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USGS2021

Eocene magma plumbing system beneath Cortez Hills Carlin-type gold deposit, Nevada: Is there a deep-seated pluton?

The magmatic-hydrothermal conceptual model for Carlin-type gold deposit genesis calls upon deep-seated Eocene plutons as the primary source of gold-bearing fluids. However, geophysical surveys, geologic mapping, drilling, geochronology, isotopic tracers, and fluid inclusion chemistry have returned ambiguous evidence for the existence of such plutons. The high-grade Cortez Hills gold deposit in northern Nevada hosts shallow, Eocene syn- and postmineralization intrusions, offering an ideal site to investigate the existence of a deep-seated pluton beneath the district. Here, major and trace element analyses of quartz-hosted melt inclusions from four Eocene rhyolite dikes cropping out within the Cortez Hills pit and results from independent thermobarometers provide a window into the subsurface Eocene magmatic plumbing system to test the existence of a deep-seated source pluton. Dissolved volatile contents, melt inclusion entrapment pressures, and thermodynamic phase equilibria indicate that dike magmas were sourced from ~4- to ≥9-km depth from a polybaric magma reservoir residing as a physically and geochemically interconnected crystal mush with extractable or eruptible magma pockets. Magmas ascended adiabatically (nearly isothermally), exsolving fluids, evolving modestly by fractional crystallization, while trapping quartz-hosted melt inclusions steadily from depth to subvolcanic levels where they were emplaced. These data represent the first unequivocal evidence for a deep-seated magma reservoir from which fluid-saturated magma emanated and released magmatic fluids beneath the Cortez district during gold mineralization. However, further investigation into the specific metallogenic potential and metal budget of parental magmas and the partitioning of gold between silicate melt and aqueous fluids will be necessary to provide evidence that exsolved magmatic fluids may have been gold bearing.

Nevada↗

USGS2004

Water-quality characteristics of quaternary unconsolidated-deposit aquifers and lower tertiary aquifers of the Bighorn Basin, Wyoming and Montana, 1999-2001

As part of the Yellowstone River Basin National Water Quality Assessment study, ground-water samples were collected from Quaternary unconsolidated-deposit and lower Tertiary aquifers in the Bighorn Basin of Wyoming and Montana from 1999 to 2001. Samples from 54 wells were analyzed for physical characteristics, major ions, trace elements, nutrients, dissolved organic carbon, radionuclides, pesticide compounds, and volatile organic compounds (VOCs) to evaluate current water-quality conditions in both aquifers. Water-quality samples indicated that waters generally were suitable for most uses, and that natural conditions, rather than the effects of human activities, were more likely to limit uses of the waters. Waters in both types of aquifers generally were highly mineralized, and total dissolved-solids concentrations frequently exceeded the U.S. Environmental Protection Agency (USEPA) Secondary Maximum Contaminant Level (SMCL) of 500 milligrams per liter (mg/L). Because of generally high mineralization, waters from nearly one-half of the samples from Quaternary aquifers and more than one-half of the samples from lower Tertiary aquifers were not classified as fresh (dissolved-solids concentration were not less than 1,000 mg/L). The anions sulfate, fluoride, and chloride were measured in some ground-water samples at concentrations greater than SMCLs. Most waters from the Quaternary aquifers were classified as very hard (hardness greater than 180 mg/L), but hardness varied much more in waters from the lower Tertiary aquifers and ranged from soft (less than 60 mg/L) to very hard (greater than 180 mg/L). Major-ion chemistry varied with dissolved-solids concentrations. In both types of aquifers, the predominant anion changes from bicarbonate to sulfate with increasing dissolved-solids concentrations. Samples from Quaternary aquifers with fresh waters generally were calcium-bicarbonate, calcium-sodium-bicarbonate, and calcium-sodium-sulfate-bicarbonate type waters, whereas samples with larger concentrations generally were calcium-sodium-sulfate, calcium-sulfate, or sodium-sulfate-type waters. In the lower Tertiary aquifers, samples with fresh waters generally were sodium-bicarbonate or sodium-bicarbonate-sulfate type waters, whereas samples with larger concentrations were sodium-sulfate or calcium-sodium-sulfate types. Concentrations of most trace elements in both types of aquifers generally were small and most were less than applicable USEPA standards. The trace elements that most often did not meet USEPA secondary drinking-water standards were iron and manganese. In fact, the SMCL for manganese was the most frequently exceeded standard; 68 percent of the samples from the Quaternary aquifers and 31 percent of the samples from the lower Tertiary aquifers exceeded the manganese standard. Geochemical conditions may control manganese in both aquifers as concentrations in Quaternary aquifers were negatively correlated with dissolved oxygen concentrations and concentrations in lower Tertiary aquifers decreased with increasing pH. Elevated nitrate concentrations, in addition to detection of pesticides and VOCs in both aquifers, indicated some effects of human activities on ground-water quality. Nitrate concentrations in 36 percent of the wells in Quaternary aquifers and 28 percent of the wells in lower Tertiary aquifers were greater than 1 mg/L, which may indicate ground-water contamination from human sources. The USEPA drinking-water Maximum Contaminant Level (MCL) for nitrate, 10 mg/L, was exceeded in 8 percent of samples collected from Quaternary aquifers and 3 percent from lower Tertiary aquifers. Nitrate concentrations in Quaternary aquifers were positively correlated with the percentage of cropland and other agricultural land (non-cropland), and negatively correlated with rangeland and riparian land. In the lower Tertiary aquifers, nitrate concentrations only were correlated with the percentage of cropland. Concentratio

Scientific Investigations Report↗

USGS2009

Structural characterization of terrestrial microbial Mn oxides from Pinal Creek, AZ

The microbial catalysis of Mn(II) oxidation is believed to be a dominant source of abundant sorption- and redox-active Mn oxides in marine, freshwater, and subsurface aquatic environments. In spite of their importance, environmental oxides of known biogenic origin have generally not been characterized in detail from a structural perspective. Hyporheic zone Mn oxide grain coatings at Pinal Creek, Arizona, a metals-contaminated stream, have been identified as being dominantly microbial in origin and are well studied from bulk chemistry and contaminant hydrology perspectives. This site thus presents an excellent opportunity to study the structures of terrestrial microbial Mn oxides in detail. XRD and EXAFS measurements performed in this study indicate that the hydrated Pinal Creek Mn oxide grain coatings are layer-type Mn oxides with dominantly hexagonal or pseudo-hexagonal layer symmetry. XRD and TEM measurements suggest the oxides to be nanoparticulate plates with average dimensions on the order of 11 nm thick × 35 nm diameter, but with individual particles exhibiting thickness as small as a single layer and sheets as wide as 500 nm. The hydrated oxides exhibit a 10-Å basal-plane spacing and turbostratic disorder. EXAFS analyses suggest the oxides contain layer Mn(IV) site vacancy defects, and layer Mn(III) is inferred to be present, as deduced from Jahn–Teller distortion of the local structure. The physical geometry and structural details of the coatings suggest formation within microbial biofilms. The biogenic Mn oxides are stable with respect to transformation into thermodynamically more stable phases over a time scale of at least 5 months. The nanoparticulate layered structural motif, also observed in pure culture laboratory studies, appears to be characteristic of biogenic Mn oxides and may explain the common occurrence of this mineral habit in soils and sediments.

