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USGS2026

A deep dive into subduction zones and the Japan Trench

Deep beneath the ocean, giant slabs of rock slide beneath one another in areas called subduction zones. These powerful movements shape the planet by building mountains, creating fiery volcanoes, and even causing huge earthquakes. Scientists study subduction zones to understand why these natural events happen and where and how they might occur so we can be better prepared. One important subduction zone is the Japan Trench, where a big earthquake happened in 2011. To learn more about subduction zones, scientists go on ocean drilling expeditions. They sail on research ships, drill into the seafloor, and collect rock samples. These samples help scientists understand what happened in the past and how subduction zones work. In turn, this information helps communities better understand and prepare for future earthquakes.

Frontiers for Young Minds↗
USGS2025

Hydrogeology and groundwater quality in the Snake River alluvial aquifer at Jackson Hole Airport, Wyoming, 2011–20

The Snake River alluvial aquifer underlying the Jackson Hole Airport (JHA) in northwest Wyoming is an important source of water used for domestic, commercial, and irrigation purposes by the airport and nearby residents. The U.S. Geological Survey, in response to previously identified water-quality concerns in the area, monitored and evaluated changes in hydrogeologic characteristics and groundwater-quality conditions of the alluvial aquifer during 2011–20. During that period, the Jackson Hole Airport made several changes that potentially improved water quality at and downgradient from the airport. Well, water level, and hydrogeologic data were collected from the alluvial aquifer to identify hydrogeologic characteristic and groundwater quality changes. Additionally, results of statistical tests were applied to water-quality results to evaluate trends in selected physical properties and constituent concentrations with time. The trends of those data show that water quality did improve overall during the study period compared to previously collected data. Presumably, these trends are in response to the changes in the aircraft deicing/anti-icing fluid (ADAF) formulation used by the JHA, the many JHA infrastructure improvements made during 2011–20, the degradation of existing ADAFs in subsurface soils and groundwater, or some combination of these possibilities.

Wyoming↗
USGS2025

Depth of magma crystallization and fluid exsolution beneath the porphyry-skarn Cu deposits at Santa Rita and Hanover-Fierro, New Mexico, USA

The depth level at which porphyry Cu–forming magmas fractionated and exsolved mineralizing fluids is actively debated. In the classic model, extensive magma fractionation occurs in large, upper crustal magma chambers, and concomitant fluid exsolution leads to forceful expulsion of residual magmas in the form of porphyry dikes, stocks, and breccia pipes, which subsequently serve as pathways for the mineralizing fluids. In contrast, some recent studies highlighting the role of deep crustal magma fractionation in the production of fertile magmas essentially deny the existence of upper crustal magma chambers at the time of mineralization. To address this, we conducted a detailed thermobarometric investigation of 13 intermediate to felsic, porphyritic intrusive rocks related to porphyry-skarn Cu mineralization at Santa Rita and Hanover-Fierro, New Mexico, United States, representing two premineralization magmas (61–60 Ma), seven synmineralization magmas (60–58 Ma), and four late- to postmineralization magmas (58–57 Ma). For each sample, the pressure of last magma crystallization before final magma ascent to the current exposure level was reconstructed based on Al-in-hornblende barometry of small hornblende inclusions trapped within quartz phenocrysts and through titanium-in-quartz (TitaniQ) thermobarometry of the host quartz phenocrysts themselves. Since quartz is one of the last crystallizing magmatic minerals, and no significant phenocryst growth could have occurred in small dikes and stocks after final magma emplacement, quartz phenocrysts and their contained hornblende inclusions record the depth of last magma crystallization before final magma ascent. When present, hornblende phenocrysts and hornblende inclusions within other major phenocrysts were also analyzed. Both quartz and hornblende barometers return consistent average pressures of 3.2 ± 0.4 kbar for the entire suite of pre- to postmineralization magmas, corresponding to depths of 11 to 14 km. The synmineralization magmas return even more consistent average pressures of 3.1 ± 0.2 kbar, corresponding to a depth of 12 ± 1 km. The volume of the mineralizing porphyry dikes and stocks at the emplacement level is far too small to have provided all the fluids and metals required to form the observed ore deposits. Therefore, the majority of the ore-forming fluids must have originated from the magmas that crystallized at 12 ± 1 km depth. The ore deposits, conversely, formed at ~5-km paleodepth. This implies that most of the mineralizing fluids traveled an average vertical distance of ~7 km from their magmatic source to the eventual site of ore precipitation. The relatively unaltered nature and low veining degree of deeper parts of mineralized porphyry dikes and stocks suggest that the fluid transport through these intrusive bodies occurred mostly at near-solidus conditions by means of fluid percolation along grain boundaries. In summary, our results suggest that (1) a large, upper crustal pluton exists ~7 km beneath the Santa Rita and Hanover-Fierro deposits; (2) abundant phenocryst crystallization occurred at this depth level; and (3) this pluton was the main source for the exsolution of ore-forming fluids. However, the investigated rocks have elevated whole-rock Sr/Y ratios, indicating magma fractionation at deep crustal levels. As a result, our preferred model is a combination of the two end-member models introduced above, with most magma fractionation having occurred in the deep crust and with residual, intermediate to felsic melts having ascended and accumulated at 11 to 14 km paleodepth, where they continued to crystallize with comparatively little crystal-liquid separation, before some of these magmas ascended further to shallow levels and quenched to porphyries.

