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Lithostratigraphic, borehole-geophysical, hydrogeologic, and hydrochemical data from the East Bay Plain, Alameda County, California

The U.S. Geological Survey, in cooperation with the East Bay Municipal Utility District, carried out an investigation of aquifer-system deformation associated with groundwater-level changes at the Bayside Groundwater Project near the modern San Francisco Bay shore in San Lorenzo, California. As a part of the Bayside Groundwater Project, East Bay Municipal Utility District proposed an aquifer storage and recovery program for 1 million gallons of water per day. The potential for aquifer-system compaction and expansion, and related subsidence, uplift, or both, resulting from aquifer storage and recovery activities were investigated and monitored in the Bayside Groundwater Project. In addition, baseline analysis of groundwater and substrata properties were performed to assess the potential effect of such activities. Chemical and physical data, obtained from the subsurface at four sites on the east side of San Francisco Bay in the San Lorenzo and San Leandro areas of the East Bay Plain, Alameda County, California, were collected during the study. The results of the study were provided to the East Bay Municipal Utility District and other agencies to evaluate the chemical and mechanical responses of aquifers underlying the East Bay Plain to the future injection and recovery of imported water from the Sierra Nevada of California. Among 4 sites, 14 piezometers and 2 extensometers were installed in 6 boreholes, which ranged in depth from 460 to 1,040 feet. The lithology of drill cuttings, collected at 5- or 10-foot intervals, was described for grain size and any other noticeable features, such as wood or shell fragments. Borehole geophysical logging was performed at each site in the deepest borehole, immediately following drilling. Drill-core samples, totaling 284 feet, were collected at the Bayside site. The drill-core sediment was subsampled to determine pore-water chemistry, vertical hydraulic conductivity, and physical and mechanical properties at different depths. Depositional environment and age were determined by luminescence geochronology and fossil identification. The elemental composition of the drill-core sediments was determined by inductively coupled plasma mass spectroscopy and instrumental neutron activation by abbreviated count analysis. Mineral composition was determined by X-ray diffraction and scanning electron microscopy analysis. Groundwater samples were collected from all 14 piezometers as part of either the USGS Groundwater Ambient Monitoring and Assessment or the USGS National Water Quality Assessment program for water-quality analyses. Sample analytes included nutrients, major and minor ions, trace elements, isotopic ratios of hydrogen and oxygen in water, carbon-14, and tritium. Water-level and aquifer-system-compaction measurements, which indicated diurnal and seasonal fluctuations, were made at the Bayside Groundwater Project site. Slug tests were performed at the Bayside piezometers and nine pre-existing wells to estimate hydraulic conductivity.

California↗

Quality of water in the Trinity and Edwards aquifers, south-central Texas, 1996-98

