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Geologic implications of gas hydrates in the offshore of India: results of the National Gas Hydrate Program Expedition 01

The Indian National Gas Hydrate Program Expedition 01 (NGHP-01) is designed to study the occurrence of gas hydrate along the passive continental margin of the Indian Peninsula and in the Andaman convergent margin, with special emphasis on understanding the geologic and geochemical controls on the occurrence of gas hydrate in these two diverse settings. The NGHP-01 expedition established the presence of gas hydrates in the Krishna-Godavari and Mahanadi Basins, and the Andaman Sea. The expedition discovered in the Krishna-Godavari Basin one of the thickest gas hydrate accumulations ever documented, in the Andaman Sea one of the thickest and deepest gas hydrate stability zones in the world, and established the existence of a fully developed gas hydrate petroleum system in all three basins. The primary goal of NGHP-01 was to conduct scientific ocean drilling/coring, logging, and analytical activities to assess the geologic occurrence, regional context, and characteristics of gas hydrate deposits along the continental margins of India. This was done in order to meet the long-term goal of exploiting gas hydrate as a potential energy resource in a cost effective and safe manner. During its 113.5-day voyage, the D/V JOIDES Resolution cored and/or drilled 39 holes at 21 sites (1 site in Kerala-Konkan, 15 sites in Krishna-Godavari, 4 sites in Mahanadi, and 1 site in the Andaman deep offshore area), penetrated more than 9250 m of sedimentary section, and recovered nearly 2850 m of core. Twelve holes were logged with logging-while-drilling (LWD) tools and an additional 13 holes were wireline logged. The science team utilized extensive on-board laboratory facilities to examine and prepare preliminary reports on the physical properties, geochemistry, and sedimentology of all the data collected prior to the end of the expedition. Samples were also analyzed in additional post-expedition shore-based studies conducted in leading laboratories around the world. One of the specific objectives of this expedition was to test gas hydrate formation models and constrain model parameters, especially those that account for the formation of concentrated gas hydrate accumulations. The necessary data for characterizing the occurrence of in situ gas hydrate, such as interstitial water chlorinities, core-derived gas chemistry, physical and sedimentological properties, thermal images of the recovered cores, and downhole measured logging data (LWD and/or conventional wireline log data), were obtained from most of the drill sites established during NGHP-01. Almost all of the drill sites yielded evidence for the occurrence of gas hydrate; however, the inferred in situ concentration of gas hydrate varied substantially from site to site. For the most part, the interpretation of downhole logging data, core thermal images, interstitial water analyses, and pressure core images from the sites drilled during NGHP-01 indicate that the occurrence of concentrated gas hydrate is mostly associated with the presence of fractures in the sediments, and in some limited cases, by coarser grained (mostly sand-rich) sediments.

Marine and Petroleum Geology↗

Oxygen isotopes in nitrite: Analysis, calibration, and equilibration

Nitrite is a central intermediate in the nitrogen cycle and can persist in significant concentrations in ocean waters, sediment pore waters, and terrestrial groundwaters. To fully interpret the effect of microbial processes on nitrate (NO 3 - ), nitrite (NO 2 - ), and nitrous oxide (N 2 O) cycling in these systems, the nitrite pool must be accessible to isotopic analysis. Furthermore, because nitrite interferes with most methods of nitrate isotopic analysis, accurate isotopic analysis of nitrite is essential for correct measurement of nitrate isotopes in a sample that contains nitrite. In this study, nitrite salts with varying oxygen isotopic compositions were prepared and calibrated and then used to test the denitrifier method for nitrite oxygen isotopic analysis. The oxygen isotopic fractionation during nitrite reduction to N 2 O by Pseudomonas aureofaciens was lower than for nitrate conversion to N 2 O, while oxygen isotopic exchange between nitrite and water during the reaction was similar. These results enable the extension of the denitrifier method to oxygen isotopic analysis of nitrite (in the absence of nitrate) and correction of nitrate isotopes for the presence of nitrite in “mixed” samples. We tested storage conditions for seawater and freshwater samples that contain nitrite and provide recommendations for accurate oxygen isotopic analysis of nitrite by any method. Finally, we report preliminary results on the equilibrium isotope effect between nitrite and water, which can play an important role in determining the oxygen isotopic value of nitrite where equilibration with water is significant.

