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At least 775 records · Page 43Linked to original sources

Transport and fate of nitrate in a glacial outwash aquifer in relation to ground water age, land use practices, and redox processes

A combination of ground water modeling, chemical and dissolved gas analyses, and chlorofluorocarbon age dating of water was used to determine the relation between changes in agricultural practices, and NO − 3 concentrations in ground water of a glacial outwash aquifer in west-central Minnesota. The results revealed a redox zonation throughout the saturated zone with oxygen reduction occurring near the water table, NO − 3 reduction immediately below it, and then a large zone of ferric iron reduction, with a small area of sulfate (SO 2− 4 ) reduction and methanogenesis (CH 4 ) near the end of the transect. Analytical and NETPATH modeling results supported the hypothesis that organic carbon served as the electron donor for the redox reactions. Denitrification rates were quite small, 0.005 to 0.047 mmol NO − 3 yr −1 , and were limited by the small amounts of organic carbon, 0.01 to 1.45%. In spite of the organic carbon limitation, denitrification was virtually complete because residence time is sufficient to allow even slow processes to reach completion. Ground water sample ages showed that maximum residence times were on the order of 50 to 70 yr. Reconstructed NO − 3 concentrations, estimated from measured NO − 3 and dissolved N gas showed that NO − 3 concentrations have been increasing in the aquifer since the 1940s, and have been above the 714 μmol L −1 maximum contaminant level at most sites since the mid- to late-1960s. This increase in NO − 3 has been accompanied by a corresponding increase in agricultural use of fertilizer, identified as the major source of NO − 3 to the aquifer.

Minnesota↗

Soil property control of biogeochemical processes beneath two subtropical stormwater infiltration basins

Substantially different biogeochemical processes affecting nitrogen fate and transport were observed beneath two stormwater infiltration basins in north-central Florida. Differences are related to soil textural properties that deeply link hydroclimatic conditions with soil moisture variations in a humid, subtropical climate. During 2008, shallow groundwater beneath the basin with predominantly clayey soils (median, 41% silt+clay) exhibited decreases in dissolved oxygen from 3.8 to 0.1 mg L -1 and decreases in nitrate nitrogen (NO 3 - &ndash;N) from 2.7 mg L -1 to <0.016 mg L -1 , followed by manganese and iron reduction, sulfate reduction, and methanogenesis. In contrast, beneath the basin with predominantly sandy soils (median, 2% silt+clay), aerobic conditions persisted from 2007 through 2009 (dissolved oxygen, 5.0&ndash;7.8 mg L -1 ), resulting in NO 3 - &ndash;N of 1.3 to 3.3 mg L -1 in shallow groundwater. Enrichment of d15N and d18O of NO 3 - combined with water chemistry data indicates denitrification beneath the clayey basin and relatively conservative NO 3 - transport beneath the sandy basin. Soil-extractable NO 3 - &ndash;N was significantly lower and the copper-containing nitrite reductase gene density was significantly higher beneath the clayey basin. Differences in moisture retention capacity between fine- and coarse-textured soils resulted in median volumetric gas-phase contents of 0.04 beneath the clayey basin and 0.19 beneath the sandy basin, inhibiting surface/subsurface oxygen exchange beneath the clayey basin. Results can inform development of soil amendments to maintain elevated moisture content in shallow soils of stormwater infiltration basins, which can be incorporated in improved best management practices to mitigate NO 3 - impacts.

