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At least 793 records · Page 44Linked to original sources

USGS2018

Salt marsh loss affects tides and sediment budget in shallow bays

The current paradigm is that salt marshes and their important ecosystem services are threatened by global climate change; indeed, large marsh losses have been documented worldwide. Morphological changes associated with salt marsh erosion are expected to influence the hydrodynamics and sediment dynamics of coastal systems. Here the influence of salt marsh erosion on the tidal hydrodynamics and sediment storage capability of shallow bays is investigated. Hydrodynamics, sediment transport, and vegetation dynamics are simulated using the numerical framework Coupled Ocean‐Atmosphere‐Wave‐Sediment Transport in the Barnegat Bay‐Little Egg Harbor system, USA. We show that salt marsh erosion influences the propagation of tides into back‐barrier basins, reducing the periodic inundation and sediment delivery to marsh platforms. As salt marshes erode, the sediment trapping potential of marsh platforms decreases exponentially. In this test case, up to 50% of the sediment mass trapped by vegetation is lost once a quarter of the marsh area is eroded. Similarly, without salt marshes the sediment budget of the entire bay significantly declines. Therefore, a positive feedback might be triggered such that as the salt marsh retreats the sediment storage capacity of the system declines, which could in turn further exacerbate marsh degradation.

New Jersey↗

USGS2012

Numerical simulations of the Shoemaker-Levy 9 impact plumes and clouds: A progress report

Preliminary 2D/3D numerical simulations were carried out for the penetration of 1-km bodies in the Jovian atmosphere and the subsequent rise and collapse of the erupted plumes. A body that crushed at a stagnation point pressure of 5 kbar produced a plume that rose to 800 km. Evolution of the shape of the calculated plume corresponds rather well to the plumes observed by HST. A crescent-shaped lobe centered on the “backfire” azimuth was produced by lateral flow during plume collapse. The plumes observed on Jupiter rose about 4 times higher, and their rise and fall times were about twice those in this calculation. Plume height is a sensitive function of the distribution of energy along the entry path; a very low-strength body will disintegrate higher along the penetration path and will produce a higher plume.

Geophysical Research Letters↗

USGS1985

Validation of an automated fluorescein method for determining bromide in water

Surface, atmospheric precipitation and deionized water samples were spiked with ??g l-1 concentrations of bromide, and the solutions stored in polyethylene and polytetrafluoroethylene bottles. Bromide was determined periodically for 30 days. Automated fluorescein and ion chromatography methods were used to determine bromide in these prepared samples. Analysis of the data by the paired t-test indicates that the two methods are not significantly different at a probability of 95% for samples containing from 0.015 to 0.5 mg l-1 of bromide. The correlation coefficient for the same sets of paired data is 0.9987. Recovery data, except for the surface water samples to which 0.005 mg l-1 of bromide was added, range from 89 to 112%. There appears to be no loss of bromide from solution in either type of container.Surface, atmospheric precipitation and deionized water samples were spiked with mu g l** minus **1 concentrations of bromide, and the solutions stored in polyethylene and polytetrafluoroethylene bottles. Bromide was determined periodically for 30 days. Automated fluorescein and ion chromatography methods were used to determine bromide in these prepared samples. Analysis of the data by the paired t-test indicates that the two methods are not significantly different at a probability of 95% for samples containing from 0. 015 to 0. 5 mg l** minus **1 of bromide. The correlation coefficient for the same sets of paired data is 0. 9987. Recovery data, except for the surface water samples to which 0. 005 mg l** minus **1 of bromide was added, range from 89 to 112%. Refs.

