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Workshop on applications of luminescence techniques to Earth resource studies

The purpose of the Workshop on Luminescence Techniques was threefold: (1) to review the state-of-the-art capabilities of luminescence methods, (2) to consider a variety of concepts for the development of future luminescence sensor systems, and (3) to discuss appropriate research and development strategies for advancing the current state-of-the-art.

Technical Report↗

Meteorite and meteoroid: New comprehensive definitions

Meteorites have traditionally been defined as solid objects that have fallen to Earth from space. This definition, however, is no longer adequate. In recent decades, man-made objects have fallen to Earth from space, meteorites have been identified on the Moon and Mars, and small interplanetary objects have impacted orbiting spacecraft. Taking these facts and other potential complications into consideration, we offer new comprehensive definitions of the terms "meteorite,""meteoroid," and their smaller counterparts: A meteoroid is a 10-??m to 1-m-size natural solid object moving in interplanetary space. A micrometeoroid is a meteoroid 10 ??m to 2 mm in size. A meteorite is a natural, solid object larger than 10 ??m in size, derived from a celestial body, that was transported by natural means from the body on which it formed to a region outside the dominant gravitational influence of that body and that later collided with a natural or artificial body larger than itself (even if it is the same body from which it was launched). Weathering and other secondary processes do not affect an object's status as a meteorite as long as something recognizable remains of its original minerals or structure. An object loses its status as a meteorite if it is incorporated into a larger rock that becomes a meteorite itself. A micrometeorite is a meteorite between 10 ??m and 2 mm in size. Meteorite- "a solid substance or body falling from the high regions of the atmosphere" (Craig 1849); "[a] mass of stone and iron that ha[s] been directly observed to have fallen down to the Earth's surface" (translated from Cohen 1894); "[a] solid bod[y] which came to the earth from space" (Farrington 1915); "A mass of solid matter, too small to be considered an asteroid; either traveling through space as an unattached unit, or having landed on the earth and still retaining its identity" (Nininger 1933); "[a meteoroid] which has reached the surface of the Earth without being vaporized" (1958 International Astronomical Union (IAU) definition, quoted by Millman 1961); "a solid body which has arrived on the Earth from outer space" (Mason 1962); "[a] solid bod[y] which reach[es] the Earth (or the Moon, Mars, etc.) from interplanetary space and [is] large enough to survive passage through the Earth's (or Mars', etc.) atmosphere" (Gomes and Keil 1980); "[a meteoroid] that survive[s] passage through the atmosphere and fall[s] to earth" (Burke 1986); "a recovered fragment of a meteoroid that has survived transit through the earth's atmosphere" (McSween 1987); "[a] solid bod[y] of extraterrestrial material that penetrate[s] the atmosphere and reach[es] the Earth's surface" (Krot et al. 2003). ?? The Meteoritical Society, 2010.

