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USGS2024

Land-use interactions, Oil-Field infrastructure, and natural processes control hydrocarbon and arsenic concentrations in groundwater, Poso Creek Oil Field, California, USA

Like many hydrocarbon production areas in the U.S., the Poso Creek Oil Field in California includes and is adjacent to other land uses (agricultural and other developed lands) that affect the hydrology and geochemistry of the aquifer overlying and adjacent to oil development. We hypothesize that the distributions of hydrocarbons and arsenic in groundwater in such areas will be controlled by complex interactions between mixed land uses, oil-field infrastructure, and natural processes. In 2020–2021, samples of groundwater and surface water were collected and analyzed for a large suite of inorganic and organic chemicals and isotope and gas tracers to test this hypothesis. Those data are supplemented with ancillary data on historical geochemistry, hydrology, geology, and oil-field infrastructure. Hydrocarbons in groundwater (e.g., methane through pentane gases and benzene) are associated with natural processes (e.g., fault offsets or transition in sediment depositional environment) and oil-field infrastructure (e.g., fluid-migration pathways associated with uncemented annulus in oil wells or unlined pits). Arsenic concentrations >10 μg per liter (μg/L; maximum concentration 12.9 μg/L) are associated with natural processes in old, high-pH groundwater, and more recent recharge of water from natural and/or engineered recharge processes. Along the southwest margin of the oil field, pumping for drinking-water and irrigation supplies in combination with engineered groundwater recharge produce a depression in groundwater elevations where groundwater with elevated sulfate concentrations from agricultural areas and groundwater with hydrocarbons from the oil field mix to produce a zone of sulfate reduction that removes hydrocarbons and arsenic from groundwater but produces elevated sulfide (S 2- ) concentrations (maximum concentration 29 mg per liter, mg/L). In this study, multiple approaches were required to resolve the overlapping effects of land uses, oil-field infrastructure, and natural processes on the distributions of hydrocarbons and arsenic in groundwater. The combined use of geographic, historical, physical, chemical, isotopic, and other information to constrain processes could be a useful approach for studies in other hydrocarbon-production areas. This is particularly important where land uses affect aquifer hydrology to an extent that causes mixing of groundwaters with different chemical compositions.

California↗

USGS2024

Simulation of groundwater flow and brine discharge to the Dolores River in the Paradox Valley, Montrose County, Colorado