Florida↗

Modeling soil moisture processes and recharge under a melting snowpack

Recharge into granitic bedrock under a melting snowpack is being investigated as part of a study designed to understand hydrologic processes involving snow at Yosemite National Park in the Sierra Nevada Mountains of California. Snowpack measurements, accompanied by water content and matric potential measurements of the soil under the snowpack, allowed for estimates of infiltration into the soil during snowmelt and percolation into the bedrock. During portions of the snowmelt period, infiltration rates into the soil exceeded the permeability of the bedrock and caused ponding to be sustained at the soil-bedrock interface. During a 5-d period with little measured snowmelt, drainage of the ponded water into the underlying fractured granitic bedrock was estimated to be 1.6 cm d?1, which is used as an estimate of bedrock permeability. The numerical simulator TOUGH2 was used to reproduce the field data and evaluate the potential for vertical flow into the fractured bedrock or lateral flow at the bedrock-soil interface. During most of the snowmelt season, the snowmelt rates were near or below the bedrock permeability. The field data and model results support the notion that snowmelt on the shallow soil overlying low permeability bedrock becomes direct infiltration unless the snowmelt rate greatly exceeds the bedrock permeability. Late in the season, melt rates are double that of the bedrock permeability (although only for a few days) and may tend to move laterally at the soil-bedrock interface downgradient and contribute directly to streamflow. ?? Soil Science Society of America.

Conference Paper↗

Lunar mare basaltic volcanism: Volcanic features and emplacement processes

Volcanism is a fundamental process in the geological evolution of the Moon, providing clues to the composition and structure of the mantle, the location and duration of interior melting, the nature of convection and lunar thermal evolution. Progress in understanding volcanism has been remarkable in the short 60-year span of the Space Age. Before Sputnik 1 in 1957, the lunar farside was unknown, the origin of the dark lunar maria was debated (sedimentary or volcanic), and significant controversy surrounded the question of how the multitude of craters on the surface formed. Was the Moon formed hot or cold, was the lunar surface young or old, were the craters of impact or volcanic origin? A lunar farside deficient in the darker maria was revealed by Luna 3 in 1959 ( Lipsky 1965a , b ). The Ranger, Lunar Orbiter, Surveyor, Luna and Zond missions significantly augmented pre-Sputnik telescopic observations and began to reveal the diversity of lunar geologic landforms. Return of lunar soil and rock samples from the lunar surface by Apollo (11–12, 14–17) ( Compton 1989 ) and Luna (16, 20, 24) missions ( Harvey 2007a , b ; Huntress and Marov 2011 ) changed the debates overnight ( Hinners 1971 ; Taylor 1975 ). The lunar rocks were igneous and extremely ancient, all from the first half of Solar System history; the oldest, highland anorthosites, were overlain by relatively younger, but still extremely old, extrusive basalts forming the maria.

Reviews in Mineralogy and Geochemistry↗

Effects of elk herbivory on vegetation and nitrogen processes

We used 35-year and 4-year ungulate exclosures to determine the effects of elk ( Cervus elaphus ) herbivory on above-ground and below-ground production and soil fertility on the elk winter range in Rocky Mountain National Park (RMNP), Colorado, USA. We used paired grazed and ungrazed plots to evaluate ungulate herbivory effects in short and tall willow ( Salix spp.), aspen ( Populus spp.), and upland grass/shrub vegetation associations. We measured nitrogen (N) fluxes (litter deposition, fecal and urinary deposition from elk, movements of N by elk, N mineralization, soil N availability, elk consumption rates) within the elk winter, above-ground and below-ground N pools (herbaceous, shrub and root biomass, %N in plants, roots, and soil), and N fluxes on and off the elk winter range (seasonal movement of N by elk). Nitrogen mineralization and soil nitrate (NO 3 ) pools were reduced in the short willow community ( P = 0.07 and 0.10, respectively; n = 4 sites) in grazed plots, but not in the upland grass/shrub community or tall willow sites ( P >0.10). Annual growth of willows was reduced by 98% in grazed plots, relative to 35-year exclosures, and 66% relative to 4-year exclosures. Thus, height, canopy size, and litter biomass of willows were reduced, and N yield of willows was 64% less in grazed plots. We evaluated movement of N by elk among 6 major vegetation associations and found that elk grazed more and bedded less in willow vegetation association compared to mixed conifer, mesic meadow, and grassland/shrub associations ( P = 0.014, 0.001, and 0.026, respectively), suggesting that elk herbivory and movement led to a net loss of N in the willow vegetation association. Elk spent less total time in willows than mesic meadow association, yet they consumed large amounts of willow plant biomass. We recommend management of elk numbers and elk herbivory that takes into consideration impacts to N process function, as negative effects from current levels of herbivory were observed in ≥1 of 3 vegetation associations studied.

