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Reconnaissance study of the hydrology of American Memorial Park, Island of Saipan, Commonwealth of the Northern Mariana Islands

American Memorial Park, a unit of the National Park Service on the Island of Saipan, includes among its features a 27-acre estuarine system that has become a rarity within the Commonwealth of the Northern Mariana Islands. The estuarine system's mosaic of marshy areas interspersed with emergent wetlands and mixed wet forests provides critical habitat for various migratory and resident waterfowl, including two Federally listed endangered species: the Marianas gallinule ( Gallinula chloropus guami ) and the nightingale reed warbler ( Acrocephalus luscinia ). With sensitivity to the park's ecologic assets and the uncertainty associated with locally rapid urbanization, a need to better understand the hydrology of American Memorial Park was recognized. To address that need, a reconnaissance study of the park was undertaken during August and September 2005. The goals of the study were (1) to describe the occurrence and salinity of surface and ground water within the park; (2) to develop a hydrologic model of the park area of the island, with emphasis on the 27-acre estuarine system; and (3) to identify additional data needed to further develop this model. With regard to surface water, three freshwater inputs to the park's natural wetland are possible: direct rainfall, seaward-flowing ground water, and overland flow. Direct rainfall, which is an important source of freshwater to the wetland, commonly exceeds evapotranspiration both seasonally and per storm. The seaward flow of ground water is likely to be a source of freshwater to the wetland because ground water generally has an upward vertical component in the nearshore environment. Overland flow upgradient of the park could potentially contribute a significant input of freshwater during periods of intense rainfall, but roads that flank the park's perimeter act as a barrier to surficial inflows. During the reconnaissance, four discrete bodies, or zones, of surface water were observed within the park's natural wetland. Conductivity within these surface-water zones typically ranged from 1,540 to 4,370 microsiemens per centimeter (µS/cm) at 25°C although values as low as 829 and as high as 8,750 µ S/cm were measured. As a result of these observations, the American Memorial Park wetland area meets the definition criteria of an estuarine system that is dominantly oligohaline. Conductivity was also measured in a constructed wetland that was built within the park to augment the storm-drainage infrastructure of the village of Garapan. Reverse-osmosis facilities, in operation at hotels adjacent to the park, have historically discharged highly saline wastewater into the storm-drainage system. This collective storm and wastewater flow is routed into the constructed wetland and from there into the ocean. The conductivity of water in the constructed wetland ranged from 45,000 to 62,500 µS/cm , exceeding nominal seawater values by as much as 25 percent, with the highest conductivities recorded near discharging storm drains. With regard to ground water, the reconnaissance included installation of a ground-water-monitoring network. Data collected from this network identified the presence of freshwater underlying the park and indicated that surface water is directly connected to ground water in the natural wetland because the water levels of both surface water and ground water directly varied with the tide. Conductivities of ground-water samples from wells in the monitoring network indicated that ground-water salinity was geographically related: conductivities were lower (801-2,490 (µS/cm) in surficially dry areas, intermediate (6,090-9,180 (µS/cm) in natural-wetland areas, and higher (18,250-27,700 (µS/cm) in areas adjacent to the constructed wetland and its associated ocean-discharge channel. Synoptic water-level surveys were made to enhance understanding of the spatial expression of the water table; they were scheduled to overlap with peak and trough tidal signals to enable limited characteri

Scientific Investigations Report↗

California GAMA program: Ground-water quality data in the northern San Joaquin Basin Study Unit, 2005

