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Field techniques for fluorescence measurements targeting dissolved organic matter, hydrocarbons, and wastewater in environmental waters: Principles and guidelines for instrument selection, operation and maintenance, quality assurance, and data reporting

The use of field deployable fluorescence sensors by the U.S. Geological Survey has become increasingly common for a wide variety of surface water and groundwater investigations. This report addresses field deployable fluorometers that measure the fluorescence response of various substances in water exposed to incident light generated by the sensor. An introduction to the basic principles of field measurements of fluorescence is provided, as well as technical background information on sensors that target dissolved organic matter, wastewater, and hydrocarbons, including sensor selection, operating principles, key features, and design elements. General deployment, operation and maintenance protocols, quality-assurance techniques, and suggestions for data reporting are presented to facilitate and standardize the collection and accurate communication of data collected by the U.S. Geological Survey across studies, sites, and sensor types. Sensor performance issues and common interferences are also described. An appendix is included to describe sensor calibration criteria and procedures, reporting units, and specific approaches to correct for interferences for fluorescence of dissolved organic matter sensors.

Techniques and Methods↗

Ground-water age dating and other tools used to assess land-use effects on water quality

A relatively new method for age dating recent ground water along with other investigative tools improve our understanding of land-use effects on the water quality in a surficial aquifer and adjacent streams in the Red River of the North Basin: Ground water commonly takes more than 20 years to reach depths in the surficial aquifer where it is withdrawn for use. Water withdrawn from most drinking-water wells was recharged through land areas greater than 1 mile upgradient. Because of these long travel times and distances, land-management practices on the land and aquifer-protection strategies may take as much as 50 years to produce measurable improvement in water quality. The amount of fertilizer and some herbicides used to enhance crop growth in this study area can be related to the distribution and trends of nitrate and herbicides found in the surficial aquifer.

Red River of the North Basin↗

Movements of water, solutes, and stable isotopes in the unsaturated zones of two sand plains in the upper Midwest

Four month-long field experiments investigated movements of water and solutes through unsaturated sand plains near Princeton, Minnesota, and Oakes, North Dakota. Atrazine and bromide were applied to bare soils and soils planted with corn. The field plots were irrigated according to local farming practices. At the end of each experiment, unsaturated soils were analyzed for atrazine and bromide concentrations and oxygen and hydrogen isotope compositions of soil water. Most soil water was affected by evaporation but groundwater beneath the plots had no evaporative isotopic signature. Therefore most recharge consisted of water that was unaffected by evaporation. Sources of such water may have included snowmelt, prolonged or high-intensity rainfalls that were not interrupted by periods of drying, and water that moved through preferential flow paths. Preferential flow also was suggested by the detection of atrazine, deethylatrazine, and bromide in groundwater shortly after each application of irrigation water at Princeton and by isolated concentrations of atrazine and bromide in soil well below the main masses of chemicals at Oakes.

