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At least 721 records · Page 40Linked to original sources
USGS2020

Technical memorandum: Compound specific isotope analysis, Oak Grove Village well site OU1, Franklin County, Missouri

A study involving Compound Specific Isotope Analysis (CSIA) of trichloroethene (TCE) in groundwater at the Oak Grove Village (OGV) Well Site was conducted by the U.S. Environmental Protection Agency (EPA) in 2014 in an effort to fingerprint the source(s). This technical memorandum, written as a joint effort between HydroGeoLogic, Inc. (HGL) and the U.S. Geological Survey (USGS) Central Midwest Water Science Center (Schumacher, 2019), documents the procedures and analysis of the CSIA investigation. CSIA is an analytical method that measures the isotopic ratios of naturally occurring stable isotopes in specific chemical compounds in environmental samples. CSIA using primarily the ratio of carbon 13 C/ 12 C (δ 13 C), known as 1-D CSIA, has been used for decades in evaluating degradation pathways of organic compounds, including chlorinated solvents such as TCE. Ratios of stable chlorine isotopes 37 Cl/ 35 Cl (δ 37 Cl) also have been used with carbon isotopes, collectively known as 2-D CSIA, and most recently isotopes of hydrogen 2 H/ 1 H (δ 2 H) have been added, collectively known as 3-D CSIA, in attempts to further determine source, transport, and fate of compounds such as TCE (Ertl et al., 1998; Hunkeler et al., 2011; Kuder et al., 2013; McHugh et al., 2011; Shouakar-Stash et al., 2003; EPA, 2008; and van Warmerdam et al., 1995.

Missouri↗
USGS2018

Leveraging geodetic data to reduce losses from earthquakes

Seismic hazard assessments that are based on a variety of data and the best available science, coupled with rapid synthesis of real-time information from continuous monitoring networks to guide post-earthquake response, form a solid foundation for effective earthquake loss reduction. With this in mind, the Earthquake Hazards Program (EHP) of the U.S. Geological Survey (USGS) Natural Hazards Mission Area (NHMA) engages in a variety of undertakings, both established and emergent, in order to provide high quality products that enable stakeholders to take action in advance of and in response to earthquakes. Examples include the National Seismic Hazard Model (NSHM), development of tools for improved situational awareness such as earthquake early warning (EEW) and operational earthquake forecasting (OEF), research about induced seismicity, and new efforts to advance comprehensive subduction zone science and monitoring. Geodetic observations provide unique and complementary information directly relevant to advancing many aspects of these efforts (fig. 1). EHP scientists have long leveraged geodetic data for a range of influential studies, and they continue to develop innovative observation and analysis methods that push the boundaries of the field of geodesy as applied to natural hazards research. Given the ongoing, rapid improvement in availability, variety, and precision of geodetic measurements, considering ways to fully utilize this observational resource for earthquake loss reduction is timely and essential. This report presents strategies, and the underlying scientific rationale, by which the EHP could achieve the following outcomes: The EHP is an authoritative source for the interpretation of geodetic data and its use for earthquake loss reduction throughout the United States and its territories. The USGS consistently provides timely, high quality geodetic data to stakeholders. Significant earthquakes are better characterized by incorporating geodetic data into USGS event response products and by expanded use of geodetic imaging data to assess fault rupture and source parameters. Uncertainties in the NSHM, and in regional earthquake models, are reduced by fully incorporating geodetic data into earthquake probability calculations. Geodetic networks and data are integrated into the operations and earthquake information products of the Advanced National Seismic System (ANSS). Earthquake early warnings are improved by more rapidly assessing ground displacement and the dynamic faulting process for the largest earthquakes using real-time geodetic data. Methodology for probabilistic earthquake forecasting is refined by including geodetic data when calculating evolving moment release during aftershock sequences and by better understanding the implications of transient deformation for earthquake likelihood. A geodesy program that encompasses a balanced mix of activities to sustain missioncritical capabilities, grows new competencies through the continuum of fundamental to applied research, and ensures sufficient resources for these endeavors provides a foundation by which the EHP can be a leader in the application of geodesy to earthquake science. With this in mind the following objectives provide a framework to guide EHP efforts: Fully utilize geodetic information to improve key products, such as the NSHM and EEW, and to address new ventures like the USGS Subduction Zone Science Plan. Expand the variety, accuracy, and timeliness of post-earthquake information products, such as PAGER (Prompt Assessment of Global Earthquakes for Response), through incorporation of geodetic observations. Determine if geodetic measurements of transient deformation can significantly improve estimates of earthquake probability. Maintain an observational strategy aligned with the target outcomes of this document that includes continuous monitoring, recording of ephemeral observations, focused data collection for use in research, and application-driven data processing and analysis systems. Collaborate on research, development, and operation of affordable, high-precision seafloor geodetic methods that improve earthquake forecasting and event response. Advance computational techniques and instrumentation to enable use of strategies like repeat-pass imagery and low-cost geodetic sensors for earthquake response, monitoring, and research. Engage stakeholders and collaborate with partner institutions to foster operational and research objectives and to safeguard the continued health of geodetic infrastructure upon which we mutually depend. Maintaining a vibrant internal research program provides the foundation by which the EHP can remain an effective and trusted source for earthquake science. Exploiting abundant new data sources, evaluating and assimilating the latest science, and pursuing novel avenues of investigation are means to fulfilling the EHP’s core responsibilities and realizing the important scientific advances envisioned by its scientists. Central to the success of such a research program is engaging personnel with a breadth of competencies and a willingness and ability to adapt these to the program’s evolving priorities, enabling current staff to expand their skills and responsibilities, and planning holistically to meet shared workforce needs. In parallel, collaboration with external partners to support scientific investigations that complement ongoing internal research enables the EHP to strengthen earthquake information products by incorporating alternative perspectives and approaches and to study topics and geographic regions that cannot be adequately covered internally. With commensurate support from technical staff who possess diverse skills, including engineering, information technology, and proficiency in quantitative analysis combined with basic geophysical knowledge, the EHP can achieve the geodetic outcomes identified in this document.