Growing concern over the closure of public-supply wells because of ground-water contamination has led the State Water Board to establish the Ground-Water Ambient Monitoring and Assessment (GAMA) Program. With the aid of the U.S. Geological Survey (USGS) and Lawrence Livermore National Laboratory, the program goals are to enhance understanding and provide a current assessment of ground-water quality in areas where ground water is an important source of drinking water. The Northern San Joaquin Basin GAMA study unit covers an area of approximately 2,079 square miles (mi2) across four hydrologic study areas in the San Joaquin Valley. The four study areas are the California Department of Water Resources (CADWR) defined Tracy subbasin, the CADWR-defined Eastern San Joaquin subbasin, the CADWR-defined Cosumnes subbasin, and the sedimentologically distinct USGS-defined Uplands study area, which includes portions of both the Cosumnes and Eastern San Joaquin subbasins. Seventy ground-water samples were collected from 64 public-supply, irrigation, domestic, and monitoring wells within the Northern San Joaquin Basin GAMA study unit. Thirty-two of these samples were collected in the Eastern San Joaquin Basin study area, 17 in the Tracy Basin study area, 10 in the Cosumnes Basin study area, and 11 in the Uplands Basin study area. Of the 32 samples collected in the Eastern San Joaquin Basin, 6 were collected using a depth-dependent sampling pump. This pump allows for the collection of samples from discrete depths within the pumping well. Two wells were chosen for depth-dependent sampling and three samples were collected at varying depths within each well. Over 350 water-quality field parameters, chemical constituents, and microbial constituents were analyzed and are reported as concentrations and as detection frequencies, by compound classification as well as for individual constituents, for the Northern San Joaquin Basin study unit as a whole and for each individual study area. Results are presented in a descending order based on detection frequencies (most frequently detected compound listed first), or alphabetically when a detection frequency could not be calculated. Only certain wells were measured for all constituents and water-quality parameters. The results of all of the analyses were compared with U.S. Environmental Protection Agency (USEPA) and California Department of Health Services (CADHS) Maximum Contaminant Levels (MCLs), Secondary Maximum Contaminant Levels (SMCLs), USEPA lifetime health advisories (HA-Ls), the risk-specific dose at a cancer risk level equal to 1 in 100,000 or 10E-5 (RSD5), and CADHS notification levels (NLs). When USEPA and CADHS MCLs are the same, detection levels were compared with the USEPA standard; however, in some cases, the CADHS MCL may be lower. In those cases, the data were compared with the CADHS MCL. Constituents listed by CADHS as 'unregulated chemicals for which monitoring is required' were compared with the CADHS 'detection level for the purposes of reporting' (DLR). DLRs unlike MCLs are not health based standards. Instead, they are levels at which current laboratory detection capabilities allow eighty percent of qualified laboratories to achieve measurements within thirty percent of the true concentration. Twenty-three volatile organic compounds (VOCs) and seven gasoline oxygenates were detected in ground-water samples collected in the Northern San Joaquin Basin GAMA study unit. Additionally, 13 tentatively identified compounds were detected. VOCs were most frequently detected in the Eastern San Joaquin Basin study area and least frequently detected in samples collected in the Cosumnes Basin study area. Dichlorodifluoromethane (CFC-12), a CADHS 'unregulated chemical for which monitoring is required,' was detected in two wells at concentrations greater than the DLR. Trihalomethanes were the most frequently detected class of VOC constituents. Chloroform (trichloromethane) was the m

California↗

Hydrogeologic framework and geologic structure of the Floridan aquifer system and intermediate confining unit in the Lake Okeechobee area, Florida

The successful implementation of aquifer storage and recovery (ASR) as a water-management tool requires detailed information on the hydrologic and hydraulic properties of the potential water storage zones. This report presents stratigraphic and hydrogeologic sections of the upper part of the Floridan aquifer system and the overlying confining unit or aquifer system in the Lake Okeechobee area, and contour maps of the upper contacts of the Ocala Limestone and the Arcadia Formation, which are represented in the sections. The sections and maps illustrate hydrogeologic factors such as confinement of potential storage zones, the distribution of permeability within the zones, and geologic features that may control the efficiency of injection, storage, and recovery of water, and thus may influence decisions on ASR activities in areas of interest to the Comprehensive Everglades Restoration Plan.

