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Conflict minerals from the Democratic Republic of the Congo: global tantalum processing plants, a critical part of the tantalum supply chain

The U.S. Geological Survey (USGS) analyzes mineral and metal supply chains to identify and describe major components of mineral and metal material flows from ore extraction, through intermediate forms, to a final product. Supply chain analyses may be used (1) to identify risks to the United States associated with the supply of critical and strategic minerals and metals and (2) to provide greater supply chain transparency so that policymakers have the fact-based information needed to formulate public policy. This fact sheet focuses on the post-mining/pre-consumer-product part of the tantalum supply chain. The USGS National Minerals Information Center (NMIC) has been asked by governmental and non-governmental organizations to provide information about tantalum, tin, tungsten, and gold (collectively known as “3TG minerals”) processing facilities worldwide in response to U.S. legislation aimed at identifying and removing the supply chain links between the trade in these minerals and civil unrest in the Democratic Republic of the Congo and adjacent countries. Post-beneficiation processing plants (generally called smelters and refineries) for 3TG mineral ores and concentrates were identified by company and industry association representatives as being the link in the 3TG mineral supply chain through which these minerals can be traced to their source of origin (mine). The determination of the source of origin is critical to the development of a complete and transparent conflict-free mineral supply chain. Tungsten processing plants were the subject of the first fact sheet in this series published by USGS NMIC in August 2014. Background information about historical conditions and multinational stakeholders’ voluntary due diligence guidance for minerals from conflict-affected and high-risk areas is presented in the tungsten fact sheet. This fact sheet, the second in a series about 3TG minerals, focuses on the tantalum supply chain by listing selected processors that produced tantalum materials commercially worldwide during 2013–14. It does not provide any information regarding the sources of material processed in these facilities.

Fact Sheet↗

Nature’s Notebook-A tool for recording the timing of seasonal activity of plants and animals

Nature's Notebook is a customizable program used by individual observers and Federal Government partners to document patterns in phenology—the timing of seasonal activity of plants and animals over the course of the calendar year. The USA National Phenology Network (USA-NPN) established Nature's Notebook in 2009 to create a standard approach for collecting phenology data on plants and animals across the country. Currently, about half of the data are submitted by independent backyard observers at individual sites and half are submitted by groups of participants as part of a Local Phenology Program. With support from the U.S. Geological Survey, the USA-NPN collects, organizes, and shares data on phenology. This information aids decision making, scientific discovery, and the development of a broader understanding of phenology.

Fact Sheet↗

Flowering plants preferred by bees of the Prairie Pothole Region

Land managers have stressed the need for improved pollinator habitat on private and public lands of the Prairie Pothole Region. Understanding flowering plant preferences of pollinators will improve the cost-effectiveness of conservation seeding mixes. The purpose of this fact sheet is to assist conservation planners and producers with developing seed mixes by highlighting flowering plants that are preferred by honey bees and wild bees across a variety of grassland cover types in the Prairie Pothole Region.

Fact Sheet↗

Borehole geophysical logs at Naval Weapons Industrial Reserve Plant, Dallas, Texas

A shallow alluvial aquifer at the Naval Weapons Industrial Reserve Plant near Dallas, Texas, has been contaminated by organic solvents used in the fabrication and assembly of aircraft and aircraft parts. Natural gamma-ray and electromagnetic-induction borehole geophysical logs were obtained from 162 poly vinyl-chloride-cased wells at the plant and were integrated with existing lithologic data to improve site characterization of the subsurface alluvium. Software was developed for filtering and classifying the log data and for processing, analyzing, and creating graphical output of the digital data. The alluvium consists of mostly fine-grained low-permeability sediments; however for this study, the alluvium was classified into low, intermediate, and high clay-content sediments on the basis of the gamma-ray logs. The low clay-content sediments were interpreted as being relatively permeable, whereas the high clay-content sediments were interpreted as being relatively impermeable. Simple statistics were used to identify zones of potentially contaminated sediments on the basis of the gamma-ray log classifications and the electromagnetic-induction log conductivity data.

