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Petrology, composition, and age of intrusive rocks associated with the Quartz Hill molybdenite deposit, southeastern Alaska

A large porphyry molybdenum deposit (Quartz Hill deposit) was recently discovered in the heart of the Coast Range batholithic complex about 70 km east of Ketchikan, southeastern Alaska. Intrusive rocks associated with the mineral deposit form two composite epizonal to hypabyssal stocks and many dikes in country rocks. The stocks are characterized by a variety of textural rock types varying from equigranular or weakly seriate biotite granite to porphyries with aphanitic or very fine grained and aplitic groundmasses. These rocks contain about equal amounts of quartz, albitic plagioclase, and microperthitic microcline and less than 2.5% biotite. Unaltered rocks contain between 0.2 and 1% CaO, less than 1.7% combined Fe 2 O 3 , FeO, and MgO, and 74.4 to 77.7% SiO 2 . Total alkalis are between 8 and 9%, and K 2 O/Na 2 O is about 1.1. The range of major-oxide variation is small, but it is systematically related to lithology. Many trace-elements, including B, Pb, Sn, and Li have low concentrations. Intrusive rocks associated with the Quartz Hill deposit are more albitic and possibly trace-element depleted compared to some other rocks associated with porphyry molybdenum deposits.All observed metallization and alteration is within the Quartz Hill stock. Molybdenite forms fracture coatings and occurs in veins with quartz. Alteration is widespread and includes development of secondary quartz, pyrite, K-feldspar, biotite, white mica, chlorite, and zeolite. Field relations indicate that the stocks were emplaced after regional uplift and erosion of the Coast Range batholithic complex, and K–Ar data show that intrusion and alteration took place in late Oligocene time, about 27 to 30 Ma ago. Data from the Ketchikan quadrangle indicate that porphyry molybdenum metallization in the Coast Range batholithic complex is associated with regionally extensive but spotty, middle Tertiary or younger, felsic magmatism.

Alaska↗

Uranium occurrences at the Moonlight Mine and Granite Point claims, Humboldt County, Nevada

The Moonlight mine and Granite Foint claims are on the western flank of the Double H Mountains between the Kings River and Quinn, River valleys in northern Humboldt County, Nev. Uranium minerals at the Moonlight mine occur in a vein in intensely altered Tertiary volcanic rocks. The knovm uranium mineralization is spotty and erratic, but ore-grade material is present in the vein. Samples of the vein taken along its outcrop and in the mine shaft contain from less than 0.02 percent to 0.40 percent U308. The uranium minerals change from autunite at the surface to torbernite, 'gummite(?)' and pitchblende below the 90-foot level of the shaft. The Granite Point claims are two miles north of the Moonlight mine at the base of a rhyolite cliff. Radioactivity traverses made along the base and slope of the rhyolite cliff indicate that a large part of the rhyolite is abnormally radioactive. Radioactivity ranges from 0.013 to 0.3 mr/hr and averaged 0.10 mr/hr. in the vicinity of the claims. A sample taken at the base of the rhyolite cliff, at the point of highest radioactivity c6ntains 0.02 percent U3O8.

Trace Elements Memorandum↗

Direct dating of mineralization at Goldfield, Nevada, by potassium-argon and fission-track methods

Potassium-argon dating of hypogene alunite and K-mica from hydrothermally altered rocks at Goldfield, Nevada, yields mineralization ages of 20 to 21 m.y., in good agreement with a mineralization age established by potassium-argon dating of unaltered premineralization and postmineralization volcanic units. Premineralization volcanic units that are pervasively propylitized cannot be dated by the potassium-argon method but yield zircon fission-track ages, and in several cases yield concordant apatite fission-track ages. Two samples from premineralization units yield apatite ages concordant with the age of mineralization established by potassium-argon geochronometry, reflecting annealing of the apatite during the hydrothermal episode.Potassium-argon dating of supergene alunite samples yields imprecise ages in the range 9 to 12 m.y. that probably record the first exposure of their hydrothermally altered host rocks to oxidizing conditions. Potassium-argon dating of postmineralization basalts and silicic tuffs interbedded with conglomerates bearing altered rock clasts shows that the altered area was eroded nearly to present topographic levels by 11 m.y. ago, at which time it was covered by basalt flows now represented only by scattered remnants. Apatites from premineralization volcanic units give fission-track ages of 20 m.y. or more, indicating that no significant thermal event has affected altered rocks at Goldfield since mineralization took place.