Florida↗

Evaluating the importance of characterizing soil structure and horizons in parameterizing a hydrologic process model

Incorporating the influence of soil structure and horizons into parameterizations of distributed surface water/groundwater models remains a challenge. Often, only a single soil unit is employed, and soil-hydraulic properties are assigned based on textural classification, without evaluating the potential impact of these simplifications. This study uses a distributed physics-based model to assess the influence of soil horizons and structure on effective parameterization. This paper tests the viability of two established and widely used hydrogeologic methods for simulating runoff and variably saturated flow through layered soils: (1) accounting for vertical heterogeneity by combining hydrostratigraphic units with contrasting hydraulic properties into homogeneous, anisotropic units and (2) use of established pedotransfer functions based on soil texture alone to estimate water retention and conductivity, without accounting for the influence of pedon structures and hysteresis. The viability of this latter method for capturing the seasonal transition from runoff-dominated to evapotranspiration-dominated regimes is also tested here. For cases tested here, event-based simulations using simplified vertical heterogeneity did not capture the state-dependent anisotropy and complex combinations of runoff generation mechanisms resulting from permeability contrasts in layered hillslopes with complex topography. Continuous simulations using pedotransfer functions that do not account for the influence of soil structure and hysteresis generally over-predicted runoff, leading to propagation of substantial water balance errors. Analysis suggests that identifying a dominant hydropedological unit provides the most acceptable simplification of subsurface layering and that modified pedotransfer functions with steeper soil-water retention curves might adequately capture the influence of soil structure and hysteresis on hydrologic response in headwater catchments.

Hydrological Processes↗

Water-quality assessment of part of the Upper Mississippi River basin, Minnesota and Wisconsin: Environmental setting and study design

The Upper Mississippi River Basin is diverse in ways that can control the areal distribution and flow of water and the distribution and concentration of constituents that affect water quality. A review of the environmental setting of the Upper Mississippi River Basin study unit of the National Water-Quality Assessment Program is intended to put water quality in perspective with the geology, soils, climate, hydrology, ecology and historical uses of the land and provides a basis for the sampling design of the study. The Upper Mississippi River Basin study unit encompasses about 47,000 square miles and includes all of the basin upstream from Lake Pepin. The climate of the study unit is subhumid continental with cold dry winters and warm, moist summers. Average annual precipitation ranges from 22 inches in the western part of the study unit to 32 inches in the east. Annual runoff ranges from less than 2 inches in the west to 14 inches in the northeast. The physiography of the study unit includes the Superior Upland and the Central Lowland Provinces. The Wisconsin Driftless Area and the Dissected Till Plains are unique physiographic sections of the Central Lowland Province. Hydrogeologic units in glacial deposits include surficial and buried sand and gravel aquifers and confining units. Bedrock aquifers and confining units are part of a thick sequence of sedimentary rocks that can be divided into major aquifers separated by confining units. The population of the study unit was about 3,640,000 as of 1990 and increased 16 percent between 1970 and 1990. Seventy-five percent of the population lives in the Twin Cities metropolitan area. An average of 413 million gallons of water per day was used 59 percent from ground water and 41 percent from surface water. Land use and land cover in the study unit consists of forested, agricultural, and urban areas. About 63 percent of the land area is agricultural. The quality of water in streams and ground water are affected by both natural and anthropogenic factors. The quality of water is generally satisfactory for most domestic, public, industrial, and irrigation uses. Most water is of the calcium-magnesium-bicarbonate type. The initial six-year phase of the Upper Mississippi River Basin National Water-Quality Assessment, lasting from 1994 to 1999, focuses on data collection and analysis in a 19,500 square-mile area in Minnesota and Wisconsin that includes the Twin Cities metropolitan area. The study design focuses on factors that have an influence on or a potential influence on the water quality in that area. The most significant contaminants include nutrients, pesticides, synthetic-organic compounds, and trace metals. Environmental stratification consists of dividing the study unit into subareas with homogeneous characteristics to assess natural and anthropogenic factors affecting water quality. The assessment of water quality in streams and in aquifers is based on the sampling design that compares water quality within homogeneous subareas defined by subbasins or aquifer boundaries. The study unit is stratified at four levels for the surface-water component: glacial deposit composition, surficial geology, general land use and land cover, and secondary land use. Ground-water studies emphasize shallow ground water where quality is most likely influenced by overlying land use and land cover. Stratification for ground-water sampling is superimposed on the distribution of shallow aquifers. For each aquifer and surface-water basin this stratification forms the basis for the proposed sampling design used in the Upper Mississippi River Basin National Water-Quality Assessment.