Salinity, or total dissolved solids (TDS), of the Colorado River affects agricultural, municipal, and industrial water users and is an important concern in the Western United States. In the Paradox Valley of southwestern Colorado, natural discharge of sodium-chloride brine to the Dolores River from the underlying core of a salt-valley anticline accounts for about 6 percent of the salinity load to the Colorado River. Formation of the Paradox Valley began during the Miocene, and subsequent erosion exposed the Pennsylvania Paradox Formation in the core of the anticline where a cap rock, collapse features, breccia, and sodium-chloride saturated brine developed at the top of the exposed salt diapir. The discharge of brine to the Dolores River is affected by these dissolution features, along with seasonal hydrologic conditions and density-dependent flow between older dense brine and the younger fresh groundwater in the overlying alluvial aquifer. To reduce TDS concentrations in the Dolores River through the Paradox Valley, the Bureau of Reclamation has pumped brine from a series of shallow wells adjacent to the river since July 1996. The pumped brine is collected and piped to a deep disposal well where it is injected into the Mississippian Leadville Limestone at a depth of about 4,570-meters below land surface. The pumping and injection operation is collectively known as the Paradox Valley Unit (PVU), and by 2015, the PVU had substantially reduced TDS concentrations in the Dolores River by about 70 percent. Since 2019, injection-pressure limits and related seismic activity have constrained deep-well injection and thus brine pumping at the PVU. In cooperation with the Bureau of Reclamation, the U.S. Geological Survey developed a MODFLOW-6 three-dimensional, variable-density groundwater flow and TDS transport model of the Paradox Valley to evaluate the effects of PVU pumping operations on brine discharge to the Dolores River and to guide additional research. The finite-difference model grid consists of 76 rows and 48 columns oriented from northwest to southeast in alignment with valley topography and groundwater-flow directions in the near-surface freshwater alluvial aquifer. A 7-layer hydrogeologic framework was developed from existing datasets to represent the alluvial aquifer, cap rock, collapse breccia, and groundwater flow and TDS transport from the underlying Paradox Formation salt to the Dolores River. The model represents a 33-year transient calibration period from 1987 through 2020 that includes pre-PVU conditions from 1987 through June 1996 and post-PVU conditions from July 1996 through 2020. A 1,000-year simulation of groundwater flow and coupled TDS transport computed the initial conditions for the subsequent 33-year transient simulation. Observations of precipitation, streamflow, evaporation, agricultural land use, and PVU brine pumping rates were used to specify appropriate boundary conditions to the model representing time-varying recharge, tributary streamflow, groundwater underflow, evapotranspiration (ET), and PVU pumping. Values for average monthly streamflow and TDS concentration at the upstream streamgage, the Dolores River at Bedrock (USGS streamgage 09169500), were specified as model input where the Dolores River enters Paradox Valley. Observed pumping from the PVU, water levels and TDS concentrations in groundwater, and streamflow and estimated TDS concentrations at the downstream streamgage, the Dolores River near Bedrock (USGS streamgage 09171100), were calibration targets that constrained the manual calibration of model parameters representing aquifer hydraulic conductivity, storage, streambed conductance, recharge, and (ET). Two primary model-calibration targets were the match between observed and simulated TDS mass flux from PVU pumping wells and the match between estimated and simulated TDS mass flux to the Dolores River. The simulated TDS mass withdrawn by pumping wells is calculated by the model as the product of the assigned pumping rate and simulated groundwater TDS concentrations. Because actual pumping rates were assigned as simulated values, the total simulated PVU pumping for the 33-year calibration is within 0.5 percent of the observed values. However, simulated concentrations and thus mass flux of TDS withdrawn by the PVU pumping wells were consistently about 26 percent less than observed values for all the simulated time periods (33-year simulation, pre-PVU, and post-PVU). The representation of brine inflow was explored through additional modeling to evaluate the effect of the simulated brine source on groundwater TDS concentrations. Results indicated that a saturated-salt constant-flux brine source best replicated the magnitude and transient pattern observed for TDS mass flux from PVU pumping wells. The simulated TDS mass flux to the Dolores River is compared to estimates based on observed streamflow and specific conductance (SC) data for the downstream streamgage. The calibrated model provided a close fit of simulated to measured streamflow at the downstream streamgage, and the calibrated model fit to estimated TDS concentrations at the downstream streamgage was reasonable. The greatest differences between simulated and estimated values occurred during drought periods from June 2000 to March 2003, May 2012 to June 2013, and October 2013 to October 2014, when simulated TDS concentrations in the river were greater than estimated concentrations. In general, simulated TDS mass flux to the river for the pre-PVU period is in good agreement with estimated values (2-percent difference), but the model overestimated TDS mass flux to the river by about 41 percent during the post-PVU period. The model uncertainty with respect to TDS mass flux to the river indicates other processes or model parameters not well represented by the model are affecting the system, especially during drought. During model calibration, the most sensitive parameters were identified as vertical hydraulic conductivity of the alluvial aquifer, conductance of the Dolores River streambed, ET extinction depth and rate, and recharge rate. Five 5-year scenarios of conditions for 2021–25 were simulated to assist evaluation of alternative strategies to manage the discharge of brine into the Dolores River. The first scenario simulates no PVU pumping and serves as a base case for comparison to the other scenarios. Two scenarios simulate the effects of varying withdrawal timing at an annual rate about one-third less than during 2010 through 2018. During high-flow spring snowmelt runoff periods when brine discharge is naturally minimized, PVU pumping does not substantially affect salinity in the Dolores River, and comparison of these two scenarios indicates that scheduling brine withdrawals during times of low river stage is nearly as effective at reducing TDS mass flux to the river as pumping brine year-round. Cessation of pumping during periods of high river stage may be advantageous for system maintenance, brine injection, and seismic-risk reduction. The fourth scenario tested the effect of reducing irrigation-return flow on brine discharge and predicted a slight reduction of TDS mass flux to the Dolores River, but not as great a reduction as that of using the PVU to remove brine. The fifth scenario simulated 5 years of drought conditions without PVU pumping and indicates brine discharge during drought about 15 percent greater than during average hydrologic conditions. Results from scenario 5 are consistent with the calibrated model results and indicate that aquifer properties and ET processes and parameters may be affecting simulation results during drought. The Paradox Valley groundwater model provides a reasonable overall match to observed conditions in the Dolores River. The model is useful for evaluating relative differences between brine management scenarios to inform PVU operational decisions and to identify gaps in data and process understanding. Representation of the brine source, hydraulic-conductivity parameters, and recharge and ET processes were identified as potential areas for additional field and modeling research. Additional research in the Paradox Valley might include field-data collection that provides additional information on the hydrogeologic framework, groundwater levels, groundwater TDS concentrations, stream characteristics, and aquifer properties. Additional modeling efforts could benefit from applying advanced tools for model development, calibration, and visualization including parameter-estimation and sensitivity analysis. Statistical evaluation of known model uncertainties such as hydraulic conductivity, streambed conductance, representations of the brine source, recharge, and ET could improve the match between simulated and estimated TDS mass flux from PVU pumping wells and to the Dolores River further informing model predictions and system understanding for the Paradox Valley.