During 1996–98, the U.S. Geological Survey studied surface- and ground-water quality in south-central Texas. The ground-water components included the upper and middle zones (undifferentiated) of the Trinity aquifer in the Hill Country and the unconfined part (recharge zone) and confined part (artesian zone) of the Edwards aquifer in the Balcones fault zone of the San Antonio region. The study was supplemented by information compiled from four ground-water-quality studies done during 1996–98. Trinity aquifer waters are more mineralized and contain larger dissolved solids, sulfate, and chloride concentrations compared to Edwards aquifer waters. Greater variability in water chemistry in the Trinity aquifer likely reflects the more variable lithology of the host rock. Trace elements were widely detected, mostly at small concentrations. Median total nitrogen was larger in the Edwards aquifer than in the Trinity aquifer. Ammonia nitrogen was detected more frequently and at larger concentrations in the Trinity aquifer than in the Edwards aquifer. Although some nitrate nitrogen concentrations in the Edwards aquifer exceeded a U.S. Geological Survey national background threshold concentration, no concentrations exceeded the U.S. Environmental Protection Agency public drinking-water standard. Synthetic organic compounds, such as pesticides and volatile organic compounds, were detected in the Edwards aquifer and less frequently in the Trinity aquifer, mostly at very small concentrations (less than 1 microgram per liter). These compounds were detected most frequently in urban unconfined Edwards aquifer samples. Atrazine and its breakdown product deethylatrazine were the most frequently detected pesticides, and trihalomethanes were the most frequently detected volatile organic compounds. Widespread detections of these compounds, although at small concentrations, indicate that anthropogenic activities affect ground-water quality. Radon gas was detected throughout the Trinity aquifer but not throughout the Edwards aquifer. Fourteen samples from the Trinity aquifer and 10 samples from the Edwards aquifer exceeded a proposed U.S. Environmental Protection Agency public drinking-water standard. Sources of radon in the study area might be granitic sediments underlying the Trinity aquifer and igneous intrusions in and below the Edwards aquifer. The presence of tritium in nearly all Edwards aquifer samples indicates that some component of sampled water is young (less than about 50 years), even for long flow paths in the confined zone. About one-half of the Trinity aquifer samples contained tritium, indicating that only part of the aquifer contains young water. Hydrogen and oxygen isotopes of water provide indicators of recharge sources to the Trinity and Edwards aquifers. Most ground-water samples have a meteorological isotopic signature indicating recharge as direct infiltration of water with little residence time on the land surface. Isotopic data from some samples collected from the unconfined Edwards aquifer indicate the water has undergone evaporation. At the time that ground-water samples were collected (during a drought), nearby streams were the likely sources of recharge to these wells.

Texas↗

The role of natural biogeochemical barriers in limiting metal loading to a stream affected by mine drainage

Rio San Giorgio (Iglesiente, Sardinia, Italy), a stream affected by abandoned mine wastes, is characterized by dense vegetation in the streambed, mainly comprised of Phragmites australis and Juncus acutus . This vegetation creates natural biogeochemical barriers that drive mineralization processes and attenuate metals load in the stream. Several techniques, covering scales from micrometres to kilometres, were applied to investigate the biogeochemical processes: water chemistry, injected hydrologic tracer, mineralogy, microscopic investigation and X-ray spectroscopy. From this multiscale and multimethod approach, we recognized two predominant sets of biogeochemical processes: microbially driven metal sulphide precipitation, mainly resulting in pyrite formation; and plant uptake of metals that leads to formation of iron oxide-hydroxide and incorporation of Zn within the roots and aerial part (stem and leaves). The dense vegetation in the Rio San Giorgio streambed controls its morphology, velocity of streamflow, and, as reflected by observed bromide-tracer loss, enhanced water exchange between the streambed and the hyporheic zone. The combined effect of these vegetative controls is to establish biogeochemical barriers that greatly retard trace-metal mobility in the hyporheic zone. We estimated this effect can lead to an apparent decrease in Zn load up to 60%.

Iglesias↗

Environmental drivers of differences in microbial community structure in crude oil reservoirs across a methanogenic gradient

Stimulating in situ microbial communities in oil reservoirs to produce natural gas is a potentially viable strategy for recovering additional fossil fuel resources following traditional recovery operations. Little is known about what geochemical parameters drive microbial population dynamics in biodegraded, methanogenic oil reservoirs. We investigated if microbial community structure was significantly impacted by the extent of crude oil biodegradation, extent of biogenic methane production, and formation water chemistry. Twenty-two oil production wells from north central Louisiana, USA, were sampled for analysis of microbial community structure and fluid geochemistry. Archaea were the dominant microbial community in the majority of the wells sampled. Methanogens, including hydrogenotrophic and methylotrophic organisms, were numerically dominant in every well, accounting for, on average, over 98% of the total Archaea present. The dominant Bacteria groups were Pseudomonas, Acinetobacter , Enterobacteriaceae, and Clostridiales, which have also been identified in other microbially-altered oil reservoirs. Comparing microbial community structure to fluid (gas, water, and oil) geochemistry revealed that the relative extent of biodegradation, salinity, and spatial location were the major drivers of microbial diversity. Archaeal relative abundance was independent of the extent of methanogenesis, but closely correlated to the extent of crude oil biodegradation; therefore, microbial community structure is likely not a good sole predictor of methanogenic activity, but may predict the extent of crude oil biodegradation. However, when the shallow, highly biodegraded, low salinity wells were excluded from the statistical analysis, no environmental parameters could explain the differences in microbial community structure. This suggests that the microbial community structure of the 5 shallow, up-dip wells was different than the 17 deeper, down-dip wells. Also, the 17 down-dip wells had statistically similar microbial communities despite significant changes in environmental parameters between oil fields. Together, this implies that no single microbial population is a reliable indicator of a reservoir's ability to degrade crude oil to methane, and that geochemistry may be a more important indicator for selecting a reservoir suitable for microbial enhancement of natural gas generation.

