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At least 757 records · Page 42Linked to original sources

Effects of hillslope gully stabilization on erosion and sediment production in the Torreon Wash watershed, New Mexico, 2009–12

Sediment erosion and deposition in two sets of paired (treated and untreated) upland drainages in the Torreon Wash watershed, upper Rio Puerco Basin, New Mexico, were examined over a 3 1/2-year period from spring 2009 through fall 2012. The objective was to evaluate the effectiveness of shallow, loose-stone check dams, or “one-rock dams,” as a hillslope gully erosion stabilization and mitigation method, and its potential for retaining upland eroded soils and decreasing delivery of sediment to lower ephemeral stream channels. Two high-resolution topographic surveys, completed at the beginning and end of the study period, were used to assess the effects of the mitigation measures at paired-drainage sites in both Penistaja Arroyo and Papers Wash watersheds, and at six main-stem-channel cross-section clusters along Penistaja Arroyo and Torreon Wash in the Torreon Wash watershed. For both drainage pairs, the treated drainage had greater sediment aggradation near the channel than the untreated drainage. Erosion was the dominant geomorphic process in the untreated Penistaja Arroyo drainage, whereas aggradation was the dominant process in the other three drainages. For the Penistaja Arroyo paired drainages, the treated site showed a 51-percent increase in area aggraded and 67-percent increase in volume aggraded per area analyzed over the untreated site. Both Papers Wash drainages showed net aggradation, but with similar treatment effect, with the treated site showing a 29-percent increase in area aggraded and 60-percent increase in volume aggraded per area analyzed over the untreated site. In the untreated Penistaja Arroyo drainage, the calculated minimum erosion rate was 0.0055 inches per year (in/yr; 0.14 millimeters per year [mm/yr]), whereas the calculated aggradation rates for the three drainages for which aggradation was the dominant geomorphic process were 0.0063 in/yr (0.16 mm/yr) for the Penistaja Arroyo treated drainage, 0.012 in/yr (0.31 mm/yr) for the Papers Wash untreated drainage, and 0.988 in/yr (2.51 mm/yr) for the Papers Wash treated drainage. Changes in the channel cross section along the main-stem Penistaja Arroyo and Torreon Wash were also examined. Channel-bank slumping and erosion of previously deposited bed material were apparent sources for sediment suspended in ephemeral streamflow. Cross-sectional channel surveys indicated examples of both erosion and deposition along each channel over the study period. Because the drainage area of the treated drainages is small compared to that of the Torreon Wash watershed, the upland mitigation measures would not be expected to measurably affect short-term concentrations of suspended sediment in main-stem channels. One-rock-dam mitigation structures in the upland drainages appear to have resulted in a decrease in sediment delivery to the main-stem channel. One-rock-dam mitigation structures may affect streamflow through their influence on runoff volume (via infiltration) and runoff rate (via detention), both of which may vary with time after structure installation.

New Mexico↗

Palynological assessment of organic tissues and metallic minerals in the Jerritt Canyon gold deposit, Nevada (U.S.A.)

Organic tissues and metallic minerals were studied in acid residues and thin section of the Jerritt Canyon (Bell Mine) gold deposit. The purpose was to compare gold-bearing and gold-free rocks, characterize their differences, and assess a possible relationship between the invisible gold and the organic tissues in these early Paleozoic, carbonaceous limestones, dolomites, and claystones. The most visually abundant acid-resistant component in the sooty, unoxidized, gold-bearing rocks is a black, rectangular, carbon-bearing mineraloid. In X-ray diffraction, it is poorly crystalline; in nuclear magnetic resonance, it is a highly aromatized structure. The increase in gold content that accompanies the increase in content of this protographite suggests that it may be the major gold-bearing compound. Less abundant among the acid-resistant residues are uncarbonized organic tissues that are typical of marine settings. The tissues not in the vicinity of silicified veins are medium to dark brown. The dominant tissues are the amorphous remains of algae and their zooplankton predators. These uncarbonized indigenous tissues indicate that temperatures were lower than those determined by geochemical and fluid inclusion methods. The presence of different kinds of carbon-bearing compounds could account for the discrepancy between the palynological and geochemical data. The uncarbonized organic tissues comprise such a small percentage of these rocks that they could be easily missed by bulk analytical methods. The presence of uncarbonized tissues helps to constrain the duration of the high heat flow that is shown by the fluid inclusion data. The presence of mixed signals suggests that the protographite may be the product of chemical rather than thermal reactions.

Nevada↗

Paleozoic sedimentary rocks in the Red Dog Zn-Pb-Ag district and vicinity, western Brooks Range, Alaska: provenance, deposition, and metallogenic significance