New Mexico↗
USGS2026

Groundwater drought in the United States: Spatial and temporal variability

Many communities and ecosystems in the United States that are dependent on groundwater are potentially adversely affected by groundwater drought. We computed yearly groundwater-drought metrics and mean groundwater levels at well locations across the conterminous United States (CONUS), using data from wells and remotely sensed and modeled Gravity Recovery and Climate Experiment Drought Monitor Data Assimilation (GRACE-DADM). We also modeled the probability of low or high human impact at each well location. The spatial distribution of groundwater-drought duration and severity from 2001 to 2020 for 1,510 wells shows longer maximum duration and higher maximum severity events in drier regions like the Southwest than in wetter regions like the Northeast. Based on 613 wells in CONUS from 1981 to 2020, there are many significant decreases in drought duration and severity in the Northeast and many significant increases in annual-mean groundwater levels. In contrast, there are many significant increases in drought metrics and decreases in mean water levels in parts of the Southeast. There are major differences in trends from 2001 to 2020 between well-based and GRACE-DADM-based groundwater metrics in some CONUS regions and a very low correlation between trends at individual locations across CONUS. A potential reason for this disparity is the low GRACE-DADM resolution (∼12 km) and the potential for a large amount of groundwater variation at the local scale. Also, GRACE-DADM represents shallow, unconfined aquifers which may not match the screened interval of the monitoring wells we evaluated. Large spatial gaps in long-term, high frequency, and quality-assured groundwater-well monitoring data present a challenge for understanding groundwater-drought variability across CONUS. Remote sensing tools such as GRACE can help but cannot fully replace well monitoring, as highlighted by our study results. Substantially more long-term monitoring wells would more accurately represent groundwater-drought trends and spatial variability across CONUS, particularly in western regions.

conterminous United States↗
USGS1984

Techniques for estimating magnitude and frequency of floods on streams in Indiana

