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At least 739 records · Page 41Linked to original sources

USGS2008

Trends in snowpack chemistry and comparison to National Atmospheric Deposition Program results for the Rocky Mountains, US, 1993-2004

Seasonal snowpack chemistry data from the Rocky Mountain region of the US was examined to identify long-term trends in concentration and chemical deposition in snow and in snow-water equivalent. For the period 1993-2004, comparisons of trends were made between 54 Rocky Mountain Snowpack sites and 16 National Atmospheric Deposition Program wetfall sites located nearby in the region. The region was divided into three subregions: Northern, Central, and Southern. A non-parametric correlation method known as the Regional Kendall Test was used. This technique collectively computed the slope, direction, and probability of trend for several sites at once in each of the Northern, Central, and Southern Rockies subregions. Seasonal Kendall tests were used to evaluate trends at individual sites. Significant trends occurred during the period in wetfall and snowpack concentrations and deposition, and in precipitation. For the comparison, trends in concentrations of ammonium, nitrate, and sulfate for the two networks were in fair agreement. In several cases, increases in ammonium and nitrate concentrations, and decreases in sulfate concentrations for both wetfall and snowpack were consistent in the three subregions. However, deposition patterns between wetfall and snowpack more often were opposite, particularly for ammonium and nitrate. Decreases in ammonium and nitrate deposition in wetfall in the central and southern rockies subregions mostly were moderately significant (p<0.11) in constrast to highly significant increases in snowpack (p<0.02). These opposite trends likely are explained by different rates of declining precipitation during the recent drought (1999-2004) and increasing concentration. Furthermore, dry deposition was an important factor in total deposition of nitrogen in the region. Sulfate deposition decreased with moderate to high significance in all three subregions in both wetfall and snowpack. Precipitation trends consistently were downward and significant for wetfall, snowpack, and snow-telemetry data for the central and southern rockies subregions (p<0.03), while no trends were noted for the Northern Rockies subregion.

Atmospheric Environment↗

USGS2006

Comparison of breeding bird and vegetation communities in primary and secondary forests of Great Smoky Mountains National Park

We compared breeding bird communities and vegetation characteristics at paired point locations in primary (undisturbed) and mature secondary forest (70-100 years old) sites in Great Smoky Mountains National Park, USA to understand how sites logged prior to creation of the park compare to undisturbed sites following 70 years of protection from human disturbance. We found that bird and vegetation communities are currently similar, but retain some differences in species composition. Rank abundance curves for primary and secondary forest bird communities showed very similar patterns of species dominance. Species composition was also similar on the two sites which shared 24 of the 25 most frequently recorded species. Nonetheless, comparisons of density estimates derived from distance sampling showed three bird species were more abundant on primary forest sites and that one bird species was significantly more abundant on secondary forest sites. Notably, comparisons based on raw counts (unadjusted for potential differences in detectability) produced somewhat different results. Analyses of vegetation samples for the paired sites also showed relative similarity, but with some differences between primary and secondary forests. Primary forest sites had more large trees (trees greater than 50 cm diameter at breast height) and late successional species. Primary forest sites had a denser tall shrub layer while secondary forest sites had a denser canopy layer. Nonetheless, tree species richness, basal area of live trees and number of standing snags did not differ between primary and secondary forest sites. Results indicate that breeding bird communities on sites within the park that were logged commercially 70 years ago are currently quite similar to bird communities on sites with no history of human disturbance. Similarities between the bird communities on previously disturbed and undisturbed sites in Great Smoky Mountains National Park may exceed those on more fragmented landscapes because large patches of primary forest, adjacent to commercially logged sites, remained in the park when it was established in 1935. These patches of primary forest may have served as source areas for commercially logged sites.