Geochemical analyses of Paleozoic sedimentary rocks in the western Brooks Range reveal a complex evolutionary history for strata surrounding the large Zn-Pb-Ag deposits of the Red Dog district. Data for major elements, trace elements, and rare earth elements (REE) were obtained on 220 samples of unaltered and unmineralized siliciclastic rocks from the Upper Devonian-Lower Mississippian Endicott Group (Hunt Fork Shale, Noatak Sandstone, Kanayut Conglomerate, Kayak Shale), the overlying Carboniferous Lisburne Group (Kuna Formation, unnamed drowned shelf facies), and the Pennsylvanian-Permian Siksikpuk Formation. Major base metal sulfide deposits of the region are present only in the Kuna Formation, which in the Red Dog district comprises siliceous black shale and black chert, minor limestone (calcareous radiolarite), and sparse lithic turbidite and bedded siliceous rock. Gray and rare black shales of the Kayak Shale and common black shales of the Kuna Formation are anomalously low in iron (avg Fe/Ti = 6.25 and 6.34, respectively) relative to other Paleozoic shales in the region (9.58-10.6) and to average shales worldwide (10.1-10.5). In contrast, the bedded siliceous rocks contain appreciable hematite (avg Fe/Ti = 35.0) and high U/Ti and REE/Ti ratios that are interpreted to reflect low amounts of detrital material and a major Fe-rich eolian component. Geochemical data (e.g., MnO <0.01 wt %; avg Cr = 317 ppm), sizes of framboidal pyrite grains, and limited bioturbation suggest anoxic and denitrifying depositional conditions for most black shales of the Kuna Formation; low Mo/Ti ratios argue against euxinic (sulfate-reducing) conditions. Organic-rich black shales of the Kuna Formation with up to 8.4 wt percent C organic and gray to black shales of the Kayak Shale with up to 4.1 wt percent C organic typically have only sparse pyrite (<1 wt % S) and very low iron-limited S/C ratios (mostly <0.2). Immobile element plots (e.g., Th-Zr/10-Sc) suggest that source terranes for all of the formations were dominated by one or more felsic-rich continental arcs; a small proportion of recycled sediments is present locally. A minor mafic igneous component also occurs in several shales of the Kuna and Siksikpuk Formations. High average values for the chemical index of alteration [Al 2 O 3 /(Al 2 O 3 + CaO + Na 2 O + K 2 O)] &infin; 100 for shales of the Endicott Group (76.4-81.5) imply moderate to intense chemical weathering in source areas of these sediments. A lower average for black shales of the Kuna Formation (73.7) does not require such weathering. Textural and geochemical data record the effects of diagenetic and/or hydrothermal fluid flow in some of the Paleozoic rocks. Mobility of P, F, U, and light REE is documented in black shales of the Kuna Formation by phosphate replacements of carbonate clasts and of matrix material surrounding the clasts. A relatively low average Ce/Ce* value of 0.73 for P-poor black shales of the Kuna Formation ( < 0.05 wt % P 2 O 5 ) and a similar Ce/Ce* value of 0.78 for a siderite concretion in Kayak Shale suggest that these diagenetic fluids were oxidizing. Many shales of the Kuna Formation have high (K 2 O &infin; 100)/(K 2 O + Al 2 O 3 ) ratios of 21.0 to 23.0, which contrast with low ratios of generally <18.0 for shales of the underlying Endicott Group. The high ratios in shales of the Kuna Formation reflect preferential reaction of smectite to illite during the Jurassic-Cretaceous Brookian orogeny, owing to high silica activities in pore fluids that were generated by the dissolution of abundant biogenic silica. The distribution and composition of Paleozoic strata in the western Brooks Range may have played a fundamental role in Zn-Pb mineralization of the Red Dog district. In our model, deposition and early lithification of biogenic chert and bedded siliceous rocks in the upper part of the Kuna Formation served as a regional hydrologic seal, acting as a cap rock to heat and hydrothermal fluids during Late Mississippian base-metal mineralization. Equally important was the iron-poor composition of black shales of the Kuna Formation (i.e., low Fe/Ti ratios), which limited synsedimentary pyrite formation in precursor sediments, resulting in significant H 2 S production in pore waters through the interaction of aqueous sulfate with abundant organic matter. This H 2 S may have been critical to the subsurface deposition of the huge quantities of Zn and Pb in the district. On the basis of this model, we propose that low Fe/Ti and S/C ratios in black shale sequences are potential basin-scale exploration guides for giant sediment-hosted, stratiform Zn-Pb-Ag deposits.

Alaska↗

Shallow groundwater quality and geochemistry in the Fayetteville Shale gas-production area, north-central Arkansas, 2011

The Mississippian Fayetteville Shale serves as an unconventional gas reservoir across north-central Arkansas, ranging in thickness from approximately 50 to 550 feet and varying in depth from approximately 1,500 to 6,500 feet below the ground surface. Primary permeability in the Fayetteville Shale is severely limited, and successful extraction of the gas reservoir is the result of advances in horizontal drilling techniques and hydraulic fracturing to enhance and develop secondary fracture porosity and permeability. Drilling and production of gas wells began in 2004, with a steady increase in production thereafter. As of April 2012, approximately 4,000 producing wells had been completed in the Fayetteville Shale. In Van Buren and Faulkner Counties, 127 domestic water wells were sampled and analyzed for major ions and trace metals, with a subset of the samples analyzed for methane and carbon isotopes to describe general water quality and geochemistry and to investigate the potential effects of gas-production activities on shallow groundwater in the study area. Water-quality analyses from this study were compared to historical (pregas development) shallow groundwater quality collected in the gas-production area. An additional comparison was made using analyses from this study of groundwater quality in similar geologic and topographic areas for well sites less than and greater than 2 miles from active gas-production wells. Chloride concentrations for the 127 groundwater samples collected for this study ranged from approximately 1.0 milligram per liter (mg/L) to 70 mg/L, with a median concentration of 3.7 mg/L, as compared to maximum and median concentrations for the historical data of 378 mg/L and 20 mg/L, respectively. Statistical analysis of the data sets revealed statistically larger chloride concentrations (p-value <0.001) in the historical data compared to data collected for this study. Chloride serves as an important indicator parameter based on its conservative transport characteristics and relatively elevated concentrations in production waters associated with gas extraction activities. Major ions and trace metals additionally had lower concentrations in data gathered for this study than in the historical analyses. Additionally, no statistical difference existed between chloride concentrations from water-quality data collected for this study from 94 wells located less than 2 miles from a gas-production well and 33 wells located 2 miles or more from a gas-production well; a Wilcoxon rank-sum test showed a p-value of 0.71. Major ion chemistry was investigated to understand the effects of geochemical and reduction-oxidation (redox) processes on the shallow groundwater in the study area along a continuum of increased rock-water interaction represented by increases in dissolved solids concentration. Groundwater in sandstone formations is represented by a low dissolved solids concentration (less than 30 mg/L) and slightly acidic water type. Shallow shale aquifers were represented by dissolved solids concentrations ranging upward to 686 mg/L, and water types evolving from a dominantly mixed-bicarbonate and calcium-bicarbonate to a strongly sodium-bicarbonate water type. Methane concentration and carbon isotopic composition were analyzed in 51 of the 127 samples collected for this study. Methane occurred above a detection limit of 0.0002 mg/L in 32 of the 51 samples, with concentrations ranging upward to 28.5 mg/L. Seven samples had methane concentrations greater than or equal to 0.5 mg/L. The carbon isotopic composition of these higher concentration samples, including the highest concentration of 28.5 mg/L, shows the methane was likely biogenic in origin with carbon isotope ratio values ranging from -57.6 to -74.7 per mil. Methane concentrations increased with increases in dissolved solids concentrations, indicating more strongly reducing conditions with increasing rock-water interaction in the aquifer. As such, groundwater-quality data collected for this study indicate that groundwater chemistry in the shallow aquifer system in the study area is a result of natural processes, beginning with recharge of dilute atmospheric precipitation and evolution of observed groundwater chemistry through rock-water interaction and redox processes.