Minnesota, Wisconsin↗

Simulation of groundwater and surface-water resources of the San Antonio Creek Valley watershed, Santa Barbara County, California

In the San Antonio Creek Valley watershed (SACVW), western Santa Barbara County, California, groundwater is the primary source of water for agricultural irrigation, the town of Los Alamos, and supplemental water to Vandenberg Space Force Base (VSFB). Groundwater pumpage has increased since the 1970s as non-irrigated agricultural land has been converted to irrigated land and as local pumping for municipal use has increased. This increase in groundwater use has resulted in declining groundwater levels, adjustments in surface-water flows and species habitats, and changes in water quality. Water managers are addressing the challenges of meeting this increased demand while maintaining sustainable groundwater supplies. To address these challenges, Santa Barbara County Water Agency, Vandenberg Space Force Base (VSFB), and the U.S. Geological Survey (USGS) undertook a cooperative study to characterize the integrated hydrologic system of the SACVW and develop tools to better understand and manage the groundwater system. The objectives of this study were to improve the understanding of the integrated hydrologic system and incorporate the understanding into an integrated groundwater and surface-water flow model that can be used to help manage the water resources in the SACVW. The San Antonio Creek integrated model (SACIM) was developed using the USGS coupled groundwater and surface-water flow model to simulate the hydrologic system of the SACVW and provide annual and average water budgets for 1948–2018 water years. Results from the SACIM indicated that between 1948 and 2018, total groundwater from storage (storage depletion) for the period was 453,300 acre-feet (acre-ft). Agricultural pumpage was the largest discharge and accounted for a total of 1,020,000 acre-ft of groundwater. Increased pumpage since the mid-1980s (of which agricultural pumpage is the primary component) is tied to an increased rate of storage depletion and reduced rates of groundwater evapotranspiration and surface leakage (groundwater discharge to the surface and soil zone). The increased pumpage also reduced subsurface inflow to Barka Slough, resulting in a decline in upward flow through the underlying hydrogeologic units and surface leakage. In addition to quantifying historical changes in the integrated hydrologic system, the SACIM is a tool than can be used by water managers to evaluate the effects of different climatic and hydrologic conditions and management strategies.

California↗

Hydraulic properties of rock units and chemical quality of water for INEL-1 — A 10,365-foot deep test hole drilled at the Idaho National Engineering Laboratory, Idaho

A 10,365-ft deep test hole drilled at the INEL (Idaho National Engineering Laboratory) in southeastern Idaho provided hydraulic information for rock units underlying the Snake River Plain aquifer. Four aquifer tests showed that the hydraulic conductivity decreased with depth--from an average of 0.03 ft/day for the interval from 1,511 to 2,206 ft below land surface to an average of 0.002 ft/day for the interval from 4 ,210 to 10,365 ft. In contrast the hydraulic conductivity of the Snake River Plain aquifer ranges from 1 to 100 ft/day. The hydraulic head increased with depth; the head at depth was about 115 ft greater than that for the Snake River Plain aquifer. Water temperature in the test hole increased from 26 C at 600 ft below land surface to 146 C at 9,985 ft. The gradient was nearly linear and averaged about 1.3 C/100 ft of depth. Water from the Snake River Plain aquifer contained 381 mg/L of dissolved solids and had a calcium bicarbonate chemical composition. The dissolved solids concentration in underlying rock units ranged from 350 to 1,020 mg/L and the water had a sodium bicarbonate composition. Hydrologic data for the test hole suggest that the effective base of the Snake River Plain aquifer near the test hole is between 840 and 1,220 ft below land surface. The upward vertical movement of water into the Snake River Plain aquifer from underlying rock units could be on the order of 15,000 acre-ft/year at INEL. (Author 's abstract)