Louisiana↗

Macroinvertebrate community change associated with the severity of streamflow alteration

Natural streamflows play a critical role in stream ecosystems, yet quantitative relations between streamflow alteration and stream health have been elusive. One reason for this difficulty is that neither streamflow alteration nor ecological responses are measured relative to their natural expectations. We assessed macroinvertebrate community condition in 25 mountain streams representing a large gradient of streamflow alteration, which we quantified as the departure of observed flows from natural expectations. Observed flows were obtained from US Geological Survey streamgaging stations and discharge records from dams and diversion structures. During low-flow conditions in September, samples of macroinvertebrate communities were collected at each site, in addition to measures of physical habitat, water chemistry and organic matter. In general, streamflows were artificially high during summer and artificially low throughout the rest of the year. Biological condition, as measured by richness of sensitive taxa (Ephemeroptera, Plecoptera and Trichoptera) and taxonomic completeness (O/E), was strongly and negatively related to the severity of depleted flows in winter. Analyses of macroinvertebrate traits suggest that taxa losses may have been caused by thermal modification associated with streamflow alteration. Our study yielded quantitative relations between the severity of streamflow alteration and the degree of biological impairment and suggests that water management that reduces streamflows during winter months is likely to have negative effects on downstream benthic communities in Utah mountain streams.

Utah, Wyoming↗

Radiocarbon dating of groundwater in a confined aquifer in southeast Arizona

Radiocarbon, δ 13 C and major-element data were used to construct a geochemical framework for interpretation of the hydrological flow system in the lower San Pedro basin, southeastern Arizona, USA. The 14 C and major-element data show a regional confined aquifer that extends throughout most of the basin. Groundwater ages, after correcting for chemistry, are greater than 10 ka bp. The groundwater ages do not increase in a downvalley direction, the assumed direction of groundwater movement in most intermontane basins in the region, but along general flow paths normal to the mountains toward the center of the basin. Recharge to the confined aquifer originates from infiltration of precipitation and runoff near the alluvium-mountain contact along the Galiuro Mountains and is discharged by evapotranspiration along the center of the basin. The hydrogeological concept of the 14 C model is supported by the water chemistry and by the mass transfer defined by the chemical model. Weathering of primary silicate minerals in the confined aquifer does not occur downvalley, but only along the direction of flow. Hydraulic conductivities calculated for the aquifer from 14 C velocities are about an order of magnitude slower than those determined through hydrological methods. The lower hydraulic-conductivity values are attributed to a thick confining layer overlying the discharge area along the San Pedro River.

Radiocarbon↗

Water quality and evaluation of pesticides in lakes in the Ridge Citrus region of central Florida

