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At least 757 records · Page 42Linked to original sources

Long-term trends of surface-water mercury and methylmercury concentrations downstream of historic mining within the Carson River watershed

The Carson River is a vital water resource for local municipalities and migratory birds travelling the Pacific Flyway. Historic mining practices that used mercury (Hg) to extract gold from Comstock Lode ore has left much of the river system heavily contaminated with Hg, a practice that continues in many parts of the world today. Between 1998 and 2013, the United States Geological Survey (USGS) collected and analyzed Carson River water for Hg and methylmercury (MeHg) concentrations resulting in a sixteen year record of unfiltered total mercury (uf.THg), filtered (dissolved) Hg (f.THg), total methylmercury (uf.MeHg), filtered MeHg (f.MeHg), and particulate-bound THg (p.THg) and MeHg (p.MeHg) concentrations. This represents one of the longest continuous records of Hg speciation data for any riverine system, thereby providing a unique opportunity to evaluate long-term trends in concentrations and annual loads. During the period of analysis, uf.THg concentration and load trended downward at rates of −0.85% and −1.8% per year, respectively. Conversely, the f.THg concentration increased at a rate of 1.7% per year between 1998 and 2005, and 4.9% per year between 2005 and 2013. Trends in flow-normalized partition coefficients for both Hg and MeHg suggest a statistically significant shift from the particulate to the filtered phase. The upwardly accelerating f.THg concentration and observed shift from the solid phase to the aqueous phase among the pools of Hg and MeHg within the river water column signals an increased risk of deteriorating ecological conditions in the lower basin with respect to Hg contamination. More broadly, the 16-year trend analysis, completed 140 years after the commencement of major Hg releases to the Carson River, provides a poignant example of the ongoing legacy left behind by gold and silver mining techniques that relied on Hg amalgamation, and a cautionary tale for regions still pursuing the practice in other countries.

Nevada↗

Spatial and temporal variations in silver contamination and toxicity in San Francisco Bay

Although San Francisco Bay has a "Golden Gate", it may be argued that it is the "Silver Estuary". For at one time the Bay was reported to have the highest levels of silver in its sediments and biota, along with the only accurately measured values of silver in solution, of any estuarine system. Since then others have argued that silver contamination is higher elsewhere (e.g., New York Bight, Florida Bay, Galveston Bay) in a peculiar form of pollution machismo, while silver contamination has measurably declined in sediments, biota, and surface waters of the Bay over the past two to three decades. Documentation of those systemic temporal declines has been possible because of long-term, ongoing monitoring programs, using rigorous trace metal clean sampling and analytical techniques, of the United States Geological Survey and San Francisco Bay Regional Monitoring Program that are summarized in this report. However, recent toxicity studies with macro-invertebrates in the Bay have indicated that silver may still be adversely affecting the health of the estuarine system, and other studies have indicated that silver concentrations in the Bay may be increasing due to new industrial inputs and/or the diagenetic remobilization of silver from historically contaminated sediments being re-exposed to overlying surface waters and benthos. Consequently, the Bay may not be ready to relinquish its title as the "Silver Estuary".

California↗

Comment on “An unconfined groundwater model of the Death Valley Regional Flow System and a comparison to its confined predecessor” by R.W.H. Carroll, G.M. Pohll and R.L. Hershey [Journal of Hydrology 373/3–4, pp. 316–328]

Carroll et al. (2009) state that the United States Geological Survey (USGS) Death Valley Regional Flow System (DVRFS) model, which is based on MODFLOW, is “conceptually inaccurate in that it models an unconfined aquifer as a confined system and does not simulate unconfined drawdown in transient pumping simulations.” Carroll et al. (2009) claim that “more realistic estimates of water availability” can be produced by a SURFACT-based model of the DVRFS that simulates unconfined groundwater flow and limits withdrawals from wells to avoid excessive drawdown. Differences in results from the original MODFLOW-based model and the SURFACT-based model stem primarily from application by Carroll et al. (2009) of head limits that can also be applied using the existing MODLOW model and not from any substantial difference in the accuracy with which the unconfined aquifer is represented in the two models. In a hypothetical 50-year predictive simulation presented by Carroll et al. (2009), large differences between the models are shown when simulating pumping from the lower clastic confining unit, where the transmissivity is nearly two orders of magnitude less than in an alluvial aquifer. Yet even for this extreme example, drawdowns and pumping rates from the MODFLOW and SURFACT models are similar when the head-limit capabilities of the MODFLOW MNW Package are applied. These similarities persist despite possible discrepancies between assigned hydraulic properties. The resulting comparison between the MODFLOW and SURFACT models of the DVRFS suggests that approximating the unconfined system in the DVRFS as a constant-saturated-thickness system (called a “confined system” by Carroll et al., 2009) performs very well.