Colorado↗

USGS2024

New methodology for assessing underground natural gas storage resources – Example from Michigan Basin, United States

Energy consumption in the United States (U.S.) and across the world is shifting away from traditional fossil fuels like coal and oil, and towards natural gas and renewable sources, including hydrogen. Because gas demand is typically greatest during cold seasons and renewable sources sometimes produce variable supplies, it is important to store energy for use when demand exceeds supply. Whereas batteries and tanks typically store energy above ground, geologic (underground) storage may be able to retain much greater quantities of energy over much longer durations (e.g., Matos et al. 2019; Buursink et al. 2023). Consequently, the U.S. Geological Survey (USGS) is developing a methodology to locate new geologic energy storage sites with an initial focus on depleted hydrocarbon reservoirs followed by estimates of associated pore space or gas storage capacity. Depleted hydrocarbon fields in Michigan Basin in the U.S. already host large quantities of injected natural gas (about 681 billion cubic feet of seasonal gas capacity in 42 gas storage facilities; U.S. Energy Information Administration 2024). Therefore, we used this basin as an example to assess potential new storage resources alongside existing storage capacity and carbon dioxide sequestration resources (e.g., Katz and Coats 1968; Haagsma et al. 2020). In Michigan Basin gas storage is taking place in reservoirs within several key hydrocarbon producing formations with different lithologies, including the informal Stray sandstone of the Michigan Formation and the pinnacle reefs of the Niagara Group (Gautier et al. 1995; Swezey et al. 2015). The assessment methodology introduced here consists of two steps relying on both well information and reservoir data.

Michigan↗

USGS2025

Evolution of permeability and strength recovery of shear fracture under hydrothermal conditions

Geothermal energy is a clean and renewable resource that depends on the ability to move water through hot rock. In many locations, the ability to move water through rock requires the presence of extensive natural or human-made systems of fractures. However, these fracture systems are influenced by a variety of complex processes that occur at the temperature and pressure conditions found in geothermal reservoirs. To make geothermal systems more efficient, it is important to understand how these fractures evolve over time in response to these processes. This study explored how fractures in rock change under high-temperature and pressure conditions, like those found in geothermal reservoirs, through laboratory experiments and numerical simulations. In general fractures, tend to close due to pressure from the surrounding rock preventing the flow of water. One set of laboratory experiments revealed that fractures in granitic rock can weaken over time at elevated temperatures. These weak fractures can then slip slowly potentially keeping the fracture open for a longer period. This study also showed that at the highest temperature examined (250 °C) large differences between the chemical composition of the rock and the fluid moving through it could improve water flow temporarily likely due to the water dissolving parts of the rock. Flow rate predicted by models shows overall good agreement with the flow rate measured in our experiments but with some long time-scale variations that may be due to mechanical wear of the fracture surface. A second set of experiments found that, over the temperature range examined, the closure of fractures was caused by brittle failure driven by high stresses at points where fracture surfaces were in contact. This result suggests that fracture closure in geothermal reservoirs could be counteracted by maintaining high pore pressures. Additionally, we also tested a new method using electrical resistance to measure fracture closure in controlled systems with high precision.

Final Technical Report↗

USGS2026

Postglacial ecosystem development of a hydrothermal landscape in Yellowstone National Park

The Yellowstone geo-ecosystem has been the subject of much research, but the ecological history of the Yellowstone Plateau volcanic field and its iconic geyser basins is less known. In this investigation, paleoenvironmental analyses of sediment cores from lakes in Lower Geyser Basin were compared with regional records and paleoclimate model simulations to reconstruct the vegetation, wildfire, limnology, hydrothermal dynamics, and climate drivers since deglaciation, 15,000 to 14,000 years ago. Pollen data from Lower Geyser Basin lakes reveal the strong influence of infertile rhyolitic soils on vegetation history: an initial late-glacial steppe was replaced by lodgepole pine forest from 12.8 to 11.0 ka, with little change in forest composition or cover thereafter despite changing climate. This stability contrasts with the more dynamic vegetation response on nonrhyolite substrates in the Yellowstone region where nutrient and moisture availability is greater. Highest wildfire activity and low lake nutrient levels in Lower Geyser Basin occurred from 12 to 4 ka, when summers were substantially warmer and drier and fire-inducing vapor pressure deficits were 29 to 56% higher. The hydrothermal history, inferred from sedimentary arsenic and cesium abundances, was spatially and temporally variable but lake-forming hydrothermal events align with periods of abundant moisture. Thus, long-term changes in wildfire, limnology, and, to some extent, hydrothermal activity were governed by insolation-driven climate variations, whereas the vegetation response was muted and constrained by geologic processes. These findings suggest that warmer, drier conditions in the future could result in less hydrothermal activity yet little change in forest cover across the Yellowstone Plateau volcanic field despite more wildfires.

Idaho, Montana, Wyoming↗

USGS2024

Characteristics of the fault damage zone From high-resolution seismic imaging along the Palos Verdes Fault, California

The distribution and intensity of fault damage zones provides insight into fault activity and its relationship to fluid flow in the crust. Presently, measures of the in-situ distribution of fault damage remain limited and along-strike studies are rare. This study focuses on an offshore section Palos Verdes Fault damage zone that spans 28 km, near Los Angeles, California. To investigate the previously unresolved shallow (∼400 m below the seafloor) fault damage zone we use densely spaced (∼500 m line separation) newly collected sparker multichannel seismic lines and sub-bottom profiles. The combination of high-resolution acquisition methods and specialized seismic processing workflows provide improved imaging of shallow faulting. We apply a multi-trace similarity technique to identify discontinuities in the seismic data that may be attributed to faults and fractures. This fault detection approach reveals diverse fault damage patterns on adjacent seismic profiles. However, a discernible damage zone pattern emerges by stacking multiple damage detection profiles along strike. We find that peak damage identified in this way corresponds to the active main fault strand, confirmed in this study, and thus the technique may be useful for identifying active fault strands elsewhere. Additionally, we observe that the variable width of the damage zone along strike is controlled by fault obliquity. Furthermore, our observations reveal a correlation between fault damage and seafloor fluid seeps visible in the water column, suggesting that damage plays a role in controlling fluid flow around the fault.