Water Research↗

USGS1999

Loch Vale Watershed Project quality assurance report, 1995-1998

The Loch Vale Watershed (LVWS) project was initiated in 1980 by the National Park Service with funding from the Aquatic Effects Research Program of the National Acid Precipitation Assessment Program. Initial research objectives were to understand the processes that would either mitigate or accelerate the effects of pollution on soil and surface water chemistry, and to build a record in which long-term trends could be identified and examined. It is important for all data collected in Loch Vale to meet the high standards of quality set forth in previous LVWS QA/QC reports and LVWS Methods Manuals. Given the ever-widening usage of data collected in Loch Vale, it is equally important to provide users of that data with a report assuring that all data are sound. Parameters covered in this report are the quality of meteorological measurements, hydrological measurements, surface water chemistry, and similarities in catch efficiency of two raingage types in Loch Vale for the period of 1995-1998. Routine sampling of weather conditions, precipitation chemistry, and stream/lake water chemistry began in 1982. Since then, all samples and data have been analyzed according to widely accepted and published methods. Weather data have been collected, analyzed, and stored by LVWS project personnel. Methods for the handling of meteorological data are well documented (Denning 1988, Edwards 1991, Newkirk 1995,and Allstott 1995). Precipitation chemistry has always been collected according to National Atmospheric Deposition Program protocol (Bigelow 1988), and analyzed at the Central Analytical Laboratory of the Illinois State Water Survey in Champaign, IL. QA/QC procedures of the National Atmospheric Deposition Program are well documented (Aubertin 1990). Protocols for sampling surface waters are also well documented (Newkirk 1995). Analysis of surface water chemistry has been performed using standard EPA protocol at the US Forest Service's Rocky Mt. Station Biogeochemistry Laboratory since 1993.

Open-File Report↗

USGS2023

External quality-assurance project report for the National Atmospheric Deposition Program’s National Trends Network and Mercury Deposition Network, 2019–20

The U.S. Geological Survey Precipitation Chemistry Quality Assurance project (PCQA) operated four distinct programs to provide external quality-assurance monitoring for the National Atmospheric Deposition Program’s (NADP) National Trends Network (NTN) and Mercury Deposition Network (MDN) during 2019–20. The NTN programs included (1) a field audit program to evaluate sample contamination and stability, and (2) an interlaboratory comparison program to evaluate analytical laboratory performance. The MDN programs included the (3) system blank program to evaluate sample contamination and stability, and (4) an interlaboratory comparison program. The results indicated increased levels of sample contamination compared to previous years for NTN samples and decreased contamination in MDN samples. Strong analytical laboratory performance with low overall variability and bias in concentration data were indicated for the NTN’s Central Analytical Laboratory. A positive bias in the hydrogen ion concentrations in NTN samples during 2019 was eliminated by correction of a pH calibration protocol during 2020. The MDN’s Mercury Analytical Laboratory performance declined in 2020 compared to 2019 as indicated by increased variability in analytical results and a negative bias of approximately -1 nanogram per liter in the concentrations of total mercury. Slight perturbations in contamination levels in NTN samples and in analytical performance for MDN are considered small. The PCQA results indicate that NADP data continue to be of sufficient quality for applications in independent research and NADP data products, including spatial interpolations and time trends for chemical constituents in wet deposition. Small shifts in data quality indicated by the 2019–20 PCQA results are intended to be used for interpretation of the NADP data products.

Scientific Investigations Report↗

USGS2021

Synoptic analysis of a decade of daily measurements of SO2 emission in the troposphere from volcanoes of the global ground-based Network for Observation of Volcanic and Atmospheric Change

