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A guide to the proper selection and use of federally approved sediment and water-quality samplers

The Federal Interagency Sedimentation Project (FISP) was created in 1939 to unify and standardize the research and development activities of Federal agencies involved in fluvial sediment studies1,2. Research and development conducted by the FISP originally focused on hydraulic and mechanical aspects of sediment sampling. The mission of the FISP has expanded to provide, identify, and evaluate tools and techniques for accurate, standardized, calibrated, cost-efficient, and safe measurement and analysis of sediment properties and transport. FISP activities focus on measurement and analysis of suspended sediment, bedload sediment, bed material, bed topography, adsorbed constituents, sediment characteristics, and water quality. Sponsoring agencies and the public gain a distinct advantage from the cooperative action that leads to common standards, methods, equipment, and procedures for the measurement and characterization of sediment. As interest in the health of rivers and streams increases3, and new water-quality regulations4 are promulgated, interest in sediment and water-quality sampling equipment and technologies has increased. While much information on the subject exists, a comprehensive summary document of sediment sampling equipment and technology is lacking. This report seeks to provide such a summary.

Open-File Report↗

Particle atlas of World Trade Center dust

The United States Environmental Protection Agency (EPA) has begun a reassessment of the presence of World Trade Center (WTC) dust in residences, public buildings, and office spaces in New York City, New York. Background dust samples collected from residences, public buildings, and office spaces will be analyzed by multiple laboratories for the presence of WTC dust. Other laboratories are currently studying WTC dust for other purposes, such as health effects studies. To assist in inter-laboratory consistency for identification of WTC dust components, this particle atlas of phases in WTC dust has been compiled.

Open-File Report↗

USGS Tampa Bay Pilot Study

Many of the nation's estuaries have been environmentally stressed since the turn of the 20th century and will continue to be impacted in the future. Tampa Bay, one the Gulf of Mexico's largest estuaries, exemplifies the threats that our estuaries face (EPA Report 2001, Tampa Bay Estuary Program-Comprehensive Conservation and Management Plan (TBEP-CCMP)). More than 2 million people live in the Tampa Bay watershed, and the population constitutes to grow. Demand for freshwater resources, conversion of undeveloped areas to resident and industrial uses, increases in storm-water runoff, and increased air pollution from urban and industrial sources are some of the known human activities that impact Tampa Bay. Beginning on 2001, additional anthropogenic modifications began in Tampa Bat including construction of an underwater gas pipeline and a desalinization plant, expansion of existing ports, and increased freshwater withdrawal from three major tributaries to the bay. In January of 2001, the Tampa Bay Estuary Program (TBEP) and its partners identifies a critical need for participation from the U.S. Geological Survey (USGS) in providing multidisciplinary expertise and a regional-scale, integrated science approach to address complex scientific research issue and critical scientific information gaps that are necessary for continued restoration and preservation of Tampa Bay. Tampa Bay stakeholders identified several critical science gaps for which USGS expertise was needed (Yates et al. 2001). These critical science gaps fall under four topical categories (or system components): 1) water and sediment quality, 2) hydrodynamics, 3) geology and geomorphology, and 4) ecosystem structure and function. Scientists and resource managers participating in Tampa Bay studies recognize that it is no longer sufficient to simply examine each of these estuarine system components individually, Rather, the interrelation among system components must be understood to develop conceptual and predictive modeling tools for effective ecosystem adaptive management. As a multidisciplinary organization, the USGS possesses the capability of developing and coordinating an integrated science strategy for estuarine research founded on partnerships and collaborative efforts, multidisciplinary teams of scientists, and integrated field work, data analysis and interpretation, and product development. The primary role of the USGS in Tamps Bay research was defined with our partners based upon this capability to address estuarine issues using an integrated science approach with a regional perspective and within a national context to complement the numerous ongoing scien efforts by state and local agencies that address local issues within Tamp Bay. Six primary components of the USGS Tamp Bay Study address critical gaps within each of the the four estuarine system components and focus on: 1.) Examining how natural and man-made physical changes affect ecosystem health through mapping and modeling. 2.) Identifying sources and quality of groundwater, surface water, and sediment, 3.) Identifying sources and quality of groundwater, surface water, and sediment, 4.) Assessing the natural and man-made changes affecting wetland health and restoration, 5.) Identifying and measuring the impact of urbanization on seafloor habitats, Providing a web-based digital information management system of information for scientists and the public, including a system that supports the work of those officials who must make decisions that affect the state of the bay. The Tampa Bay Study is in its sixth year and will continue through September 2007. This paper presents a non-inclusive summary of key findings associated with the six primary project components listed above. Component 4 (above) is described in detail in the following chapter 13. More information on the Tampa Bay Study is available from our on-line digital information system for the Tampa Bay Study at http://gulfsci.usgs.gov.