Open-File Report↗
USGS1978

Understanding natural systems; a perspective for land-use planning in Appalachian Kentucky

An eight-county area at the headwaters of the Kentucky River has been designated the Kentucky River Area Development District (KRADD) by the Appalachian Regional Commission. The objective of the project described in this report has been to provide materials to KRADD planners in a format and containing terminology usable by local people untrained in earth science. Experimental maps (not included in this report) have been prepared largely from preexisting data. Time and cost limitations required a regional analysis as well as somewhat more detailed examples of selected localities. Most of the maps produced to meet these needs show the abundance and distribution of naturally occurring materials and the areas affected by various geomorphic processes. Three types of maps, showing current land use, slope, and flood-prone areas, present both basic and derived data directly applicable to specific land-use decisions. Basic map information on quality and quantity of surface and ground water, bedrock and surficial geology, and mineral fuels can be interpreted for a wide variety of current and potential uses. Texts accompanying the maps explain bedrock control of geomorphic processes, distribution and significance of surficial deposits, and hydrologic characteristics of the intricately dissected eastern Kentucky terrain. Within this conceptual framework, geomorphic processes and the landscape may be evaluated in humanly significant terms of low to high potential risk, thereby indicating both opportunities and limitations for land use.

Kentucky↗
USGS2016

The Department of the Interior Southeast Climate Science Center synthesis report 2011–15—Projects, products, and science priorities