Volcanic plumes are common and far-reaching manifestations of volcanic activity during and between eruptions. Observations of the rate of emission and composition of volcanic plumes are essential to recognize and, in some cases, predict the state of volcanic activity. Measurements of the size and location of the plumes are important to assess the impact of the emission from sporadic or localized events to persistent or widespread processes of climatic and environmental importance. These observations provide information on volatile budgets on Earth, chemical evolution of magmas, and atmospheric circulation and dynamics. Space-based observations during the last decades have given us a global view of Earth's volcanic emission, particularly of sulfur dioxide ( SO 2 ). Although none of the satellite missions were intended to be used for measurement of volcanic gas emission, specially adapted algorithms have produced time-averaged global emission budgets. These have confirmed that tropospheric plumes, produced from persistent degassing of weak sources, dominate the total emission of volcanic SO 2 . Although space-based observations have provided this global insight into some aspects of Earth's volcanism, it still has important limitations. The magnitude and short-term variability of lower-atmosphere emissions, historically less accessible from space, remain largely uncertain. Operational monitoring of volcanic plumes, at scales relevant for adequate surveillance, has been facilitated through the use of ground-based scanning differential optical absorption spectrometer (ScanDOAS) instruments since the beginning of this century, largely due to the coordinated effort of the Network for Observation of Volcanic and Atmospheric Change (NOVAC). In this study, we present a compilation of results of homogenized post-analysis of measurements of SO 2 flux and plume parameters obtained during the period March 2005 to January 2017 of 32 volcanoes in NOVAC. This inventory opens a window into the short-term emission patterns of a diverse set of volcanoes in terms of magma composition, geographical location, magnitude of emission, and style of eruptive activity. We find that passive volcanic degassing is by no means a stationary process in time and that large sub-daily variability is observed in the flux of volcanic gases, which has implications for emission budgets produced using short-term, sporadic observations. The use of a standard evaluation method allows for intercomparison between different volcanoes and between ground- and space-based measurements of the same volcanoes. The emission of several weakly degassing volcanoes, undetected by satellites, is presented for the first time. We also compare our results with those reported in the literature, providing ranges of variability in emission not accessible in the past. The open-access data repository introduced in this article will enable further exploitation of this unique dataset, with a focus on volcanological research, risk assessment, satellite-sensor validation, and improved quantification of the prevalent tropospheric component of global volcanic emission.

Earth System Science Data↗

USGS2025

Bølling-Allerød productivity in the subarctic Pacific driven by seasonal upwelling

The Bølling-Allerød deglacial event is marked by high diatom productivity and opal deposition throughout the subarctic Pacific. This opal could either constitute a strengthened biological pump and thus carbon sequestration, or a weakened biological pump and release of marine-sequestered CO 2 to the atmosphere. We quantify silicic acid supply at IODP Site U1340 in the Bering Sea using biogenic opal and δ 30 Si of Coscinodiscus , a diatom genus. These records, along with diatom environmental indicators, suggest the Bølling-Allerød had high silicic acid availability related to a shift from stratification to seasonal upwelling dynamics. We thus propose the primary cause of the high productivity event was increased macronutrient supply from vertical exchange that injected old, nutrient-rich, CO 2 -rich waters into the surface. Enhanced CO 2 release from the subarctic Pacific may help explain critical intervals of CO 2 rise that occur at the onsets of the Bølling-Allerød and PreBoreal.

Geophysical Research Letters↗

USGS2014

Triggering and modulation of geyser eruptions in Yellowstone National Park by earthquakes, earth tides, and weather

We analyze intervals between eruptions (IBEs) data acquired between 2001 and 2011 at Daisy and Old Faithful geysers in Yellowstone National Park. We focus our statistical analysis on the response of these geysers to stress perturbations from within the solid earth (earthquakes and earth tides) and from weather (air pressure and temperature, precipitation, and wind). We conclude that (1) the IBEs of these geysers are insensitive to periodic stresses induced by solid earth tides and barometric pressure variations; (2) Daisy (pool geyser) IBEs lengthen by evaporation and heat loss in response to large wind storms and cold air; and (3) Old Faithful (cone geyser) IBEs are not modulated by air temperature and pressure variations, wind, and precipitation, suggesting that the subsurface water column is decoupled from the atmosphere. Dynamic stress changes of 0.1−0.2 MPa resulting from the 2002 M-7.9 Denali, Alaska, earthquake surface waves caused a statistically significant shortening of Daisy geyser's IBEs. Stresses induced by other large global earthquakes during the study period were at least an order of magnitude smaller. In contrast, dynamic stresses of >0.5 MPa from three large regional earthquakes in 1959, 1975, and 1983 caused lengthening of Old Faithful's IBEs. We infer that most subannual geyser IBE variability is dominated by internal processes and interaction with other geysers. The results of this study provide quantitative bounds on the sensitivity of hydrothermal systems to external stress perturbations and have implications for studying the triggering and modulation of volcanic eruptions by external forces.

