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In-situ geochronology using LA-ICP-MS/MS: Application of the Lu-Hf system in carbonate, apatite and fluorite

Geochronology is a fundamental tool for reconstructing earth history and constraining the timing of ore deposit formation. Traditionally, U-rich minerals like zircon, titanite, monazite and apatite have been analysed to determine the timing of mineralization and alteration events. However, not all deposits or alteration assemblages contain these minerals, and the U-Pb system can be disturbed due to open system behaviour. We present a methodology for obtaining in-situ Lu-Hf dates from various minerals to demonstrate the potential for dating ore deposits that lack U-rich minerals. Carbonate, apatite and fluorite minerals from different tectonic settings and geological environments were analysed. We acquired Lu-Hf and REE (rare earth element) data from carbonate minerals from a carbonatite orebody and dike samples from the Mountain Pass REE carbonatite deposit in California, USA. We also tested a ‘double-dating’ method, where U-Th-Pb dates and Lu-Hf dates were obtained from the same analysis of apatite from rocks in the Michigan’s Great Lakes Tectonic Zone. Preliminary results for Lu-Hf dating of fluorite from carbonatite rocks in the Lemitar Mountains of New Mexico are also included. The analytical methodology shows promising results in each of these cases where there is sufficient parent Lu and U and measurable daughter Hf and Pb respectively.

Conference Paper

Analyzing multi-year nitrate concentration evolution in Alabama aquatic systems using a machine learning model

Rising nitrate contamination in water systems poses significant risks to public health and ecosystem stability, necessitating advanced modeling to understand nitrate dynamics more accurately. This study applies the long short-term memory (LSTM) modeling to investigate the hydrologic and environmental factors influencing nitrate concentration dynamics in rivers and aquifers across the state of Alabama in the southeast of the United States. By integrating dynamic data such as streamflow and groundwater levels with static catchment attributes, the machine learning model identifies primary drivers of nitrate fluctuations, offering detailed insights into the complex interactions affecting multi-year nitrate concentrations in natural aquatic systems. In addition, a novel LSTM-based approach utilizes synthetic surface water nitrate data to predict groundwater nitrate levels, helping to address monitoring gaps in aquifers connected to these rivers. This method reveals potential correlations between surface water and groundwater nitrate dynamics, which is particularly meaningful given the lack of water quality observations in many aquifers. Field applications further show that, while the LSTM model effectively captures seasonal trends, limitations in representing extreme nitrate events suggest areas for further refinement. These findings contribute to data-driven water quality management, enhancing understanding of nitrate behavior in interconnected water systems.

Alabama

Beyond the mangroves: A global synthesis of tidal forested wetland types, drivers and future information opportunities

There is increasing awareness of the global diversity of tidal forested wetlands (TFWs) and their significance in the provision of ecosystem services. These ecosystems, including mangrove forests, tidal freshwater forested wetlands, supratidal forests and transitional forests together span multiple climatic zones, geomorphic settings, and inundation and salinity regimes. We utilise case studies across five continents to demonstrate the state of knowledge among TFWs. Intertidal mangroves are the best-defined of the TFWs thanks to decades of research on their geomorphology, hydrology and ecology across their broad distribution. Non-mangrove forest settings, however, demonstrate more diverse hydrological, biochemical and vegetation conditions. In many cases, non-mangrove forests are situated at upper intertidal or supratidal elevations, where surface waters and groundwater are subject to interactions between tides freshwater inputs. Salinity datasets show variations ranging from tidal freshwater forested wetlands and ‘low-salinity mangroves’ to mesohaline or marine salinities, often with high temporal variability. While the floristic composition of non-mangrove forests vary among biogeographic regions, locally dominant TFW species are commonly distributed beyond the tidal niche into non-tidal wetland and upland forests. This presents challenges for traditional remote sensing approaches to ecosystem mapping, which are mostly lacking for non-mangrove forests. Geomorphic approaches and developments in machine learning offer opportunities to address this.