Idaho↗

Characterization of geologic deposits in the vicinity of US Ecology, Amargosa Basin, southern Nevada

Multiple approaches have been applied to better understand the characteristics of geologic units exposed at the surface and buried at depth in the vicinity of US Ecology (USE), a low-level commercial waste site in the northern Amargosa Desert, Nevada. Techniques include surficial geologic mapping and interpretation of the subsurface using borehole data. Dated deposits at depth were used to estimate rates of sediment accumulation. The subsurface lithologies have been modeled in three dimensions. Lithologic cross sections have been created from the three-dimensional model and have been compared to resistivity data at the same location. Where deposits appear offset, a fault was suspected. Global Positioning System elevation transects were measured and trenches were excavated to locate a strand of the Carrara Fault. The presence of the fault helps to better understand the shape of the potentiometric surface. These data will be used to better understand the hydrologic parameters controlling the containment of the waste at US Ecology. Quaternary geologic units exposed at the surface, in the vicinity of US Ecology, are derived from the alluvium shed off the adjacent range front and the Amargosa River. These deposits vary from modern to early Pleistocene in age. At depth, heterogeneous sands and gravel occur. Observed in deep trenches and boreholes, the subsurface deposits are characterized as fining-upward sequence of sediment from 5- to 8-meters thick. No volcanic units or fine-grained playa deposits were described in the boreholes to a depth of 200 meters. Based on Infrared Stimulated Luminescence dated core samples, short-term rates of sediment accumulation (<70,000 years) are an average of 2.7 millimeters per year, however, long-term rates (<3,900,000 years) are orders of magnitude less. Resistivity data, when compared to lithologic cross sections, generally are consistent with lithology grain size and probable soil carbonate accumulations. Surface resistivity displays a fining-upward sequence of sediments at the surface with a soil carbonate imprint. Finally, trenching north of US Ecology successfully exposed offset Quaternary deposits on a splay of the Carrara Fault. Holocene deposits do not appear to be faulted, however, a fault zone does intersect middle and late Pleistocene aged units.

Nevada↗

Hydro-climatic data network (HCDN): A U.S. Geological Survey streamflow data set for the United States for the study of climate variations, 1874-1988

Records of streamflow can provide an account of climatic variation over a hydrologic basin. The ability to do so is conditioned on the absence of confounding factors that diminish the climate signal. A national data set of streamflow records that are relatively free of confounding anthropogenic influences has been developed for the purpose of studying the variation in surface-water conditions throughout the United States. Records in the U.S. Geological Survey (USGS) National Water Storage and Retrieval System (WATSTORE) data base for active and discontinued streamflow gaging stations through water year 1988 (that is, through September 30, 1988) were reviewed jointly with data specialists in each USGS District office. The resulting collection of stations, each with its respective period of record satisfying the qualifying criteria, is called the Hydro-Climatic Data Network, or HCDN. The HCDN consists of 1,659 sites throughout the United States and its territories, totaling 73,231 water years of daily mean discharge values. For each station in the HCDN, information necessary for its identification, along with any qualifying comments about the available record and a set of descriptive watershed characteristics are provided in tabular format in this report, both on paper and on computer disk (enclosed). For each station in the HCDN, the appropriate daily mean discharge values were compiled, and statistical characteristics, including monthly mean discharges and annual mean, minimum and maximum discharges, were derived. The discharge data values are provided in a companion report.