Wyoming↗

USGS2026

Seasonal estimates of nutrient loading, sources, and impacts on water availability in streams across the conterminous United States, 2000–2020

Excess riverine nutrients can limit water availability for humans and ecosystems. Nutrient monitoring on individual stream reaches provides important information about current and past conditions, yet most river reaches are unmonitored. Additionally, monitored data integrate effects of upstream sources, sinks, and pathways by which nutrients get into streams, making explicit planning for effective nutrient reduction strategies challenging. We developed and applied dynamic SPAtially Referenced Regression On Watershed attributes (SPARROW) models to quantify total nitrogen (TN) and total phosphorus (TP) delivery and source-specific loading in all stream reaches of the conterminous United States (CONUS) at a seasonal timestep from 2000 through 2020. Between one third and one half of non-point source nutrients lagged more than one season in their delivery to CONUS streams over the study period. The largest sources of nutrients that were applied and delivered to streams within a season were agricultural fertilizers, treated wastewater, atmospheric deposition, and manure. Increases in loads were widespread across the CONUS and predominantly associated with increased loading from lagged delivery of non-point source inputs and current season fertilizer application. Model results also identified extensive areas where predicted seasonal concentrations frequently exceeded the National Rivers and Streams Assessment “poor” criteria. Increased loading occurred in areas with high yields and delivery to downstream receiving waterbodies, particularly across the Midwest, raising the risk of negative impacts to downstream water availability. The modeling approach presented here provides a continental-scale framework for identifying when, where, and why nutrients are generated and how that may ultimately impact receiving waterbodies.

conterminous United States↗

USGS2008

Diagnosis of an intense atmospheric river impacting the pacific northwest: Storm summary and offshore vertical structure observed with COSMIC satellite retrievals

This study uses the new satellite-based Constellation Observing System for Meteorology, Ionosphere, and Climate (COSMIC) mission to retrieve tropospheric profiles of temperature and moisture over the data-sparse eastern Pacific Ocean. The COSMIC retrievals, which employ a global positioning system radio occultation technique combined with "first-guess" information from numerical weather prediction model analyses, are evaluated through the diagnosis of an intense atmospheric river (AR; i.e., a narrow plume of strong water vapor flux) that devastated the Pacific Northwest with flooding rains in early November 2006. A detailed analysis of this AR is presented first using conventional datasets and highlights the fact that ARs are critical contributors to West Coast extreme precipitation and flooding events. Then, the COSMIC evaluation is provided. Offshore composite COSMIC soundings north of, within, and south of this AR exhibited vertical structures that are meteorologically consistent with satellite imagery and global reanalysis fields of this case and with earlier composite dropsonde results from other landfalling ARs. Also, a curtain of 12 offshore COSMIC soundings through the AR yielded cross-sectional thermodynamic and moisture structures that were similarly consistent, including details comparable to earlier aircraft-based dropsonde analyses. The results show that the new COSMIC retrievals, which are global (currently yielding ???2000 soundings per day), provide high-resolution vertical-profile information beyond that found in the numerical model first-guess fields and can help monitor key lower-tropospheric mesoscale phenomena in data-sparse regions. Hence, COSMIC will likely support a wide array of applications, from physical process studies to data assimilation, numerical weather prediction, and climate research. ?? 2008 American Meteorological Society.