Texas↗

Simulation and Particle-Tracking Analysis of Selected Ground-Water Pumping Scenarios at Vogtle Electric Generation Plant, Burke County, Georgia

The source of ground water to production wells at Vogtle Electric Generation Plant (VEGP), a nuclear power plant in Burke County, Georgia, was simulated under existing (2002) and potential future pumping conditions using an existing U.S. Geological Survey (USGS) MODFLOW ground-water flow model of a 4,455-square-mile area in the Coastal Plain of Georgia and South Carolina. Simulation results for three steady-state pumping scenarios were compared to each other and to a 2002 Base Case condition. The pumping scenarios focused on pumping increases at VEGP resulting from projected future demands and the addition of two electrical-generating reactor units. Scenarios simulated pumping increases at VEGP ranging from 1.09 to 3.42 million gallons per day (Mgal/d), with one of the scenarios simulating the elimination of 5.3 Mgal/d of pumping at the Savannah River Site (SRS), a U.S. Department of Energy facility located across the Savannah River from VEGP. The largest simulated water-level changes at VEGP were for the scenario whereby pumping at the facility was more than tripled, resulting in drawdown exceeding 4-8 feet (ft) in the aquifers screened in the production wells. For the scenario that eliminated pumping at SRS, water-level rises of as much as 4-8 ft were simulated in the same aquifers at SRS. Results of MODFLOW simulations were analyzed using the USGS particle-tracking code MODPATH to determine the source of water and associated time of travel to VEGP production wells. For each of the scenarios, most of the recharge to VEGP wells originated in an upland area near the county line between Burke and Jefferson Counties, Georgia, with none of the recharge originating on SRS or elsewhere in South Carolina. An exception occurs for the scenario whereby pumping at VEGP was more than tripled. For this scenario, some of the recharge originates in an upland area in eastern Barnwell County, South Carolina. Simulated mean time of travel from recharge areas to VEGP wells for the Base Case and the three other pumping scenarios was between about 2,700 and 3,800 years, with some variation related to changes in head gradients because of pumping changes.

Georgia↗

Analysis of vertical flow during ambient and pumped conditions in four monitoring wells at the Pantex Plant, Carson County, Texas, July-September 2008