Preprint

Potential for continental scientific drilling to inform fault mechanics and earthquake science

Our understanding of fault mechanics and earthquake processes remains limited, largely due to minimal direct observations near active faults at seismogenic depths. This lack of data restricts our ability to accurately assess and mitigate both natural and human-induced seismic hazards. However, recent advancements in drilling capabilities and downhole sensing technologies offer an opportunity: the ability to observe the physical conditions within a volume near active fault zones. In this contribution, we highlight how scientific drilling can provide access to the near-fault environment, enabling measurements of the stress, temperature, fluid pressure, and rock properties at depths where ruptures initiate, propagate, and arrest. These observations are essential to refine models of earthquake nucleation and dynamic rupture, bridging gaps between laboratory experiments, numerical simulations, and surface observations. These insights can advance fundamental understanding in earthquake science but also support the development of more effective seismic hazard assessments and risk mitigation strategies.

Seismica

Rapid earthquake magnitude classification via P-wave strains from borehole strainmeters and Distributed Acoustic Sensing

Distributed Acoustic Sensing (DAS) offers a promising approach for earthquake early warning (EEW) in settings where seismic networks are costly to maintain. By repurposing fiber-optic cables as dense strainmeter arrays, DAS enables real-time earthquake detection wherever those fibers are accessible. However, poor azimuthal coverage and challenges in estimating magnitude from strain measurements remain key hurdles in applying for earthquake monitoring. Here, we develop a machine learning method to distinguish large (M≥5.4) earthquakes from smaller ones within the first 4 seconds of a strain waveform after a P-wave arrival without determining location. Using ensemble decision tree models trained on borehole strainmeter data (3.5≤M≤7.1) and tested on onshore DAS waveforms (including the 2024 M7 Offshore Cape Mendocino earthquake), we find that low-frequency (0.2–0.5 Hz) continuous wavelet transform coefficients are the strongest predictors of magnitude, in addition to strain amplitude. Both DAS and borehole strainmeters effectively capture long-period strain signals, making these findings valuable for EEW systems. Our method shows high precision compared to the real-time EEW system, ShakeAlert®, supporting the position that DAS is a viable technology for earthquake monitoring and magnitude classification.

California

Landslide volume estimation from seismic waveform features using a global catalog of seismogenic events

Seismic waves generated by large, rapid landslides encode information about the source and can be analyzed rapidly following an event. Even remote landslides can pose hazards to downstream communities, so rapid detection and characterization using existing seismic monitoring networks could be beneficial. In this study, we expand on past regionally limited work by presenting a globally applicable method for estimating landslide volume from seismic features that could be integrated into future landslide seismic monitoring frameworks. We train the model using multivariable linear regression and five seismic features derived from recordings of 129 landslide events of a range of styles and locations with independently estimated volumes. We present two preferred models, one that combines long‐period (LP) and high‐frequency (HF) features and one for use on smaller landslides without observed long‐period signals. We find that our best‐performing model, applicable to landslides larger than 100,000 m 3 with signals containing observable long‐period energy, requires only two features: LP (20–100 s) absolute maximum amplitude and HF (1–5 Hz) rise time (time between the signal start and the maximum envelope amplitude) and has an R 2 score of 0.79. This model predicted volumes within one order of magnitude for 55 out of 58 events. We find that this combination mitigates the trade‐off between mass and acceleration and other variations of landslide style that limit methods based on amplitude alone.

Seismological Research Letters

Searching for seismic precursors - The Barry Landslide hazard clean up

The Barry Landslide, located in Barry Arm of Prince William Sound, Alaska, poses a major hazard due to its steep, unstable slopes and the potential for a massive landslide-generated tsunami. With an estimated volume of 500–700 million cubic meters, the Barry Landslide could trigger highly destructive waves. In this study, we focus on seismic signals from the Barry Landslide, which are critical for providing timely tsunami warnings. Since the summer of 2020, the region has been instrumented to monitor the landslide, but the seismic record is complicated by the presence of nearby glaciers and frequent regional earthquakes. Among these signals, we analyze a specific class of short-duration, high-frequency seismic events that exhibit strong seasonal variability, increasing in rate from late summer to mid-winter before ceasing abruptly in late winter or early spring. Our analysis suggests that the source of these signals is likely near or beneath Cascade Glacier, adjacent to the landslide, rather than within the landslide mass itself. We apply detection algorithms to construct a time history for this signal type, which we then compare with environmental factors like precipitation, temperature, and slope displacement data from ground-based radar and remote sensing. Correlations indicate that these seismic events may be driven by seasonal hydrological changes, particularly the freeze-up of subglacial water pathways. While these events are not directly linked to landslide motion, they serve as indirect markers of subsurface hydrological conditions that influence slope stability. Our findings highlight the complex interplay between glaciers, groundwater, and landslide dynamics, emphasizing the need for multi-parameter monitoring to assess evolving geohazards in the region.