Equations are presented for estimating the magnitude and frequency of floods at ungaged sites on unregulated and nonurban streams in Indiana. The equations were developed by multiple-regression, analysis of basin characteristics and peak-flow statistical data from 242 gaged locations in Indiana, Ohio, and Illinois. The State of Indiana was divided into seven areas on the basis of the regression analysis. A set of equations for estimating peak discharges with recurrence intervals of 2, IO, 25, 50, and 100 years was developed for each area. Significant basin characteristics in the equations are drainage area, channel length, channel slope, mean annual precipitation, storage, precipitation intensity, and a runoff coefficient. Standard errors of estimate for the equations range from 24 to 45 percent. Methods are also presented for estimating flood magnitude and frequency at sites on gaged streams. Flood-frequency data based on observed peaks are given for 270 gaged locations. Twenty of these are on regulated streams, and six are on urban streams. Basin characteristics are also included car 245 of the gaged locations on unregulated and nonurban streams. No techniques are given for estimating flood magnitude and frequency at ungaged sites on regulated or urban streams. A rainfall-runoff model was tlsed to synthesize long-term peak data at 11 gaged locations on small streams. Flood-frequency curves developed from the long-term synthetic data were combined with curves based on short-term observed data to provide weighted estimates of flood magnitude and frequency at the rainfall-runoff stations.

Indiana↗
USGS2024

Characterization of groundwater resources near the southeastern part of Puget Sound, Washington

More than 1 million people live within the active model area (AMA) in the southeastern part of the lowlands surrounding Puget Sound, or Puget Lowland, Washington, and groundwater is the source for approximately one-half of their public, domestic, and irrigation water demands. The 887-square-mile AMA, located in King and Pierce Counties, represents the area of analysis for the conceptual hydrogeologic framework and numerical groundwater-flow models within the study area and includes the Puyallup River and Chambers-Clover Creek watersheds. To assess the potential hydrologic and anthropogenic impacts to groundwater and the connected surface-water resources, conceptual and numerical groundwater-flow models of groundwater flow were developed by the U.S. Geological Survey Washington Water Science Center in close cooperation with 18 water-resource agencies and stakeholders. This multichapter volume documents the development of the conceptual and numerical groundwater-flow models of groundwater flow. Chapters A, B, and C provide an overall introduction to the multichapter volume (Chapter A), the conceptual hydrogeologic framework (Chapter B), and the groundwater budget (Chapter C). Chapters D and E describe numerical groundwater-flow model construction and calibration (Chapter D) and the numerical groundwater-flow model results (Chapter E). Collectively, these reports present a characterization and simulation tool for groundwater resources near the southeastern part of Puget Sound, Washington.

Scientific Investigations Report↗
USGS2025

Cancer risk and estimated lithium exposure in drinking groundwater in the US

Importance Lithium is a naturally occurring element in drinking water and is commonly used as a mood-stabilizing medication. Although clinical studies have reported associations between receiving lithium treatment and reduced cancer risk among patients with bipolar disorder, to our knowledge, the association between environmental lithium exposure and cancer risk has never been studied in the general population. Objectives To evaluate the association between exposure to lithium in drinking groundwater and cancer risk in the general population. Design, Setting, and Participants This cohort study included participants with electronic health record and residential address information but without cancer history at baseline from the All of Us Research Program between May 31, 2017, and June 30, 2022. Participants were followed up until February 15, 2023. Statistical analysis was performed from September 2023 through October 2024. Exposure Lithium concentration in groundwater, based on kriging interpolation of publicly available US Geological Survey data on lithium concentration for 4700 wells across the contiguous US between May 12, 1999, and November 6, 2018. Main Outcome and Measures The main outcome was cancer diagnosis or condition, obtained from electronic health records. Stratified Cox proportional hazards regression models were used to estimate the hazard ratios (HRs) and 95% CIs for risk of cancer overall and individual cancer types for increasing quintiles of the estimated lithium exposure in drinking groundwater, adjusting for socioeconomic, behavioral, and neighborhood-level variables. The analysis was further conducted in the western and eastern halves of the US and restricted to long-term residents living at their current address for at least 3 years. Results A total of 252 178 participants were included (median age, 52 years [IQR, 36-64 years]; 60.1% female). The median follow-up time was 3.6 years (IQR, 3.0-4.3 years), and 7573 incident cancer cases were identified. Higher estimated lithium exposure was consistently associated with reduced cancer risk. Compared with the first (lowest) quintile of lithium exposure, the HR for all cancers was 0.49 (95% CI, 0.31-0.78) for the fourth quintile and 0.29 (95% CI, 0.15-0.55) for the fifth quintile. These associations were found for all cancer types investigated in both females and males, among long-term residents, and in both western and eastern states. For example, for the fifth vs first quintile of lithium exposure for all cancers, the HR was 0.17 (95% CI, 0.07-0.42) in females and 0.13 (95% CI, 0.04-0.38) in males; for long-term residents, the HR was 0.32 (95% CI, 0.15-0.66) in females and 0.24 (95% CI, 0.11-0.52) in males; and the HR was 0.01 (95% CI, 0.00-0.09) in western states and 0.34 (95% CI, 0.21-0.57) in eastern states. Conclusions and Relevance In this cohort study of 252 178 participants, estimated lithium exposure in drinking groundwater was associated with reduced cancer risk. Given the sparse evidence and unknown mechanisms of this association, follow-up investigation is warranted.