Arkansas↗

Water-quality assessment of the Lower Susquehanna River Basin, Pennsylvania and Maryland: sources, characteristics, analysis and limitations of nutrient and suspended-sediment data, 1975-90

This report describes analyses of available information on nutrients and suspended sediment collected in the Lower Susquehanna River Basin during water years 1975-90. Most of the analyses were applied to data collected during water years 1980-89. The report describes the spatial and temporal availability of nutrient and suspended-sediment data and presents a preliminary concept of the spatial and temporal patterns of concentrations and loads within the basin. Where data were available, total and dissolved forms of nitrogen and phosphorus species from precipitation, surface water, ground water, and springwater, and bottom material from streams and reservoirs were evaluated. Suspended-sediment data from streams also were evaluated. The U.S. Geological Survey National Water Information System (NWIS) database was selected as the primary database for the analyses. Precipitation-quality data from the National Atmospheric Deposition Program (NADP) and bottom-material-quality data from the National Uranium Resource Evaluation (NURE) were used to supplement the water-quality data from NWIS. Concentrations of nutrients were available from 3 precipitation sites established for longterm monitoring purposes, 883 wells (854 synoptic areal survey sites and 29 project and research sites), 23 springs (17 synoptic areal survey sites and 6 project and research sites), and 894 bottom-material sites (840 synoptic areal survey sites and 54 project and research sites). Concentrations of nutrients and (or) suspended sediment were available from 128 streams (36 long-term monitoring sites, 51 synoptic areal survey sites, and 41 project and research sites). Concentrations of nutrients and suspended sediment in streams varied temporally and spatially and were related to land use, agricultural practices, and streamflow. A general north-to-south pattern of increasing median nitrate concentrations, from 2 to 5 mg/L, was detected in samples collected in study unit streams. In streams that drain areas dominated by agriculture, concentrations of nutrients and suspended sediment tend to be elevated with respect to those found in areas of other land-use types and are related to the amount of commercial fertilizer and animal manure applied to the area drained by the streams. Animal manure is the dominant source of nitrogen for the streams in the lower, agricultural part of the basin. Concentrations of nutrients in samples from wells varied with season and well depth and were related to hydrogeologic setting. Median concentrations of nitrate were 2.5 and 3.5 mg/L for wells drawing water at depths of 0 to 100 ft and 101 to 200 ft, respectively. The lowest median concentrations for nitrate in ground water from wells were generally found in siliciclastic-bedrock, forested settings of the Ridge and Valley Physiographic Province, and the highest were found in carbonate-bedrock agricultural settings of the Piedmont Physiographic Province. Twenty-five percent of the measurements from wells in carbonate rocks in the Piedmont Physiographic Province exceeded the Pennsylvania drinking-water standard. An estimate of mass balance of nutrient loads within the Lower Susquehanna River Basin was produced by combining the available information on stream loads, atmosphericdeposition loads, commercial-fertilizer applications, animal-manure production, privateseptic-system nonpoint-source loads, and municipal and industrial point-source loads. The percentage of the average annual nitrate load carried in base flow of streams in the study unit ranged from 45 to 76 percent, and the average annual phosphorus load carried in base flow ranged from 20 to 33 percent. Average annual yields of nutrients and suspended sediment from tributary basins are directly related to percentage of drainage area in agriculture and inversely to drainage area. Information required to compute loads of nitrogen and phosphorus were available for all sources except atmospheric deposition, for which only nitrogen data were available. Atmospheric deposition is the dominant source of nitrogen for the mostly forested basins draining the upper half of the study unit. The estimate of total annual nitrogen load to the study unit from precipitation is 98.8 million pounds. Nonpoint and point sources of nutrients were estimated. Nonpoint and point sources combined, including atmospheric deposition, provide a potential annual load of 390 million pounds of nitrogen and 79.5 million pounds of phosphorus. The range of percentages of the estimated nonpoint and point sources that were measured in the stream was 20 to 47 percent for nitrogen and 6 to 14 percent for phosphorus. On the average, the Susquehanna River discharges 141,000 pounds of nitrogen and 7,920 pounds of phosphorus to the Lower Susquehanna River reservoir system each year. About 98 percent of the nitrogen and 60 percent of the phosphorus passes through the reservoir system. Interpretations of available water-quality data and conclusions about the water quality of the Lower Susquehanna River Basin were limited by the scarcity of certain types of water-quality data and current ancillary data. A more complete assessment of the water quality of the basin with respect to nutrients and suspended sediment would be enhanced by the availability of additional data for multiple samples over time from all water environments; samples from streams in the northern and western part of the basin; samples from streams and springs throughout the basin during high base-flow or stormflow conditions; and information on current land-use, and nutrient loading from all types of land-use settings.

