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Tungsten resources of the northern Rocky Mountains, Montana and Idaho— A synthesis and quantitative assessment of skarn-hosted resources

Mineral resource assessments performed by the U.S. Geological Survey provide a synthesis of available information about the location of known and suspected mineral deposits. This study focuses on skarn-hosted tungsten resources in the northern Rocky Mountain region of east-central Idaho and western Montana which have seen moderate tungsten trioxide production in the past from a variety of mineralization styles including skarn, vein and replacement, and wolframite-quartz veins. The area’s geology is dominated by large Cretaceous and Tertiary plutons that are emplaced into a belt of Mesoproterozoic to Permian sedimentary rock and affected by tectonism related to the Sevier and later Laramide orogenies. Known tungsten skarn mineral sites are associated with contacts between Cretaceous plutons and calcareous and argillaceous sedimentary or metasedimentary rocks, including two skarn deposits in Montana (Calvert and Browns Lake) that are consistent with an updated grade and tonnage model. This study (1) delineates permissive tracts where undiscovered tungsten skarn deposits may occur within 1 kilometer of the surface; (2) presents a tungsten mineral site dataset from a variety of public sources; (3) evaluates currently available geochemical, geophysical, and radiometric age data in support of tract delineation; (4) provides probabilistic estimates of the amount of tungsten and tungsten-mineralized rock that could be contained in undiscovered deposits within one major tract; (5) estimates the value of total undiscovered deposits using economic filter analysis; and (6) provides a synthesis of metallogenic controls on regional tungsten skarn and granitoid-related mineral deposits. Two permissive tracts were delineated: the Great Falls tectonic zone (GFTZ)-Cretaceous tract, for which a quantitative assessment was performed, and the Bitterroot tract, which was assessed in a qualitative manner. The quantitative three-part assessment, conducted in August 2019, indicates that undiscovered tungsten resources might exist in skarn-type deposits within the study area. Using a negative binomial function, a mean of 4 undiscovered deposits was calculated from panel estimates. Simulation results that combine an updated grade and tonnage model with estimates of undiscovered deposits include the amounts of ore and contained tungsten trioxide at different levels of uncertainty. A mean of 250,000 metric tons and median of 200,000 metric tons contained tungsten trioxide was calculated for the undiscovered deposits within the GFTZ-Cretaceous tract. The value of undiscovered deposits was estimated using a new economic filter that considers factors such as mine type, deposit depth, deposit geometry, metallurgical recovery rate, cutoff grade, and tract area. A review of the regional Archean to Paleogene geology suggests that ore metal (copper, molybdenum, and tungsten) variations in intrusion-related deposits of Montana and Idaho may be controlled by a number of factors including the age and composition of underlying basement terranes, depth of emplacement, pluton chemistry and degree of fractionation, redox conditions, and aqueous fluid-melt partition coefficients.

Idaho, Montana↗

Gondolellid conodonts and depositional setting of the Phosphoria Formation

The Phosphoria Formation and related rocks were deposited over an 8.9 m.y. interval beginning approximately 274.0Ma and ending approximately 265.1Ma. The Meade Peak Phosphatic Shale Member was deposited in southeastern Idaho and adjacent Wyoming over 5.4 m.y. from approximately 273.2 to 268.6 Ma. The Retort Phosphatic Shale Member was deposited in southwestern Montana and west-central Wyoming over 1.3 m.y. from approximately 267.4 to 266.1Ma. The base of the Roadian Stage of the Middle Permian occurs within the lower phosphate zone of the Meade Peak. The base of the Wordian Stage occurs within the upper phosphate zone of the Meade Peak. The presence of a cool-water brachiopod fauna, cool-water conodont faunas, and the absence of fusulinids throughout the Phosphoria basin indicate the presence of pervasive cool, upwelling waters. Acritarchs are intimately associated with phosphorites and phosphatic shales and may have been the primary organic producer to help drive phosphate production. The gondolellid conodont fauna of the Phosphoria Formation links a geographic cline of Jinogondolella nankingensis from the Delaware basin, West Texas, to the Sverdrup basin, Canadian Arctic, and shows distinct differentiation in species distribution, as do other conodont groups, within the Phosphoria basin. Ten species and two subspecies of gondolellid conodonts are recognized from the Phosphoria Formation and related rocks that belong to Mesogondolella and Jinogondolella.