contiguous United States↗
USGS2024

Ambient flow and transport in long-screened, sand-packed wells: Insights into cross contamination and wellbore flow

The presence of long-screened wells with a surrounding sand pack can have a major effect on the redistribution of contaminants in groundwater, particularly when the wells are set in low-hydraulic conductivity aquifers. Such redistribution, or cross contamination, can occur through vertical flow and advective transport or by in-well mixing via multiple non-advective transport processes. A multi-method approach, including the use of single borehole dilution tracer (SBDT) logging, was undertaken to estimate vertical transport of trichloroethylene (TCE) in 8 discontinued remedial extraction wells, all constructed with long screens (100 ft, or 30.6 m long) and surrounding sand packs, at Site 25, Edwards Air Force Base, California. The site is within an enclosed drainage basin that is underlain primarily by quartz-monzonite-granitic rocks in various states of weathering. Prior to this study, little information was available on the depths of fracture zones intersecting the wellbores. Results indicate that because of in-well mixing processes, a potential redistribution of TCE of up to 9 g/d per well occurs as a consequence of leaving the wells inactive (unpumped) and unsealed, as measured by SBDT logging. Simulations of flow made with a generic model of the site show that if the wells were to be sealed with well liners, with the intent of reducing vertical TCE transport but the sand pack left intact, TCE transport decreases by 53% overall compared to leaving the wells unlined.

Environmental Earth Sciences↗
USGS2025

Pre-Acadian tectonics of the eastern Orange-Milford Belt, south-central Connecticut

This excursion presents a reinterpretation of mapping and new analytical data from the eastern Orange-Milford belt (OMB) in south-central Connecticut. The OMB is a fault-bound terrane of argillites and mafic rocks of anomalously low metamorphic grade—and of poorly constrained ages and tectonic affinity—wedged between kyanite/sillimanite-grade peri- Laurentian rocks to the west and anatectic peri-Gondwanan rocks to the east (Fig. 1A). Our data demonstrate that Ordovician(?) igneous and sedimentary rocks of the OMB were variably metamorphosed in the Ordovician and Silurian but escaped regionally pervasive, high-grade Devonian and later metamorphism. Previous interpretations (Fritts 1963a, 1965a, 1965b; Burger, 1967; Burger and others, 1968; Rodgers, 1985) described these rocks as a conformable sequence of low-grade, Ordovician to Devonian metasediments and metavolcanics. Our results reveal that the “metavolcanics” are not extrusive rocks but rather slivers of lower oceanic crust with complicated high- and low-grade metamorphic fabrics, intruded by a swarm of Silurian sheeted basalt dikes, and in fault contact with the surrounding metasediments. The purpose of this trip is to show evidence of early Paleozoic (Taconic) deformation and metamorphism preserved in rocks of the eastern OMB. These rocks remained shallow, cool, and sufficiently dry during the regionally dominant Acadian and Alleghanian orogenies to have avoided significant overprinting. As such, these rocks serve as windows into a geologic history otherwise unavailable between anatectic rocks of the peri-Gondwanan Bronson Hill, Avalon, and Gander terranes east of the Hartford basin and sillimanite-grade rocks of the peri-Laurentian Hartland and gneiss dome belts west of the OMB. We present major and trace element geochemistry including rare-earth element patterns for all mafic units in the eastern OMB as well as 40 Ar/ 39 Ar age spectra of amphibole, muscovite, and K-feldspar from rocks of the Maltby Lakes complex (of Deasy and others, 2017), Savin Schist, and Wepawaug Schist. Our evidence demonstrates that the units of the OMB have been assembled by faulting or intrusion, and that no stratigraphic relationships exist between the argillaceous schists and the metaigneous rocks.