Maryland, Pennsylvania↗

Statistical analysis relating well yield to construction practices and siting of wells in the Piedmont and Blue Ridge provinces of North Carolina

A statistical analysis was made of data from more than 6,200 water wells drilled in the fractured crystalline rocks of the Blue Ridge, Piedmont, and western edge of the Coastal Plain where crystalline rocks underlie sediments at shallow depths. The study area encompassed 65 counties in western North Carolina, an area of 30,544 square miles, comprising nearly two-thirds of the State. Additional water supplies will be needed in western North Carolina as population and industrial development continue to increase. Ground water is an attractive alternative to surface water sources for moderate to large supplies. The statistical analysis was made to identify the geologic, topographic, and construction factors associated with high-yield wells. It is generally held that the crystalline rocks of Blue Ridge and Piedmont provinces yield only small amounts of water to wells, that water is obtained from vertical fractures that pinch out at a depth of about 300 feet because of lithostatic pressure, and that the function of a larger diameter well is primarily for storage. These concepts are reasonable when based upon the average well drilled in these rocks: a domestic well, 125 feet deep, 6 inches or less in diameter, and located on a hill or ridge. However, statistical analysis shows that wells in draws or valleys have average yields three times those of wells on hills and ridges. Wells in the most productive hydrogeologic units have average yields twice those of wells in the least productive units. Wells in draws and valleys in the most productive units average five times more yield than wells on hills and ridges in the least productive units. Well diameter can have significant influence on yield; for a given depth, yield is directly proportional to well diameter. Maximum well yields are obtained from much greater depths than previously believed. For example, the average yield of 6-inch diameter wells located in draws and valleys can be expected to reach a maximum of about 45 gallons per minute at depths of 500 to 525 feet; for similarly located 12-inch diameter wells, the average yield can be expected to reach a maximum of about 150 gallons per min at depths of 700 to 800 feet.

North Carolina↗

Evaluation of site-selection criteria, well design, monitoring techniques, and cost analysis for a ground-water supply in Piedmont crystalline rocks, North Carolina

A statistical analysis of data from wells drilled into the crystalline rocks of the Piedmont and Blue Ridge provinces of North Carolina verified and refined previously proposed criteria for the siting of wells to obtain greater than average yields. An opportunity to test the criteria was provided by the expansion of the town of Cary's municipal ground-water system. Three criteria were used: type of rock, thickness of saturated regolith based upon topography, and presence of fractures and joints based upon drainage lineations. A conceptual model of the local hydrogeologic system was developed to guide the selection of the most favorable well sites, and on the basis of the model, six type sites were determined. Eleven of 12 test wells that were located on the basis of type sites yielded from slightly above average to as much as six times the average yield to be expected from particular rock types as reported in the literature. Only one well drilled at a type site had a less than average yield. One well not located at any of the type sites produced little water. Long-term testing and monitoring after the wells were put into production showed that an 18-hour-on, 6-hour-off pumping cycle was much more effective in terms of total production, reduced head loss, and less drawdown than a 5-day-on and 2-day-off cycle. It was also observed that long-term yields by the production wells were about 75 percent of those predicted on the basis of 24-hour pumping tests and only about 60 percent of the driller's reported yields. Cost analysis showed that, by using criteria-selected well sites, a cost-effective well system can be developed that will provide water at an equivalent or lower cost than a surface-water supply. The analysis showed that the system would be cost effective if only one high-yield well were obtained out of every four drilled.

North Carolina↗

Water quality, sediment quality, and stream-channel classification of Rock Creek, Washington, D.C., 1999-2000

Rock Creek Park is within the National Capital Region in Washington, D.C., and is maintained by the National Park Service. Part of Montgomery County, Maryland, and part of the District of Columbia drain into Rock Creek, which is a tributary of the Potomac River. Water quality in Rock Creek is important to biotic life in and near the creek, and in the Potomac River Basin and the Chesapeake Bay. The water quality of the Rock Creek Basin has been affected by continued urban and agricultural growth and development. The U.S. Geological Survey, in cooperation with the National Park Service, investigated water quality and sediment quality in Rock Creek over a 2-year period (1998?2000), and performed a stream-channel classification to determine the distribution of bottom sediment in Rock Creek. This report presents and evaluates water quality and bottom sediment in Rock Creek for water years 1999 (October 1, 1998 to September 30, 1999) and 2000 (October 1, 1999 to September 30, 2000). A synoptic surface-water assessment was conducted at five stations from June 23 to June 25, 1999, a temporal surface-water assessment was conducted at one station from February 18, 1999 to September 26, 2000, and bed-sediment samples were collected and assessed from three stations from August 17 to August 19, 1999. The synoptic surface-water assessment included pesticides (parent compounds and selected transformation products), field parameters, nutrients, and major ions. The temporal surface-water assessment included pesticides (parent compounds and selected transformation products) and field parameters. The bed-sediment assessment included trace elements and organic compounds (including low- and high-molecular weight polycyclic aromatic hydrocarbons, poly-chlorinated biphenyls, pesticides, and phthalates). Some, but not all, of the pesticides known to be used in the area were included in the synoptic water-quality assessment, the temporal water-quality assessment, and the bed-sediment assessment. In addition to the water-quality and sediment-quality assessments, a Rosgen stream-channel classification was performed on a 900-foot-long segment of Rock Creek. In the synoptic water-quality assessment, two pesticides were found to be above published criteria for the protection of aquatic life. In the temporal water-quality assessment, four pesticides were found to be above published criteria for the protection of aquatic life. In the bed-sediment assessment, 8 trace elements, 14 polycyclic aromatic hydrocarbons, 6 pesticides, and 1 phthalate compound were found to be above published criteria for the protection of aquatic life. In the Rosgen classification, a comparison to a previous classification for this segment showed an increase in sands and other fine-grained sediments in the creek bed.

