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USGS2011

Acetate availability and its influence on sustainable bioremediation of Uranium-contaminated groundwater

Field biostimulation experiments at the U.S. Department of Energy's Integrated Field Research Challenge (IFRC) site in Rifle, Colorado, have demonstrated that uranium concentrations in groundwater can be decreased to levels below the U.S. Environmental Protection Agency's (EPA) drinking water standard (0.126 μM). During successive summer experiments – referred to as “Winchester” (2007) and “Big Rusty” (2008) - acetate was added to the aquifer to stimulate the activity of indigenous dissimilatory metal-reducing bacteria capable of reductively immobilizing uranium. The two experiments differed in the length of injection (31 vs. 110 days), the maximum concentration of acetate (5 vs. 30 mM), and the extent to which iron reduction (“Winchester”) or sulfate reduction (“Big Rusty”) was the predominant metabolic process. In both cases, rapid removal of U(VI) from groundwater occurred at calcium concentrations (6 mM) and carbonate alkalinities (8 meq/L) where Ca-UO 2 -CO 3 ternary complexes constitute >90% of uranyl species in groundwater. Complete consumption of acetate and increased alkalinity (>30 meq/L) accompanying the onset of sulfate reduction corresponded to temporary increases in U(VI); however, by increasing acetate concentrations in excess of available sulfate (10 mM), low U(VI) concentrations (0.1–0.05 μM) were achieved for extended periods of time (>140 days). Uniform delivery of acetate during “Big Rusty” was impeded due to decreases in injection well permeability, likely resulting from biomass accumulation and carbonate and sulfide mineral precipitation. Such decreases were not observed during the short-duration “Winchester” experiment. Terminal restriction fragment length polymorphism (TRFLP) analysis of 16S rRNA genes demonstrated that Geobacter sp. and Geobacter -like strains dominated the groundwater community profile during iron reduction, with 13 C stable isotope probing (SIP) results confirming these strains were actively utilizing acetate to replicate their genome during the period of optimal U(VI) removal. Gene transcript levels during “Big Rusty” were quantified for Geobacter -specific citrate synthase ( gltA ), with ongoing transcription during sulfate reduction indicating that members of the Geobacteraceae were still active and likely contributing to U(VI) removal. The persistence of reducible Fe(III) in sediments recovered from an area of prolonged (110-day) sulfate reduction is consistent with this conclusion. These results indicate that acetate availability and its ability to sustain the activity of iron- and uranyl-respiring Geobacter strains during sulfate reduction exerts a primary control on optimized U(VI) removal from groundwater at the Rifle IFRC site over extended time scales (>50 days).

Geomicrobiology Journal↗

USGS1993

Evaluation of 55Fe as a tracer of Fe(III) reduction in aquatic sediments

The potential utility of 55 Fe as a tracer for Fe(III) reduction in aquatic sediments was evaluated using freshwater sediments from the Potomac River, Md, in which Fe(III) reduction was the predominant terminal electron accepting process. In laboratory incubations of sediments amended with poorly crystalline 55 Fe(III) oxide, the accumulation of 55 Fe in Fe(II) over time paralleled Fe(II) production. However, within 1 h of addition of 55 Fe(III) oxide, significant quantities of 55 Fe were recovered in extractable (1 M sodium acetate, pH 5) and soluble Fe(II) pools. There was proportionately more 55 Fe(II) activity in sediments with higher Fe(II) concentrations. These results suggest that there was rapid isotopic exchange between 55 Fe in poorly crystalline Fe(III) oxide and the Fe(II) pools. Because of this exchange, 55 Fe could not be used to trace Fe(III) reduction in sediments in the manner that 35 SO 4 2− is used to trace sulfate reduction. Although accumulation of 55 Fe in Fe(II) pools paralleled unla‐beled Fe(II) production, given the relative ease with which Fe(II) pools in sediments can be measured there is no apparent advantage to using 55 Fe to follow Fe(III) reduction.