The Pantex Plant is a U.S. Department of Energy/National Nuclear Security Administration (USDOE/NNSA)-owned, contractor-operated facility managed by Babcock & Wilcox Technical Services Pantex, LLC (B&W Pantex) in Carson County, Texas, approximately 17 miles northeast of Amarillo. The U.S. Geological Survey, in cooperation with B&W Pantex through the USDOE/NNSA, made a series of flowmeter measurements and collected other borehole geophysical logs during July–September 2008 to analyze vertical flow in screened intervals of four selected monitoring wells (PTX01–1012, PTX06–1044, PTX06–1056, and PTX06–1068) at the Pantex Plant. Hydraulic properties (transmissivity values) of the section of High Plains (Ogallala) aquifer penetrated by the wells also were computed. Geophysical data were collected under ambient and pumped flow conditions in the four monitoring wells. Unusually large drawdowns occurred at two monitoring wells (PTX06–1044 and PTX06–1056) while the wells were pumped at relatively low rates. A decision was made to redevelop those wells, and logs were run again after redevelopment in the two monitoring wells. Logs collected in monitoring well PTX01–1012 during ambient conditions indicate a dynamic environment that probably was affected by pumping of nearby irrigation or public-supply wells. During pumping, downward vertical flow of 0.2 to 2.1 gallons per minute that occurred during ambient conditions was either reversed or reduced. During pumping, a gradual trend of more positive flowmeter values (upward flow) with distance up the well was observed. Estimated total transmissivity for four production zones identified from Flow–B numerical model results taken together was calculated to be about 3,100 feet squared per day. Logs collected in monitoring well PTX06–1044 during ambient conditions before redevelopment indicate a static environment with no flow. During pumping there was upward vertical flow at rates ranging from 0.1 to about 1.5 gallons per minute. During pumping, a gradual trend of more positive flowmeter values (upward flow) with distance up the well was observed. Estimated total transmissivity before redevelopment for five production zones identified from Flow–B numerical model results, and transmissivity values for each zone, are considered to be in error because of the lack of communication between the well and the aquifer before redevelopment. After redevelopment, logs for well PTX06–1044 during ambient conditions indicate a near-static environment with minimal downward flow. During pumping there was upward vertical flow at rates ranging from 0.5 to about 4.8 gallons per minute. During pumping, a gradual trend of more positive flowmeter values with distance up the well was observed. Estimated total transmissivity after redevelopment for the same five identified production zones taken together was calculated to be about 520 feet squared per day. Logs collected in monitoring well PTX06–1056 during ambient conditions before redevelopment indicate a static environment with no flow. During pumping there was upward vertical flow at rates ranging from 0.3 to about 1.5 gallons per minute. During pumping, a gradual trend of more positive flowmeter values (upward flow) with distance up the well was observed. Estimated total transmissivity before redevelopment for four production zones identified from Flow–B numerical model results taken together was calculated to be about 450 feet squared per day. After redevelopment, logs collected in monitoring well PTX06–1056 during ambient conditions indicate a near-static environment with no flow except for a very small amount of downward flow near the bottom of the well. During pumping there was upward vertical flow at rates ranging from 0.7 to about 2.9 gallons per minute. Estimated total transmissivity after redevelopment for five production zones identified from Flow–B numerical model results taken together was calculated to be about 330 feet squared per day. Logs collected in monitoring well PTX06–1068 during ambient conditions indicate a static environment with no flow. During pumping there was upward vertical flow at rates ranging from 0.4 to 4.8 gallons per minute. During pumping, a gradual trend of more positive flowmeter values (upward flow) with distance up the well was observed. Estimated total transmissivity for four production zones identified from Flow–B numerical model results taken together was calculated to be about 200 feet squared per day.

Open-File Report↗

Method description, quality assurance, environmental data, and other Information for analysis of pharmaceuticals in wastewater-treatment-plant effluents, streamwater, and reservoirs, 2004-2009

Abstract Wastewater-treatment-plant (WWTP) effluents are a demonstrated source of pharmaceuticals to the environment. During 2004-09, a study was conducted to identify pharmaceutical compounds in effluents from WWTPs (including two that receive substantial discharges from pharmaceutical formulation facilities), streamwater, and reservoirs. The methods used to determine and quantify concentrations of seven pharmaceuticals are described. In addition, the report includes information on pharmaceuticals formulated or potentially formulated at the two pharmaceutical formulation facilities that provide substantial discharge to two of the WWTPs, and potential limitations to these data are discussed. The analytical methods used to provide data on the seven pharmaceuticals (including opioids, muscle relaxants, and other pharmaceuticals) in filtered water samples also are described. Data are provided on method performance, including spike data, method detection limit results, and an estimation of precision. Quality-assurance data for sample collection and handling are included. Quantitative data are presented for the seven pharmaceuticals in water samples collected at WWTP discharge points, from streams, and at reservoirs. Occurrence data also are provided for 19 pharmaceuticals that were qualitatively identified. Flow data at selected WWTP and streams are presented. Between 2004-09, 35-38 effluent samples were collected from each of three WWTPs in New York and analyzed for seven pharmaceuticals. Two WWTPs (NY2 and NY3) receive substantial inflows (greater than 20 percent of plant flow) from pharmaceutical formulation facilities (PFF) and one (NY1) receives no PFF flow. Samples of effluents from 23 WWTPs across the United States were analyzed once for these pharmaceuticals as part of a national survey. Maximum pharmaceutical effluent concentrations for the national survey and NY1 effluent samples were generally less than 1 ug/L. Four pharmaceuticals (methadone, oxycodone, butalbital and metaxalone) in samples of NY3 effluent had median concentrations ranging from 3.4 to greater than 400 ug/L. Maximum concentrations of oxycodone (1,700 ug/L) and metaxalone (3,800 ug/L) in samples from NY3 effluent exceeded 1,000 ug/L. Three pharmaceuticals (butalbital, carisoprodol, and oxycodone) in samples of NY2 effluent had median concentrations ranging from 2 to 11 ug/L. These findings suggest that current 2 manufacturing practices at these PFFs can result in pharmaceutical concentrations from 10 to 1,000 times higher than those typically found in WWTP effluents.