Nevada↗

Isotopic study of galenas from the upper Mississippi Valley, the Illinois-Kentucky, and some Appalachian Valley mineral districts

Analyses of lead isotopes in galena in carbonate rock ore deposits collected from several mineralized districts in the Central and Eastern Interior of the United States support previous studies in establishing that the galena is anomalously radiogenic ("J"type")- This study , using care-fully selected samples to test some géologie relationships, shows region-wide and distrietwide systematic variations in isotope ratios. The genetic implications of thèse variations are discussed. Two mechanisms of origin are considered to explain thèse variations in isotopic ratios. One involves mixing of leads from multiple sources, the other calls for variable lead-isotope ratios originating from a single source. Several source materials for the lead ores have been suggested; whether a single source has predominated, or two or more main sources have predominated is still unresolved. Slopes from Pb206/Pb204 versus Pb207/Pb204 plot are compatible with a contribution of lead by the 1300 ± 300 m.y. basement rocks that underlie the deposits. The spatial relationships of alkaline igneous rocks to several of the minerai districts in the Mississippi Valley région suggest a possible mag-matic source for the lead. Isotopic analyses of galenas closely associated with several of the intrusive rocks are similar in isotopic composition to adjacent ore leads, but genetic implications are ambiguous. Galena oc-curring in shales in the Mississippi Valley région outside mineralized districts contains ordinary lead. Théories that call upon such shales to be the major source of the lead in the depoaits of the Mississippi Valley type must explain this distinct différence in isotopic compositions. Galena collected from districts within the Appalachian Ridge and Valley Province contains notably less radiogenic lead than that from the Mississippi Valley minerai districts , and the lead is of the ordinary type.

Illinois, Kentucky↗

Mesozoic magmatism in Montana

From crystalline batholiths with footprints larger than 4,500 km 2 to beds of micron-sized ash particles, a record of Mesozoic magmatism is found throughout Montana. Mesozoic igneous rocks are an important natural resource in the state because of their association with precious metal ores and industrial mineral deposits. Mesozoic magmatism in Montana is a tale of volcanic arc eruptions, pluton emplacement, crustal magma differentiation, melting, and assimilation. Explosive caldera-forming eruptions, magmatic hydrothermal and metamorphic mineralization, tectonic uplift, fluvial erosion, and redeposition of igneous rocks and mineral resources are all chronicled by Mesozoic igneous rocks. This article offers a summary of the types, locations, extents, and ages of Mesozoic igneous rocks in Montana. Then follows a discussion of the generation and emplacement of magmas and intrusive rocks, their geometries, and the style and timing of magmatism. The chapter ends with a summary of what remains unknown and offers suggestions for future research.

Montana↗

White mica geochemistry of the Catheart Mountain porphyry copper deposit, Maine

White micas from hydrothermally altered and mineralized zones in the Catheart Mountain Cu-Mo porphyry deposit have regular compositional variations that are generally related to the contents of copper, total iron, and sulfur in the whole rock. Micas in unmineralized rocks exhibit no such relationship. White mica compositions reflect primarily the control imposed by the celadonitic substitution AIIV +Aiv1 =Si+ (Fe, Mg). The variation in white mica composition in the Catheart Mountain porphyry may be explained by superposition and overprinting of mineral assemblages by ore fluids during mineralization and during the waning stages of hydrothermal alteration. Local bulk compositional differences, changing PHao and fluid compositions during mineralization, and superposition of mineral assemblages along microzoned veins contributed to variation in white mica composition. However, the general relation between white mica composition and base-metal content in the mineralized rocks at Catheart Mountain suggests that identification of this white mica population might be useful as an indicator of mineralization gradients.