North Carolina, Tennessee↗

USGS2015

Trends in Rocky Mountain amphibians and the role of beaver as a keystone species

Despite prevalent awareness of global amphibian declines, there is still little information on trends for many widespread species. To inform land managers of trends on protected landscapes and identify potential conservation strategies, we collected occurrence data for five wetland-breeding amphibian species in four national parks in the U.S. Rocky Mountains during 2002–2011. We used explicit dynamics models to estimate variation in annual occupancy, extinction, and colonization of wetlands according to summer drought and several biophysical characteristics (e.g., wetland size, elevation), including the influence of North American beaver ( Castor canadensis ). We found more declines in occupancy than increases, especially in Yellowstone and Grand Teton national parks (NP), where three of four species declined since 2002. However, most species in Rocky Mountain NP were too rare to include in our analysis, which likely reflects significant historical declines. Although beaver were uncommon, their creation or modification of wetlands was associated with higher colonization rates for 4 of 5 amphibian species, producing a 34% increase in occupancy in beaver-influenced wetlands compared to wetlands without beaver influence. Also, colonization rates and occupancy of boreal toads ( Anaxyrus boreas ) and Columbia spotted frogs ( Rana luteiventris ) were ⩾2 times higher in beaver-influenced wetlands. These strong relationships suggest management for beaver that fosters amphibian recovery could counter declines in some areas. Our data reinforce reports of widespread declines of formerly and currently common species, even in areas assumed to be protected from most forms of human disturbance, and demonstrate the close ecological association between beaver and wetland-dependent species.

Biological Conservation↗

USGS2008

The effect of acid rain and altitude on concentration, δ34S, and δ18O of sulfate in the water from Sudety Mountains, Poland

The analyses of sulfate content, δ 34 S and δ 18 O of dissolved sulfate, and δ 18 O of water were carried out in a 14 km 2 crystalline massif located in the Sudety Mountains (SW Poland) to 1) assess the amount of the sulfate delivered to the surface and groundwater systems by modern atmospheric precipitation, 2) determine the effect of altitude on these parameters, and 3) investigate their seasonal variations. In April and November of 2002, August 2003, and March and September of 2005, samples of water were collected from springs and streams of the massif. During these seasons, sulfate contents and δ 18 O(SO 4 2− ) values varied from 5.80 to 18.00 mg/l and from 3.96 to 8.23&permil;, respectively, showing distinctively higher values of δ 18 O(SO 4 2− ) in wet seasons. The δ 34 S(SO 4 2− ) values had a relatively narrow range from 4.09 to 5.28&permil; and were similar to those reported for organic matter in soil and the canopy throughfall in the Sudety Mountains. Sulfate content, δ 34 S(SO 4 2− ), δ 18 O(SO 4 2− ), and δ 18 O(H 2 O) values revealed a remarkable dependence on the altitude. The calculated altitude effects for five season averages of these parameters were − 1.00 mg/l/100 m, − 0.18&permil;/100 m, − 0.27&permil;/100 m, and − 0.17&permil;/100 m, respectively. This dependence on the altitude resulted mainly from the mixing of sulfates of different origins such as anthropogenic sulfate, sulfate produced in the soil within the weathered zone of the massif, and that one from the tree canopy. The oxygen isotope mass balance indicates that, in the study area, about one third of the sulfate delivered to the surface and groundwater by modern precipitation comes from anthropogenic pollution. Further interaction of meteoric water within the weathered rocks causes a continuous decrease of δ 18 O(SO 4 2− ) values resulting from biological transformation of the sulfate due to plant vegetation and decomposition of organic matter.

Sudety Mountains↗

USGS2010

Phosphorus and iron cycling in deep saprolite, Luquillo Mountains, Puerto Rico

Rapid weathering and erosion rates in mountainous tropical watersheds lead to highly variable soil and saprolite thicknesses which in turn impact nutrient fluxes and biological populations. In the Luquillo Mountains of Puerto Rico, a 5-m thick saprolite contains high microorganism densities at the surface and at depth overlying bedrock. We test the hypotheses that the organisms at depth are limited by the availability of two nutrients, P and Fe. Many tropical soils are P-limited, rather than N-limited, and dissolution of apatite is the dominant source of P. We document patterns of apatite weathering and of bioavailable Fe derived from the weathering of primary minerals hornblende and biotite in cores augered to 7.5 m on a ridgetop as compared to spheroidally weathering bedrock sampled in a nearby roadcut. Iron isotopic compositions of 0.5 N HCl extracts of soil and saprolite range from about δ 56 Fe = 0 to − 0.1‰ throughout the saprolite except at the surface and at 5 m depth where δ 56 Fe = − 0.26 to − 0.64‰. The enrichment of light isotopes in HCl-extractable Fe in the soil and at the saprolite–bedrock interface is consistent with active Fe cycling and consistent with the locations of high cell densities and Fe(II)-oxidizing bacteria, identified previously. To evaluate the potential P-limitation of Fe-cycling bacteria in the profile, solid-state concentrations of P were measured as a function of depth in the soil, saprolite, and weathering bedrock. Weathering apatite crystals were examined in thin sections and an apatite dissolution rate of 6.8 × 10 − 14 mol m − 2 s − 1 was calculated. While surface communities depend on recycled nutrients and atmospheric inputs, deep communities survive primarily on nutrients released by the weathering bedrock and thus are tightly coupled to processes related to saprolite formation including mineral weathering. While low available P may limit microbial activity within the middle saprolite, fluxes of P from apatite weathering should be sufficient to support robust growth of microorganisms in the deep saprolite.

