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At least 73 records · Page 4Linked to original sources

Constraints on the Pleistocene chronology of sediments from the Lomonosov Ridge

Despite its importance in the global climate system, age-calibrated marine geologic records reflecting the evolultion of glacial cycles through the Pleistocene are largely absent from the central Arctic Ocean. This is especially true for sediments older than 200 ka. Three sites cored during the Integrated Ocean Drilling Program's Expedition 302, the Arctic Coring Expedition (ACEX), provide a 27 m continuous sedimentary section from the Lomonosov Ridge in the central Arctic Ocean. Two key biostratigraphic datums and constraints from the magnetic inclination data are used to anchor the chronology of these sediments back to the base of the Cobb Mountain subchron (1215 ka). Beyond 1215 ka, two best fitting geomagnetic models are used to investigate the nature of cyclostratigraphic change. Within this chronology we show that bulk and mineral magnetic properties of the sediments vary on predicted Milankovitch frequencies. These cyclic variations record "glacial" and "interglacial" modes of sediment deposition on the Lomonosov Ridge as evident in studies of ice-rafted debris and stable isotopic and faunal assemblages for the last two glacial cycles and were used to tune the age model. Potential errors, which largely arise from uncertainties in the nature of downhole paleomagnetic variability, and the choice of a tuning target are handled by defining an error envelope that is based on the best fitting cyclostratigraphic and geomagnetic solutions. Copyright 2008 by the American Geophysical Union.

Paleoceanography

Simulation of less‐mobile porosity dynamics in contrasting sediment water interface porous media

Considering heterogeneity in porous media pore size and connectivity is essential to predicting reactive solute transport across interfaces. However, exchange with less‐mobile porosity is rarely considered in surface water/groundwater recharge studies. Previous research indicates that a combination of pore‐fluid sampling and geoelectrical measurements can be used to quantify less‐mobile porosity exchange dynamics using the time‐varying relation between fluid and bulk electrical conductivity. For this study, we use macro‐scale (10 s of cm) advection–dispersion solute transport models linked with electrical conduction in COMSOL Multiphysics to explore less‐mobile porosity dynamics in two different types of observed sediment water interface porous media. Modeled sediment textures contrast from strongly layered streambed deposits to poorly sorted lakebed sands and cobbles. During simulated ionic tracer perturbations, a lag between fluid and bulk electrical conductivity, and the resultant hysteresis, is observed for all simulations indicating differential loading of pore spaces with tracer. Less‐mobile exchange parameters are determined graphically from these tracer time series data without the need for inverse numerical model simulation. In both sediment types, effective less‐mobile porosity exchange parameters are variable in response to changes in flow direction and fluid flux. These observed flow‐dependent effects directly impact local less‐mobile residence times and associated contact time for biogeochemical reaction. The simulations indicate that for the sediment textures explored here, less‐mobile porosity exchange is dominated by variable rates of advection through the domain, rather than diffusion of solute, for typical low‐to‐moderate rate (approximately 3–40 cm/day) hyporheic fluid fluxes. Overall, our model‐based results show that less‐mobile porosity may be expected in a range of natural hyporheic sediments and that changes in flowpath orientation and magnitude will impact less‐mobile exchange parameters. These temporal dynamics can be assessed with the geoelectrical experimental tracer method applied at laboratory and field scales.

