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Use of an artificial stream to monitor avoidance behavior of larval sea lamprey in response to TFM and niclosamide

The lampricide 3-trifluoromethyl-4-nitrophenol (TFM) has been used in liquid form to control larval sea lamprey ( Petromyzon marinus ) in Great Lakes tributaries since the late 1950s. In the 1980s a dissolvable TFM bar was developed as a supplemental tool for application to small tributaries as a deterrent to larvae seeking water not activated with TFM. The size, mass, and number of bars needed in some streams, as well as the location of the streams, limit the utility of a TFM bar. The development and use of an alternative niclosamide bar has the potential to use fewer bars to achieve similar results. However, the use of a niclosamide bar is dependent upon its larval deterrent capability compared to the TFM bar. In this study, we developed a laboratory-scale, simulated stream fluvarium with several avoidance areas including two side channels and a seep. The objective was to evaluate the deterrent capabilities of TFM and niclosamide. We found similar behavioral responses, with TFM and niclosamide having similar capabilities to prevent sea lamprey from seeking refuge in side channels and seep avoidance areas. TFM-treated side channels and seep increased sea lamprey occupancy in the main channel 2.56 times more than the untreated-controls (95% CI 1.63–4.14) whereas niclosamide-treated side channels and seep increased sea lamprey occupancy of the main channel 2.68 times more than the untreated-controls (95% CI 1.72–4.32). These responses indicate a niclosamide bar would effectively prevent sea lamprey escapement into freshwater during a lampricide treatment at concentrations unlikely to harm aquatic organisms.

Journal of Great Lakes Research↗

Seasonality of nitrate sources and isotopic composition in the Upper Illinois River

To improve understanding of spatial, seasonal, and inter-annual variations in nitrate sources and in-stream processes in the Illinois River system, nitrate concentrations and isotopic compositions were measured in 445 water samples collected over a four-year period (2004–2008) from the Upper Illinois River Basin (UIRB). Samples included surface water in the river and major tributaries, effluent samples from Chicago’s largest wastewater treatment plant (WTP), and representative groundwater from shallow wells in agricultural land. Two principal nitrate endmember sources within the UIRB had distinctive isotopic compositions: WTP effluent with δ 15 N = 8.6 ± 1.7‰ and δ 18 O = 0.8 ± 1.4‰ and agricultural groundwater with δ 15 N-NO 3 = 3.4 ± 0.6‰ and δ 18 O = 3.7 ± 0.5‰ (when minimally affected by nitrate reduction). Isotopic data indicated that the large pulse of nitrate exported from the river basin during the spring was mostly derived from agricultural land drainage, while nitrate from large WTP effluent point sources was predominant in the upper reaches of the river near Chicago. During low base-flow conditions in late-summer and fall, the agricultural nitrate source was greatly diminished and the headwater WTP source was predominant in the river basin export. Our results indicated biogeochemical nitrate reduction and isotopic fractionation occurred within the river network, affecting both agricultural and urban sources during surface-water transport. In addition, diminished agricultural nitrate export was attributable to preferential discharge of biogeochemically reduced groundwater during low base flow. Isotopic indicators of spatial and seasonal variations in the relative importance of different nitrate sources, and their relative susceptibility to natural attenuation, might be useful for guiding monitoring and management practices to reduce nitrate export from complex watersheds with mixed land uses.

Upper Illinois River↗

Growth of hatchery‐reared chinook salmon in Lakes Michigan and Huron exhibits limited spatial variation but Is temporally linked to alewife abundance