Geomicrobiology Journal↗

USGS1992

Trace elements in lake sediment, macrozoobenthos, and fish near a coal ash disposal basin

Samples of lake sediment, macrozoobenthos, and fish were collected during 1983 and 1984 near a coal ash disposal basin situated on the western shoreline of Lake Erie. Neutron activation analysis was used to determine if potentially toxic trace elements were present in higher concentrations at stations near the basin than at reference stations a few kilometers away. Of the 29 trace elements examined, arsenic and cobalt were significantly ( p <0.05) more concentrated in sediment nearest the coal ash basin except in spring, when little or no difference was detected. Arsenic and bromine were significantly higher in oligochaetes, and selenium was significantly higher in both oligochaetes and chironomids taken from proximal stations than in those taken from reference stations. Selenium, bromine, cobalt, nickel, and chromium were higher in young-of-the-year brown bullheads taken nearer the disposal basin in fall 1983. Selenium was higher in adult spottail shiners taken at the proximal station in spring 1984, and bromine was higher in yearling white bass from the proximal station in fall 1983 and 1984. None of the trace elements was higher in adult yellow perch or adult brown bullheads at any time. Fewer spottail shiners and yearling white bass were caught close to the disposal basin than far away, which may indicate avoidance by these fish of increased concentrations of trace elements contained within the ash effluent.

Journal of Freshwater Ecology↗

USGS1993

Morphometric differentiation of American shad and white sucker eggs from riverine samples

We developed a statistical method to distinguish the large demersal eggs of American shad from those of white sucker in riverine samples using egg morphometric analysis. Eggs were first screened by total diameter in deionized water according to ranges reported in the published literature. Differences in relative yolk diameter between the two species were then determined statistically from known museum sources. Only those eggs with relative yolk diameters greater than two standard deviations below the mean for white sucker eggs were considered to be American shad eggs. The criteria for American shad eggs were total diameter ≥2.3 nm and relative yolk diameter ≤66%. A partial test of the model showed predicted identity to agree with observed identity for 74 out of 75 shad eggs.

Journal of Freshwater Ecology↗

USGS1997

Pharyngeal teeth of the freshwater drum ( Aplodinotus grunniens ) a predator of the zebra mussel ( Dreissena polymorpha )

The morphology of pharyngeal teeth of freshwater drum ( Aplodinotus grunniens ) was studied to determine changes that occur during growth of drum that may relate to consumption of zebra mussel ( Dreissena polymorpha ) by larger fish. Pharyngeal teeth were of three types. Cardiform teeth were replaced by villiform teeth, which were replaced by molariform teeth as the size class of drum increased. Molariform teeth comprised over 85% of total surface area of dentition in fish 265 mm long.

Journal of Freshwater Ecology↗

USGS2011

Fish species composition two second-order headwater streams the North Central Appalachians ecoregion

Fish species composition was determined for two second-order headwater streams within the North Central Appalachians ecoregion in northern Pennsylvania. The two streams were widely spaced geographically (over 193 km apart) and occurred in different drainage systems. Streams were sampled in the spring and fall over two years (1996–98) yielding similar fish assemblages. A total of five species was collected. Mottled sculpin ( Cottus bairdli ), slimy sculpin ( Cottus cognatus ), brook trout ( Salvetinus fontinalis ), and brown trout ( Salmo trutta ) were the dominant adult fishes. Two creek chubs ( Semotilus atromaculatus ) were also collected. No significant differences were found in sculpin weight, sculpin length, salmonid length, or brook trout length between streams. Paired t-tests detected eight significant seasonal differences within sites. Brook trout and mottled sculpin lengths were significantly greater in fall versus spring, while the reverse was found with slimy sculpins. Catches per unit effort were similar between the two streams, yielding 8.46 and 8.07 fish per minute of electrofishing. Both streams were very similar in faunal assemblages attributed to small, coldwater, high quality headwater streams in other regions.