Introduction In 2009, the U.S. Department of the Interior (DOI) Secretary Ken Salazar established a network of eight regional Climate Science Centers (CSCs) that, along with the Landscape Conservation Cooperatives (LCCs), would help define and implement the Department's climate adaptation response. The Southeast Climate Science Center (SE CSC) was established at North Carolina State University (NCSU) in Raleigh, North Carolina, in 2010, under a 5-year cooperative agreement with the U.S. Geological Survey (USGS), to identify and address the regional challenges presented by climate change and variability in the Southeastern United States. All eight regional CSC hosts, including NCSU, were selected through a competitive process. Since its opening, the focus of the SE CSC has been on working with partners in the identification and development of research-based information that can assist managers, including cultural and natural resource managers, in adapting to global change processes, such as climate and land use change, that operate at local to global scales and affect resources important to the DOI mission. The SE CSC was organized to accomplish three goals: Provide co-produced, researched based, actionable science that supports transparent global change adaptation decisions . Convene conversations among decision makers, scientists, and managers to identify key ecosystem adaptation decisions driven by climate and land use change, the values and objectives that will be used to make decisions, and the research-based information needed to assess adaptation options . Build the capacity of natural resource professionals, university faculty, and students to understand and frame natural resource adaptation decisions and develop and use research-based information to make adaptation decisions . This report provides an overview of the SE CSC and the projects developed by the SE CSC since its inception. An important goal of this report is to provide a framework for understanding the evolution of the SE CSC science agenda, which has evolved over the first 5 years of the Center’s operation.

Open-File Report↗
USGS2010

Gas transport in unsaturated porous media: The adequacy of Fick's law

The increasing use of natural unsaturated zones as repositories for landfills and disposal sites for hazardous wastes (chemical and radioactive) requires a greater understanding of transport processes in the unsaturated zone. For volatile constituents an important potential transport mechanism is gaseous diffusion. Diffusion, however, cannot be treated as an independent isolated transport mechanism. A complete understanding of multicomponent gas transport in porous media (unsaturated zones) requires a knowledge of Knudsen transport, the molecular and nonequimolar components of diffusive flux, and viscous (pressure driven) flux. The constitutive equations relating these flux components are available from the “dusty gas” model of Mason et al. (1967). This review presents a brief discussion of the underlying principles and interrelationships among each of the above flux mechanisms. Some aspects of these transport mechanisms are, to our knowledge, generally unrecognized in the Earth science literature. The principles underlying the transport mechanisms are illustrated with binary systems; the constitutive equations are then cast in forms thought to be most useful for the study of natural unsaturated zones. The viscous and diffusive fluxes are coupled in the constitutive equations through the Knudsen diffusivities; a knowledge of Knudsen diffusivities is necessary to calculate the viscous component of flux and pressure gradients. The Knudsen diffusivities can be calculated from measurements of the Klinkenberg effect. Two examples are presented showing that in natural systems, very small pressure gradients (1 Pa/m or less) can produce viscous fluxes greater than or equal to diffusive fluxes and that, conversely, pressure gradients of this magnitude can be generated by diffusive processes. The example calculations show that major concentration gradients can be developed for stagnant (zero flux, nonreactive) gases. A method is presented for approximating the viscous and diffusive flux components of gases in a multicomponent system from a knowledge of the concentration profiles of stagnant gases. In subsoil environments, argon and nitrogen are considered to be stagnant gases. Fick's laws are essentially, by definition, inadequate to deal with stagnant gases. In the examples presented, the error associated with estimating the total fluxes of nonstagnant gases by Fick's law, relative to stationary coordinates, ranges from a few percent to orders of magnitude.

Reviews of Geophysics↗
USGS2006

Findings of the Mars Special Regions Science Analysis Group

In summary, within the upper 5 m most of Mars is either too cold or too dry to support the propagation of terrestrial life. However, there are regions that are in disequilibrium, naturally or induced, and could be classified as "special" or, if enough uncertainty exist, could not be declared as "non-special." ?? Mary Ann Liebert, Inc.