Meteoritics and Planetary Science↗

Spectroscopy from Space

This chapter reviews detection of materials on solid and liquid (lakes and ocean) surfaces in the solar system using ultraviolet to infrared spectroscopy from space, or near space (high altitude aircraft on the Earth), or in the case of remote objects, earth-based and earth-orbiting telescopes. Point spectrometers and imaging spectrometers have been probing the surfaces of our solar system for decades. Spacecraft carrying imaging spectrometers are currently in orbit around Mercury, Venus, Earth, Mars, and Saturn, and systems have recently visited Jupiter, comets, asteroids, and one spectrometer-carrying spacecraft is on its way to Pluto. Together these systems are providing a wealth of data that will enable a better understanding of the composition of condensed matter bodies in the solar system. Minerals, ices, liquids, and other materials have been detected and mapped on the Earth and all planets and/or their satellites where the surface can be observed from space, with the exception of Venus whose thick atmosphere limits surface observation. Basaltic minerals (e.g., pyroxene and olivine) have been detected with spectroscopy on the Earth, Moon, Mars and some asteroids. The greatest mineralogic diversity seen from space is observed on the Earth and Mars. The Earth, with oceans, active tectonic and hydrologic cycles, and biological processes, displays the greatest material diversity including the detection of amorphous and crystalline inorganic materials, organic compounds, water and water ice. Water ice is a very common mineral throughout the Solar System and has been unambiguously detected or inferred in every planet and/or their moon(s) where good spectroscopic data has been obtained. In addition to water ice, other molecular solids have been observed in the solar system using spectroscopic methods. Solid carbon dioxide is found on all systems beyond the Earth except Pluto, although CO 2 sometimes appears to be trapped in other solids rather than as an ice on some objects. The largest deposits of carbon dioxide ice are found on Mars. Sulfur dioxide ice is found in the Jupiter system. Nitrogen and methane ices are common beyond the Uranian system. Saturn’s moon Titan probably has the most complex active extra-terrestrial surface chemistry involving organic compounds. Some of the observed or inferred compounds include ices of benzene (C 6 H 6 ), cyanoacetylene (HC 3 N), toluene (C 7 H 8 ), cyanogen (C 2 N 2 ), acetonitrile (CH 3 CN), water (H 2 O), carbon dioxide (CO 2 ), and ammonia (NH 3 ). Confirming compounds on Titan is hampered by its thick smoggy atmosphere, where in relative terms the atmospheric interferences that hamper surface characterization lie between that of Venus and Earth. In this chapter we exclude discussion of the planets Jupiter, Saturn, Uranus, and Neptune because their thick atmospheres preclude observing the surface, even if surfaces exist. However, we do discuss spectroscopic observations on a number of the extra-terrestrial satellite bodies. Ammonia was predicted on many icy moons but is notably absent among the definitively detected ices with possible exceptions on Charon and possible trace amounts on some of the Saturnian satellites. Comets, storehouses of many compounds that could exist as ices in their nuclei, have only had small amounts of water ice definitively detected on their surfaces from spectroscopy. Only two asteroids have had a direct detection of surface water ice, although its presence can be inferred in others.

Reviews in Mineralogy and Geochemistry↗

Development of the hydrosphere and atmosphere, with special reference to probable composition of the early atmosphere

A satisfactory hypothesis of the development of the hydrosphere and atmosphere depends upon evidence from many sciences and the solution of many other fundamental problems of earth history. But because it is so closely related to many other problems, any progress toward unravelling the history of the hydrosphere and atmosphere limits the range of permissible speculation about such distantly related questions as the origin of the solar system, continents, mountains, and living organisms. Several hypotheses of the source of the earth’s air and waters are examined for their consistency with established principles and observed geologic evidence, and special attention is given to the probable composition of the early atmosphere. Hypotheses of the origin of the atmosphere and hydrosphere fall into two chief categories: (1) that all air and water of the earth are residual from a dense primitive atmosphere that once enveloped a molten globe; or (2) that they have accumulated at the earth’s surface by leakage from the interior. The quantities of water, carbon dioxide, organic carbon, nitrogen, sulfur, etc., that have been or are now part of the earth’s atmosphere and hydrosphere may be estimated within reasonable limits of uncertainty and these “excess” volatiles afford a basis for testing chemical consequences of the alternative hypotheses. Several writers have suggested that the primitive atmosphere may have been composed largely of CH 4 and NH 3 . However, the equilibrium constants for reactions of these and other gases, combined with the evidence of the “excess” volatiles, indicate that CO 2 and N 2 are much more likely. The stabilities of methane and ammonia depend upon the presence of free hydrogen; and the escape rate of hydrogen from the earth is such that methane probably could have persisted in significant amounts in the early atmosphere no more than 10 6 to 10 8 years. For all but a relatively brief period at the very beginning of earth history, the atmosphere probably contained CO 2 and N 2 rather than CH 4 and NH 3 . When the consequences of a dense atmosphere of CO 2 and N 2 (but with almost no free O 2 or H 2 ) are examined, it is found that several chemical effects (such as the quantity of rocks that would have to be weathered, of sodium dissolved in sea water, and of CaCO 3 deposited on the sea floor very early in early history) are not borne out by the observed geologic record. From this and other lines of evidence it seems extremely improbable that the present atmosphere and hydrosphere are residual from any such dense primitive atmosphere. Instead, it seems likely that the atmosphere and hydrosphere have accumulated gradually during geologic time by the escape of water vapor, CO 2 , CO, N 2 , and other volatiles from intrusive and extrusive rocks that have risen more or less continuously from the deep interior of the earth. The amount of free oxygen in the early atmosphere is a separate problem that cannot be solved until the evidence of the earliest rocks has been appraised more fully. Current hypotheses of the origin of life appear to require a reducing atmosphere, yet it seems likely that oxygen has been accumulating from the photodissociation of water vapor ever since the earth was formed. The oxidation of ferrous iron and sulfides in the earliest sediments may have kept the oxygen content very low, and life may have begun in local reducing environments.