Open-File Report↗

Predicting spread of invasive exotic plants into dewatered reservoirs after dam removal on the Elwha River, Olympic National Park, Washington

The National Park Service is planning to start the restoration of the Elwha River ecosystem in Olympic National Park by removing two high head dams beginning in 2011. The potential for dispersal of exotic plants into dewatered reservoirs following dam removal, which would inhibit restoration of native vegetation, is of great concern. We focused on predicting long-distance dispersal of invasive exotic plants rather than diffusive spread because local sources of invasive species have been surveyed. We included the long-distance dispersal vectors: wind, water, birds, beavers, ungulates, and users of roads and trails. Using information about the current distribution of invasive species from two surveys, various geographic information system techniques and models, and statistical methods, we identified high-priority areas for Park staff to treat prior to dam removal, and areas of the dewatered reservoirs at risk after dam removal.

Washington↗

Capacitively coupled resistivity survey of the levee surrounding the Omaha Public Power District Nebraska City Power Plant, June 2011

This report is a release of digital data from a capacitively coupled resistivity survey conducted on June 13, 2011, on the flood-protection levees surrounding the Omaha Public Power District Nebraska City power plant. The U.S. Geological Survey Crustal Geophysics and Geochemistry Science Center and the Nebraska Water Science Center performed the survey in response to a flood on the Missouri River. A single line of resistivity profiling was completed along the center line of the section of levee 573 that surrounds the power plant.

Open-File Report↗

Plant distributions in the southwestern United States; a scenario assessment of the modern-day and future distribution ranges of 166 Species

The authors developed spatial models of the predicted modern-day suitable habitat (SH) of 166 dominant and indicator plant species of the southwestern United States (herein referred to as the Southwest) and then conducted a coarse assessment of potential future changes in the distribution of their suitable habitat under three climate-change scenarios for two time periods. We used Maxent-based spatial modeling to predict the modern-day and future scenarios of SH for each species in an over 342-million-acre area encompassing all or parts of six states in the Southwest--Arizona, California, Colorado, Nevada, New Mexico, and Utah. Modern-day SH models were predicted by our using 26 annual and monthly average temperature and precipitation variables, averaged for the years 1971-2000. Future SH models were predicted for each species by our using six climate models based on application of the average of 16 General Circulation Models to Intergovernmental Panel on Climate Change emission scenarios B1, A1B, and A2 for two time periods, 2040 to 2069 and 2070 and 2100, referred to respectively as the 2050 and 2100 time periods. The assessment examined each species' vulnerability to loss of modern-day SH under future climate scenarios, potential to gain SH under future climate scenarios, and each species' estimated risk as a function of both vulnerability and potential gains. All 166 species were predicted to lose modern-day SH in the future climate change scenarios. In the 2050 time period, nearly 30 percent of the species lost 75 percent or more of their modern-day suitable habitat, 21 species gained more new SH than their modern-day SH, and 30 species gained less new SH than 25 percent of their modern-day SH. In the 2100 time period, nearly half of the species lost 75 percent or more of their modern-day SH, 28 species gained more new SH than their modern-day SH, and 34 gained less new SH than 25 percent of their modern-day SH. Using nine risk categories we found only two species were in the least risk category, while 20 species were in the highest risk category. The assessment showed that species respond independently to predicted climate change, suggesting that current plant assemblages may disassemble under predicted climate change scenarios. This report presents the results for each species in tables (Appendix A) and maps (14 for each species) in Appendix B.

