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At least 721 records · Page 40Linked to original sources
USGS2017

Niobium and tantalum

Niobium and tantalum are transition metals that are almost always found together in nature because they have very similar physical and chemical properties. Their properties of hardness, conductivity, and resistance to corrosion largely determine their primary uses today. The leading use of niobium (about 75 percent) is in the production of high-strength steel alloys used in pipelines, transportation infrastructure, and structural applications. Electronic capacitors are the leading use of tantalum for high-end applications, including cell phones, computer hard drives, and such implantable medical devices as pacemakers. Niobium and tantalum are considered critical and strategic metals based on the potential risks to their supply (because current production is restricted to only a few countries) and the significant effects that a restriction in supply would have on the defense, energy, high-tech industrial, and medical sectors. The average abundance of niobium and tantalum in bulk continental crust is relatively low—8.0 parts per million (ppm) niobium and 0.7 ppm tantalum. Their chemical characteristics, such as small ionic size and high electronic field strength, significantly reduce the potential for these elements to substitute for more common elements in rock-forming minerals and make niobium and tantalum essentially immobile in most aqueous solutions. Niobium and tantalum do not occur naturally as pure metals but are concentrated in a variety of relatively rare oxide and hydroxide minerals, as well as in a few rare silicate minerals. Niobium is primarily derived from the complex oxide minerals of the pyrochlore group ((Na,Ca,Ce) 2 (Nb,Ti,Ta) 2 (O,OH,F) 7 ), which are found in some alkaline granite-syenite complexes (that is, igneous rocks containing sodium- or potassium-rich minerals and little or no quartz) and carbonatites (that is, igneous rocks that are more than 50 percent composed of primary carbonate minerals, by volume). Tantalum is derived mostly from the mineral tantalite ((Fe,Mn)(Ta,Nb) 2 O 6 ), which is found as an accessory mineral in rare-metal granites and pegmatites that are also enriched in lithium and cesium (termed lithium-cesium-tantalum (LCT)-type pegmatites). Brazil and Canada are the leading nations that produce niobium mineral concentrates, but Brazil is by far the leading producer, accounting for about 90 percent of production, which comes mostly from weathered material derived from carbonatites. Brazil and Canada also have the largest identified niobium resources; additional resources, although they are less well reported, occur in Angola, Australia, China, Greenland, Malawi, Russia, and South Africa. Australia and Brazil have been the leading producers of tantalum mineral concentrates, although recently Ethiopia and Mozambique have also been significant suppliers of tantalum. Artisanal mining of columbite-tantalite (also called coltan) is practiced in many countries, particularly Burundi, the Democratic Republic of the Congo (Congo [Kinshasa]), Nigeria, Rwanda, and Uganda. Brazil has about 40 percent of the identified tantalum resources; other countries and regions with identified tantalum resources include, in decreasing order of resources, Australia, Asia, Russia and the Middle East, Africa, North America, and Europe. Identified niobium and tantalum resources in the United States are small, low grade, and difficult to recover and process, and are thus not commercially recoverable at current prices. Consequently, the United States meets its current and expected future needs for niobium and tantalum through imports of primary mineral concentrates and alloys and through recovery from foreign and domestic alloy scrap that contain the metals. Environmentally, the main issues related to niobium and tantalum mining are land disruptions, the volume of waste materials and their disposal, and the radioactivity of some tailings and waste materials that contain thorium and uranium. Because of the relative biological inertness of niobium and tantalum, human and ecological health concerns are generally minimal under most natural conditions. Demand for both niobium and tantalum is expected to increase as the world economy continues to recover from the downturn that began in 2008. Increased demand for niobium is linked to increased consumption of microalloyed steel, which is used in the manufacture of cars, buildings, ships, and refinery equipment. Demand for these steels will likely increase with continued economic development in such countries as Brazil, China, and India. In addition, increased global demand for cars, cell phones, computers, superconducting magnets, and other high-tech devices will likely spur increased demand for both niobium and tantalum. The estimated global reserves and resources of niobium and tantalum are large and appear more than sufficient to meet global demand for the foreseeable future, possibly the next 500 years. The sale of “conflict coltan” attributed to rebel forces waging a civil war in Congo (Kinshasa) has been of recent concern and has highlighted the need for a transparent and traceable global supply chain that can exclude illegal columbite-tantalite from the conventional market while discerning legitimate artisanal mine production in central Africa.

Professional Paper↗
USGS2004

Ancient wet aeolian environments on Earth: Clues to presence of fossil/live microorganisms on Mars

Ancient wet aeolian (wet-sabkha) environments on Earth, represented in the Entrada and Navajo sandstones of Utah, contain pipe structures considered to be the product of gas/water release under pressure. The sediments originally had considerable porosity allowing the ingress of living plant structures, microorganisms, clay minerals, and fine-grained primary minerals of silt and sand size from the surface downward in the sedimentary column. Host rock material is of a similar size and porosity and presumably the downward migration of fine-grained material would have been possible prior to lithogenesis and final cementation. Recent field emission scanning electron microscopy (FESEM) and EDS (energy-dispersive spectrometry) examination of sands from fluidized pipes in the Early Jurassic Navajo Sandstone reveal the presence of fossil forms resembling fungal filaments, some bearing hyphopodium-like structures similar to those produced by modern tropical leaf parasites. The tropical origin of the fungi is consistent with the paleogeography of the sandstone, which was deposited in a tropical arid environment. These fossil fungi are silicized, with minor amounts of CaCO3 and Fe, and in some cases a Si/Al ratio similar to smectite. They exist as pseudomorphs, totally depleted in nitrogen, adhering to the surfaces of fine-grained sands, principally quartz and orthoclase. Similar wet aeolian paleoenvironments are suspected for Mars, especially following catastrophic sediment-charged floods of enormous magnitudes that are believed to have contributed to rapid formation of large water bodies in the northern plains, ranging from lakes to oceans. These events are suspected to have contributed to a high frequency of constructional landforms (also known as pseudocraters) related to trapped volatiles and water-enriched sediment underneath a thick blanket of materials that were subsequently released to the martian surface, forming piping structures at the near surface and constructional landforms at the surface. This constructional process on Mars may help unravel the complex history of some of the piping structures observed on Earth; on Earth, evidence for the constructional landforms has been all but erased and the near-surface piping structures exposed through millions of years of differential erosion and topographic inversion now occur as high-standing promontories. If the features on both Earth and Mars formed by similar processes, especially involving water and other volatiles, and since the piping structures of Earth provided suitable environments for life to thrive in, the martian features in the northern plains should be considered as prime targets for physico/mineral/chemical/microbiological analyses once the astrobiological exploration of the red planet begins in earnest. ?? 2004 Elsevier Inc. All rights reserved.