Hydrological Processes

Weathering rates as a function of flow through an alpine soil

The effect of flow on release rates of solutes from soil in a 39-m2 alpine catchment in the Colorado Rockies was measured during the summers of 1990-1994. Flow rates through the soil were varied by augmenting natural rainfall with deionized irrigation water. Daily water inputs averaged between 96 and 216 1 day-1 during the five field seasons, and mean discharge (inputs minus evapotranspiration) varied from 35 to 175 1 day-1. Volume-weighted mean concentrations of base cations and silica decreased only moderately in response to the increased water inputs. Input fluxes of solutes in precipitation were similar in each of the study seasons, but output fluxes of base cations and silica in surface outflow increased substantially in conjunction with the average water input rate for the season. Weathering rates calculated from the chemical fluxes increased substantially in response to increases in water input rates. The increases appear to be largely attributable to enhanced transport of solutes from the soil matrix under high flow conditions. At high flow, physical flushing of micropores presumably occurs to a greater extent than during low-flow periods because of greater soil wetness and higher hydrologic head. Increased flushing would also cause an increased rate of diffusion of solutes from microcracks in mineral surfaces and constricted pore spaces in response to an increased concentration gradient between those regions and adjacent areas in the soil matrix. Another consequence of the increased flushing that occurs during periods of high flow is that concentrations throughout the soil matrix tend to be lower, which might increase chemical weathering rates of some silicate minerals such as microcline, which are relatively close to saturation. Decreased Si concentrations under high-flow conditions appear to promote dissolution of amorphous aluminosilicates or desorption of Si from mineral surfaces, buffering Si concentrations in the soil solutions. Thus, both physical transport of solutes and subsequent chemical effects appear to be responsible for the positive relation observed between fluxes of weathering products and water input rates.

Chemical Geology

Drawdown and stream depletion produced by pumping in the vicinity of a partially penetrating stream

Commonly used analytical approaches for estimation of pumping-induced drawdown and stream depletion are based on a series of idealistic assumptions about the stream-aquifer system. A new solution has been developed for estimation of drawdown and stream depletion under conditions that are more representative of those in natural systems (finite width stream of shallow penetration adjoining an aquifer of limited lateral extent). This solution shows that the conventional assumption of a fully penetrating stream will lead to a significant overestimation of stream depletion (> 100 %) in many practical applications. The degree of overestimation will depend on the value of the stream leakance parameter and the distance from the pumping well to the stream. Although leakance will increase with stream width, a very wide stream will not necessarily be well represented by a model of a fully penetrating stream. The impact of lateral boundaries depends upon the distance from the pumping well to the stream and the stream leakance parameter. In most cases, aquifer width must be on the order of hundreds of stream widths before the assumption of a laterally infinite aquifer is appropriate for stream-depletion calculations. An important assumption underlying this solution is that stream-channel penetration is negligible relative to aquifer thickness. However, an approximate extension to the case of nonnegligible penetration provides reasonable results for the range of relative penetrations found in most natural systems (up to 85%). Since this solution allows consideration of a much wider range of conditions than existing analytical approaches, it could prove to be a valuable new tool for water management design and water rights adjudication purposes.

Ground Water

Salinity and total dissolved solids measurements for natural waters: An overview and a new salinity method based on specific conductance and water type

The total concentration of dissolved constituents in water is routinely quantified by measurements of salinity or total dissolved solids (TDS). However, salinity and TDS are operationally defined by their analytical methods and are not equivalent for most waters. Furthermore, multiple methods are available to determine salinity and TDS, and these methods have inherent differences. TDS is defined as the mass of anhydrous residue remaining in a sample vessel after evaporation and subsequent oven drying at a defined temperature. Salinity is a measure of the mass of dissolved salts in a given mass of solution. In addition, there are approaches that quantify the total solute (TS) concentration, including gases. The purpose of this study is to develop a proxy method using specific conductance and major-ion water type to reliably predict salinity, TDS, and/or TS. Thus, we compared several methods to calculate salinity, TDS, and TS for 6391 surface water samples and conclude the following: TDS measurements are best suited for studies of anhydrous residue (e.g., evaporites); salinity determined by summing the speciated ion concentrations, termed S ∑spec , is the most comprehensive method to represent the concentration of dissolved constituents in natural waters; and TS determinations are useful if dissolved CO 2 and other gases are of interest. Thus, we utilized S ∑spec to compare differences between the various salinity, TDS, and TS methods, and to develop a new proxy method to predict salinity based on specific conductance (SC) and major ion water type, termed S SC_WT . For the surface waters used in this study, the median difference between TDS and S ∑Spec was between −19% and −24%, depending on the method. The median difference between S SC_WT and S ∑Spec was −2.4% for the samples in this study. The S SC_WT approach is cost effective, rapid, and capable of providing reliable real-time salinity determinations at surface water sites where SC data are available and water type is known.