Montana, Wyoming↗

Mapping the mineral resource base for mineral carbon-dioxide sequestration in the conterminous United States

This database provides information on the occurrence of ultramafic rocks in the conterminous United States that are suitable for sequestering captured carbon dioxide in mineral form, also known as mineral carbon-dioxide sequestration. Mineral carbon-dioxide sequestration is a proposed greenhouse gas mitigation technology whereby carbon dioxide (CO 2 ) is disposed of by reacting it with calcium or magnesium silicate minerals to form a solid magnesium or calcium carbonate product. The technology offers a large capacity to permanently store CO 2 in an environmentally benign form via a process that takes little effort to verify or monitor after disposal. These characteristics are unique among its peers in greenhouse gas disposal technologies. The 2005 Intergovernmental Panel on Climate Change report on Carbon Dioxide Capture and Storage suggested that a major gap in mineral CO 2 sequestration is locating the magnesium-silicate bedrock available to sequester the carbon dioxide. It is generally known that silicate minerals with high concentrations of magnesium are suitable for mineral carbonation. However, no assessment has been made in the United States that details their geographical distribution and extent, nor has anyone evaluated their potential for use in mineral carbonation. Researchers at Columbia University and the U.S. Geological Survey have developed a digital geologic database of ultramafic rocks in the conterminous United States. Data were compiled from varied-scale geologic maps of magnesium-silicate ultramafic rocks. The focus of our national-scale map is entirely on ultramafic rock types, which typically consist primarily of olivine- and serpentine-rich rocks. These rock types are potentially suitable as source material for mineral CO 2 sequestration.

Conterminous United States↗

Pesticides in the Lower Clackamas River Basin, Oregon, 2000-01

In 2000-01, the U. S. Geological Survey sampled the Clackamas River and its major lower-basin tributaries during storm runoff conditions for 86 dissolved pesticides and selected breakdown products. Twenty-seven compounds, including 18 herbicides, 7 insecticides, and 2 pesticide breakdown products, were detected in 18 stream samples. The most commonly detected pesticides, in decreasing frequency, included atrazine, simazine, diazinon, metolachlor, and diuron, which variously occurred in 46-92% of samples collected from the tributaries. Of these, atrazine, simazine, and metolachlor, plus six other compounds, also were detected in the main-stem Clackamas River. Pesticides were detected more frequently and at higher concentrations in the four lowermost tributaries (Deep, Richardson, Rock, and Sieben Creeks). In these streams, 12 to 18 pesticides were detected per stream in samples collected during spring and fall. Pesticides always occurred with at least one other pesticide, and about half of the samples, including one sample from the Clackamas River in October 2000, contained six or more pesticides. Nine pesticides, including the insecticide diazinon and the herbicides 2,4-D, atrazine, dichlobenil, diuron, imazaquin, metolachlor, simazine, and trifluralin, were detected in five water samples of Clackamas River water. No pesticides were detected in three samples of treated Clackamas River water used for drinking-water supply. Concentrations of six compounds--carbaryl, chlorpyrifos, diazinon, dieldrin, malathion, and the breakdown product of DDT (p,p'-DDE)--exceeded established or recommended criteria for the protection of aquatic life in some of the tributaries, sometimes for multiple pesticides in one sample. Identifying the sources of pesticides detected in the Clackamas River Basin is difficult because of the diverse land use in the basin and the multiple-use nature of many of the pesticides detected. Of the 25 parent compounds detected, 22 have agricultural uses, 23 have urban uses, 16 are applied to golf courses, 11 are applied along roads and other right-of-ways, and 5 have or had forestry applications. Because only a small fraction of the thousands of pesticide products registered for use in Oregon were tested for in this study, future monitoring could benefit from knowledge of what pesticides are applied so that potential problems can be identified and managed.

Water-Resources Investigations Report↗

Gallium

Gallium is a soft, silvery metallic element with an atomic number of 31 and the chemical symbol Ga. Gallium is used in a wide variety of products that have microelectronic components containing either gallium arsenide (GaAs) or gallium nitride (GaN). GaAs is able to change electricity directly into laser light and is used in the manufacture of optoelectronic devices (laser diodes, light-emitting diodes [LEDs], photo detectors, and solar cells), which are important for aerospace and telecommunications applications and industrial and medical equipment. GaAs is also used in the production of highly specialized integrated circuits, semiconductors, and transistors; these are necessary for defense applications and high-performance computers. For example, cell phones with advanced personal computer-like functionality (smartphones) use GaAs-rich semiconductor components. GaN is used principally in the manufacture of LEDs and laser diodes, power electronics, and radio-frequency electronics. Because GaN power transistors operate at higher voltages and with a higher power density than GaAs devices, the uses for advanced GaN-based products are expected to increase in the future. Gallium technologies also have large power-handling capabilities and are used for cable television transmission, commercial wireless infrastructure, power electronics, and satellites. Gallium is also used for such familiar applications as screen backlighting for computer notebooks, flat-screen televisions, and desktop computer monitors. Gallium is dispersed in small amounts in many minerals and rocks where it substitutes for elements of similar size and charge, such as aluminum and zinc. For example, gallium is found in small amounts (about 50 parts per million) in such aluminum-bearing minerals as diaspore-boehmite and gibbsite, which form bauxite deposits, and in the zinc-sulfide mineral sphalerite, which is found in many mineral deposits. At the present time, gallium metal is derived mainly as a byproduct of the processing of bauxite ore for aluminum; lesser amounts of gallium metal are produced from the processing of sphalerite ore from three types of deposits (sediment-hosted, Mississippi Valley-type, and volcanogenic massive sulfide) for zinc. The United States is expected to meet its current and expected future needs for gallium through imports of primary, recycled, and refined gallium, as well as through domestic production of recycled and refined gallium. The U.S. Geological Survey estimates that world resources of gallium in bauxite exceed 1 billion kilograms, and a considerable quantity of gallium could be present in world zinc reserves.