Alaska

A review and synthesis of post-wildfire shifts in hydrologic processes and streamflow generation mechanisms

Critical water supply watersheds in the western United States (WUS) are impacted by wildfires, with potential negative effects on water quality and quantity. Scientific understanding is currently insufficient to deliver estimates of wildfire consequences for water quantity that are regionally accurate. Regional variability in the directionality and magnitude of post-wildfire shifts in streamflow generation fuels uncertainty in estimates of wildfire effects on water supply. In this work we provide a narrative review of wildfire effects on hydrologic processes and the resulting changes in streamflow generation mechanisms with a focus on the WUS, incorporating other global regions when pertinent. A conceptual model summary of wildfire effects on streamflow generation emphasizes: (1) precipitation seasonality, (2) synchrony of precipitation and potential evapotranspiration, (3) net shifts in interception, evaporation, and transpiration relative to total annual precipitation, (4) vegetation changes, including compensatory uptake and type conversion, (5) degree of overlap in rainfall rates and infiltration, (6) fire extent and severity, (7) burn scar positioning (e.g. in headwaters or proximal to watershed outlet), (8) scale-dependent groundwater leakage, (9) near-surface water storage reduction, and (10) soil to groundwater connectivity. Ongoing gaps and challenges include separating the influences of precipitation variability, water withdrawals, and post-fire land management; compound and overlapping disturbances; and lack of pre-fire data. Notable future opportunities include: harnessing ever-improving gridded and remotely sensed precipitation and fire-effects data; linking geophysical, isotopic tracer, and geochemical signatures to diagnose hydrologic changes; leveraging physically based and data-driven model advancements; and analyzing streamflow generation recovery trajectories across diverse watersheds.

western United States

Surface variable‐based machine learning for scalable arsenic prediction in undersampled areas

In the United States, private wells are not federally regulated, and many households do not test for Arsenic (As). Chronic exposure is linked with multiple health outcomes, and risk can change sharply over short distances and with well depth. Coarse maps or sparse sampling often miss exceedances. Most existing models operate at ∼1 km resolution and use groundwater chemistry or detailed geologic logs, which limits their use in undersampled areas where improved guidance is most needed. We overcome these limitations by developing a machine learning model for Minnesota, USA, that predicts As exposure risk using only surficial variables from remote sensing and global data sets. Variables related to surface water hydrology and geomorphology are selected based on mechanistic links that control redox conditions and As mobilization. Local training was essential, and surficial geology variables that are more sensitive to local conditions were needed to maximize model accuracy. The resulting complete model was sufficiently sensitive to generate accurate and detailed risk maps and depth profiles of As concentrations above the 10 μg/L maximum contaminant level. Accuracy depended on local training data density. We identified a training data density of 0.07 wells/km 2 as a practical target for stable county-level performance. Maps of exceedance probabilities highlight priority areas for testing that are particularly important in rural communities that have received less sampling. These results support public health action by guiding where to install wells and where to test them, how much new sampling is needed, and where treatment outreach is most urgent.

Minnesota

The 3D National Topography Model Call for Action—Part 2: The Next Generation 3D Elevation Program

The three-dimensional (3D) National Topography Model initiative to integrate elevation and hydrography data includes the next generation of hydrography data from the 3D Hydrography Program and the next generation of elevation data from the 3D Elevation Program (3DEP). The first-ever collection of light detection and ranging (lidar) data for the nation (IfSAR for Alaska) provides a critical baseline reference, and the addition of multiple repeat elevation mapping projects as part of the next generation of 3DEP would substantially expand analysis capabilities. As the U.S. Geological Survey (USGS) is closing in on our goal of complete coverage with 3DEP data available or in progress for 98.3 percent of the Nation at the end of fiscal year 2024, the USGS is already transitioning to the next generation of 3DEP. Based on the 3D Nation Study results and input from a broad range of stakeholders, the USGS National Geospatial Program has finalized a new design for 3DEP that provides increased lidar quality levels and refresh rates. The new program is designed with more flexibility to meet changing user needs and take advantage of improvements in mapping technologies. The program will aim to expand the level of interagency coordination for topobathymetric lidar acquisition for inland rivers. The next generation of 3DEP will also aim to emphasize research, including advancing program design, products, and services and engaging and leveraging the evolving 3D industry. Research goals also include becoming more flexible in meeting user needs and taking advantage of evolving remote-sensing technologies. The program also plans to move from focusing on producing standard products to producing a concept of a 3D Nation Ecosystem with a variety of inputs, products, and services.