Applied Geochemistry

Reactive solute-transport simulation of pre-mining metal concentrations in mine-impacted catchments: Redwell Basin, Colorado, USA

With the increased importance of water resources in the western United States and many areas worldwide, the remediation of impacts from historical mining becomes ever more important. A possible process of making decisions about remediation for a catchment might include identification of principal sources of metals in the catchment, classification of the sources as natural or anthropogenic, and simulations to evaluate different options for removal of anthropogenic sources. The application of this process is based on understanding the pre-mining conditions in the catchment, so that remediation goals appropriately correct for the impacts of mining. A field experiment in Redwell Basin, Colorado, provided a setting to demonstrate this process and to evaluate pre-mining concentrations through reactive solute-transport modeling. The field experiment provided spatially detailed stream and inflow samples that were the basis for model calibration. Only two inflows along the study reach were affected by mining or mine exploration. To simulate pre-mining conditions, these inflows were removed from the model calibration; the result was a simulation of the stream with all the non-mining inputs. At a point downstream from the two mining inflows, the simulated pre-mining pH would have been 5.1, up from the measured 3.8. At the higher pH, the streambed likely would have been coated with Al precipitate. Simulated pre-mining Zn and Cu would have been 1300 µg/L and 18 µg/L, lower than the measured concentrations of 3340 and 93 µg/L. Despite these changes, the pre-mining conditions would not have met aquatic-life standards.

Colorado

Structural stability of coprecipitated natural organic matter and ferric iron under reducing conditions

The objective was to assess the interaction of Fe coprecipitated with dissolved organic matter (DOM) and its effect on Fe (hydr)oxide crystallinity and DOM retention under abiotic reducing conditions. A Fe-based coagulant was reacted with DOM from an agricultural drain and the resulting precipitate (floc) was exposed to S(-II) and Fe(II). Solution concentrations of Fe(II/III) and DOM were monitored, floc crystallinity was determined using X-ray diffraction, and the composition and distribution of functional groups were assessed using scanning transmission X-ray microscopy (STXM) and near edge X-ray absorption fine structure (NEXAFS) spectroscopy. Results indicate coprecipitation of Fe(III) with DOM forms a non-crystalline floc that withstands crystallization regardless of change in pH, Fe:DOM ratio and type of reductant added. There was no evidence that exposure to reducing conditions led to release of DOM from the floc, indicating that coprecipitation with complex natural DOM in aquatic environments may stabilize Fe (hydr)oxides against crystallization upon reaction with reduced species and lead to long term sequestration of the DOM. STXM analysis identified spatially distinct regions with remarkable functional group purity, contrary to the model of DOM as a relatively uniform complex polymer lacking identifiable organic compounds. Polysaccharide-like OM was strongly and directly correlated with the presence of Fe but showed different Fe binding strength depending on the presence of carboxylic acid functional groups, whereas amide and aromatic functional groups were inversely correlated with Fe content.

Organic Geochemistry

On the air-scattering of gamma rays from thick uranium sources

Semiquantative interpretation of data from airborne radioactivity surveying requires detailed knowledge of air-scattered gamma-ray intensity at considerable air distances from natural, thick uranium sources. Based on the concept of an elementary source of infinite thickness rather than on the classical point source, semi-empirical expressions, are developed for measured gamma-radiation intensities from . the two extreme types of natural, thick uranium sources, the elementary (point) and t-he broad (semi-infinite) source. These expressions agree both with extensive experimental data and with the form and structure of theory. Theoretical computations based on published solutions of the Boltzmann equation for ga.m.ma-ray transport in one medium agree closely with experimental measurements. The calculated value for primary, scattered, and total intensities from thick uranium sources show that at considerable air distances the scattered intensities are more than half of the total intensities for energies above 0.4 Mev and become considerably more than half as the lower limit of detector energy response is decreased below 0.4 Mev.