Open-File Report↗

Forecasting drought probabilities for streams in the northeastern United States

Maximum likelihood logistic regression (MLLR) models for the northeastern United States forecast drought probability estimates for water flowing in rivers and streams using methods previously identified and developed. Streamflow data from winter months are used to estimate chances of hydrological drought during summer months. Daily streamflow data collected from 1,143 streamgages from April 1, 1877, through October 31, 2018, are used to provide hydrological drought streamflow probabilities for July, August, and September as functions of streamflows during October, November, December, January, and February. This allows estimates of outcomes from 5 to 11 months ahead of their occurrence. Models specific to the northeastern United States were investigated and updated. The MLLR models of drought stream-flow probabilities utilize the explanatory power of temporally linked water flows. Models with strong drought streamflow probability correct-classification rates were produced for streams throughout the northeastern United States. A test of northeastern United States drought streamflow probability predictions found that overall correct-classification rates for drought streamflow probabilities in the northeastern United States exceeded 97 percent when predicting July 2019 drought probability using February 2019 monthly mean streamflow data. Using hydrological drought probability estimates in a water-management context informs understandings of possible future streamflow drought conditions in the northeastern United States, provides warnings of potential future drought conditions, and aids water-management decision making and responses to changing circumstances.

Connecticut, Delaware, Massachusetts, Maine, New H↗

Geomorphic change and sediment transport during a small artificial flood in a transformed post-dam delta: The Colorado River delta, United States and Mexico

The Colorado River delta is a dramatically transformed landscape. Major changes to river hydrology and morpho-dynamics began following completion of Hoover Dam in 1936. Today, the Colorado River has an intermittent and/or ephemeral channel in much of its former delta. Initial incision of the river channel in the upstream ∼50 km of the delta occurred in the early 1940s in response to spillway releases from Hoover Dam under conditions of drastically reduced sediment supply. A period of relative quiescence followed, until the filling of upstream reservoirs precipitated a resurgence of flows to the delta in the 1980s and 1990s. Flow releases during extreme upper basin snowmelt in the 1980s, flood flows from the Gila River basin in 1993, and a series of ever-decreasing peak flows in the late 1990s and early 2000s further incised the upstream channel and caused considerable channel migration throughout the river corridor. These variable magnitude post-dam floods shaped the modern river geomorphology. In 2014, an experimental pulse-flow release aimed at rejuvenating the riparian ecosystem and understanding hydrologic dynamics flowed more than 100 km through the length of the delta’s river corridor. This small artificial flood caused localized meter-scale scour and fill of the streambed, but did not cause further incision or significant bank erosion because of its small magnitude. Suspended-sand-transport rates were initially relatively high immediately downstream from the Morelos Dam release point, but decreasing discharge from infiltration losses combined with channel widening downstream caused a rapid downstream reduction in suspended-sand-transport rates. A zone of enhanced transport occurred downstream from the southern U.S.-Mexico border where gradient increased, but effectively no geomorphic change occurred beyond a point 65 km downstream from Morelos Dam. Thus, while the pulse flow connected with the modern estuary, deltaic sedimentary processes were not restored, and relatively few new open surfaces were created for establishment of native riparian vegetation. Because water in the Colorado River basin is completely allocated, exceptional floods from the Gila River basin are the most likely mechanism for major changes to delta geomorphology for the foreseeable future.

Colorado River Delta↗

Geohydrologic systems in Kansas physical framework of the western interior plains confining system

The purpose of this Hydrologic Investigations Atlas is to provide a description of the principal geohydrologic systems in the Upper Cambrian through Lower Cretaceous rocks in Kansas. This investigation was made as part of the Central Midwest Regional Aquifer-System Analysis (CMRASA). The CMRASA is one of several major investigations by the U.S. Geological Survey of regional aquifer systems in the United States. These regional investigations are designed to increase knowledge of the flow regime and hydrologic properties of major aquifer systems and to provide quantitative information for assessing, developing, and managing water supplies. The CMRASA study area includes all or parts of 10 Central Midwestern States (Jorgensen and Signor, 1981) as shown on the envelope cover.