Circular

The GorDAS Distributed Acoustic Sensing experiment above the Cascadia locked zone and subducted Gorda Slab

The southernmost portion of the Cascadia Subduction zone in Northern California produces high rates of moderate and large earthquakes owing to subduction of the Gorda slab and deformation associated with the Mendocino Triple Junction. Distributed Acoustic Sensing (DAS) is rapidly advancing as a method for detecting earthquakes and imaging crustal structure. We have begun a long-term DAS monitoring experiment on buried telecom fiber in Arcata, California, with the goal of increasing the available recordings of moderate to large earthquakes as well as imaging seismogenic structures. We have recorded over a year's worth of data, including most aftershocks of the 2022 M w 6.4 Ferndale earthquake, though not the mainshock itself. The dataset includes numerous magnitude 3.5 and larger earthquakes including the 2023/01/01 M w 5.4 Rio Dell earthquake. Here we present initial results comparing an earthquake detection algorithm, run in real-time on the processing unit of the interrogator system, with both the ShakeAlert earthquake early warning system as well as a post-processed earthquake catalog developed with deep-learning phase-picker algorithms. The rapid onboard processing of the detector demonstrates the potential utility of DAS-based edge computing for earthquake early warning. We also verify the quality of the strain waveforms both in terms of peak amplitudes and waveform similarity using about five months of nodal seismometer data. These instruments were deployed roughly every 300 m along the ~15km long cable and validate large variations in peak strain over short distances that are seen in the DAS data. All data from time windows surrounding both the local and teleseismic earthquakes are publicly available, which will improve our understanding of both the performance of DAS systems in moderate earthquakes and earthquake hazards associated with the Gorda subduction zone.

California

Remote compositional analyses of space-weathered lunar maria

Visible-to-shortwave infrared (VSWIR) reflectance spectroscopy has revolutionized our understanding of planetary surface compositions. However, space-weathering processes on airless bodies complicate quantitative compositional analyses. Here, we present a framework to isolate the signatures of space weathering in VSWIR spectra of lunar maria by leveraging radiative transfer modeling under the assumptions that (i) a space-weathered target can be expressed as a mixture of fresh and fully space-weathered components and (ii) remaining signatures can be modeled by including agglutinates as an end-member component. We first validate this approach against laboratory spectra of space-weathered Apollo mare soils of known mineral compositions using a probabilistic Markov Chain Monte Carlo implementation of the Hapke radiative transfer model. Second, we illustrate how this approach can be applied to orbital Moon Mineralogy Mapper data. The proposed space-weathering correction workflow for lunar maria could be expanded to other lunar lithologies and applied to existing and future data sets.

Planetary Science Journal

From hydrated silica to quartz: Potential hydrothermal precipitates found in Jezero crater, Mars

On Earth, silica-rich phases from opal to quartz are important indicators and tracers of geological processes. Hydrated silica, such as opal, is a particularly good matrix for the preservation of molecular and macroscopic biosignatures. Cherts, a type of silica-dominated rocks, provide a unique archive of ancient terrestrial life while quartz is the emblematic mineral of the Earth's continental crust. On Mars, hydrated silica has been detected in several locations based on remote sensing and rover-based studies. In the present article we report on the detection of cobbles made of hydrated silica (opal or chalcedony), as well as well-crystallized quartz. These detections were made with the SuperCam instrument onboard Perseverance (Mars 2020 mission), using a combination of LIBS, infrared and Raman spectroscopy. Quartz-dominated stones are detected unambiguously for the first time on the Martian surface, and based on grain size and crystallinity are proposed to be of hydrothermal origin. Although these rocks were all found as float, we propose that these detections are part of a common hydrothermal system, and represent different depths / temperatures of precipitation. This attests that hydrothermal processes were active in and around Jezero crater, possibly triggered by the Jezero crater-forming impact. These silica-rich rocks, in particular opaline silica, are very promising targets for sampling and return to Earth given their high biosignature preservation potential.