Open-File Report↗

Population genomic surveys for six rare plant species in San Diego County, California

San Diego County is a hotspot of biodiversity, situated at the intersection of the Baja peninsula, the California floristic province, and the desert southwest. This hotspot is characterized by a high number of rare and endemic species, which persist alongside a major urban epicenter. San Diego County has implemented a strategic management plan that identifies species, based on low numbers of occurrences or high level of threat, for which management practices are recommended. In creating a management plan for rare species, it is important to strike a balance between preserving locally adapted traits and maintaining genetic diversity, as species’ ranges fluctuate in response to a changing climate and habitat fragmentation. This project, in partnership with the San Diego Natural History Museum, aims to provide a reference point for the current status of genetic diversity of rare plant species that will inform future preservation and restoration efforts. We focused on six threatened or endangered plant species: Acanthomintha ilicifolia , Baccharis vanessae , Chloropyron maritimum ssp. maritimum , Deinandra conjugens , Dicranostegia orcuttiana , and Monardella viminea . For each species, botanists from the San Diego Natural History Museum visited all known occurrences in San Diego County and collected leaf tissue for genetic and cytological analysis. We then developed a panel of genetic markers to estimate genetic diversity and population structure. This population genetic survey provided insight into the amount of genetic differentiation across each species’ range, identified isolated occurrences potentially subject to inbreeding or genetic bottlenecks, and identified areas that are rich sources of allelic diversity. Finally, we convened a panel of experts to review results and compatible management options for each species. A summary of the management workshop is included in this report. Overall, we found low genetic differentiation among occurrences across the San Diego region for all species, with the exception of A. ilicifolia . Relative inbreeding was low and consistent across sites, and genetic diversity across sites was variable, with noted exceptions. These findings allow for a wide array of management options that are compatible with panmictic population structure in five of the six surveyed species.

California↗

Hydrogeologic characterization of part of the Lower Floridan aquifer at the South District Wastewater Treatment Plant, Miami-Dade County, Florida

The South District Wastewater Treatment Plant in southeastern Miami-Dade County, Florida, includes a Class I treated wastewater injection well system. The detection of ammonia in monitoring zones above the injection zone in the Lower Floridan aquifer has elicited a need to understand the nature of confinement within the Lower Floridan aquifer as it pertains to the vertical migration of injectate out of the injection zone upward into the Underground Source of Drinking Water in the upper part of the Floridan aquifer system. Geologic and geophysical data, borehole video imagery, and aquifer performance data were used to refine and clarify the geologic and hydrogeologic frameworks of part of the Lower Floridan aquifer at the treatment plant. The data provide evidence for zones of enhanced dissolution permeability, extensive secondary porosity, fractures, karst collapse structures, and faults that could provide vertical cross-formational fluid pathways that transect the Lower Floridan aquifer.

Florida↗

Identification of potential wetlands in training areas on Ravenna Army Ammunition Plant, Ohio, and guidelines for their management

Potential wetlands in training areas on Ravenna Army Ammunition Plant, Ohio, were mapped by use of geographic information system (GIS) data layers and field inspection. The GIS data layers were compiled from existing sources and interpretation of aerial photography. Data layers used in the GIS analysis were wetland-plant communities, hydric soils, National Wetlands Inventory designated areas, and wet areas based on photogrammetry. According to review of these data layers, potential wetlands constitute almost one-third of the land in the training areas. A composite map of these four data layers was compiled for use during inspection of the training areas. Field inspection focused on the presence of hydrophytic vegetation and macroscopic evidences of wetland hydrology. Results of the field inspection were in general agreement with those predicted by the GIS analysis, except that some wet areas were more extensive than predicted because of high amounts of precipitation during critical periods of 1995 and 1996. Guidelines for managing wetlands in the training areas are presented.