Icarus↗
USGS1962

Nordstrandite from Guam

NORDSTRANDITE (Al 2 O 3 ·3H 2 O), previously reported only as a synthetic product 1,2 , occurs in Miocene limestone on Guam. In south Guam this limestone forms a cap several hundred feet thick, on the Mount Alifan–Mount Lamlan ridge, and overlies late Eocene and early Miocene basalt flows and volcanic conglomerates. The volcanic rocks below the limestone are deeply weathered. The nordstrandite occurs in secondary solution cavities and is concentrated mainly in the basal part of the limestone near its contact with the weathered basalt. In thin section the nordstrandite crystals are seen as flamboyant aggregates reaching lengths of as much as 0.4 mm. The optical properties of the mineral are as follows: The hardness is about 3 and the specific gravity was determined by Edward J. Young to be 2.436.

Guam↗
USGS2001

Geologic map of the Chewelah 30' x 60' Quadrangle, Washington and Idaho

This data set maps and describes the geology of the Chewelah 30' X 60' quadrangle, Washington and Idaho. Created using Environmental Systems Research Institute's ARC/INFO software, the data base consists of the following items: (1) a map coverage containing geologic contacts and units, (2) a point coverage containing site-specific geologic structural data, (3) two coverages derived from 1:100,000 Digital Line Graphs (DLG); one of which represents topographic data, and the other, cultural data, (4) two line coverages that contain cross-section lines and unit-label leaders, respectively, and (5) attribute tables for geologic units (polygons), contacts (arcs), and site-specific data (points). In addition, the data set includes the following graphic and text products: (1) A PostScript graphic plot-file containing the geologic map, topography, cultural data, and two cross sections, and on a separate sheet, a Correlation of Map Units (CMU) diagram, an abbreviated Description of Map Units (DMU), modal diagrams for granitic rocks, an index map, a regional geologic and structure map, and a key for point and line symbols; (2) PDF files of the Readme text-file and expanded Description of Map Units (DMU), and (3) this metadata file. The geologic map database contains original U.S. Geological Survey data generated by detailed field observation and by interpretation of aerial photographs. The map was compiled from geologic maps of eight 1:48,000 15' quadrangle blocks, each of which was made by mosaicing and reducing the four constituent 7.5' quadrangles. These 15' quadrangle blocks were mapped chiefly at 1:24,000 scale, but the detail of the mapping was governed by the intention that it was to be compiled at 1:48,000 scale. The compilation at 1:100,000 scale entailed necessary simplification in some areas and combining of some geologic units. Overall, however, despite a greater than two times reduction in scale, most geologic detail found on the 1:48,000 maps is retained on the 1:100,000 map. Geologic contacts across boundaries of the eight constituent quadrangles required minor adjustments, but none significant at the final 1:100,000 scale. The geologic map was compiled on a base-stable cronoflex copy of the Chewelah 30' X 60' topographic base and then scribed. The scribe guide was used to make a 0.007 mil-thick blackline clear-film, which was scanned at 1200 DPI by Optronics Specialty Company, Northridge, California. This image was converted to vector and polygon GIS layers and minimally attributed by Optronics Specialty Company. Minor hand-digitized additions were made at the USGS. Lines, points, and polygons were subsequently edited at the USGS by using standard ARC/INFO commands. Digitizing and editing artifacts significant enough to display at a scale of 1:100,000 were corrected. Within the database, geologic contacts are represented as lines (arcs), geologic units as polygons, and site-specific data as points. Polygon, arc, and point attribute tables (.pat, .aat, and .pat, respectively) uniquely identify each geologic datum.

Miscellaneous Field Studies Map↗
USGS2010

Karst map of Puerto Rico

This map is a digital compilation, combining the mapping of earlier geologists. Their work, cited on the map, contains more detailed descriptions of karst areas and landforms in Puerto Rico. This map is the basis for the Puerto Rico part of a new national karst map currently being compiled by the U.S. Geological Survey. In addition, this product is a standalone, citable source of digital karst data for Puerto Rico. Nearly 25 percent of the United States is underlain by karst terrain, and a large part of that area is undergoing urban and industrial development. Accurate delineations of karstic rocks are needed at scales suitable for national, State, and local maps. The data on this map contribute to a better understanding of subsidence hazards, groundwater contamination potential, and cave resources as well as serve as a guide to topical research on karst. Because the karst data were digitized from maps having a different scale and projection from those on the base map used for this publication, some karst features may not coincide perfectly with physiographic features portrayed on the base map.