Monthly Weather Review↗

USGS2018

Geospatial data for developing nutrient SPARROW models for the Midcontinental region of Canada and the United States

Through the International Watersheds Initiative of the International Joint Commission (IJC), the SpatiallyReferenced Regressions on Watershed attributes (SPARROW) model developed by the U.S. Geological Survey (USGS) is being applied to the Great Lakes, Rainy River – Lake of the Woods and Red-Assiniboine basins. The objective of this binational application of the SPARROW model is to better understand and quantify the sources of phosphorus (P) and nitrogen (N) that contribute to regional water-quality issues like algal blooms and eutrophication in Lake Erie and other parts of the Great Lakes, as well as Lake of the Woods. Led by the IJC, a team of researchers from the National Research Council of Canada – Ocean, Coastal and River Engineering Research Centre, USGS, and IJC are extending the SPARROW modelling work previously completed for the Red-Assiniboine basin and the U.S. portions of the Great Lakes, Ohio, Upper Mississippi, and Souris-Red-Rainy river basins to cover all of the Great Lakes, Rainy River – Lake of the Woods and RedAssiniboine basins. The current effort is termed the Midcontinent SPARROW modelling study. This report describes the data used to develop the Midcontinent SPARROW models, specifically the sources of original data, assembling the data, and the processing and harmonization required between the U.S. and Canada data needed to produce these models. Details provided include the: development of a digital stream network and related catchments – most significantly in the Canadian regions of the Great Lakes and Rainy River – Lake of the Woods basins where these data were not available to create a seamless binational network across the model domain; calculation of variables to aid in the determination of in-stream and in-reservoir decay of P and N; quantification of Canadian diversions within the Midcontinental region (i.e., Lake St. Joseph, Long Lake and the Ogoki Reservoir); development of binational input nutrient sources considered for model development (i.e., land cover, inorganic farm fertilizer, manure, atmospheric deposition, point-source pollution from wastewatertreatment plants and contribution from non-modelled watersheds); and development of delivery variables considered to be most predominant (i.e., temperature, precipitation and ensuing runoff, soil permeability and clay content, slope of the catchments, and tile drainage). The majority of the geospatial data collection and processing was required for Canadian datasets because many of the U.S. datasets were already assembled for previous SPARROW model applications in the U.S. The task of harmonizing data between the U.S. and Canada was important to ensure consistency of the datasets used in the models. The harmonized digital stream network, delineated catchments and input data for each catchment (i.e., source and delivery variables), created for the Midcontinent SPARROW models, are available for download at url: https://doi.org/10.4224/300.0001.

Technical Report↗

USGS2001

TES premapping data: Slab ice and snow flurries in the Martian north polar night

In the 1970s, Mariner and Viking spacecraft observations of the north polar region of Mars revealed polar brightness temperatures that were significantly below the expected kinetic temperatures for CO 2 sublimation. For the past few decades, the scientific community has speculated as to the nature of these Martian polar cold spots. Thermal Emission Spectrometer (TES) thermal spectral data have shown these cold spots to result largely from fine‐grained CO 2 and have constrained most of these cold spots to the surface (or near‐surface). Cold spot formation is strongly dependent on topography, forming preferentially near craters and on polar slopes. TES data, combined with Mars Orbiter Laser Altimeter (MOLA) cloud data, suggest atmospheric condensates form a small fraction of the observed cold spots. TES observations of spectra close to a blackbody indicate that another major component of the polar cap is slab CO 2 ice; these spectrally bland regions commonly have a low albedo. The cause is uncertain but may result from most of the light being reflected toward the specular direction, from the slab ice being intrinsically dark, or from it being transparent. Regions of the cap where the difference between the brightness temperatures at 18 μm ( T 18 ) and 25 μm ( T 25 ) is less than 5° are taken to indicate deposits of slab ice. Slab ice is the dominant component of the polar cap at latitudes outside of the polar night.

