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At least 757 records · Page 42Linked to original sources
USGS2025

Soil-microbial communities respond less than plant communities to synthetic- or bio-herbicides applied to address the exotic grass-fire cycle in rangelands

The exotic grass-fire cycle is degrading semiarid rangelands, such as the vast areas of shrub-steppe in North America now invaded by fire-promoting cheatgrass. Chemical- or bio-herbicides are sprayed onto soils to inhibit the invaders, but information on chemical- or bio-herbicide impacts to soil microbial communities is limited. We asked how the soil-microbiome responded to the bioherbicide Pseudomonas fluorescens strain ACK55 in comparison to the separate and combined effects of a conventional pre-emergent chemical herbicide, imazapic, in two cheatgrass-invaded sagebrush-steppe sites. First-year microbial responses were evaluated using targeted sequencing of the 16S and LSU rRNA genes for bacteria+archaea and fungi, respectively, and were related to plant-community responses. A strong cheatgrass reduction with imazapic at one site was accompanied by a small shift in bacteria+archaea (16S) community composition with no effect on microbial alpha diversity, and this shift was small in comparison to natural microbiome variation between sites. ACK55 was not detected in soil a year after application, and it caused only transient and marginally significant reductions in annual grass cover accompanied by small reductions in soil fungi species richness. Full-length sequencing of the ACK55 16S rRNA gene and phylogenetic analyses revealed that ACK55 is more likely P. salmonii than P. fluorescens . Knowledge gaps remain on the duration and consequences of microbial-community shifts with imazapic and why molecular analyses showed ACK55 did not persist in soils. Confusion regarding microbial biopesticides can result where isolation, effectiveness testing, commercial release, and regulation are not guided by molecular taxonomic analyses.

Idaho↗
USGS2010

A spectral index for estimating soil salinity in the Yellow River Delta region of China using EO-1 Hyperion data

Soil salinization is one of the most common land degradation processes. In this study, spectral measurements of saline soil samples collected from the Yellow River Delta region of China were conducted in laboratory and hyperspectral data were acquired from an EO-1 Hyperion sensor to quantitatively map soil salinity in the region. A soil salinity spectral index (SSI) was constructed from continuum-removed reflectance (CR-reflectance) at 2 052 and 2 203 nm, to analyze the spectral absorption features of the salt-affected soils. There existed a strong correlation ( r =0.91) between the SSI and soil salt content (SSC). Then, a model for estimation of SSC with SSI was established using univariate regression and validation of the model yielded a root mean square error (RMSE) of 0.986 and an R 2 of 0.873. The model was applied to a Hyperion reflectance image on a pixel-by-pixel basis and the resulting quantitative salinity map was validated successfully with RMSE = 1.921 and R 2 =0.627. These suggested that the satellite hyperspectral data had the potential for predicting SSC in a large area.

Yellow River↗
USGS2004

The geochemical and magnetic record of coal combustion products in West Virginia reservoir sediments and soils