Puerto Rico↗

USGS2019

Resilience of benthic macroinvertebrates to extreme floods in a Catskill Mountain river, New York, USA: Implications for water quality monitoring and assessment

Changes in the timing, magnitude, frequency, and duration of extreme hydrologic events are becoming apparent and could disrupt species assemblages and stream ecosystems across the Northeastern United States. Between August 28 and 29 of 2011, an average of 31 cm of rain from Tropical Storm Irene fell across Eastern New York State in less than 24 h and caused historic flooding in numerous streams of the Catskill Mountain Region. Peak discharges exceeded the 0.01 annual exceedance probability (> 100 year flood) in many Catskill Mountain streams. Approximately one week later, the remnants of Tropical Storm Lee deposited another 19 cm of rain onto saturated soils and caused additional flooding. Data from annual benthic macroinvertebrate surveys completed at 5 sites in the Upper Esopus Creek, a premier trout stream in the region, during August 2009–2011 (before the floods) were compared to data collected from the same sites in September 2011, November 2011, March 2012 and August 2012 (after the floods). The impact, rate of recovery and the factors which might affect the resilience of benthic macroinvertebrate communities were evaluated. The results of biological water quality assessment metrics immediately after the floods resembled those of highly polluted waters, yet severe floods were the only disturbance. Prior to the floods, standard biological assessment metrics showed that communities were not impacted and water quality was pristine. A large decrease in macroinvertebrate density was evident in the September 2011 surveys following the floods and bioassessment metrics reflected highly degraded water quality conditions. Most community metrics rebounded in 3–7 months (November 2011 and March 2012), and full recovery was evident in 12 months (August 2012) which suggests that macroinvertebrate assemblages are relatively resilient to the effects of extreme floods in these low-order streams. Therefore, macroinvertebrate samples collected from a flood-impacted stream before full recovery occurs might reflect loss of diversity and abundance from the flood disturbance and incorrectly attribute the impact to impaired water quality. The strong short-term impacts and the relatively rapid recovery of macroinvertebrate communities following catastrophic floods have important ramifications for routine bioassessment programs considering changing hydrologic regimes in streams across the Northeast and elsewhere.

New York↗

USGS2017

Analyzing land-use change scenarios for trade-offs among culturalecosystem services in the Southern Rocky Mountains

Significant increases in outdoor recreation participants are projected over the next 50 years for national forests across the United States, with even larger increases possible for forests located in the Southern Rocky Mountains. Forest managers will be challenged to balance increasing demand for outdoor recreation with other ecosystem services. Future management needs could be better anticipated with information describing how and where stakeholders value these forests’ cultural ecosystem services, as well as how management might impact these values. We analyzed land-use change scenarios to quantify changes in aesthetic and recreational ecosystem service values and assessed trade-offs between these values relative to forest stakeholder groups defined by their attitudes regarding motorized recreation. We adapted the GIS tool, Social Values for Ecosystem Services (SolVES), for scenario analysis and applied it to two national forests in the Southern Rocky Mountains to examine impacts of road-network expansion on stakeholder values. Our approach allowed us to quantify changes in the spatial distribution and intensity of aesthetic and recreation values. Trade-off assessments between the two values indicated that areas of conflicting value changes were limited, even when accounting for different user groups. However, this approach could be an important means of conflict resolution for multi-use management.