Astrobiology↗
USGS2016

Seismic‐hazard forecast for 2016 including induced and natural earthquakes in the central and eastern United States

The U.S. Geological Survey (USGS) has produced a one‐year (2016) probabilistic seismic‐hazard assessment for the central and eastern United States (CEUS) that includes contributions from both induced and natural earthquakes that are constructed with probabilistic methods using alternative data and inputs. This hazard assessment builds on our 2016 final model ( Petersen et al. , 2016 ) by adding sensitivity studies, illustrating hazard in new ways, incorporating new population data, and discussing potential improvements. The model considers short‐term seismic activity rates (primarily 2014–2015) and assumes that the activity rates will remain stationary over short time intervals. The final model considers different ways of categorizing induced and natural earthquakes by incorporating two equally weighted earthquake rate submodels that are composed of alternative earthquake inputs for catalog duration, smoothing parameters, maximum magnitudes, and ground‐motion models. These alternatives represent uncertainties on how we calculate earthquake occurrence and the diversity of opinion within the science community. In this article, we also test sensitivity to the minimum moment magnitude between M 4 and M 4.7 and the choice of applying a declustered catalog with b =1.0 rather than the full catalog with b =1.3. We incorporate two earthquake rate submodels: in the informed submodel we classify earthquakes as induced or natural, and in the adaptive submodel we do not differentiate. The alternative submodel hazard maps both depict high hazard and these are combined in the final model. Results depict several ground‐shaking measures as well as intensity and include maps showing a high‐hazard level (1% probability of exceedance in 1 year or greater). Ground motions reach 0.6 g horizontal peak ground acceleration (PGA) in north‐central Oklahoma and southern Kansas, and about 0.2 g PGA in the Raton basin of Colorado and New Mexico, in central Arkansas, and in north‐central Texas near Dallas–Fort Worth. The chance of having levels of ground motions corresponding to modified Mercalli intensity (MMI) VI or greater earthquake shaking is 2%–12% per year in north‐central Oklahoma and southern Kansas and New Madrid similar to the chance of damage at sites in high‐hazard portions of California caused by natural earthquakes. Hazard is also significant in the Raton basin of Colorado/New Mexico; north‐central Arkansas; Dallas–Fort Worth, Texas; and in a few other areas. Hazard probabilities are much lower (by about half or more) for exceeding MMI VII or VIII. Hazard is 3‐ to 10‐fold higher near some areas of active‐induced earthquakes than in the 2014 USGS National Seismic Hazard Model (NSHM), which did not consider induced earthquakes. This study in conjunction with the LandScan TM Database (2013) indicates that about 8 million people live in areas of active injection wells that have a greater than 1% chance of experiencing damaging ground shaking (MMI≥VI) in 2016. The final model has high uncertainty, and engineers, regulators, and industry should use these assessments cautiously to make informed decisions on mitigating the potential effects of induced and natural earthquakes.

Seismological Research Letters↗
USGS2022

Optimizing management of invasions in an uncertain world using dynamic spatial models

Dispersal drives invasion dynamics of nonnative species and pathogens. Applying knowledge of dispersal to optimize the management of invasions can mean the difference between a failed and a successful control program and dramatically improve the return on investment of control efforts. A common approach to identifying optimal management solutions for invasions is to optimize dynamic spatial models that incorporate dispersal. Optimizing these spatial models can be very challenging because the interaction of time, space, and uncertainty rapidly amplifies the number of dimensions being considered. Addressing such problems requires advances in and the integration of techniques from multiple fields, including ecology, decision analysis, bioeconomics, natural resource management, and optimization. By synthesizing recent advances from these diverse fields, we provide a workflow for applying ecological theory to advance optimal management science and highlight priorities for optimizing the control of invasions. One of the striking gaps we identify is the extremely limited consideration of dispersal uncertainty in optimal management frameworks, even though dispersal estimates are highly uncertain and greatly influence invasion outcomes. In addition, optimization frameworks rarely consider multiple types of uncertainty (we describe five major types) and their interrelationships. Thus, feedbacks from management or other sources that could magnify uncertainty in dispersal are rarely considered. Incorporating uncertainty is crucial for improving transparency in decision risks and identifying optimal management strategies. We discuss gaps and solutions to the challenges of optimization using dynamic spatial models to increase the practical application of these important tools and improve the consistency and robustness of management recommendations for invasions.