Chinook Salmon Oncorhynchus tshawytscha were introduced into Lakes Michigan and Huron in the 1960s to diversify recreational fisheries and reduce overabundant, nonnative Alewife Alosa pseudoharengus. Alewife remain the primary prey of Chinook Salmon but have experienced substantial declines in abundance due to reduced food resources and salmonine predation pressure. The movements of Chinook Salmon have been linked to the density and spatial distribution of Alewife, but spatial patterns in Chinook Salmon growth have not been well documented and the temporal relationship between growth and Alewife density has not been evaluated during the current period of low Alewife abundance. We evaluated spatial and temporal variation in growth of Chinook Salmon in Lake Michigan and the U.S. waters of Lake Huron and explored linkages with Alewife density. Von Bertalanffy growth parameters were generally similar for recaptured coded‐wire‐tagged Chinook Salmon from different stocking locations and different recovery locations. Only a few small differences among stocking and recovery regions were evident, with regions divided into two subtly different groups with shared growth parameters. The small regional differences may be attributable to unique habitat and/or stocking characteristics of specific regions. In Lake Michigan average Chinook Salmon length at age also varied across years and was tightly coupled with annual lakewide densities of age‐1 and older Alewife, suggesting that Chinook Salmon growth from 2012 to 2016 was constrained by Alewife density. Our findings are consistent with evidence of lakewide movements associated with foraging and support continued management of Chinook Salmon in Lake Michigan as a single population. Furthermore, similar growth in Chinook Salmon from Lakes Michigan and Huron corroborates evidence that Chinook Salmon move from U.S. waters of Lake Huron to Lake Michigan to feed and reinforces the recent decision to include most fish stocked in northwestern Lake Huron in the Lake Michigan population when managing for predator–prey balance.

Lake Michigan, Lake Huron↗

Micromorphology and stable-isotope geochemistry of historical pedogenic siderite formed in PAH-contaminated alluvial clay soils, Tennessee, U.S.A

Alluvial clay soil samples from six boreholes advanced to depths of 400-450 cm (top of limestone bedrock) from the Chattanooga Coke Plant (CCP) site were examined micromorphologically and geochemically in order to determine if pedogenic siderite (FeCO3) was present and whether siderite occurrence was related to organic contaminant distribution. Samples from shallow depths were generally more heavily contaminated with polycyclic aromatic hydrocarbons (PAHs) than those at greater depth. The upper 1 m in most boreholes consisted of mixtures of anthropogenically remolded clay soil fill containing coal clinker, cinder grains, and limestone gravel; most layers of coarse fill were impregnated with creosote and coal tar. Most undisturbed soil (below 1 m depth) consisted of highly structured clays exhibiting fine subangular blocky ped structures, as well as redox-related features. Pedogenic siderite was abundant in the upper 2 m of most cores and in demonstrably historical (< 100 years old) soil matrices. Two morphologies were identified: (1) sphaerosiderite crystal spherulites ranging from 10 to 200 um in diameter, and (2) coccoid siderite comprising grape-like "clusters" of crystals 5-20 ??n in diameter. The siderite, formed in both macropores and within fine-grained clay matrices, indicates development of localized anaerobic, low-Eh conditions, possibly due to microbial degradation of organic contaminants. Stable-isotope compositions of the siderite have ??13C values spanning over 25%o (+7 to - 18%o VPDB) indicating fractionation of DIC by multiple microbial metabolic pathways, but with relatively constant ??18O values from (-4.8 ?? 0.66%o VPDB) defining a meteoric sphaerosiderite line (MSL). Calculated isotope equilibrium water ??18O values from pedogenic siderites at the CCP site are from 1 to 5 per mil lighter than the groundwater ??18O values that we estimate for the site. If confirmed by field studies in progress, this observation might call for a reevaluation of low-temperature siderite-water 18O fractionations. Investigations at the CCP site thus provide valuable information on the geochemical conditions under which siderite can form in modern soils, and thus insight on controls on siderite formation in ancient soils. Copyright ?? 2010, SEPM (Society for Sedimentary Geology).

Journal of Sedimentary Research↗

Limited occurrence of denitrification in four shallow aquifers in agricultural areas of the United States

The ability of natural attenuation to mitigate agricultural nitrate contamination in recharging aquifers was investigated in four important agricultural settings in the United States. The study used laboratory analyses, field measurements, and flow and transport modeling for monitoring well transects (0.5 to 2.5 km in length) in the San Joaquin watershed, California, the Elkhorn watershed, Nebraska, the Yakima watershed, Washington, and the Chester watershed, Maryland. Ground water analyses included major ion chemistry, dissolved gases, nitrogen and oxygen stable isotopes, and estimates of recharge date. Sediment analyses included potential electron donors and stable nitrogen and carbon isotopes. Within each site and among aquifer-based medians, dissolved oxygen decreases with ground water age, and excess N 2 from denitrification increases with age. Stable isotopes and excess N 2 imply minimal denitrifying activity at the Maryland and Washington sites, partial denitrification at the California site, and total denitrification across portions of the Nebraska site. At all sites, recharging electron donor concentrations are not sufficient to account for the losses of dissolved oxygen and nitrate, implying that relict, solid phase electron donors drive redox reactions. Zero-order rates of denitrification range from 0 to 0.14 μmol N L −1 d −1 , comparable to observations of other studies using the same methods. Many values reported in the literature are, however, orders of magnitude higher, which is attributed to a combination of method limitations and bias for selection of sites with rapid denitrification. In the shallow aquifers below these agricultural fields, denitrification is limited in extent and will require residence times of decades or longer to mitigate modern nitrate contamination.