Analytical Chemistry↗

Cooperative investigation of precision and accuracy in chemical analysis of silicate rocks

This is the preliminary report of the first extensive program ever organized to study the analysis of igneous rocks, a study sponsored by the United States Geological Survey, the Massachusetts Institute of Technology, and the Geophysical Laboratory of the Carnegie Institution of Washington. Large samples of two typical igneous rocks, a granite and a diabase, were carefully prepared and divided. Small samples (about 70 grams) of each were sent to 25 rock-analysis laboratories throughout the world; analyses of one or both samples were reported by 34 analysts in these laboratories. The results, which showed rather large discrepancies, are presented in histograms. The great discordance in results reflects the present unsatisfactory state of rock analysis. It is hoped that the ultimate establishment of standard samples and procedures will contribute to the improvement of quality of analyses. The two rock samples have also been thoroughly studied spectrographically and petrographically. Detailed reports of all the studies will be published.

Analytical Chemistry↗

Water‐level fluctuations caused by Montana earthquake

The major earthquake of August 17, 1959, near the Montana‐Wyoming border had marked effects on water levels and artesian pressures in wells throughout the United States. Preliminary reports from field offices of the U. S. Geological Survey in 21 states show that water‐level fluctuations were automatically recorded in 136 observation wells. These wells for which records are available, and the maximum double amplitude of the fluctuations, are listed in Table 1.

Eos, Transactions, American Geophysical Union↗

Palæomagnetism of Hawaiian lava flows

PALÆOMAGNETIC investigations of volcanic rocks extruded in various parts of the world during the past several million years have generally revealed a younger sequence of lava flows magnetized nearly parallel to the field of a theoretical geocentric axial dipole, underlain by a sequence of older flows with exactly the opposite direction of remanent magnetization. A 180-degree reversal of the geomagnetic field, occurring near the middle of the Pleistocene epoch, has been inferred by many workers from such results 1–3 . This is a preliminary report of an investigation of 755 oriented samples collected from 152 lava flows on the island of Hawaii, selected to represent as many stratigraphic horizons as possible. (Sampling details are indicated in Table 1.) This work was undertaken because Hawaii's numerous thick sequences of lava flows, previously mapped as Pliocene to Historic by Stearns and Macdonald 4 , and afterwards assigned ages ranging from later Tertiary to Recent, by Macdonald and Davis 5 , appeared to offer an ideal opportunity to examine the most recent reversal of Earth's field.

Nature↗

Observations of ocean circulation and sediment transport experiment offshore of Fire Island, NY

Researchers from the U.S. Geological Survey (USGS) Woods Hole Coastal and Marine Science Center (WHCMSC), in collaboration with Coastal Carolina University (CCU) and University of South Carolina (USC), conducted a scientific field study to investigate the ocean circulation and sediment transport processes offshore of Fire Island, NY. Although the physical processes along the entire linear extent of Fire Island (~50 km) are of interest to the project, one particular region of focus is at the western end of the island where offshore sand ridges out to depths of 20 m extend across the inner shelf and connect to the near-shore bar system. The primary objective was to measure the physical processes around the sand ridges, including circulation patterns, wave parameters, bottom stress, and suspended sediment. Transects of instrumentation were positioned along and across the crests and troughs of the ridge field. A site at the top of a ridge and a site at the bottom of an adjacent trough were each populated with two tripods designed to provide high-resolution measurements near the sea-bed to record sediment re-suspension events. Measurements at these two sites include near bottom velocity profiles, acoustic Doppler velocimeters, pressure, optical transmission and backscatter at high sampling rates. Other measurements include upward looking velocity profiles, temperature, salinity, sonar images and profiles, and sediment size classes. Five smaller tripods were deployed to complete lines alongshore and across shore over a 5 km area to provide a regional picture. These tripods recorded upward looking velocity profiles and near bottom temperature, pressure and salinity. Surface buoys marked the position of the tripods and collected surface measurements at six of the sites. One buoy gathered meteorological measurements. The sites were occupied from January to April, 2012. This deployment was similar to previous efforts off Cape Hatteras, NC, in 2009, and is part of an ongoing effort to understand regional patterns in circulation and sediment transport and the interaction of inner shelf and near shore processes. New instrumentation for the USGS was introduced, including a variety of current and wave measurement equipment, acquisition and telemetry in near-realtime of the weather data, time series sonar imaging equipment, and anti-fouling wipers. Preliminary results suggest a complex and subtle relationship between wind and across shore current velocity in this region, and a more straightforward relationship between winds and alongshore currents. This paper also includes a preliminary report on the effectiveness of new measurement techniques used during this experiment.