Ecological Applications↗
USGS2001

Temporal and spatial variations in fly ash quality

Fly ash quality, both as the amount of petrographically distinguishable carbons and in chemistry, varies in both time and space. Temporal variations are a function of a number of variables. Variables can include variations in the coal blend organic petrography, mineralogy, and chemistry; variations in the pulverization of the coal, both as a function of the coal's Hardgrove grindability index and as a function of the maintenance and settings of the pulverizers; and variations in the operating conditions of the boiler, including changes in the pollution control system. Spatial variation, as an instantaneous measure of fly ash characteristics, should not involve changes in the first two sets of variables listed above. Spatial variations are a function of the gas flow within the boiler and ducts, certain flow conditions leading to a tendency for segregation of the less-dense carbons in one portion of the gas stream. Caution must be applied in sampling fly ash. Samples from a single bin, or series of bins, m ay not be representative of the whole fly ash, providing a biased view of the nature of the material. Further, it is generally not possible to be certain about variation until the analysis of the ash is complete. ?? 2001 Elsevier Science B.V. All rights reserved.

Fuel Processing Technology↗
USGS2004

Colorado Canyons National Conservation Area 2003 visitor use survey: Completion report

This report represents the analysis of research conducted by the U.S. Geological Survey (USGS) for the Bureau of Land Management (BLM). The purpose is to provide socio-economic and recreational use information that can be used in the development of a Resource Management Plan (RMP) for the Colorado Canyons National Conservation Area (CCNCA). The results reported here deal primarily with recreation-based activities in four areas: Kokopelli Loops, Rabbit Valley, Loma Boat Launch, and Devil’s Canyon. In the fall of 2002, researchers from the Policy Analysis and Science Assistance Program (PASA) of the Fort Collins Science Center (FORT) in the USGS met with the staff of the CCNCA to discuss the issues related to social, economic, and human dimensions of natural resource management related to the RMP. As a result, a research study was designed to investigate the recreational experiences of visitors and their attitudes toward the management of the conservation area. In the spring of 2003, PASA conducted an intercept survey of recreational users at the CCNCA and a mail survey of local residents who were actively involved in decision-making regarding recreation on public lands in Mesa County, Colorado. Two hundred and three (203) mail surveys (66%) were returned and all of them were completed in full and considered usable. The intercept survey had a response rate with a range from 56%–64% among the four sites that were surveyed. We developed a questionnaire (OMB Control Number: 1040-0001) to answer the following questions: What are the important differences in citizens’ attitudes regarding recreation at the CCNCA? What are the factors that explain the differences in attitudes and preferences regarding recreation management of the NCA? What are citizens’ attitudes and preferences regarding their attitudes about paying a fee to visit the CCNCA? In general, respondents at all sites reported having an excellent or good recreation experience and almost all indicated that they intended to return. The results from the intercept survey indicated that across four sites 1(Kokopelli Loops, Devil’s Canyon, Loma Boat Launch, and Rabbit Valley) respondents reported support for undeveloped use and recreation restrictions to limit resource impacts. Respondents indicated that managing sites for undeveloped use was a good idea. The respondents from the mail survey generally had a positive orientation toward current management practices of the CCNCA. According to our surveys, non-motorized trail related activities were among the three most popular activities people engaged in both close to home and while away. These trail-based recreational activities included walking, running, mountain bike riding, and horseback riding. Research has shown that people participate in these activities for many reasons including learning about nature, exercising, to learning about paleontology, escaping for awhile, and socializing with family and friends (Taylor, 2000). National data indicate that larger percentages of the general American population engage in trail activities than in many other traditional outdoor activities (Cordell, 1999). Over 65% of people in the U.S. engage in walking as a recreational activity (Figure 1). We found that people wanted to experience the outdoors and the CCNCA provided a good place to do it. Trail activities are often those that people participate in on a regular basis as a way to exercise. This can make trail related activities more attractive from a management standpoint because people who participate in an activity may be more likely to be repeat visitors.