Minnesota, North Dakota↗

Hydrogeology and water quality of the Leetown area, West Virginia

The U.S. Geological Survey’s Leetown Science Center and the co-located U.S. Department of Agriculture’s National Center for Cool and Cold Water Aquaculture both depend on large volumes of cold clean ground water to support research operations at their facilities. Currently, ground-water demands are provided by three springs and two standby production wells used to augment supplies during periods of low spring flow. Future expansion of research operations at the Leetown Science Center is dependent on assessing the availability and quality of water to the facilities and in locating prospective sites for additional wells to augment existing water supplies. The hydrogeology of the Leetown area, West Virginia, is a structurally complex karst aquifer. Although the aquifer is a karst system, it is not typical of most highly cavernous karst systems, but is dominated by broad areas of fractured rock drained by a relatively small number of solution conduits. Characterization of the aquifer by use of fluorometric tracer tests, a common approach in most karst terranes, therefore only partly defines the hydrogeologic setting of the area. In order to fully assess the hydrogeology and water quality in the vicinity of Leetown, a multi-disciplinary approach that included both fractured rock and karst research components was needed. The U.S. Geological Survey developed this multi-disciplinary research effort to include geologic, hydrologic, geophysical, geographic, water-quality, and microbiological investigations in order to fully characterize the hydrogeology and water quality of the Leetown area, West Virginia. Detailed geologic and karst mapping provided the framework on which hydrologic investigations were based. Fracture trace and lineament analysis helped locate potential water-bearing fractures and guided installation of monitoring wells. Monitoring wells were drilled for borehole geophysical surveys, water-quality sampling, water-level measurements, and aquifer tests to characterize the quality of water and the hydraulic properties of the aquifer. Surface geophysical surveys provided a 3-dimensional view of bedrock resistivity in order to assess geologic and lithologic controls on ground-water flow. Borehole geophysical surveys were conducted in monitoring wells to assess the storage and movement of water in subsurface fractures. Numerous single-well, multi-well, and straddle packer aquifer tests and step-drawdown tests were conducted to define the hydraulic properties of the aquifer and to assess the role of bedrock fractures and solution conduits in the flow of ground water. Water samples collected from wells and springs were analyzed to assess the current quality of ground water and provide a baseline for future assessment. Microbiological sampling of wells for indicator bacteria and human and animal DNA provided an analysis of agricultural and suburban development impacts on ground-water quality. Light detection and ranging (LiDAR) data were analyzed to develop digital elevation models (DEMs) for assessing sinkhole distribution, to provide elevation data for development of a ground-water flow model, and to assess the distribution of major fractures and faults in the Leetown area. The flow of ground water in the study area is controlled by lithology and geologic structure. Bedrock, especially low permeability units such as the shale Martinsburg Formation and the Conococheague Limestone, act as barriers to water flowing down gradient and across bedding. This retardation of cross-strike flow is especially pronounced in the Leetown area, where bedding typically dips at steep angles. Highly permeable fault and fracture zones that disrupt the rocks in cross-strike directions provide avenues through which ground water can flow laterally across or through strata of low primary permeability. Significant strike parallel thrust faults and cross-strike faults typically coincide with larger solution conduits and act as drains for the more pervasive network of interconnected diffuse fractures. Results of borehole geophysical surveys indicate that although numerous fractures may intersect a borehole, only one or two of the fractures typically transmit most of the water to a well. The diffuse-flow dominated network of fractures that provides the majority of storage occupies only a small proportion of the total aquifer volume but constitutes the majority of porosity within the aquifer. Solution conduits, while occupying a relatively small volume of the overall aquifer, are especially important because they serve as primary drains for the ground-water flow system. Surface resistivity maps and cross-sectionsshow anomalous areas of low resistivities coincident with the prevailing geologic strike at N. 20º E., with major cross-strike faults, and with major springs in the region. Transmissivity derived from straddle packer tests was highly variable, and ranged over three orders of magnitude (1.8 x 10 -6 to 5.9 x 10 -3 ft 2 /d) in diffuse-flow fractures. A similar large variability in transmissivity was documented by single- and multi-well aquifer tests conducted in conduit-flow dominated portions of the aquifer (2.0 x 10 3 to 1.4 x 10 4 ft 2 /d) in lowland areas immediately adjacent to the Leetown Science Center. A stream-gaging station installed on Hopewell Run near the point where the stream exits the Leetown watershed indicates average daily streamflow for the Hopewell Run of approximately 11.2 ft 3 /s, and ranged from a minimum of 1.80 ft 3 /s on September 28, 2005, to a maximum of 73.0 ft 3 /s on December 11, 2003. Base-flow (ground-water) discharge surveys identified numerous small seeps adjacent to streams in the area. Hydrographs of the stage of Balch Spring show rapid response to individual storms. Strong correlation of the flow of Hopewell Run and Balch Spring indicates the nearby losing stream reach is partly responsible for higher fluctuations in the stage of Balch Spring. A water budget for the study period (2003-2005), based on measured precipitation and hydrograph analyses, is expressed as Precipitation (38.60 in/yr) = Surface Runoff (1.36 in/yr) + Ground-Water Discharge (17.73 in/yr) + Evapotranspiration (24.23 in/yr) – Change in storage (4.72 in/yr). Flow of ground water through the epikarst, a shallow zone of intensely weathered rock and regolith, can be rapid (on the order of days or weeks) as flow is concentrated in solution conduits. Flow within the intermediate and deeper zones is typically much slower. Eight dye-tracer tests conducted in the Leetown area found ground-water flow patterns to be divergent, with velocities ranging from about 12.5 to 610 ft/day and a median velocity of 50 ft/day. Estimates of ground-water age in carbonate rocks in the region are on the order of 15 years in the shallower portions of the aquifer to 50 years or older for deeper portions of the aquifer. Shallow springs can have a significant component of fairly young water (< 5 years in age). Ground-water samples collected from 16 sites (12 wells and 4 springs) in the Leetown area were analyzed for more than 340 constituents. Only turbidity, indicator bacteria, and radon were typically present in concentrations exceeding U.S. Environmental Protection Agency (USEPA) drinking-water or aquatic life standards.