Colorado, Utah, Wyoming↗

USGS2021

Assessing specific-capacity data and short-term aquifer testing to estimate hydraulic properties in alluvial aquifers of the Rocky Mountains, Colorado, USA

Study Region : Rocky Mountains, United States Study Focus : Groundwater-flow modeling requires estimates of hydraulic properties, namely hydraulic conductivity. Hydraulic conductivity values commonly vary over orders of magnitudes however and estimation may require extensive field campaigns applying slug or pumping tests. As an alternative, specific-capacity tests can be used to estimate hydraulic properties for large areas when benchmarked with slug or pumping tests. This study combined aquifer testing with specific capacity data to estimate hydraulic properties in a large alluvial aquifer. New hydrological insights for region : In the Wet Mountain Valley, Colorado, both slug tests and pumping tests were conducted, resulting in a likely range of hydraulic-conductivity values. Aquifer-testing results were related to specific-capacity data, a more spatially distributed dataset, to expand the area of aquifer characterization beyond the distribution of wells included in aquifer testing. Specific-capacity data were used in two ways: (1) a regression was built between specific-capacity values and transmissivity derived from aquifer testing; and (2) an iterative method was utilized to estimate transmissivity from specific capacity at all sites (including sites lacking aquifer tests). Study results indicate that there is a statistically significant difference between hydraulic-conductivity values estimated using the two approaches and that the regression method yields systematically greater values. These results indicate that careful consideration of methods that use specific capacity for extrapolating aquifer properties is warranted as bias could be introduced depending on the applied methodology.

Colorado↗

USGS2017

The response of soil and stream chemistry to decreases in acid deposition in the Catskill Mountains, New York, USA

The Catskill Mountains have been adversely impacted by decades of acid deposition, however, since the early 1990s, levels have decreased sharply as a result of decreases in emissions of sulfur dioxide and nitrogen oxides. This study examines trends in acid deposition, stream-water chemistry, and soil chemistry in the southeastern Catskill Mountains. We measured significant reductions in acid deposition and improvement in stream-water quality in 5 streams included in this study from 1992 to 2014. The largest, most significant trends were for sulfate (SO 4 2− ) concentrations (mean trend of −2.5 μeq L −1 yr −1 ); hydrogen ion (H + ) and inorganic monomeric aluminum (Al im ) also decreased significantly (mean trends of −0.3 μeq L −1 yr −1 for H + and −0.1 μeq L −1 yr −1 for Al im for the 3 most acidic sites). Acid neutralizing capacity (ANC) increased by a mean of 0.65 μeq L −1 yr −1 for all 5 sites, which was 4 fold less than the decrease in SO 4 2− concentrations. These upward trends in ANC were limited by coincident decreases in base cations (−1.3 μeq L −1 yr −1 for calcium + magnesium). No significant trends were detected in stream-water nitrate (NO 3 − ) concentrations despite significant decreasing trends in NO 3 − wet deposition. We measured no recovery in soil chemistry which we attributed to an initially low soil buffering capacity that has been further depleted by decades of acid deposition. Tightly coupled decreasing trends in stream-water silicon (Si) (−0.2 μeq L −1 yr −1 ) and base cations suggest a decrease in the soil mineral weathering rate. We hypothesize that a decrease in the ionic strength of soil water and shallow groundwater may be the principal driver of this apparent decrease in the weathering rate. A decreasing weathering rate would help to explain the slow recovery of stream pH and ANC as well as that of soil base cations.

New York↗

USGS2006

Temporal variations in slip rate of the White Mountain Fault Zone, Eastern California

The evolution of fault slip through time may yield insight into the geodynamics of deforming lithosphere. Precise determination of temporal variations in fault slip is often hindered, however, by a dearth of markers of varying age from which to reconstruct fault slip. Here we determine slip rates across the White Mountain Fault Zone over the past ca. 0.8??Ma from displaced alluvial deposits preserved along the flank of the White Mountains. Displacement histories inferred from deposits containing the ??? 760??ka Bishop Tuff contrast strongly with those inferred from Late Pleistocene alluvial fans dated by cosmogenic 36Cl, indicating that the fault has experienced significant temporal variations in slip rate. Oblique-slip rates over the past ??? 760??ky are determined to have been > 0.9??m/ky parallel to a net slip vector plunging shallowly (< 20??) toward 340??-350??. Displacement of markers in Late Pleistocene alluvial deposits, in contrast, yield slip rates between 0.3 and 0.4??m/ky parallel to a vector plunging somewhat more steeply (20??-40??) toward 320??-340??. These variations in slip rate appear to have operated over timescales > ca. 70??ky, yet occurred on a well-established fault system. Moreover, the timing and magnitude of slip rate variation mimics behavior documented for the northern Fish Lake Valley fault zone. Together, our data provide evidence for coordinated slip rate variations across the Eastern California Shear Zone during the Pleistocene. ?? 2006 Elsevier B.V. All rights reserved.