California↗

USGS2021

New York and Landsat

From the iconic skyline of New York City to the forested landscapes of the Adirondack Mountains and the countryside of the Allegheny Plateau, the State of New York is overflowing with diversity and life. Bordered by the Atlantic Ocean on the east and two of the Great Lakes to the north and west, New York has more than 7,600 lakes, ponds, and reservoirs and more than 70,000 miles of rivers and streams. New York’s stewardship of its freshwater resources is fundamental to the health and well-being of all who work at, reside in, and visit the State’s landmarks and places. Harmful algal blooms in the State’s waterbodies are a growing concern and threaten the health of the region and its inhabitants. Images and data from Landsat satellites continue to provide critical information to scientists, public health officials, and resource managers who are studying the effects and risks of the problem.

New York↗

USGS1976

A comparison of electronic particle counting and pipette techniques in routine mud analysis

Electronic particle counting and pipette size-analysis techniques are compared for their relative effectiveness in large-scale routine mud analysis. Optimum laboratory procedures for conducting electronic analyses with a Model TA Coulter Counter are presented. Comparative electronic and pipette analyses conducted on the same samples resulted in equivalent precision for both techniques. Results of electronic analyses consistently showed size distributions significantly coarser than those obtained by pipette analyses. The laboratory efficiency of the relatively rapid electronic technique is far superior to that of the pipette technique, although more extensive precautionary measures are required to maintain a high level of analytical accuracy and precision. The quality of electronic analyses largely depends upon the effectiveness of standardized operational procedures established within the laboratory.

Open-File Report↗

USGS2026

Tringa flavipes (Lesser Yellowlegs) from separate breeding sites subdivides the Prairie Pothole Region in space and time during southbound migration

Some staging regions support multiple groups of the same migratory species, each of which may use the region differently. Characterizing the ways, in which separate groups use such regions can therefore help to identify vulnerabilities during this sensitive period of the annual cycle. The Prairie Pothole Region (PPR) is a massive wetland complex in the northern Great Plains of North America used by ∼11 million shorebirds during migration. The PPR has been heavily modified by agriculture and is experiencing varied effects of global climate change, threatening the health of the shorebirds that rely on it. Here, we used 6 seasons of southbound tracking data of Tringa flavipes (Lesser Yellowlegs)—a long-distance migratory shorebird species with an estimated population decline of 63% over the last 4 decades—from 9 sites across their breeding range to explore differences in migratory behavior within this important staging region. We found that 75% of tracked individuals used the region during southbound migration, and T. flavipes from different breeding sites detoured 110–875 km from their most direct migratory route to access the PPR. Individuals that arrived later stayed longer and made more stops within the region than those that arrived early. Individuals originating from different breeding sites also displayed spatial and temporal segregation within the region: T. flavipes from southwest and central Alaska relied heavily on the northwestern PPR, while those from Canada used the central and southeastern portions of the PPR. Finally, timing of use varied among groups, but the southeastern PPR became increasingly important over the course of the southbound migratory window, as other wetlands likely dried out. Our study highlights the portions of the PPR of critical importance to migrating T. flavipes and the diversity of ways, in which different groups from within the same species can use a single staging region.

Alaska, Manitoba, Northwest Territories, Ontario, ↗

USGS2026

Lunar analog study using portable gamma-ray neutron detector: Radiochemical mapping of silicic-to-basaltic volcanic terrains in the San Francisco Volcanic Field, Arizona