Trace Elements Investigations

Model coupling intraparticle diffusion/sorption, nonlinear sorption, and biodegradation processes

Diffusion, sorption and biodegradation are key processes impacting the efficiency of natural attenuation. While each process has been studied individually, limited information exists on the kinetic coupling of these processes. In this paper, a model is presented that couples nonlinear and nonequilibrium sorption (intraparticle diffusion) with biodegradation kinetics. Initially, these processes are studied independently (i.e., intraparticle diffusion, nonlinear sorption and biodegradation), with appropriate parameters determined from these independent studies. Then, the coupled processes are studied, with an initial data set used to determine biodegradation constants that were subsequently used to successfully predict the behavior of a second data set. The validated model is then used to conduct a sensitivity analysis, which reveals conditions where biodegradation becomes desorption rate-limited. If the chemical is not pre-equilibrated with the soil prior to the onset of biodegradation, then fast sorption will reduce aqueous concentrations and thus biodegradation rates. Another sensitivity analysis demonstrates the importance of including nonlinear sorption in a coupled diffusion/sorption and biodegradation model. While predictions based on linear sorption isotherms agree well with solution concentrations, for the conditions evaluated this approach overestimates the percentage of contaminant biodegraded by as much as 50%. This research demonstrates that nonlinear sorption should be coupled with diffusion/sorption and biodegradation models in order to accurately predict bioremediation and natural attenuation processes. To our knowledge this study is unique in studying nonlinear sorption coupled with intraparticle diffusion and biodegradation kinetics with natural media.

Journal of Contaminant Hydrology

Surface complexation and precipitate geometry for aqueous Zn(II) sorption on ferrihydrite I: X-ray absorption extended fine structure spectroscopy analysis

“Two-line” ferrihydrite samples precipitated and then exposed to a range of aqueous Zn solutions (10 −5 to 10 −3 M), and also coprecipitated in similar Zn solutions (pH 6.5), have been examined by Zn and Fe K-edge X-ray absorption spectroscopy. Typical Zn complexes on the surface have Zn-O distances of 1.97(.02) Å and coordination numbers of about 4.0(0.5), consistent with tetrahedral oxygen coordination. This contrasts with Zn-O distances of 2.11(.02) Å and coordination numbers of 6 to 7 in the aqueous Zn solutions used in sample preparation. X-ray absorption extended fine structure spectroscopy (EXAFS) fits to the second shell of cation neighbors indicate as many as 4 Zn-Fe neighbors at 3.44(.04) Å in coprecipitated samples, and about two Zn-Fe neighbors at the same distance in adsorptionsamples. In both sets of samples, the fitted coordination number of second shell cations decreases as sorption density increases, indicating changes in the number and type of available complexing sites or the onset of competitive precipitation processes. Comparison of our results with the possible geometries for surface complexes and precipitates suggests that the Zn sorption complexes are inner sphere and at lowest adsorption densities are bidentate, sharing apical oxygens with adjacent edge-sharing Fe(O,OH) 6 octahedra. Coprecipitation samples have complexes with similar geometry, but these are polydentate, sharing apices with more than two adjacent edge-sharing Fe(O,OH) 6 polyhedra. The results are inconsistent with Zn entering the ferrihydrite structure (i.e., solid solution formation) or formation of other Zn-Fe precipitates. The fitted Zn-Fe coordination numbers drop with increasing Zn density with a minimum of about 0.8(.2) at Zn/(Zn + Fe) of 0.08 or more. This change appears to be attributable to the onset of precipitation of zinc hydroxide polymers with mainly tetrahedral Zn coordination. At the highest loadings studied, the nature of the complexes changes further, and a second type of precipitate forms. This has a structure based on a brucite layer topology, with mainly octahedral Zn coordination. Amorphous zinc hydroxide samples prepared for comparison had a closely similar local structure. Analysis of the Fe K-edge EXAFS is consistent with surface complexation reactions and surface precipitation at high Zn loadings with little or no Fe-Zn solid solution formation. The formation of Zn-containing precipitates at solution conditions two or more orders of magnitude below their solubility limit is compared with other sorption and spectroscopic studies that describe similar behavior.

Geochimica et Cosmochimica Acta

Joint analysis of geodetic and earthquake fault-plane solution data to constrain magmatic sources: A case study from Kīlauea Volcano