West Virginia↗

Sea water in coastal aquifers

Investigations in the coastal part of the Biscayne aquifer, a highly productive aquifer of limestone and sand in the Miami area, Florida, show that the salt-water front is dynamically stable as much as 8 miles seaward of the position computed according to the Ghyben-Herzberg principle. This discrepancy results, at least in part, from the fact that the salt water in the Biscayne aquifer is not static, as explanations of the dynamic balance commonly assume. Cross sections showing lines of equal fresh-water potential indicate that during periods of heavy recharge, the fresh-water head is high enough to cause the fresh water, the salt water, and the zone of diffusion between them to move seaward. When the fresh-water head is low, salt water in the lower part of the aquifer intrudes inland, but some of the diluted sea water in the zone of diffusion continues to flow seaward. Thus, salt water circulates inland from the floor of the sea through the lower part of the aquifer becoming progressively diluted with fresh water to a line along which there is no horizontal component of flow, after which it moves upward and returns to the sea. This cyclic flow is demonstrated by a flow net which is constructed by the use of horizontal gradients determined from the low-head equipotential diagram. The flow net shows that about seven-eights of the total discharge at the shoreline originates as fresh water in inland parts of the aquifer. The remaining one-eighth represents a return of sea water entering the aquifer through the floor of the sea.

Water Supply Paper↗

Relationships between water quality, stream metabolism, and water stargrass growth in the lower Yakima River, 2018 to 2020

Since the early 2000s, water clarity on the lower Yakima River has improved. Changes in best management practices combined with a total maximum daily load for suspended sediment led to these improved conditions. As water clarity improved, so did conditions for aquatic plants; the clearer the water, the better the light penetration, and dramatic increases in plant biomass were observed. In the lower Yakima River, beds of native water stargrass (grass-leaf mud-plantain, Heteranthera dubia) are prolific and can extend bank to bank in some locations. Increased primary productivity can alter local water quality by increasing daily swings of dissolved oxygen (DO) and pH from photosynthesis. In this study, we collected continuous water quality data for 2.5 years at three sites on the lower Yakima River to provide a detailed examination of water quality conditions. These sites were located just below the Prosser Dam (Prosser site, USGS station 12509489), at a long-term USGS streamgage in Benton County (Kiona site, USGS station 12510500), and in West Richland, WA (Van Giesen site; USGS station 12511800). In addition to the continuous water quality data collected, estimates of water stargrass biomass were made through the growing season (June through September) during water years 2018–2020. The main objectives of this study were to document water quality conditions on the lower Yakima River and to analyze if there was a statistical relation between the amount of water stargrass biomass and the observed daily cycles of water quality. During summer, frequent exceedances of established water quality criteria were documented each year during this study. Maximum daily temperatures exceeded 21o C, minimum DO concentrations were below 8 milligrams per liter (mg/L), and maximum pH surpassed 8.5 almost every day from June through August each water year across all three monitoring locations. Water stargrass biomass tended to increase from June through August and September but was ‘reset’ by the following summer likely from high winter and spring streamflows and natural die-off. Results from this study suggest that spring peak discharge and average spring discharge affects late-season water stargrass biomass. In 2018, the highest peak discharge of the study took place, and the August water stargrass biomass values were lower in 2018 than in 2019 and 2020. Seven different water quality metrics were computed for a 7-day and 28-day period prior to each water stargrass sample to examine possible correlations between the plant biomass and water quality. We examined daily maximum temperature, DO minimum, DO range, pH maximum, pH range, mean nitrate, and nitrate range. While there were some statistically significant correlations among the seven water quality metrics and median water stargrass biomass, the correlations were not consistent across all three sites. At the Prosser site, the 7-day average daily maximum pH and average daily pH range showed significant correlations with median water stargrass biomass. At the Kiona site, both the 7-day and 28-day mean nitrate values showed a significant relationship to median water stargrass biomass. At the Van Giesen site, there were no significant correlations between the seven water quality metrics and median water stargrass biomass. However, whole-stream estimates of gross primary productivity at the Kiona site, which incorporate the entire river community, were related to temperature, DO, and pH indicating the whole river community is influencing surface water quality to some extent. Additional data on water stargrass biomass and continuous water quality could help elucidate the complex interactions between growth and water quality. At a minimum, collection of water stargrass biomass data near the end of the growing season (mid to late August) could be added to locations where continuous water quality and streamflow discharge measurements are also being collected. In addition, experimental removal of water stargrass and its effects on local water quality could provide insight into the complex relationships between water stargrass growth and water quality. Finally, further investigations into streamflow and its effects on water stargrass could be improved. Our data showed a qualitative relationship between spring peak discharge, average spring discharge, and August water stargrass biomass, but more data are needed to confirm this. If spring high streamflows are important for late-season biomass, then targeted flow releases from reservoirs in the upper watershed could be used to slow down water stargrass growth during summer months.