New York↗

Blood parasites of birds of the District of Columbia and Patuxent Research Refuge vicinity

Recently a number of surveys of blood parasites of birds have been made in different parts of this country by different workers, the general purpose of which was to further the knowledge of the distribution and pathogenicity of these protozoa. This paper treats the distribution of parasites found in sampling miscellaneous birds of the District of Columbia and vicinity and contains a preliminary report on the more important phase of the problem of pathogenicity.

Maryland↗

Hydrocarbons in sediment of the Weddell Sea, Antarctica

Heavy hydrocarbons (about C15+) are ubiquitous but minor components in sediment from three sites (692, 693, and 694) drilled during Ocean Drilling Program (ODP) Leg 113. This preliminary report is the first to describe the distribution of some of these hydrocarbons in sediment of the Weddell Sea. Samples from Sites 692 and 693, located on a mid-slope bench along the margin of Queen Maud Land, span a time interval from Early Cretaceous to Pleistocene. In samples from the Tertiary portion of the record, having an average organic-carbon content of about 0.2%, n-alkanes are common and are characterized by populations that indicate both marine and terrigenous sources. In contrast, samples from the Cretaceous portion of the record, having an average organic carbon content of about 4%, contain mixtures of hydrocarbons in which n-alkanes are secondary in abundance to the isoprenoid hydrocarbons, pristane and phytane. Diasterenes, sterenes, and hopenes are present in anomalously high concentrations and indicate immaturity. The Cretaceous hydrocarbons appear to be mainly primary, whereas the Tertiary hydrocarbons contain compounds which indicate that the sediment, along with its organic content, has been recycled. Samples from Site 694, located in the Weddell Sea on the abyssal plain, range in age from late Miocene to early Pliocene.

Proceedings of the Ocean Drilling Program: Scienti↗

Altitudes between Lake Superior and the Rocky Mountains

In the survey of Lake Agassiz, a preliminary report of which forms Bulletin No. 39, it was found necessary to ascertain the altitudes determined within its area by railroad surveys as the basis for leveling along the shore lines of that glacial lake, and learning their relations in height to each other, to the great lakes of the St. Lawrence and Nelson Rivers, and to the ocean. From the time of the first observations and description of the upper beaches of Lake Agassiz by the author in 1879 and 1881, for the Geological Survey of Minnesota, and especially since the work was extended in 1885, under the U. S. Geological Survey, to include both sides of this lacustrine area in Minnesota and North Dakota now drained by the Red River of the North, much attention has been given to this collection of altitudes, and to the means of referring them to the sea level. The greater part of Lake Agassiz, however, was in Manitoba and adjacent British Territory, stretching north to the Saskatchewan; and in 1887, jointly for the Geological Surveys of the United States and of Canada, the author continued his examination of the beaches and deltas on the west side of the lake along a distance of a hundred miles north from the international boundary, across the prairie region of southwestern Manitoba, the leveling in this work being based on the altitudes of the Canadian Pacific Railway and its branches and connecting railways.

Bulletin↗

Stratigraphic sections of the Phosphoria formation in Idaho, 1949, part 1

The U. S. Geological Survey has recently measured and sampled the Phosphoria formation at many localities in Idaho and other western states. These data. will not be fully synthesized and analyzed for several years, but segments of the data, accompanied by little or no interpretation, are published as preliminary reports as they are assembled. This report, which contains abstracts -of many of the sections measured in southeastern Idaho (fig. 1), is one of this series and is the fourth report on Idaho; it includes about half the data gathered in Idaho in 1949. The field and laboratory procedures adopted in these investigations are described rather fully in a previous report (McKelvey and others, 1953a).