A joint analysis of geodetic and seismic datasets from Kīlauea Volcano during a period of magmatic unrest in 2006 demonstrates the effectiveness of this combination for testing and constraining models of magma dynamics for a complex, multi-source system. At the end of 2003, Kīlauea's summit began a four-year-long period of inflation due to a surge in magma supply to the volcano. In 2006, for the first time since 1982, Kīlauea's Southwest Rift Zone (SWRZ) also experienced inflation. To investigate the characteristics of active magma sources and the nature of their interactions with faults in the SWRZ during 2006, we integrate, through Coulomb stress modeling, contemporary geodetic data from InSAR and GPS with a new catalogue of double-couple fault-plane solutions for volcano-tectonic earthquakes. We define two periods of inflation during 2006 based on the rate of deformation measured in daily GPS data, spanning February to 15 March 2006 (Period 1) and 16 March to 30 September 2006 (Period 2). InSAR data for these two periods are inverted to determine the position, change in size, and shape of inflation sources in each period. Our new models are consistent with microseismic activity from each period. They suggest that, during Period 1, deformation in the SWRZ can be explained by pressurization of magma in a spherical reservoir beneath the south caldera, and that, during Period 2, magma was also aseismically intruded farther to the southwest into the SWRZ along a sub-horizontal plane. Our Coulomb stress analysis shows that the microseismicity recorded in the SWRZ is induced by overpressurization of the south caldera reservoir, and not by magma intrusion into the SWRZ. This study highlights the importance of a joint analysis of independent geophysical datasets to fully constrain the nature of magma accumulation.

Hawaii

Results of mineral, chemical, and sulfate isotopic analyses of water, soil, rocks, and soil extracts from the Pariette Draw Watershed, Uinta Basin, Utah

In 2010, Utah Department of Environmental Quality (DEQ) Division of Water Quality (UDWQ, 2010) determined that water quality in Pariette Draw was in violation of Federal and State water quality criteria for total dissolved solids (TDS), selenium (Se), and boron (B). The measure of total dissolved solids is the sum of all the major ion concentrations in solution and in this case, the dominant ions are sodium (Na) and sulfate (SO4), which can form salts like thenardite (Na2SO4) and mirabilite (Na2SO4⋅H2O). The Utah Department of Environmental Quality (2010) classified the contamination as natural background and from nonpoint sources related to regional lithology and irrigation practices. Although the daily loads of the constituents of concern and water chemistry have been characterized for parts of the watershed, little is known about the controls that bedrock and soil mineralogy have on salt, Se, and B storage and the water-rock interactions that influence the mobility of these components in ground and surface waters. Studies in the Uncompahgre River watershed in Colorado by Tuttle and others (2014a, 2014b) show that salt derived from weathering of shale in a semiarid climate is stored in a variety of minerals that contribute solutes to runoff and surface waters based on a complex set of conditions such as water availability, geomorphic position (for example, topography controls the depth of salt accumulation in soils), water-table fluctuations, redox conditions, mineral dissolution kinetics, ion-exchange reactions, and secondary mineral formation. Elements like Se and B commonly reside in soluble salt phases, so knowledge of the behavior of salt minerals also sheds light on the behavior of associated contaminants. The goal of this study was to establish a process-based understanding of salt, Se, and B behavior to address whether these contaminants can be better managed, or if uncontrollable natural processes will overwhelm any attempts to bring Pariette Draw into compliance with respect to recently established total maximum daily limits (TMDLs). We collected data to refine our knowledge about the role of rock weathering and soil formation in the transport and storage of salt in the watershed and to show how salt is cycled under irrigated and natural conditions. Our approach was to sample rock, soils, and sediment on irrigated and natural terrain for mineralogical analysis to determine the residence of salt and associated Se and B, classify minerals as primary (related to rock formation) or secondary weathering products, and characterize mineral dissolution kinetics. Mineral and chemical analyses and selective extractions of rocks and soils provide useful information in understanding solute movement and mineral dissolution/ formation. The resulting data are critical in determining residence of salt, Se, and B in weathered rock and soil and understanding the mobility during water-rock-soil interactions. This report summarizes our methods for sample and data collection and tabulates the mineral, chemical, and isotopic data collected.