Puerto Rico↗
USGS1977

Summary appraisals of the Nation's ground-water resources; Souris-Red-Rainy region

A broad-perspective analysis of the ground-water resources and present and possible future water development and management in the Souris-Red-Rainy Region is presented. The region includes the basins of the Souris River within Montana and North Dakota; the Red River of the North in South Dakota, North Dakota, and Minnesota; and the Rainy River within Minnesota. The region includes 59,645 square miles, mostly in North Dakota and Minnesota. The terrain is relatively flat, but ranges in altitude from 2,541 to 750 feet. Annual average precipitation ranges from 14 inches in the west to 28 inches in the east and about 75 percent of it is rain. The mean annual snow fall ranges from 32 inches in the west to 64 inches in the east. Temperatures range from -55° to 118°F (-48.3° to 47.8°C). Irrigation is needed at least part of the time to assure crop production, particularly in the western part of the region. Sand and gravel deposits in the drift form the most important fresh-water aquifers. Other aquifers are found in at least parts of the region in the Precambrian, Paleozoic, Cretaceous, and Tertiary rocks. The potentiometric surface in the bedrock generally decreases in altitude toward the Red River of the North, indicating that the general direction of ground-water movement is toward the river. Ground-water with less than 3,000 milligrams per liter dissolved solids is available throughout the region. Ground water with less than 1,000 milligrams per liter occurs in most of the region east of the Red River of the North and in most of the shallow aquifers west of the river. The total volume of water available from storage having less than 3,000 milligrams per liter dissolved solids is estimated to be 5 x 10 8 acre-feet. In addition to the fresh and slightly saline water, the region has abundant highly mineralized water that can be considered as a resource. Yields of wells in individual bedrock aquifers are generally less than 100 gallons per minute but locally yields may be as much as 500 gallons per minute and more. Yields in drift aquifers are frequently less than 100 gallons per minute but range from 5 to 1,000 gallons per minute. In a few places outwash yields more than 1,000 gallons per minute. Ground water is the sole or a primary source of water supply in much of the region, including supplies for irrigation, domestic and livestock, municipal, and industrial needs. Reportedly, the potential irrigation development is 1,550,000 acres, as compared with 50,200 acres in 1975. Both ground- and surface-water supplies would be required to meet these demands. Rural domestic and livestock water supplies are derived almost entirely from ground-water sources. Smaller communities and towns generally rely on ground water, and the cities and industries use ground water, surface water, or both. The municipalities using surface water generally depend upon reservoir storage. Water quality rather than quantity is the greater water-supply problem for many communities in the region. Increased demands on both ground-water and surface-water supplies likely will be made in the future. Storage of surface water in the ground-water reservoirs during times of surplus for withdrawal during times of scarcity would aid in meeting these demands. The surplus (flood) water is of better chemical quality than underlying ground water in parts of the western half of the region. Fresh water could be stored in saline- or fresh-water aquifers, and pumped out later, as needed. Thus, the ground-water reservoirs have a definite present and potential role in water management. To understand the hydrologic system for management purposes there is a need to determine more adequately the geologic and hydrologic characteristics of existing aquifers and the location of new aquifers. Also, as pumping and other stresses on any part of the hydrologic system affect other parts of the system, monitoring programs ideally should be started and maintained to detect changes and determine effects of the stresses. Many alternatives are available for managing water in the region. Some of these are operational and others are undergoing research. Adequate hydrologic information is needed to aid in solving problems of water supply, use and pollution.

Minnesota, Montana, North Dakota, South Dakota↗
USGS2011

Hydrogeologic framework and hydrologic budget components of the Columbia Plateau Regional Aquifer System, Washington, Oregon, and Idaho

The Columbia Plateau Regional Aquifer System (CPRAS) covers an area of about 44,000 square miles in a structural and topographic basin within the drainage of the Columbia River in Washington, Oregon, and Idaho. The primary aquifers are basalts of the Columbia River Basalt Group (CRBG) and overlying sediment. Eighty percent of the groundwater use in the study area is for irrigation, in support of a $6 billion per year agricultural economy. Water-resources issues in the Columbia Plateau include competing agricultural, domestic, and environmental demands. Groundwater levels were measured in 470 wells in 1984 and 2009; water levels declined in 83 percent of the wells, and declines greater than 25 feet were measured in 29 percent of the wells. Conceptually, the system is a series of productive basalt aquifers consisting of permeable interflow zones separated by less permeable flow interiors; in places, sedimentary aquifers overly the basalts. The aquifer system of the CPRAS includes seven hydrogeologic units-the overburden aquifer, three aquifer units in the permeable basalt rock, two confining units, and a basement confining unit. The overburden aquifer includes alluvial and colluvial valley-fill deposits; the three basalt units are the Saddle Mountains, Wanapum, and Grande Ronde Basalts and their intercalated sediments. The confining units are equivalent to the Saddle Mountains-Wanapum and Wanapum-Grande Ronde interbeds, referred to in this study as the Mabton and Vantage Interbeds, respectively. The basement confining unit, referred to as Older Bedrock, consists of pre-CRBG rocks that generally have much lower permeabilities than the basalts and are considered the base of the regional flow system. Based on specific-capacity data, median horizontal hydraulic conductivity (Kh) values for the overburden, basalt units, and bedrock are 161, 70, and 6 feet per day, respectively. Analysis of oxygen isotopes in water and carbon isotopes in dissolved inorganic carbon from groundwater samples indicates that groundwater in the CPRAS ranges in age from modern (<50 years) to Pleistocene (>10,000 years). The oldest groundwater resides in deep, downgradient locations indicating that groundwater movement and replenishment in parts of this regional aquifer system have operated on long timescales under past natural conditions, which is consistent with the length and depth of long flow paths in the system. The mean annual recharge from infiltration of precipitation for the 23-year period 1985-2007 was estimated to be 4.6 inches per year (14,980 cubic feet per second) using a polynomial regression equation based on annual precipitation and the results of recharge modeling done in the 1980s. A regional-scale hydrologic budget was developed using a monthly SOil WATer (SOWAT) Balance model to estimate irrigation-water demand, groundwater flux (recharge or discharge), direct runoff, and soil moisture within irrigated areas. Mean monthly irrigation throughout the study area peaks in July at 1.6 million acre-feet (MAF), of which 0.45 and 1.15 MAF are from groundwater and surface-water sources, respectively. Annual irrigation water use in the study area averaged 5.3 MAF during the period 1985-2007, with 1.4 MAF (or 26 percent) supplied from groundwater and 3.9 MAF supplied from surface water. Mean annual recharge from irrigation return flow in the study area was 4.2 MAF (1985-2007) with 2.1 MAF (50 percent) occurring within the predominately surface-water irrigated regions of the study area. Annual groundwater-use estimates were made for public supply, self-supplied domestic, industrial, and other uses for the period 1984 through 2009. Public supply groundwater use within the study area increased from 200,600 acre-feet per year (acre-ft/yr) in 1984 to 269,100 acre-ft/yr in 2009. Domestic self-supplied groundwater use increased from 54,580 acre-ft/yr in 1984 to 71,160 acre-ft/yr in 2009. Industrial groundwater use decreased from 53,390 acre-ft/yr in 1984 t