Connecticut↗
USGS1993

Ground-water quality near an inactive landfill and sludge-spreading area, Tallahassee, Florida

Ground-water quality of a 120-acre area encompassing an inactive landfill southwest of Tallahassee, Florida, was assessed by installing and sampling 21 monitoring wells. Sludge from a municipal sewage-treatment plant was also applied to the land surface near the landfill site. Water samples were collected from the 21 monitoring wells from June 1987 through September 1990 and analyzed for concentrations of major ions, nitrogen species, trace metals, field measurements, and more than 140 organic constituents. Water quality in the Upper Floridan aquifer at the study site was compared to background water quality in other areas of Leon County. Ground-water quality of the study site was evaluated by the location of wells sampled in relation to the landfill and the sludge-spreading areas. Results of nonparametric statistical analysis indicated that potassium and nitrite plus nitrate as nitrogen concentrations in water samples from wells completed in the Upper Floridan aquifer at the study site were significantly different at the 5 percent probability level from those in samples from background wells completed in this aquifer in Leon County. Median potassium concentrations were 0.4 mg/L (milligrams per liter) in water from wells at the study site and 0.7 mg/L in water from background wells in Leon County. Median nitrite plus nitrate concentrations were 6.48 mg/L in water samples from wells at the study site and 0.51 mg/L in water samples from background wells. Graphical comparison of the water quality characteristics in water from six categories of wells; upgradient, landfill, adjacent to the landfill, downgradient onsite, downgradient offsite, and background Leon County, indicated that sodium, bicarbonate, sulfate, iron, manganese, and dissolved solids concentrations and specific conductance values were highest within the landfill. Upgradient and downgradient well categories include wells in areas affected by sludge spreading. Localized reducing conditions were indicated in a downgradient area by median iron concentrations of 930 and 30 ug/L (micrograms per liter) in samples from wells only 5 feet apart. Nitrite plus nitrate concentrations were lowest in water from wells in the landfill compared to water from the other categories. Concentrations of most trace elements and organic compounds were mostly below detection limits, although State maximum contaminant levels of 1 ug/L for benzene and vinyl chloride and 3 ug/L for tetrachloroethene were exceeded in 14 samples. Concentrations of sodium, potassium, chloride, sulfate, nitrite plus nitrate, total organic and ammonia nitrogen, and ammonia nitrogen in ground water were statistically analyzed in areas affected by sludge-spreading and other areas. Only nitrite plus nitrate and chloride concentrations were significantly different between the two areas. Median nitrite plus nitrate and chloride concentrations in sludge-spreading areas were 6.9 mg/L and 2.9 mg/L, respectively, compared to 1.1 mg/L and 1.8 mg/L in other areas.

Florida↗
USGS2026

Aspergillosis (Avian) case definition for wildlife

Diagnostic laboratories receive carcasses and samples for diagnostic evaluation and pathogen/toxin detection. Case definitions bring clarity and consistency to the evaluation process. Their use within and between organizations allows more uniform reporting of diseases and etiologic agents. The intent of a case definition is to provide scientifically based criteria for determining: (a) if an individual carcass has a specific disease and degree of confidence in that diagnosis and (b) if there is evidence of a pathogen or toxin in a carcass or sample (for example, swab, tissue sample, skin scraping, blood/serum sample, environmental sample, or other). This case definition is specific to aspergillosis and applies to all avian species.