Earth and Planetary Science Letters↗

USGS2019

Whitebark pine (Pinus albicaulis) growth and defense in response to mountain pine beetle outbreaks

Whitebark pine (Pinus albicaulis) is a critical forest species of Northern Rocky Mountain upper subalpine ecosystems, yet little is known about the physiological response of whitebark pine to disturbance (e.g. fire, bark beetles, and pathogens) across a range of diverse environmental gradients. Resin–based defenses have long been recognized as the primary mechanism by which conifers respond to attack by bark beetles and pathogens and several studies have linked resin duct properties to survivorship during periods of increased beetle activity. However, to our knowledge, no studies have compared axial resin ducts in the secondary xylem of whitebark pine across pairs of living and dead whitebark pine trees to better understand survivorship following multiple disturbances including mountain pine beetle and white pine blister rust. We found a clear distinction in growth and defense characteristics between live and dead whitebark pine. Across our study sites on the Flathead Indian Reservation in northwestern Montana, live whitebark pine produced larger resin ducts with a greater annual investment in resin–based defenses than whitebark pine that died. Resin duct size, duct area, and relative duct area were all greater in live whitebark pine (by 56%, 48%, and 57%, respectively) and these were the most important variables influencing whitebark pine survivorship. In contrast, whitebark pine that had died grew faster over time (22% larger ring widths) than their live counterparts and also produced more resin duct structures (20% more ducts on average). Whitebark pine at our study sites exhibit differing strategies in the allocation of resources toward growth and defense, with the majority of survivors of recent disturbance investing more in defensive structures than growth. Our results support the idea that maintaining genetic variability and the associated suite of differing physiological traits promotes diverse response strategies to a complex array of biophysical and biological stressors that might leave a species vulnerable to extinction across its range.

Northern Rocky Mountain↗

USGS2021

Pollinator communities vary with vegetation structure and time since management within regenerating timber harvests of the Central Appalachian Mountains

Native pollinator populations across the United States are increasingly threatened by a multitude of ecological stressors. Although the drivers behind pollinator population declines are varied, habitat loss/degradation remains one of the most important threats. Forested landscapes, where the impacts of habitat loss/degradation are minimized, are known to support robust pollinator populations in eastern North America. Within heavily forested landscapes, timber management is already implemented as a means for improving forest health and enhancing wildlife habitat, however, little is known regarding the characteristics within regenerating timber harvests that affect forest pollinator populations. In 2018-19, we monitored insect pollinators in 143 regenerating (≤ 9 growing seasons post-harvest) timber harvest sites across Pennsylvania. During 1,129 survey events, we observed over 9,100 bees and butterflies, 220 blooming plant taxa, and collected over 2,200 pollinator specimens. Bee and butterfly abundance were positively associated with season-wide floral abundance and negatively associated with dense vegetation that inhibits the growth of understory floral resources. Particularly in late summer, few pollinators were observed in stands > 6 years post-harvest, with models predicting five times more bees in 1-year-old harvests than in 9-year-old harvests. Pollinator species diversity was positively associated with floral diversity and percent forb cover, and negatively associated with percent tall (>1m) sapling cover. These results suggest that regenerating timber harvests promote abundant and diverse pollinator communities in the Appalachian Mountains, though pollinator abundance declined quickly as woody stems regenerated. Ultimately, our findings contribute to a growing body of literature suggesting that dynamic forest management producing an even mix of age classes would benefit forest pollinator populations in the Central Appalachian Mountains.