Colorado↗

Retention and transport of nutrients in a third-order stream: Channel processes

Chloride was injected as a conservative tracer with nitrate to examine nitrate retention (storage plus biotic uptake) and transport in a 327—m reach of a third—order stream draining a forested basin in northwestern California. Prior to injections, diel patterns of nutrient concentrations were measured under background conditions. Nitrate concentration of stream water increased downstream, indicating that the reach was a source of dissolved inorganic nitrogen to downstream communities under background, low—flow conditions, despite uptake by photoautotrophs. At the onset of continuous solute injection over a 10—d period, timing the passage of the solute front indicated that storage dominated nitrate retention. Instantaneous concentration differences at the base of the reach at hour 24 indicated that biotic uptake accounted for 13% of the nitrate amendment while hydrologic storage constituted 29%. Corrected for groundwater dilution (11.7%), saturation of the stream's channel and hyporheic zones was not complete until 6.8 d of continuous injection. By day 3 nitrate retention was dominated by biotic processes. Biotic uptake was greatest during daylight hours indicating retention by photoautotrophs, but also occurred during darkness. After 10 d of continuous injection, mass balance calculations indicated that 29% of N (339 g) was retained from the total injected (1155 g), while the balance of injected nitrate was transported downstream. Storage of NO 3 — N was 117 g or 10% while biotic uptake was 222 g or 19%. Periphyton biomass on slides, chlorophyll a both on slides and on natural cobbles, and net community primary production all indicated a lag in periphyton response to nitrate amendment. Earliest indicators of a biotic response to nutrient amendment were decreases in both tissue C/N and epilithic respiration.

Ecology↗

Catastrophic lava flow levee failure: Precursors, processes, and implications

During an effusive eruption crisis the initial advance of a lava flow is typically the primary focus of model forecasts and hazard management efforts. Flow branching and lateral expansion of lava flows can pose significant dangers within evolving flow fields throughout the duration of an eruption and are an underappreciated hazard. We use field monitoring, infrasound, time lapse imagery, and lidar data collected during the 2018 lower East Rift Zone eruption of Kīlauea (Hawai‘i) to track the origins, progression, and implications of a flow branching event caused by catastrophic levee failure. Our analyses show that surges in effusion rate, rheologic transitions between pāhoehoe and ‘a‘ā flow regimes, slope-breaks, pre-existing topographic highs, and the structure of perched levee walls all played a role in the failure of the levee and subsequent re-routing of the lava flow. Failure of perched lava structures leads to an acutely hazardous situation because lava impounded by the structure can rapidly inundate the landscape. This is the first time a levee failure event has been observed in such detail with numerous monitoring techniques; this unprecedented level of observation provides quantifiable insights into levee failure processes that have important implications for hazard mitigation and an improved understanding of lava flow emplacement dynamics.

Hawaii↗

Digital processing of array seismic recordings

This technical letter contains a brief review of the operations which are involved in digital processing of array seismic recordings by the methods of velocity filtering, summation, cross-multiplication and integration, and by combinations of these operations (the "UK Method" and multiple correlation). Examples are presented of analyses by the several techniques on array recordings which were obtained by the U.S. Geological Survey during chemical and nuclear explosions in the western United States. Seismograms are synthesized using actual noise and P n -signal recordings, such that the signal-to-noise ratio, onset time and velocity of the signal are predetermined for the synthetic record. These records are then analyzed by summation, cross-multiplication, multiple correlation and the UK technique, and the results are compared. For all of the examples presented, analysis by the non-linear techniques of multiple correlation and cross-multiplication of the traces on an array recording are preferred to analyses by the linear operations involved in summation and the UK Method.