Water-Resources Investigations Report↗

Toward digital geologic map standards: a progress report

Establishing modern scientific and technical standards for geologic maps and their derivative map products is vital to both producers and users of such maps as we move into an age of digital cartography. Application of earth-science data in complex geographic information systems, acceleration of geologic map production, and reduction of population costs require that national standards be developed for digital geologic cartography and computer analysis. Since December 1988, under commission of the Chief Geologic of the U.S. Geological Survey and the mandate of the National Geologic Mapping Program (with added representation from the Association of American State Geologists), a committee has been designing a comprehensive set of scientific map standards. Three primary issues were: (1) selecting scientific symbology and its digital representation; (2) creating an appropriate digital coding system that characterizes geologic features with respect to their physical properties, stratigraphic and structural relations, spatial orientation, and interpreted mode of origin; and (3) developing mechanisms for reporting levels of certainty for descriptive as well as measured properties. Approximately 650 symbols for geoscience maps, including present usage of the U.S Geological Survey, state geological surveys, industry, and academia have been identified and tentatively adopted. A proposed coding system comprises four-character groupings of major and minor codes that can identify all attributes of a geologic feature. Such a coding system allows unique identification of as many as 105 geologic names and values on a given map. The new standard will track closely the latest developments of the Proposed Standard for Digital Cartographic Data soon to be submitted to the National Institute of Standards and Technology by the Federal Interagency Coordinating Committee on Digital Cartography. This standard will adhere generally to the accepted definitions and specifications for spatial data transfer. It will require separate specifications of digital cartographic quality relating to positional accuracy and ranges of measured and interpreted values such as geologic age and rock composition. Provisional digital geologic map standards will be published for trial implementation. After approximately two years, when comments on the proposed standards have been solicited and modifications made, formal adoption of the standards will be recommended. Widespread acceptance of the new standards will depend on their applicability to the broadest range of earth-science map products and their adaptability to changing cartographic technology.

Conference Paper↗

Geochemistry of Selected Coal Samples from Sumatra, Kalimantan, Sulawesi, and Papua, Indonesia

Introduction Indonesia is an archipelago of more than 17,000 islands that stretches astride the equator for about 5,200 km in southeast Asia (figure 1) and includes major Cenozoic volcano-plutonic arcs, active volcanoes, and various related onshore and offshore basins. These magmatic arcs have extensive Cu and Au mineralization that has generated much exploration and mining in the last 50 years. Although Au and Ag have been mined in Indonesia for over 1000 years (van Leeuwen, 1994), it was not until the middle of the nineteenth century that the Dutch explored and developed major Sn and minor Au, Ag, Ni, bauxite, and coal resources. The metallogeny of Indonesia includes Au-rich porphyry Cu, porphyry Mo, skarn Cu-Au, sedimentary-rock hosted Au, epithermal Au, laterite Ni, and diamond deposits. For example, the Grasberg deposit in Papua has the world's largest gold reserves and the third-largest copper reserves (Sillitoe, 1994). Coal mining in Indonesia also has had a long history beginning with the initial production in 1849 in the Mahakam coal field near Pengaron, East Kalimantan; in 1891 in the Ombilin area, Sumatra, (van Leeuwen, 1994); and in South Sumatra in 1919 at the Bukit Asam mine (Soehandojo, 1989). Total production from deposits in Sumatra and Kalimantan, from the 19thth century to World War II, amounted to 40 million metric tons (Mt). After World War II, production declined due to various factors including politics and a boom in the world-wide oil economy. Active exploration and increased mining began again in the 1980's mainly through a change in Indonesian government policy of collaboration with foreign companies and the global oil crises (Prijono, 1989). This recent coal revival (van Leeuwen, 1994) has lead Indonesia to become the largest exporter of thermal (steam) coal and the second largest combined thermal and metallurgical (coking) coal exporter in the world market (Fairhead and others, 2006). The exported coal is desirable as it is low sulfur and ash (generally <1 and < 10 wt.%, respectively). Coal mining for both local use and for export has a very strong future in Indonesia although, at present, there are concerns about the strong need for a major revision in mining laws and foreign investment policies (Wahju, 2004; United States Embassy Jakarta, 2004). The World Coal Quality Inventory (WoCQI) program of the U.S. Geological Survey (Tewalt and others, 2005) is a cooperative project with about 50 countries (out of 70 coal-producing countries world-wide). The WoCQI initiative has collected and published extensive coal quality data from the world's largest coal producers and consumers. The important aspects of the WoCQI program are; (1) samples from active mines are collected, (2) the data have a high degree of internal consistency with a broad array of coal quality parameters, and (3) the data are linked to GIS and available through the world-wide-web. The coal quality parameters include proximate and ultimate analysis, sulfur forms, major-, minor-, and trace-element concentrations and various technological tests. This report contains geochemical data from a selected group of Indonesian coal samples from a range of coal types, localities, and ages collected for the WoCQI program.