Earth and Planetary Science Letters

Woods Hole Coastal and Marine Science Center—2023 annual report

The 2023 annual report of the U.S. Geological Survey Woods Hole Coastal and Marine Science Center highlights accomplishments of 2023, includes a list of 2023 publications, and summarizes the work of the center, as well as the work of each of its science groups. This product allows readers to gain a general understanding of the focus areas of the center’s scientific research and learn more about specific projects and progress made throughout 2023, all while enjoying photographs taken in various environments and laboratories, and applicable maps and figures.

Circular

Woods Hole Coastal and Marine Science Center—2024 annual report

The 2024 annual report of the U.S. Geological Survey Woods Hole Coastal and Marine Science Center highlights accomplishments of 2024, includes a list of 2024 publications, and summarizes the work of the center, as well as the work of each of its science groups. This product allows readers to gain a general understanding of the focus areas of the center’s scientific research and learn more about specific projects and progress made throughout 2024, all while enjoying photographs taken in various environments and laboratories, and applicable maps and figures.

Circular

Assessing nonpoint-source uranium pollution in an irrigated stream-aquifer system

Uranium (U) in rocks and soils of arid and semi-arid environments can be mobilized by irrigation and fertilization, posing environmental and health risks. Elevated U, along with selenium (Se) and nitrate (NO 3 ) co-constituents, necessitates careful monitoring and management. We developed a distributed-parameter numerical model to assess U pollution in an irrigated stream-aquifer system, applying it to a 552 km 2 region in Colorado's Lower Arkansas River Valley (LARV) over 14 years. A MODFLOW model, describing groundwater and stream flow, was coupled with an RT3D-OTIS model to portray reactive U transport. Calibration using the PESTPP-iES iterative ensemble smoother (iES) software indicated good agreement with observed U concentrations. The model revealed substantial and variable U levels across the LARV, highlighting potential hotspots and possible contributing factors, such as geological composition of the bedrock and near-surface shale and aquifer sediments derived from them, irrigation practices, and riparian landscape. U levels exceed the chronic standard (85th percentile = 30 μg/L, set by the US Environmental Protection Agency), which is the permissible regulatory threshold, in groundwater across 44 % of the region and along the river by an average factor of 2.9. Simulated average U concentrations in the non-riparian aquifer and river are 124 μg/L and 60 μg/L, respectively, compared with 112 μg/L and 62 μg/L for measured values. The average 85th percentile U concentration is 222 μg/L in the aquifer and 82 μg/L in the river. Average simulated U mass loading to the river is 0.17 kg/day per km, compared to an estimated 0.23 kg/day per km. Findings provide a baseline for comparing future simulated outcomes of alternative best management practices (BMPs) for U pollution mitigation and offer a methodology applicable to other irrigated regions.

Colorado

Remote single-station seismic monitoring of the July–October 2022 earthquake swarm at Tau volcano, American Samoa

From July to October 2022, a non-eruptive volcanic earthquake swarm occurred within ~15 km of Taʻū Island, located in eastern American Samoa. Felt reports from local residents were the only available information about the swarm when it started, as American Samoa lacked a seismic monitoring network. We developed a consistent single-station catalog for the entire swarm, using seismic data from the nearest station IU.AFI, ~250 km away. We applied the EQTransformer deep-learning model (Mousavi et al., 2020), automatically picking Pn and Sn arrivals on IU.AFI continuous data. We retained only events with Sn-Pn times of 22.5–25 seconds, consistent with the expected locations based on felt reports, then detected smaller swarm events with subsequent template-matching. This single-station catalog characterized the swarm’s onset and escalation to peak activity before a multi-agency field response team installed a local seismic network in mid-August 2022. This permanent seismic network captured the swarm’s decline. EQTransformer identified short S-P times on the first two locally deployed seismometers, both Raspberry Shake sensors, to constrain the swarm’s distance from Taʻū Island. Modern seismological processing methods, combined with basic observations such as felt reports, can quickly contribute useful information during an earthquake response in a poorly monitored region.

American Somoa