Journal of Environmental Quality↗

Origin and properties of hydrothermal tremor at Lone Star Geyser, Yellowstone National Park, USA

Geysers are rare geologic features that intermittently discharge liquid water and steam driven by heating and decompression boiling. The cause of variability in eruptive styles and the associated seismic signals are not well understood. Data collected from five broadband seismometers at Lone Star Geyser, Yellowstone National Park are used to determine the properties, location, and temporal patterns of hydrothermal tremor. The tremor is harmonic at some stages of the eruption cycle and is caused by near‐periodic repetition of discrete seismic events. Using the polarization of ground motion, we identify the location of tremor sources throughout several eruption cycles. During preplay episodes (smaller eruptions preceding the more vigorous major eruption), tremor occurs at depths of 7–10 m and is laterally offset from the geyser's cone by ~5 m. At the onset of the main eruption, tremor sources migrate laterally and become shallower. As the eruption progresses, tremor sources migrate along the same path but in the opposite direction, ending where preplay tremor originates. The upward and then downward migration of tremor sources during eruptions are consistent with warming of the conduit followed by evacuation of water during the main eruption. We identify systematic relations among the two types of preplays, discharge, and the main eruption. A point‐source moment tensor fit to low‐frequency waveforms of an individual tremor event using half‐space velocity models indicates average V S ≳ 0.8 km/s, source depths ~4–20 m, and moment tensors with primarily positive isotropic and compensated linear vector dipole moments.

Wyoming↗

Comparing historical catch rates of American shad in multifilament and monofilament nets: A step toward setting restoration targets for Virginia stocks

Recreational and commercial harvest of American shad Alosa sapidissima in the Virginia waters of the Chesapeake Bay and its tributaries has been prohibited since 1994. The Atlantic States Marine Fisheries Commission Shad and River Herring Management Plan requires that Virginia develop restoration targets for its shad populations, but estimates of their sizes are not available and there is little information about historic population levels. Thus, establishing restoration targets based on population size is problematic. A current spawning stock monitoring program yields catch rate information that can be compared with historic catch rate information recorded in commercial fishery logbooks from the 1950s and the 1980s. However, multifilament gill nets were used in the 1950s and monofilament nets were used in the 1980s (as well as in the current monitoring program). A Latin square design was employed to test the differences in relative fishing power of the two gear types over 2 years of seasonal sampling on the York River, Virginia. Estimates are that the monofilament nets are roughly twice as efficient as the multifilament nets. Reported catch rates in the 1950s and 1980s are roughly equivalent. However, when adjustments are made for the differences in fishing gear, catch rates for the 1950s are twice as high as those during the 1980s. These results provide valuable information for setting restoration targets for Virginia stocks of American shad. ?? Copyright by the American Fisheries Society 2006.

North American Journal of Fisheries Management↗

Effects of habitat disturbance on survival rates of softshell turtles (Apalone spinifera) in an urban stream

We monitored Spiny Softshell Turtles (Apalone spinifera) using mark-recapture during 1994-2005 in Gin Creek, Searcy, Arkansas. In 1997-2000 the creek bed and riparian zone were bulldozed in an effort to remove debris and improve water flow. This disturbance appeared to reduce the quantity and quality of turtle habitat. We tested for the potential effect of this habitat disturbance on the survival rates of marked turtles. We estimated annual survival rates for the population using models that allowed for variation in survival by state of maturation, year, and effects of the disturbance; we evaluated two different models of the disturbance impact. The first disturbance model incorporated a single change in survival rates, following the disturbance, whereas the second disturbance model incorporated three survival rates: pre- and postdisturbance, as well as a short-term decline during the disturbance. We used a state-transition model for our mark-recapture analysis, as softshells transition from juveniles to adults in a variable period of time. Our analysis indicated that survival varied by maturation state and was independent of a time trend or the disturbance. Annual survival rates were lower for juveniles (S?? = 0.717, SE = 0.039) than for adults (S?? = 0.836, SE = 0.025). Despite the dramatic habitat disturbance, we found no negative effects on survival rates. Our results demonstrate that, like a few other freshwater turtle species known to thrive in urban environments, populations of A. spinifera are resilient and can persist in urban environments despite periodic habitat disturbances. Copyright 2008 Society for the Study of Amphibians and Reptiles.