Open-File Report↗

Germanium and indium

Germanium and indium are two important elements used in electronics devices, flat-panel display screens, light-emitting diodes, night vision devices, optical fiber, optical lens systems, and solar power arrays. Germanium and indium are treated together in this chapter because they have similar technological uses and because both are recovered as byproducts, mainly from copper and zinc sulfides. The world’s total production of germanium in 2011 was estimated to be 118 metric tons. This total comprised germanium recovered from zinc concentrates, from fly ash residues from coal burning, and from recycled material. Worldwide, primary germanium was recovered in Canada from zinc concentrates shipped from the United States; in China from zinc residues and coal from multiple sources in China and elsewhere; in Finland from zinc concentrates from the Democratic Republic of the Congo; and in Russia from coal. World production of indium metal was estimated to be about 723 metric tons in 2011; more than one-half of the total was produced in China. Other leading producers included Belgium, Canada, Japan, and the Republic of Korea. These five countries accounted for nearly 95 percent of primary indium production. Deposit types that contain significant amounts of germanium include volcanogenic massive sulfide (VMS) deposits, sedimentary exhalative (SEDEX) deposits, Mississippi Valley-type (MVT) lead-zinc deposits (including Irish-type zinc-lead deposits), Kipushi-type zinc-lead-copper replacement bodies in carbonate rocks, and coal deposits. More than one-half of the byproduct indium in the world is produced in southern China from VMS and SEDEX deposits, and much of the remainder is produced from zinc concentrates from MVT deposits. The Laochang deposit in Yunnan Province, China, and the VMS deposits of the Murchison greenstone belt in Limpopo Province, South Africa, provide excellent examples of indium-enriched deposits. The SEDEX deposits at Bainiuchang, China (located in southeastern Yunnan Province), and the Dabaoshan SEDEX deposit (located in the Nanling region of China) contain indium-enriched sphalerite. Another major potential source of indium occurs in the polymetallic tin-tungsten belt in the Eastern Cordillera of the Andes Mountains of Bolivia. Deposits there occur as dense arrays of narrow, elongate, indium-enriched tin oxide-polymetallic sulfide veins in volcanic rocks and porphyry stocks. Information about the behavior of germanium and indium in the environment is limited. In surface weathering environments, germanium and indium may dissolve from host minerals and form complexes with chloride, fluoride, hydroxide, organic matter, phosphate, or sulfate compounds. The tendency for germanium and indium to be dissolved and transported largely depends upon the pH and temperature of the weathering solutions. Because both elements are commonly concentrated in sulfide minerals, they can be expected to be relatively mobile in acid mine drainage where oxidative dissolution of sulfide minerals releases metals and sulfuric acid, resulting in acidic pH values that allow higher concentrations of metals to be dissolved into solution.

Professional Paper↗

Geohydrology of rocks penetrated by test well USW H-4, Yucca Mountain, Nye County, Nevada

Test well USW H-4 is one of several wells drilled in the southwestern part of the Nevada Test Site for hydraulic testing, hydrologic monitoring, and geophysical logging. The work was performed in cooperation with the U.S. Department of Energy. The rocks penetrated by the well to a total depth of 1,219 m were volcanic tuffs of Tertiary age. Hydraulic coefficients calculated from pumping test data indicate that transmissivity ranged from 200 to 790 sq m/day. A radioactive tracer, borehole flow survey indicated that the two most productive zones during this borehole flow survey occurred in the upper part of the Bullfrog Member of the Crater Flat Tuff, depth interval from 721 to 731.5m, and in the underlying part of the Tram Member, depth interval from 864 to 920m. The water is predominantly a sodium biocarbonate type with small concentrations of calcium, magnesium, and sulfate. The apparent age of this composite water sample was determined by carbon-14 date of 17,200 years before present. (USGS)

Water-Resources Investigations Report↗

Tectonic evolution and Cretaceous gold metallogenesis of southwestern Alaska

Cretaceous gold metallogenesis in southwestern Alaska comprises three distinct episodes related to the accretionary evolution of northwestern North America. The oldest mineralizing event is characterized by 112 Ma Cu-Au-Bi-Te porphyry-type(?) veining in the zoned Bonanza and adjacent plutons that intruded rocks of the Nyac terrane. Tectonic reconstructions and limited geological and geochemical data suggest that Cu-Au mineralization in the Nyac district may be related to terminal subduction during accretion of the Togiak-Koyukuk arc. The subsequent 100 to 89 Ma metallogenic event is a product of subduction-related magmatism immediately following accretion of the Peninsular-Alexander-Wrangellia superterrane and includes formation of the giant Pebble porphyry Cu-Au-Mo deposit. Pebble underwent a complex history of highly oxidized magmatism that is isotopically linked to enriched lithosphere or metasomatized mantle sources. Pebble and other porphyryrelated plutons were emplaced as a consequence of changes in plate motion and onset of dextral transpression along the continental margin to the southeast of their present-day locations. The final 75 to 65 Ma metallogenic event is regionally the most extensive. It followed a ~15-m.y.-long magmatic lull and is related to enigmatic subduction-related magmatism in the western part of the Alaska Range and the Kuskokwim basin. This event resulted in the formation of porphyry, reduced pluton-related, orogenic, and possible epithermal Au deposits. In the better-studied relatively low-relief areas of the Kuskokwim basin, many of the mineralized systems are spatially associated with ilmenite-series monzonite to quartz monzonite composite plutons that have isotopic signatures consistent with derivation from crustally contaminated mantle sources. These pluton-hosted Au deposits comprise low-sulfide stockworks, sheeted veins, and/or breccias in the cupolas of moderately differentiated intrusions that contain high Au; anomalous As, Bi, Sb, and/or Te; and have variable, but not uneconomic, Cu concentrations. In addition, Au, Sb, and/or Hg deposits hosted by competent NE-trending granite porphyry dike-sill complexes or along faults in flysch are widespread in the Kuskokwim basin. These deposits, including the giant Donlin Creek Au deposit, formed at shallow crustal levels and are classified here as epizonal orogenic Au deposits and related Hg and Sb lodes. Mesozonal orogenic Au deposits were formed along the margins of the uplifting Willow Creek pluton that is now exposed along the southern side of the Talkeetna Mountains batholith. Recent discoveries in the rugged Alaska Range comprise less well-studied porphyry Au-Cu (Whistler, Island Mountain), epithermal(?) Au (Terra), and reduced pluton-hosted Au deposits (Estelle). The cause of the broad latest Cretaceous magmatism associated with the final metallogenic event is enigmatic, but indicates widespread high heat flow possibly related to flat-slab subduction, lithospheric mantle delamination, or escape tectonics. Plutonism postdated regional folding and coincided with periods of movement along regional faults and formation of the NE-trending structural fabric. Magmatism resulted from initiation of transpressional faulting in more landward positions during oblique subduction of the Kula plate. Crustal contamination of mantle melts, either near their source or during ascent through the thick flysch of the Kuskokwim basin, produced low oxidation state magmas and controlled much of the metallogeny, particularly for those deposits that display similarities to both reduced porphyry Au-Cu deposits and, to a lesser degree, reduced intrusion-related Au systems. High heat flow also induced crustal melting and metamorphic devolatilization to form orogenic Au deposits. A transition to extension at ~60 Ma recorded elsewhere in Alaska temporally corresponds to termination of gold deposit formation in southwestern Alaska. The multiple periods of gold metallogenesis in southwestern Alaska offer a wide variety of targets for exploration within discrete parts of the region.