Techniques and Methods↗
USGS2025

Rapid fault healing from cementation controls the dynamics of deep slow slip and tremor

Despite its status as one of the most important discoveries in geophysics, the physical mechanism(s) responsible for slow slip events (SSEs) are not well understood. Here, we synthesize observations of deep SSEs in the Cascadia Subduction Zone and argue that rapid, cohesive fault strengthening may control the dynamics of deep SSEs. Cohesive strength is frequently ignored in constitutive laws used to describe fault rheology in numerical simulations of earthquakes and SSEs alike. To demonstrate its importance, we perform and analyze a suite of petrological experiments that simulate fault healing under representative pressure and temperature conditions. We show that significant cohesive strength recovery caused by dissolution-precipitation processes occurs on timescales of just a few hours. Together, our experimental and observational results support the idea that cohesion is a key component of fault strength under SSE conditions and highlight the need for its inclusion in both future experiments and numerical models of fault slip.

British Columbia, Washington↗
USGS2025

Unveiling coseismic deformation from differenced legacy aerial photography and modern lidar topography: The 1983 M6.9 Borah Peak earthquake, Idaho, USA

The 1983 M6.9 Borah Peak, Idaho, earthquake is one of the largest historical normal fault earthquakes in the western United States. We quantified meter-scale vertical change along the 35 km-long rupture using topographic differencing of 1966 aerial imagery and 2019 lidar-derived data. The initial differencing results are largely obscured by horizontal and vertical georeferencing errors and flight-line stripes. Our error corrections are designed to be insensitive to the coseismic deformation and reduced error by 50%. We calculated vertical separation and resolved a maximum of 2.02 ± 0.46 m at Doublespring Pass. Our vertical separation measurements are generally consistent with those from prior studies using field data and post-earthquake topographic data. However, the differencing measurements are a few decimeters lower than these prior measurements, indicating that differencing can isolate historical from prehistoric earthquake deformation. Our study demonstrates that revisiting historical earthquakes can provide new insights into the magnitude and patterns of coseismic deformation.

Idaho↗
USGS2026

USGS 2025 critical minerals review

The United States Geological Survey (USGS) provides scientific information for the Department of Interior and the nation, consistent with its original mission expressed in the Organic Act of 1879 (43 U.S.C. 31): “the classification of the public lands and examination of the geological structure, mineral resources, and products within and outside the national domain.” Legislation such as the Energy Act of 2020 and the 2022 Infrastructure Investment and Jobs Act (43 USC 31l) and recent executive actions (Executive Orders 14154 , 14153, 14241 Secretary’s Orders 3417, 3418, 3422, 3436) underscore the importance of mineral resources and focus USGS activities on mapping and assessing mineral resources, with a particular focus on those presently identified as critical, both in ground and above ground in mine wastes. This article reviews selected activities and accomplishments by the USGS Mineral Resources Program related to critical minerals in 2025. Highlights include a new List of Critical Minerals, a first-ever national mine waste inventory, international minerals partnerships, mineral resource assessment advancements, and national data collection activities and outcomes of the Earth Mapping Resources Initiative (Earth MRI). The selected contributions are not comprehensive but are intended to demonstrate USGS leadership in critical mineral mapping and assessment, the importance of domestic and global partnerships, and the breadth of research activities that are responsive to national needs and priorities.