Florida↗

Regional-scale associations between indicators of biological integrity and indicators of streamflow modification

Although streamflow is widely recognized as a controlling factor in stream health, empirical relations between indicators of anthropogenic modification of streamflow and ecological indicators have been elusive. The objective of this report is to build upon specific findings reported in recent publications by providing a library of empirical models that describe the relations between streamflow modification and indicators of biological integrity. Biological monitoring data from 812 streams and rivers across the United States were matched with sites where daily streamflow was also monitored by the U.S. Geological Survey. Of these sites, 118 were sampled by the U.S. Geological Survey along gradients of streamflow modification within 3 regional focus studies. The integrity of invertebrate and fish communities was expressed as a binary variable, “impaired” or “unimpaired,” signifying whether or not the composition and structure of the biological community was statistically reduced relative to regional reference sites. Streamflow modification at each gaged site was quantified with 509 streamflow statistics scaled to express the ratio of observed streamflow conditions to site-specific expected conditions in the absence of human influences on watershed hydrology. For each region, generalized additive modeling was used to examine relations between each indicator of streamflow modification and indicators of biological integrity (response variable). In every region examined, statistically defensible and ecologically realistic relations were found between indicators of streamflow modification and indicators of biological integrity. These findings can aid practitioners and managers seeking to (1) propose empirically based hypotheses about the specific components of streamflow regimes that are critical to aquatic communities, which can subsequently be explored in detail in a region or river basin of interest; and (2) predict biological responses to anthropogenic modification of specific components of the streamflow regime.

Open-File Report↗

Permafrost characterization and feature identification using public domain airborne electromagnetic data, interior Alaska

The Alaska Division of Geological & Geophysical Surveys (DGGS) airborne electromagnetic (AEM) data are an excellent resource for permafrost characterization. AEM data can be used for pingo identification, estimating permafrost thickness, estimating surface talik thickness, evaluating permafrost health (temperature), talik identification and more. Data examples are shown from discontinuous permafrost areas just north of Fairbanks, Alaska, USA. Interpretations are made from 2D and 3D resistivity models created from 1D inversions of the Goldstream Valley AEM survey data (Emond, 2018a).

Alaska↗

Assessing cyanobacterial frequency and abundance at surface waters near drinking water intakes across the United States

This study presents the first large-scale assessment of cyanobacterial frequency and abundance of surface water near drinking water intakes across the United States. Public water systems serve drinking water to nearly 90% of the United States population. Cyanobacteria and their toxins may degrade the quality of finished drinking water and can lead to negative health consequences. Satellite imagery can serve as a cost-effective and consistent monitoring technique for surface cyanobacterial blooms in source waters and can provide drinking water treatment operators information for managing their systems. This study uses satellite imagery from the European Space Agency's Ocean and Land Colour Instrument (OLCI) spanning June 2016 through April 2020. At 300-m spatial resolution, OLCI imagery can be used to monitor cyanobacteria in 685 drinking water sources across 285 lakes in 44 states, referred to here as resolvable drinking water sources. First, a subset of satellite data was compared to a subset of responses ( n = 84) submitted as part of the U.S. Environmental Protection Agency's fourth Unregulated Contaminant Monitoring Rule (UCMR 4). These UCMR 4 qualitative responses included visual observations of algal bloom presence and absence near drinking water intakes from March 2018 through November 2019. Overall agreement between satellite imagery and UCMR 4 qualitative responses was 94% with a Kappa coefficient of 0.70. Next, temporal frequency of cyanobacterial blooms at all resolvable drinking water sources was assessed. In 2019, bloom frequency averaged 2% and peaked at 100%, where 100% indicated a bloom was always present at the source waters when satellite imagery was available. Monthly cyanobacterial abundances were used to assess short-term trends across all resolvable drinking water sources and effect size was computed to provide insight on the number of years of data that must be obtained to increase confidence in an observed change. Generally, 2016 through 2020 was an insufficient time period for confidently observing changes at these source waters; on average, a decade of satellite imagery would be required for observed environmental trends to outweigh variability in the data. However, five source waters did demonstrate a sustained short-term trend, with one increasing in cyanobacterial abundance from June 2016 to April 2020 and four decreasing.