Society of Economic Geologists Special Publication↗

Tungsten skarn potential of the Yukon-Tanana Upland, eastern Alaska, USA—A mineral resource assessment

Tungsten (W) is used in a variety of industrial and technological applications and has been identified as a critical mineral for the United States, India, the European Union, and other countries. These countries rely on W imports mostly from China, which leaves them vulnerable to supply disruption. Consequently, the U.S. government has a current initiative to understand domestic resource potential. The eastern Alaska portion of the Yukon-Tanana Upland (YTU), is prospective for W skarn deposits, the major source of global W supply. The regional geology consists of juxtaposed Paleozoic lithotectonic packages that were reaccreted to North America in the Mesozoic . Multiple subsequent episodes of arc-related magmatism intruded the lithotectonic packages, accompanied by W skarn formation mostly associated with 100–90 Ma intrusions; major W skarn deposits in Canada are part of the same metallogenic event (e.g., Mactung, Cantung). In this paper, we present an assessment for undiscovered W skarn resources for parts of the lesser-explored western (Alaskan) portion of the YTU. We used GIS proximity analysis to map the intersection of pluton and carbonate-bearing rocks to define three permissive tracts for W skarn deposits. The permissive tracts were qualitatively assessed by mineral potential mapping using region-wide sediment geochemistry and mineral concentrate datasets. This analysis showed that much of the western YTU has high potential for undiscovered W skarn deposits, whereas the eastern and southern YTU had only isolated areas of medium to high potential. Historical production and the quality of the geochemistry data of the western YTU tract (ca. 9200 km 2 ) permitted a quantitative assessment of undiscovered W resources. Probabilistic estimates by a panel of 20 experts predicted a 70% chance of one to three undiscovered W skarn deposits in the western YTU tract. The rationale for favorability employed by the expert panel included favorable lithology, previous production, clustering of previously mined deposits, W placers in the area, lack of recent exploration, pan concentrates containing W minerals, and W geochemical anomalies. Estimates were combined with a global grade and tonnage model for W skarns in a Monte Carlo simulation and provided a median estimate of undiscovered resources of 94 kt WO 3 . If the undiscovered W skarn deposits are located close to infrastructure (e.g., near Fairbanks, or close to roads and/or power grid), application of an economic filter indicates that the median total economically recoverable WO 3 is 63 kt with a net present value (NPV) of $330 million USD (2008 dollars). Whereas if deposits are far from infrastructure, median recoverable WO 3 is only 30 kt and the NPV is $44 million. Our models for contained WO 3 resources and NPV estimates for the western YTU tract are considerably lower than the known resources in skarns in adjacent areas in Canada. Estimates for the western YTU are also lower than preliminary estimates for undiscovered W skarn deposits in areas of the western conterminous United States. We speculate that lower permeability and continuity of favorable carbonate rock horizons in the relatively higher-grade metamorphic country rocks in the Alaska portion of the YTU may explain some of the differences in prospectivity. More detailed geologic mapping, modern geochemistry, and geophysical surveys are needed to refine the resource potential of the whole YTU. Regardless, quantitative mineral resource assessment provides a useful tool for making first-order regional estimates of undiscovered resources, identifying target areas for new data acquisition, and guiding research on the fundamental controls of district-scale metallogenic endowments.

Alaska↗

4D petroleum system model of the Mississippian System in the Anadarko Basin Province, Oklahoma, Kansas, Texas, and Colorado, U.S.A.

The Upper Devonian and Lower Mississippian Woodford Shale is an important petroleum source rock for Mississippian reservoirs in the Anadarko Basin Province of Oklahoma, Kansas, Texas, and Colorado, based on results from a 4D petroleum system model of the basin. The Woodford Shale underlies Mississippian strata over most of the Anadarko Basin portions of Oklahoma and northeastern Texas. The Kansas and Colorado portions of the province are almost entirely thermally immature for oil generation from the Woodford Shale or potential Mississippian source rocks, based mainly on measured vitrinite reflectance and modeled thermal maturation. Thermal maturities of the Woodford Shale range from mature for oil to overmature for gas generation at present-day depths of about 5,000 to 20,000 ft. Oil generation began at burial depths of about 6,000 to 6,500 ft. Modeled onset of Woodford Shale oil generation was about 330 million years ago (Ma); peak oil generation was from 300 to 220 Ma. Mississippian production, including horizontal wells of the informal Mississippi limestone, is concentrated within and north of the Sooner Trend area in the northeast Oklahoma portion of the basin. This large pod of oil and gas production is within the area modeled as thermally mature for oil generation from the Woodford Shale. The southern boundary of the trend approximates the 99% transformation ratio of the Woodford Shale, which marks the end of oil generation. Because most of the Sooner Trend area is thermally mature for oil generation from the Woodford Shale, the trend probably includes short- and longer-distance vertical and lateral migration. The Woodford Shale is absent in the Mocane-Laverne Field area of the eastern Oklahoma panhandle; because of this, associated oil migrated from the south into the field. If the Springer Formation or deeper Mississippian strata generated oil, then the southern field area is within the oil window for associated petroleum source rocks. Mississippian fields along the western boundary of the study area were supplied by oil that flowed northward from the Panhandle Field area and westward from the deep basin.