GSA Special Papers↗

Countdown to Apophis close approach—Cascading hazards from asteroid impacts

Introduction Apophis (officially 99942 Apophis, pronounced “uh-PAW-fiss”) is a Near-Earth Object. Primarily composed of the materials that make up the leftover building blocks of the solar system, Near-Earth Objects are small solar system bodies in an orbit around the Sun that brings them close to the Earth. Apophis has been classified as a “potentially hazardous object,” a Near-Earth Object that may be large enough to cause significant damage in the event of an impact. Apophis is not projected to hit the Earth, but it will come close. The U.S. Geological Survey (USGS) is working with other federal partners, industry, academic institutions, and international cooperators to characterize Apophis, prepare for the flyby on Friday, April 13, 2029, and develop investigative and mitigation strategies for potential impacts from other Near-Earth Objects. Close approaches of objects the size of Apophis (approximately 340 meters in diameter) or larger are considered rare events, occurring every few thousand years or so. Although Apophis will not impact Earth, the Specific Action Team was convened and included USGS participation, to (1) identify and quantify effects on Apophis from its close flyby with Earth; (2) assess the importance of measuring these effects; (3) categorize these effects according to different tiers of detectable limits; and (4) assess the risk to Earth of a spacecraft rendezvous with Apophis.

Fact Sheet↗

This dynamic planet: World map of volcanoes, earthquakes, impact craters and plate tectonics

Our Earth is a dynamic planet, as clearly illustrated on the main map by its topography, over 1500 volcanoes, 44,000 earthquakes, and 170 impact craters. These features largely reflect the movements of Earth's major tectonic plates and many smaller plates or fragments of plates (including microplates). Volcanic eruptions and earthquakes are awe-inspiring displays of the powerful forces of nature and can be extraordinarily destructive. On average, about 60 of Earth's 550 historically active volcanoes are in eruption each year. In 2004 alone, over 160 earthquakes were magnitude 6.0 or above, some of which caused casualties and substantial damage. This map shows many of the features that have shaped--and continue to change--our dynamic planet. Most new crust forms at ocean ridge crests, is carried slowly away by plate movement, and is ultimately recycled deep into the earth--causing earthquakes and volcanism along the boundaries between moving tectonic plates. Oceans are continually opening (e.g., Red Sea, Atlantic) or closing (e.g., Mediterranean). Because continental crust is thicker and less dense than thinner, younger oceanic crust, most does not sink deep enough to be recycled, and remains largely preserved on land. Consequently, most continental bedrock is far older than the oldest oceanic bedrock. (see back of map) The earthquakes and volcanoes that mark plate boundaries are clearly shown on this map, as are craters made by impacts of extraterrestrial objects that punctuate Earth's history, some causing catastrophic ecological changes. Over geologic time, continuing plate movements, together with relentless erosion and redeposition of material, mask or obliterate traces of earlier plate-tectonic or impact processes, making the older chapters of Earth's 4,500-million-year history increasingly difficult to read. The recent activity shown on this map provides only a present-day snapshot of Earth's long history, helping to illustrate how its present surface came to be. The map is designed to show the most prominent features when viewed from a distance, and more detailed features upon closer inspection. The back of the map zooms in further, highlighting examples of fundamental features, while providing text, timelines, references, and other resources to enhance understanding of this dynamic planet. Both the front and back of this map illustrate the enormous recent growth in our knowledge of planet Earth. Yet, much remains unknown, particularly about the processes operating below the ever-shifting plates and the detailed geological history during all but the most recent stage of Earth's development.

IMAP↗

Current loops fitted to geomagnetic model spherical harmonic coefficients.