Bulletin↗

Magmatic infiltration and melting in the lower crust and upper mantle beneath the Cima volcanic field, California

Xenoliths of lower crustal and upper mantle rocks from the Cima volcanic field (CVF) commonly contain glass pockets, veins, and planar trains of glass and/or fluid inclusions in primary minerals. Glass pockets occupy spaces formerly occupied by primary minerals of the host rocks, but there is a general lack of correspondence between the composition of the glass and that of the replaced primary minerals. The melting is considered to have been induced by infiltration of basaltic magma and differentiates of basaltic magma from complex conduits formed by hydraulic fracturing of the mantle and crustal rocks, and to have occurred during the episode of CVF magmatism between ∼7.5 Ma and present. Variable compositions of quenched melts resulted from mixing of introduced melts and products of melting of primary minerals, reaction with primary minerals, partial crystallization, and fractionation resulting from melt and volatile expulsion upon entrainment of the xenoliths. High silica melts ( >∼60% SiO 2 ) may result by mixing introduced melts with siliceous melts produced by reaction of orthopyroxene. Other quenched melt compositions range from those comparable to the host basalts to those with intermediate Si compositions and elevated Al, alkalis, Ti, P, and S; groundmass compositions of CVF basalts are consistent with infiltration of fractionates of those basalts, but near-solidus melting may also contribute to formation of glass with intermediate silica contents with infiltration only of volatile constituents.

California↗

Petrogenesis and rare earth element mineralization of the Elk Creek carbonatite, Nebraska, USA

Although carbonatites are the primary source of the world’s rare earth elements (REEs), the processes responsible for ore-grade REE enrichment in carbonatites are still poorly understood. In this study, we present a petrologic, geochemical, and isotopic evaluation of the Elk Creek carbonatite in southeast Nebraska to constrain the origin of REE mineralization. The Elk Creek carbonatite is a multilithologic carbonatite comprised of an early apatite-dolomite carbonatite, a middle/heavy REE-enriched magnetite-dolomite carbonatite, and a late-stage light REE-enriched, barite-dolomite carbonatite, as well as a suite of breccias. Neodymium, strontium, and carbon isotopic data from the early apatite-dolomite carbonatite, ε Nd (T) = 2.3 to 3.4, 87 Sr/ 86 Sr (i) = 0.702704 to 0.702857, and δ 13 C = −3.3 to −3.4, indicate that the parental magma and REEs were derived from the mantle, and textural and chemical data suggest that hydrothermal processes played an important role in reaching ore-grade enrichment. Higher initial 87 Sr/ 86 Sr values (∼0.7041) of REE-mineralized lithologies are evidence that these fluids were derived, in part, from meteoric water that interacted with the country rock. Modeling of the C-O isotopic data reveals that some of the isotopic variation results from closed-system Rayleigh fractionation of an evolving carbonatitic magma between 300 and 500 °C, but an excursion to heavier δ 18 O is likely the result of interaction with H 2 O-CO 2 -fluids at temperatures from 400 to 100 °C. Hydrothermal dolomite has higher 87 Sr/ 86 Sr values than early-formed magmatic dolomite, consistent with metasomatism by fluids derived, in part, from a more radiogenic source such as the Precambrian-age wall rock. Rare earth element mineralization occurs primarily in fine-grained, cavity filling minerals including monazite, bastnäsite, parisite, and synchysite along with barite, dolomite, quartz, and iron oxides. We interpret the LREE enrichment at Elk Creek to be the product of hydrothermal fluids derived from the evolving carbonatite magma and fluids from the wall rock. The REEs likely became enriched in late-stage fluids from the evolving magma as well as being remobilization by the dissolution of earlier formed minerals. Middle/heavy REE-enrichment in the magnetite-dolomite carbonatite is hosted in hydrothermal dolomite and is attributed to variations in the composition of hydrothermal fluids.

Nebraska↗

Ground-followup studies of the 1977 airborne electromagnetic survey in the Assifar and Mulhal areas, Wadi Bidah district, Kingdom of Saudi Arabia

Parts of four airborne electromagnetic (AEM) anomalies were selected for study in order to determine the cause of high conductivity of Precambrian rocks underlying extensive areas in the southern Wadi Bidah district, Kingdom of Saudi Arabia. In the Assifar area, which contains an ancient mine or prospect having the same name, geophysical data suggest that a mineralized body may lie beneath and immediately south of the ancient workings. Many other conductive zones detected during the course of the geophysical survey are thought to be related to metavolcanic rocks containing carbonaceous materials. Detailed geologic mapping, and possibly diamond core drilling, will be necessary to fully evaluate the area. In the Mulhal No. 2 area, located about 2 km south of the Mulhal ancient mine, geophysical studies suggest that mineralized rocks extend about 500 m along strike beneath outcrops of gossanous material. A brief review of the AEM ground-followup studies in the Wadi Bidah district suggests that most, if not all, of the AEM conductors are carbonaceous rocks. Secondary causes of conductivity are intense faulting and shearing.