Kansas↗

Digital surfaces and hydrogeologic data for the Floridan aquifer system in Florida and in parts of Georgia, Alabama, and South Carolina

A digital dataset for the Floridan aquifer system in Florida and in parts of Georgia, Alabama, and South Carolina was developed from selected reports published as part of the Regional Aquifer-System Analysis (RASA) Program of the U.S. Geological Survey (USGS) in the 1980s. These reports contain maps and data depicting the extent and elevation of both time-stratigraphic and hydrogeologic units of which the aquifer system is composed, as well as data on hydrology, meteorology, and aquifer properties. The three primary reports used for this dataset compilation were USGS Professional Paper 1403-B (Miller, 1986), Professional Paper 1403-C (Bush and Johnston, 1988), and USGS Open-File Report 88-86 (Miller, 1988). Paper maps from Professional Papers 1403-B and 1403-C were scanned and georeferenced to the North American Datum of 1927 (NAD27) using the Lambert Conformal Conic projection (standard parallels 33 and 45 degrees, central longitude -96 degrees, central latitude 39 degrees). Once georeferenced, tracing of pertinent line features contained in each image (for example, contours and faults) was facilitated by specialized software using algorithms that automated much of the process. Resulting digital line features were then processed using standard geographic information system (GIS) software to remove artifacts from the digitization process and to verify and update attribute tables. The digitization process for polygonal features (for example, outcrop areas and unit extents) was completed by hand using GIS software.

Alabama, Florida, Georgia, South Carolina↗

Chloroform in the hydrologic system--sources, transport, fate, occurrence, and effects on human health and aquatic organisms

Chloroform is one of the volatile organic compounds (VOCs) detected most frequently in both ground and surface water. Because it is also one of the four trihalomethanes (THMs) produced in the highest concentrations during the chlorination of drinking water and wastewater, the frequent detection of this compound in ground and surface water of the United States is presumed to be caused primarily by the input of chlorinated water to the hydrologic system. Although anthropogenic sources of the compound are substantial, they are currently estimated to constitute only 10 percent of the total global input to the hydrologic system. Natural sources of the compound include volcanic gases, biomass burning, marine algae, and soil microorganisms. Under most conditions (except in the presence of unusually high bromide concentrations), chloroform is the THM produced in the highest concentrations during chlorination. Furthermore, in most cases where more than one THM is produced from chlorination, the relative concentrations among the different compounds usually decrease with increasing bromination (chloroform > dichlorobromomethane > chlorodibromomethane > bromoform). This phenomenon is presumed to be responsible for the common observation that when more than one THM is detected during investigations of the occurrence of these compounds in the hydrologic system, this same trend is typically observed among their relative concentrations or, for a uniform reporting limit, their relative frequencies of detection. This pattern could provide a valuable means for distinguishing between chlorinated water and other potential sources of chloroform in the environment. Chloroform has been widely detected in national, regional, and local studies of VOCs in ground, surface, source, and drinking waters. Total THM (TTHM) concentrations of the compound, however, were typically less than the Maximum Contaminant Level (MCL) of 80 ?g/L (micrograms per liter) established by the U.S. Environmental Protection Agency (USEPA) for TTHMs. In the studies that compared land-use settings, frequencies of detection of chloroform were higher beneath urban and residential areas than beneath agricultural or undeveloped areas. Because chloroform is a suspected human carcinogen, its presence in drinking water is a potential human health concern. Liver damage, however, is known to occur at chloroform exposures lower than those required to cause cancer, an observation that has been considered by the USEPA as the basis for setting a new, non-zero Maximum Contaminant Level Goal of 70 ?g/L for the compound. As part of its National Water-Quality Assessment Program, the U.S. Geological Survey has been assembling and analyzing data on the occurrence of VOCs (including chloroform) in ground and surface water on a national scale from studies conducted between 1991 and the present. This report presents a summary of current (2004) information on the uses, sources, formation, transport, fate, and occurrence of chloroform, as well as its effects on human health and aquatic organisms.

Scientific Investigations Report↗

Integrating terrestrial and aquatic ecosystems to constrain estimates of land-atmosphere carbon exchange

In this Perspective, we put forward an integrative framework to improve estimates of land-atmosphere carbon exchange based on the accumulation of carbon in the landscape as constrained by its lateral export through rivers. The framework uses the watershed as the fundamental spatial unit and integrates all terrestrial and aquatic ecosystems as well as their hydrologic carbon exchanges. Application of the framework should help bridge the existing gap between land and atmosphere-based approaches and offers a platform to increase communication and synergy among the terrestrial, aquatic, and atmospheric research communities that is paramount to advance landscape carbon budget assessments.