Scientific Investigations Report↗
USGS1978

Origin of two clay-mineral facies of the Potomac Group (Cretaceous) in the Middle Atlantic States

Sedimentary clay that crops out in the coastal plains of New Jersey, Delaware, the part of Maryland north and east of Washington, B.C., and the northeast half of Washington, D.C., in the nonmarine Cretaceous Potomac Group is predominantly kaolinite and illite. In contrast, in part of southeastern Maryland, the southwest half of Washington, D.C., and most of eastern Virginia, Potomac Group clay is predominantly montmorillonite. Kaolinite and illite were probably derived by intense acid weathering of metamorphic and granitic rocks to the west during the Cretaceous and were deposited in a well-drained basin. Montmorillonite was most likely produced by deep weathering of a mainly granitic source. Poor drainage and alkaline surface- and ground-water conditions probably accompanied the production, transportation, deposition, and burial of the montmorillonite. Kaolinization of the montmorillonite is taking place now at the surface in northern Virginia.

Delaware, Maryland, New Jersey, Pennsylvania, Virg↗
USGS2002

Environmental impacts of petroleum production: The fate of petroleum and other organics associated with produced water from the Osage-Skiatook Petroleum Environmental Research sites, Osage County, OK

We are involved in a multidisciplinary investigation to study the transport, fate, and natural attenuation of inorganic salts, trace metals, radionuclides and organic compounds present in produced water, and their impacts on soil, surface and ground water and the local ecosystem at the Osage-Skiatook Petroleum Environmental Research (OSPER) A and B sites, located in Osage County, OK. About one hectare of land at each of the OSPER A and B sites is affected by salt scarring, soil salinization and brine and petroleum contamination. The main environmental concern results because the sites are adjacent to Skiatook Lake, a 4250-hectare reservoir that provides drinking water to the local communities and is a major recreational fishery. Petroleum wells and tank batteries at the A site have been inactive for some time and the bulk of the hydrocarbon (now degraded and weathered oil) and produced water releases occurred more than 60 years ago. One pit at this site however, contains relatively fresh asphaltic oil and high salinity brine. The B site includes an active production tank battery and adjacent brine and oil pit, an inactive tank battery and an injection well with a small brine pit. For this study oil, gas and/or brine samples were obtained from several oil wells at the B site and areas adjoining the A and B sites, from the two active brine pits at the B site, from the asphaltic pit and adjacent weathered oil pit at the A site and from several of the 40 boreholes (1-71 m deep), recently drilled and completed. Water samples for dissolved organics were obtained from selected boreholes with high salinity water and measurable hydrocarbon gases in the unsaturated zone. Soil and rock core samples were obtained from these selected boreholes to determine the amount and composition of oil sorbed onto the sediments. Finally samples of sediments and/or water from these selected boreholes and from the brine and oil pits were obtained for bacterial characterization. Chemical analysis and bacterial determinations on the collected samples are continuing. Results completed to date show the crude oil source (samples from B and adjacent production wells) is a typical paraffinic-naphthenic light (API gravity of ~35) oil, containing n-alkanes as the dominant components. The four samples examined are identical in their maturity and chemical characteristics. Even though petroleum production is from shallow sandstones (300-600 m depth), these fresh oils show no sign of biodegradation, indicating that bacteria are unable to survive in the associated high salinity (~150,000 mg/L total dissolved solids) brine. Bacterial action, volatilization and water washing are likely responsible for the transformation of source oil to the surficial asphaltic and weathered oil observed at the A site. The leakage of oil with brine from the main active pit at the B site is indicated by the detection of a thin, but discrete oil phase in at least one borehole, the presence of hydrocarbon gases in several boreholes and the smell of oil in many sediment cores from the impacted area located down gradient from this pit. The measured concentrations of DOC, acetate and other organic acid anions, BTEX, phenols and other organics in the source brine are relatively low, but their values in water samples from the impacted areas are not yet available.

Oklahoma↗
USGS1987

Mineralogy and petrology of the Cretaceous- Tertiary boundary clay bed and adjacent clay-rich rocks, Raton Basin, New Mexico and Colorado.