Studying lunar silicic volcanism provides key insights into the Moon’s crustal evolution, magmatic processes, and volcanic history. The Lunar-VISE (Lunar Vulkan Imaging and Spectroscopy Explorer) mission will investigate the Gruithuisen domes, a unique lunar region hypothesized to have formed through silicic volcanism. Using instruments on a Firefly Aerospace lander and a Honeybee Robotics rover, Lunar-VISE will analyze mineralogy, geochemistry, and surface properties to determine the origin and evolution of the domes, with a gamma-ray and neutron spectrometer (LV-GRNS) among its payload instruments. In preparation for this mission, we conducted preliminary fieldwork using a handheld gamma-ray neutron detector with NaI(Tl) and Cs LiYCl :Ce (CLYC) scintillators. This study focuses on various rhyolitic and basaltic volcanic centers in the San Francisco Volcanic Field (SFVF) near Flagstaff, Arizona—specifically Sugarloaf Peak, Bonito Lava Flow, and Robinson Mountain, a region containing several well-characterized lunar analog sites. The SFVF was selected for this study due to its broad compositional diversity spanning basaltic to rhyolitic compositions, its well-preserved volcanic morphologies, and its extensive use in previous NASA field campaigns and astronaut training exercises, making it an ideal terrestrial laboratory for testing planetary exploration techniques. We measured natural radioactivity, specifically from potassium (K), thorium (Th), and uranium (U) and other elements in their decay chains, which serve as diagnostic tracers of magmatic differentiation and crustal evolution processes, to assess geochemical variability across compositionally diverse terrains. The detector’s sensitivity was assessed across varying concentration levels. Regionally averaged concentrations of radioisotopes were determined by gamma-ray spectroscopy at selected sites. Our measurements reveal significant compositional variations between sites, with Sugarloaf Peak (rhyolitic, silicic dome) exhibiting the highest average radioisotope concentrations (K: 3.29 ± 0.24 wt%, U: 14.35 ± 1.81 ppm, Th: 27.14 ± 2.43 ppm), while Bonito Lava Flow (K: 1.13 ± 0.08 wt%, U: 3.86 ± 0.52 ppm, Th: 7.52 ± 1.02 ppm), and Robinson Mountain (K: 1.46 ± 0.16 wt%, U: 5.59 ± 1.06 ppm, Th: 11.75 ± 1.98 ppm) show lower concentrations aligned with basaltic compositions. Gamma-ray fluxes were elevated by a factor of approximately three to four at Sugarloaf Peak relative to nearby basaltic terrains, consistent with expected geochemical differentiation patterns. Furthermore, at meter scales, proximity to geological features significantly affects measurements. Th concentrations adjacent to a cliff face at Sugarloaf’s base were 28% higher than values measured 3-5 meters away from the same feature, demonstrating localized compositional heterogeneity. Analysis of station-by-station measurements reveals that K, U, and Th concentrations show an elevation trend at Robinson Mountain and generally higher concentrations near Sugarloaf Peak’s summit, suggesting progressive magmatic differentiation and/or the presence of more evolved lithologies at higher elevations. By mapping these elements on Earth using GRNS, we aim to optimize measurement techniques for Lunar-VISE and similar rover-borne missions by demonstrating the applicability of portable GRNS instruments for planetary surface exploration in an analog environment.

Arizona↗

USGS2025

Tapwater exposures, residential risk, and mitigation in a PFAS-impacted-groundwater community

Tapwater (TW) safety and sustainability are priorities in the United States. Per/polyfluoroalkyl substance(s) (PFAS) contamination is a growing public-health concern due to prolific use, widespread TW exposures, and mounting human-health concerns. Historically-rural, actively-urbanizing communities that rely on surficial-aquifer private wells incur elevated risks of unrecognized TW exposures, including PFAS, due to limited private-well monitoring and contaminant-source proliferation in urbanizing landscapes. Here, a broad-analytical-scope TW-assessment was conducted in a hydrologically-vulnerable, Mississippi River alluvial-island community, where PFAS contamination of the shallow-alluvial drinking-water aquifer has been documented, but more comprehensive contaminant characterization to inform decision-making is currently lacking. In 2021, we analyzed 510 organics, 34 inorganics, and 3 microbial groups in 11 residential and community locations to assess (1) TW risks beyond recognized PFAS issues, (2) day-to-day and year-to-year risk variability, and (3) suitability of the underlying sandstone aquifer as an alternative source to mitigate TW-PFAS exposures. Seventy-six organics and 25 inorganics were detected. Potential human-health risks of detected TW exposures were explored based on cumulative benchmark-based toxicity quotients ( ∑ TQ ). Elevated risks ( ∑ TQ ≥ 1) from organic and inorganic contaminants were observed in all alluvial-aquifer-sourced synoptic samples but not in sandstone-aquifer-sourced samples. Repeated sampling at 3 sites over 52–55 h indicated limited variability in risk over the short-term. Comparable PFAS-specific ∑ TQ for spatial-synoptic, short-term (3 days) temporal, and long-term (3 years quarterly) temporal samples indicated that synoptic results provided useful insight into the risks of TW-PFAS exposures at French Island over the long-term. No PFAS detections in sandstone-aquifer-sourced samples over a 3 year period indicated no PFAS-associated risk and supported the sandstone aquifer as an alternative drinking-water source to mitigate community TW-PFAS exposures. This study illustrated the importance of expanded contaminant monitoring of private-well TW, beyond known concerns (in this case, PFAS), to reduce the risks of a range of unrecognized contaminant exposures.

Wisconsin↗

USGS2024

Inset groundwater-flow models for the Cache and Grand Prairie Critical Groundwater Areas, northeastern Arkansas