Geochimica et Cosmochimica Acta↗

USGS2014

Variation in the terrestrial isotopic composition and atomic weight of argon

The isotopic composition and atomic weight of argon (Ar) are variable in terrestrial materials. Those variations are a source of uncertainty in the assignment of standard properties for Ar, but they provide useful information in many areas of science. Variations in the stable isotopic composition and atomic weight of Ar are caused by several different processes, including (1) isotope production from other elements by radioactive decay (radiogenic isotopes) or other nuclear transformations (e.g., nucleogenic isotopes), and (2) isotopic fractionation by physical-chemical processes such as diffusion or phase equilibria. Physical-chemical processes cause correlated mass-dependent variations in the Ar isotope-amount ratios ( 40 Ar/ 36 Ar, 38 Ar/ 36 Ar), whereas nuclear transformation processes cause non-mass-dependent variations. While atmospheric Ar can serve as an abundant and homogeneous isotopic reference, deviations from the atmospheric isotopic ratios in other Ar occurrences limit the precision with which a standard atomic weight can be given for Ar. Published data indicate variation of Ar atomic weights in normal terrestrial materials between about 39.7931 and 39.9624. The upper bound of this interval is given by the atomic mass of 40 Ar, as some samples contain almost pure radiogenic 40 Ar. The lower bound is derived from analyses of pitchblende (uranium mineral) containing large amounts of nucleogenic 36 Ar and 38 Ar. Within this interval, measurements of different isotope ratios ( 40 Ar/ 36 Ar or 38 Ar/ 36 Ar) at various levels of precision are widely used for studies in geochronology, water–rock interaction, atmospheric evolution, and other fields.

Pure and Applied Chemistry↗

USGS2004

Chapter G: Tentative Correlation Between CIPW Normin pl (Total Plagioclase) and Los Angeles Wear in Precambrian Midcontinental Granites-Examples from Missouri and Oklahoma, with Applications and Limitations for Use

The normative chemical classification of Cross, Iddings, Pirsson, and Washington (CIPW) is commonly used in igneous petrology to distinguish igneous rocks by comparing their magmatic chemistries for similar and dissimilar components. A potential use for this classification other than in petrologic studies is in the rapid assessment of aggregate sources, possibly leading to an economic advantage for an aggregate producer or user, by providing the opportunity to determine whether further physical testing of an aggregate is warranted before its use in asphalt or concrete pavement. However, the CIPW classification currently should not be substituted for the physical testing required in specifications by State departments of transportation. Demands for physical testing of aggregates have increased nationally as users seek to maximize the quality of the aggregate they purchase for their pavements. Concrete pavements are being laid with increased thicknesses to withstand increasing highway loads. New pavement mixes, most notably Superior Performance Asphalt Pavement ('Superpave'), are designed for additional service life. For both concrete and asphalt, the intent is to generate a durable pavement with a longer service life that should decrease overall life-cycle costs. Numerous aggregate producers possess chemical-composition data available for examination to answer questions from the potential user. State geological surveys also possess chemical-composition data for stone sources. Paired with the results of physical testing, chemical- composition data provide indicative information about stone durability and aggregate strength. The Missouri Department of Transportation has noted a possible relation among coarse-grained Precambrian granites of the midcontinental region, correlating the results of abrasion testing with the contents of normative minerals, also known as normins, calculated from chemical composition data. Thus, normin pl ( total plagioclase) can predict, by way of simple regression, the Los Angeles wear for granite samples collected in Missouri. The results of this abrasion testing were extended to another granite in Oklahoma where normin pl predicted Los Angeles wear to within 0.6 percent. This relation may also exist for granitic rocks outside the Oklahoma-Missouri region, as well as for other igneous-rock types.

Bulletin↗

USGS1997

Physical and chemical characteristics of Terrace Reservoir, Conejos County, Colorado, May 1994 through May 1995

Terrace Reservoir receives drainage of low-pH, metal-enriched water from mineralized areas, including the Summitville Mine, within the Alamosa River Basin. Drainage from the Summitville Mine has contributed a substantial part of the metal load to Terrace Reservoir. From May 1994 through May 1995, a study was done by the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency, to evaluate the physical and chemical characteristics of Terrace Reservoir. Terrace Reservoir was thermally stratified from about mid-May through August 1994. Thermal stratification was absent from September\x111994through March 1995. During periods of stratification, underflow of the Alamosa River was predominant, and residence times of the underflow were shortened by 40 to 75\x11percent of the theoretical residence times for a well-mixed reservoir. Transport and deposition of suspended solids in Terrace Reservoir varied spatially and temporally. Most of the suspended solids were deposited in Terrace Reservoir. The concentration of dissolved oxygen in the reservoir varied little spatially or temporally and generally was within a few tenths of the dissolved-oxygen concentration of the inflow. The pH of water in the reservoir generally ranged from about 4.0 to about 7.0, depending on date, depth, and location. The largest pH values were measured during May. A markeddecrease of about 1.5\x11pH units occurred at site T5 in the reservoir about mid-June. The pH of the reservoir remained at or below 5.5 from mid-June through November. Dissolved-metal concentrations varied spatially and temporally in response to several factors, which included inflow characteristics, reservoir stratification and mixing, inflow-routing and flow-through patterns, residence times, sedimentation, dissolved oxygen, and pH.Inflow chemistry is the dominant controlling factor of metal chemistry within Terrace Reservoir.During periods of stratification, large vertical variations in metal concentrations occurred. The highest metal concentrations in the reservoir generally were measured in the hypolimnion between June and August. During June, epilimnetic water of the reservoir had pH values greater than 6.0, and metal concentrations were lower than hypolimnetic concentrations. In the hypolimnion, pH values were less than 5.5. The difference between the chemistry of the epilimnion and the hypolimnion was due to differences in flow routing and residence times of water in those respective layers. The dissolved-metal concentrations were larger during July and August than during June.During September, small vertical variations in metalconcentrations occurred, and the dissolved-metal concentrations were nearly equivalent to the average August metal concentrations, indicatingthat the metal concentrations measured during September resulted largely from reservoir mixing.During March, the largest metal concentrationsoccurred in the epilimnion, where pH was about 5.5; in the hypolimnion, where the pH was about 6.0, dissolved-metal concentrations were substantially lower and reflected inflow concentrations.