Water Research↗

Perspectives on the future of ecology, evolution, and biodiversity from the Council on Microbial Sciences of the American Society for Microbiology

The field of microbial ecology, evolution, and biodiversity (EEB) is at the leading edge of understanding how microbes shape our biosphere and influence the well-being of humankind. To that end, EEB is developing new tools to analyze the massive, complex, transdisciplinary datasets that result from such studies. The American Society for Microbiology’s Council on Microbial Sciences hosted a virtual retreat in 2023 to identify the trajectory of EEB both within the Society and microbiology at large. Retreat presentations and discussions collectively emphasized the interconnectedness of microbes and their outsized global influence on environmental and host health. The retreat repeatedly emphasized that the future of science is through transdisciplinary collaborations that promote integration of diverse datasets and advanced technologies, while also genuinely fostering inclusivity, global collaborations, and public engagement. The American Society for Microbiology and EEB stand poised to lead a paradigm shift that will result in a new era of collaboration, innovation, and societal relevance for microbiology.

mSphere↗

The Pacific northwest stream quality assessment

In 2015, the U.S. Geological Survey (USGS) National Water-Quality Assessment (NAWQA) program is assessing stream quality in the Pacific Northwest. The goals of the Pacific Northwest Stream Quality Assessment (Pacific Northwest study) are to assess the quality of streams in the region by characterizing multiple water-quality factors that are stressors to aquatic life and to evaluate the relation between these stressors and biological communities. The effects of urbanization and agriculture on stream quality for the Puget Lowlands and Willamette Valley are the focus of this regional study. Findings will provide the public and policymakers with information regarding which human and environmental factors are the most critical in affecting stream quality and, thus, provide insights about possible approaches to protect or improve the health of streams in the region. The Pacific Northwest study will be the third regional study by the NAWQA program, and it will be of similar design and scope as the first two—the Midwest in 2013 and the Southeast in 2014 (Van Metre and others, 2012, 2014).

Oregon, Washington↗

Water-quality comparison of the Gulf Coast aquifer system and Carrizo-Wilcox aquifer in Texas from National Water-Quality Assessment Project Principal Aquifer Surveys, 2013 and 2015

The U.S. Geological Survey’s National Water-Quality Assessment (NAWQA) Project assessed the quality of groundwater in aquifers that are important sources of drinking water in the United States. One major aquifer in Texas that was assessed by NAWQA in 2013 is the coastal lowlands aquifer system, which is often referred to in Texas as the “Gulf Coast aquifer system.” The coastal lowlands aquifer system supplies water for millions of people; self-supplied (private) well withdrawals in 2005 from this aquifer system were the sixth largest among all major aquifer systems in the Nation. A major aquifer in Texas that was assessed by NAWQA in 2015 is the Texas coastal uplands aquifer system; the Carrizo-Wilcox aquifer is one of several aquifers that compose this aquifer system in Texas. The rocks composing the Texas coastal uplands aquifer system extend east from Texas as part of the Mississippi embayment aquifer system and underlie areas of several States. The Texas coastal uplands aquifer system and Mississippi embayment aquifer system are often collectively referred to as the “Mississippi embayment-Texas coastal uplands aquifer system.” Self-supplied withdrawals from the Mississippi embayment-Texas coastal uplands aquifer system in 2005 were the eighth largest among all major aquifer systems in the Nation. The coastal lowlands aquifer system and Mississippi embayment-Texas coastal uplands aquifer system were assessed as part of the NAWQA Principal Aquifer Surveys (PAS), which were designed to evaluate constituent concentrations in water samples obtained from domestic and public-supply wells prior to any treatment. PAS assessments like these allow for the comparison of water-quality concentrations in untreated groundwater using preestablished benchmarks for the protection of human health and for aesthetic qualities such as taste, color, and odor. The use of preestablished benchmarks can provide a basis for comparison of groundwater quality among principal aquifers.