Journal of Herpetology↗

Groundwater-level trends in the U.S. glacial aquifer system, 1964-2013

The glacial aquifer system in the United States is a major source of water supply but previous work on historical groundwater trends across the system is lacking. Trends in annual minimum, mean, and maximum groundwater levels for 205 monitoring wells were analyzed across three regions of the system (East, Central, West Central) for four time periods: 1964-2013, 1974-2013, 1984-2013, and 1994-2013. Trends were computed separately for wells in the glacial aquifer system with low potential for human influence on groundwater levels and ones with high potential influence from activities such as groundwater pumping. Generally there were more wells with significantly increasing groundwater levels (levels closer to ground surface) than wells with significantly decreasing levels. The highest numbers of significant increases for all four time periods were with annual minimum and/or mean levels. There were many more wells with significant increases from 1964 to 2013 than from more recent periods, consistent with low precipitation in the 1960s. Overall there were low numbers of wells with significantly decreasing trends regardless of time period considered; the highest number of these were generally for annual minimum groundwater levels at wells with likely human influence. There were substantial differences in the number of wells with significant groundwater-level trends over time, depending on whether the historical time series are assumed to be independent, have short-term persistence, or have long-term persistence. Mean annual groundwater levels have significant lag-one-year autocorrelation at 26.0% of wells in the East region, 65.4% of wells in the Central region, and 100% of wells in the West Central region. Annual precipitation across the glacial aquifer system, on the other hand, has significant autocorrelation at only 5.5% of stations, about the percentage expected due to chance.

Journal of Hydrology↗

Rapid chemical evolution of tropospheric volcanic emissions from Redoubt Volcano, Alaska, based on observations of ozone and halogen-containing gases

We report results from an observational and modeling study of reactive chemistry in the tropospheric plume emitted by Redoubt Volcano, Alaska. Our measurements include the first observations of Br and I degassing from an Alaskan volcano, the first study of O 3 evolution in a volcanic plume, as well as the first detection of BrO in the plume of a passively degassing Alaskan volcano. This study also represents the first detailed spatially-resolved comparison of measured and modeled O 3 depletion in a volcanic plume. The composition of the plume was measured on June 20, 2010 using base-treated filter packs (for F, Cl, Br, I, and S) at the crater rim and by an instrumented fixed-wing aircraft on June 21 and August 19, 2010. The aircraft was used to track the chemical evolution of the plume up to ~ 30 km downwind (2 h plume travel time) from the volcano and was equipped to make in situ observations of O 3 , water vapor, CO 2 , SO 2 , and H 2 S during both flights plus remote spectroscopic observations of SO 2 and BrO on the August 19th flight. The airborne data from June 21 reveal rapid chemical O 3 destruction in the plume as well as the strong influence chemical heterogeneity in background air had on plume composition. Spectroscopic retrievals from airborne traverses made under the plume on August 19 show that BrO was present ~ 6 km downwind (20 min plume travel time) and in situ measurements revealed several ppbv of O 3 loss near the center of the plume at a similar location downwind. Simulations with the PlumeChem model reproduce the timing and magnitude of the observed O 3 deficits and suggest that autocatalytic release of reactive bromine and in-plume formation of BrO were primarily responsible for the observed O 3 destruction in the plume. The measurements are therefore in general agreement with recent model studies of reactive halogen formation in volcanic plumes, but also show that field studies must pay close attention to variations in the composition of ambient air entrained into volcanic plumes in order to unambiguously attribute observed O 3 anomalies to specific chemical or dynamic processes. Our results suggest that volcanic eruptions in Alaska are sources of reactive halogen species to the subarctic troposphere.