Open-File Report↗

Characterization and modes of occurrence of elements in feed coal and coal combustion products from a power plant utilizing low-sulfur coal from the Powder River Basin, Wyoming

The U.S. Geological Survey and the University of Kentucky Center for Applied Energy Research are collaborating with an Indiana utility company to determine the physical and chemical properties of feed coal and coal combustion products from a coal-fired power plant. The Indiana power plant utilizes a low-sulfur (0.23 to 0.47 weight percent S) and lowash (4.9 to 6.3 weight percent ash) subbituminous coal from the Wyodak-Anderson coal zone in the Tongue River Member of the Paleocene Fort Union Formation, Powder River Basin, Wyoming. Based on scanning electron microscope and X-ray diffraction analyses of feed coal samples, two mineral suites were identified: (1) a primary or detrital suite consisting of quartz (including beta-form grains), biotite, feldspar, and minor zircon; and (2) a secondary authigenic mineral suite containing alumino-phosphates (crandallite and gorceixite), kaolinite, carbonates (calcite and dolomite), quartz, anatase, barite, and pyrite. The primary mineral suite is interpreted, in part, to be of volcanic origin, whereas the authigenic mineral suite is interpreted, in part, to be the result of the alteration of the volcanic minerals. The mineral suites have contributed to the higher amounts of barium, calcium, magnesium, phosphorus, sodium, strontium, and titanium in the Powder River Basin feed coals in comparison to eastern coals. X-ray diffraction analysis indicates that (1) fly ash is mostly aluminate glass, perovskite, lime, gehlenite, quartz, and phosphates with minor amounts of periclase, anhydrite, hematite, and spinel group minerals; and (2) bottom ash is predominantly quartz, plagioclase (albite and anorthite), pyroxene (augite and fassaite), rhodonite, and akermanite, and spinel group minerals. Microprobe and scanning electron microscope analyses of fly ash samples revealed quartz, zircon, and monazite, euhedral laths of corundum with merrillite, hematite, dendritic spinels/ferrites, wollastonite, and periclase. The abundant calcium and magnesium mineral phases in the fly ash are attributed to the presence of carbonate, clay, and phosphate minerals in the feed coal and their alteration to new phases during combustion. The amorphous diffraction-scattering maxima or glass 'hump' appears to reflect differences in chemical composition of fly ash and bottom ash glasses. In Wyodak-Anderson fly and bottom ashes, the center point of scattering maxima is due to calcium and magnesium content, whereas the glass 'hump' of eastern fly ash reflects variation in aluminum content. The calcium- and magnesium-rich and alumino-phosphate mineral phases in the coal combustion products can be attributed to volcanic minerals deposited in peat-forming mires. Dissolution and alteration of these detrital volcanic minerals occurred either in the peat-forming stage or during coalification and diagenesis, resulting in the authigenic mineral suite. The presence of free lime (CaO) in fly ash produced from Wyodak-Anderson coal acts as a self-contained 'scrubber' for SO3, where CaO + SO3 form anhydrite either during combustion or in the upper parts of the boiler. Considering the high lime content in the fly ash and the resulting hydration reactions after its contact with water, there is little evidence that major amounts of leachable metals are mobilized in the disposal or utilization of this fly ash.