Western West Virginia lies downwind from numerous coal-fired power plants along the Ohio River Valley. To test whether geochemical and mineralogical impacts from these power plants are detectable on the West Virginia landscape, we obtained reservoir cores, soils, and rocks from two separate sites in West Virginia, one in Harrison County (Hinkel and Deegan Reservoirs) and the other in Roane County (Miletree Run Reservoir). Both have small drainage basins that have the effect of maximizing atmospheric inputs relative to weathering inputs. Sediments from Hinkel Reservoir were dated using the 137 Cs method, and by knowledge of the age of the base of the sedimentary section. Major elements in Hinkel Reservoir sediments do not vary systematically over time, suggesting that the depositional history of these sediments has been relatively constant. In contrast, minor elements and sulfur do show dramatic shifts. Zn, Pb, As, S, Cd, Ge, and Hg all peak during the late 1960s and early 1970s. Polyaromatic hydrocarbons associated with combustion processes likewise show this same behavior. Coincident with these maxima is a peak in isothermal remnant magnetization (IRM), a parameter that is proportional to magnetite abundance. We separated the magnetic fraction of the sediments and examined this fraction petrographically. It is dominated by magnetite with a spherical morphology, which is characteristic of magnetite produced by combustion processes. Chemical analyses on local rocks showed that they were not the likely source for the trace element and magnetite enrichments. To compare soils and reservoir sediments, we normalized geochemical data to Ti; the underlying assumption is that Ti will track physical inputs of soil materials into the reservoir sediments. The normalized sediment data for the elements Zn, Pb, As, and S are all higher for sediments deposited during the late 1960s and early 1970s compared to normalized soil data, implying that soils are not the source for the element enrichments. We thus attribute the enrichment to atmospheric inputs. However, a coal-burning zinc smelter within 10 km of the reservoir site that operated until 1971 may have supplied some or all of the anomalous input: There are no nearby major atmospheric pollution sites near Miletree Run Reservoir. A core from this reservoir was dated based on knowledge of the time it was impounded. Like Hinkel Reservoir, there are no systematic shifts in major element contents over its depositional history. Like Hinkel Reservoir, there are also significant shifts in trace elements and IRM that cannot be explained by local soil sources. Magnetic separates from this reservoir are also dominated by spherical combustion-produced magnetite. Covariance over the period 1930-1980 between magnetite and sulfur with US SO 2 production (which comes dominantly from coal combustion) is strongly suggestive of a significant atmospheric input into Miletree Run Reservoir sediments. The nearest upwind power plants are between 50 and 75 km distant. Thus, relatively long distance transmission of particulate matter from the power plants of the Ohio River Valley is likely in this case.

West Virginia↗
USGS2018

Elevated manganese concentrations in United States groundwater, role of land surface–soil–aquifer connections

Chemical data from 43 334 wells were used to examine the role of land surface–soil–aquifer connections in producing elevated manganese concentrations (>300 μg/L) in United States (U.S.) groundwater. Elevated concentrations of manganese and dissolved organic carbon (DOC) in groundwater are associated with shallow, anoxic water tables and soils enriched in organic carbon, suggesting soil-derived DOC supports manganese reduction and mobilization in shallow groundwater. Manganese and DOC concentrations are higher near rivers than farther from rivers, suggesting river-derived DOC also supports manganese mobilization. Anthropogenic nitrogen may also affect manganese concentrations in groundwater. In parts of the northeastern U.S. containing poorly buffered soils, ∼40% of the samples with elevated manganese concentrations have pH values < 6 and elevated concentrations of nitrate relative to samples with pH ≥ 6, suggesting acidic recharge produced by the oxidation of ammonium in fertilizer helps mobilize manganese. An estimated 2.6 million people potentially consume groundwater with elevated manganese concentrations, the highest densities of which occur near rivers and in areas with organic carbon rich soil. Results from this study indicate land surface–soil–aquifer connections play an important role in producing elevated manganese concentrations in groundwater used for human consumption.

Environmental Science & Technology↗
USGS2009

Estimation of the potential for atrazine transport in a silt loam soil

The transport potential of the herbicide atrazine (2-chloro-4-ethyl-6-isopropyl- s -triazine) through a 1-meter-thick root zone of corn ( Zea mays L.) in a silty-loam soil in Kansas was estimated for a 22-year period (1972-93) using the one-dimensional water-flow and solute-transport model LEACHM. Results demonstrate that, for this soil, atrazine transport is directly related to the amount and timing of rain that follows spring applications of atrazine. Two other critical transport factors were important in wet years — [1] variability in atrazine application rate, and [2] atrazine degradation rates below the root zone. Results demonstrate that the coincidence of heavy rain soon after atrazine application can cause herbicide to move below the rooting zone into depths at which biodegradation rates are assumed to be low but are often unknown. Atrazine that reaches below the rooting zone and persists in the underlying soil can subsequently be transported into ground water as soil water drains, typically after the growing season. A frequency analysis of atrazine concentrations in subsurface drainage, combined with field data, demonstrates the relative importance of critical transport factors and confirms a need for definitive estimates of atrazine-degradation rates below the root zone. The analysis indicates that periodic leaching of atrazine can be expected for this soil when rainfall that exceeds 20 cm/mo coincides with atrazine presence in soil.