Water chemistry, including major inorganic constituents, nutrients, and pesticide compounds, was compared between seven lakes surrounded by citrus agriculture and an undeveloped lake on the Lake Wales Ridge (herein referred to as the Ridge) in central Florida. The region has been recognized for its vulnerability to the leaching of agricultural chemicals into the subsurface due to factors including soils, climate, and land use. About 40 percent of Florida's citrus cultivation occurs in 'ridge citrus' areas characterized by sandy well drained soils, with the remainder in 'flatwoods citrus' characterized by high water tables and poorly drained soils. The lakes on the Ridge are typically flow-through lakes that exchange water with adjacent and underlying aquifer systems. This study is the first to evaluate the occurrence of pesticides in lakes on the Ridge, and also represents one of the first monitoring efforts nationally to focus on regional-scale assessment of current-use pesticides in small- to moderate-sized lakes (5 to 393 acres). The samples were collected between December 2003 and September 2005. The lakes in citrus areas contained elevated concentrations of major inorganic constituents (including alkalinity, total dissolved solids, calcium, magnesium, sodium, potassium, chloride, and sulfate), total nitrogen, pH, and pesticides compared to the undeveloped lake. Nitrate (as N) and total nitrogen concentrations were typically elevated in the citrus lakes, with maximum values of 4.70 and 5.19 mg/L (milligrams per liter), respectively. Elevated concentrations of potassium, nitrate, and other inorganic constituents in the citrus lakes likely reflect inputs from the surficial ground-water system that originated predominantly from agricultural fertilizers, soil amendments, and inorganic pesticides. A total of 20 pesticide compounds were detected in the lakes, of which 12 compounds exceeded the standardized reporting level of 0.06 ug/L (microgram per liter). Those most frequently detected above the 0.06-ug/L level were aldicarb sulfoxide, diuron, simazine degradates hydroxysimazine and didealkylatrazine (DDA), bromacil, norflurazon, and demethyl norflurazon which occurred at detection rates ranging from 25 to 86 percent of samples, respectively. Typically, pesticide concentrations in the lake samples were less than 1 microgram per liter. The number of targeted pesticide compounds detected per lake in the citrus areas ranged from 9 to 14 compared to 3 compounds detected at trace levels in the undeveloped lake. Consistent detections of parents and degradates in quarterly samples indicated the presence of pesticide compounds in the lakes many months or years (for example, bromacil) after their application, signaling the persistence of some pesticide compounds in the lakes and/or ground-water systems. Pesticide degradate concentrations frequently exceeded parent concentrations in the lakes. This study was the first in the Ridge citrus region to analyze for glyphosate - widely used in citrus - and its degradate aminomethylphosphonic acid (AMPA), neither of which were detected, as well as a number of triazine degradates, including hydroxysimazine, which were detected. The lake pesticide concentrations did not exceed current Federal aquatic-life benchmarks, available for 10 of the 20 detected pesticide compounds. Limited occurrences of bromacil, diuron, or norflurazon concentrations were within about 10 to 90 percent of benchmark guidelines for acute effects on nonvascular aquatic plants in one or two of the lakes. The lake pesticide concentrations for several targeted pesticides were relatively high compared to corresponding national stream-water percentiles, which is consistent with this region's vulnerability for pesticide leaching into water resources. Several factors were evaluated to gain insight into the processes controlling pesticide transport and fate, and to assess their utility for estimating th

Florida↗

Ground-water quality and geochemistry of aquifers associated with coal in the Allegheny and Monongahela formations, southeastern Ohio

Ground water from aquifers associated with coal beds in the Allegheny and Monongahela Formations in southeastern Ohio is predominantly a calcium magnesium bicarbonate type. Sodium bicarbonate type water is less common. Isolated areas of sodium chloride and calcium sulfate types also are present. The water is predominantly very hard, and has a median hardness concentration of 258 milligrams per liter as calcium carbonate and a median dissolved-solids concentration of 436 milligrams per liter. Few wells contain water with dissolved-solids concentrations in excess of 1,000 milligrams per liter. Bicarbonate concentration in ground water was found to be significantly different among coals, whereas concentrations of bicarbonate, hardness, calcium, magnesium, sodium, iron, manganese, and strontium were significantly different between ground water in the Allegheny and Monongahela Formations. Many constituents are significantly correlated, but few correlation coefficients are high. The presence of sulfate or iron is attributed to the kinetic mechanism operating during the oxidation of pyrite. The position along the sulfide or ferrous-iron oxidation pathways controls the reaction products of pyrite found in solution, and the formation of either the sulfate of iron constituents. The availability and rate of diffusion of oxygen in the formations exerts control on the water quality. Discriminant-function analysis correctly classifies 89 percent of the observations into the Allegheny or Monongahela Formations. As a verifications, 39 of 41 observations from another study were correctly classified by formation. The differences in water chemistry between the Allegheny and the Monongahela Formations are gradational and are attributed the oxidation of iron sulfide. The diffusion and availability of oxygen, which controls the chemical reaction, is regulated by the porosity and permeability of the rock with respect to oxygen and the presence or absence of carbonates, which controls the pH.

