore considered remote by land managers. A comprehensive knowledge of geothermal development is necessary to avoid dangers and seize opportunities. This handbook is intended to serve as a working tool in the field. It anticipated where geothermal resource development will occur in the western United States in the near future. A set of environmental assessment procedures are presented which will allow the Service to provide input to the federal leasing process. As an impact information source by which to judge the appropriateness of a specific activity at a specific site, a discussion of activities-impacts is provided on a phase by phase basis. Mitigation and possible enhancement techniques are also presented so that the impacts of the development can be dealt with and the fish and wildlife situation improved. The Service can achieve its objective only if biological input is made throughout the entire process of geothermal development, from exploration to testing to full field operation. A discussion of geothermal leasing procedures emphasizes the timing and nature of Service participation in current interagency lease processing, and there is a provision for the utilization of new knowledge, techniques, and responses as experience is accumulated.

FWS/OBS↗

USGS2011

Development of a bioenergetics model for age-0 American shad

Bioenergetics modeling can be used as a tool to investigate the impact of non-native age-0 American shad ( Alosa sapidissima ) on reservoir and estuary food webs. The model can increase our understanding of how these fish influence lower trophic levels as well as predatory fish populations that feed on juvenile salmonids. Bioenergetics modeling can be used to investigate ecological processes, evaluate alternative research hypotheses, provide decision support, and quantitative prediction. Bioenergetics modeling has proven to be extremely useful in fisheries research (Ney et al. 1993,Chips and Wahl 2008, Petersen et al. 2008). If growth and diet parameters are known, the bioenergetics model can be used to quantify the relative amount of zooplankton or insects consumed by age-0 American shad. When linked with spatial and temporal information on fish abundance, model output can guide inferential hypothesis development to demonstrate where the greatest impacts of age-0 American shad might occur. Bioenergetics modeling is particularly useful when research questions involve multiple species and trophic levels (e.g. plankton communities). Bioenergetics models are mass-balance equations where the energy acquired from food is partitioned between maintenance costs, waste products, and growth (Winberg 1956). Specifically, the Wisconsin bioenergetics model (Hanson et al. 1997) is widely used in fisheries science. Researchers have extensively tested, reviewed, and improved on this modeling approach for over 30 years (Petersen et al. 2008). Development of a bioenergetics model for any species requires three key components: 1) determine physiological parameters for the model through laboratory experiments or incorporate data from a closely related species, 2) corroboration of the model with growth and consumption estimates from independent research, and 3) error analysis of model parameters. Wisconsin bioenergetics models have been parameterized for many of the salmonids and predatory fishes encountered in the lower Columbia River (Petersen and Ward 1999). The Wisconsin bioenergetics model has not been developed for American shad, however Limburg (1996) parameterized a simplified bioenergetics growth model for this species. A common application for the Wisconsin bioenergetics model is to estimate the consumption or growth of a fish population under different temperature and feeding scenarios (Ney 1993). One advantage of the bioenergetics approach is that consumption can be estimated without direct field measurements of predation rate (prey·predator -1 · day -1 ; Petersen and Ward 1999). Field estimates of fish consumption are time consuming and costly to determine, and estimates may show wide variance due to environmental and sampling variability. However, the consumption parameters used in a newly developed bioenergetics model must be verified with field and laboratory estimates of consumption (Ney 1993). The objective of this research was to parameterize a Wisconsin bioenergetics model for age-0 American shad using published physiological data on American shad and closely related alosine species. The American shad bioenergetics model will be used as a tool to explore various hypotheses about how age-0 American shad directly and indirectly affect Columbia River salmon through ecological interactions in lower Columbia River food webs. One over-arching focus of the larger research project was to identify potential interactions between age-0 American shad and juvenile salmonids, addressing potential outcomes through bioenergetics modeling scenarios. This report contains two bioenergetics modeling applications to demonstrate how these models can be used to address management questions and direct research effort. The first modeling application uses the American shad bioenergetics model described in this report to explore prey consumption by age-0 American shad (Chapter 1, this report). Dietary data on age-0 American shad and previously published reports on the diet of juvenile fall Chinook salmon (Rondorf et al. 1990, USGS unpublished data) suggested there might be considerable dietary overlap between these species in the lower Columbia River. The U.S. Geological Survey (USGS) was interested in using the American shad bioenergetics model to explore hypotheses concerning dietary overlap between age-0 American shad and emigrating fall Chinook salmon. The second modeling application uses the fall Chinook salmon bioenergetics model (Koehler et al. 2006) to explore the growth potential of juvenile fall Chinook salmon predating on age-0 American shad in the lower Columbia River. This modeling was based dietary information on a small number of age-0 fall Chinook salmon (n = 13) collected in John Day Reservoir in 1994 - 1996 (unpublished USGS data). Analysis of this dietary data found that these salmonids were feeding primarily on age-0 American shad (> 75% by weight).