ACS Symposium Series↗
USGS2004

Development and Application of Pyrolysis Gas Chromatography/Mass Spectrometry for the Analysis of Bound Trinitrotoluene Residues in Soil

TNT (trinitrotoluene) is a contaminant of global environmental significance, yet determining its environmental fate has posed longstanding challenges. To date, only differential extraction-based approaches have been able to determine the presence of covalently bound, reduced forms of TNT in field soils. Here, we employed thermal elution, pyrolysis, and gas chromatography/mass spectrometry (GC/MS) to distinguish between covalently bound and noncovalently bound reduced forms of TNT in soil. Model soil organic matter-based matrixes were used to develop an assay in which noncovalently bound (monomeric) aminodinitrotoluene (ADNT) and diaminonitrotoluene (DANT) were desorbed from the matrix and analyzed at a lower temperature than covalently bound forms of these same compounds. A thermal desorption technique, evolved gas analysis, was initially employed to differentiate between covalently bound and added 15N-labeled monomeric compounds. A refined thermal elution procedure, termed "double-shot analysis" (DSA), allowed a sample to be sequentially analyzed in two phases. In phase 1, all of an added 15N-labeled monomeric contaminant was eluted from the sample at relatively low temperature. In phase 2 during high-temperature pyrolysis, the remaining covalently bound contaminants were detected. DSA analysis of soil from the Louisiana Army Ammunition Plant (LAAP; ???5000 ppm TNT) revealed the presence of DANT, ADNT, and TNT. After scrutinizing the DSA data and comparing them to results from solvent-extracted and base/acid-hydrolyzed LAAP soil, we concluded that the TNT was a noncovalently bound "carryover" from phase 1. Thus, the pyrolysis-GC/MS technique successfully defined covalently bound pools of ADNT and DANT in the field soil sample.

Environmental Science & Technology↗
USGS2005

Assessing the potential for re-emission of mercury deposited in precipitation from arid soils using a stable isotope

A solution containing 198 Hg in the form of HgCl 2 was added to a 4 m 2 area of desert soils in Nevada, and soil Hg fluxes were measured using three dynamic flux chambers. There was an immediate release of 198 Hg after it was applied, and then emissions decreased exponentially. Within the first 6 h after the isotope was added to the soil, ∼12 ng m - 2 of 198 Hg was emitted to the atmosphere, followed by a relatively steady flux of the isotope at 0.2 ± 0.2 ng m - 2 h - 1 for the remainder of the experiment (62 days). Over this time, ∼200 ng m - 2 or 2% of the 198 Hg isotope was emitted from the soil, and we estimate that ∼6% of the isotope would be re-emitted in a year's time. During the experiment, dry deposition of elemental Hg from the atmosphere was measured with an average deposition rate of 0.2 ± 0.1 ng m - 2 h - 1 . Emission of ambient Hg from the soil was observed after soil wetting with the isotope solution and after a storm event. However, the added moisture from the storm event did not affect 198 Hg flux. Results suggest that in this desert environment, where there is limited precipitation, Hg deposited by wet processes is not readily re-emitted and that dry deposition of elemental Hg may be an important process.

Environmental Science & Technology↗
USGS2007

Effects of sorbate speciation on sorption of selected sulfonamides in three loamy soils

Sorption of sulfamethazine (SMN) and sulfathiazole (STZ) was investigated in three soils, a North Carolina loamy sand, an Iowa sandy loam, and a Missouri loam, under various pH conditions. A significant increase in the sorption coefficient ( K D ) was observed in all three soils, as the sulfonamides converted from an anionic form at higher pH to a neutral/cationic form at lower pH. Above pH 7.5, sulfonamides exist primarily in anionic form and have higher aqueous solubility and no cationic character, thereby consequently leading to lower sorption to soils. The effect of speciation on sorption is not the same for all sulfonamides; it is a function of the pH of the soil and the p K a of the sulfonamides. The results indicate that, for the soils under investigation, SMN has comparatively lower K D values than STZ. The pH-dependent sorption of sulfonamides was observed to be consistent in all three soils investigated. The K D values for each speciated form cationic, neutral, and anionic were calculated using an empirical model in which the species-specific sorption coefficients ( K D0 , K D1 , and K D2 ) were weighted with their respective fractions present at any given pH.