Mining Engineering↗
USGS2025

Hydrogeology of unconsolidated and bedrock aquifers along the Salmon River, including Malone, Franklin County, New York

The U.S. Geological Survey, in cooperation with the New York State Department of Environmental Conservation, investigated the hydrogeology of the unconsolidated and bedrock aquifers along the Salmon River corridor in northern Franklin County, New York. The study area covers roughly 147 square miles and includes the village of Malone and parts of the Towns of Malone, Bellmont, Burke, Constable, Westville, Bangor, Duane, and Franklin, New York. Groundwater is the primary source for water supply within the study area. Eighty-three percent of all residents use public water supplied from two production wells that draw water from a thick, highly productive sand-and-gravel aquifer likely receiving induced infiltration from the Salmon River. Twenty-four percent of the 187 verified domestic wells in the study area outside of the production well service area boundary are screened in typically discontinuous deposits of stratified sand and sand and gravel. Seventy-six percent of the wells are completed in bedrock aquifers including the Potsdam Sandstone, metamorphic rocks, Theresa Formation, and unknown bedrock. Characterizing and understanding potential groundwater resources is critical for protecting the quality of the groundwater. The information in this report may be used to guide delineation of groundwater contributing areas, assess potential threats to aquifers from both point and nonpoint sources, respond to contamination from spills or leaks from underground storage facilities or other sources, and to support assessments for future development of municipal water supplies.

New York↗
USGS1976

Technique for estimating magnitude and frequency of floods in Kentucky

This report presents flood magnitude and frequency relations applicable to unregulated streams in Kentucky. The relations are based on flood data at 117 gaging stations in Kentucky and 14 in adjacent states having 10 or more years of record not significantly affected by man-made changes. Equations that relate flood magnitude and frequency to contributing drainage area in 16 geographic areas may be used to estimate magnitude of future floods with recurrence intervals of as much as 100 years on gaged and ungaged streams having drainage areas of 10 to 4,300 square miles (25 .9 to 11,100 square kilometers) . Estimating equations are also presented in graphical form for the convenience of the user. Additional graphs are presented to estimate flood magnitude for selected recurrence intervals along the Cumberland, Kentucky, and Ohio Rivers.

Kentucky↗
USGS2025

The δ13C signature of dissolved organic and inorganic carbon reveals complex carbon transformations within a salt marsh

Coastal wetlands have high rates of atmospheric CO 2 uptake, which is subsequently respired back to the atmosphere, stored as organic matter within flooded, anoxic soils, or exported to the coastal ocean. Transformation of fixed carbon occurs through a variety of subsurface aerobic and anaerobic microbial processes, and results in a large inventory of dissolved carbon. Carbon source and the roles of aerobic respiration, sulfate reduction, and methane cycling were evaluated within salt marsh peat and the underlying sandy subterranean estuary. There is a large increase in dissolved inorganic carbon (DIC, 7,350 ± 3,900 μmol L −1 ), dissolved organic carbon (DOC, 1,040 ± 1,480 μmol L −1 ) and CH 4 (14.5 ± 33.3 μmol L −1 ) within the marsh porewaters compared to creek waters. Alkalinity production (5,730 ± 2,170 μeq L −1 ) and sulfate removal (1,810 ± 1,970 μmol L −1 ) indicate anaerobic respiration, however, relative contributions from the various decomposition pathways cannot be identified due to overlapping geochemical signatures. The δ 13 C of the DOC (−29.0 ± 3.7‰) and DIC (−11.2 ± 1.1‰) produced within the marsh differed from the bulk soil organic matter δ 13 C (−14.5 ± 0.2‰). We explore a variety of mechanisms that could result in co-occurring depleted δ 13 C-DOC and enriched δ 13 C-DIC compared to the bulk soil organic carbon pool and salt marsh vegetation, including selective mineralization, production of δ 13 C-depleted bacterial biomass, and methane-derived DOC. While important questions remain about carbon cycling pathways, we found evidence of a cryptic methane cycle. Alteration of the δ 13 C of carbon species complicates source attribution in solid and dissolved phases and careful consideration should be used when carbon is partitioned between in situ salt marsh production and external marine and terrestrial sources.

Massachusetts↗