Utah

Geochemical characterization of shallow ground water in the Eutaw aquifer, Montgomery, Alabama

Ground water samples were collected from 30 wells located in, or directly down gradient from, recharge areas of the Eutaw aquifer in Montgomery, Alabama. The major ion content of the water evolves from calcium-sodium-chloride- dominated type in the recharge area to calcium-bicarbonate-dominated type in the confined portion of the aquifer. Ground water in the recharge area was undersaturated with respect to aluminosilicate and carbonate minerals. Ground water in the confined portion of the aquifer was at equilibrium levels for calcite and potassium feldspar. Dissolved oxygen and nitrite-plus-nitrate concentrations decreased as ground water age increased; pH, iron, and sulfate concentrations increased as ground water age increased. Aluminum, copper, and zinc concentrations decreased as ground water age and pH increased. These relations indicate that nitrate, aluminum, copper, and zinc are removed from solution as water moves from recharge areas to the confined areas of the Eutaw aquifer. The natural evolution of ground water quality, which typically increases the pH and decreases the dissolved oxygen content, may be an important limiting factor to the migration of nitrogen based compounds and metals.

Alabama

Thermal decarboxylation of acetic acid: Implications for origin of natural gas

Laboratory experiments on the thermal decarboxylation of solutions of acetic acid at 200°C and 300°C were carried out in hydrothermal equipment allowing for on-line sampling of both the gas and liquid phases for chemical and stable-carbon-isotope analyses. The solutions had ambient pH values between 2.5 and 7.1; pH values and the concentrations of the various acetate species at the conditions of the experiments were computed using a chemical model. Results show that the concentrations of acetic acid, and not total acetate in solution, control the reaction rates which follow a first order equation based on decreasing concentrations of acetic acid with time. The decarboxylation rates at 200°C (1.81 × 10 −8 per second) and 300°C (8.17 × 10 −8 per second) and the extrapolated rates at lower temperatures are relatively high. The activation energy of decarboxylation is only 8.1 kcal/mole. These high decarboxylation rates, together with the distribution of short-chained aliphatic acid anions in formation waters, support the hypothesis that acid anions are precursors for an important portion of natural gas. Results of the δ 13 C values of CO 2 , CH 4 , and total acetate show a reasonably constant fractionation factor of about 20 permil between CO 2 and CH 4 at 300°C. The δ 13 C values of CO 2 and CH 4 are initially low and become higher as decarboxylation increases.

Geochimica et Cosmochimica Acta

Removal of inorganic mercury and methylmercury from surface waters following coagulation of dissolved organic matter with metal-based salts

The presence of inorganic mercury (IHg) and methylmercury (MeHg) in surface waters is a health concern worldwide. This study assessed the removal potential use of metal-based coagulants as a means to remove both dissolved IHg and MeHg from natural waters and provides information regarding the importance of Hg associations with the dissolved organic matter (DOM) fraction and metal hydroxides. Previous research indicated coagulants were not effective at removing Hg from solution; however these studies used high concentrations of Hg and did not reflect naturally occurring concentrations of Hg. In this study, water collected from an agricultural drain in the Sacramento-San Joaquin Delta was filtered to isolate the dissolved organic matter (DOM) fraction. The DOM was then treated with a range of coagulant doses to determine the efficacy of removing all forms of Hg from solution. Three industrial-grade coagulants were tested: ferric chloride, ferric sulfate, and polyaluminum chloride. Coagulation removed up to 85% of DOM from solution. In the absence of DOM, all three coagulants released IHg into solution, however in the presence of DOM the coagulants removed up to 97% of IHg and 80% of MeHg. Results suggest that the removal of Hg is mediated by DOM-coagulant interactions. There was a preferential association of IHg with the more aromatic, higher molecular weight fraction of DOM but no such relationship was found for MeHg. This study offers new fundamental insights regarding large-scale removal of Hg at environmentally relevant regarding large-scale removal of Hg at environmentally relevant concentrations.

Science of the Total Environment

I. Thermal evolution of Ganymede and implications for surface features. II. Magnetohydrodynamic constraints on deep zonal flow in the giant planets. III. A fast finite-element algorithm for two-dimensional photoclinometry