Alaska↗

Inverse modeling of BTEX dissolution and biodegradation at the Bemidji, MN crude-oil spill site

The U.S. Geological Survey (USGS) solute transport and biodegradation code BIOMOC was used in conjunction with the USGS universal inverse modeling code UCODE to quantify field-scale hydrocarbon dissolution and biodegradation at the USGS Toxic Substances Hydrology Program crude-oil spill research site located near Bemidji, MN. This inverse modeling effort used the extensive historical data compiled at the Bemidji site from 1986 to 1997 and incorporated a multicomponent transport and biodegradation model. Inverse modeling was successful when coupled transport and degradation processes were incorporated into the model and a single dissolution rate coefficient was used for all BTEX components. Assuming a stationary oil body, we simulated benzene, toluene, ethylbenzene, m , p -xylene, and o -xylene (BTEX) concentrations in the oil and ground water, respectively, as well as dissolved oxygen. Dissolution from the oil phase and aerobic and anaerobic degradation processes were represented. The parameters estimated were the recharge rate, hydraulic conductivity, dissolution rate coefficient, individual first-order BTEX anaerobic degradation rates, and transverse dispersivity. Results were similar for simulations obtained using several alternative conceptual models of the hydrologic system and biodegradation processes. The dissolved BTEX concentration data were not sufficient to discriminate between these conceptual models. The calibrated simulations reproduced the general large-scale evolution of the plume, but did not reproduce the observed small-scale spatial and temporal variability in concentrations. The estimated anaerobic biodegradation rates for toluene and o -xylene were greater than the dissolution rate coefficient. However, the estimated anaerobic biodegradation rates for benzene, ethylbenzene, and m , p -xylene were less than the dissolution rate coefficient. The calibrated model was used to determine the BTEX mass balance in the oil body and groundwater plume. Dissolution from the oil body was greatest for compounds with large effective solubilities (benzene) and with large degradation rates (toluene and o -xylene). Anaerobic degradation removed 77% of the BTEX that dissolved into the water phase and aerobic degradation removed 17%. Although goodness-of-fit measures for the alternative conceptual models were not significantly different, predictions made with the models were quite variable.

Minnesota↗

Fresh ground water found deep beneath Nantucket Island, Masachusetts

In a deep water-resources and stratigraphic test well near the center of Nantucket Island, about 30 miles (48 kilometres) off the New England coast, freshwater has been found at greater depths than predicted by the Ghyben-Herzberg principle. An uppermost lens of freshwater, which occupies relatively permeable glacial-outwash sand and gravel to a depth of 520 feet (158 metres), is believed to be in hydrodynamic equilibrium with the present level of the sea and the height of the water table. However, two zones of freshwater at 730 to 820 ft (222-249 m) and 900 to 930 ft (274-283 m) are anomalously deep. Although several explanations are possible, the most likely is that the entire surface of the Continental Shelf was exposed to recharge by precipitation during long periods of low sea level in Pleistocene time. After the last retreat of glacial ice, seawater rapidly drowned the shelf around Nantucket Island. Since then, about 8,000 years ago, the deep freshwater zones which underlie dense clay layers have not had time to adjust to a new equilibrium. Under similar circumstances, freshwater may remain trapped under extensive areas of the Continental Shelf wherever clay confining beds have not permitted saltwater to intrude rapidly to new hydrodynamic equilibria positions. The implications are far reaching because all continental shelves worldwide were exposed to similar hydrologic influences during Pleistocene time.

Massachusetts↗

Noble gases, stable isotopes, and radiocarbon as tracers of flow in the Dakota aquifer, Colorado and Kansas

A suite of chemical and isotope tracers (dissolved noble gases, stable isotopes of water, radiocarbon, and CI) have been analyzed along a flow path in the Dakota aquifer system to determine likely recharge sources, ground water residence times, and the extent of mixing between local and intermediate flow systems, presumably caused by large well screens. Three water types were distinguished with the tracers, each having a very different history. Two of the water types were found in south-eastern Colorado where the Dakota is poorly confined. The tracer data suggest that the first group recharged locally during the last few thousand years and the second group was composed of ground water that recharged earlier during a cooler climate, presumably during the last glacial period (LGP) and mixed aged water. The paleotemperature record archived in this groundwater system indicates that south-eastern Colorado was about 5??C cooler during the LGP than during the late Holocene. Similar temperature changes derived from dissolved noble gases in other aquifer systems have been reported earlier for the south-western United States. The third water type was located down gradient of the first two in the confined Dakota in western and central Kansas. Groundwater residence time of this water mass is on the order of 104-105 yrs and its recharge location is near the Colorado and Kansas border down gradient of the other water types. The study shows the importance of using multiple tracers when investigating ground water systems.A suite of chemical and isotope tracers (dissolved noble gases, stable isotopes of water, radiocarbon, and CL) were analyzed along a flow path in the Dakota aquifer system to determine likely recharge sources, ground water residence times, and the extent of mixing between local and intermediate flow systems. Three water types were distinguished with the tracers, each having a very different history. Two of the water types were located in south-eastern Colorado where the Dakota is poorly confined. The third water type was located down gradient of the first two in the confined Dakota in western and central Kansas.