Colorado, Kansas, New Mexico, Oklahoma, Texas↗

Recent trends in the nonfuel minerals industry of Iran

Summary In response to the recent removal of international sanctions on Iran, including the lifting of &ldquo;secondary&rdquo; sanctions by the United States on investment into and trade with Iran, the U.S. Geological Survey National Minerals Information Center compiled and analyzed available information on the current state of Iran&rsquo;s nonfuel minerals industry. This Circular features a new map and table that identify existing mines and mineral-processing facilities and provide information on location, ownership, and capacity for metals and industrial minerals whose output levels may substantially change in the near future. Additionally, the report covers Iran&rsquo;s mineral resources and reserves, official mineral production targets for 2025, and current output and share of global mineral production. Recent trends and developments in individual mineral commodities are discussed, including mineral exploration and partnerships with foreign investors. The U.S. Geological Survey estimated that Iran held globally significant reserves of feldspar (2d largest in the world), barite (5th largest), gypsum (5th largest), fluorspar (8th largest), and iron ore (10th largest). The Government of Iran claimed to also have significant reserves of chromium, copper, gold, manganese, phosphate rock, and zinc. In 2014, Iran was the second-leading producer of gypsum and the sixth-leading producer of barite, with 6.1 percent and 3.6 percent of world output, respectively. Iran was also the world&rsquo;s 7th-leading producer of cement, feldspar, and fluorspar; 8th-leading producer of bentonite; 9th-leading producer of molybdenum; 11th-leading producer of iron ore; and 14th-leading producer of crude steel. The Government of Iran plans to quadruple the output of aluminum, copper cathode, direct-reduced iron, and iron ore pellets; triple that of crude steel and gold; and double that of cement, pig iron, and zinc by 2025. It also plans to double the contribution of mining and to quadruple that of mineral processing to the national economy in the next decade. In order to achieve these major goals, the construction and expansion of several mines and mineral facilities are planned or under development. Whether Iran&rsquo;s annual mineral production increases as rapidly as envisioned by the Government will depend largely on the amount of foreign investment into the minerals industry; integration of modern technology into mineral facilities; and availability of energy to aluminum, copper, and steel plants at competitive prices to international investors.

Circular↗

Genetic and grade and tonnage models for sandstone-hosted roll-type uranium deposits, Texas Coastal Plain, USA

The coincidence of a number of geologic and climatic factors combined to create conditions favorable for the development of mineable concentrations of uranium hosted by Eocene through Pliocene sandstones in the Texas Coastal Plain. Here 254 uranium occurrences, including 169 deposits, 73 prospects, 6 showings and 4 anomalies, have been identified. About 80 million pounds of U 3 O 8 have been produced and about 60 million pounds of identified producible U 3 O 8 remain in place. The development of economic roll-type uranium deposits requires a source, large-scale transport of uranium in groundwater, and deposition in reducing zones within a sedimentary sequence. The weight of the evidence supports a source from thick sequences of volcanic ash and volcaniclastic sediment derived mostly from the Trans-Pecos volcanic field and Sierra Madre Occidental that lie west of the region. The thickest accumulations of source material were deposited and preserved south and west of the San Marcos arch in the Catahoula Formation. By the early Oligocene, a formerly uniformly subtropical climate along the Gulf Coast transitioned to a zoned climate in which the southwestern portion of Texas Coastal Plain was dry, and the eastern portion humid. The more arid climate in the southwestern area supported weathering of volcanic ash source rocks during pedogenesis and early diagenesis, concentration of uranium in groundwater and movement through host sediments. During the middle Tertiary Era, abundant clastic sediments were deposited in thick sequences by bed-load dominated fluvial systems in long-lived channel complexes that provided transmissive conduits favoring transport of uranium-rich groundwater. Groundwater transported uranium through permeable sandstones that were hydrologically connected with source rocks, commonly across formation boundaries driven by isostatic loading and eustatic sea level changes. Uranium roll fronts formed as a result of the interaction of uranium-rich groundwater with either (1) organic-rich debris adjacent to large long-lived fluvial channels and barrier–bar sequences or (2) extrinsic reductants entrained in formation water or discrete gas that migrated into host units via faults and along the flanks of salt domes and shale diapirs. The southwestern portion of the region, the Rio Grande embayment, contains all the necessary factors required for roll-type uranium deposits. However, the eastern portion of the region, the Houston embayment, is challenged by a humid environment and a lack of source rock and transmissive units, which may combine to preclude the deposition of economic deposits. A grade and tonnage model for the Texas Coastal Plain shows that the Texas deposits represent a lower tonnage subset of roll-type deposits that occur around the world, and required aggregation of production centers into deposits based on geologic interpretation for the purpose of conducting a quantitative mineral resource assessment.

Texas↗

Kulshan caldera: A quaternary subglacial caldera in the North Cascades, Washington

Calderas that collapse during large pyroclastic eruptions are anomalously rare in the Cascade arc. Recognition of the early Pleistocene 4.5 × 8 km Kulshan caldera, filled with rhyodacite ignimbrite at the northeast foot of Mount Baker, brings to only three the Quaternary calderas identified in the Cascades. A near-vertical ring fault cut in basement rocks of the North Cascades encloses 30 km 2 of intracaldera ignimbrite (and intermixed collapse breccia) >1 km thick but with no floor exposed. The Lake Tapps tephra in the Puget lowland is the correlative fallout; 200 km from the source, it is as thick as 30 cm. Features of the distal ash fall and the intracaldera tuff suggest large-scale phreatomagmatism during an eruption that may have started subglacially. Several advances of the Cordilleran ice sheet subsequently obliterated the topographic rim, removed every vestige of extracaldera ignimbrite and proximal fallout, and stripped any precaldera extrusive rocks-the former existence of which is suggested only by a few silicic intrusions that cut the circumcaldera basement. Although the caldera is not structurally resurgent, several early intracaldera rhyodacite lavas intrude and rest directly on ignimbrite or on ashy caldera-lake sediments reworked from the eruption products. Subsidence areas, pumice compositions, and volumes of magma erupted (>50 km 3 ) are similar for the Kulshan, Rockland, and Crater Lake (Mazama) events, the three Quaternary caldera-forming eruptions now recognized in the Cascades.

Geological Society of America Bulletin↗