EarthArXiv↗

Delineation of ground-water contamination using soil-gas analyses near Jackson, Tennessee

An investigation of the ground-water resources near Jackson, West Tennessee, was conducted during 1988-89. The study included determination of the occurrence of contaminants in the shallow aquifer using soil-gas analyses in the unsaturated zone. Between 1980 and 1988, an underground fuel-storage tank leaked about 3,000 gallons of unleaded fuel to the water table about 4 feet below land surface. A survey of soil gas using a gas chromatograph equipped with a photoionization detector showed concentrations of volatile organic compounds greater than IO, 000 parts per million near the leak These compounds were detected in an area about 240 feet long and 110 feet wide extending west from the point source. The chromatograms provided two distinct 'fingerprints' of volatile organic compounds. The first revealed the presence of benzene, toluene, andxylenes, which are constituents of unleaded fuel, in addition to other volatile compounds, in soil gas in the area near the leak The second did not reveal any detectable benzene, toluene, or xylenes in the soil-gas samples, but showed the presence of other unidentified volatile organic compounds in soil gas north of the storage tank. The distribution of total concentrations of volatile organic compounds in the unsaturated zone indicated that a second plume about 200 feet long and 90 feet wide was present about 100 feet north of the storage tank The second plume could have been the result of previous activities at this site during the 1950's or earlier. Activities at the site are believed to have included storage of solvents used at the nearby railyard and flushing of tanks containing tar onto a gravel-covered parking area. The delineation of these plumes has shown that soil-gas analyses can be a useful technique for identifying areas of contamination with volatile organic compounds in shallow water-table aquifers and may have broad applications in similar situations where the water table is relatively close to the surface.

Tennessee↗

Water-quality assessment of the Cook Inlet Basin, Alaska — Summary of data through 1997

Among the first activities undertaken in each National Water-Quality Assessment (NAWQA) investigation are the compilation, screening, and statistical summary of available data concerning water-quality conditions in the study unit. The water-quality conditions of interest are those that are representative of the general ambient water quality of a given stream reach or area of an aquifer. This report identifies which existing water-quality data are suitable for characterizing general conditions in a nationally consistent manner and describes, to the extent possible, general water-quality conditions in the Cook Inlet Basin in southcentral Alaska. The study unit consists of all lands that drain into Cook Inlet, but not the marine environment itself. Surface-water-quality data are summarized for 31 sites on streams. Ground-water quality data are summarized for four regions using analyses from about 550 wells that yield water from unconsolidated glacial and alluvial deposits and analyses from 17 wells in western Cook Inlet, some of which may yield water from coal or weakly consolidated sandstone or conglomerate. The summaries focus on the central tendencies and typical variations in the data and use nonparametric statistics such as frequencies and percentile values. Few surface- and ground-water sites have long-term water-quality records and very few data are available for dissolved oxygen, nutrients, metals, trace elements, organic compounds, and radionuclides. In general, most waters in streams and wells have small concentrations of major inorganic constituents, nutrients, trace elements, and organic compounds. Most streams have water that is generally suitable for drinking-water supply, the growth and propagation of cold-water anadromous fish, and water-contact recreation. However, suspended-sediment concentrations in glacier-fed streams are naturally high and can make water from glacier-fed streams unsuitable for many uses unless the water is treated to remove the suspended sediment. Several streams and lakes in Anchorage have fecal coliform bacteria concentrations higher than allowed for drinking or water-contact recreation. Ground water in the major withdrawal regions is generally suitable for drinking and most other purposes, but some wells yield water having nitrate, iron, or arsenic concentrations higher than drinking-water criteria. Ground-water quality has been degraded in several areas as the result of leaks or spills of petroleum products.