Journal of Hydrology↗

A 450-year record of environmental change from Castle Lake, California (USA), inferred from diatoms and organic geochemistry

A 39-cm sediment core from Castle Lake, California (USA) spans the last ~ 450 years and was analyzed for diatoms and organic geochemistry (δ 15 N, δ 13 C, and C:N), with the goal of determining sensitivity to natural climate variation and twentieth century anthropogenic effects. Castle Lake is a subalpine, nitrogen-limited lake with ~ 5 months of annual ice cover. Human impacts include light recreational use, past fish stocking, and experimental use by the Castle Lake Research Station. The base of the core (below 32 cm; pre mid-1700s) represents the period of maximum ice cover. In contrast, the end of the Little Ice Age (mid 1700s–early 1800s) is dominated by cyclotelloids (mostly Discostella stelligera ), indicating significant open-water periods, a condition that persisted into the early 1900s. Cyclotelloids began to decline in the 1960s and were replaced by the Fragilaria tenera grp. (peak in 1970s), succeeded by Asterionella formosa (peak ~ 2010), and accompanied by a reduction in δ 15 N values and a decrease in C:N that may represent increased atmospheric nitrogen deposition. Another anthropogenic signal was discerned in the core and was interpreted to be the result of an ammonium nitrate fertilization experiment of the epilimnion that was conducted in 1980 and 1981. This signal was manifested in the core largely by a negative excursion in δ 15 N, possibly caused by fractionation during denitrification in surface sediment. A phytoplankton monitoring dataset collected by the Castle Lake Research Station from 1967 to 1984 corroborates the timing of increased araphid euplanktonic species in the 1970s, and increases in two benthic diatoms ( Staurosirella pinnata and Tabellaria fenestrata) , entrained in the phytoplankton tows during the experimentation years. Both ice cover and nitrogen addition appear to be strong drivers that affected the lake diatoms, although additional drivers, such as fish stocking and associated cascade effects need further exploration. These data will be helpful for interpreting longer core records from Castle Lake, should the opportunity arise, as well as cores from similar systems in the region.

California↗

Evaluation of multidimensional transport through a field-scale compacted soil liner

A field-scale compacted soil liner was constructed at the University of Illinois at Urbana-Champaign by the U.S. Environmental Protection Agency (USEPA) and Illinois State Geological Survey in 1988 to investigate chemical transport rates through low permeability compacted clay liners (CCLs). Four tracers (bromide and three benzoic acid tracers) were each added to one of four large ring infiltrometers (LRIs) while tritium was added to the pond water (excluding the infiltrometers). Results from the long-term transport of Br - "> Br - from the localized source zone of LRI are presented in this paper. Core samples were taken radially outward from the center of the Br - "> Br - LRI and concentration depth profiles were obtained. Transport properties were evaluated using an axially symmetric transport model. Results indicate that (1) transport was diffusion controlled; (2) transport due to advection was negligible and well within the regulatory limits of k sat &#x2A7D; 1 &#xD7; 10 - 7 cm / s ; "> k sat ⩽ 1 × 10 − 7 cm / s; (3) diffusion rates in the horizontal and vertical directions were the same; and (4) small positioning errors due to compression during soil sampling did not affect the best fit advection and diffusion values. The best-fit diffusion coefficient for bromide was equal to the molecular diffusion coefficient multiplied by a tortuosity factor of 0.27, which is within 8% of the tortuosity factor (0.25) found in a related study where tritium transport through the same liner was evaluated. This suggests that the governing mechanisms for the transport of tritium and bromide through the CCL were similar. These results are significant because they address transport through a composite liner from a localized source zone which occurs when defects or punctures in the geomembrane of a composite system are present.