Pennsylvanaia↗

USGS2009

Lake St. Clair zooplankton: Evidence for post-Dreissena changes

We surveyed the zooplankton of Lake St. Clair at 12 sites over ten dates from May to October 2000. Mean zooplankton density by site and date was 168.6 individuals/L, with Dreissena spp. veligers the most abundant taxon at 122.7 individuals/L. Rotifers, copepods, and cladocerans were far lower in mean abundance than in the early 1970s (rotifers, 20.9/L; copepods, 18.1/L; and cladocerans, 6.8/L). Species richness of zooplankton taxa in 2000 was 147, which was virtually unchanged from that of the first reported survey in 1894. Overall, the decline in abundance was greatest for rotifers (-90%) and about equal for cladocerans (-69%) and copepods (-66%). The decrease in abundance of Daphnia spp. was especially dramatic in Canadian waters. The decline in the southeastern region was significant for all three major groups of zooplankton, whereas in the northwestern region the decline was significant only for rotifers. From June to August 2000, Lake St. Clair open waters were numerically dominated by Dreissena spp. veligers, with a reduced abundance of rotifers and crustaceans compared to pre-Dreissena spp. surveys. Mean nutrient concentrations were not different from the 1970s, but Secchi depth (greater) and chlorophyll a concentration (lower) were. Disproportionate reduction in rotifer abundance is consistent with hypotheses implicating direct consumption by settled Dreissena spp. Reduction of crustaceans is likely due to more complex interactions including removal of nauplii as well as resource competition for phytoplankton.

Michigan, Ontario↗

USGS2014

Landsat TM memory effect characterization and correction

Before radiometric calibration of Landsat Thematic Mapper (TM) data can be done accurately, it is necessary to minimize the effects of artifacts present in the data that originate in the instrument's signal processing path. These artifacts have been observed in downlinked image data since shortly after launch of Landsat 4 and 5. However, no comprehensive work has been done to characterize all the artifacts and develop methods for their correction. In this paper, the most problematic artifact is discussed: memory effect (ME). Characterization of this artifact is presented, including the parameters necessary for its correction. In addition, a correction algorithm is described that removes the artifact from TM imagery. It will be shown that this artifact causes significant radiometry errors, but the effect can be removed in a straightforward manner.

Canadian Journal of Remote Sensing↗

USGS1992

Placer and lode platinum-group minerals in south Kalimantan, Indonesia: Evidence for derivation from Alaskan-type ultramafic intrusions

Platinum‐group element minerals (PGM) occur in significant proportions in placer deposits in several localities in South Kalimantan. They consist of Pt‐Fe alloy that may be intergrown with or contain inclusions of Ir‐Os‐Ru alloy, laurite and chromite. Alluvial PGM found along Sungai Tambanio are in part derived from chromitite schlieren in dunitic bodies intruded into clinopyroxene cumulates that may be part of an Alaskan‐type ultramafic complex. A chromitite schlieren in serpentinite from one of these dunitic bodies is anomalous in PGE (Pt: 580 ppb; Pd: 3.4 ppb; Rh: 1 ppb; Ru: 9 ppb; Ir: 21 ppb; and Os: 3.9 ppb). The chondrite‐normalized PGE pattern for this rock, pan concentrates from this area, and PGM concentrates from diamond‐Au‐PGM placer deposits have an ‘M'‐shaped pattern enriched in Ir and Pt that is typical of PGE‐mineralization associated with Alaskan‐type ultramafic complexes.

South Kalimantan↗

USGS1997

Episodic nature of earthquake activity in stable continental regions revealed by palaeoseismicity studies of Australian and North American Quaternary faults

Palaeoseismic investigations of recent faulting in stable continental regions of Australia, North America and India show that these faults typically have a long-term behaviour characterised by episodes of activity separated by quiescent intervals of at least 10 000 and commonly 100 000 years or more. Long recurrence intervals such as these are well documented by detailed studies of the faults that ruptured during the 1986 Marryat Creek, South Australia and 1988 Tennant Creek, Northern Territory earthquakes. Thus, neotectonic features associated with stable continental region faults such as scarps and grabens commonly have subtle geomorphic expression and may be poorly preserved. Many potentially hazardous faults in stable continental regions are aseismic, which is one reason why the inventory of these faults is incomplete. Although they may be currently aseismic, faults in stable continental regions that are favourably oriented for movement in the current stress field could produce damaging earthquakes, often in unexpected places. Comprehensive palaeoseismic investigations of modern and prehistoric faulting events in stable continental regions are needed to understand the long-term behaviour of these faults, and thereby, improve seismic-hazard assessments.