One hundred-sixty circular current loops with radial axes were fitted by least squares to the 899 spherical harmonic coefficients of a 29 th degree model. In the first case, the parameters that were fitted for each loop were the normalized magnetic moment, the distance from the center of the Earth to the current element, the colatitude and E. longitude of the loop axis, and one-half of the central apex angle of the loop. For this case, two of the loops converged near the inner-core outer-core boundary. They accounted for most of the dipolar field. Twenty of the loops, all with much smaller magnetic moments than the two deep loops, converged in the distance range of 0.42 to 0.67 Earth's radius from the center of the Earth. The other 138 loops, after many iterations, were located at distances between 0.81 and 1.0 Earth's radius from the center of the Earth. The loops with radial distances between 0.21 and 0.67 Earth's radius from the center of the Earth are referred to as “core” loops and those at distances greater than 0.81 Earth's radius as “crustal” loops. The spherical harmonic coefficients from these 160 loops, when subtraced from the 899 coefficients of the original model, left a root-mean-square residual of only 0.2nT. A second case was tried which constrained the 138 “crustal” loops to be at 0.996 Earth's radius (25.5km depth). In this case, the root-mean-square residual of the spherical harmonic coefficients from the original model was 0.9nT.

Journal of Geomagnetism & Geoelectricity↗

Fractionation of families of major, minor, and trace metals across the melt-vapor interface in volcanic exhalations

Chemical families of metals fractionate systematically as they pass from a silicate melt across the interface with the vapor phase and on into a cooled volcanic plume. We measured three groups of metals in a small suite of samples collected on filters from the plumes of Kilauea (Hawaii, USA), Etna (Sicily), and Merapi (Java) volcanoes. These were the major, minor, and trace metals of the alkali and alkaline earth families (K, Rb, Cs, Ca, Sr, Ba), a group of ordinarily rare metals (Cd, Cu, In, Pb, Tl) that are related by their chalcophile affinities, and the radon daughter nuclides 210Po, 210Bi, and 210Pb. The measurements show the range and some details of systematic melt-vapor fractionation within and between these groups of metals. In the plumes of all three volcanoes, the alkali metals are much more abundant than the alkaline earth metals. In the Kilauea plume, the alkali metals are at least six times more abundant than the alkaline earth metals, relative to abundances in the melt; at Etna, the factor is at least 300. Fractionations within each family are, commonly, also distinctive; in the Kilauea plume, in addition to the whole alkaline earth family being depleted, the heaviest metals of the family (Sr, Ba) are progressively more depleted than the light metal Ca. In plumes of fumaroles at Merapi, K/Cs ratios were approximately three orders of magnitude smaller than found in other earth materials. This may represent the largest observed enrichment of the "light ion lithophile" (LIL) metals. Changes in metal ratios were seen through the time of eruption in the plumes of Kilauea and Etna. This may reflect degree of degassing of volatiles, with which metals complex, from the magma bodies. At Kilauea, the changes in fractionation were seen over about three years; fractionation within the alkaline earth family increased, and that between the two families decreased, over that time. All of the ordinarily rare chalcophile metals measured are extremely abundant in volcanic plumes, and Cd and Tl are enriched relative to the others. Indium is much more abundant in the plume of the hotspot volcano Kilauea than in the Etna plume (probably non-hotspot in character). It may be a useful indicator of the tapping of deep mantle zones, or could aid in the interpretation of reports of Pt group metals in exhalations from hot spot volcanoes. Indium in old glacial ice strata could help assess magnitude and variability of exhalations from hotspot volcanoes in past time. Strong melt-vapor fractionation of the alkali and alkaline earth metals may only be observed in plumes during quiescent degassing of volcanoes; when large amounts of ash or spatter (undifferentiated lava) enter the plume, its alkali and alkaline earth metal composition may approach that of the melt. Ratios among the chalcophile metals may not be much changed by addition of ash, because their concentrations in melt are so small, and masses of them in any plume may remain dominated by transfer across the melt-vapor interface. Radon daughter nuclides give information about state of volcanic activity at time of sampling. The precisely known origins, ultratrace detectability, decay systematics, and wide variations in volatility of these species provide information about residence times, degassing and travel histories, and identities of melt bodies in volcanic systems. ?? 1994.