The Cretaceous-Tertiary (K-T) boundary is preserved in a sequence of coal-bearing, fluvial rocks in the lower part of the Raton Formation (Late Cretaceous and Paleocene) at several sites in the east-central part of the Raton Basin. The K-T boundary occurs at the top of a kaolinitic claystone layer, commonly referred to as the "boundary clay layer," in an interval of coal and carbonaceous shale. The boundary is defined by the disappearance of certain fossil-pollen taxa. The boundary clay layer also contains shocked quartz grains and abundance anomalies of iridium, chromium, and other elements. Each of these characteristics support the hypothesis of an asteroid impact at the end of the Cretaceous. Small goyazite spheres were also found in the boundary clay bed; however, their origin is uncertain. X-ray powder diffraction (XRD), scanning electron microscopy (SEM), and thin-section petrography have shown that the boundary clay bed exhibits unique mineralogic and petrologic characteristics not possessed by other clay-rich beds in coal-bearing rocks of the Raton Basin. The boundary clay bed is composed primarily of well-crystallized kaolinite but also contains subordinate, randomly interstratified, mixed-layer illite/smectite, both of which appear to have been formed by the alteration of vitreous material in a coal-swamp environment. The bulk mineralogy of the boundary clay bed is similar to that of other kaolinite-rich clay beds (tonsteins) that altered in coal swamps from airfall volcanic ash. The alteration process and diagenetic products of the host material in the boundary clay bed, however, differed from those of the tonsteins, resulting in a unique petrographic fabric. The boundary clay bed is characterized by an overall imbricate fabric that may reflect an original vitreous material that included shards, bubbles, and spheres. The original fallout material of the boundary clay bed first altered to "cabbage-like" microspherules, indicating a halloysite or allophane precursor, and then to well-crystallized kaolinite; the well-crystallized kaolinite is the diagenetic stable phase for these rocks at their maximum burial conditions. In comparison, the vitreous components of the tonsteins were altered directly to coarse vermicular and platey kaolinite. Alteration of the original fallout material in the boundary bed was probably rapid, leading to hydrated, disordered, fine-grained clay minerals that formed into curled spherical or tubular shapes. The factors that produced these unique fabrics in the boundary clay bed existed at all K-T sites in the Raton Basin and were much different from those that formed the coarse platey and vermicular fabrics of ordinary tonsteins. The distinctive character of the boundary clay may be due to the unique nature and chemistry of the fallout material and (or) physical or chemical conditions existing shortly after its deposition.

Journal of Sedimentary Petrology↗
USGS2023

User’s Guide to planetary image analysis and geologic mapping in ArcGIS Pro

Geologic maps are valuable tools in planetary science. Though planetary geologic maps are similar to terrestrial (Earthbased) geologic maps, the nature of planetary exploration introduces unique challenges for geologic mappers. Terrestrial geologic mappers prepare products from field-based observation, often comparing or refining those with aerial and (or) orbital images. Planetary geologic mapping relies almost exclusively on remote observations, which are made by orbiting spacecraft. Therefore, with a few exceptions for locations with rovers, landers, or crewed surface missions, planetary geologic mappers are not able to observe their map area in detail or at smaller scales. As a result, they must interpret and describe their map features differently than those used in terrestrial geologic maps. For example, terrestrial geologic mappers commonly divide units by lithology (rock type) or grain size. However, planetary geologic mappers often do not have detailed enough information to know what type of rock or grain size is present, and instead must divide the planet’s surface into geologic units using differences in tone, color, and surface texture (at multiple scales). Cross-cutting relationships, where apparent, can provide excellent—and often crucial—observations for identifying and subdividing geologic units using orbital datasets. The process of creating planetary maps has evolved over time, from original hand-drawn maps created during the early 1800s through the late 1900s, to the fully digital products created today. Modern-day planetary geologic mapping uses Geographic Information Systems (GIS) software and tools to visualize data, delineate units and landforms, and accurately convey spatial relationships to a map user using cartographic features represented by points, lines, and polygons. This tutorial was written to familiarize both new and experienced planetary geologic mappers with ArcGIS Pro, a commonly used GIS software package developed by Esri. This tutorial introduces new planetary geologic mappers to fundamental concepts and best practices in planetary geologic mapping. For mappers with experience using ArcMap (a previous version of ArcGIS), this tutorial will help to familiarize users with new changes in layout and functionality, so current projects may be migrated into the ArcGIS Pro environment. No prior knowledge is required, although a general familiarity with geology, GIS, and planetary science is recommended. This tutorial includes links to helpful glossaries of common GIS terms and other GIS and planetary science resources in appendix 1. For additional information on planetary geologic mapping, see the U.S Geological Survey (USGS) Astrogeology NASA Planetary Geologic Mapping Program website and the Planetary Mapping Guidelines. Numerous ArcGIS tutorials are also available from Esri’s Tutorials page, through the Esri Academy catalog, and Esri’s ArcGIS Pro Resources page.

Techniques and Methods↗
USGS2006

U.S. industrial garnet

The United States presently consumes about 16 percent of global production of industrial garnet for use in abrasive airblasting, abrasive coatings, filtration media, waterjet cutting, and grinding. As of 2005, domestic garnet production has decreased from a high of 74,000 t in 1998, and imports have increased to the extent that as much as 60 percent of the garnet used in the United States in 2003 was imported, mainly from India, China, and Australia; Canada joined the list of suppliers in 2005. The principal type of garnet used is almandite (almandine), because of its specific gravity and hardness; andradite is also extensively used, although it is not as hard or dense as almandite. Most industrial-grade garnet is obtained from gneiss, amphibolite, schist, skarn, and igneous rocks and from alluvium derived from weathering and erosion of these rocks. Garnet mines and occurrences are located in 21 States, but the only presently active (2006) mines are in northern Idaho (garnet placers; one mine), southeastern Montana (garnet placers; one mine), and eastern New York (unweathered bedrock; two mines). In Idaho, garnet is mined from Tertiary and (or) Quaternary sedimentary deposits adjacent to garnetiferous metapelites that are correlated with the Wallace Formation of the Proterozoic Belt Supergroup. In New York, garnet is mined from crystalline rocks of the Adirondack Mountains that are part of the Proterozoic Grenville province, and from the southern Taconic Range that is part of the northern Appalachian Mountains. In Montana, sources of garnet in placers include amphibolite, mica schist, and gneiss of Archean age and younger granite. Two mines that were active in the recent past in southwestern Montana produced garnet from gold dredge tailings and saprolite. In this report, we review the history of garnet mining and production and describe some garnet occurrences in most of the Eastern States along the Appalachian Mountains and in some of the Western States where industrial-grade garnet or its possible occurrence has been reported. Other natural and manmade materials compete with garnet in nearly all of the applications for which garnet can be used; garnet, however, has the advantages that it is reusable, nontoxic, and nonreactive. In addition, garnet produces much less dust than other abrasive materials, and spills are relatively benign and easy to clean up.