Death Valley↗

Co-occurrence of pesticides and pharmaceuticals and personal care products (PPCPs) across Zostera marina (common eelgrass) communities

Anthropogenic pressures are driving changes in eelgrass communities, which are altering baseline conditions in estuarine environments. Field detections have validated the transport of land-sourced pollutants to aquatic systems; however, studies rarely sample concurrently for pesticides, and pharmaceuticals and personal care products (PPCPs) across environmental compartments. Moreover, studies on contaminant uptake by eelgrass and associated species are even more limited. In collaboration with the Confederated Tribes of the Coos, Lower Umpqua and Siuslaw Indians (CTCLUSI), this study collected samples of water, eelgrass, clams, and sediment at sites of Tribal significance in Southern Oregon to test for organic contaminants (i.e., herbicides and pharmaceuticals). Paired sampling was conducted for analysis by the CTCLUSI in tandem with the United States Geological Survey (USGS) in order for the Tribe to develop analytical standards for future sampling efforts. Ten pesticides and eight pharmaceuticals were detected across the four sites, with the highest number of overall detections (27) at the Florence Marina site. The insecticide bifenthrin was most frequently detected across all media (0.012–1.565 μg/g organic carbon in sediment, 2.7–30 ng/g in organismal tissue) and the anti-diabetic agent metformin was the most detected PPCP in clam tissues (1.33–3.78 ng/g). Pesticides and PPCPs were observed to co-occur in eelgrass habitats, with numerous pesticide detections across media types. These findings demonstrate numerous routes of exposure for estuarine organisms which could be addressed with pharmaceutical disposal strategies or pesticide use restrictions near these habitats.

Oregon↗

Sensitivity of Pliocene ice sheets to orbital forcing

The stability of the Earth's major ice sheets is a critical uncertainty in predictions of future climate and sea level change. One method of investigating the behaviour of the Greenland and the Antarctic ice sheets in a warmer-than-modern climate is to look back at past warm periods of Earth history, for example the Pliocene. This paper presents climate and ice sheet modelling results for the mid-Pliocene warm period (mPWP; 3.3 to 3.0 million years ago), which has been identified as a key interval for understanding warmer-than-modern climates (Jansen et al., 2007). Using boundary conditions supplied by the United States Geological Survey PRISM Group (Pliocene Research, Interpretation and Synoptic Mapping), the Hadley Centre coupled ocean–atmosphere climate model (HadCM3) and the British Antarctic Survey Ice Sheet Model (BASISM), we show large reductions in the Greenland and East Antarctic Ice Sheets (GrIS and EAIS) compared to modern in standard mPWP experiments. We also present the first results illustrating the variability of the ice sheets due to realistic orbital forcing during the mid-Pliocene. While GrIS volumes are lower than modern under even the most extreme (cold) mid-Pliocene orbit (losing at least 35% of its ice mass), the EAIS can both grow and shrink, losing up to 20% or gaining up to 10% of its present-day volume. The changes in ice sheet volume incurred by altering orbital forcing alone means that global sea level can vary by more than 25 m during the mid-Pliocene. However, we have also shown that the response of the ice sheets to mPWP orbital hemispheric forcing can be in anti-phase, whereby the greatest reductions in EAIS volume are concurrent with the smallest reductions of the GrIS. If this anti-phase relationship is in operation throughout the mPWP, then the total eustatic sea level response would be dampened compared to the ice sheet fluctuations that are theoretically possible. This suggests that maximum eustatic sea level rise does not correspond to orbital maxima, but occurs at times where the anti-phasing of Northern and Southern Hemisphere ice sheet retreat is minimised.