The water resources in the Mississippi alluvial plain, located in parts of Missouri, Kentucky, Tennessee, Mississippi, Louisiana, and Arkansas, supports a multibillion-dollar agricultural industry that relies heavily on pumping of groundwater for irrigation of crops and aquaculture. The primary source of groundwater for agricultural-related pumping is the Mississippi River Valley alluvial aquifer, which has declined in storage for decades; secondary groundwater sources include the middle Claiborne aquifer and Wilcox aquifer system. Two areas in northeastern Arkansas that lie within the Mississippi alluvial plain, part of the Cache and Grand Prairie regions, have been designated as Critical Groundwater Areas owing to decades of groundwater declines that resulted from past and current water use. The multidisciplinary Mississippi Alluvial Plain project, led by the U.S. Geological Survey, and funded by their Water Availability and Use Science Program, included objectives to develop numerical groundwater models in focus regions, including the part of the Cache and Grand Prairie regions of northeastern Arkansas. Two inset models were developed using the child model capabilities of MODFLOW 6, the U.S. Geological Survey’s Modular Hydrologic Model simulation software. Both models, called the Cache model and Grand Prairie model, simulated the groundwater system and surface-water/groundwater interactions for the Mississippi River Valley alluvial aquifer and underlying Tertiary-age aquifers and confining units to the Midway confining unit. Each model was spatially discretized into 500-meter x 500-meter orthogonal cells on a grid with 5-meter constant-thickness vertical layers that represented the Mississippi River Valley alluvial aquifer and increasing thickness layers for the aquifers and confining units below the alluvial aquifer. The Cache and Grand Prairie models were calibrated with the PEST++ iterative ensemble smoother Version 5 and employed high dimensional parameterization schemes of 13,740 and 30,436 parameters, respectively. The Cache mean absolute residual for groundwater-level observations within each model domain for the priority well was 1.58 meters. Grand Prairie mean absolute residuals for the alluvial aquifer and middle Claiborne aquifer groundwater-level observations were 2.71 and 10.78 meters, respectively. The groundwater budgets for the Cache and Grand Prairie models were characterized by substantial outflows to irrigation wells, which constituted about 52 and 54 percent of all outflows, with the primary source of water to those wells being releases from unconfined aquifer storage.

Arkansas↗

USGS2026

Validating antler- and movement-based estimates of caribou reproduction using video camera collars

Wildlife agencies invest substantial resources in monitoring ungulate reproductive rates given ongoing concerns about population trends and their implications for management. For barren-ground caribou ( Rangifer tarandus ) in the North American Arctic, data on parturition and neonate survival have traditionally been collected using visual observations of antler retention and calf presence from small, fixed-wing aircraft. However, these surveys are weather-dependent, expensive, and dangerous, motivating the development of movement-based approaches that infer reproductive events from global positioning system (GPS) location data. We had the unique opportunity to use video camera collars to validate both antler- and movement-based methods for estimating reproduction in barren-ground caribou, using data from the Porcupine (2018–2023) and Western Arctic (2021, 2023) herds in Alaska, USA, and Yukon, Canada. For the movement-based approaches, we assessed individual-based and population-based methods, which both inferred parturition following a sharp decline in movement and inferred calf loss following a sharp increase in movement. We investigated these approaches using rarified 1-, 2-, 4-, and 8-hour fix intervals. Based on video collar observations, we found that antler retention at the onset of the calving period was highly accurate for predicting parturition (96% accuracy) but became unreliable as calving progressed, as approximately 80% of parturient females shed their antlers during the calving period. In contrast, both movement methods performed marginally for estimating caribou parturition (~70% accuracy), with estimates from the individual-based method exhibiting greater bias than those from the population-based method. The individual-based method also poorly predicted neonate survival (≤49% accuracy for detecting parturition and calf fate for the Porcupine Herd). Video data revealed that inaccuracies with the movement methods often occurred when caribou bedded during storms, rested after traversing mountainous terrain, lost a calf shortly after birth, or increased movement to evade insects. These results have important implications for management agencies using antler- and movement-based methods to estimate caribou reproduction, particularly when informing assessments of population decline or recovery. Our results demonstrate the utility of video collar data for validating reproductive monitoring approaches and provide insights into how these approaches can be improved.

Alaska, Yukon↗

USGS2026

Assessing environmental drivers of denitrification in restored riverine floodplains

Restoration of impaired floodplains is an increasingly prevalent strategy for alleviating water quality concerns and reducing downstream flooding at watershed scales. Floodplains temporarily store water and slow flow velocity to promote sedimentation during overbank flooding and remove inorganic nitrogen from floodwater and groundwater via denitrification. Evaluating the impacts of different restoration strategies on denitrification can inform more strategic investments into floodplain modifications that improve water quality outcomes. Our research investigates how denitrification rates in floodplains respond to environmental factors that are actionable from an engineering perspective through design and water resources management. We seasonally measured soil denitrification enzyme activity and various environmental characteristics in 4 floodplains with different restoration design and management approaches at the confluence of the Wabash and Tippecanoe Rivers in Indiana, United States. Our results showed that denitrification rates in an agricultural floodplain were significantly lower than in restored floodplains with native vegetation. Certain soil conditions characteristic of floodplain wetlands were associated with higher denitrification, particularly elevated total nitrogen, moisture, silt, and organic matter contents. Vegetation species composition was correlated with denitrification rates. This link may reflect the direct effects of vegetation on soil conditions, such as supplying labile organic carbon, or indirect effects, such as vegetation acting as an indicator of hydrologic regime and land use. Denitrification seasonally varied, peaking in winter when nitrate supply from rivers draining agricultural watersheds in the region is also high. Substrate limitation of soil denitrification enzyme activity was most significant during the summer when overbank flooding, which replenishes soil nitrogen stocks, rarely occurs. Our findings indicate that denitrification capacity will likely be maximized in riverine floodplains that are restored as wetlands with diverse native vegetation and enhanced hydrologic connectivity. Such restoration activities promote higher denitrification rates via elevated moisture, fine sediment deposition, and soil organic matter.