Oregon↗

USGS2020

Precious and base metal mineralization within the lower stratigraphy of the Stillwater Complex: New targets defined and old targets revisited

Group Ten Metals is exploring for base and precious metals within the Stillwater Complex, a 2.7 Ga layered mafic/ultramafic intrusion, host to the world-class Sibanye platinum group element (PGE) mines. Group Ten controls approximately 25 kilometers of strike length of prospective mafic and ultramafic rocks in the western portion of the Complex. The property includes multiple target types and individual prospects. Stillwater Complex magmatic stratigraphy is divided into three major series based on the proportions of cumulus minerals—Basal, Ultramafic and Banded. Group Ten explores primarily within the lower third of the intrusion, from the Basal Series at the footwall contact, upwards into the Ultramafic Series which is divided into a lower Peridotite Zone and an upper Bronzitite Zone. Rocks of the Peridotite Zone are repetitive, laterally continuous and layered sequences of olivine, chromite and pyroxene cumulates. This model was developed in the eastern portion of the Complex. Mapping in the western portion of the Complex indicates that the Peridotite Zone is thinner than to the east and with cyclic units not as regularly developed. Group Ten has reviewed data from over 50 years of historical exploration in light of different commodity focus, land positions, analytical menus, and petrogenetic models to define a series of exploration targets. A six hole, 1,600 meter diamond drilling program targeting the Iron Mountain sector was completed in 2019; results are discussed in more detail below. At Iron Mountain the primary targets are Ni-Cu-PGE magmatic sulfides located within the Basal Series and lower Peridotite Zone, near the basal contact of the Complex. Important objectives included establishing the PGE tenor of sulfide mineralization drilled by AMAX in the 1970’s and penetrating basement rock rafts known to conceal mineralized (but not previously analyzed) ultramafic rocks beneath. Drilling also tested the PGE-enriched A-B chromitite package which rests stratigraphically above the previously tested zones. At Chrome Mountain, magmatic layering was disturbed or destroyed over large areas along a WNW axis that may be an artifact of early magma chamber deformation or result from much later, Laramide tectonism. Correlation of marker units, for example chromitite seams, are problematic in the disturbed area; these rocks are termed the Hybrid Unit. In addition, normal igneous stratigraphy appears to be intruded by discordant dunite masses, pyroxenite pegmatoids and magmatic breccias. This unusual assemblage of rock types is accompanied by significant and previously underappreciated PGE mineralization related to chromite schlieren and minor but persistent base metal sulfides.

Conference Paper↗

USGS2021

Tectonic and magmatic controls on the metallogenesis of porphyry deposits in Alaska