Colorado↗

USGS1996

Physical and chemical characteristics of Terrace Reservoir, Conejos County, Colorado, May 1994 through May 1995; interim report

Terrace Reservoir receives drainage of low-pH, metal-enriched water from mineralized areas, including the Summitville Mine, within the Alamosa River Basin. Drainage from the Summitville Mine has contributed a substantial part of the metal load to Terrace Reservoir. From May 1994 through May 1995, a study was done by the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency, to evaluate the physical and chemical characteristics of Terrace Reservoir. Terrace Reservoir was thermally stratified from about mid-May through August 1994. Thermal stratification was absent from September\x111994through March 1995. During periods of stratification, underflow of the Alamosa River was predominant, and residence times of the underflow were shortened by 40 to 75\x11percent of the theoretical residence times for a well-mixed reservoir. Transport and deposition of suspended solids in Terrace Reservoir varied spatially and temporally. Most of the suspended solids were deposited in Terrace Reservoir. The concentration of dissolved oxygen in the reservoir varied little spatially or temporally and generally was within a few tenths of the dissolved-oxygen concentration of the inflow. The pH of water in the reservoir generally ranged from about 4.0 to about 7.0, depending on date, depth, and location. The largest pH values were measured during May. A markeddecrease of about 1.5\x11pH units occurred at site T5 in the reservoir about mid-June. The pH of the reservoir remained at or below 5.5 from mid-June through November. Dissolved-metal concentrations varied spatially and temporally in response to several factors, which included inflow characteristics, reservoir stratification and mixing, inflow-routing and flow-through patterns, residence times, sedimentation, dissolved oxygen, and pH. Inflow chemistry is the dominant controlling factor of metal chemistry within Terrace Reservoir. During periods of stratification, large vertical variations in metal concentrations occurred. The highest metal concentrations in the reservoir generally were measured in the hypolimnion between June and August. During June, epilimnetic water of the reservoir had pH values greater than 6.0, and metal concentrations were lower than hypolimnetic concentrations. In the hypolimnion, pH values were less than 5.5. The difference between the chemistry of the epilimnion and the hypolimnion was due to differences in flow routing and residence times of water in those respective layers. The dissolved-metal concentrations were larger during July and August than during June. During September, small vertical variations in metal concentrations occurred, and the dissolved-metal concentrations were nearly equivalent to the average August metal concentrations, indicatingthat the metal concentrations measured during September resulted largely from reservoir mixing.During March, the largest metal concentrationsoccurred in the epilimnion, where pH was about 5.5; in the hypolimnion, where the pH was about 6.0, dissolved-metal concentrations were substantially lower and reflected inflow concentrations.

Colorado↗

USGS1971

Magnetic susceptibility and triangular exchange coupling in the tourmaline mineral group

Magnetic susceptibilities of three iron-rich tourmaline crystals from Mexquitic (Mexico), Pierpont (New York), and Madagascar with different and known chemical compositions have been studied from 8° to 300°K. The iron atoms in the tourmaline crystal structure, space group R3m , a∼15·9, c∼7·2 , are situated at the three corners of an equilateral triangle and are close enough for magnetic exchange interaction. For buergerite, the Mexquitic sample, the susceptibility data lead to an exchange constant J/k of 7·5°K. Although the amount of aluminum would be sufficient to fill point position 18(c) exactly, the magnetic data are consistent with some substitution of ferric iron for aluminum, as previously determined from X-ray and neutron diffraction studies. Some aluminum thus replaces iron in position 9(b). Exchange constants were also estimated for the other two magnesium-iron specimens, of which the madagascar sample is aluminum deficient. The results agree with the evidence from optical spectra that there is considerable deviation from octahedral symmetry in the oxygen coordination polyhedra about the 9(b) and 18(c) point positions.

New York↗

USGS1992

Rare earth, major and trace element composition of Leg 127 sediments

The relative effects of paleoceanographic and paleogeographic variations, sediment lithology, and diagenetic processes on the final preserved chemistry of Japan Sea sediments are evaluated by investigating the rare earth element (REE), major element, and trace element concentrations in 59 squeeze-cake whole-round and 27 physical-property sample residues from Sites 794, 795, and 797, cored during ODP Leg 127. The most important variation in sedimentary chemical composition is the increase in SiO2 concentration through the Pliocene diatomaceous sequences, which dilutes most other major and trace element components by various degrees. This biogenic input is largest at Site 794 (Yamato Basin), moderately developed at Site 797 (Yamato Basin), and of only minor importance at Site 795 (Japan Basin), potentially reflecting basinal contrasts in productivity with the Yamato Basin recording greater biogenic input than the Japan Basin and with the easternmost sequence of Site 794 lying beneath the most productive waters. There are few systematic changes in solid-phase chemistry resulting from the opal-A/opal-CT or opal-CT/quartz silica phase transformations. Most major and trace element concentrations are controlled by the aluminosilicate fraction of the sediment, although the effects of diagenetic silica phases and manganese carbonates are of localized importance. REE total abundances (IREE) in the Japan Sea are strongly dependent upon the paleoceanographic position of a given site with respect to terrigenous and biogenic sources. REE concentrations at Site 794 overall correspond well to aluminosilicate chemical indices and are strongly diluted by SiO2 within the upper Miocene-Pliocene diatomaceous sequence. Eu/Eu* values at Site 794 reach a maximum through the diatomaceous interval as well, most likely suggesting an association of Eu/Eu* with the siliceous component, or reflecting slight incorporation of a detrital feldspar phase. XREE at Site 795 also is affiliated strongly with aluminosilicate phases and yet is diluted only slightly by siliceous input. At Site 797, ΣRE E is not as clearly associated with the aluminosilicate fraction, is correlated moderately to siliceous input, and may be sporadically influenced by detrital heavy minerals originating from the nearby rifted continental fragment composing the Yamato Rise. Ce/Ce* profiles at all three sites increase essentially monotonically with depth and record progressive diagenetic LREE fractionation. The observed Ce/Ce* increases are not responding to changes in the paleoceanographic oxygenation state of the overlying water, as there is no independent evidence to suggest the proper Oceanographic conditions. Ce/Ce* correlates slightly better with depth than with age at the two Yamato Basin sites. The downhole increase in Ce/Ce* at Sites 794 and 797 is a passive response to the diagenetic transfer of LREE (except Ce) from sediment to interstitial water. At Site 795, the overall lack of correlation between Ce/Ce* and La/Y^ suggests that other processes mask the diagenetic behavior of all LREEs. First-order calculations of the Ce budget in Japan Sea waters and sediment indicate that ~20% of the excess Ce adsorbed by settling particles is recycled within the water column and that an additional -38% is recycled at or near the seafloor. Thus, because the remaining excess Ce is only -10% of the total Ce, there is not a large source of Ce to the deeply buried sediment, further suggesting that the downhole increase in Ce/Ce* is a passive response to diagenetic behavior of the other LREEs. The REE chemistry of Japan Sea sediment therefore predicts successive downhole addition of LREEs to deeply buried interstitial waters.