Crustal Studies Technical Letter↗

Processing of Landsat imagery to map surface mineral alteration on the Alaska Peninsula: A section in USGS research on mineral resources, 1985 program and abstracts

Landsat images were digitally processed to facilitate assessment of the mineral resources of the Port Moller, Stepovak Bay, and Simeonof Island 1:250,000 quadrangles. Field mapping and assessment of these quadrangles were begun in 1983 as part of the Alaska Mineral Resource Assessment Program (AMRAP). It was quickly realized that time and budget constraints would limit mapping coverage. Therefore, at the suggestion of Roger Ashley, we used existing Landsat multispectral scanner imagery to aid in locating surface alteration, which could be field checked or related to stream-sediment or hand-sample geochemical data.

Circular↗

Processing and analysis of commercial satellite image data of the nuclear accident near Chernobyl, U.S.S.R.

Advanced digital processing techniques were applied to Landsat-5 Thematic Mapper (TM) data and SPOT highresolution visible (HRV) panchromatic data to maximize the utility of images of a nuclear powerplant emergency at Chernobyl in the Soviet Ukraine. The images demonstrate the unique interpretive capabilities provided by the numerous spectral bands of the Thematic Mapper and the high spatial resolution of the SPOT HRV sensor.

Bulletin↗

Processing of single channel air and water gun data for imaging an impact structure at the Chesapeake Bay

Processing of 20 seismic profiles acquired in the Chesapeake Bay area aided in analysis of the details of an impact structure and allowed more accurate mapping of the depression caused by a bolide impact. Particular emphasis was placed on enhancement of seismic reflections from the basement. Application of wavelet deconvolution after a second zero-crossing predictive deconvolution improved the resolution of shallow reflections, and application of a match filter enhanced the basement reflections. The use of deconvolution and match filtering with a two-dimensional signal enhancement technique (F-X filtering) significantly improved the interpretability of seismic sections.

Bulletin↗

Processes influencing the transport and fate of contaminated sediments in the coastal ocean– Boston Harbor and Massachusetts Bay