Geochimica et Cosmochimica Acta↗

U.S. Geological Survey Library classification system

The U.S. Geological Survey library classification system has been designed for an earth science library. It is a tool for assigning classification numbers to earth science and allied pure science library materials in order to collect these materials into related subject groups on the library shelves and arrange them alphabetically by author and title. It can also be used as a retrieval system to access these materials through the subject and visible geographic classification numbers. The classification scheme has been developed over the years since 1904 to meet the ever-changing needs of increased specialization and new areas of study in the earth sciences. This system contains seven schedules: Subject schedule Geological survey schedule Earth science periodical schedule Government documents periodical schedule General science periodical schedule Earth science maps schedule Geographic schedule A geographic number, from the geographic schedule, is distinguished from other numbers in the system in that it is always enclosed in parentheses; for example, (200) is the geographic number for the United States. The geographic number is used in conjunction with the six other previously listed schedules, and it represents slightly different nuances of meanings, in respect to geographic locale, for each schedule. When used with a subject number, the geographic number indicates the country, state, province, or region in which the research was made. The subject number, 203, geology, when combined with the geographic number, (200), for example 203(200), is the classification number for library materials on the geology of the United States. The geographic number, combined with the capital letter G, for example, G(211), is the classification number for an earth science periodical issued by a geological association or university geology department in the State of Maine. When the letter S is combined with a geographic number, for example, S(276), it represents a general science periodical for a university or association in California. When the letter P is combined with a geographic number, for example, P(200), it represents a governmental periodical issued by the United States Federal Government. Geographic numbers standing alone represent classification numbers for the publications of geological surveys; for example, (200) represents publications of the U.S. Geological Survey. Map call numbers have a geographic number preceded by the capital letter M, followed by an abbreviated subject number. For example: M(200)2 where: M = Map (200) = Geographic region of the United States 2 = Abbreviation for the subject number 203— geology. The introduction, which follows this abstract, provides detailed procedures on the construction of complete call numbers for works falling into the framework of the aforesaid classification schedules. The tables following the introduction can be quickly accessed through the use of the newly expanded subject index. The purpose of this publication is to provide the earth science community with a classification and retrieval system for earth science materials, to provide sufficient explanation of its structure and use, and to enable library staff and clientele to classify or access research materials in a library collection.