Water-Resources Investigations Report↗

The application of an integrated biogeochemical model (PnET-BGC) to five forested watersheds in the Adirondack and Catskill regions of New York

PnET-BGC is an integrated biogeochemical model formulated to simulate the response of soil and surface waters in northern forest ecosystems to changes in atmospheric deposition and land disturbances. In this study, the model was applied to five intensive study sites in the Adirondack and Catskill regions of New York. Four were in the Adirondacks: Constable Pond, an acid-sensitive watershed; Arbutus Pond, a relatively insensitive watershed; West Pond, an acid-sensitive watershed with extensive wetland coverage; and Willy's Pond, an acid-sensitive watershed with a mature forest. The fifth was Catskills: Biscuit Brook, an acid-sensitive watershed. Results indicated model-simulated surface water chemistry generally agreed with the measured data at all five sites. Model-simulated internal fluxes of major elements at the Arbutus watershed compared well with previously published measured values. In addition, based on the simulated fluxes, element and acid neutralizing capacity (ANC) budgets were developed for each site. Sulphur budgets at each site indicated little retention of inputs of sulphur. The sites also showed considerable variability in retention of NO3-. Land-disturbance history and in-lake processes were found to be important in regulating the output of NO3- via surface waters. Deposition inputs of base cations were generally similar at these sites. Various rates of base cation outputs reflected differences in rates of base cation supply at these sites. Atmospheric deposition was found to be the largest source of acidity, and cation exchange, mineral weathering and in-lake processes served as sources of ANC. ?? 2004 John Wiley and Sons, Ltd.

Hydrological Processes↗

Unprocessed atmospheric nitrate in waters of the Northern Forest Region in the USA and Canada

Little is known about the regional extent and variability of nitrate from atmospheric deposition that is transported to streams without biological processing in forests. We measured water chemistry and isotopic tracers (δ 18 O and δ 15 N) of nitrate sources across the Northern Forest Region of the U.S. and Canada and reanalyzed data from other studies to determine when, where, and how unprocessed atmospheric nitrate was transported in catchments. These inputs were more widespread and numerous than commonly recognized, but with high spatial and temporal variability. Only 6 of 32 streams had high fractions (>20%) of unprocessed atmospheric nitrate during baseflow. Seventeen had high fractions during stormflow or snowmelt, which corresponded to large fractions in near-surface soil waters or groundwaters, but not deep groundwater. The remaining 10 streams occasionally had some (<20%) unprocessed atmospheric nitrate during stormflow or baseflow. Large, sporadic events may continue to be cryptic due to atmospheric deposition variation among storms and a near complete lack of monitoring for these events. A general lack of observance may bias perceptions of occurrence; sustained monitoring of chronic nitrogen pollution effects on forests with nitrate source apportionments may offer insights needed to advance the science as well as assess regulatory and management schemes.

Environmental Science and Technology↗

Data file: the 1976 Atlantic Margin Coring (AMCOR) Project of the U.S. Geological Survey

In 1976, the U.S. Geological Survey conducted the Atlantic Margin Coring Project (AMCOR) to obtain information on stratigraphy, hydrology and water chemistry, mineral resources other than petroleum hydrocarbons, and geotechnical engineering properties at sites widely distributed along the Continental Shelf and Slope of the Eastern United States (Hathaway and others, 1976, 1979). This program's primary purpose was to investigate a broad variety of sediment properties, many of which had not been previously studied in this region. Previous studies of sediments recovered by core drilling in this region were usually limited to one or two aspects of the sediment properties (Hathaway and others, 1979, table 2). The AMCOR program was limited by two factors: water depth and penetration depth. Because the ship selected for the program, the Glomar Conception , lacked dynamic positioning capability, its anchoring capacity determined the maximum water depth in which drilling could take place. Although it was equipped to anchor in water 450 m deep and did so successfully at one site, we attmepted no drilling in water depths greater than 300 m. Strong Gulf Stream currents at the one attempted deep (443 m) site frustrated attempts to "spud in" to begin the hole.