The work is divided into three independent papers: PAPER I: Thermal evolution models are presented for Ganymede, assuming a mostly differentiated initial state of a water ocean overlying a rock layer. The only heat sources are assumed to be primordial heat (provided by accretion) and the long-lived radiogenic heat sources in the rock component. As Ganymede cools, the ocean thins, and two ice layers develop, one above composed of ice I, and the other below composed of high-pressure polymorphs of ice. Subsolidus convection proceeds separately in each ice layer, its transport of heat calculated using a simple parameterized convection scheme and the most recent data on ice rheology. The model requires that the average entropy of the deep ice layer exceed that of the ice I layer. If the residual ocean separating these layers becomes thin enough, then a Rayleigh-Taylor-like ("diapiric") instability may ensue, driven by the greater entropy of the deeper ice and merging the two ice mantles into a single convective layer. This instability is not predicted by linear analysis but occurs for plausible finite amplitude perturbations associated with large Rayleigh number convection. The resulting warm ice diapirs may lead to a dramatic "heat pulse" at the surface and to fracturing of the lithosphere, and may be directly or indirectly responsible for resurfacing and grooved terrain formation on Ganymede. The timing of this event depends rather sensitively on poorly known rheological parameters but could be consistent with chronologies deduced from estimated cratering rates. Irrespective of the occurrence or importance of the heat pulse, we find that lithospheric fracturing requires rapid stress loading (on a timescale ≾ 10 4 ) years). Such a timescale can be realized by warm ice diapirism, but not directly by gradual global expansion. In the absence of any quantitative and self-consistent model for the resurfacing of Ganymede by liquid water, we favor resurfacing by warm ice flows,which we demonstrate to be physically possible, a plausible consequence of our models, compatible with existing observations, and a hypothesis testable by Galileo. We discuss core formation as an alternative driver for resurfacing, and conclude that it is less attractive. We also consider anew the puzzle of why Callisto differs so greatly from Ganymede, offering several possible explanations. The models presented do not provide a compelling explanation for all aspects of Ganymedean geological evolution, since we have identified several potential problems, most notably the apparently extended period of grooved terrain formation (several hundred million years), which is difficult to reconcile with the heat pulse phenomenon. PAPER II: The observed zonal flows of the giant planets will, if they penetrate below the visible atmosphere, interact significantly with the planetary magnetic field outside the metalized core. The appropriate measure of this interaction is the Chandrasekhar number Q = ( H 2 )/(4πρνα 2 λ) (where H = radial component of the magnetic field, ν = eddy viscosity, λ = magnetic diffusivity, α -1 = lengthscale on which λ varies); at depths where Q ≳ 1 the velocity will be forced to oscillate on a small lengthscale or decay to zero. We estimate the conductivity due to semiconduction in H 2 (Jupiter, Saturn) and ionization in H 2 O (Uranus, Neptune) as a function of depth; the value λ ≃ 10 10 cm 2 s -1 needed for Q = 1 is readily obtained well outside the metallic core (where λ ≃ 10 2 cm 2 s -1 ). These assertions are quantified by a simple model of the equatorial zonal jet in which the flow is assumed uniform on cylinders concentric with the spin axis, and the viscous and magnetic torques on each cylinder are balanced. We solve this "Taylor constraint" simultaneously with the dynamo equation to obtain the velocity and magnetic field in the equatorial plane. With this model we reproduce the widely differing jet widths of Jupiter and Saturn (though not the flow at very high or low latitudes) using ν = 2500 cm 2 s -1 , consistent with the requirement that viscous dissipation not exceed the specific luminosity. A model Uranian jet consistent with the limited Voyager data can also be constructed, with appropriately smaller ν, but only if one assumes a two-layer interior. We tentatively predict a wide Neptunian jet. For Saturn (but not Jupiter or Uranus) the model has a large magnetic Reynolds number where Q = 1 and hence exhibits substantial axisymmetrization of the field in the equatorial plane . This effect may or may not persist at higher latitudes. The one-dimensional model presented is only a first step. Variation of the velocity and magnetic field parallel to the spin axis must be modeled in order to answer several important questions, including: 1) What is the behavior of flows at high latitudes, whose Taylor cylinders are interrupted by the region with Q ≳ 1? 2) To what extent is differential rotation in the envelope responsible for the spin-axisymmetry of Saturn's magnetic field? PAPER III: It is shown that the problem of two-dimensional photoclinometry (PC) -- the reconstruction of a surface z ( x , y ) from a brightness image B( x , y ) -- may be formulated in a natural way in terms of finite elements. The resulting system of equations is underdetermined as a consequence of the lack of boundary conditions for z , but a unique solution may be chosen by minimizing a function S expressing the "roughness" of the surface. An efficient PC algorithm based on this formulation is presented, requiring ~ 10.66 (four-byte) memory locations and ~10 4 floating multiplications/additions per pixel, and incorporating: 1) Minimization of the roughness by the penalty method, which yields the smallest set of equations. 2) Iterative solution of the nonlinear equations by Newton's method. 3) Solution of the linearized equations by an inner iterative cycle of successive over-relaxation, which takes advantage of the extreme sparseness of the system. 4) Multigridding, in which the solutions to the smaller problems obtained by reducing the resolution are used recursively to greatly speed convergence at the higher resolutions, and 5) A rapid noniterative initial estimate of z obtained by exploiting the special symmetry of the equations obtained in the first linearization. The algorithm is extensively demonstrated on 200 by 200 pixel synthetic "images" generated from digital topographic data for northern Utah over a range of phase angles. Rms error in the solution is ~ 22 m, out of ~ 660 m total relief. The error is dominated by "stripes" with the same azimuth as the light source, resulting from use of the roughness criterion in lieu of boundary conditions; the rms error along profiles parallel to the stripes is only ~ 2-8 m, depending on the phase angle. Satisfactory solutions are obtained even in the presence of quantization error, noise, and moderate blur in the image. Applications of the PC algorithm to both remote sensing and photomicrography are sketched; a photoclinometric map of a low-relief Precambrian era fossil is presented as an example of the latter. Prospects for dealing with photometrically inhomogeneous surfaces, and an extension of the method to the analysis of side-looking radar data ("radarclinometry") are also discussed.