Open-File Report↗

Geochemistry of hydrothermal alteration at the Qolqoleh gold deposit, northern Sanandaj–Sirjan metamorphic belt, northwestern Iran: Vectors to high-grade ore bodies

The Qolqoleh orogenic gold deposit in the northern part of the Sanandaj–Sirjan metamorphic belt in northwestern Iran is hosted by a steeply dipping sequence of greenschist facies Cretaceous volcano–sedimentary rocks, including mafic to intermediate metavolcanic rocks, sericite and chlorite schist, and marble. Geochemical and petrochemical data including the ∑ REE, (La/Yb) N and Eu/Eu* ratios were obtained from country rocks, ore-enveloping alteration zones, and mineralized zones to assess the nature of the trace element and rare earth element (REE) interaction between the wall rock and the mineralizing fluid. Quartz–sulfide veins at the deposit are characterized by a pyrite–pyrrhotite–chalcopyrite–sphalerite–arsenopyrite–native gold assemblage. Alteration halos border the mineralized zones and broadly comprise: (1) an outer carbonate–chlorite alteration zone in all rock types, particularly in chlorite schist; (2) a middle sericite–carbonate alteration zone in the sericite schist; and (3) an inner quartz–sulfide alteration zone in sericite schist and mafic to intermediate metavolcanic rocks. The geochemical data indicate that the concentrations of Al 2 O 3 , P 2 O 5 , TiO 2 , Y, and Zr are relatively constant, suggesting that these elements were the least mobile during hydrothermal activity. Using Al 2 O 3 as the immobile component, there is evidence for mobility of trace elements, particularly light REE, TiO 2 , and Zr in the altered wall rocks. The altered rocks show a relatively light REE depletion ((La/Yb) N ≅ 9.41), which clearly correlates with the grades of gold mineralization and intensity of the alteration (3 ppm Au). The depletion of light REE is best indicated by a decrease in (La/Yb) N as shown by ratios of 10.5 to 11.8. Wall rock decarbonation reactions during infiltration of the mineralizing fluid resulted in differential mobilization of REE, from a fluid with initially low REE content. The overall trace element geochemistry of the altered wall rock is controlled by the initial composition of the wall rocks and the ore-fluid composition. Hydrothermal ore-forming fluids are recognized as CO 2 -rich near-neutral reduced fluids with high values of H 2 S, K, and S content. Observed variability in alteration halos at the Qolqoleh deposit points to major differences in REE and trace element content in original host rocks that have interacted with a relatively similar ore fluid. Therefore, depending on the composition of each host rock lithology, the geochemistry of hydrothermal alteration (e.g., ∑ REE content and (La/Yb) N ratios) and alteration mineralogy including the carbonate–sericite–quartz–sulfide assemblages may be used as a primary tool for lithogeochemical exploration for gold deposits in northwestern Iran.

Journal of Geochemical Exploration↗

The zonal distribution of selected elements above the Kalamazoo porphyry copper deposit, San Manuel district, Pinal County, Arizona

There may be many as-yet-undiscovered porphyry copper deposits that exist as blind deposits deep within exposed rock bodies. The Kalamazoo porphyry copper-molybdenum deposit is a blind deposit present at depths up to at least 1,000 m (about 3,200 ft) that contains zoning features common to many of the known porphyry copper deposits found in western North and South America. As the preliminary phase in a geochemical study of the Kalamazoo deposit, whole-rock samples of core and cuttings from two drill holes have been analyzed for 60 different elements. Each hole represents a different major rock unit and each has penetrated completely through all the existing alteration zones and the ore zone. Plots of concentration vs. depth for 17 selected elements show distinct high- or low-concentration zones that are spatially related to the ore zone. For most of the ore-related elements no significant correlation with the two lithologies is apparent. The spatial distribution and abundance of elements such as Co, Cu, S, Se, Mn, Tl, Rb, Zn, B, and Li may be useful in determining the direction for exploration to proceed to locate a blind deposit. Trace element studies should be valuable in evaluating areas containing extensive outcrops of rocks with disseminated pyrite. Elemental zoning should be at least as useful as alteration-mineralization zoning for evaluating rock bodies thought to contain blind deposits similar to the Kalamazoo deposit.