Conference Paper↗

USGS1990

Textural development of clayey and quartzofeldspathic fault gouges relative to their sliding behavior

Many of the secondary fault structures developed during triaxial friction experiments have been generally correlated with the structures of natural fault zones. Therefore, any physical differences that can be found between laboratory samples that slide stably and those that show stick-slip motion may help to identify the cause of earthquakes. We have examined petrographically the run products of many triaxial friction experiments using clayey and quartzofeldspathic gouges, which comprise the principal types of natural fault gouge material. The examined samples were tested under a wide range of temperature, confining and fluid pressure, and velocity conditions. The clayey and quartzofeldspathic gouges show some textural differences, owing to their different mineral contents and grain sizes and shapes. In the clayey gouges, for example, a clay mineral fabric and kink band sets are commonly developed, whereas in the quartzofeldspathic gouges fracturing and crushing of the predominately quartz and feldspar grains are important processes. For both types of gouge, however, and whatever the pressure-temperature-velocity conditions of the experiments, the transition from stable sliding to stick-slip motion is correlated with: (i) a change from pervasive deformation of the gouge layer to localized slip in subsidiary shears; and (ii) an increase in the angle betweem the shears that crosscut the gouge layer (Riedel shears) and ones that form along the gouge-rock cylinder boundaries (boundary shears). This suggests that the localization of shear within a fault zone combined with relatively high Riedel-shear angles are somehow connected with earthquakes. Secondary fracture sets similar to Riedel shears have been identified at various scales in major strike-slip faults such as the San Andreas of the western United States (Wallace, 1973) and the Luhuo and Fuyun earthquake faults of China (Deng and Zhang, 1984; Deng et al. , 1986). The San Andreas also contains locked and creeping sections that correspond to the stick-slip and stably sliding experimental samples, respectively. We plan to study the physical structure of the San Andreas fault, to see if the experimentally observed differences related to sliding behavior can also be distinguished in the field.

Physics and Chemistry of the Earth↗

USGS2015

Applied Geochemistry Special Issue on Environmental geochemistry of modern mining

Environmental geochemistry is an integral part of the mine-life cycle, particularly for modern mining. The critical importance of environmental geochemistry begins with pre-mining baseline characterization and the assessment of environmental risks related to mining, continues through active mining especially in water and waste management practices, and culminates in mine closure. The enhanced significance of environmental geochemistry to modern mining has arisen from an increased knowledge of the impacts that historical and active mining can have on the environment, and from new regulations meant to guard against these impacts. New regulations are commonly motivated by advances in the scientific understanding of the environmental impacts of past mining. The impacts can be physical, chemical, and biological in nature. The physical challenges typically fall within the purview of engineers, whereas the chemical and biological challenges typically require a multidisciplinary array of expertise including geologists, geochemists, hydrologists, microbiologists, and biologists. The modern mine-permitting process throughout most of the world now requires that potential risks be assessed prior to the start of mining. The strategies for this risk assessment include a thorough characterization of pre-mining baseline conditions and the identification of risks specifically related to the manner in which the ore will be mined and processed, how water and waste products will be managed, and what the final configuration of the post-mining landscape will be. In the Fall 2010, the Society of Economic Geologists held a short course in conjunction with the annual meeting of the Geological Society of America in Denver, Colorado (USA) to examine the environmental geochemistry of modern mining. The intent was to focus on issues that are pertinent to current and future mines, as opposed to abandoned mines, which have been the focus of numerous previous short courses. The geochemical challenges of current and future mines share similarities with abandoned mines, but differences also exist. Mining and ore processing techniques have changed; the environmental footprint of waste materials has changed; environmental protection has become a more integral part of the mine planning process; and most historical mining was done with limited regard for the environment. The 17 papers in this special issue evolved from the Society of Economic Geologists’ short course. The relevant geochemical processes encompass the source, transport, and fate of contaminants related to the life cycle of a mine. Contaminants include metals and other inorganic species derived from geologic sources such as ore and solid mine waste, and substances brought to the site for ore processing, such as cyanide to leach gold. Factors, such as mine-waste mineralogy, hydrologic setting, mine-drainage chemistry, and microbial activity, that affect the hydrochemical risks from mining are reviewed by Nordstrom et al. In another paper, Nordstrom discusses baseline characterization at mine sites in a regulatory framework, and emphasizes the influence of mineral deposits in producing naturally elevated concentrations of many trace elements in surface water and groundwater. Surface water quality in mineralized watersheds is influenced by a number of processes that act on daily (diel) cycles and can produce dramatic variations in trace element concentrations as described by Gammons et al. Pre-mining baseline characterization studies should strive to capture the magnitude of these diel variations. Desbarats et al., using a case study of mine drainage from a gold mine, illustrate how elements that commonly occur as negatively charged species (anions) in solution, such as arsenic as arsenate, behave in an opposite fashion than most metals, which occur as positively charged species (cations). Significant improvement in the understanding of factors that influence the toxicity of metals to aquatic organisms in surface water has highlighted the importance of aqueous chemistry, particularly dissolved organic carbon, as described by Smith et al. Stream sediment contamination is another important pathway for affecting aquatic organisms, as reviewed by Besser et al. Understanding and predicting environmental consequences from mining begins with knowing the mineralogy and mineral reactivity of the ore, the wastes, and of secondary minerals formed later. Jamieson et al. review the importance of mineralogical studies in mine planning and remediation. A number of types of site-specific studies are needed to identify environmental risks related to individual mines. Lapakko reviews the general framework of mine waste characterization studies that are integral to the mine planning process. Hageman et al. present a comparative study of several static tests commonly used to characterize mine waste. The mining and ore processing practices employed at a specific mine site will vary on the basis of the commodities being targeted, the geology of the deposit, the geometry of the deposit, and the mining and ore processing methods used. Thus, these factors, in addition to the waste management practices used, can result in a variety of end-member mine waste features, each of which has its own set of challenges. Open pit mines and underground mines require waste rock to be removed to access ore. Waste rock presents unique problems because the rock is commonly mineralized at sub-economic grades and has not been processed to remove potentially problematic minerals, such as pyrite. Amos et al. examine the salient aspects of the geochemistry of waste rock. Mill tailings – the waste material after ore minerals have been removed – are a volumetrically important solid waste at many mine sites. Their fine grain size and the options for their management make their behavior in the environment distinct from that of waste rock. Lindsay et al. describe some of these differences through three case-study examples. Subaqueous disposal of tailings is another option described by Moncur et al. Cyanide leaching for gold extraction is a common method throughout the world. Johnson describes environmental aspects of cyanidation. Uranium mining presents unique environmental challenges, particularly since in-situ recovery has seen widespread use. Campbell et al. review the environmental geochemistry of uranium mining and current research on bioremediation. Ore concentrates from many types of metal mining undergo a pyrometallurgical technique known as smelting to extract the metal. Slag is the result of smelting, and it may be an environmental liability or a valuable byproduct, as described by Piatak et al. Finally, the open pits that result from surface mining commonly reach below the water table. At the end of mining, these pits may fill to form lakes that become part of the legacy of the mine. Castendyk et al., in two papers, review theoretical aspects of the environmental limnology of pit lakes. They also describe approaches that have been used to model pit lake water balance, wall-rock contributions to pit lake chemistry, pit lake water quality, and limnological processes, such as vertical mixing, through the use of three case studies.