Australian Journal of Earth Sciences↗

USGS2014

Florfenicol residues in Rainbow Trout after oral dosing in recirculating and flow-through culture systems

Aquaflor is a feed premix for fish containing the broad spectrum antibacterial agent florfenicol (FFC) incorporated at a ratio of 50% (w/w). To enhance the effectiveness of FFC for salmonids infected with certain isolates of Flavobacterium psychrophilum causing coldwater disease, the FFC dose must be increased from the standard 10 mg·kg −1 body weight (BW)·d −1 for 10 consecutive days. A residue depletion study was conducted to determine whether FFC residues remaining in the fillet tissue after treating fish at an increased dose would be safe for human consumption. Groups of Rainbow Trout Oncorhynchus mykiss (total n = 144; weight range, 126–617 g) were treated with FFC at 20 mg·kg −1 BW·d −1 for 10 d in a flow-through system (FTS) and a recirculating aquaculture system (RAS) each with a water temperature of ∼13°C. The two-tank RAS included a nontreated tank containing 77 fish. Fish were taken from each tank (treated tank, n = 16; nontreated tank, n = 8) at 6, 12, 24, 48, 72, 120, 240, 360, and 480 h posttreatment. Florfenicol amine (FFA) concentrations (the FFC marker residue) in skin-on fillets from treated fish were greatest at 12 h posttreatment (11.58 μg/g) in the RAS and were greatest at 6 h posttreatment (11.09 μg/g) in the FTS. The half-lives for FFA in skin-on fillets from the RAS and FTS were 20.3 and 19.7 h, respectively. Assimilation of FFC residues in the fillets of nontreated fish sharing the RAS with FFC-treated fish was minimal. Florfenicol water concentrations peaked in the RAS-treated tank and nontreated tanks at 10 h (453 μg/L) and 11 h (442 μg/L) posttreatment, respectively. Monitoring of nitrite concentrations throughout the study indicated the nitrogen oxidation efficiency of the RAS biofilter was minimally impacted by the FFC treatment.

Journal of Aquatic Animal Health↗

USGS1998

Issues and prospects for the next generation of the spatial data transfer standard (SDTS)

The Spatial Data Transfer Standard (SDTS) was designed to be capable of representing virtually any data model, rather than being a prescription for a single data model. It has fallen short of this ambitious goal for a number of reasons, which this paper investigates. In addition to issues that might have been anticipated in its design, a number of new issues have arisen since its initial development. These include the need to support explicit feature definitions, incremental update, value-added extensions, and change tracking within large, national databases. It is time to consider the next stage of evolution for SDTS. This paper suggests development of an Object Profile for SDTS that would integrate concepts for a dynamic schema structure, OpenGIS interface, and CORBA IDL.

International Journal of Geographical Information ↗

USGS2009

Experimental feeding of DDE and PCB to female big brown bats (Eptesicus fuscus)

Twenty-two female big brown bats (Eptesicus fuscus) were collected in a house attic in Montgomery County, Maryland. Seventeen were fed mealworms (Tenebrio molitor larvae) that contained 166 ppm DDE; the other five were fed uncontaminated mealworms. After 54 days of feeding, six dosed bats were frozen and the remaining 16 were starved to death. In a second experiment, 21 female big brown bats were collected in a house attic in Prince Georges County, Maryland. Sixteen were fed mealworms that contained 9.4 ppm Aroclor 1254 (PCB). After 37 days, two bats had died, four dosed bats were frozen, and the remaining 15 were starved to death. Starvation caused mobilization of stored residues. After the feeding periods, average weights of all four groups (DDE-dosed, DDE control, PCB-dosed, PCB control) had increased. However, weights of DDE-dosed bats had increased significantly more than those of their contols, whereas weights of PCB-dosed bats had increased significantly less than those of their controls. During starvation, PCB-dosed bats lost weight significantly more slowly than controls. Because PCB levels in dosed bats resembled levels found in some free-living big brown bats, PCBs may be slowing metabolic rates of some free-living bats. It is not known how various common organochlorine residues may affect metabolism in hibernating bats. DDE and PCB increased in brains of starving bats as carcass fat was metabolized. Because the tremors and/or convulsions characteristic of neurotoxicity were not observed, we think even the maximum brain levels attained (132 ppm DDE, 20 ppm PCB) were sublethal. However, extrapolation of our DDE data predicted lethal brain levels when fat reserves declined sufficiently. PCB-dosed bats were probably in no danger of neurotoxic poisoning. However, PCB can kill by a nonneurotoxic mode, and this could explain the deaths of two bats on PCB dosage.