Journal of Geophysical Research E: Planets↗

USGS2024

External quality-assurance project report for the National Atmospheric Deposition Program National Trends Network and Mercury Deposition Network, 2021–22

The U.S. Geological Survey Precipitation Chemistry Quality Assurance project (PCQA) operated five distinct programs to provide external quality-assurance monitoring for the National Atmospheric Deposition Program (NADP) National Trends Network (NTN) and Mercury Deposition Network (MDN) during 2021–22. The NTN programs included (1) a field audit program to evaluate sample contamination and stability, (2) an interlaboratory-comparison program to evaluate analytical laboratory performance, and (3) a colocated sampler program to estimate overall variability of NTN wet-deposition measurements, and the MDN programs included the (4) system blank program to evaluate sample contamination and stability and (5) an interlaboratory-comparison program. The results indicated increased levels of sample contamination compared to previous years for NTN samples and decreased contamination in MDN samples. Strong analytical laboratory performance with low overall variability and bias in concentration data was indicated for the NTN Central Analytical Laboratory. Slight perturbations in contamination levels in NTN samples and in analytical performance for MDN are considered inconsequential. The colocated sampler program results indicated overall variability in NTN data to range from 0 to 30.3 percent for cations, 1.6 to 11.4 percent for ammonium, 0.8 to 20.2 percent for anions, 10.3 to 17.2 percent for hydrogen-ion concentration, and 1.5 to 12.2 percent for specific conductance. The PCQA results indicate that NADP data continue to be of sufficient quality for applications in independent research and NADP data products, including spatial interpolations and time trends for chemical constituents in wet deposition. Small shifts in data quality indicated by the 2021–22 PCQA results are included to be used for interpretation of the NADP data products.

Scientific Investigations Report↗

USGS2008

Application of Wind Fetch and Wave Models for Habitat Rehabilitation and Enhancement Projects

Models based upon coastal engineering equations have been developed to quantify wind fetch length and several physical wave characteristics including significant height, length, peak period, maximum orbital velocity, and shear stress. These models, developed using Environmental Systems Research Institute's ArcGIS 9.2 Geographic Information System platform, were used to quantify differences in proposed island construction designs for three Habitat Rehabilitation and Enhancement Projects (HREPs) in the U.S. Army Corps of Engineers St. Paul District (Capoli Slough and Harpers Slough) and St. Louis District (Swan Lake). Weighted wind fetch was calculated using land cover data supplied by the Long Term Resource Monitoring Program (LTRMP) for each island design scenario for all three HREPs. Figures and graphs were created to depict the results of this analysis. The difference in weighted wind fetch from existing conditions to each potential future island design was calculated for Capoli and Harpers Slough HREPs. A simplistic method for calculating sediment suspension probability was also applied to the HREPs in the St. Paul District. This analysis involved determining the percentage of days that maximum orbital wave velocity calculated over the growing seasons of 2002-2007 exceeded a threshold value taken from the literature where fine unconsolidated sediments may become suspended. This analysis also evaluated the difference in sediment suspension probability from existing conditions to the potential island designs. Bathymetric data used in the analysis were collected from the LTRMP and wind direction and magnitude data were collected from the National Oceanic and Atmospheric Administration, National Climatic Data Center.

Open-File Report↗

USGS1997

High-temperature hot spots on Io as seen by the Galileo solid state imaging (SSI) experiment

High-temperature hot spots on Io have been imaged at ∼50 km spatial resolution by Galileo's CCD imaging system (SSI). Images were acquired during eclipses (Io in Jupiter's shadow) via the SSI clear filter (∼0.4–1.0 µm), detecting emissions from both small intense hot spots and diffuse extended glows associated with Io‧s atmosphere and plumes. A total of 13 hot spots have been detected over ∼70% of Io–s surface. Each hot spot falls precisely on a low-albedo feature corresponding to a caldera floor and/or lava flow. The hot-spot temperatures must exceed ∼700 K for detection by SSI. Observations at wavelengths longer than those available to SSI require that most of these hot spots actually have significantly higher temperatures (∼1000 K or higher) and cover small areas. The high-temperature hot spots probably mark the locations of active silicate volcanism, supporting suggestions that the eruption and near-surface movement of silicate magma drives the heat flow and volcanic activity of Io.