Open-File Report↗

North Dakota

North Dakota prairies contain numerous wetlands. The complex functions of these prairie wetlands have been of interest for decades. The hydrology, water chemistry, and biological characteristics of these wetlands are highly variable because of extreme warm/cold and wet/dry conditions. The U.S. Geological Survey (USGS) has been conducting studies (fig. 1) to gain insight into the functions of the prairie wetlands. The USGS Northern Prairie Wildlife Research Center in Jamestown has maintained an active wetland research program since the mid-1960’s. Current work in North Dakota began in 1978, and focuses on the response of biological communities to climate-induced variations in hydrology and chemistry, and on evaluating the success of previously drained wetlands restored under the Conservation Reserve Program (CRP) and on similar lands. The information provided from this long-term study has provided the bulk of our knowledge about prairie wetlands, and has provided land managers with valuable information to manage the Nation’s prairie wetland resource.

North Dakota↗

Hydraulic characterization of carbonate-rock and basin-fill aquifers near Long Canyon, Goshute Valley, northeastern Nevada

Understanding groundwater flow and pumping effects near pending mining operations requires accurate subsurface hydraulic characterization. To improve conceptual models of groundwater flow and development in the complex hydrogeologic system near Long Canyon Mine, in northwestern Goshute Valley, northeastern Nevada, the U.S. Geological Survey characterized the hydraulic properties of carbonate rocks and basin-fill aquifers using an integrated analysis of steady-state and stressed aquifer conditions informed by water chemistry and aquifer-test data. Hydraulic gradients and groundwater-age data in northern Goshute Valley indicate carbonate rocks in the Pequop Mountains just west and south of the Long Canyon Mine project area constitute a more permeable and active flow system than saturated rocks in the northern Pequop Mountains, western Toano Range, and basin fill. Permeable carbonate rocks in the northern Pequop Mountains, in part, discharge to the Johnson Springs wetland complex (JSWC), where mean groundwater ages range from 500 to 2,400 years and samples all contain a small fraction of modern waters, relative to mean ages of 8,600 to more than 22,000 years for most groundwater sampled to the north and east. Recharge to the JSWC occurs from a roughly 27-square-mile area in the upgradient Pequop Mountains to the west, composed mostly of permeable carbonate rock and fractured quartzite, and bounded by low-permeability shales and marbleized and siliclastic rocks. Single-well aquifer-test analyses provided transmissivity estimates at pumped wells. Transmissivity estimates ranged from 7,000 to 400,000 feet squared per day (ft 2 /d) in carbonate rocks and from 2,000 to 80,000 ft 2 /d in basin fill near the Long Canyon Mine. Water-level drawdown from multiple-well aquifer testing and rise from unintentional leakage into the overlying basin-fill aquifer were estimated and distinguished from natural fluctuations in 93 pumping and monitoring sites using analytical water-level models. Leakage of disposed aquifer-test pumpage occurred south of the aquifer test area through an unlined irrigation ditch. Drawdown was detected at distances of as much as 3 miles (mi) from pumping wells at all but one carbonate-rock site, at basin-fill sites on the alluvial fan immediately downgradient from pumping wells, and in Big Spring and spring NS-05. Similar drawdowns in carbonate rocks within the drawdown detection area suggest all wells penetrate a highly transmissive zone (HTZ) that is bounded by low-permeability rocks. Drawdown was not detected in carbonate rocks to the west of Canyon fault, in any basin-fill sites on the valley floor east of the Hardy fault, or at volcanic sites to the north, indicating that these major fault structures and (or) permeability contrasts between hydrogeologic units impeded groundwater flow or obscured pumping signals. Alternatively, unintentional leakage might have obscured drawdown at basin-fill sites on the valley floor, where water-level rise was detected at nine sites over 3 mi. Consistent hydraulic properties were estimated by simultaneously interpreting steady-state flow during predevelopment conditions and changes in groundwater levels and springflows from the 2016 carbonate-rock aquifer test with an integrated groundwater-flow model. Hydraulic properties were distributed across carbonate rocks, basin fill, volcanic rocks, and siliciclastic rocks with a hydrogeologic framework developed from geologic mapping and hydraulic testing. Estimated transmissivity distributions spanned at least three orders of magnitude in each rock unit. In the HTZ, simulated transmissivities ranged from 10,000 to 23,000,000 ft 2 /d, with the most transmissive areas occurring around Big Spring. Comparatively low carbonate-rock transmissivities of less than 10,000 ft 2 /d were estimated in the northern Pequop Mountains and poorly defined values of less than 1,000 ft 2 /d were estimated in the western Toano Range. Transmissivities in basin fill ranged from less than 10 to 80,000 ft 2 /d and were minimally constrained by the 2016 carbonate-rock aquifer test because poorly quantified leakage affected water levels more so than pumping. The most transmissive areas were informed by single-well aquifer tests along the eastern edge of the Pequop Mountains near Long Canyon Mine and could be indicative of a hydraulic connection between basin fill and more transmissive underlying carbonate rocks. Simulated transmissivities of volcanic and low-permeability rocks mostly are less than 1,000 ft 2 /d. The estimated hydraulic-property distributions and informed interpretation of hydraulic connections among hydrogeologic units improved the characterization and representation of groundwater flow near the Long Canyon Mine.