Idaho↗

The Fire Clay and Whitesburg coals in the Hyden quadrangle, Leslie, Clay, and Perry Counties, Kentucky

This preliminary report on the coal in the Hyden quadrangle, Kentucky, presents data on two of the principal commercial coals. The Fire Clay is the most valuable commercial coal in the quadrangle, and locally the Whitesburg bed is of minable thickness. Special emphasis has been placed on determining the thickness, extent, composition, and structure of these beds, and on obtaining an accurate estimate of the coal reserves.

Kentucky↗

General hydrogeology of the aquifers of Mesozoic age, Upper Colorado River Basin - excluding the San Juan Basin - Colorado, Utah, Wyoming, and Arizona

The objective of the Upper Colorado Regional Aquifer Systems Analyses (RASA) project is to assess quantitatively the occurrence, movement, and availability of water stored in rock formations underlying the basin. This is one of a series of preliminary reports that describe what is currently known (1984) about the geometry and hydrologic properties of the aquifer systems, and the chemistry of the water in known or potential aquifers. This report provides the foundation needed for the assessment of the ground-water resources of the region. The report describes only part of the hydrologic system; that is, formations of Mesozoic age. Younger and older formations significant to the hydrologic system are described in other reports.

Arizona, Colorado, Utah, Wyoming↗

Manganese, iron, and barite deposits of the James River-Roanoke River district, Virginia

During the period 1940-1942 the United States Geological Survey made a geologic study of the manganese deposits of the James River-Roanoke River district, in the general vicinity of Lynchburg, Va. (fig. 1), as part of its program of strategic minerals investigations. This work was done by the writer and supervised by D. F. Hewett. John Rodgers and W. R. Wagner assisted during part of the project. In the course of the investigation, the geology was mapped over an area about 60 miles long and several miles wide, from Altavista on the Roanoke River northeast to Howardsville on the James River (fig. 2); and the mineral deposits-principally manganese, iron, and barite-were studied. After completion of the geologic studies, the writer participated in an exploration project conducted by the United States Bureau of Mines in the early summer of 1942 at five manganese deposits in the district. This preliminary report presents the essential information concerning the mineral deposits of the region in advance of the more comprehensive report on the geology and mineral deposits that will be published as a bulletin of the U.S. Geological Survey.

Virginia↗

Review of lignite resources of western Tennessee and the Jackson Purchase area, western Kentucky

Introduction: This review of the lignite deposits of western Tennessee and the Jackson Purchase area in western Kentucky (Fig. 1) is a preliminary report on part of the U.S. Geological Survey's National Coal Resource Assessment of the Gulf Coastal Plain Coal Province. Lignite deposits of western Kentucky and Tennessee are an extension of the Gulf Coastal Plain Coal Province (Cushing and others, 1964), and currently are not economic to mine. These deposits have not been extensively investigated or developed as an energy resource. This review includes a description of the geology of the lignite-bearing units, a discussion of the available coal quality data, and information on organic petrology. Palynological data for lignite samples collected in Kentucky and Tennessee as part of this work are presented in an Appendix.

Open-File Report↗

Information relevant to the U.S. Geological Survey assessment of the Middle Devonian Shale of the Appalachian Basin Province, 2011

The U.S. Geological Survey recently assessed the potential for natural gas resources in the Middle Devonian Marcellus Shale of the Appalachian Basin Province. The Marcellus Shale was assessed as a continuous gas accumulation using a methodology identical to that used in the assessment of shale and other continuous-type assessment units throughout the United States. This preliminary report provides some additional geologic information used in the Marcellus Shale assessment. The Appalachian Basin Province encompasses rocks of the Paleozoic passive margins, the foreland basins, and fold and thrust belts formed during several episodes in the Paleozoic. The Marcellus Shale is one of many marine shales deposited in the area that is now encompassed by the Appalachian Basin Province.

Appalachian Basin Province↗

Memorandum on the hydrology of the Johnson Creek area, Dover-Madbury, New Hampshire

Ground-water conditions in the Johnson Creek area (Dover-Madbury, N.H.) are described on pages 23-26 in "Preliminary report on the ground-water resources of part of the seacoast region of New Hampshire," by Edward Bradley, U.S. Geological Survey open-file report, 1955. A copy of those pages is attached as an appendix to this memorandum. The purpose of the present memorandum is to outline the hydrology of the Johnson Creek as now understood, with particular reference to stream-discharge characteristics and their relation to geologic and ground-water conditions.

New Hampshire↗