Geophysical Research Letters↗

USGS2018

Drivers of variability in public‐supply water use across the contiguous United States

This study explores the relationship between municipal water use and an array of climate, economic, behavioral, and policy variables across the contiguous U.S. The relationship is explored using Bayesian‐hierarchical regression models for over 2,500 counties, 18 covariates, and three higher‐level grouping variables. Additionally, a second analysis is included for 83 cities where water price and water conservation policy information is available. A hierarchical model using the nine climate regions (product of National Oceanic and Atmospheric Administration) as the higher‐level groups results in the best out‐of‐sample performance, as estimated by the Widely Available Information Criterion, compared to counties grouped by urban continuum classification or primary economic activity. The regression coefficients indicate that the controls on water use are not uniform across the nation: e.g., counties in the Northeast and Northwest climate regions are more sensitive to social variables, whereas counties in the Southwest and East North Central climate regions are more sensitive to environmental variables. For the national city‐level model, it appears that arid cities with a high cost of living and relatively low water bills sell more water per customer, but as with the county‐level model, the effect of each variable depends heavily on where a city is located.

Water Resources Research↗

USGS2007

Assessing methane release from the colossal Storegga submarine landslide

Marine slope failure involving methane-gas-hydrate-bearing sediments is one mechanism for releasing enormous quantities of methane to the ocean and atmosphere. The Storegga Slide, on the Norwegian margin, is the largest known Holocene-aged continental margin slope failure complex and is believed to have occurred in sediments that may have initially contained gas hydrate. Here, we report pore water sulfate gradient measurements that are used as a proxy for the relative amounts of methane that exist in continental margin sediments associated with the colossal Storegga Slide. These measurements suggest that a considerable inventory of methane occurs in sediments adjacent to, and unaffected by, the Storegga Slide events, but indicate that methane is notably absent from sediments on the sole of the slide and distal deposits created by the slide events. Either methane was lost during previous Pleistocene failure events or was never present in significant concentrations within the sediments that failed.

Geophysical Research Letters↗

USGS2020

Timescales and processes of methane hydrate formation and breakdown, with application to geologic systems

Gas hydrate is an ice-like form of water and low molecular weight gas stable at temperatures of roughly -10ºC to 25ºC and pressures of ~3 to 30 MPa in geologic systems. Natural gas hydrates sequester an estimated one-sixth of Earth’s methane and are found primarily in deepwater marine sediments on continental margins, but also in permafrost areas and under continental ice sheets. When gas hydrate is removed from its stability field, its breakdown has implications for the global carbon cycle, ocean chemistry, marine geohazards, and interactions between the geosphere and the ocean-atmosphere system. Gas hydrate breakdown can also be artificially driven as a component of studies assessing the resource potential of these deposits. Furthermore, geologic processes and perturbations to the ocean-atmosphere system (e.g., warming temperatures) can cause not only dissociation, but also more widespread dissolution of hydrate or even formation of new hydrate in reservoirs. Linkages between gas hydrate and disparate aspects of Earth’s near-surface physical, chemical, and biological systems render an assessment of the rates and processes affecting the persistence of gas hydrate an appropriate Centennial Grand Challenge. This paper reviews the thermodynamic controls on methane hydrate stability and then describes the relative importance of kinetic, mass transfer, and heat transfer processes in the formation and breakdown (dissociation and dissolution) of gas hydrate. Results from numerical modeling, laboratory, and some fields studies are used to summarize the rates of hydrate formation and breakdown, followed by an extensive treatment of hydrate dynamics in marine and cryospheric gas hydrate systems.

Journal of Geophysical Research-Solid Earth↗