Nevada↗

Geohydrologic data for test well USW H-5, Yucca Mountain area, Nye County, Nevada

This report presents data on drilling operations, lithology, borehole geophysics, water-level monitoring, core analysis, ground-water chemistry, pumping tests, and packer-injection tests for test well USW H-5. The well is one of a series of test wells drilled in and near the southwestern part of the Nevada Test Site, Nye County, Nevada, in cooperation with the U.S. Department of Energy. These test wells are part of the Nevada Nuclear Waste Storage Investigations to identify suitable sites for storage of high-level radioactive wastes. Test well USW H-5 was drilled to a total depth of 1,219 meters through volcanic rocks consisting mostly of ash-flow tuff. Depth to water in the well ranged between 703.8 and 707.2 meters below land surface, at an approximate altitude of 704 meters above sea level. Drawdown in the well exceeded 6 meters after test pumping more than 3,000 minutes at a rate of 10 liters per second. Borehole-flow surveys showed that about 90 percent of the water in the well is contributed by the zone between 707 and about 820 meters below land surface. Two composite water samples collected after well completion contained 206 and 220 milligrams per liter of dissolved solids. Sodium and bicarbonate were the predominant dissolved anion and cation. The concentration of dissolved silica was 48 milligrams per liter in both samples, which is a relatively large concentration for most natural waters.

Nevada↗

Climatic drivers for multidecadal shifts in solute transport and methane production zones within a large peat basin

Northern peatlands are an important source for greenhouse gases, but their capacity to produce methane remains uncertain under changing climatic conditions. We therefore analyzed a 43 year time series of the pore-water chemistry to determine if long-term shifts in precipitation altered the vertical transport of solutes within a large peat basin in northern Minnesota. These data suggest that rates of methane production can be finely tuned to multidecadal shifts in precipitation that drive the vertical penetration of labile carbon substrates within the Glacial Lake Agassiz Peatlands. Tritium and cation profiles demonstrate that only the upper meter of these peat deposits was flushed by downwardly moving recharge from 1965 to 1983 during a Transitional Dry-to-Moist Period. However, a shift to a moister climate after 1984 drove surface waters much deeper, largely flushing the pore waters of all bogs and fens to depths of 2 m. Labile carbon compounds were transported downward from the rhizosphere to the basal peat at this time producing a substantial enrichment of methane in Δ 14 C with respect to the solid-phase peat from 1991 to 2008. These data indicate that labile carbon substrates can fuel deep production zones of methanogenesis that more than doubled in thickness across this large peat basin after 1984. Moreover, the entire peat profile apparently has the capacity to produce methane from labile carbon substrates depending on climate-driven modes of solute transport. Future changes in precipitation may therefore play a central role in determining the source strength of peatlands in the global methane cycle.