Journal of Agricultural and Food Chemistry↗
USGS2002

Carbon isotope fractionation of methyl bromide during agricultural soil fumigations

The isotopic composition of methyl bromide (CH3Br) has been suggested to be a potentially useful tracer for constraining the global CH3Br budget. In order to determine the carbon isotopic composition of CH3Br emitted from the most significant anthropogenic application (pre-plant fumigation) we directly measured the ??13C of CH3Br released during commercial fumigation. We also measured the isotopic fractionation associated with degradation in agricultural soil under typical field fumigation conditions. The isotopic composition of CH3Br collected in soil several hours after injection of the fumigant was -44.5??? and this value increased to -20.7??? over the following three days. The mean kinetic isotope effect (KIE) associated with degradation of CH3Br in agricultural soil (12???) was smaller than the reported value for methylotrophic bacterial strain IMB-1, isolated from previously fumigated agricultural soil, but was similar to methylotrophic bacterial strain CC495, isolated from a pristine forest litter zone. Using this fractionation associated with the degradation of CH3Br in agricultural soil and the mean ??13C of the industrially manufactured CH3Br (-54.4???), we calculate that the agricultural soil fumigation source has a carbon isotope signature that ranges from -52.8??? to -42.0???. Roughly 65% of industrially manufactured CH3Br is used for field fumigations. The remaining 35% is used for structural and post-harvest fumigations with a minor amount used during industrial chemical manufacturing. Assuming that the structural and post-harvest fumigation sources of CH3Br are emitted without substantial fractionation, we calculate that the ??13C of anthropogenically emitted CH3Br ranges from -53.2??? to -47.5???.

Conference Paper↗
USGS2001

Budgets of soil erosion and deposition for sediments and sedimentary organic carbon across the conterminous United States

The fate of soil organic matter during erosion and sedimentation has been difficult to assess because of the large size and complex turnover characteristics of the soil carbon reservoir. It has been assumed that most of the carbon released during erosion is lost to oxidation. Budgets of bulk soil and soil organic carbon erosion and deposition suggest that the primary fates of eroded soil carbon across the conterminous United States are trapping in impoundments and other redeposition. The total amount of soil carbon eroded and redeposited across the United States is ???0.04 Gt yr-1. Applying this revision to the U. S. carbon budget by Houghton et al. [1999] raises their net sequestration estimate by 20-47 %. If comparable rates of erosion and redeposition occur globally, net carbon sequestration would be ???1 Gt yr-1.

Global Biogeochemical Cycles↗
USGS2008

Hydrothermal processes at Gusev Crater: An evaluation of Paso Robles class soils

The Mars Exploration Rover Spirit analyzed multiple occurrences of sulfur-rich, light-toned soils along its traverse within Gusev Crater. These hydrated deposits are not readily apparent in images of undisturbed soil but are present at shallow depths and were exposed by the actions of the rover wheels. Referred to as 'Paso Robles' class soils, they are dominated by ferric iron sulfates, silica, and Mg-sulfates. Ca-sulfates, Ca-phosphates, and other minor phases are also indicated in certain specific samples. The chemical compositions are highly variable over both centimeter-scale distances and between the widely separated exposures, but they clearly reflect the elemental signatures of nearby rocks. The quantity of typical basaltic soil mixed into the light-toned materials prior to excavation by the rover wheels is minimal, suggesting negligible reworking of the deposits after their initial formation. The mineralogy, geochemistry, variability, association with local compositions, and geologic setting of the deposits suggest that Paso Robles class soils likely formed as hydrothermal and famarolic condensates derived from magma degassing and/ or oxidative alteration of crustal iron sulfide deposits. Their occurrence as unconsolidated, near-surface soils permits, though does not require, an age that is significantly younger than that of the surrounding rocks. Copyright 2008 by the American Geophysical Union.