Palaeogeography, Palaeoclimatology, Palaeoecology↗

The global Landsat archive: Status, consolidation, and direction

New and previously unimaginable Landsat applications have been fostered by a policy change in 2008 that made analysis-ready Landsat data free and open access. Since 1972, Landsat has been collecting images of the Earth, with the early years of the program constrained by onboard satellite and ground systems, as well as limitations across the range of required computing, networking, and storage capabilities. Rather than robust on-satellite storage for transmission via high bandwidth downlink to a centralized storage and distribution facility as with Landsat-8, a network of receiving stations, one operated by the U.S. government, the other operated by a community of International Cooperators (ICs), were utilized. ICs paid a fee for the right to receive and distribute Landsat data and over time, more Landsat data was held outside the archive of the United State Geological Survey (USGS) than was held inside, much of it unique. Recognizing the critical value of these data, the USGS began a Landsat Global Archive Consolidation (LGAC) initiative in 2010 to bring these data into a single, universally accessible, centralized global archive, housed at the Earth Resources Observation and Science (EROS) Center in Sioux Falls, South Dakota. The primary LGAC goals are to inventory the data held by ICs, acquire the data, and ingest and apply standard ground station processing to generate an L1T analysis-ready product. As of January 1, 2015 there were 5,532,454 images in the USGS archive. LGAC has contributed approximately 3.2 million of those images, more than doubling the original USGS archive holdings. Moreover, an additional 2.3 million images have been identified to date through the LGAC initiative and are in the process of being added to the archive. The impact of LGAC is significant and, in terms of images in the collection, analogous to that of having had two additional Landsat-5 missions. As a result of LGAC, there are regions of the globe that now have markedly improved Landsat data coverage, resulting in an enhanced capacity for mapping, monitoring change, and capturing historic conditions. Although future missions can be planned and implemented, the past cannot be revisited, underscoring the value and enhanced significance of historical Landsat data and the LGAC initiative. The aim of this paper is to report the current status of the global USGS Landsat archive, document the existing and anticipated contributions of LGAC to the archive, and characterize the current acquisitions of Landsat-7 and Landsat-8. Landsat-8 is adding data to the archive at an unprecedented rate as nearly all terrestrial images are now collected. We also offer key lessons learned so far from the LGAC initiative, plus insights regarding other critical elements of the Landsat program looking forward, such as acquisition, continuity, temporal revisit, and the importance of continuing to operationalize the Landsat program.

Remote Sensing of Environment↗

Mixed-chemical exposure and predicted effects potential in wadeable southeastern USA streams

Complex chemical mixtures have been widely reported in larger streams but relatively little work has been done to characterize them and assess their potential effects in headwaterstreams. In 2014, the United States Geological Survey (USGS) sampled 54 Piedmont streams over ten weeks and measured 475 unique organic compounds using five analytical methods. Maximum and median exposure conditions were evaluated in relation to watershed characteristics and for potential biological effects using multiple lines of evidence. Results demonstrate that mixed-contaminant exposures are ubiquitous and varied in sampled headwater streams. Approximately 56% (264) of the 475 compounds were detected at least once across all sites. Cumulative maximum concentrations ranged 1,922–162,346 ng L −1 per site. Chemical occurrence significantly correlated to urban land use but was not related to presence/absence of wastewater treatment facility discharges. Designed bioactive chemicals represent about 2/3rd of chemicals detected, notably pharmaceuticals and pesticides, qualitative evidence for possible adverse biological effects. Comparative Toxicogenomics Database chemical-gene associations applied to maximum exposure conditions indicate >12,000 and 2,900 potential gene targets were predicted at least once across all sites for fish and invertebrates, respectively. Analysis of cumulative exposure-activity ratios provided additional evidence that, at a minimum, transient exposures with high probability of molecular effects to vertebrates were common. Finally, cumulative detections and concentrations correlated inversely with invertebrate metrics from in-stream surveys. The results demonstrate widespread instream exposure to extensive contaminant mixtures and compelling multiple lines of evidence for adverse effects on aquatic communities.

Science of the Total Environment↗

Polyphenyl fluorides

Studies related to the chemistry of aromatic fluorine compounds have been carried out at the Illinois State Geological Survey since 1933. In our reference collection we have several compounds that have not previously been described. This communication records data on 18 biphenyl, three terphenyl and some benzene fluorinated derivatives that were obtained as by-products and/or by specific synthesis. ?? 1973.

Journal of Fluorine Chemistry↗

Rapid implementation of high-frequency wastewater surveillance of SARS-CoV-2

There have been over 507 million cases of COVID-19, the disease caused by the severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2), resulting in 6 million deaths globally. Wastewater surveillance has emerged as a valuable tool in understanding SARS-CoV-2 burden in communities. The National Wastewater Surveillance System (NWSS) partnered with the United States Geological Survey (USGS) to implement a high-frequency sampling program. This report describes basic surveillance and sampling statistics as well as a comparison of SARS-CoV-2 trends between high-frequency sampling 3–5 times per week, referred to as USGS samples, and routine sampling 1–2 times per week, referred to as NWSS samples. USGS samples provided a more nuanced impression of the changes in wastewater trends, which could be important in emergency response situations. Despite the rapid implementation time frame, USGS samples had similar data quality and testing turnaround times as NWSS samples. Ensuring there is a reliable sample collection and testing plan before an emergency arises will aid in the rapid implementation of a high-frequency sampling approach. High-frequency sampling requires a constant flow of information and supplies throughout sample collection, testing, analysis, and data sharing. High-frequency sampling may be a useful approach for increased resolution of disease trends in emergency response.