Bulletin↗
USGS2020

Sample mounting for organic petrology: No thermal effects from transient exposure to elevated temperatures

For sample mounting, organic petrology laboratories typically use cold-setting epoxy-resin (e.g., 40 °C, used by Oklahoma Geological Survey, OGS) or heat-setting thermoplastic (e.g., 180 °C, used by U.S. Geological Survey, USGS). Previous workers have suggested a systematic huminite/vitrinite reflectance (VR o ) increase was associated with the thermoplastic preparation process, relative to epoxy mounting, which was possibly attributed to moisture loss from organic matter due to the transient high temperatures of plastic mounting. In this study, we evaluated thermal effects to low thermal maturity organic matter from transient exposure to elevated temperatures. A subbituminous coal sample was subjected to long-term (4 to 38 weeks) exposure to temperatures of 85 to 120 °C and afterward evaluated by multiple approaches to test thermal advance [elemental analyses, Rock-Eval pyrolysis, Fourier transform infrared spectroscopy (FTIR), nuclear magnetic resonance (NMR), pyrolysis gas chromatography, and petrographic analyses, including huminite/vitrinite reflectance and spectral fluorescence], all of which showed no detectable systematic (statistically insignificant) changes between the original sample and its heat-treated products. We also compared huminite/vitrinite reflectance of six low thermal maturity samples (those most likely to react to transient heating) mounted via both cold-setting epoxy-resin and heat-setting thermoplastic. Results indicate measured VR o of a sample prepared by one mounting process was within the standard deviation of reflectance for the same sample prepared via the other process. Moreover, VR o results were not systematically higher in thermoplastic mounts. Contrary to previous work, these results suggest thermoplastic mounting or other transient exposure to elevated temperatures does not impact thermal maturity estimates from reflectance measurement for low thermal maturity organic samples. Furthermore, the average interlaboratory difference in measured VR o (between OGS and USGS) for the same sample prepared by either epoxy-resin or thermoplastic mounting was 0.038%, about double the average difference between VR o for the same sample prepared via epoxy-resin versus thermoplastic in a single laboratory (0.024%). This result indicates interlaboratory variability impacts VR o measurement reproducibility to the extent that systematic differences could not be observed between thermoplastic and cold-setting sample preparation approaches, even if such differences were present.

International Journal of Coal Geology↗
USGS2011

Eruptive history of South Sister, Oregon Cascades

South Sister is southernmost and highest of the Three Sisters, three geologically dissimilar stratovolcanoes that together form a spectacular 20km reach along the Cascade crest in Oregon. North Sister is a monotonously mafic edifice as old as middle Pleistocene, Middle Sister a basalt-andesite-dacite cone built between 48 and 14ka, and South Sister is a basalt-free edifice that alternated rhyolitic and intermediate modes from 50ka to 2ka (largely contemporaneous with Middle Sister). Detailed mapping, 330 chemical analyses, and 42 radioisotopic ages show that the oldest exposed South Sister lavas were initially rhyolitic ~50ka. By ~37ka, rhyolitic lava flows and domes (72-74% SiO 2 ) began alternating with radially emplaced dacite (63-68% SiO 2 ) and andesite (59-63% SiO 2 ) lava flows. Construction of a broad cone of silicic andesite-dacite (61-64% SiO 2 ) culminated ~30ka in a dominantly explosive sequence that began with crater-forming andesitic eruptions that left fragmental deposits at least 200m thick. This was followed at ~27ka by growth of a steeply dipping summit cone of agglutinate-dominated andesite (56-60.5% SiO 2 ) and formation of a summit crater ~800m wide. This crater was soon filled and overtopped by a thick dacite lava flow and then by >150m of dacitic pyroclastic ejecta. Small-volume dacite lavas (63-67% SiO 2 ) locally cap the pyroclastic pile. A final sheet of mafic agglutinate (54-56% SiO 2 ) - the most mafic product of South Sister - erupted from and drapes the small (300-m-wide) present-day summit crater, ending a summit-building sequence that lasted until ~22ka. A 20kyr-long-hiatus was broken by rhyolite eruptions that produced (1) the Rock Mesa coulee, tephra, and satellite domelets (73.5% SiO 2 ) and (2) the Devils Chain of ~20 domes and short coulees (72.3-72.8% SiO 2 ) from N-S vent alignments on South Sister's flanks. The compositional reversal from mafic summit agglutinate to recent rhyolites epitomizes the frequently changing compositional modes of the South Sister locus throughout its lifetime. South Sister is part of a reach of the Cascades unusually active in the last 50kyr, characterized by high vent density, N-S vent alignments, and numerous eruptive units of true rhyolite (≥ 72% SiO 2 ) that distinguishes it from much of the Quaternary Cascade arc; these are eruptive expressions of the complex confluence of arc and intraplate magmatic-tectonic regimes.