Pennsylvania↗

USGS2004

Improved spatial resolution for U-series dating of opal at Yucca Mountain, Nevada, USA, using ion-microprobe and microdigestion methods

Two novel methods of in situ isotope analysis, ion microprobe and microdigestion, were used for 230Th/U and 234U/238U dating of finely laminated opal hemispheres formed in unsaturated felsic tuff at Yucca Mountain, Nevada, proposed site for a high-level radioactive waste repository. Both methods allow analysis of layers as many as several orders of magnitude thinner than standard methods using total hemisphere digestion that were reported previously. Average growth rates calculated from data at this improved spatial resolution verified that opal grew at extremely slow rates over the last million years. Growth rates of 0.58 and 0.69 mm/m.y. were obtained for the outer 305 and 740 ??m of two opal hemispheres analyzed by ion microprobe, and 0.68 mm/m.y. for the outer 22 ??m of one of these same hemispheres analyzed by sequential microdigestion. These Pleistocene growth rates are 2 to 10 times slower than those calculated for older secondary calcite and silica mineral coatings deposited over the last 5 to 10 m.y. dated by the U-Pb method and may reflect differences between Miocene and Pleistocene seepage flux. The microdigestion data also imply that opal growth rates may have varied over the last 40 k.y. These data are the first indication that growth rates and associated seepage in the proposed repository horizon may correlate with changes in late Pleistocene climate, involving faster growth during wetter, cooler climates (glacial maximum), slower growth during transition climates, and no growth during the most arid climate (modern). Data collected at this refined spatial scale may lead to a better understanding of the hydrologic variability expected within the thick unsaturated zone at Yucca Mountain over the time scale of interest for radioactive waste isolation. ?? 2004 Elsevier Ltd.

Geochimica et Cosmochimica Acta↗

USGS2013

Aeolian controls of soil geochemistry and weathering fluxes in high-elevation ecosystems of the Rocky Mountains, Colorado

When dust inputs are large or have persisted for long periods of time, the signature of dust additions are often apparent in soils. The of dust will be greatest where the geochemical composition of dust is distinct from local sources of soil parent material. In this study the influence of dust accretion on soil geochemistry is quantified for two different soils from the San Juan Mountains of southwestern Colorado, USA. At both study sites, dust is enriched in several trace elements relative to local rock, especially Cd, Cu, Pb, and Zn. Mass-balance calculations that do not explicitly account for dust inputs indicate the accumulation of some elements in soil beyond what can be explained by weathering of local rock. Most observed elemental enrichments are explained by accounting for the long-term accretion of dust, based on modern isotopic and geochemical estimates. One notable exception is Pb, which based on mass-balance calculations and isotopic measurements may have an additional source at one of the study sites. These results suggest that dust is a major factor influencing the development of soil in these settings and is also an important control of soil weathering fluxes. After accounting for dust inputs in mass-balance calculations, Si weathering fluxes from San Juan Mountain soils are within the range observed for other temperate systems. Comparing dust inputs with mass-balanced based flux estimates suggests dust could account for as much as 50–80% of total long-term chemical weathering fluxes. These results support the notion that dust inputs may sustain chemical weathering fluxes even in relatively young continental settings. Given the widespread input of far-traveled dust, the weathering of dust is likely and important and underappreciated aspect of the global weathering engine.

Colorado↗

USGS2020

Zircon-hosted melt inclusion record of silicic magmatism in the Mesoproterozoic St. Francois Mountains terrane, Missouri: Origin of the Pea Ridge iron oxide-apatite rare earth element deposit and implications for regional crustal pathways of mineralization