Scientific Investigations Report↗

Evaluation of the Contributing Area for Recovery Wells at the Naval Industrial Reserve Ordnance Plant, Fridley, Minnesota

The Naval Industrial Reserve Ordnance Plant is located on the southernmost tip of Anoka County, Minnesota, within the City of Fridley, and about one-quarter mile east of the Mississippi River. Industrial production at the plant began in 1941 and has continued since that time. Contamination spills and poor disposal practices in the past have led to significant ground-water contamination beneath the facility. A ground-water recovery (and containment) system began operation in 1992 to prevent contaminated ground-water from migrating off site. In an effort to determine the effectiveness of the recovery system, pressure transducers were installed in 23 monitoring wells, multiple hand water-level measurements were taken in an additional 56 wells, and two extensive rounds of water-level measurements were taken in all wells (one during pumping and one during non-pumping conditions). The cones of depression of the shallow flow zone wells AT-8 (17 gallons per minute (gal/min) and AT-9 (142 gal/min) overlap to form one broad cone, while the cone of depression of well AT-7 (42 gal/min) was more isolated. Shallow flow zone well AT-5A (156 gal/min) had a large, broad cone of depression which was the result of the relatively high pumping rate and the relatively high permeability of 200 feet per day (ft/d). Intermediate flow zone well AT-3A (182 gal/min) had a broad cone of depression that extended to the intermediate clays; well AT-10 (23 gal/min) had a relatively steep cone because it was screened in a relatively low-permeability zone. Deep flow zone well AT-5B (86 gal/min) had a broad cone of depression. Intermediate well AT-3A appears to be drawing water up vertically out of the deep flow zone. The combined contributing areas of recovery wells AT-7, AT-8, and AT-9 capture the high levels of trichloroethene (TCE) contamination (greater than 100 parts per billion (ppb) along their combined axis. Well AT-5A has a broad contributing area that reaches approximately halfway to the Mississippi River and captures the eastern flank of the highest levels of contamination in the shallow zone; but it does not capture the highest levels that will still discharge to the Mississippi River. The combined contributing areas of wells AT-3A and AT-10 should capture the TCE contamination in the intermediate zone that is moving off site. Well AT-5B captures about a third of the TCE contamination in the deep flow zone where the concentration exceeds 100 ppb.

Scientific Investigations Report↗

The biogeochemistry and occurrence of unusual plant species inhabiting acidic, metal-rich water, Red Mountain, Bonnifield district, Alaska Range: Chapter J in Recent U.S. Geological Survey studies in the Tintina Gold Province, Alaska, United States, and Yukon, Canada--results of a 5-year project

This report presents results on the occurrence and biogeochemistry of unusual plant species, and of their supporting sediment, in an undisturbed volcanogenic massive sulfide deposit in the Tintina Gold Province (see fig. 1 of Editors’ Preface and Overview). The extraordinary plant assemblage found growing in the acidic metal-rich waters that drain the area is composed predominantly of bryophytes (liverworts and mosses). Ferricrete-cemented silty alluvial sediments within seeps and streams are covered with the liverwort Gymnocolea inflata, whereas the mosses Polytrichum commune and P. juniperinum inhabit the area adjacent to the water and within the splash zone. Both the liverwort-encrusted sediment and Polytrichum thalli have high concentrations of major- and trace-metal cations (for example, Al, As, Cu, Fe, Hg, La, Mn, Pb, and Zn). Soils in the area do not reflect the geochemical signature of the mineral deposit, and we suspect that they are most influenced by the chemistry of airborne dust (aeolian material) derived from outside the area.

Alaska;Yukon↗

Reconnaissance of contaminants in selected wastewater-treatment-plant effluent and stormwater runoff entering the Columbia River, Columbia River Basin, Washington and Oregon, 2008-10