ES&T: Water↗

River discharge measurements by using helicopter-mounted radar

The United States Geological Survey and the University of Washington collaborated on a series of initial experiments on the Lewis, Toutle, and Cowlitz Rivers during September 2000 and a detailed experiment on the Cowlitz River during May 2001 to determine the feasibility of using helicopter-mounted radar to measure river discharge. Surface velocities were measured using a pulsed Doppler radar, and river depth was measured using ground-penetrating radar. Surface velocities were converted to mean velocities, and horizontal registration of both velocity and depth measurements enabled the calculation of river discharge. The magnitude of the uncertainty in velocity and depth indicate that the method error is in the range of 5 percent. The results of this experiment indicate that helicopter-mounted radar can make the rapid, accurate discharge measurements that are needed in remote locations and during regional floods.

Washington↗

Assessing the validity of station location assumptions made in the calculation of the geomagnetic disturbance index, Dst

In this paper, the effects of the assumptions made in the calculation of the Dst index with regard to longitude sampling, hemisphere bias, and latitude correction are explored. The insights gained from this study will allow operational users to better understand the local implications of the Dst index and will lead to future index formulations that are more physically motivated. We recompute the index using 12 longitudinally spaced low-latitude stations, including the traditional 4 (in Honolulu, Kakioka, San Juan, and Hermanus), and compare it to the standard United States Geological Survey definitive Dst. We look at the hemisphere balance by comparing stations at equal geomagnetic latitudes in the Northern and Southern hemispheres. We further separate the 12-station time series into two hemispheric indices and find that there are measurable differences in the traditional Dst formulation due to the undersampling of the Southern Hemisphere in comparison with the Northern Hemisphere. To analyze the effect of latitude correction, we plot latitudinal variation in a disturbance observed during the year 2005 using two separate longitudinal observatory chains. We separate these by activity level and find that while the traditional cosine form fits the latitudinal distributions well for low levels of activity, at higher levels of disturbance the cosine form does not fit the observed variation. This suggests that the traditional latitude scaling is insufficient during active times. The effect of the Northern Hemisphere bias and the inadequate latitude scaling is such that the standard correction underestimates the true disturbance by 10–30 nT for storms of main phase magnitude deviation greater than 150 nT in the traditional Dst index.

Space Weather↗

Simulating the volatilization of solvents in unsaturated soils during laboratory and field infiltration experiments

This paper describes laboratory and field experiments which were conducted to study the dynamics of trichloroethylene (TCE) as it volatilized from contaminated groundwater and diffused in the presence of infiltrating water through the unsaturated soil zone to the land surface. The field experiments were conducted at the Picatinny Arsenal, which is part of the United States Geological Survey Toxic Substances Hydrology Program. In both laboratory and field settings the gas and water phase concentrations of TCE were not in equilibrium during infiltration. Gas-water mass transfer rate constants were calibrated to the experimental data using a model in which the water phase was treated as two phases: a mobile water phase and an immobile water phase. The mass transfer limitations of a volatile organic compound between the gas and liquid phases were described explicitly in the model. In the laboratory experiment the porous medium was nonsorbing, and water infiltration rates ranged from 0.076 to 0.28 cm h −1 . In the field experiment the water infiltration rate was 0.34 cm h −1 , and sorption onto the soil matrix was significant. The laboratory-calibrated gas-water mass transfer rate constant is 3.3×10 −4 h −1 for an infiltration rate of 0.076 cm h −1 and 1.4×10 −3 h −1 for an infiltration rate of 0.28 cm h −1 . The overall mass transfer rate coefficients, incorporating the contribution of mass transfer between mobile and immobile water phases and the variation of interfacial area with moisture content, range from 3×10 −4 h −1 to 1×10 −2 h −1 . A power law model relates the gas-water mass transfer rate constant to the infiltration rate and the fraction of the water phase which is mobile. It was found that the results from the laboratory experiments could not be extrapolated to the field. In order to simulate the field experiment the very slow desorption of TCE from the soil matrix was incorporated into the mathematical model. When desorption from the soil matrix was added to the model, the calibrated gas-water mass transfer rate constant is 2 orders of magnitude lower than that predicted using the power law model developed for the nonsorbing laboratory soil.