Texas↗

Quantifying aspects of rangeland health at watershed scales in Colorado using remotely sensed data products

During grazing permit renewals, the Bureau of Land Management assesses land health using indicators typically measured using field-based data collected from individual sites within grazing allotments. However, agency guidance suggests assessments be completed at larger spatial scales. We explored how the current generation of remotely sensed data products could be used to quantify aspects of land health at watershed scales in Colorado to provide broad spatial and temporal context for the land health assessment process. We found multiple indicators could be quantified using these data products and were relevant to land health standards. Within focal watersheds, bare ground cover decreased over the past 30 years, while annual herbaceous cover has increased over the last 10 years. Vegetation productivity was variable over time, but interannual fluctuations were consistent across watersheds. Remotely sensed data products can help resource managers understand how current conditions relate to broad spatial and temporal trends in the region and could provide another line of evidence for the land health assessment process. They may also identify target areas where management strategies, such as eradication of invasive annual grasses, should be focused, and could help resource managers communicate complex issues to the public.

Colorado↗

Occurrence of selected contaminants in water, fish tissue, and streambed sediments in central Nebraska, 1992-95

Surface and ground water in Nebraska may contain contaminants resulting from human activities. For purposes of this publication, a contaminant is any element or compound whose presence may affect the water's suitability for certain uses. For example, herbicide concentrations may exceeed the U.S. Environmental Protection Agency's (USEPA) Health Advisory Levels (HAL) for drinking water or trace-element concentrations may exceed guidelines for the protection of aquatic life. In general, the contaminats discussed in this report enter the aquatic system through nonpoint-source runoff from agricultural lands that dominate the Nebraska landscape. However,because this assessment was conducted as part of a larger, national program, a screening for contaminants with non-agricultural origins was included. The measurement of water quality involves a variety of steps, each contributing unique information while also aggregating to an overall assessment. One aspect of water-quality assesment is to describe the occurrence and distribution of contaminants. Some contaminants may be hundreds or thousands of times more concentrated in the tissues of aquatic organisms or in fine sediments than they are in the water. As a result, fish tissue and streambed sediments are well suited for the detection of certain contaminants. For example, pesticides used in the United States prior to the early 1970's, such as DDT, may have degraded into more stable but still toxic compounds that are highly concentrated in fish tissues. Conversely, other contaminants are not concentrated in sediments or tissues but are readily detected in water samples. Organonitrogen herbicides (such as atrazine), the most commonly used herbicides in Nebraska, are examples of water-soluble contaminants. Several sampling strategies were used to address specific questions. Some sites were sampled repeatedly through time and during all hydrologic conditions, whereas others were sampled only once to determine presence of contaminants. Because a strong relation between concentration and streamflow often exists for contaminants originating from nonpoint sources, streams typically were sampled near gaging stations that monitor streamflow.