Professional Paper↗

Boulder train of silicified paleozoic wood, southeastern Massachusetts

Pebbles of silicified gymnospermous wood occur widely in the drift of southeastern Massachusetts. An investigation of the distribution of these pebbles shows the bedrock source of the wood to be tuffaceous beds that apparently overlie older granite in the Middleboro-Plympton area, Massachusetts, and are at the base of the Carboniferous rocks of the Narragansett Basin. A second center of distribution of the wood may lie offshore, north of Cape Cod. It is estimated that many thousands of large logs were broken up and carried away from the outcrop by Pleistocene ice sheets in the production of the boulder train. © 1964, The Geological Society of America, Inc.

Massachusetts↗

Pimienta-Tamabra(!)— A giant supercharged petroleum system in the southern Gulf of Mexico, onshore and offshore Mexico

Pimienta-Tamabra(!) is a giant supercharged petroleum system in the southern Gulf of Mexico with cumulative production and total reserves of 66.3 billion barrels of oil and 103.7 tcf of natural gas, or 83.6 billion barrels of oil equivalent (BOE). The effectiveness of this system results largely from the widespread distribution of good to excellent thermally mature, Upper Jurassic source rock underlying numerous stratigraphic and structural traps that contain excellent carbonate reservoirs. Expulsion of oil and gas as a supercritical fluid from Upper Jurassic source rock occurred when the thickness of overburden rock exceeded 5 km. This burial event started in the Eocene, culminated in the Miocene, and continues to a lesser extent today. The expelled hydrocarbons started migrating laterally and then upward as a gas-saturated 35-40° API oil with less than 1 wt.% sulfur and a gas-to-oil ratio (GOR) of 500-1000 ft 3 /BO. The generation-accumulation efficiency is about 6%.

southern Gulf of Mexico↗

Limestone - A Crucial and Versatile Industrial Mineral Commodity

Limestone, as used by the minerals industry, is any rock composed mostly of calcium carbonate (CaCO3). Although limestone is common in many parts of the United States, it is critically absent from some. Limestone is used to produce Portland cement, as aggregate in concrete and asphalt, and in an enormous array of other products, making it a truly versatile commodity. Portland cement is essential to the building industry, but despite our Nation's abundance of limestone, there have been cement shortages in recent years. These have been caused in part by a need to find new areas suitable for quarrying operations. To help manage our Nation's resources of such essential mineral commodities, the U.S. Geological Survey (USGS) provides crucial data and scientific information to industry, policymakers, and the public.

Fact Sheet↗

Hydrogeologic framework and geochemistry of the intermediate aquifer system in parts of Charlotte, De Soto, and Sarasota counties, Florida