Alaska↗

Transport of ARS-labeled hydroxyapatite nanoparticles in saturated granular media is influenced by surface charge variability even in the presence of humic acid

Hydroxyapatite nanoparticle (nHAP) is increasingly being used to remediate soils and water polluted by metals and radionuclides. The transport and retention of Alizarin red S (ARS)-labeled nHAP were investigated in water-saturated granular media. Experiments were carried out over a range of ionic strength ( I c , 0–50 mM NaCl) conditions in the presence of 10 mg L −1 humic acid. The transport of ARS-nHAP was found to decrease with increasing suspension I c in part, because of enhanced aggregation and chemical heterogeneity. The retention profiles (RPs) of ARS-nHAP exhibited hyperexponential shapes (a decreasing rate of retention with increasing transport distance) for all test conditions, suggesting that some of the attachment was occurring under unfavorable conditions. Surface charge heterogeneities on the collector surfaces and especially within the ARS-nHAP population were contributing causes for the hyperexponential RPs. Consideration of the effect(s) of I c in the presence of HA is needed to improve the efficacy of nHAP for scavenging metals and actinides in real soils and groundwater environments.

Journal of Hazardous Materials↗

Assessment of ecosystem response to a temporary water level drawdown and subsequent refilling at Topock Marsh, Arizona—July 2011–October 2014

Topock Marsh is a 1,637-hectare (4,045-acre) wetland adjacent to the Colorado River near Needles, California, and a main feature of Havasu National Wildlife Refuge (NWR). The U.S. Fish and Wildlife Service, in cooperation with the Bureau of Reclamation, began construction of an infrastructure improvement project in 2010 to increase the efficiency of water use and to help protect the habitats and species found within the Havasu NWR. During construction, normal water delivery from the Colorado River into Topock Marsh through the Inlet Canal was restricted, which resulted in unusually low water elevations in 2011. The U.S. Geological Survey, commissioned by the U.S. Fish and Wildlife Service, undertook the investigation of the water quality and aquatic flora and fauna during the low water conditions. Subsequently, water elevations in the marsh returned to more normal elevations after the new concrete-lined Fire Break Canal became fully operational in January 2012. The U.S. Geological Survey made 11 field trips to the Havasu NWR between July 2011 and October 2014 to assess the effects of the temporary low water conditions and the change of inflow location (from the Inlet Canal to the Fire Break Canal) on water quality and aquatic habitat. The following conditions were monitored: water quality, sediment and plant chemistry, phytoplankton, zooplankton, aquatic macro-invertebrates, and emergent and submerged aquatic vegetation (SAV). Water-quality and biota data collected during 2013–14 were then compared with data collected during the 2011–12 low water period. Once the new Fire Break Canal became operational and Colorado River water flowed regularly into the marsh, concentrations of several water quality parameters decreased (for example, specific conductance, total dissolved solids, turbidity, chlorophyll a , and total and organic nitrogen), and phytoplankton abundance was reduced at the upstream sampling stations (TP-3, TP-2, and TP-6); the water flow pushed water with higher concentrations of these components downstream (measured at TP-8). The upstream sampling locations in 2013–14 had decreased turbidity, therefore more SAV biomass accumulated, especially in shallow areas with water depths of ≤1.0 meter (≤3.3 feet). However, the furthest downstream station had higher turbidity caused by both the suspension of autochthonous sediment and high phytoplankton density and biovolume. This higher turbidity resulted in minimal SAV growth, especially in the deeper water (>1.0 meter [>3.3 feet]). Emergent vegetation not only survived the low water conditions of 2011, but expanded its areal coverage and subsequently thrived in the higher water elevations. Overall, no immediate critically negative consequences were detected for aquatic fauna or flora that could be attributd unequivocally to the effect of low water levels. Concentrations of nutrient and trace elements in all water samples were below wildlife toxicity thresholds as established by Arizona Department of Environmental Quality. Three nonnative species were discovered shortly after the Fire Break Canal went into operation. Of the three, gizzard shad ( Dorosoma cepedianum ) and Eurasian watermilfoil ( Myriophyllum spicatum ) increased substantially in numbers from 2011–14, but quagga mussels ( Dreissena bugensis ) did not increase. Future monitoring will determine the long-term impact of the new flow regime

Arizona↗

Hydrologic Influences on Water Levels at Three Oaks Recreation Area, Crystal Lake, Illinois, April 14 through September 27, 2016