Minnesota↗

Relationship between annual runoff and watershed area for the eastern United States

As part of the U.S. Environmental Protection Agency's effort to determine the long-term effects of acidic deposition on surface water chemistry, annual runoff was estimated for about 1000 ungaged sites in the eastern U.S. using runoff contour maps. One concern in using contour maps was that a bias may be introduced in the runoff estimates due to the size of the 1000 ungaged sites relative to the size of the watersheds used in developing the maps. To determine if a bias was present the relationship between the annual runoff (expressed as depth) and the watershed area for the Northeast (NE) and Southern Blue Ridge Province (SBRP) was tested using five regional data bases. One short-term data base (1984 Water Year, n = 531) and two long-term data bases (1940&ndash;57, n = 134 and 1951&ndash;80, n = 342) were used in the NE. In the SBRP one short-term database (1984 Water Year, n = 531) and one long-term data base (1951&ndash;80, n = 60) were used. For the NE and the SBRP, runoff was not directly correlated with watershed area using the five regional databases. Also, runoff normalized by precipitation was not related to watershed area.

northeastern United States↗

Geohydrologic data for test well USW H-6 Yucca Mountain area, Nye County, Nevada

The following data are presented for test well USW H-6: drilling operations, lithology, availability of borehole geophysical logs , water levels, future availability of core analyses, water chemistry, pumping tests, and packer-injection tests. The well is one of a series of test wells drilled in and near Yucca Mountain adjacent to the Nevada Test Site, Nye County, Nevada, in cooperation with the U.S. Department of Energy. These investigations are part of the Nevada Nuclear Waste Storage Investigations to identify suitable sites for underground storage of high-level radioactive wastes. Test well USW H-6 was drilled to a total depth of 1,220 m. Rocks penetrated are predominantly ash-flow tuffs. Lava was encountered from 877 to 1 ,126 m. The composite static water level is approximately 526 m below land surface. The well was pumped during two periods. Maximum drawdown was about 18 m after pumping for 4,822 min at 28 L/sec, and 12 m after pumping for 2,226 min at 27 L/sec. A borehole flow survey showed that 91% of the water withdrawn from the well came from the depth intervals from 616 to 631 m, and from 777 to 788 m. (Author 's abstract)

Open-File Report↗

Geohydrology of the aquifers that may be affected by the surface mining of coal in the Fruitland Formation in the San Juan Basin, northwestern New Mexico

A monitoring network of 50 wells was installed from 1975 to 1979 in the surface-mineable coal area. The purpose of the network was to collect hydrologic data and to establish a data base. The hydrologic data consist of water level measurements, water chemistry, and selected aquifer characteristics. The four aquifers considered in this study are: (1) The Pictured Cliffs Sandstone; (2) coal seams and interbedded lithologic units of the Fruitland Formation; (3) overburden of the Kirtland Shale and Fruitland Formation; and (4) the alluvium along the Chaco River and its eastern and northeastern tributaries. Five sites were selected for study. Four of these sites, Western Coal Company 's lease near Fruitland, Bisti West, Kimbeto, and Ojo Encino, have surface-mineable coal. The Chaco River alluvium was selected because it is downstream from anticipated mining activity. The specific conductances of the representative water samples from selected wells in the 4 aquifers in the 5 study areas ranged from 800 to 23,000 microsiemens/cm at 25 C. The dominant cation in all samples was sodium. The water is brackish in the Pictured Cliffs Sandstone and in the coal seams and interbedded lithologic units of the Fruitland Formation. It is fresh to saline in the overburden of the Fruitland Shale and Fruitland Formation, and fresh to brackish in the Chaco River alluvium. (Author 's abstract)

Water-Resources Investigations Report↗