Toxic contamination is a significant concern in the Columbia River Basin in Washington and Oregon. To help water managers and policy makers in decision making about future sampling efforts and toxic-reduction activities, a reconnaissance was done to assess contaminant concentrations directly contributed to the Columbia River through wastewater-treatment-plant (WWTP) effluent and stormwater runoff from adjacent urban environments and to evaluate instantaneous loadings to the Columbia River Basin from these inputs. Nine cities were selected in Oregon and Washington to provide diversity in physical setting, climate characteristics, and population density—Wenatchee, Richland, Umatilla, The Dalles, Hood River, Portland, Vancouver, St. Helens, and Longview. Samples were collected from a WWTP in each city and analyzed for anthropogenic organic compounds, pharmaceuticals, polychlorinated biphenyls (PCBs), polybrominated diphenyl ether (PBDEs [brominated flame-retardants]), organochlorine or legacy compounds, currently used pesticides, mercury, and estrogenicity. Of the 210 compounds analyzed in the WWTP-effluent samples, 112 (53 percent) were detected, and the detection rate for most compound classes was greater than 80 percent. Despite the differences in location, population, treatment type, and plant size, detection frequencies were similar for many of the compounds detected among the WWTPs. By contrast, the occurrence of polycyclic aromatic hydrocarbons (PAHs) was sporadic, and PCBs were detected at only three WWTPs. The stormwater-runoff samples were analyzed for a slightly different set of contaminants, with the focus on those expected to be related to road and land runoff—PCBs, PBDEs, organochlorine compounds, PAHs, currently used pesticides, trace elements, mercury, and oil and grease. A complex mixture of compounds was detected in stormwater runoff, with detections of 114 (58 percent) of the 195 compounds analyzed. The detection patterns and concentrations measured in the stormwater-runoff samples, however, were more heterogeneous than in the WWTP-effluent samples. This reflects differences in various factors, including suspended-sediment concentrations and known contamination sources present in some watersheds. Trace elements and PAHs, which are related to automobiles and impervious surfaces, were the most widespread compound classes detected in stormwater runoff, a typical finding in stormwater runoff in urban areas. With a better understanding of the presence of these contaminants in the environment, future work can focus on developing research to characterize the effects of these contaminants on aquatic life and prioritize toxic-reduction efforts for the Columbia River Basin.

Washington;Oregon↗

Effects of groundwater withdrawals associated with combined-cycle combustion turbine plants in west Tennessee and northern Mississippi

The Mississippi Embayment Regional Aquifer Study groundwater-flow model was used to simulate the potential effects on future groundwater withdrawals at five powerplant sites-Gleason, Weakley County, Tennessee; Tenaska, Haywood County, Tennessee; Jackson, Madison County, Tennessee; Southaven, DeSoto County, Mississippi; and Magnolia, Benton County, Mississippi. The scenario used in the simulation consisted of a 30-year average water-use period followed by a 30-day peak water-demand period. Effects of the powerplants on the aquifer system were evaluated by comparing the difference in simulated water levels in the aquifers at the end of the scenario (30 years plus 30 days) with and without the combined-cycle-plant withdrawals. Simulated potentiometric surface declines in source aquifers at potential combined-cycle-plant sites ranged from 56 feet in the upper Wilcox aquifer at the Magnolia site to 20 feet in the Memphis aquifer at the Tenaska site. The affected areas in the source aquifers at the sites delineated by the 4-foot potentiometric surface-decline contour ranged from 11,362 acres at Jackson to 535,143 acres at Southaven. The extent of areas affected by potentiometric surface declines was similar at the Gleason and Magnolia sites. The affected area at the Tenaska site was smaller than the affected areas at the other sites, most likely as a result of lower withdrawal rates and greater aquifer thickness. The extent of effect was smallest at the Jackson site, where the nearby Middle Fork Forked Deer River may act as a recharge boundary. Additionally, the Jackson site lies in the Memphis aquifer outcrop area where model-simulated recharge rates are higher than in areas where the Memphis aquifer underlies less permeable deposits. The potentiometric surface decline in aquifers overlying or underlying a source aquifer was generally 2 feet or less at all the sites except Gleason. At the Gleason site, withdrawals from the Memphis aquifer resulted in declines of as much as 9 feet in the underlying Fort Pillow aquifer. The simulated potentiometric surface change occurring in the Fort Pillow aquifer appears to be the result of leakage through the Flour Island Formation separating the Memphis and Fort Pillow aquifers where this confining unit is thin, sandy, or absent.

Arkansas;Kentucky;Mississippi;Missouri;Tennessee↗