Open-File Report↗
USGS2009

Specific Conductance and Dissolved-Solids Characteristics for the Green River and Muddy Creek, Wyoming, Water Years 1999-2008

Southwestern Wyoming is an area of diverse scenery, wildlife, and natural resources that is actively undergoing energy development. The U.S. Department of the Interior's Wyoming Landscape Conservation Initiative is a long-term science-based effort to assess and enhance aquatic and terrestrial habitats at a landscape scale, while facilitating responsible energy development through local collaboration and partnerships. Water-quality monitoring has been conducted by the U.S. Geological Survey on the Green River near Green River, Wyoming, and Muddy Creek near Baggs, Wyoming. This monitoring, which is being conducted in cooperation with State and other Federal agencies and as part of the Wyoming Landscape Conservation Initiative, is in response to concerns about potentially increased dissolved solids in the Colorado River Basin as a result of energy development. Because of the need to provide real-time dissolved-solids concentrations for the Green River and Muddy Creek on the World Wide Web, the U.S. Geological Survey developed regression equations to estimate dissolved-solids concentrations on the basis of continuous specific conductance using relations between measured specific conductance and dissolved-solids concentrations. Specific conductance and dissolved-solids concentrations were less varied and generally lower for the Green River than for Muddy Creek. The median dissolved-solids concentration for the site on the Green River was 318 milligrams per liter, and the median concentration for the site on Muddy Creek was 943 milligrams per liter. Dissolved-solids concentrations ranged from 187 to 594 milligrams per liter in samples collected from the Green River during water years 1999-2008. Dissolved-solids concentrations ranged from 293 to 2,485 milligrams per liter in samples collected from Muddy Creek during water years 2006-08. The differences in dissolved-solids concentrations in samples collected from the Green River compared to samples collected from Muddy Creek reflect the different basin characteristics. Relations between specific conductance and dissolved-solids concentrations were statistically significant for the Green River (p-value less than 0.001) and Muddy Creek (p-value less than 0.001); therefore, specific conductance can be used to estimate dissolved-solids concentrations. Using continuous specific conductance values to estimate dissolved solids in real-time on the World Wide Web increases the amount and improves the timeliness of data available to water managers for assessing dissolved-solids concentrations in the Colorado River Basin.

Scientific Investigations Report↗
USGS2013

National Park Service Vegetation Inventory Program, Cuyahoga Valley National Park, Ohio