Porphyry Cu and Mo deposits and occurrences are found throughout Alaska; they formed episodically during repeated subduction and arc-continent collisions spanning the Silurian to Quaternary. Porphyry systems occur in continental-margin and island arcs, which are broadly grouped into pre-accretionary or post-accretionary arcs. Pre-Mesozoic occurrences formed in continental or island arcs prior to accretion onto the margin of North America, whereas Mesozoic and younger systems formed in arcs that developed after terrane fragments were accreted to the margin of North America. As a result, older porphyry systems are typically in the interior and northern metallogenic belts, whereas the younger porphyry systems are predominantly found in the southern third of the state, closer to the modern continental margin. Alaska porphyry formation peaked in the mid-Cretaceous and continued through the Late Cretaceous to Tertiary, in association with continental-margin arcs extending from the eastern interior, into southwest Alaska and along the Alaska Peninsula and Aleutian Islands. Porphyry system formation is not generally recognized in the Early Cretaceous, Triassic, or early Paleozoic – time periods that coincide with continental collisional events or extension. Relatively few pre-accretionary porphyry systems are documented in more deeply exhumed arc segments due to low preservation potential in areas of rapid or repeated bedrock uplift and associated erosion that occurred during later tectonic events. Significant diversity is observed in porphyry occurrences across the state and even within the same region. Occurrences form in association with arc-related intrusions or intrusive complexes, that range in composition from diorite to syenite, but are commonly monzonitic to granitic. Some porphyry occurrences are associated with alkaline intrusive belts that exhibit a stronger crustal contribution to magmatic sources. Intrusions associated with porphyry formation in Alaska are commonly moderately oxidized, however, a distinct group of porphyry systems are associated with more-reduced magmas. Hydrothermal alteration described at many occurrences exhibits zoning from proximal potassic alteration to typically peripheral and(or) later sericitic alteration, that is flanked by large zones of propylitic alteration. Diversity in alteration is observed where sodic and sodic-calcic alteration is present, commonly in more-enigmatic deposits, such as Island Mountain and Chicken Mountain. Advanced argillic alteration is rare, but present in notable examples, such as the Pebble porphyry Cu(-Au-Mo) deposit. Sulfide mineralization is characterized by pyrite, chalcopyrite, molybdenite, and rare bornite hosted in veinlets, veins and disseminations in wallrocks and causative intrusions. Some porphyry systems contain abundant pyrrhotite and(or) arsenopyrite in the mineral assemblages. Systems that exhibit bornite-bearing assemblages containing abundant molybdenite are commonly arsenic- and gold-poor and tend to be associated with more oxidized arc magmas. In contrast, those systems that are pyrrhotite and(or) arsenopyrite dominant tend to be gold, arsenic, and bismuth bearing, and are commonly associated with more-reduced magmas. Exploration for porphyry occurrences in Alaska has experienced a resurgence and currently constitutes about 20% of exploration dollars in the state. Many systems lack complete descriptions, and coupled with the cost of exploration, remain incompletely explored. Additional understanding of known occurrences combined with a framework geologic understanding of porphyry-bearing metallogenic belts will likely result in new discoveries in the future.

Alaska↗

USGS2025

Seamless Geologic Map Database for the Intermountain West, United States: A foundational dataset for mineral systems analysis

The Intermountain West has a complex geologic history, resulting in the formation of a diverse array of mineral deposits. Effective mineral exploration requires understanding the spatial and temporal relationships among geologic processes and events, a key focus of the mineral systems approach to exploration. This paper presents the Intermountain West Seamless Geologic Map Database, a unified dataset designed to support mineral exploration. Integrating geologic provinces, structural settings, and hydrothermal alteration, the database leverages the Seamless Integrated Geologic Mapping (SIGMa) extension to the USGS Geologic Map Schema (GeMS) to standardize geologic data from varied sources. SIGMa's hierarchical stratigraphic organization and feature-level metadata enhance data interoperability and reusability, enabling seamless query, analysis, and visualization of lithology, structural features, mineral deposits, geochronology, hydrothermal alteration. volcanic activity, and By providing a regionally consistent and dynamically evolving geologic map, this database provides a foundational framework for mineral exploration and geologic research. It also allows for an efficient workflow that expedites the publication of integrated geologic map databases.

Conference Paper↗

USGS2016

Dynamics of permeability evolution in stimulated geothermal reservoirs

Spatially and temporally evolving permeability fields are fundamentally associated with the operation of enhanced geothermal systems. This chapter explores the resulting magnitude and patterns of permeability alteration as well as the coupled physical processes that control the evolution of permeability during shear stimulation and long-term evolution of a geothermal reservoir. It also explores mechanisms involved in the enhancement of fracture permeability, targeting injection pressures that encourage self-propping shear stimulation alongside elastic pressure and thermal dilatation of fracture sets. Simulation of a short-term, high-injection-rate enhanced geothermal system stimulation explored the importance of hydraulic versus thermal effects and the impact of a temperature differential between fluid in the fractures and the adjoining rock matrix. The effects of variations in fracture spacing on the evolution of permeability is at least as important as the magnitude of initial permeability, and quantifying the driving mechanisms is critical to understanding reservoir response.

Book chapter↗

USGS2023

Evidence for infection influencing survival of the freshwater copepod Salmincola californiensis, a parasite of Pacific salmon and trout

Objective We explore apparent infection of Salmincola californiensis arising during investigations involving this lernaeopodid copepod parasitic on Pacific salmon and trout Oncorhynchus spp. Methods We noted occasional unusual coloration of adult female copepods collected from the wild. These females were bright blue and pink in contrast to the cream white coloration characteristic of the copepod. We also observed that similar color patterns developed under laboratory settings when copepod eggs were held for hatching. In paired egg cases, we found consistent hatching failure of blue and pink eggs and patterns in apparent disease development that would be consistent with both vertical and horizontal transmission. Result Attempts to identify the cause of the apparent infection using genetic methods and transmission electron microscopy were inconclusive. Conclusion Iridovirus infection was initially suspected, but bacterial infection is also plausible. This apparent reduced hatching success of S. californiensis warrants further exploration as it could reduce local abundances. Given the potential importance of a disease impacting this copepod, a parasite that itself affects endangered and commercially important Pacific salmon and trout, future research would benefit from clarification of the apparent infection through additional sequencing, primer development, visualization, and exploration into specificity and transmission.