Journal of Geophysical Research E: Planets↗
USGS2020

Recovery of soils from acidic deposition may exacerbate nitrogen export from forested watersheds

Effects of ambient decreases in N deposition on forest N cycling remain unclear as soils recover from acidic deposition. To investigate, repeated soil sampling data were related to deposition, vegetation, and stream data, for 2000–2015 in North and South Buck Creek watersheds, in the Adirondack region of New York, USA. In 63 other Adirondack streams, NO 3 − concentrations were also compared between 2004–2005 and 2014–2015, and a link between soil calcium and stream NO 3 − was investigated using data from 387 Adirondack streams that were sampled in either 2003–2005 or 2010–2011. No trends in N export or NO 3 − concentrations were observed in either Buck watershed despite a 45% decrease in N deposition, although South Buck N export was 2 to 3 times higher than in North Buck, where 48% of deposited N was accounted for by accumulation in the upper soil. In marked contrast, the upper profile in South Buck showed a net loss of N. Increased decomposition appeared likely in South Buck as those soils are adjusted to lower levels of acidifying S deposition, whereas decomposition increases in North Buck were likely suppressed by high levels of natural organic acidity. Stream NO 3 − concentrations in Buck watersheds bracketed regional results and were consistent with the regional streams that showed no overall change in NO 3 − concentrations between 2004 and 2014. A negative correlation observed between NO 3 − concentration and watershed buffering capacity expressed as the ratio of Ca 2+ to SO 4 2− also suggested that stream NO 3 − concentrations were elevated where soil Ca depletion had occurred.

JGR: Biogeosciences↗
USGS2021

Clays are not created equal: How clay mineral type affects soil parameterization

Clay minerals dominate the soil colloidal fraction and its specific surface area. Differences among clay mineral types significantly influence their effects on soil hydrological and mechanical behavior. Presently, the soil clay content is used to parameterize soil hydraulic and mechanical properties (SHMP) for land surface models while disregarding the type of clay mineral. This undifferentiated use of clay leads to inconsistent parameterization, particularly between tropical and temperate soils, as shown herein. We capitalize on recent global maps of clay minerals that exhibit strong climatic and spatial segregation of active and inactive clays to consider spatially resolved clay mineral types in SHMP estimation. Clay mineral-informed pedotransfer functions and machine learning algorithms trained with datasets including different clay types and soil structure formation processes improve SHMP representation regionally with broad implications for hydrological and geomechanical Earth surface processes.

Geophysical Research Letters↗
USGS2025

Exploring the use of non-invasive drone-based Ground Penetrating Radar (GPR) to characterize biogenic gas dynamics in subtropical peat soils

Peat soils are a critical component of the global carbon cycle as natural producers of biogenic greenhouse gases (e.g., methane and carbon dioxide) that accumulate within the soil matrix and are episodically released to the atmosphere. Previous studies have showed the unique ability of ground-based minimally-invasive geophysical methods like ground-penetrating radar (GPR) to characterize carbon dynamics in peat soils. However, the GPR methods are still limited by the scale of measurements and soil disturbance potentially altering biogenic gas releases during deployment. Here we explore the potential of drone-based GPR for identification of hot spots and hot moments of gas accumulation and release in subtropical peat soils. We collected drone-based GPR datasets across two grids (~ 17,500 m2) in the Florida Everglades during January, September, and November of 2023 to characterize peat thickness and seasonal variability of gas content. Results show that drone-based GPR is effective and efficient for: 1) capturing the temporal variation of in-situ biogenic gas content in peat soils with changes between 1-25% volumetric gas content over repeatable grids; 2) inferring peat thickness from discrete measurements ranging between 0.8-1.2 m; and 3) estimating methane flux releases of 63 and 135 mg CH4 m-2 day-1 for specific locations and time periods that are strikingly consistent with our coincident gas trap measurements. This work also indicates that (1) spatial distribution of gas content in the Everglades is strongly controlled by landscape morphology such as ridges and sloughs and (2) the temporal variation of gas content is seasonal with increased gas production during the wet season.