Nebraska↗

Water resources inventory of Connecticut Part 8: Quinnipiac River basin

The Quinnipiac River basin area in southcentral Connecticut covers 363 square miles, and includes all drainage basins that enter Long Island Sound from the Branford to the Wepawaug Rivers. Its population in 1970 was estimated at 535,000. Precipitation averages 47 inches per year and provides an abundant supply of water. Twenty-one inches returns to the atmosphere as evapotranspiration; the remainder flows directly to streams or percolates to the water table and discharges to Long Island Sound. Small amounts of water are exported from the basin by the New Britain Water Department, and small amounts are imported to the basin by the New Haven Water Company. The amount of water that can be developed at a given place depends upon precipitation, variability of streamflow, hydraulic properties and areal extent of the aquifers, and hydraulic connection between the aquifers and major streams. The quality of the water is determined by the physical environment and the effects of man. Stratified drift is the only aquifer capable of large sustained yields of water to individual wells. Yields of 64 screened wells tapping stratified drift range from 17 to 2,000 gpm (gallons per minute); their median yield is 500 gpm. Till is widespread and generally provides only small amounts of water. Wells in till normally yield only a few hundred gallons of water daily and commonly are inadequate during dry periods. Till is generally used only as an emergency or secondary source of water. Bedrock aquifers underlie the entire report area and include sedimentary, igneous, and metamorphic rock types. These aquifers supply small but reliable quantities of water to wells throughout the basin and are the chief source for many nonurban homes and farms. About 90 percent of the wells tapping bedrock yield at least 2 pgm, and much larger yields are occasionally reported. Maximum well yields of 305 gpm for sedimentary, 75 gpm for igneous, and 200 gpm for metamorphic bedrock have been reported. Water potentially available from stratified drift was estimated on the basis of hydraulic characteristics of the aquifers and evaluation of natural and induced recharge. Long-term yields estimated for 14 favorable areas of stratified drift range from 0.8 to 16.1 mgd (million gallons per day), but detailed verification studies are needed before development. The natural quality of water in the report area is good. The water is generally low in dissolved solid and is soft to moderately hard. Surface water is less mineralized than ground water, especially during high flow when it is primarily surface runoff. A median dissolved-solids concentration of 117 mg/l (milligrams per liter) and a median hardness of 58 mg/l was determined for water samples collected at 20 sites on 16 streams during high flow. A median dissolved-solids concentration of 146 mg/l and a median hardness of 82 mg/l was determined for samples collected at the same sites during low flow. In contrast water from 130 wells had a median dissolved-solids concentration of 188 mg/l and a median hardness of 110 mg/l. Iron and manganese occur in objectionable concentrations in parts of the report area, particularly in water from streams draining swamps and in water from aquifers rich in iron- and manganese-bearing minerals. Concentrations of iron in excess of 0.3 mg/l were found in 40 percent of the high-streamflow samples, 59 percent of the low-streamflow samples and 20 percent of the ground-water samples. Human activities have modified the quality of water in much of the basin. Wide and erratic fluctuations in concentration of dissolved solids in streams, high bacterial content of the Quinnipiac River, and locally high nitrate and chloride concentrations in ground water are evidence of man's influence. Streams, wetlands, and some aquifers along the southern boundary of the basin contain salty water. Overpumping has caused extensive saltwater intrusion in aquifers in the southern and eastern parts of New Haven. The total amount of fresh water used in the area during 1970 is estimated at 35,710 million gallons, or 183 gallons per day per capita. Public water-supply systems met the domestic requirements of about 90 percent of the population; all the systems supplied water that met the drinking water standards of the Connecticut Department of Health.

Connecticut↗

Drinking water health standards comparison and chemical analysis of groundwater for 72 domestic wells in Bradford County, Pennsylvania, 2016