Applied Geochemistry↗

USGS2002

Physical data of soil profiles formed on late Quaternary marine terraces near Santa Cruz, California

The marine terraces in and around Santa Cruz, California, represent a set of well-preserved terraces formed as a product of geology, sea level, and climate. A marine terrace begins as a wave cut platform. Eustatic sea level changes, seacliff erosion, and tectonic uplift work together to generate marine terraces. "When a wave-cut platform is raised (due to tectonic activity) above sea level and cliffed by wave action it becomes a marine terrace" (Bradley, 1957, p. 424). During glacial periods, eustatic sea level is estimated to have dropped by 150 meters (Fairbanks, 1989). Cliff retreat measured from aerial photographs between 1930 and 1980 vary from 0.0 to 0.2 m yr–1 (Best and Griggs, 1991). Estimates of uplift rates along the Santa Cruz coastline vary from 0.10 to 0.48 m kyr–1 (Bradley and Griggs, 1976; Weber and others, 1999). Uplift mechanisms include coseismic uplift associated both with a reverse component of slip on the steeply SW dipping Loma Prieta fault in the restraining bend of the San Andreas Fault and a small component of reverse slip on the steeply SE dipping San Gregorio fault (Anderson and Menking 1994). Previous work studying physical properties on these terraces include Pinney and others (in press) and Aniku (1986) and Bowman and Estrada (1980). Sedimentary deposits of the marine terraces are a mixture of terrestrial and marine sediments but generally consist of a sheet of marine deposits overlying the old platform and a wedge of nonmarine deposits banked against the old sea cliff (Bradley, 1957). Bedrock underlying the terraces in the Santa Cruz area is generally either Santa Margarita Sandstone or Santa Cruz Mudstone. The Santa Margarita Sandstone represents an upper Miocene, transgressive, tidally dominated marine-shelf deposit with crossbedded sets of sand and gravel and horizontally stratified and bioturbated invertebrate-fossils beds (Phillips, 1990). The siliceous Santa Cruz Mudstone, of late Miocene age, conformably overlies the Santa Margarita Sandstone. The Santa Cruz Mudstone is a thin to medium-bedded siliceous mudstone with nonsiliceous mudstone and siltstone and minor amounts of sandstone. The siliceous nature implies organic deposition in a quiescent, deep-water environment. Bedrock is mantled by 1–4 meters of medium to coarse-grained regressive beach sediment and fluvial deposits from the Ben Lomond Mountains. Terrace age increases with elevation above sea level, and weathering of primary minerals increases with age. The suite of soils formed on the terraces is referred to as a soil chronosequence. Soil chronosequences, important tools in characterizing natural weathering rates, are defined as a group of soils that differ in age and therefore in duration of weathering but have similar climatic conditions, vegetation, geomorphic position, and parent material (Jenny, 1941; Birkland, 1999). Soils are frequently useful indicators of geomorphic age (Muhs, 1982; Switzer and others, 1988) and are a function of pedogenic and/or eolian processes. Some aspects of soil development can be episodic but when viewed on large time scales can be perceived as continuous (Switzer and others, 1988). The age of the soil may be constrained by the age of the deposit, since soil formation generally commences when deposition has ceased (Birkland, 1999). Dating of the terraces provides an unprecedented opportunity to study weathering and soil-formation rates (Perg and others, 2001; Hanks and others, 1984; Bradley and Griggs, 1976; Bradley and Addicott, 1968; Bradley, 1956). Ages of the terraces recently dated by cosmogenic radionuclide are, starting with the youngest, 65, 92, 137, 139, and 226 k.y. (Perg and others, 2001). However, these ages are much younger than recent radiometric dates on mollusk shells (Muhs, U.S. Geological Survey, personal communication, 2002; Bradley and Addicott, 1968). For this study, soils were sampled on five terraces. Terrace one in the Lighthouse Field along Westcliff in Santa Cruz was the last site selected, and this report contains minimal data on this terrace. Sites on the second, third, and fourth terraces are located in Wilder Ranch, Santa Cruz, California. Site five is on private property north of Wilder Ranch. Careful consideration was taken in selecting field sites, choosing locations in a topographically flat area to avoid effects of erosion, and trying to keep parent material similar. This report contains physical properties of the soil profiles on four of the five marine terraces near Santa Cruz, California, excluding the youngest terrace in all tables except 6 and 7. Data includes field descriptions, bulk density, grain size analyses, weight percent magnetic fraction, and the soil development index. Soil properties are important when trying to understand the chemistry of a given profile or when comparing profiles. Grain size constrains the movement of water in a profile, thus controlling movement of chemicals and weathering rates. Bulk density is a useful property to calculate chemical inventory. Quantifying the magnetic fraction aids in understanding the Fe inventory for these soils. The soil development index is a semi-quantitative way to define the degree of development of a soil profile. This is a useful way to compare development of profiles for this chronosequence or compare the Santa Cruz terraces to a suit of other terraces or another chronosequence.