The hydrogeologic framework underlying the 600-square-mile study area in Charlotte, De Soto, and Sarasota Counties, Florida, consists of the surficial aquifer system, the intermediate aquifer system, and the Upper Floridan aquifer. The hydrogeologic framework and the geochemical processes controlling ground-water composition were evaluated for the study area. Particular emphasis was given to the analysis of hydrogeologic and geochemical data for the intermediate aquifer system. Flow regimes are not well understood in the intermediate aquifer system; therefore, hydrogeologic and geochemical information were used to evaluate connections between permeable zones within the intermediate aquifer system and between overlying and underlying aquifer systems. Knowledge of these connections will ultimately help to protect ground-water quality in the intermediate aquifer system. The hydrogeology was interpreted from lithologic and geophysical logs, water levels, hydraulic properties, and water quality from six separate well sites. Water-quality samples were collected from wells located along six ground-water flow paths and finished at different depth intervals. The selection of flow paths was based on current potentiometric-surface maps. Ground-water samples were analyzed for major ions; field parameters (temperature, pH, specific conductance, and alkalinity); stable isotopes (deuterium, oxygen-18, and carbon-13); and radioactive isotopes (tritium and carbon-14). The surficial aquifer system is the uppermost aquifer, is unconfined, relatively thin, and consists of unconsolidated sand, shell, and limestone. The intermediate aquifer system underlies the surficial aquifer system and is composed of clastic sediments interbedded with carbonate rocks. The intermediate aquifer system is divided into three permeable zones, the Tamiami/Peace River zone (PZ1), the Upper Arcadia zone (PZ2), and the Lower Arcadia zone (PZ3). The Tamiami/Peace River zone (PZ1) is the uppermost zone and is the thinnest and generally, the least productive zone in the intermediate aquifer system. The Upper Arcadia zone (PZ2) is the middle zone and productivity is generally higher than the overlying permeable zone. The Lower Arcadia zone (PZ3) is the lowermost permeable zone and is the most productive zone in the intermediate aquifer system. The intermediate aquifer system is underlain by the Upper Floridan aquifer, which consists of a thick, stratified sequence of limestone and dolomite. The Upper Floridan aquifer is the most productive aquifer in the study area; however, its use is generally restricted because of poor water quality. Interbedded clays and fine-grained clastics separate the aquifer systems and permeable zones. The hydraulic properties of the three aquifer systems are spatially variable. Estimated trans-missivity and horizontal hydraulic conductivity varies from 752 to 32,900 feet squared per day and from 33 to 1,490 feet per day, respectively, for the surficial aquifer system; from 47 to 5,420 feet squared per day and from 2 to 102 feet per day, respectively, for the Tamiami/Peace River zone (PZ1); from 258 to 24,633 feet squared per day and from 2 to 14 feet per day, respectively, for the Upper Arcadia zone (PZ2); from 766 to 44,900 feet squared per day and from 10 to 201 feet per day, respectively, for the Lower Arcadia zone (PZ3); and from 2,350 to 7,640 feet squared per day and from 10 to 41 feet per day, respectively, for the Upper Floridan aquifer. Confining units separating the aquifer systems have leakance coefficients estimated to range from 2.3 x 10-5 to 5.6 x 10-3 feet per day per foot. Strata composing the confining unit separating the Upper Floridan aquifer from the intermediate aquifer system are substantially more permeable than confining units separating the permeable zones in the intermediate aquifer system or separating the surficial aquifer and intermediate aquifer systems. In Charlotte, Sarasota, and western De Soto Counties, hydraulic

Water-Resources Investigations Report↗

Palladium, platinum, and rhodium concentrations in mafic and ultramafic rocks from the Kizildag and Guleman areas, Turkey, and the Faryab and Esfandagheh-Abdasht areas, Iran

The Kizildag and Guleman areas, Turkey, and the Faryab and Esfandagheh-Abdasht areas, Iran, have produced chromite from ophiolite complexes consisting of harzburgite tectonite, dunite tectonite containing chromitite, pyroxenite, wehrlite, and gabbro. Forty-six samples from these complexes were analyzed in order to investigate the possibility of platinum-group metals being present that could be produced as byproducts. The results, however, indicate concentrations of palladium, platinum, and rhodium ranging up to 46 ppb (parts per billion), 55 ppb, and 24 ppb, respectively. The concentration levels and ratios of these metals are similar to other alpine ultramafic bodies that have been analyzed by modern analytical techniques. Ten samples from massive sulfide deposits in the Gunes and Ergani-Maden areas, Turkey, and the Sheikh Ali mine, Iran, were analyzed also. The results of the analysis suggests a low potential for byproduct palladium, platinum, and rhodium production in these ophiolite-associated massive sulfide deposits. The four ultramafic and mafic areas in Turkey and Iran under consideration have, and are, producing in 1978 chromite from podiform chromitites in alpine-type complexes. Because of the known association of chromitites and platinum-group metals, a collection of chromitites was made to check their palladium, platinum, and rhodium content to determine if economic concentrations might exist. Also, inasmuch as such rocks are thought to represent parts of the oceanic crust and upper mantle, data on platinum-group elements from these rocks can provide information to design geochemical models for the distribution of these elements. During the field excursions of the CENTO Working Group on Volcanic and Intrusive Rocks and Their Associated Ore Deposits, the Kizildag and Gunes areas, Turkey, were sampled in 1974 and the Guleman area, Turkey; Faryab and Esfandagheh-Abdasht areas, Iran, were sampled in 1975. In addition, samples of massive sulfide ores from the Ergani-Maden area, Turkey, were also collected for analysis, and the results included here. In this report the geologic framework of these areas is briefly examined as a background for interpreting the concentrations of palladium, platinum, and rhodium in the chromitites and ultramafic and mafic rocks. Comparisons of these analyses with analyses from other areas containing similar rocks show few differences in concentration or proportions of these three platinum-group metals.