Pennsylvania has the second highest number of residential wells of any state in the Nation with approximately 2.4 million residents that depend on groundwater for their domestic water supply. Despite the widespread reliance on groundwater in rural areas of the state, publicly available data to characterize the quality of private well water are limited. In Bradford County, more than half of the residents use groundwater from private domestic-supply wells as their primary drinking source. The quality of private well water is influenced by the regional and local setting, including the surrounding soil, geology, land use, household plumbing, and well construction. The groundwater used for domestic water supply in Bradford County is obtained primarily from shallow bedrock and from unconsolidated (glacial) deposits that overlie the bedrock. Historical land use has been predominately forested, agricultural, and residential, but more recently unconventional oil/gas development has been distributed throughout the landscape. Pennsylvania is one of only two states in the Nation without statewide water-well construction standards. To better assess the quality of groundwater used for drinking water supply in Bradford County, data for 72 domestic wells were collected and analyzed for a wide range of constituents that could be evaluated in relation to drinking water health standards, geology, land use, and other environmental factors. Groundwater samples were collected from May through August 2016 and analyzed for physical and chemical properties, including major ions, nutrients, trace elements, volatile organic compounds, ethylene and propylene glycol, alcohols, gross-alpha/beta-particle activity, uranium, radon-222, and dissolved gases. A subset of samples was analyzed for radium isotopes (radium-226 and -228) and for the isotopic composition of methane. This study was conducted by the U.S. Geological Survey in cooperation with the Northern Tier Regional Planning and Development Commission and is part of a regional effort to characterize groundwater in rural areas of Pennsylvania. Results of the 2016 study show that groundwater quality generally met most drinking-water standards. However, a percentage of samples failed to meet maximum contaminant levels (MCLs) for total coliform bacteria (49.3 percent), Escherichia coli (8.5 percent), barium (2.8 percent), and arsenic (2.8 percent); and secondary maximum contaminant levels (SMCL) for sodium (48.6 percent), manganese (30.6 percent), gross alpha and beta activity (16.7 percent), iron (11.1 percent), pH (8.3 percent), total dissolved solids (5.6 percent), chloride (1.4 percent), and aluminum (1.4 percent). Radon-222 activities exceeded the proposed drinking-water standard of 300 picocuries per liter (pCi/L) in 70.4 percent of the samples. There were no exceedances of drinking water health standards for any volatile organic compounds, and the only detections were for three trihalomethanes in one sample. The pH of the groundwater had a large influence on chemical characteristics and ranged from 6.18 to 9.31. Generally, the higher pH samples had higher potential for elevated concentrations of several constituents, including total dissolved solids, sodium, lithium, chloride, fluoride, boron, arsenic, and methane. For the Bradford County well-water samples, calcium/bicarbonate type waters were most abundant, with others classified as sodium/bicarbonate or mixed water types including calcium-sodium/bicarbonate, calcium-sodium/bicarbonate-chloride, sodium/bicarbonate-chloride, sodium/bicarbonate-sulfate, or sodium/chloride types. Six principal components (pH, redox, hardness, chloride-bromide, strontium-barium, and molybdenum-arsenic) explained nearly 78.3 percent of the variance in the groundwater dataset. Groundwater from 12.5 percent of the wells had concentrations of methane greater than the Pennsylvania action level of 7 milligrams per liter (mg/L); detectable methane concentrations ranged from 0.01 to 77 mg/L. In addition, low levels of ethane (as much as 0.13 mg/L) were present in seven samples with the highest methane concentrations. The isotopic composition of methane in five of these groundwater samples was consistent with the isotopic compositions reported for mud-gas logging samples from these geologic units and a thermogenic source. Isotopic composition from a sixth sample suggested the methane in that sample may be of microbial origin. Well-water samples with the higher methane concentrations also had higher pH values and elevated concentrations of sodium, lithium, boron, fluoride, arsenic, and bromide. Relatively elevated concentrations of some other constituents, such as barium and chloride, commonly were present in, but not limited to, those well-water samples with elevated methane. Four of the six groundwater samples with the highest methane concentrations had chloride/bromide ratios that indicate mixing with a small amount of brine (0.02 percent or less) similar in composition to those reported for gas and oil well brines in Pennsylvania. In several other eastern Pennsylvania counties where gas drilling is absent, groundwater with comparable chloride/bromide ratios and chloride concentrations have been reported, implying a potential natural source of brine. Most of Bradford County well-water samples have chloride concentrations less than 20 mg/L, and those with higher chloride concentrations have chloride/bromide ratios that indicate anthropogenic sources (such as road-deicing salt and septic effluent) or brine. Brines that are naturally present may originate from deeper parts of the aquifer system, whereas anthropogenic sources are more likely to affect shallow groundwater because they occur on or near the land surface. The available data for this study indicate that no one physical factor, such as the topographic setting, well depth, or altitude at the bottom of the well, was particularly useful for predicting those well locations with an elevated dissolved concentration of methane. The 2016 assessment of groundwater quality in Bradford County shows groundwater is generally of good quality, but methane and some constituents that occur in high concentration in naturally occurring brine and also in produced waters may be present at low to moderate concentrations in groundwater in various parts of the aquifer.