The National Park Service (NPS) Vegetation Inventory Program (VIP) is an effort to classify, describe, and map existing vegetation of national park units for the NPS Natural Resource Inventory and Monitoring (I&M) Program. The NPS VIP is managed by the NPS Biological Resources Management Division and provides baseline vegetation information to the NPS Natural Resource I&M Program. The U.S. Geological Survey (USGS) Vegetation Characterization Program lends a cooperative role in the NPS VIP. The USGS Upper Midwest Environmental Sciences Center, NatureServe, and NPS Cuyahoga Valley National Park (CUVA) have completed vegetation classification and mapping of CUVA. Mappers, ecologists, and botanists collaborated to identify and describe vegetation types within the National Vegetation Classification Standard (NVCS) and to determine how best to map them by using aerial imagery. The team collected data from 221 vegetation plots within CUVA to develop detailed descriptions of vegetation types. Data from 50 verification sites were also collected to test both the key to vegetation types and the application of vegetation types to a sample set of map polygons. Furthermore, data from 647 accuracy assessment (AA) sites were collected (of which 643 were used to test accuracy of the vegetation map layer). These data sets led to the identification of 45 vegetation types at the association level in the NVCS at CUVA. A total of 44 map classes were developed to map the vegetation and general land cover of CUVA, including the following: 29 map classes represent natural/semi-natural vegetation types in the NVCS, 12 map classes represent cultural vegetation (agricultural and developed) in the NVCS, and 3 map classes represent non-vegetation features (open-water bodies). Features were interpreted from viewing color-infrared digital aerial imagery dated October 2010 (during peak leaf-phenology change of trees) via digital onscreen three-dimensional stereoscopic workflow systems in geographic information systems (GIS). The interpreted data were digitally and spatially referenced, thus making the spatial database layers usable in GIS. Polygon units were mapped to either a 0.5 ha or 0.25 ha minimum mapping unit, depending on vegetation type. A geodatabase containing various feature-class layers and tables shows the locations of vegetation types and general land cover (vegetation map), vegetation plot samples, verification sites, AA sites, project boundary extent, and aerial photographic centers. The feature-class layer and relate tables for the CUVA vegetation map provides 4,640 polygons of detailed attribute data covering 13,288.4 ha, with an average polygon size of 2.9 ha. Summary reports generated from the vegetation map layer show map classes representing natural/semi-natural types in the NVCS apply to 4,151 polygons (89.4% of polygons) and cover 11,225.0 ha (84.5%) of the map extent. Of these polygons, the map layer shows CUVA to be 74.4% forest (9,888.8 ha), 2.5% shrubland (329.7 ha), and 7.6% herbaceous vegetation cover (1,006.5 ha). Map classes representing cultural types in the NVCS apply to 435 polygons (9.4% of polygons) and cover 1,825.7 ha (13.7%) of the map extent. Map classes representing non-NVCS units (open water) apply to 54 polygons (1.2% of polygons) and cover 237.7 ha (1.8%) of the map extent. A thematic AA study was conducted of map classes representing natural/semi-natural types in the NVCS. Results present an overall accuracy of 80.7% (kappa index of 79.5%) based on data from 643 of the 647 AA sites. Most individual map-class themes exceed the NPS VIP standard of 80% with a 90% confidence interval. The CUVA vegetation mapping project delivers many geospatial and vegetation data products in hardcopy and/or digital formats. These products consist of an in-depth project report discussing methods and results, which include descriptions and a dichotomous key to vegetation types, map classification and map-class descriptions, and a contingency table showing AA results. The suite of products also includes a database of vegetation plots, verification sites, and AA sites; digital pictures of field sites; field data sheets; aerial photographic imagery; hardcopy and digital maps; and a geodatabase of vegetation types and land cover (map layer), fieldwork locations (vegetation plots, verification sites, and AA sites), aerial photographic index, project boundary, and metadata. All geospatial products are projected in Universal Transverse Mercator, Zone 17, by using the North American Datum of 1983. Information on the NPS VIP and completed park mapping projects are located on the Internet at <http://science.nature.nps.gov/im/inventory/veg> and <http://www.usgs.gov/core_science_systems/csas/vip/index.html>.

Natural Resource Technical Report↗
USGS1978

Decomposition of hydroxy amino acids in foraminiferal tests; kinetics, mechanism and geochronological implications

The diagenesis of the hydroxy amino acids serine and threonine in foraminiferal tests has been investigated. The decomposition pathways of these amino acids are complex; the principal reactions appear to be dehydration, aldol cleavage and decarboxylation. Stereochemical studies indicate that the α-amino-n-butyric acid (ABA) detected in foraminiferal tests is the end product of threonine dehydration pathway. Decomposition of serine and threonine in foraminiferal tests from two well-dated Caribbean deep-sea cores, P6304-8 and -9, has been found to follow irreversible first-order kinetics. Three empirical equations were derived for the disappearance of serine and threonine and the appearance of ABA. These equations can be used as a new geochronological method for dating foraminiferal tests from other deep-sea sediments. Preliminary results suggest that ages deduced from the ABA kinetics equation are most reliable because “species effect” and contamination problems are not important for this nonbiological amino acid. Because of the variable serine and threonine contents of modern foraminiferal species, it is likely that the accurate age estimates can be obtained from the serine and threonine decomposition equations only if a homogeneous species assemblage or single species sample isolated from mixed natural assemblages is used.