California↗

USGS1981

Natural occurrence and significance of fluids indicating high pressure and temperature

Most natural minerals have formed from a fluid phase such as a silicate melt or a saline aqueous solution. Fluid inclusions are tiny volumes of such fluids that were trapped within the growing crystals. These inclusions can provide valuable but sometimes ambiguous data on the temperature, pressure, and composition of these fluids, many of which are not available from any other source. They also provide “visual autoclaves” in which it is possible to watch, through the microscope, the actual phase changes take place as the inclusions are heated. This paper reviews the methods of study and the results obtained, mainly on inclusions formed from highly concentrated solutions, at temperatures ≥500°C. Many such fluids have formed as a result of immiscibility with silicate melt in igneous or high-temperature metamorphic rocks. These include fluids consisting of CO 2 , H 2 O, or hydrosaline melts that were <50% H 2 O. From the fluid inclusion evidence it is clear that a boiling, very hot, very saline fluid was present during the formation of most of the porphyry copper deposits in the world. Similarly, from the inclusion evidence it is clear that early (common) pegmatites formed from essentially silicate melts and that the late, rare-element-bearing and chamber-type pegmatites formed from a hydrosaline melt or a more dilute water solution. The evidence on whether this change in composition from early to late solutions was generally continuous or involved immiscibility is not as clear.

Physics and Chemistry of the Earth↗

USGS2017

Groundwater quality for 75 domestic wells in Lycoming County, Pennsylvania, 2014

Groundwater is a major source of drinking water in Lycoming County and adjacent counties in north-central and northeastern Pennsylvania, which are largely forested and rural and are currently undergoing development for hydrocarbon gases. Water-quality data are needed for assessing the natural characteristics of the groundwater resource and the potential effects from energy and mineral extraction, timber harvesting, agriculture, sewage and septic systems, and other human influences. This report, prepared in cooperation with Lycoming County, presents analytical data for groundwater samples from 75 domestic wells sampled throughout Lycoming County in June, July, and August 2014. The samples were collected using existing pumps and plumbing prior to any treatment and analyzed for physical and chemical characteristics, including nutrients, major ions, metals and trace elements, volatile organic compounds, gross-alpha particle and gross beta-particle activity, uranium, and dissolved gases, including methane and radon-222. Results indicate groundwater quality generally met most drinking-water standards, but that some samples exceeded primary or secondary maximum contaminant levels (MCLs) for arsenic, iron, manganese, total dissolved solids (TDS), chloride, pH, bacteria, or radon-222. Arsenic concentrations were higher than the MCL of 10 micrograms per liter (µg/L) in 9 of the 75 (12 percent) well-water samples, with concentrations as high as 23.6 μg/L; arsenic concentrations were higher than the health advisory level (HAL) of 2 μg/L in 23 samples (31 percent). Total iron concentrations exceeded the secondary maximum contaminant level (SMCL) of 300 μg/L in 20 of the 75 samples. Total manganese concentrations exceeded the SMCL of 50 μg/L in 20 samples and the HAL of 300 μg/L in 2 of those samples. Three samples had chloride concentrations that exceeded the SMCL of 250 milligrams per liter (mg/L); two of those samples exceeded the SMCL of 500 mg/L for TDS. The pH ranged from 5.3 to 9.15 and did not meet the SMCL range of 6.5 to 8.5 in 22 samples, with 17 samples having a pH less than 6.5 and 8 samples having pH greater than 8.5. Generally, the samples that had elevated TDS, chloride, or arsenic concentrations had high pH. Total coliform bacteria were detected in 39 of 75 samples (52 percent), with Escherichia coli detected in 10 of those 39 samples. Radon-222 activities ranged from non-detect to 7,420 picocuries per liter (pCi/L), with a median of 863 pCi/L, and exceeded the proposed drinking-water standard of 300 pCi/L in 50 (67 percent) of the 75 samples; radon-222 activities were higher than the alternative proposed standard of 4,000 pCi/L in 3 samples. Water from 15 of 75 (20 percent) wells had concentrations of methane greater than the reporting level of 0.01 mg/L; detectable methane concentrations ranged from 0.04 to 16.8 mg/L. Two samples had methane concentrations (13.1 and 16.8 mg/L) exceeding the action level of 7 mg/L. Low levels of ethane (up to 0.12 mg/L) were present in the five samples with the highest methane concentrations (near or above 1 mg/L) that were analyzed for hydrocarbon compounds and isotopic composition. The isotopic composition of methane in four of these groundwater samples, from the Catskill and Lock Haven Formations and the Hamilton Group, have sample carbon isotopic ratio delta values (carbon-13/carbon-12) ranging from –42.36 to –36.08 parts per thousand (‰) and hydrogen isotopic ratio delta values (deuterium/protium) ranging from –212.0 to –188.4 ‰, which are consistent with the isotopic compositions reported for mud-gas logging samples from these geologic units and a thermogenic source of the methane. However, the isotopic composition and ratios of methane to ethane in a fifth sample indicate the methane in that sample may be of microbial origin that subsequently underwent oxidation. The fifth sample had the highest concentration of methane, 16.8 mg/L, with an carbon isotopic ratio delta values of -50.59 ‰ and a hydrogen isotopic ratio delta values of -209.7 ‰. The six well-water samples with the highest methane concentrations also had among the highest pH values (8.25 to 9.15) and elevated concentrations of sodium, lithium, boron, fluoride, arsenic, and bromide. Relatively elevated concentrations of some other constituents, such as barium, strontium, and chloride, commonly were present in, but not limited to, those well-water samples with elevated methane. Three of the six groundwater samples with the highest methane concentrations had chloride/bromide ratios that indicate mixing with a small amount of brine (0.02 percent or less) similar in composition to those reported at undetermined depth below the freshwater aquifer and for gas and oil well brines in Pennsylvania. The sample with the highest methane concentration and most other samples with low methane concentrations (less than about 1 mg/L) have chloride/bromide ratios that indicate predominantly anthropogenic sources of chloride, such as road-deicing salt, septic systems, and (or) animal waste. Brines that are naturally present may originate from deeper parts of the aquifer system, while anthropogenic sources are more likely to affect shallow groundwater because they occur on or near the land-surface. The spatial distribution of groundwater compositions generally indicate that (1) uplands along the western border of Lycoming County usually have dilute, slightly acidic oxygenated, calcium-bicarbonate type waters; (2) intermediate altitudes or areas of carbonate bedrock usually have water of near neutral pH, with highest amounts of hardness (calcium and magnesium); (3) stream valleys, low elevations where groundwater may be discharging, and deep wells in uplands usually have water with pH values greater than 8 and highest arsenic, sodium, lithium, bromide concentrations. Geochemical modeling indicated that for samples with elevated pH, sodium, lithium, bromide, and alkalinity, the water chemistry could have resulted by dissolution of calcite (calcium carbonate) combined with cation-exchange and mixing with a small amount of brine. Through cation-exchange reactions between water and bedrock, which are equivalent to processes in a water softener, calcium ions released by calcite dissolution are exchanged for sodium ions on clay minerals. Thus, the assessment of groundwater quality in Lycoming County indicates groundwater is generally of good quality, but various parts of Lycoming County can have groundwater with low to moderate concentrations of methane and other constituents that appear in naturally present brine and produced waters from gas and oil wells at high concentrations."