Pennsylvania↗

A tool to monitor hydrologic conditions on tree islands in the Everglades

Tree islands are patchy upland forested habitats in Florida's Everglades that face degradation and disappearance due to altered hydrologic patterns. The U.S. Geological Survey coordinated with the Miccosukee Tribe of Indians of Florida and the Seminole Tribe of Florida to co-develop a decision-support tool based on tree-island hydrologic conditions. Everglades managers can use this tool to help with restoration planning and water operations decisions that affect tree-island conditions. After a series of organized workshops and meetings, a list of hydrologic metrics was selected as indicators of tree-island health, including hydroperiod, number of days since last dry, and maximum water depth at the head of the island. As a result, a web application tool, called ETree, has been developed and is publicly available online. This web application provides data on daily metrics for the current Everglades water year and annual summaries for past years, beginning in 2000.

Florida↗

Water-quality indicators of surface-water-influenced groundwater supplies in the Ohio River alluvial aquifer of West Virginia

The U.S. Geological Survey, in cooperation with the West Virginia Department of Health and Human Resources, studied surface-water-influenced groundwater supplies in the Ohio River alluvial aquifer of West Virginia for the purpose of understanding the influence of surface water on groundwater chemistry. Public groundwater supplies obtained from these aquifers receive substantial recharge from surface-water sources and are highly susceptible to degradation from water-soluble contaminants. Water samples were collected from 4 sites in the Ohio River and 23 groundwater wells in the alluvial aquifer from June 2019 to January 2020. Surface-water influence was assessed through characterization of groundwater quality, determination of recharge sources, estimation of groundwater age, and estimation of the fraction of Ohio River water entering groundwater pumped by wells in the alluvial aquifers. Hydrogeochemical processes controlling solute concentrations in the Ohio River alluvial aquifer were evaluated with multivariate statistical analysis and identified to be primarily controlled by redox processes, input from sources of salinity, and carbonate dissolution. Meteoric recharge from the Ohio River and precipitation on the alluvium are the main sources of water entering the aquifer. The age of groundwater in the system was determined to be primarily from a modern source. Groundwater samples from every well included in this study had detections for at least one geochemical indicator of surface-water influence, and every well was determined to be susceptible and vulnerable to contamination from surface sources. Results from binary mixing models and inverse geochemical models showed that sulfate, silica, and bicarbonate concentrations predict the fraction of Ohio River water entering alluvial wells for preliminary determination of surface-water influence when compared to fractions predicted using a numerical groundwater-flow model. In the absence of extensive analytes and geochemical or groundwater modeling capabilities, preliminary assessment of the fraction of Ohio River water entering groundwater wells in the Ohio River alluvium can be estimated for most sites using a linear relation between the equivalent ratio of bicarbonate to sulfate and the fraction of water computed by the average of the three geochemical models presented in this report. This approximation of the fraction of Ohio River water, coupled with information on the hydrogeological framework and geochemical indicators of surface-water influence, may be sufficient for preliminary assessment of surface-water influence in the absence of more detailed site information or reaction-transport models.