Hydrologic influences on water levels were investigated at Three Oaks Recreation Area (TORA), a former sand-and-gravel quarry converted into recreational lakes in Crystal Lake, Illinois. From 2009 to 2015, average water levels in the lakes declined nearly 4 feet. It was not clear if these declines were related to variations in weather (precipitation or evaporation) or other hydrologic influences such as municipal supply pumping or nearby quarry operations. Data were collected using three approaches to determine the possibility of such hydrologic influences. First, water levels were collected at 15 minute intervals at three wells equipped with pressure transducers from April 14 through September 27, 2016. The continuous data allowed assessment of lake and well water level responses to precipitation, pumping influences, and quarry operations. Second, a single-day synoptic water-level survey was completed to create a water table map to determine groundwater flow directions. Third, single-well aquifer tests (slug tests) were completed on the three data-collection wells to estimate the aquifer’s horizontal hydraulic conductivity. Collectively, these data were used to determine the velocity and volume of water entering and exiting TORA.

Illinois↗

Assessing ecosystem effects of reservoir operations using food web-energy transfer and water quality models

We investigated the effects on the reservoir food web of a new temperature control device (TCD) on the dam at Shasta Lake, California. We followed a linked modeling approach that used a specialized reservoir water quality model to forecast operation-induced changes in phytoplankton production. A food web–energy transfer model was also applied to propagate predicted changes in phytoplankton up through the food web to the predators and sport fishes of interest. The food web–energy transfer model employed a 10% trophic transfer efficiency through a food web that was mapped using carbon and nitrogen stable isotope analysis. Stable isotope analysis provided an efficient and comprehensive means of estimating the structure of the reservoir's food web with minimal sampling and background data. We used an optimization procedure to estimate the diet proportions of all food web components simultaneously from their isotopic signatures. Some consumers were estimated to be much more sensitive than others to perturbations to phytoplankton supply. The linked modeling approach demonstrated that interdisciplinary efforts enhance the value of information obtained from studies of managed ecosystems. The approach exploited the strengths of engineering and ecological modeling methods to address concerns that neither of the models could have addressed alone: (a) the water quality model could not have addressed quantitatively the possible impacts to fish, and (b) the food web model could not have examined how phytoplankton availability might change due to reservoir operations.

Ecosystems↗

Pathogenic human viruses in coastal waters

This review addresses both historical and recent investigations into viral contamination of marine waters. With the relatively recent emergence of molecular biology-based assays, a number of investigations have shown that pathogenic viruses are prevalent in marine waters being impacted by sewage. Research has shown that this group of fecal-oral viral pathogens (enteroviruses, hepatitis A viruses, Norwalk viruses, reoviruses, adenoviruses, rotaviruses, etc.) can cause a broad range of asymptomatic to severe gastrointestinal, respiratory, and eye, nose, ear, and skin infections in people exposed through recreational use of the water. The viruses and the nucleic acid signature survive for an extended period in the marine environment. One of the primary concerns of public health officials is the relationship between the presence of pathogens and the recreational risk to human health in polluted marine environments. While a number of studies have attempted to address this issue, the relationship is still poorly understood. A contributing factor to our lack of progress in the field has been the lack of sensitive methods to detect the broad range of both bacterial and viral pathogens. The application of new and advanced molecular methods will continue to contribute to our current state of knowledge in this emerging and

Clinical Microbiology Reviews↗

Magnitude, frequency, and trends of floods at gaged and ungaged sites in Washington, based on data through water year 2014