Pennsylvania↗

USGS2008

Evolving magma storage conditions beneath Mount St. Helens inferred from chemical variations in melt inclusions from the 1980-1986 and current (2004-2006) eruptions

Major element, trace element, and volatile concentrations in 187 glassy melt inclusions and 25 groundmass glasses from the 1980-86 eruption of Mount St. Helens are presented, together with 103 analyses of touching FE-Ti oxide pairs from the same samples. These data are used to evaluate the temporal evolution of the magmatic plumbing system beneath the volcano during 1980-86 and so provide a framework in which to interpret analyses of melt inclusions from the current (2004-2006) eruption. Major and trace element concentrations of all melt inclusions lie at the high SiO 2 end of the data array defined by eruptive products of the late Quaternary age from Mount St. Helens. For several major and trace elements, the glasses define a trend that is oblique to the whole-rock trend, indicating that different mineral assemblages were responsible for the two trends. The whole-rock trend can be ascribed to differentiation of hydrous basaltic parents in a deep-seated magma reservoir, probably at depths great enough to stabilize garnet. In contrast, the glass trends were generated by closed-system crystallization of the phenocryst and microlite mineral assemblages at low pressures. The dissolved H 2 O content of the melt inclusions from 1980-86, as measured by the ion microprobe, ranges from 0 to 6.7 wt. percent, with the highest values obtained from the plinian phase of May 18, 1980. Water contents decrease with increasing SiO 2 , consistent with decompression-driven crystallization. Preliminary data for dissolved CO 2 in melt inclusions from the May 18 plinian phase from August 7, 1980, indicate that X H 2 O in a vapor phase was approximately constant at 0.80, irrespective of H 2 O content, suggestive of closed-system degassing with a high bubble fraction or gas streaming through the subvolcanic system. Temperature and f O 2 estimates for touching Fe-Ti oxides show evidence for heating during crystallization owing to release of latent heat. Consequently, magmas with the highest microlite crystallinities record the highest temperatures. Magmas also become progressively reduced during ascent and degassing, probably as a result of redox equilibria between exsolving S-bearing gases and magmas. The lowest temperature oxides have f O 2 ≈ NNO, similar to high-temperature fumarole gases from the volcano. The temperature and f O 2 of the magma tapped by the plinian phase of May 18, 1980, are 870-875°C and NNO+0.8, respectively. The dissolved volatile contents of the melt inclusions have been used to calculate sealing pressures; that is, the pressure at which chemical exchange between inclusion and matrix melt ceased. These are greatest for the May 18 plinian magma (120 to 320 MPa); lower pressures are recorded by samples of the preplinian cryptodome and by all post-May 18 magmas. Magma crystallinity, calculated from melt-inclusion Rb contents, is negatively correlated with sealing pressure, consistent with decompression crystallization. Elevated contents of Li in melt inclusions from the cryptodome and post-May 18 samples are consistent with transfer of Li in a magmatic vapor phase from deeper parts of the magma system to magma stored at shallower levels. The Li enrichment attains its maximum extent at ~150 MPa, which is ascribed to separation of a single vapor phase into H 2 O-rich gas and dense Li-rich brine at the top of the magma column. There are striking correlations between melt-inclusion chemistry and monitoring data for the 1980-86 eruption. Dissolved SO 2 contents of melt inclusions from any given event, multiplied by the mass of magma erupted during that event, correlate with the measured flux of SO 2 at the surface, suggesting that magma degassing and melt-inclusion sealing are closely related in time and space. Textural and chemical evidence indicates that melt inclusions became effectively sealed (physically or kinetically) shortly before eruption. Thus by converting pressure to depth using a density model and edifice-loading algorithm for the volcano, changing depths of magma extraction with time can be tracked and compared to the seismic record. The plinian eruption of May 18, 1980, involved magma stored 5-11 km below sea level; this is inferred to be the subvolcanic magma chamber. The preceding eruptions, including the May 18, 1980, blast, involved magma withdrawal from the cryptodome and conduit down to 5 km below sea level. Subsequent 1980 eruptions tapped magma down to depths of ≤10 km below sea level. Tapping of magma stored deeper than 2 km below sea level stopped abruptly at the end of 1980, coincident with the onset of extensive shallow seismicity and a change from explosive to effusive eruption style from 1981 to 1986. Overall, the 1980-86 eruption is consistent with the evisceration of a thin, vertically extensive body of magma extending from 5 to at least 11 km below sea level and connected to the surface by a thin conduit. In the absence of sustained high magma-supply rates from depth, decompression crystallization of magma ascending through the system leads eventually to plugging of the conduit. The current eruption of Mount St. Helens shares some similarities with the 1981-86 dome-building phase of the previous eruption, in that there is extensive shallow seismicity and extrusion of highly crystalline material in the form of a sequence of flows and spines. Melt inclusions from the current eruption have low H 2 O contents, consistent with magma extraction from shallow depths. Highly enriched Li in melt inclusions suggests that vapor transport of Li is a characteristic feature of Mount St. Helens. Melt inclusions from the current eruption have subtly different trace-element chemistry from all but one of the 1980-86 melt inclusions, with steeper rareearth-element (REE) patterns and low U, Th, and high-fieldstrength elements (HFSE), indicating addition of a new melt component to the magma system. It is anticipated that increasing involvement of the new melt component will be evident as the current eruption proceeds.

Washington↗

USGS2022

Potential effects of energy development on environmental resources of the Williston Basin in Montana, North Dakota, and South Dakota—Water resources