Journal of Toxicology and Environmental Health↗

USGS2020

Riverbank stability assessment of lower Osage River during hydro-peak flow events: The lower Osage River case (Missouri, USA)

The fluctuation of water level downstream from dams due to hydropower flow releases can negatively affect riverbank stability. This research aims to investigate riverbank instability resulting from the outflow variation of hydropower plants, using Bagnell Dam and the lower Osage River (Missouri, USA) as the basis of analysis. The effects of the water releases from the Bagnell Dam were investigated by computing a series of safety factors in relation to outflow events for 78 cross sections along the 130-km stretch of the lower Osage River using the BSTEM algorithm integrated into the HEC-RAS model package. The results showed that the rate of change in the flow magnitude at each cross section impacts the calculated safety factor. The flow release fluctuations will change the value of the safety factor along the river over time, as the safety factor value closely follows the variation in the flow rate. Also, the results show that the cross sections closer to Bagnell Dam are subjected to be more unstable than those farther downstream of Osage River.

Missouri↗

USGS2024

The influence of channel morphology and hydraulic complexity on larval pallid sturgeon (Scaphirhynchus albus) drift and dispersal dynamics in the Fort Peck Segment, Upper Missouri River: Insights from particle tracking simulations

Longitudinal dispersal of migratory fish species can be interrupted by factors that fragment rivers, such as dams and reservoirs with incompatible habitats, and indirect alterations to variables, such as water temperature or turbidity. The endangered pallid sturgeon ( Scaphirhynchus albus ) population in the Upper Missouri River Basin in North Dakota and Montana is an example of such fragmentation and alteration due to the construction of dams. We applied a high-resolution, 2+-dimensional modelling framework composed of hydrodynamic and Lagrangian particle tracking components to simulate pallid sturgeon larval drift and dispersal along a 33-km section of the Upper Missouri River to evaluate three main issues: a comparison between multidimensional models and traditional 1-dimensional models, the sensitivity of hydrodynamics to channel morphology, and the implications of channel morphology on retention and transport-time metrics for larval fish. The results indicate that multidimensional models better represent breakthrough curves of transporting larvae compared to 1-dimensional models, especially for the long tail of slow drifters in the population. Results also indicate that channel morphology and hydraulic complexity play significant roles in larval dispersal with certain flow conditions and channel features increasing larval retention and providing potential management options to increase survival rates by adjusting flow conditions during spawning events. For example, modelling indicates increased retention times at discharges 23–38% daily flow exceedance, coincident with emergence of mid-channel sandbars. Findings additionally emphasize the need for improved understanding of biological factors that affect larval drift and dispersal.

Montana, North Dakota↗

USGS2002

Groundwater contamination downstream of a contaminant penetration site. I. Extension-expansion of the contaminant plume

This study concerns the possible use of boundary layer (BL) approach for the analysis and evaluation of contaminant transport in groundwater due to contaminant penetration into the groundwater aquifer through a site of limited size. The contaminant penetration may occur through either the upper (surface) or lower (bedrock) boundary of the aquifer. Two general cases of contaminant penetration mechanisms are considered: (1) the contaminant is transferred through an interface between a contaminating and freshwater fluid phases, and (2) the contaminant arrives at groundwater by leakage and percolation. For the purpose of BL evaluation the contaminant plume is divided into three different sections: (1) the penetration section, (2) the extension-expansion section, and (3) the spearhead section. In each section a different BL method approach yields simple analytical expressions for the description of the contaminant plume migration and contaminant transport. Previous studies of the BL method can be directly applied to the evaluation of contaminant transport at the contaminant penetration section. The present study extends those studies and concerns the contaminant transport in the two other sections, which are located downstream of the penetration section. This study shows that the contaminant concentration profiles in sections 2 and 3 incorporate two BLs: (1) an inner BL adjacent to the aquifer bottom or surface boundary, and (2) an outer BL, which develops above or below the inner one. The method developed in the present study has been applied to practical issues concerning salinity penetration into groundwater in south central Kansas.