Voluminous silicic magmatism was coeval with iron ore mineralization in the St. Francois Mountains terrane in southeast Missouri, part of the broader Mesoproterozoic Granite-Rhyolite province along the eastern margin of Laurentia. Some of the iron deposits contain extraordinary endowments of critical elements, such as the Pea Ridge iron oxide-apatite (IOA) deposit, which has an average grade of ~12 wt% rare earth oxides in breccia pipes that flank the ore body. To assess the role of silicic magmatism in the genesis of the Pea Ridge deposit, we present a high-spatial resolution study of zirconhosted melt inclusions from rhyolitic ash-flow tuffs. Melt inclusion data are combined with textural, geochemical, and geochronological analyses of zircon hosts to elucidate the magmatic-hydrothermal evolution of the Pea Ridge system. Two contemporaneous silicic igneous centers in the St. Francois Mountains terrane, Bourbon and Eminence, were studied for comparison. Pea Ridge melt inclusions are trachydacitic to rhyolitic (~63-79 wt% SiO2, ~5.6-11.7 wt% Na2O+K2O) with very high Cl in the least-evolved and most alkaline melt inclusions (~2,000-5,000 ppm Cl). Rare earth elements (REE) in melt inclusions have identical chondrite-normalized patterns to the mineralized breccia pipes, but with systematically lower absolute concentrations. Haplogranite ternary pressures range from ~0.5-10 kbar, with an average of ~2-3 kbar (7-12 km depth), and liquidus temperatures are ~850-950 °C, with an average of ~920 °C. Silicate and phosphate mineral inclusions have compositions that overlap minerals from the iron ore body and breccia pipes, recording a transition from igneous to hydrothermal zircon growth. Igneous iron oxide inclusions have compositions that indicate Pea Ridge magmas were reduced to moderately oxidized (log fO2 of -0.8 to -1.84 NNO). Zircons from two Pea Ridge samples have 207Pb/206Pb concordia ages of 1456 ± 9 Ma and 1467 ± 13 Ma that overlap published ages for the breccia pipes and iron ore zones of the Pea Ridge deposit. A population of texturally and chemically disrupted zircons have discordant domains that correspond to high Fe, U, and REE concentrations, consistent with the unique geochemical attributes of the IOA-REE ore body. Inherited cores in Pea Ridge and Bourbon zircons have concordant 207Pb/206Pb dates of 1550-1618 Ma, providing direct evidence of cratonic basement beneath these centers. Oxygen isotope data for inherited and autocrystic igneous zircons span from mantle to crustal values (18Ozircon=5.5-7.9‰). Our data are consistent with a model in which metasomatized mantle components were mixed with cratonic and accreted crustal material in a back-arc or rifted segment of a volcanic arc, with ore fluids derived from Cl-rich melts to transport Fe and REE in a long-lived (tens of Myr), pulsed, magmatic-hydrothermal system. Bourbon, which also possesses IOA mineralization, shares key petrologic similarities with the Pea Ridge system, whereas Eminence, which is not mineralized, has disparate geochemical and isotopic signatures that indicate it formed in a different crustal setting. The location of Pea Ridge and Bourbon along a cratonic margin may have been important in focusing silicic melts and mineralization in the upper crust, serving as a guide for future exploration efforts.

Missouri↗

USGS2013

Temporal and spatial distribution of alteration, mineralization and fluid inclusions in the transitional high-sulfidation epithermal-porphyry copper system at Red Mountain, Arizona

Red Mountain, Arizona, is a Laramide porphyry Cu system (PCD) that has experienced only a modest level of erosion compared to most other similar deposits in the southwestern United States. As a result, the upper portion of the magmatic–hydrothermal system, which represents the transition from shallower high-sulfidation epithermal mineralization to deeper porphyry Cu mineralization, is well preserved. Within the Red Mountain system, alteration, mineralization and fluid inclusion assemblages show a systematic distribution in both time and space. Early-potassic alteration (characterized by the minerals biotite and magnetite) is paragenetically earlier than late-potassic alteration (K-feldspar–anhydrite) and both are followed by later phyllic (sericite–pyrite) alteration. Advanced argillic alteration (pyrophyllite–alunite–other clay minerals) is thought to be coeval with or postdate phyllic alteration. Minerals characteristic of advanced argillic alteration are present in the near surface. Phyllic alteration extends to greater depths compared to advanced argillic alteration. Early-potassic and late-potassic alteration are only observed in the deepest part of the system. Considerable overlap of phyllic alteration with both early-potassic and late-potassic alteration zones is observed. The hypogene mineralization contains 0.4–1.2% Cu and is spatially and temporally related to the late-potassic alteration event. Molybdenum concentration is typically < 300 ppm but positive anomalies (between 600 and 1200 ppm) occur, and typically correlate with the zones of higher Cu grades. Silver and Au range up to 50 ppm and 1 ppm, respectively, and mostly occur in the deeper parts of the system. Individual assays of up to 18 ppm Au and 274 ppm Ag in the shallower part of the system are interpreted to be associated with areas of highly focused fluid flow (i.e., breccias and thick veins). A near-surface, discontinuous chalcocite blanket is represented by scattered Cu anomalies within the mixed oxide/sulfide zone and its discontinuous nature may reflect differential permeability along fractures and faults. In the deepest part of the system, an early generation of low-to-moderate density and salinity liquid + vapor inclusions with opaque daughter minerals is followed in time by halite-bearing inclusions that also contain opaque daughter minerals indicating that an early intermediate-density magmatic fluid evolved to a high-density, high-salinity mineralizing fluid. The increase in density and salinity of fluids with time observed in the deeper parts of the system may be the result of immiscibility (“boiling”) of the earlier magmatic fluids or may reflect the compositional evolution of fluids that exsolved from the magma. Trails of inclusions consisting of only vapor-rich inclusions are common in the shallow parts of the system, and are associated with advanced argillic alteration, suggesting that intense boiling (“flashing”) occurred at (or below) this level. Fluid inclusion assemblages consisting of coexisting vapor-rich and halite-bearing inclusions are observed in samples extending from the surface to the upper part of the late-potassic zone, indicating that fluid immiscibility occurred within this depth interval.