The Williston Basin has been a leading oil and gas producing area for more than 50 years. While oil production initially peaked within the Williston Basin in the mid-1980s, production rapidly increased in the mid-2000s, largely because of improved horizontal (directional) drilling and hydraulic fracturing methods. In 2012, energy development associated with the Bakken Formation was identified as a priority requiring collaboration toward improved timeliness of issuing permits for new wells combined with reasonable measures to maintain environmental quality. Shortly thereafter, the Bakken Federal Executive Group was created to address common challenges associated with energy development. The Bakken Federal Executive Group partner agencies identified a gap in current understanding of the cumulative environmental challenges attributed to energy development throughout the area, resulting in an effort to aggregate scientific data and identify additional research and information needs related to natural resources within areas of energy development in the Williston Basin. As part of this effort, water resources in the area (including groundwater; streams and rivers; and lakes, reservoirs, and wetlands) were characterized and described in terms of physical occurrence, flow characteristics, recharge, water quality, and water use. Similarly, waters produced during energy-development activities also were characterized even though these waters are not considered usable resources within the area. Groundwater resources were characterized by the major hydrogeologic units, or aquifers, identifying the units that supply most groundwater used for domestic, stock, agricultural, and industrial purposes. The groundwater characterization included other deeper hydrogeologic units in the Williston Basin that may be a useable source of water with treatment, have utility as a reservoir for reinjection of produced waters, or be a source of minerals and energy resources. A generalized groundwater budget and flow system identifying the sources of recharge (stream infiltration, precipitation, and movement [leakage] from other aquifers) and the general groundwater flow direction is included for each of the major hydrogeologic units. Rivers and streams within the Williston Basin with 10 or more years of continuous streamflow data were identified. For a subset of these sites, streamflow characteristics, including the monthly and annual mean flow, were generated to identify seasonal and interannual changes in streamflow and thus provide information on the drivers and reliability of streamflow at the seasonal or multiyear scale. Daily streamflow and annual extreme flows (peak and low flow) also were estimated for the subset of sites. The daily streamflow and annual extreme flow values provide information on short-term or extreme events that are relevant to infrastructure design and evaluating spills, leaks, or accidental discharges of water or petroleum products. Surface-water features (lakes, ponds, and wetlands) were classified using the Cowardin system and identified on the National Wetlands Inventory maps generated by the U.S. Fish and Wildlife Service. The spatial distribution of the surface-water features was analyzed by State, county, and specifically in comparison to the Prairie Pothole Region. The proximity of the surface-water features to energy development infrastructure (specifically oil or gas well pads) was evaluated. It was determined that, although oil or gas wells are often near a surface-water feature, most surface-water features do not have wells nearby, with the exception of wells in the Prairie Pothole Region. Water-quality data were aggregated from two data sources: (1) the Water-Quality Portal, sponsored by the U.S. Geological Survey (USGS), U.S. Environmental Protection Agency (EPA), and National Water Quality Monitoring Council; and (2) a data compilation completed as part of the USGS National Water-Quality Assessment project. The Water-Quality Portal integrates publicly available water-quality data from databases maintained by the USGS, EPA, and U.S. Department of Agriculture, including water-quality data from Tribal, State, and local databases. Water-quality data for 15 commonly measured water-quality constituents were aggregated for groundwater, rivers and streams, and lakes and reservoirs. For each aggregated dataset (groundwater, rivers and streams, and lakes and reservoirs), analyses of the water-quality data included summary statistics, maps of spatial distribution of constituent values, boxplots of constituent values by timeframe or hydrogeologic unit, spatial comparisons of site locations and constituent values to petroleum well density, and comparisons of the constituent values measured to EPA drinking-water standards/guidelines. Produced water includes all fluids brought to the surface along with the targeted hydrocarbons as part of the oil and gas exploration and extraction processes. These fluids may include formation water (waters that co-exist with rock/oil/gas), hydraulic fracturing fluids, and other combinations of water and chemicals used during oil and gas well drilling, development, treatments, recompletions, and workovers. Produced water datasets were aggregated from two sources: the USGS National Produced Waters Geochemical database (ver. 2.1) and a series of projects focused specifically on sampling produced water in the Williston Basin from 2010 to 2014. The National Produced Waters Geochemical database was useful for a general understanding of produced-water chemistry. Produced waters are characterized by extreme salinity and contain elevated concentrations of other constituents (including arsenic, barium, cadmium, lead, zinc, radium-226/radium-228, and ammonium) that could negatively affect water and aquatic resources if released. Produced waters also have a generally unique chemical (isotopic) signature that may be useful in tracking water from different geologic units; for example, the oxygen/deuterium and strontium ratio values measured in brine waters from the Bakken Formation are distinct from brines collected from other geologic units in the Williston Basin. Water-use information related to energy production in the area also was aggregated and summarized. The summary of water use is not limited to oil and gas production but includes water used to produce all types of energy resources in the Williston Basin, including coal/lignite, thermoelectric power, oil and gas, hydropower, biomass and biofuels, wind, geothermal, and solar. Each State has its own methods for regulating and reporting water usage within its jurisdiction. These methods can introduce problems when examining water use from sources, such as the Missouri River or Fox Hills aquifer, that are shared across political boundaries. Without the one-to-one match for usage types and amounts used from a water source, it is difficult to develop a comprehensive water budget for the water source being evaluated. A large amount of freshwater is required to prepare a well for oil and gas well production; in some cases, 3 to 7 million gallons of water are needed per well. The EPA estimates that hydraulic fracturing in the Williston Basin uses between 70 to 140 billion gallons per year. Water also is used for myriad other purposes related to ancillary oil and gas extraction. In addition to water used for immediate energy development, the expanded human workforce migrating into the area and other support staff who have moved into the area during the development also use water. Research and information needs were identified that could be relevant in the evaluation of the effects of energy development on water resources. Information needs related to the evaluation of groundwater resources include the following: improved potentiometric-surface maps for glacial units; availability of a uniform stream network digital geographic coverage that spans the international boundary with Canada; enhanced surface-water use information with regards to the gain and loss of streamflow to shallow groundwater, which would increase understanding groundwater and surface-water interactions; and expanded geophysical assessments. Gaps in the availability of streamflow data include the lack of information on ice-jam flooding despite potential for effects to infrastructure (pipelines, roads, and facilities) and an understanding of the cumulative effects of largely undocumented stock and diversion dams. Although this study resulted in the aggregation of a large quantity of water-quality data, the availability of consistently collected, systematically processed and reported data over large parts of the Williston Basin is sparse. Few samples have been analyzed for constituents that may indicate the effect of energy development on water resources. Constituents that could be considered include boron, chloride, bromide, iodine, fluoride, manganese, lithium, radium, strontium isotopes, volatile organic compounds, and isotopes of inorganic ions (such as hydrogen and carbon). Collaboration between Tribal, Federal, State, and local entities to identify a common study design, common monitoring constituents, and consistent sampling locations would generate datasets with broad utility and would likely result in overall cost savings for monitoring over time. Similarly, there is a need for standardized sample collection, processing, laboratory analytical methods, and the collection of ancillary data for produced waters sampling. Additional characterization of the range of chemical, microbial, and isotopic compositions and quantities of “end-member” produced waters, and the collection of time-series datasets to document the changes in produced waters during and after well development also were needs identified during this study. Water-use estimates would be improved through the implementation of comprehensive studies of water use from groundwater and surface-water sources using consistent methodologies across the Williston Basin. The submission of chemical and water data related to hydraulic fracturing collected by the oil and gas industry would add to the quantity of available data. Consistent implementation of regulations and monitoring controls across political boundaries (State, county, and international) would further improve the consistency of data available for the estimates of water use.

Montana, North Dakota, South Dakota↗