Journal of Volcanology and Geothermal Research↗
USGS2022

Outgassing through magmatic fractures enables effusive eruption of silicic magma

Several mechanisms have been proposed to allow highly viscous silicic magma to outgas efficiently enough to erupt effusively. There is increasing evidence that challenges the classic foam-collapse model in which gas escapes through permeable bubble networks, and instead suggests that magmatic fracturing and/or accompanying localized fragmentation and welding within the conduit play an important role in outgassing. The 2011–2012 eruption at Cordón Caulle volcano, Chile, provides direct observations of the role of magmatic fractures. This eruption exhibited a months-long hybrid phase, in which rhyolitic lava extrusion was accompanied by vigorous gas-and-tephra venting through fractures in the lava dome surface. Some of these fractures were preserved as tuffisites (tephra-filled veins) in erupted lava and bombs. We integrate constraints from petrologic analyses of erupted products and video analyses of gas-and-tephra venting to construct a model for magma ascent in a conduit. The one-dimensional, two-phase, steady-state model considers outgassing through deforming permeable bubble networks, magmatic fractures, and adjacent wall rock. Simulations for a range of plausible magma ascent conditions indicate that the eruption of low-porosity lava observed at Cordón Caulle volcano occurs because of significant gas flux through fracture networks in the upper conduit. This modeling emphasizes the important role that outgassing through magmatic fractures plays in sustaining effusive or hybrid eruptions of silicic magma and in facilitating explosive-effusive transitions.

Puyehue Cordon Caulle volcanic complex↗
USGS1988

Ferromanganese deposits from the Gulf of Alaska Seamount Province: Mineralogy, chemistry, and origin

Ferromanganese-oxide deposits dredged from four seamounts (Welker, Miller, Murray, and Patton) in the Gulf of Alaska Seamount Province include poorly crystallized microlaminated crusts on basalt substrate, well-crystallized Mn-oxide veins in epiclastic sedimentary rocks, and crystalline Mn-oxide layers and micronodules in phosphorite. The principal rock types dredged are alkali-basalt pillow fragments and tuffaceous conglomerate and sandstone. The glassy rims of pillow fragments, the glassy goundmass of large volcanic clasts, and the tuffaceous component of the sediment are altered to palagonite. Other low-temperature alteration products include phillipsite, smectite, and carbonate-apatite.Thick (10–50 mm) Fe–Mn crusts consist mainly of δ-MnO 2 ; straight and cuspate growth laminae indicate variable growth rates and periods of nondeposition. A larger number of detrital particles toward the top of thick crusts record the increasing influence of active volcanoes of the Aleutian arc during northwestward movement of the Pacific plate. Thick crusts on basalt substrate have higher Mn/Fe ratios and lower Co content than Fe–Mn crusts from low-latitude seamounts of the central Pacific region. Thin (< 10 mm) crusts on volcaniclastic substrate contain todorokite and birnessite and have higher Mn/Fe ratios, Ni, and Cu and lower Fe and Co than thick Gulf of Alaska crusts.Veins of todorokite and cryptomelane with complex internal structure occur in altered tuffaceous sandstone and conglomerate from Miller Seamount. Fibrous todorokite has a composition similar to those of other marine examples but may contain up to 7% Mn 2+ in M2 sites. Microprobe analysis of the marine cryptomelane indicates a composition that is approximately (K,Ba) 1–2 (Mn 4+ ,Co) 7–8 O 16 ∙ x (H 2 O).A third type of Fe–Mn deposit in phosphorite is an intimate mixture of todorokite (and minor δ-MnO 2 )-bearing layers and micronodules, carbonate-apatite, and phillipsite that encloses grains of altered volcanic glass and lithic fragments.The microlaminated structure, mineralogy (predominantly δ-MnO 2 ), and composition (Mn/Fe ratio and transition metal, rare earth element, U, and Th contents) of the thick crusts are characteristic of hydrogenetic Fe–Mn crusts elsewhere in the Pacific. Conversely, the crystallinity and chemical composition of the Mn-oxide veins and thin crusts indicate formation during diagenesis of the volcanogenic sediment substrate. Mn and other transition metals are mobilized during low-temperature oxidative alteration (palagonitization) of basaltic volcanic glass; the oxidation of Fe 2+ to Fe 3+ during palagonitization and the dissolution of the dilute biogenic fraction of the sediment combine to lower the Eh of ambient pore fluid and enhance the mobility of Mn 2+ . Diagenesis in the phosphatic sandstone from Patton Seamount involves organic-rich sediment and pore waters elevated in phosphorus owing to upwelling above a large volcanic edifice.

Alaska↗
USGS1980

Summary of regional geology, petroleum potential, resource assessment and environmental considerations for oil and gas lease sale area #56

This report summarizes our general knowledge of the petroleum potential, as well as problems and hazards associated with development of petroleum resources in the area proposed for nominations for lease sale number 56. This area includes the U.S. eastern continental margin from the North Carolina-Virginia border south to approximately Cape Canaveral, Florida and from three miles from shore, seaward to include the upper Continental Slope and inner Blake Plateau. The area for possible sales is shown in figure 1; major physiographic features of the region are shown in figure 2. No wells have been drilled for petroleum within this proposed lease area and no significant commercial production has been obtained onshore in the Southeast Georgia Embayment. The COST GE-1 stratigraphic test well, drilled on the Continental Shelf off Jacksonville, Fla. (fig- 1), reached basement at 3,300 m. The bottom third of the section consists of dominantly continental rocks that are typically poor sources of petroleum (Scholle, 1979) and the rocks that contain organic carbon adequate for generation of petroleum at the well are seen in seismic profiles always at shallow subbottom depths, so they probably have not reached thermal maturity. However, seismic profiles indicate that the sedimentary deposits thicken markedly in a seaward direction where more of the section was deposited under marine conditions; therefore, commercial accumulations of petroleum offshore are more likely. Several potential sources of environmental hazard exist. Among the most important are hurricanes, the Gulf Stream, and earthquakes. The potential danger from high wind, waves, storm surges, and storm-driven currents associated with hurricanes is obvious. Evidence for significant bottom scour by the Gulf Stream is abundant; such scour is a threat to the stability of bottom-mounted structures. The fast-flowing water also will hamper floating drill rigs and control of drill strings. A major earthquake of about magnitude 6.8 struck Charleston in 1886; it may have been associated with a zone of active seismicity that crosses South Carolina. The likelihood of a repetition of the 1886 event is presently not predictable but a seismic hazard must be assumed to exist.