Bulletin↗

Television observations from Surveyor 3

A total of 6315 pictures were taken by the television camera on Surveyor 3 after the lunar landing. These pictures have provided much new information about the location of the landing site on the moon, the detailed topographic and geologic characteristics of the lunar surface, and the appearance of the earth as seen from the moon, both during eclipse of the sun and during partial direct illumination by the sun. Surveyor 3 landed in a subdued crater slightly more than 200 meters in diameter, which has a low rounded rim and is about 15 meters deep. The spacecraft is situated on the east wall of the crater, about half way between the center of the crater and the rim crest. The spacecraft is inclined 14.7° ± 1.0° toward the west. The selenographic coordinates of the landing site are 2.94°S latitude, 23.34°W longitude, relative to selenodetic control adopted by the Aeronautical Chart and Information Center. Small morphologic elements of the landing site include small craters, linear ridges and troughs, and fragmental debris. The craters and fragmental debris resemble those observed at the Surveyor 1 landing site, both in distribution of shape and in distribution of size. Most of the craters in Surveyor 1 and 3 pictures are inferred to be of impact origin. Their size-frequency distribution corresponds to the distribution that would be produced by repetitive bombardment by meteoroids, a bombardment sufficiently prolonged that the crater population has reached a steady state or has come to equilibrium. Some of the craters observed at the Surveyor 3 landing site are inferred to be of secondary impact origin, and some probably have been formed either by subsidence or by drainage of fragmental debris into cracks or fissures in the subsurface. Fragmental debris at the landing site is inferred to have been derived primarily by the same process of repetitive bombardment that produced the majority of craters. The inferred volumetric size-frequency distribution of fragments, derived from the observed size distribution of fragments on the surface, is similar to the distribution that would be produced by repetitive bombardment of coherent rocks by meteoroids with a mass-frequency distribution like that found from observed meteors and recovered meteorites on earth. Two prominent strewn fields of blocky debris were observed around two craters, 13 and 15 meters across, at the Surveyor 3 site. The 13-meter crater has a sharp raised rim, and the 15-meter crater has a more subdued rounded rim. The blocks associated with the subdued crater have twice as high a mean roundness as the blocks associated with the raised-rim crater, and they are much more deeply buried. The size-frequency distribution function for the fragments in each of the strewn fields of blocks resembles the size-frequency distribution for fragments ejected by impacts in strong rock, such as Meteor Crater, Arizona. Most of the fragments at the surface of the Surveyor 3 landing site are evidently part of a layer of fragmental material of low cohesion that is at least 1 meter thick along the upper parts of the wall of the crater in which Surveyor 3 landed and may be much thicker near the center of the crater. The evidence from the Surveyor 3 pictures suggests that this layer of debris, or regolith, is subject to downslope creep or mass movement. Creep is probably caused by seismic shaking, due mainly to near and far impact events and perhaps due partly to internal lunar seismicity. Disturbances of the lunar surface produced by Surveyor 3, like those produced by Surveyor 1, exposed material at depths of a few centimeters or less that was darker than the material at the surface. The albedo of the fine-grained fragmental debris is probably 20 to 30% lower at depths of only a fraction of a millimeter than it is at the optically observed surface. All coarse fragments protruding above the general level of the surface have a higher albedo than the fine-grained matrix of the surface. These general photometric relationships can be explained if it is assumed that the surfaces of the particles in the shallow lunar subsurface tend to become coated with a dark substance; the term proposed for this hypothetical substance is ‘lunar varnish’ On the protruding surface of blocks and coarse fragments the lunar varnish is scrubbed off by the processes that cause rounding. The exposed surfaces of fine particles on the lunar surface are similarly affected, but, because they are mixed relatively rapidly with particles just beneath the surface, the process is incomplete and the fine-grained material exposed at the lunar surface, therefore, has a lower albedo than blocks and other large fragments. Coating of particles by lunar varnish evidently takes place just beneath the surface. The estimated normal luminance factor (normal albedo) of an undisturbed part of the lunar surface next to footpad 2 of the Surveyor 3 spacecraft is 8.5%. An area of the lunar surface disturbed by the surface sampler has an estimated normal luminance factor of 6.6%, and fine-grained material placed on footpad 2 by the surface sampler has an estimated normal luminance factor of 7.6%. The errors in all these estimates may be as high as 25% because of uncertainties of correction required for light scattered from the camera mirror. Preliminary search for color differences, by color reconstitution methods, revealed no determinable differences in color among various coarse blocks, the fine-grained matrix of the surface, or fine-grained material disturbed by the surface sampler. Surveyor 3 pictures of the eclipse of the sun by the earth revealed a bright region in the refraction halo surrounding the earth, which was correlated with the position of the sun, and a series of bright beads that occurred over regions of the earth largely clear of clouds. Clouds tend to occult the refracted rays of the sun, most of which pass through the lower part of the atmosphere at the limb; the beads occurred in the depressions in the optical silhouette of the earth. Preliminary reduction of the color of the refracted light showed that the brightest region, near the position of the sun, exhibited a correlated color temperature close to 4800°K. The color temperature tended to be lower for light that followed paths of greater atmospheric absorption. Preliminary analysis of Surveyor 3 pictures of the partly illuminated earth revealed colors similar to the colors recorded from orbit by the Mercury and Gemini astronauts.

Journal of Geophysical Research↗

Fossils, rocks, and time

We study our Earth for many reasons: to find water to drink or oil to run our cars or coal to heat our homes, to know where to expect earthquakes or landslides or floods, and to try to understand our natural surroundings. Earth is constantly changing--nothing on its surface is truly permanent. Rocks that are now on top of a mountain may once have been at the bottom of the sea. Thus, to understand the world we live on, we must add the dimension of time. We must study Earth's history. When we talk about recorded history, time is measured in years, centuries, and tens of centuries. When we talk about Earth history, time is measured in millions and billions of years. Time is an everyday part of our lives. We keep track of time with a marvelous invention, the calendar, which is based on the movements of Earth in space. One spin of Earth on its axis is a day, and one trip around the Sun is a year. The modern calendar is a great achievement, developed over many thousands of years as theory and technology improved. People who study Earth's history also use a type of calendar, called the geologic time scale. It looks very different from the familiar calendar. In some ways, it is more like a book, and the rocks are its pages. Some of the pages are torn or missing, and the pages are not numbered, but geology gives us the tools to help us read this book.

Report↗