Open-File Report↗

Radionuclides, trace elements, and radium residence in phosphogypsum of Jordan

Voluminous stockpiles of phosphogypsum (PG) generated during the wet process production of phosphoric acid are stored at many sites around the world and pose problems for their safe storage, disposal, or utilization. A major concern is the elevated concentration of long-lived 226Ra (half-life = 1,600 years) inherited from the processed phosphate rock. Knowledge of the abundance and mode-of-occurrence of radium (Ra) in PG is critical for accurate prediction of Ra leachability and radon (Rn) emanation, and for prediction of radiation-exposure pathways to workers and to the public. The mean (??SD) of 226Ra concentrations in ten samples of Jordan PG is 601 ?? 98 Bq/kg, which falls near the midrange of values reported for PG samples collected worldwide. Jordan PG generally shows no analytically significant enrichment (< 10%) of 226Ra in the finer (< 53 ??m) grain size fraction. Phosphogypsum samples collected from two industrial sites with different sources of phosphate rock feedstock show consistent differences in concentration of 226Ra and rare earth elements, and also consistent trends of enrichment in these elements with increasing age of PG. Water-insoluble residues from Jordan PG constitute <10% of PG mass but contain 30-65% of the 226Ra. 226Ra correlates closely with Ba in the water-insoluble residues. Uniformly tiny (< 10 ??m) grains of barite (barium sulfate) observed with scanning electron microscopy have crystal morphologies that indicate their formation during the wet process. Barite is a well-documented and efficient scavenger of Ra from solution and is also very insoluble in water and mineral acids. Radium-bearing barite in PG influences the environmental mobility of radium and the radiation-exposure pathways near PG stockpiles. ?? 2010 US Government.

Environmental Geochemistry and Health↗

Silt fraction heavy-mineral distributions in a lateritic environment: The rivers and insular shelf of north-central Puerto Rico

This fraction, which is enriched in heavy minerals relative to the sand fraction, is mainly detrital but contains a strong authigenic component. The authigenic silt heavy-mineral fraction is largely a product of the lateritic weathering and dominated by iron oxides and alterites. Grains of bladed rutile and leached ilmenite are common. Spatial variability in silt-fraction mineralogy is considerable. Within the Rio Cibuco system variability is related to compositional differences in rapidly eroding source rocks. On the shelf, silt heavy-mineral abundances are greatest at the river mouths and decrease seaward. Variability in the shelf samples is controlled primarily by source rivers and shelf sorting processes.

Puerto Rico↗

Summary of recent research in Long Valley Caldera, California

Since 1978, volcanic unrest in the form of earthquakes and ground deformation has persisted in the Long Valley caldera and adjacent parts of the Sierra Nevada. The papers in this special volume focus on periods of accelerated seismicity and deformation in 1980, 1983, 1989-1990, and 1997-1998 to delineate relations between geologic, tectonic, and hydrologic processes. The results distinguish between earthquake sequences that result from relaxation of existing stress accumulation through brittle failure and those in which brittle failure is driven by active intrusion. They also indicate that in addition to a relatively shallow (7-10-km) source beneath the resurgent dome, there exists a deeper (???15-km) source beneath the south moat. Analysis of microgravimety and deformation data indicates that the composition of the shallower source may involve a combination of silicic magma and hydrothermal fluid. Pressure and temperature fluctuations in wells have accompanied periods of crustal unrest, and additional pressure and temperature changes accompanying ongoing geothermal power production have resulted in land subsidence. The completion in 1998 of a 3000-m-deep drill hole on the resurgent dome has provided useful information on present and past periods of circulation of water at temperatures of 100-200??C within the crystalline basement rocks that underlie the post-caldera volcanics. The well is now being converted to a permanent geophysical monitoring station. ?? 2003 Elsevier B.V. All rights reserved.