Florida↗
USGS2011

Soil clay content underlies prion infection odds

Environmental factors—especially soil properties—have been suggested as potentially important in the transmission of infectious prion diseases. Because binding to montmorillonite (an aluminosilicate clay mineral) or clay-enriched soils had been shown to enhance experimental prion transmissibility, we hypothesized that prion transmission among mule deer might also be enhanced in ranges with relatively high soil clay content. In this study, we report apparent influences of soil clay content on the odds of prion infection in free-ranging deer. Analysis of data from prion-infected deer herds in northern Colorado, USA, revealed that a 1% increase in the clay-sized particle content in soils within the approximate home range of an individual deer increased its odds of infection by up to 8.9%. Our findings suggest that soil clay content and related environmental properties deserve greater attention in assessing risks of prion disease outbreaks and prospects for their control in both natural and production settings.

Colorado↗
USGS2023

Permafrost microbial communities and functional genes are structured by latitudinal and soil geochemical gradients

Permafrost underlies approximately one quarter of Northern Hemisphere terrestrial surfaces and contains 25–50% of the global soil carbon (C) pool. Permafrost soils and the C stocks within are vulnerable to ongoing and future projected climate warming. The biogeography of microbial communities inhabiting permafrost has not been examined beyond a small number of sites focused on local-scale variation. Permafrost is different from other soils. Perennially frozen conditions in permafrost dictate that microbial communities do not turn over quickly, thus possibly providing strong linkages to past environments. Thus, the factors structuring the composition and function of microbial communities may differ from patterns observed in other terrestrial environments. Here, we analyzed 133 permafrost metagenomes from North America, Europe, and Asia. Permafrost biodiversity and taxonomic distribution varied in relation to pH, latitude and soil depth. The distribution of genes differed by latitude, soil depth, age, and pH. Genes that were the most highly variable across all sites were associated with energy metabolism and C-assimilation. Specifically, methanogenesis, fermentation, nitrate reduction, and replenishment of citric acid cycle intermediates. This suggests that adaptations to energy acquisition and substrate availability are among some of the strongest selective pressures shaping permafrost microbial communities. The spatial variation in metabolic potential has primed communities for specific biogeochemical processes as soils thaw due to climate change, which could cause regional- to global- scale variation in C and nitrogen processing and greenhouse gas emissions.

The ISME Journal↗
USGS2026

Functional restructuring of the global soil microbiome under multiple stressors

Microbes, as the planet’s most abundant and diverse organisms, drive soil functions globally and are vulnerable to environmental stressors triggered by global change. Yet, knowledge regarding the impacts of multiple environmental stressors on their functional profiles as well as the consequences for soil functionality largely remains unknown. Here, we analyze two global-scale datasets including information on soil metagenomics and multiple environmental stressors. We find that across terrestrial ecosystems worldwide, up to 60% of all functional genes significantly shift when soil microbes experience the high-level of concurrent stressors. In this regard, the relative abundances of genes involved in microbial growth are negatively linked to the increasing number of stressors. Conversely, those genes linked to stress resistance and energy production exhibit positive responses. Taken together, our findings highlight a significant restructuring of global soil functional microbiomes in response to multiple environmental stressors. Consequently, such restructuring drives community-level shifts in matter and energy reallocations, thereby impacting the maintenance of soil functionality under the projected global change.

Nature Communications↗
USGS2023

Global dataset of soil organic carbon in tidal marshes

Tidal marshes store large amounts of organic carbon in their soils. Field data quantifying soil organic carbon (SOC) stocks provide an important resource for researchers, natural resource managers, and policy-makers working towards the protection, restoration, and valuation of these ecosystems. We collated a global dataset of tidal marsh soil organic carbon (MarSOC) from 99 studies that includes location, soil depth, site name, dry bulk density, SOC, and/or soil organic matter (SOM). The MarSOC dataset includes 17,454 data points from 2,329 unique locations, and 29 countries. We generated a general transfer function for the conversion of SOM to SOC. Using this data we estimated a median (± median absolute deviation) value of 79.2 ± 38.1 Mg SOC ha −1 in the top 30 cm and 231 ± 134 Mg SOC ha −1 in the top 1 m of tidal marsh soils globally. This data can serve as a basis for future work, and may contribute to incorporation of tidal marsh ecosystems into climate change mitigation and adaptation strategies and policies.

Scientific Data↗