Nature Communications↗

Evapotranspiration terminology and definitions

Evapotranspiration (ET), the combined process of evaporation from soil and plant surfaces and transpiration from plant tissue, plays a pivotal role in the global water and energy balance. Accurately quantifying ET at various spatial scales is important for diverse applications, including irrigation and natural resource management. While efforts to standardize ET methodology have progressed over the last few decades, some confusion and disagreements in terminology persist among communities of researchers and practitioners involved in the measurement, estimation, and simulation of ET. This technical note addresses the historical evolution and standardization of ET terminology, aiming to reduce and mitigate disparities in definitions and usage by advocating for standardized definitions and emphasizing the adoption of reference ET ( ET ref ) terminology to promote consistency and accuracy and to avoid ambiguity. This document provides comprehensive definitions of key terms, including crop (i.e., vegetation cover) coefficients, consumptive use (CU), actual crop evapotranspiration ( ET a ), and ET ref variants for short (grass, ET o ) and tall (alfalfa, ET r ) reference crops. Practical discussion on several relevant topics is given: (1) single and dual crop coefficient approaches, (2) applications to nonagricultural vegetation, (3) recommended subscripts for terms, (4) practical guidelines and considerations for ET ref calculation, (5) encouragement to replace “potential ET” terminology with better terms, (6) clarification on maximum ET ( ET max ) and maximum crop coefficient ( K c max ) terms, (7) ET products derived from remote sensing, (8) a brief description of the role of ET in water rights, and (9) a figure illustrating the use of the terms defined herein. The conclusion emphasizes the importance of consistent terminology for effective communication among researchers and end-users, which will facilitate the adoption of standardized ET methods and technologies. This technical note was created by the American Society of Civil Engineers, Environmental and Water Resources Institute (ASCE-EWRI), Evapotranspiration in Irrigation and Hydrology Committee, with input and endorsement from other relevant organizations in the United States and internationally. This note serves as a comprehensive reference guide for ET practitioners and researchers.

Irrigation and Drainage Engineering↗

A multi-scale soil moisture monitoring strategy for California: Design and validation

A multi‐scale soil moisture monitoring strategy for California was designed to inform water resource management. The proposed workflow classifies soil moisture response units (SMRUs) using publicly available datasets that represent soil, vegetation, climate, and hydrology variables, which control soil water storage. The SMRUs were classified, using principal component analysis and unsupervised K‐means clustering within a geographic information system, and validated, using summary statistics derived from measured soil moisture time series. Validation stations, located in the Sierra Nevada, include transect of sites that cross the rain‐to‐snow transition and a cluster of sites located at similar elevations in a snow‐dominated watershed. The SMRUs capture unique responses to varying climate conditions characterized by statistical measures of central tendency, dispersion, and extremes. A topographic position index and landform classification is the final step in the workflow to guide the optimal placement of soil moisture sensors at the local‐scale. The proposed workflow is highly flexible and can be implemented over a range of spatial scales and input datasets can be customized. Our approach captures a range of soil moisture responses to climate across California and can be used to design and optimize soil moisture monitoring strategies to support runoff forecasts for water supply management or to assess landscape conditions for forest and rangeland management.

California↗

Understanding the relationship between audiomagnetotelluric data and models, and borehole data in a hydrological environment

Audiomagnetotelluric (AMT) data and resulting models are analyzed with respect to geophysical and geological borehole logs in order to clarify the relationship between the two methodologies of investigation of a hydrological environment. Several profiles of AMT data collected in basins in southwestern United States are being used for groundwater exploration and hydrogeological framework studies. In a systematic manner, the AMT data and models are compared to borehole data by computing the equivalent one-dimensional AMT model and comparing with the two-dimensional (2-D) inverse AMT model. The spatial length is used to determine if the well is near enough to the AMT profile to quantify the relationship between the two datasets, and determine the required resolution of the AMT data and models. The significance of the quality of the borehole data when compared to the AMT data is also examined.

Conference Paper↗