Most of the major urban centers of the United States including Boston, New York, Washington, Chicago, New Orleans, Miami, Los Angeles, San Francisco, and Seattle—are on a coast (fig. 1.1). All of these cities discharge treated sewage effluent into adjacent waters. In 2000, 74 percent of the U.S. population lived within 200 kilometers (km) of the coast. Between 1980 and 2002, the population density in coastal communities increased approximately 4.5 times faster than in noncoastal areas of the U.S. (Perkins, 2004). More people generate larger volumes of wastes, increase the demands on wastewater treatment, expand the area of impervious land surfaces, and use more vehicles that contribute contaminants to street runoff. According to the National Coastal Condition Report II (U.S. Environmental Protection Agency, 2005a), on the basis of coastal habitat, water and sediment quality, benthic index, and fish tissue, the overall national coastal condition is only poor to fair and the overall coastal condition in the highly populated Northeast is poor. Scientific information helps managers to prioritize and regulate coastal-ocean uses that include recreation, commercial fishing, transportation, waste disposal, and critical habitat for marine organisms. These uses are often in conflict with each other and with environmental concerns. Developing a strategy for managing competing uses while maintaining sustainability of coastal resources requires scientific understanding of how the coastal ocean system behaves and how it responds to anthropogenic influences. This report provides a summary of a multidisciplinary research program designed to improve our understanding of the transport and fate of contaminants in Massachusetts coastal waters. Massachusetts Bay and Boston Harbor have been a focus of U.S. Geological Survey (USGS) research because they provide a diverse geographic setting for developing a scientific understanding of the geology, geochemistry, and oceanography of coastal systems in general. Scientific data from this region can also be used to inform decisions about important economic, environmental, and political issues. From the economic viewpoint, the annual value of tourism and shipping in Massachusetts and Cape Cod Bays is about $1.5 billion and $1.9 billion, respectively. Commercial and recreational fishing generates about $240 million per year in the same region (U.S. Environmental Protection Agency, 2005b). The environmental issue is the 300-year history of waste discharge from the Boston metropolitan area into the harbor. This history is punctuated by cycles of environmental degradation, public outcry, and improvements in the sewage treatment system. With each improvement, however, the continuous growth of population in greater Boston (fig. 1.2) and the resulting increase in the volume of waste exceeded the capacity of the treatment system, thereby setting the stage for a new contamination crisis. By the 1980s, the levels of contaminants in sediments of Boston Harbor were among the highest in the nation (National Oceanic and Atmospheric Administration, 1987). Fish were diseased, shellfish beds were closed, and swimming beaches were unsafe after heavy rains; in general, water quality and aesthetics were below acceptable standards. Legal and political issues have always been part of Boston Harbor’s history. The environmental conditions in the 1980s were highlighted in a 1983 legal suit brought by the city of Quincy against the Metropolitan District Commission (MDC, the state agency responsible for sewage treatment) and heads of three state agencies for discharging untreated or poorly treated sewage into the harbor (Dolin, 2004). The suit never went to trial, but through the actions of a Massachusetts Superior Court, the issue of Boston Harbor contamination remained on the political and public agenda. The judge called the harbor “unsafe, unsanitary, indecent, in violation of the law (Clean Water Act), and a danger to the health and welfare of the people” (Forman, 1984). To force the state legislature to implement a plan to improve harbor conditions, the judge threatened to place the MDC in receivership and curtail new sewage hookups for industry. Under intense lobbying by business, the legislature created the Massachusetts Water Resources Authority (MWRA) in December 1984. The independent MWRA was established to manage Boston’s waste treatment system and was given the authority to float bonds to pay for major improvements in the treatment system. In 1985, a Federal court began hearings on a suit brought by the Conservation Law Foundation, the Environmental Protection Agency (USEPA), and towns of Quincy and Winthrop against the MDC and MWRA (as heir to responsibilities of the MDC) for years of violation of the Clean Water Act. The judge ruled against the defendants and required all the parties to submit a construction plan and schedule for a new sewage treatment system. From these submissions, he developed a schedule for treatment system upgrades that would give the “citizens of this commonwealth a public assurance that Boston Harbor will be cleaned up within a defined period of time” (Dolin, 2004). The MWRA’s Boston Harbor cleanup program (Levy and Connor, 1992) has transformed the Boston sewage system. Key improvements were to (1) reduce contaminants at the industrial source; (2) remediate leaks in the sewage-collection system; (3) eliminate sewage sludge discharge to the harbor; (4) upgrade sewage treatment from primary to secondary; (5) construct a new ocean outfall 15.2 km offshore in Massachusetts Bay for discharge of treated effluent (fig. 1.3); and (6) implement improvements in the combined-sewer-overflow system. As part of the harbor cleanup program, the MWRA developed a comprehensive monitoring program (summarized in MWRA, 2004) to assess changes in the harbor and bays that specifically related to the new sewage system. Additional information about conditions and processes in the coastal system on a regional scale and over a long time period was and continues to be important in predicting and interpreting local change. Implementation of the MWRA’s program and the mission of the USGS to understand the geology of the nation’s offshore waters provided an opportunity to conduct a cooperative multidisciplinary research program. This USGS program addresses basic scientific questions as well as concerns raised by management regarding the design, implementation, and assessment of the new sewage treatment system. Already active in Boston Harbor during the late 1970s, the USGS expanded research into Massachusetts Bay with a multidisciplinary program in 1989.

Massachusetts↗

Selected Geochemical Data for Modeling Near-Surface Processes in Mineral Systems

The database herein was initiated, designed, and populated to collect and integrate geochemical, geologic, and mineral deposit data in an organized manner to facilitate geoenvironmental mineral deposit modeling. The Microsoft Access database contains data on a variety of mineral deposit types that have variable environmental effects when exposed at the ground surface by mining or natural processes. The data tables describe quantitative and qualitative geochemical analyses determined by 134 analytical laboratory and field methods for over 11,000 heavy-mineral concentrate, rock, sediment, soil, vegetation, and water samples. The database also provides geographic information on geology, climate, ecoregion, and site contamination levels for over 3,000 field sites in North America.