Journal of Environmental Science and Health - Part↗

USGS2002

Groundwater contamination downstream of a contaminant penetration site. II. Horizontal penetration of the contaminant plume

Part I of this study (Rubin, H.; Buddemeier, R.W. Groundwater Contamination Downstream of a Contaminant Penetration Site Part 1: Extension-Expansion of the Contaminant Plume. J. of Environmental Science and Health Part A (in press).) addressed cases, in which a comparatively thin contaminated region represented by boundary layers (BLs) developed within the freshwater aquifer close to contaminant penetration site. However, at some distance downstream from the penetration site, the top of the contaminant plume reaches the top or bottom of the aquifer. This is the location of the "attachment point," which comprises the entrance cross section of the domain evaluated by the present part of the study. It is shown that downstream from the entrance cross section, a set of two BLs develop in the aquifer, termed inner and outer BLs. It is assumed that the evaluated domain, in which the contaminant distribution gradually becomes uniform, can be divided into two sections, designated: (a) the restructuring section, and (b) the establishment section. In the restructuring section, the vertical concentration gradient leads to expansion of the inner BL at the expense of the outer BL, and there is almost no transfer of contaminant mass between the two layers. In the establishment section, each of the BLs occupies half of the aquifer thickness, and the vertical concentration gradient leads to transfer of contaminant mass from the inner to the outer BL. By use of BL approximations, changes of salinity distribution in the aquifer are calculated and evaluated. The establishment section ends at the uniformity point, downstream from which the contaminant concentration profile is practically uniform. The length of the restructuring section, as well as that of the establishment section, is approximately proportional to the aquifer thickness squared, and is inversely proportional to the transverse dispersivity. The study provides a convenient set of definitions and terminology that are helpful in visualizing the gradual development of uniform contaminant concentration distribution in an aquifer subject to contaminant plume penetration. The method developed in this study can be applied to a variety of problems associated with groundwater quality, such as initial evaluation of field data, design of field data collection, the identification of appropriate boundary conditions for numerical models, selection of appropriate numerical modeling approaches, interpretation and evaluation of field monitoring results, etc.

Journal of Environmental Science and Health - Part↗

USGS2000

Timing of the Acadian Orogeny in northern New Hampshire

New U-Pb geochronology constrains the timing of the Acadian orogeny in the Central Maine Terrane of northern New Hampshire. Sixteen fractions of one to six grains each of zircon or monazite have been analyzed from six samples: (1) an early syntectonic diorite that records the onset of the Acadian, (2) a schist, a migmatite, and two granites that together record the peak of the Acadian; and (3) a postkinematic pluton that records the end of the Acadian. Zircon from the syntectonic Wamsutta Diorite gives a 207Pb/206Pb age of circa 408 Ma, the time at which the boundary between the deforming orogenic wedge and the foreland basin was in the vicinity of the Presidential Range. This age agrees well with the Emsian position of the northwest migrating Acadian orogenic front and records the beginning of the Acadian in this part of the Central Maine Terrane. We propose a possible Acadian tectonic model that incorporates the geochronologic, structural, and stratigraphic data. Monazite from the schist, migmatite, Bigelow Lawn Granite, and Slide Peak Granite gives 207Pb/206U ages, suggesting the peak of Acadian metamorphism and intrusion of two-mica granites occurred at circa 402-405 Ma, the main pulse of Acadian orogenesis. Previously reported monazite ages from schists that likely record the peak metamorphism in the Central Maine Terrane of New Hampshire and western Maine range from circa 406-384 Ma, with younger ages in southeastern New Hampshire and progressively older ages to the west, north, and northeast. Acadian orogenesis in the Presidential Range had ended by circa 355 Ma, the 207Pb/235U age of monazite from the Peabody River Granite. From 408 to perhaps at least 394 Ma, Acadian orogenesis in the Presidential Range was typical of the tectonic style, dominated by synkinematic metamorphism, seen in central and southern New Hampshire, Massachusetts, and Connecticut. From no earlier than 394 Ma to as late as 355 Ma, the orogenesis was typical of the style in parts of Maine dominated by postkinematic metamorphism.

Journal of Geology↗