Journal of Geochemical Exploration↗

Boulder Creek batholith, Colorado part II: Isotopic age of emplacement and morphology of zircon

Zircon separated from six rocks whose compositions spanned the range of differentiation in the Boulder Creek batholith yielded a “discordia” age of emplacement of 1725 m.y., close to the average PB 207 /Pb 206 age 1720 m.y.) and indicating that the constituent rocks are cogenetic within approximately ± 20 m.y. Statistical studies show that from 20 to 80 percent of the zircon in any one sample (1) is no-neuhedral, (2) has lower (length/width) ratios than the associated euhedral zircon, and (3) in direct contrast to the euhedral, increases markedly interior of the batholith toward contacts with the older metasediments and internal zones of contamination; it is inferred to have been “inherited” via assimilation. Unlike the noneuhedral fraction the euhedral zircon shows a linear decrease in length/width ratio with an increase in SiO 2 content of the containing rocks; it is inferred to be magmatic in origin. Regardless of the relative abundance of inherited versus magmatic zircon, all samples closely fit a single discordia chord, indicating that both zircon fractions formed at about the same time. This conclusion is compatible with field relationships that indicate the emplacement of the syntectonic Boulder Creek rocks took place during a period of metamorphism notable for the widespread development of new minerals in the country rocks. (1) Zircon from a Silver Plume Granite dike intruding the Boulder Creek batholith, (2) zircon from Silver Plume correlatives immediately to the north (Tilton and co-workers), and (3) uraninite from a probable Silver Plume correlative in the Central City district, together yield a sharply defined discordia age of emplacement of 1415 m.y. The separate “discordia” chords for the Boulder Creek and Silver Plume zirconconverge close to their lower intercepts with “concordia” indicative of a one-step lead loss during the Laramide disturbance. The Silver Plume “thermal event” left no age imprint on the Boulder Creek zircon, presumably because insufficient time had elapsed to produce significant metamictization.

Colorado↗

Occurrences of alunite, pyrophyllite, and clays in the Cerro La Tiza area, Puerto Rico

A deposit of hydrothermally altered rocks in the Cerro La Tiza area located between the towns of Comerio and Aguas Buenas, approximately 25 kilometers southwest of San Juan, Puerto Rico, was mapped and studied to determine the principal minerals, their extent distribution and origin, and the possibility of their economic utilization, especially in Puerto Rico. The Cerro la Tiza area is about 7 1 / 2 kilometers long, has an average width of about 1 1 / 2 kilometers and embraces a total area of approximately 15 square kilometers. The principal mineralized zone, a dike-like mass of light-colored rocks surrounded by dark-colored volcanic country rocks, occupies the crest and upper slopes of east-trending Cerro La Tiza ridge and is believed to be of Late Cretaceous or Eocene age. This zone is approximately 5,300 meters long, 430 meters wide and has an area of approximately 225 hectares (556 acres). The rocks of the mineralized zone are of mixed character and consist mainly of massive quartzose rocks and banded quartz-alunite rocks closely associated with foliated pyrophyllitic, sericitic and clayey rocks. The principal minerals in probably order of abundance are quartz, alunite, pyrophyllite, kaolin group clays (kaolinite and halloysite) and sericite. Minerals of minor abundance are native sulfure, diaspore, svanbergite (?), sunyite (?), hematite, goethite, pyrite, rutile (?) and very small quantities of unidentified minerals. The mineralized zone has broken down to deposits of earth-rock debris of Quaternary age that cover much of the slopes and flanks of Cerro La Tiza. This debris consists generally of fragments and boulders with a very large size range embedded in a clayey matrix. The distribution of the earth-rock debris with respect to the present topography and drainage suggests that it may have undergone at least two cycles of erosion. Underlying the earth-rock debris and completely enclosing the mineralized zone are country rocks of probably Late Cretaceous age. These consist principally of low flows and volcanic and flow breccias but contain thin interbedded siltstones and sandstones. The lavas are generally predominant at the western end of the area and the breccias at the eastern end. The mineralized zone and the country rocks are sheared along two predominant directions that are approximately N 70 degrees E and N 70 degrees W. The ridge of Cerro La Tiza appears to be a broad shear zone through which hydrothermal emanations gained access to the country rocks. The emanations are believed to have originated from intrusive rocks that probably underlie the area. The surrounding area contains both large and small exposed intrusive bodies. The largest one is the San Lorenzo batholith of Late Cretaceous or Eocene age whose exposed northwest edge is approximately 19 kilometers southeast of the eastern end of the Cerro La Tiza area. Other zones of hydrothermally altered rocks were discovered along a mineralized belt extending eastward from Cerro La Tiza through the Rio Gurabo Valley nearly to the Vieques Passage bordering the east coast of Puerto Rico. Other zones were discovered north and south of this belt and still others were found circumventing the San Lorenzo batholith. The most abundant minerals of the mineralized zone can be exploited for economic utilization in Puerto Rico. Alunite can be utilized in the manufacture of aluminum sulfate for water purification. It can also be used in the manufacture of alumina refractory materials. Pyrophyllite can be used as a carrier for insecticides and fungicides. It can also be utilized for the manufacture of ceramic products, as a filler in the soap industry and as a carrier for paint pigments. Kaolinite can be used in the ceramic industry and in the manufacture of glass as a substitute for feldspar. Halloysite might be utilized as a catalyst support in the cracking of petroleum. Tonnages of reserve ore on Cerro La Tiza are calculated to be 1,590,000 inferred short tons (1,440,000,000 inferred metric tons) of mixed minerals. These tonnages are based on the assumption that the depth of the mineralized zone is one-half of the exposed width. The deposit is well situated for open pit mining, but because of the existing cover of earth-rock debris, soil foliage, exploration should proceed exploitation for better determination of the most promising areas containing the best concentrations of the minerals sought.