An investigation into the magnitude and frequency of floods in Washington State computed the annual exceedance probability (AEP) statistics for 648 U.S. Geological Survey unregulated streamgages in and near the borders of Washington using the recorded annual peak flows through water year 2014. This is an updated report from a previous report published in 1998 that used annual peak flows through the water year 1996. New in this report, a regional skew coefficient was developed for the Pacific Northwest region that includes areas in Oregon, Washington, Idaho and western Montana within the Columbia River drainage basin south of the United States-Canada border, the coastal areas of Oregon and western Washington, and watersheds draining into Puget Sound, Washington. The skew coefficient is an important term in the Log Pearson Type III equation used to define the distribution of the log-transformed annual peaks. The Expected Moments Algorithm was used to fit historical and censored peak-flow data to the log Pearson Type III distribution. A Multiple Grubb-Beck test was employed to censor low outliers of annual peak flows to improve on the frequency distribution. This investigation also includes a section on observed trends in annual peak flows that showed significant trends ( p -value < 0.05) in 21 of 83 long-term sites, but with small magnitude Kendall tau values suggesting a limited monotonic trend in the time series of annual peaks. Most of the sites with a significant trend in western Washington were positive and all the sites with significant trends (three sites) in eastern Washington were negative. Multivariate regression analysis with measured basin characteristics and the AEP statistics at long-term, unregulated, and un-urbanized (defined as drainage basins with less than 5 percent impervious land cover for this investigation) streamgages within Washington and some in Idaho and Oregon that are near the Washington border was used to develop equations to estimate AEP statistics at ungaged basins. Washington was divided into four regions to improve the accuracy of the regression equations; a set of equations for eight selected AEPs and for each region were constructed. Selected AEP statistics included the annual peak flows that equaled or exceeded 50, 20, 10, 4, 2, 1, 0.5 and 0.2 percent of the time equivalent to peak flows for peaks with a 2-, 5-, 10-, 25-, 50-, 100-, 200-, and 500-year recurrence intervals, respectively. Annual precipitation and drainage area were the significant basin characteristics in the regression equations for all four regression regions in Washington and forest cover was significant for the two regression regions in eastern Washington. Average standard error of prediction for the regional regression equations ranged from 70.19 to 125.72 percent for Regression Regions 1 and 2 on the eastern side of the Cascade Mountains and from 43.22 to 58.04 percent for Regression Regions 3 and 4 on the western side of the Cascade Mountains. The pseudo coefficient of determination (where a value of 100 signifies a perfect regression model) ranged from 68.39 to 90.68 for Regression Regions 1 and 2, and 92.35 to 95.44 for Regions 3 and 4. The calculated AEP statistics for the streamgages and the regional regression equations are expected to be incorporated into StreamStats after the publication of this report. StreamStats is the interactive Web-based map tool created by the U.S. Geological Survey to allow the user to choose a streamgage and obtain published statistics or choose ungaged locations where the program automatically applies the regional regression equations and computes the estimates of the AEP statistics.

Washington↗

Simulation of the effects of hypothetical residential development on water levels in Graber Pond, Middleton, Wisconsin

An investigation of the effects of hypothetical residential development in the Graber Pond watershed was done by the U.S. Geological Survey in cooperation with the city of Middleton. The investigation entailed evaluation of the existing (1989) water budget and water-level conditions for the pond and the water-level conditions expected to result from the hypothetical development that may occur by the year 2000. A water-budget model was calibrated to closely match water levels observed from July 18-August 31, 1989. Water input to the pond during this period was computed to be about 2.58 feet. Of this, about 25 percent (0.65 foot) was from direct rainfall on the pond surface, about 19 percent (0.50 foot) was from storm runoff, and about 55 percent (1.43 feet) was discharge from a nearby manufacturing plant. Simulation of the hypothetical development conditions in the watershed predicts that the average late-summer pond level may rise about 0.7 foot.

Wisconsin↗

Selected ground-water data for Yucca Mountain region, southern Nevada and eastern California, through December 1992

Tne U.S. Geological Survey. in support of the U.S. Department of Energy, Yucca Mountain Site- Characterization Project, collects, compiles, and summarizes water-resource data in the Yucca Mountain region. The data are collected to document the historical and current condition of ground-water resources, to detect and document changes in those resources through time, and to allow assessments of ground-water resources during investigations to determine the potential suitability of Yucca Mountain for storing high-level nuclear waste. Data on ground-water levels at 36 sites, ground- water discharge at 6 sites, ground-water quality at 19 sites, and ground-water withdrawals within Crater Fiat, Jackass Flats, Mercury Valley, and the Amargosa Desert are presented. Data on ground-water levels, discharges, and withdrawals collected by other agencies or as part of other programs are included to further indicate variations through time. A statistical summary of ground-water levels and median annual ground-water withdrawals in Jackass Flats is presented. The statistical summary includes the number of measurements, the maximum, minimum, and median water-level altitudes, and the average deviation of a11 water-level altitudes for selected baseline periods and for calendar year 1992. Data on ground-water quality are compared to established, proposed, or tentative primary and secondary drinking-water standards, and measures which exceeded those standards are listed for 18 sites. Detected organic compounds for which established, proposed, or tentative drinking-water standards exist also are listed.

California, Nevada↗