Journal of Aquatic Animal Health↗

USGS2004

Data and understanding

In the year 1534 when Cabeza de Vaca escaped from the aborigines of southern Texas by whom he had been enslaved for six years, he made his way on foot from the vicinity of Galveston to the west coast of Mexico. Although his Relación was not printed until 1542, the verbal report of Cabeza de Vaca gave impetus to the growing interest in exploration of New Spain. Estevanico, the black, one of de Vaca's companions, served as guide to Fray Marcos de Niza on the first Spanish reconnaissance to reach the village of Zuni in New Mexico. The earliest Spanish exploring parties hoped to find riches, but expected to acquire, at the least, facts. These "gentlemen of high quality," as Castaneda called them, wanted to see for themselves whether the cities of Cibola had streets of silver. Hearsay was not enough. Rumor was to be replaced by first-hand knowledge. Without discounting the hope for personal gain, these men presumably were fired with some further intellectual and spiritual motivation, among which must have been the desire for facts about these parts where we are assembled. Inscription Rock, only a few miles west of Albuquerque, bears illuminating tidbits of history. Don Diego de Vargas, says the carved inscription of 1692, came here "A su costa"—at his own expense. We are attempting to survey and correlate some of the facts which people have gained about the nature of semi-arid lands. We are better off than the early Spanish explorers, for in the intervening period data and information have been accumulated in scope and in detail beyond the imagination of our predecessors. We have available excellent maps, knowledge of the soils and of the rocks, both at the surface and below the ground, measurements of precipitation, descriptions of the vegetation, data on the flow of streams, experience in the use, if not the husbandry, of the land. It is true that for the purposes of our complex civilization, the need for additional data has far outstripped the programs of fact-finding. But it appears that an indefinite expansion of the collection of routine measurements would still leave something lacking. I draw the distinction between measurement data and understanding; between the collection of facts and knowledge of processes and interrelationships. Although we have a wealth of data, our understanding of the semi-arid environment is poor. Understanding the physical and biologic processes operating in an environment is important for living in and with the land. As an example, let us look briefly at the interrelation of the water and sediment in ephemeral streams, and the problem of valley trenching or arroyo cutting.

Conference Paper↗

USGS2026

Deep learning models for mapping surficial geology in selected physiographic regions of New York

Surficial geologic mapping is required for decisions including infrastructure and water-resource development and management. Deep learning, a type of machine learning that uses training data to self-learn and perform tasks, is explored as a tool to help increase efficiency of the labour- and time-intensive mapping process. Deep learning models were trained, and their potential to aid in mapping surficial geology was explored for two physiographic regions in New York: the high-relief Allegheny Plateau and the low-relief Erie-Ontario Lowlands. Key to the development of deep learning models is the availability of highly detailed surficial geologic maps in each of these regions from which the models can learn. Through exploring different groupings of surficial deposits and their corresponding spatial data, deep learning models were iteratively developed to reproduce published mapping for greater than 79% of the training areas, and with similar accuracy in test areas within the same physiographic region. These models were trained using only two inputs: high-resolution lidar data and previously published surficial geologic maps. This straightforward approach is intended to make the methods and models created easily reproducible using widely accessible datasets. This research describes the strengths and limitations of lidar-derived surficial geologic models and how broadly grouping surficial types, characteristics of different physiographic regions, and testing models in physiographic regions outside of their training areas affect model creation and performance. In addition, the models created could be used as a tool for mapping surficial geology in similar physiographic regions, in addition to establishing a framework for creating similar models elsewhere.