Tippecanoe River, Wabash River↗

USGS1976

Uranium analysis of single drops of natural waters using the fission-track technique

The fission-track technique has been applied to uranium analysis of natural waters using a single drop of water. Samples may be collected in the field by evaporating a drop of water on a detector, and samples may then be analyzed by returning the detector to the laboratory. A sample collecting kit has been assembled, which facilitates the designed sampling method. Some unique advantages of this technique are picogram sensitivity (10 -12 g) for uranium on single drops of water, maintenance of sample integrity during transport and storage, and the ability to discern whether the uranium is in solution or in the suspended material. Counting the tracks is the most time-consuming part of the analysis, but it can be reduced by using automatic counting systems. The analytical error is generally ± 10 percent over the entire range of concentrations.

Open-File Report↗

USGS1999

Water-quality assessment of south-central Texas — Descriptions and comparisons of nutrients, pesticides, and volatile organic compounds at three intensive fixed sites, 1996-98

Water-quality samples were collected during April 1996-April 1998 at three intensive fixed sites in the San Antonio region of the South-Central Texas study unit as part of the U.S. Geological Survey National Water-Quality Assessment Program. The sampling strategy for the intensive fixed-site assessment is centered on obtaining information about the occurrence and seasonal patterns of selected constituents including nutrients, pesticides, and volatile organic compounds. The three sites selected to determine the effects of agriculture and urbanization on surface-water quality in the study unit are Medina River at LaCoste (agriculture indicator site), Salado Creek (lower station) at San Antonio (urban indicator site), and San Antonio River near Elmendorf (integrator site). Concentrations of two nutrients, dissolved nitrite plus nitrate nitrogen and total phosphorus, were largest at the integrator site, which is downstream of municipal wastewater treatment plants. Nitrite plus nitrate nitrogen concentrations at this site often exceeded the U.S. Environmental Protection Agency (EPA) maximum contaminant level (MCL) for drinking water. All total phosphorus concentrations at the site exceeded the EPA recommended maximum concentration for streams not discharging directly into reservoirs. Nitrite plus nitrate nitrogen concentrations at the integrator site tended to be smaller, and total phosphorus concentrations at the urban site tended to be larger in samples collected during stormflow than during base flow. The most detections and largest concentrations of three pesticides (atrazine, diazinon, and prometon) were in samples collected at the urban site. Some pesticide concentrations at the agriculture site showed a seasonal pattern of increasing concentrations during spring, the peak application season. Four pesticides (atrazine, deethylatrazine, diazinon, and prometon) were detected in at least 38 percent of samples collected at all three sites. The concentrations of all detected pesticides that have an MCL were less than the MCL at the three sites. More volatile organic compounds (VOC) were detected at the urban indicator site than at the agriculture indicator site, mostly likely because more sources are located in urbanized areas. The most VOCs detected and the largest concentrations of two VOCs (chloroform and tetrahydrofuran) were in samples from the integrator site. More VOCs were detected in samples collected at the integrator site during stormflow than during base flow. The concentrations of all detected VOCs that have an MCL were less than the MCL at the three sites.

Texas↗

USGS2025

Reconnaissance of potential alternate water supply sources for the City of Gary, West Virginia