Journal of Volcanology and Geothermal Research↗

Metalliferous deposits of the greater Helena mining region, Montana

The ore deposits described in this bulletin are distributed through a region of about 3,000 square miles surrounding the city of Helena, Mont. In general the surface of this region is mountainous, but it includes several large intermontane valleys. Large areas in the northern and eastern parts of the region sire underlain by sedimentary rocks of the Algonkian Belt series, and on the northeast and southwest the Belt rocks are overlain without any noticeable angular unconformity by Paleozoic and Mesozoic beds. Oligocene, Miocene, and possibly Pliocene sediments, composed chiefly of volcanic ash and land waste of local origin, occupy large areas in the intermontane valleys and lie unconformably upon Cretaceous and older rocks. A thin veneer of Pleistocene and Recent alluvium generally overspreads the Tertiary. In the extreme northern part of the region are large deposits of glacial drift that represent two stages of the Pleistocene. The principal igneous body of the region is the northern part of the early Tertiary or late Cretaceous Boulder batholitb of quartz monzonite. The main exposure of this body occupies an area of nearly 1,200 square miles and extends southward beyond the limits of the particular region considered. Smaller areas of similar rocks are clustered around this exposure. Most of the exposures probably represent bodies that are connected in depth to form a single mass. The late Cretaceous and older sedimentary rocks are involved in a series of northwestward-trending folds. Along the east side of the region overthrust faults related to the great Lewis overthrust of Glacier National Park cause Belt rocks to overlie rocks of Paleozoic and Mesozoic ages. Large normal faults occur near Marysville and faults of moderate displacement near Helena. The Tertiary beds are slightly deformed by folds and faults that are unrelated to the structure of the older rock. The geologic history of the region includes two contrasting periods, the earlier of which was characterized by the accumulation of marine sediments and the later by mountain building and erosion. The later period began with folding and elevation in late Cretaceous or early Eocene time, followed by overthrust faulting and the intrusion of the Boulder batholith. Next, there ensued a period of crustal stability, during which erosion reduced the region to a surface of low relief and cut away at least 10,000 feet of strata in the area north of Helena. In Oligocene, Miocene, and Pliocene (?) time sediments composed of land waste and volcanic ash were deposited, and this event was followed by warping and faulting that elevated the present mountains. During Pliocene and Pleistocene time the mountains were maturely dissected, and in middle and late Pleistocene time local glaciers formed in the higher mountains and large valley glaciers invaded the extreme northern part of the region. The ore deposits include lodes and placers that have yielded gold, silver, lead, copper, and zinc to a value of at least $176,860,000. The placers were formed mostly during interglacial stages of the Pleistocene. They have been almost entirely exhausted. Most of the lodes are classified as regards age in two groups, an older and a younger. The older lodes are related in origin to the Boulder batholith or some of the neighboring intrusive granitic bodies and were probably formed during early Eocene time. The younger lodes were formed after dacite of probable Miocene age was erupted. They are possibly related in origin to some unexposed intrusive granitic rock. For convenience in description the region is divided into three parts districts north of Helena, districts in the Belt Mountains, and districts south of Helena. The districts north of Helena include a 50-mile stretch of the Continental Divide that forms a broad ridge surmounted with considerable areas of flat or gently sloping surface at a general altitude of 7,000 feet. Narrow valleys 1,000 to 2,000 feet deep are cut into this surface and lead out to the neighboring wide intermontane valleys. The area is underlain mostly by shale, sandstone, and limestone of the upper part of the Belt series. Beds of Paleozoic and Mesozoic age occur south of the Belt area and extend from Helena west and northwest. The igneous rocks of the area include diorite and gabbro sills and dikes of probable Cretaceous age, extrusive andesite that is probably Oligocene or Miocene, and stocks of quartz monzonite, granodiorite, and quartz diorite, probably of Oligocene or Miocene age. The ore deposits of the northern districts are chiefly lodes that are valuable for gold and silver but contain some lead and copper. In the Ophir district bodies of gold and silver ore occur mainly in limestone near a body of quartz monzonite. In the Scratchgravel Hills and Grass Valley districts veins of gold quartz and veins containing lead-silver ore occur in quartz monzonite and in the adjoining metamorphic rocks. In the Austin district lodes containing gold; silver, lead, and copper are found in limestone near intrusive quartz monzonite. An unusual mineral in one of these lodes is corkite, a hydrous sulphate of lead containing arsenic. A small stock of quartz diorite in the Marysville district has invaded and domed Belt rocks. Marginal and radial fractures formed during the cooling and contraction of the igneous body became the receptacles of gold and silver veins, one of which, the Drumlummon, has produced $16,000,000. The veins filled open fractures and are characterized by a gangue of platy calcite and quartz. Lodes in Towsley Gulch in the western part of the district contain lead in addition to gold. In the Gould district a small stock of the granodiorite has invaded the Belt rocks and caused the deposition of veins similar to those near Marysville. In the Heddleston district lodes valuable for gold, silver, lead, and copper occur in Belt sedimentary rocks and diorite, some of them associated with porphyry dikes. In the Wolf Creek district veins in Belt rocks have produced copper ore composed mainly of chalcopyrite or chalcopyrite and tennantite accompanied by pyrite and a gangue of quartz and barite. Placer deposits along the western slope of the Belt Mountains have produced $17,500,000 in gold. Sapphires were formerly obtained from some of these deposits. The central part of the Belt Mountains is a plateaulike area considered to be the remnant of a surface produced by erosion during Tertiary time. This surface was elevated and has been deeply trenched by narrow, transverse valleys that are bordered with remnants of low terraces in which most of the placer deposits occur. Most of the western slope of the mountains is underlain by sedimentary rocks of the Belt series. At the foot of the mountains these give place to Paleozoic rocks, and these in turn are overlain unconformably in Townsend Valley by Tertiary and later deposits. The main structural feature is a great arch called the York anticline, which occupies most of the west side of the mountains. At the west foot of the mountains this fold is bordered by a series of small synclines that are tightly squeezed, faulted, and overturned as a result of pressure exerted from the west or southwest along a fracture described as the El Dorado overthrust On another fracture called1 the Scout Camp overthrust the Belt rocks composing the western slope of the mountains are thrust eastward over Paleozoic beds. Both faults are regarded as branches of the Lewis overthrust of Glacier Park. Igneous rocks that probably range in age from early Eocene to Pleistocene are widely but sparingly distributed.' They include sills and dikes of quartz dibrite, porphyry dikes, small stocks of quartz monzonite and quartz diorite, and surface flows of andesite and basalt. The deposits in the Belt Mountains that are of most interest at the present time are lodes that are chiefly valuable for gold. Most of them are found in the vicinity of York and Confederate Gulch. Nearly all are small quartz veins formed along fractures in diorite dikes and stocks or on bedding planes in the adjoining Belt sedimentary rocks. An exception is the Golden Messenger, a replacement deposit of large size but low grade, formed along fractures in a quartz diorite dike. Other veins in the same dike belong to the rather uncommon class called ladder veins. Many of the small veins contain shoots and bunches of rich ore in their upper parts. Downward- enrichment in gold is indicated to have occurred in some of the veins near York that lie below an old erosion surface. Elsewhere the origin of the placer deposits from erosion o'f the lodes during interglacial stages of the Pleistocene is indicated. Lodes containing chalcopyrite occupy tension fractures in the Belt shales that were produced by lateral movements of the mass composing the mountain front. In the districts south of Helena mining began with the discovery, on July 14, 1864, of rich placer deposits at the present site of the city of Helena, on Last Chance Creek. Since then the placer and lode deposits of these districts have produced metals worth $130,000,000 or more, of which about one-third was gold, the remainder chiefly lead and zinc. Sedimentary rocks ranging in age from Algonkian to Cretaceous underlie parts of the region, and other parts are underlain by a bedded series of andesite and latite tuffs, breccias, and flows. These rocks have been intruded and severely metamorphosed by the quartz monzonite of the Boulder batholith, the exposures of which occupy a large area. Rocks later than the intrusion of the batholith are chiefly a series of late Tertiary dacites and rhyolites. The placers of the southern districts have been almost entirely worked out. The lodes have yielded metals worth $111,600,000, but many of them are still productive. They include veins and contact-metamorphic deposits. Some of the contact deposits contain copper ore, and others contain iron ore valuable for fluxing. The veins are of two ages. The older veins have yielded most of the metallic production of the region. Their ores in general are heavy sulphide aggregates composed mainly of galena, sphalerite, and pyrite. Arsenopyrite is generally present; tetrahedrite and chalcopyrite are less common. Many of the veins are distinguished from the usual type of ore body by the occurrence of abundant tourmaline. The, metals produced are chiefly silver, lead, gold, and zinc, with some copper. The younger veins are essentially precious-metal deposits. They are mainly fissure veins but include some disseminated deposits of low grade. They are widely distributed and include several productive bodies. A distinguishing feature is the occurrence in the gangue of cryptocrystalline quartz and lamellar calcite. A dominant eastward trend of the vein fractures of the older group indicates them to be tension cracks in the crust block lying west of the Lewis overthrust that were produced by stretching in a direction at right angles to the thrust.