New York↗

USGS2013

Bridging groundwater models and decision support with a Bayesian network

Resource managers need to make decisions to plan for future environmental conditions, particularly sea level rise, in the face of substantial uncertainty. Many interacting processes factor in to the decisions they face. Advances in process models and the quantification of uncertainty have made models a valuable tool for this purpose. Long-simulation runtimes and, often, numerical instability make linking process models impractical in many cases. A method for emulating the important connections between model input and forecasts, while propagating uncertainty, has the potential to provide a bridge between complicated numerical process models and the efficiency and stability needed for decision making. We explore this using a Bayesian network (BN) to emulate a groundwater flow model. We expand on previous approaches to validating a BN by calculating forecasting skill using cross validation of a groundwater model of Assateague Island in Virginia and Maryland, USA. This BN emulation was shown to capture the important groundwater-flow characteristics and uncertainty of the groundwater system because of its connection to island morphology and sea level. Forecast power metrics associated with the validation of multiple alternative BN designs guided the selection of an optimal level of BN complexity. Assateague island is an ideal test case for exploring a forecasting tool based on current conditions because the unique hydrogeomorphological variability of the island includes a range of settings indicative of past, current, and future conditions. The resulting BN is a valuable tool for exploring the response of groundwater conditions to sea level rise in decision support.

Water Resources Research↗

USGS2020

Passive seismic survey of sediment thickness, Dasht-e-Nawar basin, eastern Afghanistan

Exploration of water resources is needed for public supply, extraction of mineral resources, and economic development in Afghanistan. Remotely-sensed data are useful for identifying the general nature of surface sediments, however, “boots on the ground” geophysical surveys or drilling programs are needed to quantify the thickness of sediments or aquifers. The nature of such investigations presents a risk to field crews that may prohibit exploration of potentially valuable aquifers or mineral resources. The Dasht-e-Nawar basin, in east-central Afghanistan, contains a 400 km2 playa that includes evaporative mineral deposits, particularly lithium, which has been of interest since the 1970s. However, exploration of the basin, as with many areas of Afghanistan, has been hampered by decades of conflict. In 2014, an investigation of the basin was conducted by the U.S. Department of Defense Task Force for Business and Stability Operations (TFBSO), and their contractor, in cooperation with the U.S. Geological Survey (USGS). For this investigation the USGS compared the results of a rapid passive seismic survey of basin sediment thickness to the results of an independently conducted gravity survey of the same area. Each point measurement for the passive seismic method requires less than 30 minutes in the field by one person. The technique utilizes ambient seismic noise without an external sound source such as required by traditional seismic surveys. Additionally, the technique does not require external sensor arrays, which can be kilometers long for some geophysical techniques. The passive seismic equipment used in this study weighs approximately 1 kilogram and is about 10 cm3 in size. Although relatively new for assessment of sediment thickness, several investigations have found this method to be capable of estimating sediment thicknesses, in the 10’s to 1000 meter range, in settings with unconsolidated sediment over bedrock and a contrast in acoustic impedance. In this investigation, the gravity survey was conducted during a period of 3 weeks by an experienced field crew; required a detailed, centimeter-scale land elevation survey; and required laboratory analyses of sediment and rock densities to interpret the gravity data. In contrast, the passive seismic survey was collected by two inexperienced operators over a period of 8 days and required no additional data to interpret. Due to security restrictions, USGS personnel could not visit the site and the seismic operator was trained immediately prior to the field work. Although the quality of the seismic survey was affected by strong afternoon winds, and by the inexperience of the field operator, the results were fairly comparable to the gravity survey. Similar basin sediment thicknesses and patterns in sediment thickness were identified by both surveys in the basin with an estimated maximum thickness of approximately 170 m. The passive seismic technique required substantially less field resources and time than would be required by other geophysical surveys. Although this method will not be effective in all geologic settings, it may be a valuable assessment tool for use before conducting other, more intensive, geophysical efforts or drilling programs, especially in regions with elevated security risks such as Afghanistan.

Dasht-e-Nawar basin↗

USGS2023

Cold-water corals of the world: Gulf of Mexico

The Gulf of Mexico is a semi-enclosed sea that borders the USA and Mexico and covers approximately 1.5 million square kilometers. The northern Gulf is topographically complex and is a rich source of oil and gas deposits, which has led to a great deal of research on benthic ecosystems from the coastal zone to the deep sea. While not fully explored, the distribution of cold seeps and deep corals in the northern Gulf is reasonably well described. The eastern Gulf has a moratorium on energy industry development and consequently less exploration and research has been conducted in this region; however, recent explorations have revealed deep scleractinian reefs on the west Florida slope and extensive octocoral gardens on the deep escarpment. The Gulf is a productive sea with lucrative fisheries in addition to oil and gas. Exploitation of natural resources and potential climate change impacts threaten vulnerable ecosystems in the Gulf, including those in the deep sea. This chapter describes the oceanography and geology of the Gulf of Mexico, presents the current state of the knowledge of cold-water coral distribution, physiology and ecology, and provides an assessment of the threats to these vulnerable ecosystems.

Book chapter↗