Data Series↗

Raw and processed ground-penetrating radar and postprocessed differential global positioning system data collected from Assateague Island, Maryland, October 2014

Scientists from the U.S. Geological Survey, St. Petersburg Coastal and Marine Science Center acquired sediment cores, sediment surface grab samples, ground-penetrating radar (GPR) and Differential Global Positioning System (DGPS) data from Assateague Island, Maryland, in October 2014. The objectives were to identify washover deposits in the stratigraphic record to aid in understanding barrier island evolution. This report serves as an archive of GPR and DGPS data collected from Assateague Island in October 2014. Data products, including raw GPR and processed DGPS data, elevation corrected GPR profiles, and accompanying Federal Geographic Data Committee metadata can be downloaded from the Data Downloads page.

Maryland↗

Natural processes for managing nitrate in ground water discharged to Chesapeake Bay and other surface waters: More than forest buffers

Ground-water discharge is a significant source of nitrate load to tidal creeks, coastal estuaries, and Chesapeake Bay. Different studies have found that forest buffers greater than 200 feet wide remove most of the nitrate from passing ground water. These buffers are commonly included in regional nutrient-management strategies. Results of a U.S. Geological Survey study on the Eastern Shore of Virginia, however, indicate that the presence of forest buffers alone may not significantly decrease nitrate load in ground-water discharge. The effectiveness of forest buffers largely depends on the composition of local soils and ground-water flow paths. Study results also indicate that large amounts of nitrate are removed from ground water by the natural process of denitrification, which may occur independently of the presence or absence of forest buffers. The results of this study indicate that in addition to the presence of forest buffers, a range of other natural factors, such as soil texture and organic matter content and ground-water flow paths, affect the fate of nitrate in ground water. These factors are important to include along with forest buffers in developing comprehensive nutrient-management strategies.

Fact Sheet↗

Seafloor erosional processes offshore of the Chandeleur Islands, Louisiana

The Chandeleur Islands are a chain of barrier islands that lies along the eastern side of the modern Mississippi River Delta plain. The island chain is located near the seaward edge of the relict St. Bernard Delta, the part of the Mississippi Delta that formed between approximately 4,000 and 2,000 years before present and was later abandoned as sedimentation shifted southward. After abandonment of the St. Bernard Delta, deposits were reworked, and the sandy component was shaped into the Chandeleur Islands. With continued subsidence, the islands became separated from their original delta headland sources and presently are isolated from the mainland by the shallow Chandeleur Sound. Newly acquired geophysical data and vibracores provide an opportunity to better understand the processes that are shaping seafloor morphology (i.e., shape, geometry, and structure of the seafloor) on the inner shelf adjacent to the Chandeleur Islands. The inner shelf offshore of the Chandeleur Islands was mapped in 2006 and 2007 using swath bathymetry, sidescan sonar, and high-resolution seismic-reflection techniques. The detailed results of this study were published in December 2009 (Twichell and others, 2009) as part of a special issue of Geo-Marine Letters that documents early results from the Northern Gulf of Mexico (NGOM) Ecosystem Change and Hazard Susceptibility Project. This study addresses questions and concerns related to limited sand resources along the Louisiana shelf and their implications to long-term relative sea-level rise and storm impacts.

Louisiana↗

Methods for processing and imaging marsh foraminifera

This study is part of a larger U.S. Geological Survey (USGS) project to characterize the physical conditions of wetlands in southwestern Louisiana. Within these wetlands, groups of benthic foraminifera-shelled amoeboid protists living near or on the sea floor-can be used as agents to measure land subsidence, relative sea-level rise, and storm impact. In the Mississippi River Delta region, intertidal-marsh foraminiferal assemblages and biofacies were established in studies that pre-date the 1970s, with a very limited number of more recent studies. This fact sheet outlines this project's improved methods, handling, and modified preparations for the use of Scanning Electron Microscope (SEM) imaging of these foraminifera. The objective is to identify marsh foraminifera to the taxonomic species level by using improved processing methods and SEM imaging for morphological characterization in order to evaluate changes in distribution and frequency relative to other environmental variables. The majority of benthic marsh foraminifera consists of agglutinated forms, which can be more delicate than porcelaneous forms. Agglutinated tests (shells) are made of particles such as sand grains or silt and clay material, whereas porcelaneous tests consist of calcite.

Fact Sheet↗