Montana↗

Mount Rainier volcanic hazard information

Introduction Eruptions at Mount Rainier produce lava flows, plumes of airborne volcanic ash, and avalanches of hot rock, ash, and gas—pyroclastic flows—that rush down the steep, ice-covered slopes of the volcano. Hot rock and ash ejected during an eruption can melt large quantities of snow and ice, forming huge, fast moving mudflows called lahars that travel 30+ miles, all the way to Puget Sound. Very large lahars can also form when weak and water-saturated rock high on the volcano collapses with or without volcanic activity. Learn more inside!

Washington↗

Economic filters for evaluating porphyry copper deposit resource assessments using grade-tonnage deposit models, with examples from the U.S. Geological Survey global mineral resource assessment: Chapter H in Global mineral resource assessment

An analysis of the amount and location of undiscovered mineral resources that are likely to be economically recoverable is important for assessing the long-term adequacy and availability of mineral supplies. This requires an economic evaluation of estimates of undiscovered resources generated by traditional resource assessments (Singer and Menzie, 2010). In this study, simplified engineering cost models were used to estimate the economic fraction of resources contained in undiscovered porphyry copper deposits, predicted in a global assessment of copper resources. The cost models of Camm (1991) were updated with a cost index to reflect increases in mining and milling costs since 1989. The updated cost models were used to perform an economic analysis of undiscovered resources estimated in porphyry copper deposits in six tracts located in North America. The assessment estimated undiscovered porphyry copper deposits within 1 kilometer of the land surface in three depth intervals. The results of the updated engineering cost model analysis for open-pit porphyry copper deposits are in agreement with the grade-tonnage boundary defining positive economic returns for copper deposits developed between 1989 and 2008. This correspondence demonstrates that the updated engineering cost equations are performing well and appear to be appropriate to evaluate the economic status of open-pit porphyry copper mines under current, and potentially future, economic conditions. Economic filters based on these simplified engineering cost models provide a method for estimating potential tonnages of undiscovered metals that may be economic in individual assessment areas. One implication of the economic filter results for undiscovered copper resources is that global copper supply will continue to be dominated by production from a small number of giant deposits. This domination of resource supply by a small number of producers may increase in the future, because an increasing proportion of new deposit discoveries are likely to occur in remote areas and be concealed deep beneath covering rock and sediments. Extensive mineral exploration activity will be required to meet future resource demand, because these deposits will be harder to find and more costly to mine than near-surface deposits located in more accessible areas. Relatively few of the new deposit discoveries in these high-cost settings will have sufficient tonnage and grade characteristics to assure positive economic returns on development and exploration costs.