Open-File Report↗
USGS2006

Hydrogeologic framework refinement, ground-water flow and storage, water-chemistry analyses, and water-budget components of the Yuma area, southwestern Arizona and southeastern California

The ground-water and surface-water system in the Yuma area in southwestern Arizona and southeastern California is managed intensely to meet water-delivery requirements of customers in the United States, to manage high ground-water levels in the valleys, and to maintain treaty-mandated water-quality and quantity requirements of Mexico. The following components in this report, which were identified to be useful in the development of a ground-water management model, are: (1) refinement of the hydrogeologic framework; (2) updated water-level maps, general ground-water flow patterns, and an estimate of the amount of ground water stored in the mound under Yuma Mesa; (3) review and documentation of the ground-water budget calculated by the Bureau of Reclamation, U.S. Department of the Interior (Reclamation); and (4) water-chemistry characterization to identify the spatial distribution of water quality, information on sources and ages of ground water, and information about the productive-interval depths of the aquifer. A refined three-dimensional digital hydrogeologic framework model includes the following hydrogeologic units from bottom to top: (1) the effective hydrologic basement of the basin aquifer, which includes the Pliocene Bouse Formation, Tertiary volcanic and sedimentary rocks, and pre-Tertiary metamorphic and plutonic rocks; (2) undifferentiated lower units to represent the Pliocene transition zone and wedge zone; (3) coarse-gravel unit; (4) lower, middle, and upper basin fill to represent the upper, fine-grained zone between the top of the coarse-gravel unit and the land surface; and (5) clay A and clay B. Data for the refined model includes digital elevation models, borehole lithology data, geophysical data, and structural data to represent the geometry of the hydrogeologic units. The top surface of the coarse-gravel unit, defined by using borehole and geophysical data, varies similarly to terraces resulting from the down cutting of the Colorado River. Clay A is nearly the same as the previous conceptual hydrogeologic model definition (Olmsted and others, 1973), except for a minor westward extension from the city of Yuma. Clay B is extended to the southerly international boundary and increased in areal extent by about two-thirds of the original extent (Olmsted and others, 1973). The other hydrogeologic units generally are the same as in the previous conceptual hydrogeologic model. Before development, the Colorado and Gila Rivers were the sources of nearly all the ground water in the Yuma area through direct infiltration of water from river channels and annual overbank flooding. After construction of upstream reservoirs and clearing and irrigation of the floodplains, the rivers now act as drains for the ground water. Ground-water levels in most of the Yuma area are higher now than they were in predevelopment time. A general gradient of ground-water flow toward the natural discharge area south of the Yuma area still exists, but many other changes in flow are evident. Ground water in Yuma Valley once flowed away from the Colorado River, but now has a component of flow towards the river and Mexicali Valley. A ground-water mound has formed under Yuma Mesa from long-term surface-water irrigation; about 600,000 to 800,000 acre-ft of water are stored in the mound. Ground-water withdrawals adjacent to the southerly international boundary have resulted in water-level declines in that area. The reviewed and documented water budget includes the following components: (1) recharge in irrigated areas, (2) evapotranspiration by irrigated crops and phreatophytes, (3) ground-water return flow to the Colorado River, and (4) ground-water withdrawals (including those in Mexicali Valley). Recharge components were calculated by subtracting the amount of water used by crops from the amount of water delivered. Evapotranspiration rates were calculated on the basis of established methods, thus were appropriate for input to the ground-water flow model developed by the Bureau of Reclamation (William Greer, hydrologist, Bureau of Reclamation, written commun., 2005). Evapotranspiration by crops and phreatophytes were calculated by using crop coefficient methods and meteorological data. Other methods of calculating evapotranspiration rates by using combinations of satellite imagery and ground-based data could be used for higher spatial and temporal resolution. Ground-water return flow during years of low flow on the Colorado River (1972–82, 1987–92, and 1994–96) averaged 79,000 acre-ft per year. Ground-water withdrawal data for 1970–99 were similar to other estimates made by the U.S. Geological Survey for the Yuma area. New water-chemistry data were collected in 12 wells and 8 canals/drains to characterize spatial patterns in chemical constituents, determine isotopic ages of water, infer possible sources of ground water, and locate the vertical intervals of the aquifer that contribute most water to wells. Depth-dependent samples were collected at one of the wells (YM-10). A large quantity of water-quality data were compiled from Bureau of Reclamation and U.S. Geological Survey records and merged into the U.S. Geological Survey National Water Information System database. New samples were analyzed for major ions, nutrients, stable isotopes of oxygen and hydrogen, tritium ( 3 H), and carbon-14 ( 14 C) (along with C 13 /C 12 ratios). Light values of oxygen-18 ( 18 O) and deuterium ( 2 H, D) in well 242-2 indicate recharge from the Colorado River. Heavy water samples from wells 242-22, CADC, and Mesa del Sol indicate local recharge sources. Tritium data indicate there is young water in wells in the valleys and near the edge of Yuma Mesa, while older water is found far from the Colorado River. 14 C data indicate that water from wells near the southerly international boundary is at least several thousand years old.

Arizona, California↗