Water Resources Research↗

Toward a comprehensive catalog of global historical seismicity

The United States Geological Survey (USGS) and the Colorado School of Mines (CSM) have initiated a project to locate more accurately all earthquakes recorded by instruments during the period 1900 to 1963. Seismicity for this period (hereafter referred to as historical seismicity, following Lee et al . [1988]) is still poorly understood, even for basic parameters such as earthquake locations (see Figure 1). In some cases this is the result of inherent limitations in the distribution, response characteristics, and timing of the instruments. However, locations for most of the pre-1964 earthquakes are poorly determined simply because modern data analysis techniques have yet to be applied to the available arrival-time observations, which are mainly preserved as printed bulletins and not in a computer-ready digital format. The arduous task of hand-entering these data has prevented the systematic analysis and relocation of historical seismicity.

Eos, Transactions, American Geophysical Union↗

The volcanic history of the San Juan Mountains, Colorado

The San Juan Mountains, which are made up chiefly of volcanic rocks, are located in southwestern Colorado and occupy a rudely circular area of over 10,000 square miles, or larger than the state of Massachusetts. They have been studied and mapped geologically by the United States Geological Survey, chiefly by field parties under Whitman Cross and Esper S. Larsen.

Colorado↗

Notes on the relation between the moisture‐equivalent and the specific retention of water‐bearing materials

The moisture‐equivalent and specific retention have been widely used as quasi‐physical constants to measure the power of a water‐bearing material or a soil to retain water against gravitative force. Comparatively little has been demonstrated, however, as to the relation of one to the other. This paper is a preliminary statement of the apparent relation between these two measures of retentive power and is based on a study of alluvial materials made in connection with an investigation by the United States Geological Survey into the ground‐water resources of the Mokelumne Area, central California.

California↗

Rare chemical constituents of amelia (Virginia) pegmatite dikes, and their mineral sources

Students of Igneous phenomena have long since become familiar with the occurrence of rare minerals in pegmatitic bodies. The great local concentration of rare elements in pegmatite minerals provides a remarkably good opportunity for the Investigation of deep-seated rock constituents, for it is reasonable to suppose that these same elements are widely distributed in minute amounts through the parent rocks to which they are genetically related; but their concentration in pegmatite bodies affords a record of their presence that is lacking in other rocks. The unusual number of rare minerals of the Amelia, Virginia, pegmatites has long attracted attention, and the rare elements of the more abundant minerals which have been investigated in the laboratories of the United States Geological Survey afford an unusual opportunity to study the rare constituents of a pegmatite. This famous locality for rare minerals is situated 38 miles southwest of Richmond, just south of Appomattox River, on the Piedmont plateau.

Eos, Transactions, American Geophysical Union↗

Appendix A—permeability

In the paper entitled “The measurement of the permeability of porous media for homogeneous fluids” by R. D. Wyckoff and others [42] a unit of permeability is proposed which is based on centimeters, seconds, and atmospheres of pressure (76 centimeters of mercury). In 1923, when the Hydrologic Laboratory of the United States Geological Survey was organized, much study was given to the question of a coefficient of permeability, and a coefficient was adopted which is based on feet and gallons a day (U.S. Geol. Survey Water-Supply Paper 596, p. 148). This coefficient has been extensively used and has proved very satisfactory in ground-water work. It has the merit of being readily applicable to field-conditions. It is, moreover, of convenient size, the coefficients of most water-bearing materials being integers of two or three figures, that is, between 10 and 1000. It was adopted in place of Slichter's “transmission-constant” (U.S. Geol. Survey Water-Supply Paper 67, p. 27, 1902), after much careful consideration, largely because the “transmission-constant” of most water-bearing materials is inconvenient in being only a small decimal.

Eos, Transactions, American Geophysical Union↗

Further tests of permeability with low hydraulic gradients

Many of the water‐bearing formations in the United States have hydraulic gradients of much less than 20 feet to the mile, and some may have gradients of less than one foot to the mile, whereas most laboratory‐ tests of permeability are made with much higher gradients . An investigation was therefore undertaken by the writer, under the direction of 0. E. Meinzer, in the Hydrologic Laboratory of the United States Geological Survey, to determine whether Darcy's law is valid for very low hydraulic gradients —that is, whether under such low gradients the rate of flow remains proportional to the gradient . In a previous paper by Meinzer and the writer (Amer. Geophysical Union,15th annual meeting, pp.405–409, 1934), it was shown that for the sand tested the rate of flow varies directly with the hydraulic gradient down to a gradient of about one foot to the mile. More recently six additional tests have been made on this sand with the same apparatus, and these tests give evidence of the validity of Darcy's law for still lower gradients .

Eos, Transactions, American Geophysical Union↗