West Virginia↗

Water Quality in the Delaware River Basin, Pennsylvania, New Jersey, New York, and Delaware, 1998-2001

This report contains the major findings of a 1998-2001 assessment of water quality in the Delaware River Basin. It is one of a series of reports by the National Water-Quality Assessment (NAWQA) Program that present major findings in 51 major river basins and aquifer systems across the Nation. In these reports, water quality is discussed in terms of local, State, and regional issues. Conditions in a particular basin or aquifer system are compared to conditions found elsewhere and to selected national benchmarks, such as those for drinking-water quality and the protection of aquatic organisms. This report is intended for individuals working with water-resource issues in Federal, State, or local agencies, universities, public interest groups, or in the private sector. The information will be useful in addressing a number of current issues, such as the effects of agricultural and urban land use on water quality, human health, drinking water, source-water protection, hypoxia and excessive growth of algae and plants, pesticide registration, and monitoring and sampling strategies. This report is also for individuals who wish to know more about the quality of streams and ground water in areas near where they live, and how that quality compares to the quality of water in other areas across the Nation. The water-quality conditions in the Delaware River Basin summarized in this report are discussed in detail in other reports that can be accessed from https://www.usgs.gov/centers/new-jersey-water-science-center/science/delaware-river-basin-delr-nawqa-study-unit . Detailed technical information, data and analyses, collection and analytical methodology, models, graphs, and maps that support the findings presented in this report, in addition to reports in this series from other basins, can be accessed from the national NAWQA Web site ( http://water.usgs.gov/nawqa ).

Delaware, New Jersey, New York, Pennsylvania↗

Water Quality in the Delmarva Peninsula, Delaware, Maryland, and Virginia, 1999-2001

This report contains the major findings of a 1999-2001 assessment of water quality in the Delmarva Peninsula. It is one of a series of reports by the National Water-Quality Assessment (NAWQA) Program that present major findings in 51 major river basins and aquifer systems across the Nation. In these reports, water quality is assessed at many scales?from local ground-water flow paths to regional ground-water networks and in surface water?and is discussed in terms of local, State, and regional issues. Conditions in the Delmarva Peninsula are compared to conditions found elsewhere and to selected national benchmarks, such as those for drinking-water quality and the protection of aquatic organisms. This report is intended for individuals working with water-resource issues in Federal, State, or local agencies; universities; public interest groups; or in the private sector. The information will be useful in addressing a number of current issues, such as the effects of agricultural and urban land use on water quality, human health, drinking water, source-water protection, hypoxia and excessive growth of algae and plants, pesticide registration, and monitoring and sampling strategies. This report is also for individuals who wish to know more about the quality of streams and ground water in areas near where they live, and how that water quality compares to the quality of water in other areas across the Nation. Other products describing water-quality conditions in the Delmarva Peninsula are available. Detailed technical information, data and analyses, methodology, models, graphs, and maps that support the findings presented in this report can be accessed from http://md.water.usgs.gov/delmarva. Other reports in this series and data collected from other basins can be accessed from the national NAWQA Web site (http://water.usgs.gov/nawqa).

Circular↗

Water quality in the Great and Little Miami River Basins, Ohio and Indiana, 1999-2001

This report contains the major findings of a 1999?2001 assessment of water quality in the Great and Little Miami River Basins. It is one of a series of reports by the National Water-Quality Assessment (NAWQA) Program that present major findings in 51 major river basins and aquifer systems across the Nation. In these reports, water quality is discussed in terms of local, State, and regional issues. Conditions in a particular basin or aquifer system are compared to conditions found elsewhere and to selected national benchmarks, such as those for drinking-water quality and the protection of aquatic organisms. This report is intended for individuals working with water-resource issues in Federal, State, or local agencies, universities, public interest groups, or in the private sector. The information will be useful in addressing a number of current issues, such as the effects of agricultural and urban land use on water quality, human health, drinking water, source-water protection, hypoxia and excessive growth of algae and plants, pesticide registration, and monitoring and sampling strategies. This report is also for individuals who wish to know more about the quality of streams and ground water in areas near where they live and how that water quality compares to the quality of water in other areas across the Nation. The water-quality conditions in the Great and Little Miami River Basins summarized in this report are discussed in detail in other reports that can be accessed from (http://oh.water.usgs.gov/miam/intro.html). Detailed technical information, data and analyses, collection and analytical methodology, models, graphs, and maps that support the findings presented in this report, in addition to reports in this series from other basins, can be accessed from the national NAWQA Web site (http://water.usgs.gov/nawqa).

Circular↗