Cerro La Tiza↗

Pre-Elsonian mafic magmatism in the Nain Igneous Complex, Labrador: The bridges layered intrusion

Decades of work on the pristine, unmetamorphosed, and well exposed anorthositic, mafic and granitic rocks of the Nain igneous complex, Labrador, have led to the conclusion that all plutonic rocks in that area were emplaced in a short time intercal at about 1300 ± 10 Ma). We report here new isotopic data for mafic intrusive rocks that appear to have crystallized several hundred Ma earlier than the bulk of the plutonic activity in the Nain complex. The Bridges layered intrusion (BLI) is a small (15–20 km 2 ) lens of layered mafic rocks about 1.5 km thick, surrounded and intruded by anorthositic, leuconoritic and leucotroctolitic plutons in the middle of the coastal section of the Nain igneous complex. BLI shows very well developed magmatic structures, including channel scours, slump structures, and ubiquitous modally graded layering. Most rocks, however, show granular textures indicative of recrystallization, presumably caused by emplacement of younger anorthositic rocks. BLI contains cumulate rocks with slightly more primitive mineral compositions (An 60–83 , Fo 66–71 ) than those of other mafic intrusions in the Nain igneous complex, including Kiglapait. Sm-Nd isotopic data for 7 BLI whole-rocks ranging in composition between olivine melagabbro and olivine leucogabbro yield an age of 1667 ± 75 Ma, which we interpret as the time of primary crystallization. The internal isotopic systematics of the BLI have been reset, probably by intrusion of adjacent anorthositic plutons. A SmNd mineral isochron (plag, whole-rock, mafics) for a BLI olivine melagabbro gives an age of 1283 ± 22 Ma, equivalent within error of a mineral array (plag, whole-rock, opx, cpx) for an adjacent, igneous-textured, leuconorite vein (1266 ± 152 Ma). The initial Nd ratio for BLI corresponds to ϵ Nd = −3.18 ± 0.44. Other whole-rock samples, however, some with vein-like alteration (Chlorite, serpentine, amphiboles), show ϵ Nd values as low as −9.1, suggesting variable contamination by direct assimilation of early Archean crustal rocks and/or by fluids that have interacted with such crust. Adjacent anorthositic rocks also show variable ϵ Nd some as low as −14.7, implying larger degrees if crustal assimilation, perhaps by parental magmas during lower crustal ponding prior to emplacement. These contamination effects preclude straightforward determination of the isotopic character of mantle sources for both BLI and the anorthositic rocks.

Labrador↗

Mineral resource of the month: natural and synthetic zeolites

Volcanic rocks containing natural zeolites — hydrated aluminosilicate minerals that contain alkaline and alkaline-earth metals — have been mined worldwide for more than 1,000 years for use as cements and building stone. For centuries, people thought natural zeolites occurred only in small amounts inside cavities of volcanic rock. But in the 1950s and early 1960s, large zeolite deposits were discovered in volcanic tuffs in the western United States and in marine tuffs in Italy and Japan. And since then, similar deposits have been found around the world, from Hungary to Cuba to New Zealand. The discovery of these larger deposits made commercial mining of natural zeolite possible.