Journal of Geotechnical and Geoenvironmental Engin↗

Mudflow generated by retrogressive slope failure, Santa Barbara Basin, California continental borderland

The morphology and internal geometry of a mudflow deposit on the mainland slope of the Santa Barbara Basin are defined using high-resolution seismic-reflection data in combination with core samples. Sediment failure occurred on a 4 degrees slope in the uppermost part of late Quaternary well-bedded slope deposits. The failure zone extends from water depths of 374-510 m near the base of slope, occupies an area of 4 km 2 , and involved the translation of 0.01-0.02 km 3 of sediment. Major geomorphic features of the mudflow deposit include a headscarp 6-8 m high, a scar 50-700 m wide, and a main body 1 km long and 12 m thick. The hummocky surface of the mudflow deposits, their chaotic internal structure, and the bulbous toe tapering upslope to a thin tail are consistent with mass flow involving extensive internal deformation. Sediment failed in stages, ending with upslope retrogressive retreat of the headwall along the east side of the failure zone. Known sedimentation rates of 0.8-1.4 m/k.y., as well as the presence of a thin (0.15-0.5 m thick) sediment cap resting atop the scar surface, indicate that the failure probably occurred within the past few centuries. A geotechnical analysis incorporating the results of both static and dynamic triaxial strength tests shows that the failure was probably caused by a strong (M nearly equal 7.5) nearby earthquake. The weakened sediment that remained after earthquake shaking continued to flow down the gentle basin slope under the stresses generated by gravity alone. The analysis also shows that much of the slope sediment is marginally stable and that additional mudflows will probably occur during future strong seismic shaking.

California↗

Long-term trends in the St. Marys River open water fish community

We examined trends in species composition and abundance of the St. Marys River fish community. Abundance data were available approximately once every six years from 1975 through 2006, and size and age data were available from 1995 through 2006. We also compared survey data in 2006 with results of a concurrent creel survey that year, as well as data from prior surveys spanning a 69 year time frame. The St. Marys River fish community was best characterized as a coolwater fish community with apparent little variation in species composition, and only slight variation in overall fish abundance since 1975. However, we did find recent trends in abundance among target species sought by anglers: centrarchids increased, percids appeared stable, and both northern pike Esox lucius and cisco Coregonus artedii declined. Survey results suggested that walleye ( Sander vitreus ) and yellow perch ( Perca flavescens ) experienced moderate exploitation but benefited from recent strong recruitment and faster growth. Mechanisms underlying declines of northern pike and cisco were not clear; reduced abundance could have resulted from high exploitation, variation in recruitment, or a combination of both factors. Despite these challenges, the St. Marys River fish community appears remarkably stable. We suggest that managers insure that creel surveys occur simultaneously with assessments, but periodic gill net surveys may no longer provide adequate data in support of recent, more complex management objectives. While additional surveys would add costs, more frequent data might ensure sustainability of a unique fish community that supports a large proportion of angler effort on Lake Huron.

Michigan;Ontario↗

High-resolution mapping of the freshwater-brine interface using deterministic and Bayesian inversion of airborne electromagnetic data at Paradox Valley, USA

Salt loads in the Colorado River Basin are a primary water quality concern. Natural groundwater brine discharge to the Dolores River where it passes through the collapsed salt anticline of the Paradox Valley in western Colorado is a significant source of salt to the Colorado River. An airborne electromagnetic survey of Paradox Valley has provided insights into the 3D distribution of brine in the surficial aquifer. A combination of stochastic and deterministic resistivity inversions were used to interpret the top of the freshwater-brine interface and to qualitatively describe the vertical salinity gradients across the interface. Low-resistivity regions indicative of brine occur near the land surface where brine discharges to the Dolores River and increase in depth several kilometers up-gradient along the axis of the valley. The most conductive parts of the brine plume are found in the areas below and adjacent to the river, suggesting that the brine becomes shallower and more concentrated as it reaches its natural discharge location. A significant freshwater lens overlying the brine west of the Dolores River is spatially correlated to the intermittent West Paradox Creek and agricultural irrigation. Below this lens, the transition from freshwater to brine appears to occur abruptly over a few meters and correlates to available well information. However, away from these regions and particularly with distance from the river, the freshwater-brine interface appears to be more diffuse.

Colorado↗