Earth and Planetary Science Letters↗
USGS2012

Sources of shaking and flooding during the Tohoku-Oki earthquake: a mixture of rupture styles

Modeling strong ground motions from great subduction zone earthquakes is one of the great challenges of computational seismology. To separate the rupture characteristics from complexities caused by 3D sub-surface geology requires an extraordinary data set such as provided by the recent Mw9.0 Tohoku-Oki earthquake. Here we combine deterministic inversion and dynamically guided forward simulation methods to model over one thousand high-rate GPS and strong motion observations from 0 to 0.25 Hz across the entire Honshu Island. Our results display distinct styles of rupture with a deeper generic interplate event (~Mw8.5) transitioning to a shallow tsunamigenic earthquake (~Mw9.0) at about 25 km depth in a process driven by a strong dynamic weakening mechanism, possibly thermal pressurization. This source model predicts many important features of the broad set of seismic, geodetic and seafloor observations providing a major advance in our understanding of such great natural hazards.

Earth and Planetary Science Letters↗
USGS2001

Methyl tert-butyl ether biodegradation by indigenous aquifer microorganisms under natural and artificial oxic conditions

Microbial communities indigenous to a shallow groundwater system near Beaufort, SC, degraded milligram per liter concentrations of methyl tert -butyl ether (MTBE) under natural and artificial oxic conditions. Significant MTBE biodegradation was observed where anoxic, MTBE-contaminated groundwater discharged to a concrete-lined ditch. In the anoxic groundwater adjacent to the ditch, concentrations of MTBE were >1 mg/L. Where groundwater discharge occurs, dissolved oxygen (DO) concentrations beneath the ditch exceeded 1.0 mg/L to a depth of 1.5 m, and MTBE concentrations decreased to <1 μg/L prior to discharge. MTBE mass flux calculations indicate that 96% of MTBE mass loss occurs in the relatively small oxic zone prior to discharge. Samples of a natural microbial biofilm present in the oxic zone beneath the ditch completely degraded [U- 14 C]MTBE to [ 14 C]CO 2 in laboratory liquid culture studies, with no accumulation of intermediate compounds. Upgradient of the ditch in the anoxic, MTBE- and BTEX-contaminated aquifer, addition of a soluble oxygen release compound resulted in oxic conditions and rapid MTBE biodegradation by indigenous microorganisms. In an observation well located closest to the oxygen addition area, DO concentrations increased from 0.4 to 12 mg/L in <60 days and MTBE concentrations decreased from 20 to 3 mg/L. In the same time period at a downgradient observation well, DO increased from <0.2 to 2 mg/L and MTBE concentrations decreased from 30 to <5 mg/L. These results indicate that microorganisms indigenous to the groundwater system at this site can degrade milligram per liter concentrations of MTBE under natural and artificial oxic conditions.

Environmental Science & Technology↗
USGS2010

Carbon dioxide emission factors for U.S. coal by origin and destination

This paper describes a method that uses published data to calculate locally robust CO 2 emission factors for U.S. coal. The method is demonstrated by calculating CO 2 emission factors by coal origin (223 counties, in 1999) and destination (479 power plants, in 2005). Locally robust CO 2 emission factors should improve the accuracy and verification of greenhouse gas emission measurements from individual coal-fired power plants. Based largely on the county origin, average emission factors for U.S. lignite, subbituminous, bituminous, and anthracite coal produced during 1999 were 92.97,91.97,88.20, and 98.91 kg CO 2 /GJ gross , respectively. However, greater variation is observed within these rank classes than between them, which limits the reliability of CO 2 emission factors specified by coal rank. Emission factors calculated by destination (power plant) showed greater variation than those listed in the Emissions & Generation Resource Integrated Database (eGRID), which exhibit an unlikely uniformity that is inconsistent with the natural variation of CO 2 emission factors for U.S. coal. ?? 2010 American Chemical Society.

Environmental Science & Technology↗
USGS1963

Uranyl ion coordination

A review of the known crystal structures containing the uranyl ion shows that plane-pentagon coordination is equally as prevalent as plane0square or plane-hexagon. It is suggested that puckered-hexagon configurations of OH - or H 2 O about the uranyl group will tend to revert to plane-pentagon coordination. The concept of pentagonal coordination is invoked for possible explanations of the complex crystallography of the natural uranyl hydroxides and the unusual behavior of polynuclear ions in hydrolyzed uranyl solutions.

Science↗