Scientific Investigations Report↗

Emplacement of Holocene silicic lava flows and domes at Newberry, South Sister, and Medicine Lake volcanoes, California and Oregon

This field guide for the International Association of Volcanology and Chemistry of the Earth’s Interior (IAVCEI) Scientific Assembly 2017 focuses on Holocene glassy silicic lava flows and domes on three volcanoes in the Cascade Range in Oregon and California: Newberry, South Sister, and Medicine Lake volcanoes. Although obsidian-rich lava flows have been of interest to geologists, archaeologists, pumice miners, and rock hounds for more than a century, many of their emplacement characteristics had not been scientifically observed until two very recent eruptions in Chile. Even with the new observations, several eruptive processes discussed in this field trip guide can only be inferred from their final products. This makes for lively debates at outcrops, just as there have been in the literature for the past 30 years. Of the three volcanoes discussed in this field guide, one (South Sister) lies along the main axis defined by major peaks of the Cascade Range, whereas the other two lie in extensional tectonic settings east of the axis. These two tectonic environments influence volcano morphology and the magmatic and volcanic processes that form silicic lava flows and domes. The geomorphic and textural features of glass-rich extrusions provide many clues about their emplacement and the magma bodies that fed them. The scope of this field guide does not include a full geologic history or comprehensive explanation of hazards associated with a particular volcano or volcanic field. The geochemistry, petrology, tectonics, and eruption history of Newberry, South Sister, and Medicine Lake volcanic centers have been extensively studied and are discussed on other field excursions. Instead, we seek to explore the structural, textural, and geochemical evolution of well-preserved individual lava flows—the goal is to understand the geologic processes, rather than the development, of a specific volcano.

California, Oregon↗

Recycling of water, carbon, and sulfur during subduction of serpentinites: A stable isotope study of Cerro del Almirez, Spain

We use the concentrations and isotope compositions of water, carbon, and sulfur in serpentinites and their dehydration products to trace the cycling of volatiles during subduction. Antigorite serpentinites from the Cerro del Almirez complex, Spain, contain 9–12 wt.% H2O and 910 ± 730 ppm sulfur, and have bulk δ18O values of 8.6 ± 0.4‰, δD = − 54 ± 5‰, and δ34S = 5.0‰, consistent with serpentinization at temperatures of ~ 200 °C by seawater hydrothermal fluids in a seafloor setting. The serpentinites were dehydrated to chlorite–harzburgite (olivine + orthopyroxene + chlorite) at 700 °C and 1.6–1.9 GPa during subduction metamorphism, resulting in loss of water, and sulfur. The chlorite–harzburgites contain 5.7 ± 1.9 wt.% H2O, and have bulk δ18O = 8.0 ± 0.9‰, and δD = − 77 ± 11‰. The rocks contain 650 ± 620 ppm sulfur having δ34S = 1.2‰. Dehydration of serpentinite resulted in loss of 5 wt.% H2O having δ18O = 8–10‰ and δD = − 27 to − 65‰, and loss of 260 ppm sulfur as sulfate, having δ34S = 14.5‰. The contents and δ13C of total carbon in the two rock types overlap, with a broad trend of decreasing carbon contents and δ13C from ~ 1300 to 200 ppm and − 9.6 to − 20.2‰. This reflects mixing between reduced carbon in the rocks (210 ppm, δ13C ≈ − 26‰) and seawater-derived carbonate (δ13C ≈ − 1‰). Our results indicate: 1) Serpentinized oceanic peridotites carry significant amounts of isotopically fractionated water, carbon and sulfur into subduction zones; 2) Subduction of serpentinites to high P and T results in loss of water, and sulfur, which can induce melting and contribute to 18O, D, and 34S enrichments and oxidation of the sub-arc mantle wedge; and 3) Isotopically fractionated water, carbon, and sulfur in serpentinite dehydration products are recycled deeper into the mantle where they can contribute to isotope heterogeneities and may be significant for volatile budgets of the deep Earth.

Cerro Del Almirez;Betic Cordillera In Southern Spa↗