Seven potential sources of water, consisting of free-flowing discharge from abandoned coal mines at six locations and one abandoned flooded underground coal mine air shaft, were sampled for chemical analysis to assess the quality of the groundwater emanating from the seven mine sources. The six free-flowing mine discharge sources were also assessed for discharge by current-meter measurements on two separate occasions. The U.S. Geological Survey assessed these seven sources to provide information to the City of Gary, West Virginia (W. Va.), and the City of Gary’s consulting engineer with groundwater-quality and flow data to allow them to assess the seven sites as potential alternate sources of water for the City of Gary to augment its existing supply. For the six sites where discharge could be measured, discharge ranged from a minimum of 0.082 cubic feet per second (ft 3 /s) to a maximum of 3.685 ft 3 /s. Of the six sites measured, only two, Harmon Branch at Thorpe, W. Va. (USGS site 372201081303501) and the abandoned public-supply water wells near Havaco, W. Va. (USGS site 372358081344601), had discharge in excess of 1.00 ft 3 /s. Discharge from the abandoned public supply wells was 3.685 ft 3 /s on September 20, 2023, and 2.888 ft 3 /s on October 16, 2023, and discharge from Harmon Branch at Thorpe, W. Va., was 1.049 ft 3 /s on September 22, 2023, and 1.038 ft 3 /s on October 17, 2023. Discharge in the abandoned underground mine air shaft (USGS site 372224081340901) could not be assessed, but the air shaft drains an abandoned mine that likely contains water stored in approximately 1.7 square miles (mi 2 ) of abandoned underground coal mines in the Pocahontas No. 3 coal seam, and possibly an additional 0.9 mi 2 of leakage from the overlying Pocahontas No. 4 coal seam. Discharge for the six sites measured for the study was measured during a period between September 20 and October 18, 2023, and corresponded to the 12th to the 15th percentile of flow-duration statistics for the Tug Fork downstream of Elkhorn Creek at Welch, W. Va. streamgage (USGS site 03212750). Water-quality data for the seven sites sampled overall were acceptable with respect to drinking water standards. Of the 203 constituents analyzed, only a few failed to meet applicable U.S. Environmental Protection Agency (EPA) drinking water standards. Iron exceeded the 300 micrograms per liter (μg/L) secondary maximum contaminant level (SMCL) at only 1 of the 7 sites (14.3 percent) sampled. Iron concentrations ranged from a minimum of less than (<) 5.00 μg/L to a maximum of 724 μg/L with a median concentration of 7.62 μg/L. Manganese exceeded the 50.0 μg/L SMCL at 2 of the 7 sites (28.6 percent) sampled. Manganese concentrations ranged from a minimum of 1.93 μg/L to a maximum of 271 μg/L with a median concentration of 4.03 μg/L. No sites sampled exceeded the arsenic maximum contaminant level (MCL) of 10 μg/L. Arsenic concentrations ranged from a minimum of <0.100 μg/L to a maximum of 2.35 μg/L with a median arsenic concentration of 0.200 μg/L. None of the seven sites sampled for selenium for this study exceeded the EPA MCL of 50.0 μg/L. Selenium concentrations ranged from a minimum of <0.050 μg/L to a maximum of 5.26 μg/L with a median concentration of 3.21 μg/L. All seven sites were sampled for volatile organic compounds (VOCs), semivolatile organic compounds (SVOCs), and polychlorinated biphenyls (PCBs), but most had concentrations below the detection limit. Of the 10 PCB compounds analyzed for the seven sites sampled, none contained detectable concentrations of PCBs or Aroclor compounds. Of the 44 SVOCs analyzed at each of the seven sites sampled, only 1 SVOC, acenaphthene, was detected, at a concentration of 0.02 μg/L. Of the 96 VOCs analyzed, from each of the seven sites sampled, only two were found at detectable concentrations. Trichloromethane was detected only at 1 of the 7 (14.3 percent) sites sampled at a concentration of 0.027 μg/L, and benzene was detected at the same site and 3 additional sites (4 of the 7 sites or 57.1 percent of the sites sampled) at concentrations of 0.028, 0.029, 0.021, and 0.035 μg/L, but none exceeded the EPA MCL for benzene of 5.00 μg/L. Total coliform bacteria are ubiquitous in the environment, and their presence only suggests the potential for contamination by near-surface processes. Escherichia coli ( E. coli ) bacteria are derived from either human or animal fecal material and can be an indicator of potential contamination by pathogenic bacteria or viruses. Total coliform bacteria were detected at all 7 sites sampled at concentrations ranging from 17.5 to greater than (>) 2,420 most probable number per 100 mL (MPN/100 mL) of sample, with a median total coliform concentration of 1,553 MPN/100 mL. Escherichia coli bacteria were detected at 4 of the 7 sites sampled at concentrations ranging from <1 to 11.9 MPN/100 mL, with a median E. coli concentration of 5.1 MPN/100 mL.

West Virginia↗

USGS2026

Ground-motion simulations for the 2024 Mw 4.8 Tewksbury, New Jersey, earthquake

Ground-motion simulations of notable earthquakes in the central and eastern United States are limited and typically assume one-dimensional (1D) Earth structure. In this study, we use a three-dimensional (3D) seismic velocity model to better constrain the depth and focal mechanism of the April 5th, 2024, moment magnitude 4.8 Tewksbury earthquake and investigate the spatial variability of earthquake ground motions and the effects of nearby sedimentary basins. We perform earthquake ground-motion simulations up to 0.5 Hz using the 3D spectral-element wave-propagation solver SPECFEM3D over a region 280-km wide by 260-km long by 77-km deep. Topography and subsurface geophysical structure are assigned using the U.S. Geological Survey National Crustal Model with a minimum shear-wave velocity of 200 m/s. We use earthquake time series from 13 broadband seismic stations in the region that have a uniform azimuthal distribution and epicentral distances ranging from 76 to 131 km to compare with synthetics and explore the effects of 1D versus 3D seismic structure on focal mechanism and depth solutions. Ground-motion intensity metrics are also presented relative to the NGA-East ground-motion models (GMMs) currently used in seismic hazard assessments for the region. We find that the 3D model, which reveals a wide spatial variability of period-dependent ground motions, yields better predictions of earthquake ground motions relative to the 1D model and the NGA-East ergodic ground-motion model, with 76 percent reduction of residual variance in observed ground motions averaged over 3-, 5-, 7-, and 10-second periods. Use of the 3D model to solve for a focal mechanism yields a shallower focal depth at 4 km and a shallower east-dipping focal plane relative to the U.S. Geological Survey regional moment tensor and Global Centroid Moment Tensor. Our study demonstrates that use of 3D seismic velocity models can improve estimates of earthquake focal mechanisms, ground motions, and seismic hazard.

New Jersey↗