Arizona↗

USGS2012

Rocky Mountain hydroclimate: Holocene variability and the role of insolation, ENSO, and the North American Monsoon

Over the period of instrumental records, precipitation maximum in the headwaters of the Colorado Rocky Mountains has been dominated by winter snow, with a substantial degree of interannual variability linked to Pacific ocean–atmosphere dynamics. High-elevation snowpack is an important water storage that is carefully observed in order to meet increasing water demands in the greater semi-arid region. The purpose here is to consider Rocky Mountain water trends during the Holocene when known changes in earth's energy balance were caused by precession-driven insolation variability. Changes in solar insolation are thought to have influenced the variability and intensity of the El Niño Southern Oscillation (ENSO), Pacific Decadal Oscillation (PDO), and North American Monsoon and the seasonal precipitation balance between rain and snow at upper elevations. Holocene records are presented from two high elevation lakes located in northwest Colorado that document decade-to-century scale precipitation seasonality for the past ~ 7000 years. Comparisons with sub-tropical records of ENSO indicate that the snowfall-dominated precipitation maxima developed ~ 3000 and 4000 years ago, coincident with evidence for enhanced ENSO/PDO dynamics. During the early-to-mid Holocene the records suggest a more monsoon affected precipitation regime with reduced snowpack, more rainfall, and net moisture deficits that were more severe than recent droughts. The Holocene perspective of precipitation indicates a far broader range of variability than that of the past century and highlights the non-linear character of hydroclimate in the U.S. west.

Colorado↗

USGS2007

Distributed energy-balance modeling of snow-cover evolution and melt in rugged terrain: Tobacco Root Mountains, Montana, USA

A distributed energy-balance model was developed for simulating snowpack evolution and melt in rugged terrain. The model, which was applied to a 43-km2 watershed in the Tobacco Root Mountains, Montana, USA, used measured ambient data from nearby weather stations to drive energy-balance calculations and to constrain the model of Liston and Sturm [Liston, G.E., Sturm, M., 1998. A snow-transport model for complex terrain. Journal of Glaciology 44 (148), 498-516] for calculating the initial snowpack thickness. Simulated initial snow-water equivalent ranged between 1 cm and 385 cm w.e. (water equivalent) with high values concentrated on east-facing slopes below tall summits. An interpreted satellite image of the snowcover distribution on May 6, 1998, closely matched the simulated distribution with the greatest discrepancy occurring in the floor of the main trunk valley. Model simulations indicated that snowmelt commenced early in the melt season, but rapid meltout of snow cover did not occur until after the average energy balance of the entire watershed became positive about 45 days into the melt season. Meltout was fastest in the lower part of the watershed where warmer temperatures and tree cover enhanced the energy income of the underlying snow. An interpreted satellite image of the snowcover distribution on July 9, 1998 compared favorably with the simulated distribution, and melt curves for modeled canopy-covered cells mimicked the trends measured at nearby snow pillow stations. By the end of the simulation period (August 3), 28% of the watershed remained snow covered, most of which was concentrated in the highest parts of the watershed where initially thick accumulations had been shaded by surrounding summits. The results of this study provide further demonstration of the critical role that topography plays in the timing and magnitude of snowmelt from high mountain watersheds. ?? 2006 Elsevier B.V. All rights reserved.

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