Geotimes↗

Report on exploration of the Wadi Yiba copper prospect, Tihamat Ash Sham quadrangle, Kingdom of Saudi Arabia

The first phase of an exploration program at The Wadi Yiba copper prospect consisted of geologic mapping, prospecting, sampling, geophysical surveys, and diamond drilling. Copper mineralization is in a sedimentary rock sequence comprised mostly of siliceous, calcareous, and dolomitic rocks metamorphosed to the greenschist facies. The metasedimentary rocks are overlain and underlain by metavolcanic rocks. They are folded into a tight north-plunging syncline transected by two fault systems. Results from the exploration program indicate that a fault zone which sub-parallels the synclinal axis and cuts siliceous dolomite contains copper mineralization and small amounts of gold and silver. Copper and silver beaming pyroclastic rocks were found in the upper part of the metasedimentary rock sequence. Concentrations of copper mineralization seem to be restricted to particular rock units in the metasedimentary rock sequence. Primary sulfides have not been encountered in the drill holes to date and the results from one drill hole indicate secondary copper sulfide minerals to a vertical depth of 60 meters. Further exploration seems to be warranted and a program is proposed which includes the investigation of other mineral occurrences and geophysical anomalies in the region.

Open-File Report↗

Reconnaissance geology and geochronology of the Precambrian of the Granite Mountains, Wyoming

The Precambrian of the western part of the Granite Mountains contains a metamorphic complex of gneisses, schists and amphibolites that were derived through amphibolite-grade metamorphism from a sedimentary-volcanic sequence perhaps similar to that exposed in the southeastern Wind River Mountains. Whole-rock Rb-Sr dating places the time of metamorphism at 2925 ± 81 m.y. A high initial 87 Sr/ 86 Sr ratio of 0.7048 suggests that either the protoliths or the source terrane of the sedimentary component is several hundred million years older than the time of metamorphism. Following an interval of 300 ± 100 m.y. for which the geologic record is lacking or still undeciphered, the metamorphic complex was intruded by a batholith and satellite bodies of medium to coarse-grained, generally massive biotite granite and related pegmatite and aplite. The main body of granite is dated at 2602 ± 60 m.y. by the Rb-Sr method. Limited data suggest that diabase dikes were emplaced and nephrite veins were formed only shortly after intrusion of the granite. Emplacement of the granite at about 2600 m.y. ago appears to be related to a major period of regional granitic plutonism in the Precambrian of southern and western Wyoming. Granites sensu stricto that are dated between 2500 and 2600 m.y. occur in the Teton Range, the Sierra Madre, the Medicine Bow Mountains and the Laramie Range. This episode of granitic plutonism occurred some 50 to 100 m.y. later than the major tonalitic to granitic plutonism in the Superior Province of northern Minnesota and adjacent Ontario--the nearest exposed Precambrian W terrane that is analogous to the Wyoming Province. Initial 87 Sr/ 86 Sr ratios of some of the Wyoming granites are higher than expected if the rocks had been derived from juvenile magmas and it is likely that older crustal rocks were involved to some degree in the generation of these granites. Slightly to highly disturbed Rb-Sr and K-Ar mineral ages are obtained on rocks of the metamorphic complex arid on the granite. These ages range from about 2450 to 1450 m.y. and are part of a regional pattern of lowered mineral ages of Precambrian W rocks of southern Wyoming. A major discontinuity in these mineral ages occurs along a line extending from the northern Laramie Range, through the northern part of the Granite Mountains, to the southeastern Wind River Mountains. North of this line, Rb-Sr and K-Ar biotite ages are 2350 m.y. or greater whereas to the south, the biotite ages decrease drastically over a short distance to a common range of 1400-1600 m.y. We suggest that these lowered ages represent regional cooling below the 300° C isotherm as a consequence of uplift and erosion of the large crustal block occurring south of the age discontinuity. In this interpretation, the westerly-trending age discontinuity would be a zone of major crustal dislocation that resulted from vertical tectonics in late Precambrian X or early Precambrian Y time.

Wyoming↗