Thesis

SToRM: A numerical model for environmental surface flows

SToRM (System for Transport and River Modeling) is a numerical model developed to simulate free surface flows in complex environmental domains. It is based on the depth-averaged St. Venant equations, which are discretized using unstructured upwind finite volume methods, and contains both steady and unsteady solution techniques. This article provides a brief description of the numerical approach selected to discretize the governing equations in space and time, including important aspects of solving natural environmental flows, such as the wetting and drying algorithm. The presentation is illustrated with several application examples, covering both laboratory and natural river flow cases, which show the model’s ability to solve complex flow phenomena.

Conference Paper

Marshes are the new beaches: Integrating sediment transport into restoration planning

Recent coastal storms and associated recovery efforts have led to increased investment in nature-based coastal protection, including restoration of salt marshes and construction of living shorelines. In particular, many of these efforts focus on increasing vertical elevation through sediment nourishment, where sediment is removed from the tidal channel and placed on the marsh plain, or preventing lateral erosion through shoreline protection. In the USA alone, millions of dollars have been allocated or spent on these coastal protection solutions over the last few decades because of their perceived sustainability and ecologically positive co-benefits including habitat provision and carbon sequestration. These projects would benefit from integration of sediment transport pathways, budgets, and metrics during planning and modeling of restoration outcomes, in order to evaluate sustainability before investment. This is analogous to the decades of experience with coastal management and engineering on the open coast. Salt marshes are geomorphic features that rely partially on external sediment supply to maintain their network of tidal channels, intertidal flats, and marsh plain. Removing sediment from one component of the overall system to nourish another component may be counterproductive, given that the net sediment budget is unchanged. For example, dredging a tidal channel beyond its equilibrium condition will cause it to fill with sediment from the tidal flat or elsewhere in the system. This may cause slumping of the marsh edge, or over-deepening of other sections of the channel to compensate. Similarly, shoreline protection that prevents edge erosion hampers the marsh plain’s ability to accrete on the levee and naturally transgress landward or it starves other components of the system of regularly supplied sediment. A limited vertical or lateral-only perspective, instead of a three-dimensional perspective, during project planning and evaluation may lead to suboptimal decision-making regarding restoration priorities, approaches, and outcomes. I contend that before significant investments are made in marsh restoration through sediment nourishment or shoreline protection, sediment transport measurements and models that consider sediment dynamics should be integrated into the early phases of restoration planning. This will help identify where and under what conditions marsh restoration will most likely be successful and economically justified. Triaging and prioritizing is then possible, which is a sustainable approach for restoration, given the persistent vulnerability of marshes to sea-level rise, storms, and sediment deficits.

Estuaries and Coasts